Geology topics

Walter E. Dean

Publications and source records attributed to Walter E. Dean.

At least 73 records · Page 4Linked to original sources

USGS1988

Pyrite formation in the Lower Cretaceous Mowry Shale: Effect of organic matter type and reactive iron content

Geochemical analysis of the Lower Cretaceous Mowry Shale in Wyoming and Montana shows that organic matter type and reactive iron content limited pyrite formation during early diagenesis. Consequently, direct interpretation of paleosalinity cannot be made from a carbon/sulfur plot. Mowry Shale samples with hydrogen index (HI) less than 150 (mg hydrocarbon/ organic carbon) contain low amounts of sulfur. In these samples, bacterial reduction of sulfate may have been inhabited by low nutritive content of the organic matter. For Mowry samples with HI greater than 150 there is a range of sulfur values and a positive correlation between iron and sulfur. The iron sulfur regression is approximately parallel to the stoichiometric pyrite line and intersects the iron axis at 0.5 percent. On average, 60 percent of the iron present was nonreactive; the remaining iron reacted with sulfide to form pyrite. For samples with HI greater than 150, pyrite formation was limited by sulfide or organic carbon content but by reactive iron content. In one modern setting, where salinity is greater than one-half normal seawater, sulfate content does not limit pyrite formation (Berner and Raiswell, 1984). From this analysis then, it can be estimated that the Mowry Sea was not a fresh water body but was either of normal marine salinity or contained brackish water with greater than one-half normal salinity.

Wyoming↗

USGS1987

15N/14N variations in Cretaceous Atlantic sedimentary sequences: Implication for past changes in marine nitrogen biogeochemistry

At two locations in the Atlantic Ocean (DSDP Sites 367 and 530) early to middle Cretaceous organic-carbon-rich beds (“black shales”) were found to have significantly lower δ 15 N values (lower 15 N/ 14 N ratios) than adjacent organic-carbon-poor beds (white limestones or green claystones). While these lithologies are of marine origin, the black strata in particular have ° 15 N values that are significantly lower than those previously found in the marine sediment record and most contemporary marine nitrogen pools. In contrast, black, organic-carbon-rich beds at a third site (DSDP Site 603) contain predominantly terrestrial organic matter and have C- and N-isotopic compositions similar to organic matter of modern terrestrial origin. The recurring 15 N depletion in the marine-derived Cretaceous sequences prove that the nitrogen they contain is the end result of an episodic and atypical biogeochemistry. Existing isotopic and other data indicate that the low 15 N relative abundance is the consequence of pelagic rather than post-depositional processes. Reduced ocean circulation, increased denitrification, and, hence, reduced euphotic zone nitrate availability may have led to Cretaceous phytoplankton assemblages that were periodically dominated by N 2 -fixing blue-green algae, a possible source of this sediment 15 N-depletion. Lack of parallel isotopic shifts in Cretaceous terrestrially-derived nitrogen (Site 603) argues that the above change in nitrogen cycling during this period did not extend beyond the marine environment.

Earth and Planetary Science Letters↗

USGS1987

Inorganic and organic geochemistry of Eocene to Cretaceous strata recovered from the lower continental rise, North American Basin, Site 603, Deep Sea Drilling Project Leg 93

About one hundred samples of sediments and rocks recovered in Hole 603B were analyzed for type, abundance, and isotopic composition of organic matter, using a combination of Rock-Eval pyrolysis, C-H-N-S elemental analysis, and isotope-ratio mass spectrometry. Concentrations of major, minor, and trace inorganic elements were determined with a combination of X-ray fluorescence and induction-coupled plasma spectrometry. The oldest strata recovered in Hole 603B (lithologic Unit V) consist of interbedded light-colored limestones and marlstones, and black calcareous claystones of Neocomian age. The inorganic and organic geochemical results suggest a very terrigenous aspect to the black claystones. The organic geochemical results indicate that the limestones and marlstones contain a mixture of highly degraded marine and terrestrial organic matter. Comparison of the Neocomian carbonates at Site 603 with those on the other side of the North Atlantic, off Northwest Africa at Site 367, shows that the organic matter at Site 367 contains more marine organic matter, as indicated by higher pyrolysis hydrogen indices and lighter values of δ 13 C. Comparison of inorganic geochemical results for the carbonate lithologies at Site 603 with those for carbonate lithologies at Site 367 suggests that the Site 603 carbonates may contain clastic material from both North American and African sources. The black claystones at Site 603, on the other hand, probably were derived almost entirely from North American clastic sources. Lithologic Unit IV overlying the Neocomian carbonates, consists of interbedded red, green, and black claystones. The black claystones at Site 603 contain more than ten times the organic carbon concentration of the interbedded green claystones. The average concentration of organic carbon in the black claystones (2.8%), however, is low relative to most mid-Cretaceous black claystones and shales in the Atlantic, particularly those found off Northwest Africa. The geochemical data all suggest that the organic matter in the black claystones is more abundant but generally more degraded than the organic matter in the green claystones, and that it was derived mainly from terrestrial sources and deposited in oxygenated bottom waters. The increased percentage of black claystone beds in the upper Cenomanian section, and the presence of more hydrogen-rich organic matter in this part of the section, probably resulted from the increased production and accumulation of marine organic matter that is represented worldwide near the Cenomanian/Turonian boundary in deep-sea and land sections. A few upper Cenomanian black claystone samples that have hydrogen indices > 150 also contain particularly high concentrations of V and Zn. Most samples of black claystone, however, are not particularly metal-rich compared with other black claystones and shales. Compared with red claystones from lithologic Unit IV, the green and black claystones are enriched in many trace transition elements, especially V, Zn, Cu, Co, and Pb. The main difference between the "carbonaceous" claystones of lithologic Unit IV and "variegated" or "multicolored" claystones of the overlying Upper Cretaceous to lower Tertiary Unit III is the absence of black claystone beds. As observed at several other sites (105 and 386), the multicolored claystones at Site 603 are somewhat enriched in several trace transition elements—especially Cu, Ni, and Cr—relative to most deep-sea clays. The multicolored claystones are not enriched in Fe and Mn, and therefore are not "metalliferous" sediments in the sense of those found at several locations in the eastern Pacific. The source of the slightly elevated concentrations of transition metals in the multicolored claystones probably is upward advection and diffusion of metals from the black claystones of the underlying Hatteras Formation. The red, orange, and green claystone beds of lithologic Unit II (Eocene), like those of Unit III, really represent a continuation of deposition of multicolored claystone that began after the deposition of the Neocomian carbonates. The color of the few black beds that occur within this unit results from high concentrations of manganese oxide rather than high concentrations of organic matter.

Initial Reports of the D.S.D.P.↗

USGS1986

Depletion of 13C in Cretaceous marine organic matter: Source, diagenetic, or environmental sigal?

Geochemical studies of Cretaceous strata rich in organic carbon (OC) from Deep Sea Drilling Project (DSDP) sites and several land sections reveal several consistent relationships among amount of OC, hydrocarbon generating potential of kerogen (measured by pyrolysis as the hydrogen index, HI), and the isotopic composition of the OC. First, there is a positive correlation between HI and OC in strata that contain more than about 1% OC. Second, percent OC and HI often are negatively correlated with carbon isotopic composition (σ 13 C) of kerogen. The relationship between HI and OC indicates that as the amount of organic matter increases, this organic matter tends to be more lipid rich reflecting the marine source of the organic matter. Cretaceous samples that contain predominantly marine organic matter tend to be isotopically lighter than those that contain predominantly terrestrial organic matter. Average σ 13 C values for organic matter from most Cretaceous sites are between −26 and −28‰, and values heavier than about −25‰ occur at very few sites. Most of the σ 13 C values of Miocene to Holocene OC-rich strata and modern marine plankton are between −16 to −23‰. Values of σ 13 C of modern terrestrial organic matter are mostly between −23 and −33‰. The depletion of terrestial OC in 13 C relative to marine planktonic OC is the basis for numerous statements in the literature that isotopically light Cretaceous organic matter is of terrestrial origin, even though other organic geochemical and(or) optical indicators show that the organic matter is mainly of marine origin. A difference of about 5‰ in σ 13 C between modern and Cretaceous OC-rich marine strata suggests either that Cretaceous marine planktonic organic matter had the same isotopic signature as modern marine plankton and that signature has been changed by diagenesis, or that OC derived from Cretaceous marine plankton was isotopically lighter by about 5‰ relative to modern plankton OC. Diagenesis does not produce a significant shift in σ 13 C in Miocene to Holocene sediments, and therefore probably did not produce the isotopically light Cretaceous OC. This means that Cretaceous marine plankton must have had σ 13 C values that were about 5‰ lighter than modern marine plankton, and at least several per mil lighter than Cretaceous terrestrial vegetation. The reason for these lighter values, however, is not obvious. It has been proposed that concentrations of CO 2 were higher during the middle Cretaceous, and this more available CO 2 may be responsible for the lighter σ 13 C values of Cretaceous marine organic matter.

Marine Geology↗

USGS1986

Rhythmic bedding in Upper Cretaceous pelagic carbonate sequences: Varying sedimentary response to climatic forcing

Rhythmic bedding is a prominent feature of North American and European Upper Cretaceous pelagic carbonate sequences deposited in epicontinental and continental-edge settings. Such bedding rhythms can result from variations in carbonate productivity, terrigenous dilution, redox conditions, or bottom currents. Each type of bedding cycle is expressed differently in the stratigraphic record but probably was caused by climatic cycles that are linked to variations in the Earth's orbital characteristics (Milankovitch cycles). Thus, pelagic carbonates of Cretaceous age acted as particularly sensitive recorders of orbitally induced changes in climate. Documentation of these bedding rhythms will permit detailed chronostratigraphic and lithostratigraphic correlations and will further illuminate depositional processes in Upper Cretaceous carbonate sequences.

Geology↗

USGS1986

Cretaceous paleoceanography of the western North Atlantic Ocean

In this paper we summarize available information on the Cretaceous lithostratigraphy and paleoceanography of the western North Atlantic. The data and some of our interpretations draw in large part on papers published in the Deep Sea Drilling Project (DSDP) volumes. We have attempted to cite relevant references when possible, but space limitations make it difficult to give proper credit to all sources; we apologize for any omissions. Organic carbon (Corg) and carbonate (CaCO 3 ) analyses were tabulated for each site from papers in the DSDP Initial Report volumes and other published works (e.g., Summerhayes,1981). Corg, CaCO 3 , and non-CaCO 3 mass accumulation rates (MARS) were calculated using core by core averages of component percentages for the more continuously cored sites; core averages for wet bulk density and porosity (from DSDP data files); biostratigraphies of de Graciansky and others (1982), Roth and Bowdler (1981), and Cool (1982); and the time scales of the Decade of North American Geology (Palmer, 1983; Kent and Gradstein, this volume) or Harland and others (1982; see Plate 1). Backtracked paleodepths for western North Atlantic DSDP Sites from Tucholke and Vogt (1979) with the revised stratigraphy of de Graciansky and others (1982) were used in plotting Corg and CaCO 3 in Figures 2, 3, 4 and 5 (see also Thierstein, 1979). Backtracking curves of seafloor paleodepth versus age (Sclater and others, 1977; Tucholke and Vogt, 1979) for selected western North Atlantic DSDP sites. Average CaCO 3 concentrations per core are shown by code number

Book chapter↗

USGS1986

Late Neogene and Quaternary coarse-fraction and carbonate stratigraphies for Site 586 on Ontong-Java Plateau and Site 591 on Lord Howe Rise

Carbonate oozes recovered by hydraulic piston coring at DSDP Site 586 on Ontong-Java Plateau and Site 591 on Lord Howe Rise have carbonate contents that are consistently higher than 90% with only minor variations. Consequently, paleoceanographic signals were not recorded in detail in the carbonate contents. However, mass accumulation rates of carbonate increased in the late Miocene to mid-Pliocene, reflecting an increase in productivity, then abruptly decreased from mid-Pliocene to the present. Variations in relative abundances of coarse material (foraminifers) and fine material (mostly calcareous nannofossils) do reflect histories of current winnowing and biogenic productivity at the two sites. The late Miocene from 10.5 to 6.5 m.y. ago was a time of relatively constant, quiet, pelagic sedimentation with typical southwest Pacific sedimentation rates of 20-25 m/m.y. The average coarse-fraction abundances are always higher at Site 586 than at Site 591, which reflects winnowing at Site 586. These conditions were interrupted between 6.5 to 4.0 m.y. ago when increased upwelling at the Subtropical Divergence and the Equatorial Divergence produced greater productivity of calcareous planktonic organisms. The increased productivity is suggested by large increases in both fineand coarse-fraction material and constant ratios of foraminifers to nannofossils. The maximum of productivity was about 4.0 m.y. ago. This period of increased upwelling is coincident with the inferred development of the West Antarctic ice sheet. The high productivity was followed by an abrupt increase in winnowing about 2.5 m.y. ago at Site 591, but not until about 2.0 m.y. ago at Site 586. By 2.0 m.y. ago in the late Pliocene, quiet, pelagic sedimentation conditions prevailed, similar to those of the late Miocene. The last 0.7 m.y. has been a period of relatively intense winnowing on Lord Howe Rise but not on Ontong-Java Plateau. The coarse-fraction data have both long- and short-period fluctuations. Long-period fluctuations at Site 591 average about 850 × 103 yr./cycle and those at Site 586 average 430 × 103 yr./cycle. The highest amplitudes are found in the Pliocene and Quaternary sections. The short-period fluctuations range from 100 to 48 × 103 yr./cycle at Site 586 and from 250 to 33 × 103 yr./cycle at Site 591. The effects of local fluctuations of productivity and winnowing have modified the primary orbital forcing signals at these two sites to yield complex paleoceanographic records

Initial Reports of the D.S.D.P.↗

USGS1985

Sedimentation in a blast-zone lake at Mount St. Helens, Washington—Implications for varve formation

Sediment collected in traps in a newly formed lake in the blast-impact area at Mount St. Helens recorded a sediment yield that is about two orders of magnitude greater than for comparable basins with vegetation and similar precipitation. Most sediment was mobilized by storms and runoff at the onset of the wet season. The sedimentation response to strongly seasonal precipitation, in the absence of vegetation, produced turbidites and graded annual couplets. The style of sedimentation suggests an alternate mechanism for the formation of long sequences of graded clastic varves.

Washington↗

USGS1985

Classification of deep-sea, fine-grained sediments

Most deep-sea sediments contain one or more biogenic components and one dominant nonbiogenic component, usually clay or silty clay. The authors present a descriptive classification scheme in which deep-sea, fine-grained sediments are placed within a three-components system of calcareous-biogenic, siliceous-biogenic, and nonbiogenic components. In a three-procedure the user assesses whether the dominant component is biogenic or nonbiogenic, whether the dominant biogenic component is siliceous or calcareous, and what the relative abundances of the biogenic components are within limits of 10, 25, and 50%. The terminology proposed is that commonly used by many sedimentologists, with some refinements and greater precision in the use of terms.

Journal of Sedimentary Petrology↗

USGS1985

Comparative geochemical and mineralogical studies of two cyclic transgressive pelagic limestone units, cretaceous Western Interior Basin, U.S.

Pelagic limestone units were deposited in the North American Western Interior seaway during two major Cretaceous transgressive episodes. The Bridge Creek Limestone Member of the Greenhorn Formation, deposited during the Late Cenomanian-Early Turonian transgression, and the Smoky Hill Member of the Niobrara Formation, deposited during the overall Early Coniacian-Early Campanian transgression, are both enriched in organic-carbon and exhibit smallscale carbonate cycles representing periodicities in the range 20 to 40 ky. The distinct periodicity and overall unusual depositional milieu of both units are reflected in their sedimentary structures, mineralogy, and geochemistry. The Bridge Creek Limestone at Pueblo, Colorado, averages 78% CaCO 3 and 1.75% organic carbon with ranges of 42-96% and 0.06-6.97%, respectively, across small-scale cycles. High concentrations of Al, Fe, Mg, K, Ti, Na, Cr, Ni, V; higher Sr/Ca and lower Si/Al ratios; and lighter δ 18 0 in CaCO 3 in dark-colored clay-rich beds all suggest periodic influx of terrestrial clay minerals during times of peak fresh water runoff from uplifted highlands to the west. Higher Sr/Ca ratios in marlstone beds than in limestone beds suggest that the marlstone beds have undergone less diagenetic removal of Sr. Higher concentrations of organic carbon, hydrogen, and sulfur, and preservation of some lamination in the clay-rich beds also suggest that the times of enhanced runoff may have induced stable salinity stratification in the water column, which led to gradual depletion of dissolved oxygen in the bottom waters and enhanced preservation of organic carbon in sediments. The geochemistry also suggests that a significant change in sedimentation occurred at the Cenomanian-Turonian boundary. The geochemical characteristics of the Niobrara Formation near Fort collins, Colorado, are very similar to those of the Bridge Creek Limestone at Pueblo, suggesting similar depositional conditions and source of clastic materials. However, the small scale cycles are present but more subdued in the Niobrara Formation than in the Bridge Creek Limestone, and the Niobrara Formation in the Fort Collins area has not been as altered by diagenesis.

SEPM Special Publication↗

USGS1985

EVALUATION OF THE EFFECTS OF WEATHERING ON A 50-YEAR OLD RETORTED OIL-SHALE WASTE PILE, RULISON EXPERIMENTAL RETORT, COLORADO.

An oil-shale mine and experimental retort were operated near Rulison, Colorado by the U. S. Bureau of Mines from 1926 to 1929. Samples from seven drill cores from a retorted oil-shale waste pile were analyzed to determine 1) the chemical and mineral composition of the retorted oil shale and 2) variations in the composition that could be attributed to weathering. Unweathered, freshly-mined samples of oil shale from the Mahogany zone of the Green River Formation and slope wash collected away from the waste pile were also analyzed for comparison. The waste pile is composed of oil shale retorted under either low-temperature (400-500 degree C) or high-temperature (750 degree C) conditions. The results of the analyses show that the spent shale within the waste pile contains higher concentrations of most elements relative to unretorted oil shale.

Conference Paper↗

USGS1985

Cyclic variations in calcium carbonate and organic carbon in Miocene to Holocene sediments, Walvis Ridge, South Atlantic Ocean

The entire upper Miocene to Holocene sedimentary sequence recovered in a hydraulic piston core at DSDP Site 532 on Walvis Ridge shows distinct cycles in amount of CaCO sub(3) that correlate with dark and light cycles of sediment color. The average periodicities of the carbonate cycles for the Quaternary, upper Pliocene, and lower Pliocene are about 35, 46, and 28 ky, respectively, with an overall average of about 36 ky for the last 5 my. Most minima in carbonate abundance correspond to dark parts of the color cycles, and most maxmia in carbonate abundance correspond to dark parts of color cycles, The darker parts of the color cycle usually contain higher concentrations of organic carbon, but organic carbon does not follow the color cycles in detail. Organic carbon cycles were analyzed only for the last 2.5 my, and for this interval they have an average periodicity of about 34 ky. The carbonate and color cycles persist through more than 5my during which major changes in relative proportions of siliceous-biogenic, calcareous- biogenic and terrigenous- clastic components occurent in response to climate change and to the waxing and waning of the Benguela Current upwelling systems off southwest Africa. The cyclic nature of these sediments probably is the result of dilution by terrigrnous clastic material and not dissolution of carbonate. We believe that the forcing mechanisms that produced the cycliclity was external to the area of site 532. Because of the similarity among the periodicities of the Walvis Ridge cycles and those of carbonate cycles in the northeastern Atlantic, Caribbean and eastern equatorial Pacific, these cycles probably are responses to global events. We conclude that fluctuations om global sea level with an average period of about 36 ky during the last 5 my caused variations in influx of terrigenous clastic materials from the Africans continental margin

Book chapter↗

USGS1984

The variability of Holocene climate change: Evidence from varved lake sediments

Varved sediments from a lake near the present forest-prairie border in northwestern Minnesota provide an annual record of climate change for the last 10,400 years. Climate-sensitive mineral, chemical, and biological components show that the mid-Holocene dry interval between 8500 and 4000 years ago is asymmetrical and actually consists of two distinct drier pulses separated by a moister interval that lasted about 600 years. Cyclic fluctuations with periods of several hundred years were abrupt and persistent throughout the Holocene and are most clearly recorded within the two drier pulses.

Minnesota↗

USGS1984

Shimada Seamount: An example of recent mid-plate volcanism

Shimada Seamount is an isolated volcanic feature located between the Clipperton and Clarion Fracture Zones ∼1,150 km west of the East Pacific Rise and ∼600 km west of the inactive spreading center represented by the Mathematician Seamounts. It rises ∼3,900 m above the surrounding sea floor to within 50 m of present-day sea level. The area of Shimada Seamount should be volcanically dormant, because it is far from an active spreading center and is located on oceanic crust of early Miocene age. Nevertheless, evidence was found that Shimada Seamount has formed geologically recently. For example, seismic-reflection profiles-indicate that virtually no sediment has accumulated on the summit or flanks of the seamount; television, still-camera, and dredge-haul data indicate that a platform near the summit at a water depth of ∼180 m is a carbonate build-up formed by coralline red algae attached to fresh pillow basalt. Glassy pillow basalt too young to date by the K/Ar method and showing little or no devitrification and lacking manganese encrustations was dredged from the seamount below the algal reefs (500–750 m). Several cores taken from the adjacent basin (∼3,900 m deep) contain fresh glassy basalt detritus, and one core sampled a thin flow of unaltered basaltic glass at the sediment surface. The origin and history of Shimada Seamount differ importantly from volcanoes generally thought to form at spreading centers, along transform faults, or at hot spots. The existence of Shimada Seamount, therefore, has implications about tectonic processes that occur in interplate regions.

GSA Bulletin↗

USGS1984

Models for the deposition of Mesozoic-Cenozoic fine-grained organic-carbon-rich sediment in the deep sea

The widespread occurrence of organic-carbon-rich strata (‘black shales’) in certain portions of Jurassic, Cretaceous and Cenozoic sequences has been well-documented from Deep Sea Drilling Project sites in the Atlantic and Pacific Oceans and from sequences, now exposed on land, originally deposited in the Tethyan ocean. These ancient black shales usually have been explained by analogy with examples of modern deep-sea sediments in which organic matter locally is preserved by (1) increasing the supply of organic matter, (2) increasing the rate of sedimentation, and/or (3) decreasing the oxygen content of the bottom water. However, detailed examination of many black shales reveals characteristics that cannot be explained by simple local models, including: their approximate coincidence in time globally; their occurrence in a variety of different environments, including open oxygenated oceans, restricted basins, deep and shallow water; their interbedding with organic-carbonpoor strata which often dominate a so-called black shale sequence; their deposition by pelagic, hemipelagic, turbiditic and other processes; and the variations in type and amount of organic matter that occur even within the same sequence. A more complex model for the origin of black shales therefore appears most appropriate, in which the cyclic preservation of organic matter depends on the interplay of the three main variables, namely supply of organic matter, sedimentation rate, and deep-water oxygenation, each of which varies independently to some extent. The variation and relative importance of these parameters in individual basins and widespread black shale deposition in general are linked globally and temporally by changes in global sea-level, climate and related changes in oceanic circulation. An important and often overlooked factor for the supply of organic matter to deep-basin sediments is the frequency and magnitude of redepositional processes. The interplay of these variables is discussed in relation to the middle Cretaceous and Cenozoic organic-carbon-rich strata, in particular, which show marked differences in the relative importance of the different variables.

Geological Society of London Special Publications↗

USGS1984

Geologic evolution, sedimentation, and paleoenvironments of the Angola Basin and adjacent Walvis Ridge: Synthesis of results of Deep Sea Drilling Project Leg 75

The section recovered at Site 530 (Holes 53OA and 530B) consists of eight sedimentary units and one basalt unit. The composition of the basalt recovered in Hole 53OA is distinct from typical mid-ocean ridge basalts (MORBs) but is similar to that of Hawaiian tholeiites and basalt from the central part of Walvis Ridge. Throughout most of its history, the southern Angola Basin received large volumes of redeposited material in the form of turbidites and, most recently, debris-flow deposits. Most of this material was derived from Walvis Ridge to the south, but thickness trends of acoustic units suggest that some of the sediment was derived from the African continental margin to the east. The basal sedimentary unit (Albian to Santonian) at Site 530 contains 262 beds of black shale that are interbedded with green and red claystone. Black shale makes up less than 10% of the total section, but in two cores of early Turonian age, black shale beds compose about 50% of the section. The black shales contain up to 19% organic carbon (average of about 5%) that is mainly of autochthonous marine origin but with significant contributions from terrigenous organic matter. The origin of these more- and less-reduced interbedded lithologies with varying amounts and types of organic matter, and variable amounts of pelagic, hemipelagic, and turbiditic sediment is complex and cannot be explained by any one simple process. Many factors affecting the concentration of dissolved oxygen in the bottom waters of the Angola Basin varied throughout the middle Cretaceous to produce bottom-water conditions that fluctuated between mildly oxic and oxygen-deficient, but most of the time bottom-waters and sediment-interstitial waters were sufficiently oxic to permit the accumulation of red oxidized sediment. A relatively complete sedimentary record of the Cretaceous/Tertiary boundary was recovered within a sequence of mudstone and marlstone turbidites in Hole 530A. There is a significant increase in the concentration of iridium above background levels at the boundary. High concentrations of many other elements also occur within the same stratigraphic interval as the iridium anomaly. Furthermore, there is a marked decrease in CaCO3 in the Tertiary strata above the iridium anomaly which suggests that the production of shallow-water carbonate also may have been affected by whatever caused elevated concentrations of iridium and other elements. These observations are consistent with the asteroid-impact theory proposed to explain the worldwide occurrence of an iridium anomaly at the Cretaceous/Tertiary boundary. The Cenozoic history of the Angola Basin was controlled mainly by (1) restriction of bottom-water flow from the south by Walvis Ridge; (2) development of glaciation on Antarctica; (3) opening of circulation passages in the southern oceans; (4) rapid turnover of cold, nutrient-rich waters that resulted in high productivity of diatoms; (5) influx of terrigenous sediment mainly by turbidity currents; and (6) production and preservation of carbonate sediment. The most distinctive Cenozoic event recorded in the section at Site 530 is the beginning of extensive glaciation on Anarctica and concomitant initiation of modern thermohaline bottom-water circulation that is manifested as a middle Eocene to middle Oligocene unconformity or compressed section accompanied by a drastic decrease in accumulation of CaCO3. Diatom abundances in HPC cores from Walvis Ridge (Site 532) and Angola Basin (Hole 53OB) indicate that Benguela upwelling in these areas began in the late Miocene, reached a peak in the late Pliocene to early Pleistocene, and declined thereafter. Short-term variations in sediment composition at Site 532 are manifested as cyclic variations in concentrations of clay, CaCO3, and organic carbon with average periodicities of about 30-60 k.y. The main variability that produced the cycles probably was the influx of terrigenous clastic material which diluted the CaCO3. The sediment at Site 532 also contains several percent organic carbon that is dominantly of marine origin, but with significant terrigenous components. Data from multichannel seismic, gravity, and magnetic surveys were used to define the regional stratigraphic and structural evolution of Walvis Ridge and adjacent Cape and Angola basins. Six structural provinces are recognized, four on Walvis Ridge and two additional provinces that correspond to the Cape and Angola basins. The two eastern structural provinces on Walvis Ridge are underlain by continental crust. The two western structural provinces are underlain by oceanic basement. Two main directions of faults are evident in seismic profiles, one trending N 10° and one trending N 60°. The N 60° trend corresponds to the general orientation of the northern and southern flanks of Walvis Ridge as well as to the dominant direction of fracture zones. During the first phase of separation of Africa from South America (ca. 120-130 m.y. ago), a voluminous mass of volcanics was emplaced simultaneous with the emplacement of basalt in the Parana Basin of Brazil and the Kaokoveld Region of South Africa. This period of volcanism also formed the series of seaward-dipping internal basement reflectors that are characteristic of the two structural provinces of Walvis Ridge. A system of fault blocks developed in the brittle upper part of the newly formed crust. During the second phase of rifting, which ended before late Aptian, more tilted fault blocks were created in the upper brittle stratified continental crust. Magnetic lineations in basement rocks in the Angola and Cape basins in the vicinity of Walvis Ridge are not distinct but suggest that oceanic crust began to be emplaced between 120 and 112 m.y. ago (Barremian to early Aptian). At least part of the oceanic crust of the central plateau of eastern Walvis Ridge (structural province 3) may have been emplaced before any oceanic crust formed in the adjacent basins. A ridge jump occurred during the late Aptian to early Albian in the southern part of the Angola Basin which translated the previously formed oceanic crust and its overlying evaporite deposits on the South American side. Several ridge jumps occurred on both sides of Walvis Ridge during the Late Cretaceous and early Tertiary to produce a 500-km-long segment of mid-ocean ridge.

Initial Reports of the D.S.D.P.↗

USGS1984

Middle Cretaceous black shales at Site 530 in the southeastern Angola Basin

The middle Cretaceous black shale interval at Site 530 is 170 m thick and late Albian to Coniacian in age. The organic-carbon-rich sediments occur as 260 separate beds (average 4 cm, maximum 60 cm thick) and make up less than 10% of the recovered section. Associated lithologies are greenish, grayish, and reddish mudstones, marlstones, and rare limestones. Organic-carbon contents of the black shales average about 5% (maximum 16%), and of the interbedded sediments, less than 0.5%. Careful study of the sedimentary and biogenic structures and composition and review of paleoceanographic conditions in the Angola Basin indicate that a complex interplay of processes controlled black shale accumulation. Relatively low oxygen concentrations in sediment and bottom waters occurred periodically, and conditions locally may have been anoxic or near anoxic both in the basin and on the continental margin. Pelagic, hemipelagic, and turbiditic depositional processes all operated to varying degrees at different times.

Initial Reports of the D.S.D.P.↗

USGS1984

Origin and geochemistry of Cretaceous deep-sea black shales and multicolored claystones, with emphasis on Deep Sea Drilling Project Site 530, southern Angola Basin

Deep-water sedimentary sequences of mid-Cretaceous age, rich in organic carbon, have been recovered at many DSDP sites in the Atlantic Ocean. Most of these sequences have a marked cyclicity in amount of organic carbon resulting in interbedded multicolored shale, marlstone, and (or) limestone that have cycle periods of 20,000 to 100,000 years and average 40,000 to 50,000 years. These cycles may be related to some climatic control on influx of terrigenous organic matter and sediment, rates of upwelling and sea-surface production of organic matter, and preservation of organic matter related to deeper-water dissolved oxygen concentration. These variations in supply of organic matter had pronounced effects on the potential of the sediment for subsequent diagenetic changes and geochemical partitioning in adjacent beds. Many trace elements are enriched in organic-carbon-rich lithologies relative to interbedded organic-carbon-poor lithologies. Elements that are most commonly enriched are Cr, Ni, V, Cu, Zn, and Mo. The association of high traceelement concentrations with organic matter may be the result of concentration of these elements by organisms or by chemical sorption and precipitation processes under anoxic conditions. Detailed trace-element profiles from organiccarbon-rich strata at Site 530 suggest that there may be differential mobility of trace elements, with diffusion of some elements over distances of at least tens of meters. The sequence of trace-element mobility, from highest to lowest, is approximately Ba, Mn, Pb, Ni, Co, Cr, Cu, Zn, V, Cd, and Mo. Slowly deposited, oxidized clays directly overlying some black shale sequences are enriched in some metals, particularly Fe, Mn, Zn, and Cu, relative to normal pelagic clays, and this enrichment may be the result of upward migration of metals in pore waters during compaction or diffusion from the underlying black shale. Most depositional models that have been used to explain the accumulation of the organic-carbon-rich strata imply that reducing conditions in the sediments (and therefore the increased degree of preservation of organic matter) were the result of anoxic or near-anoxic conditions in oceanic bottom waters, or in a midwater oxygen-minimum zone. Evidence from several DSDP sites in the Atlantic, however, indicate that some of these middle Cretaceous "black shale" beds may be the result of variations in rate of supply of organic matter that produced anoxia or near-anoxia within midwater oxygen-minimum zones and possibly, under extreme conditions, throughout much of the bottomwater mass. Although bottom-water anoxia may have occurred during periods of organic-carbon-rich strata, it was not necessarily the only cause for accumulation of these strata. The main reason for the accumulation of organic-carbonrich strata was an increase in the relative amount of organic debris being deposited. Some of this organic debris was derived from continental-margin areas of increased production, accumulation, and preservation of organic matter from marine, terrestrial, or mixed sources and transported to slope and basinal sites by turbidity currents.

Initial Reports of the D.S.D.P.↗