Geology topics

Robert A. Ayuso

Publications and source records attributed to Robert A. Ayuso.

At least 19 recordsLinked to original sources

USGS2024

Lead isotopes in New England (USA) volcanogenic massive sulphide deposits: Implications for metal sources and pre-accretionary tectonostratigraphic terranes

Lead isotope values for volcanogenic massive sulfide (VMS) deposits provide important insights into metal sources and the nature of pre-accretionary tectonostratigraphic terranes and underlying basements. Deposits of this type in New England formed in diverse tectonic settings including volcanic arcs and backarcs, a supra–subduction zone arc, a rifted forearc foreland basin, and a rifted continental margin. Following VMS mineralization on or near the seafloor, components of the tectonostratigraphic assemblages—volcanic ± sedimentary rocks, coeval intrusions, sulfide deposits, and underlying basements—were diachronously accreted to the Laurentian margin during the Paleozoic. Lead isotope data for galena show relatively large ranges for 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, and 208 Pb/ 204 Pb. Evaluation of potential lead sources, using for comparison Pb-isotope data from modern and ancient settings, suggests that principal sources include the mantle, volcanic ± sedimentary rocks, and deeper basement rocks. Integration of the Pb-isotope values with published data such as Nd isotopes for the volcanic rocks and from deep seismic reflection profiles points to the involvement of several basements, including those of Grenvillian, Ganderian, Avalonian, and West African (and (or) Amazonian) affinity. Clustering of Pb-isotope data for VMS deposits within individual Cambrian and Ordovician volcanic and volcanosedimentary settings, delineated by differences in 206 Pb/ 204 Pb and µ ( 238 U/ 204 Pb) values, are consistent with lead derivation from at least four and possibly five different tectonostratigraphic assemblages with isotopically distinct basements. Collectively, our Pb-isotope data for New England VMS deposits provide a novel window into the nature of subarc basement rocks during pre-accretionary sulfide mineralization outboard of Laurentia during early Paleozoic time.

Canadian Journal of Earth Sciences↗

USGS2024

Conventional rare earth element mineral deposits: The global landscape

Four conventional mineral deposit types—carbonatite, alkaline igneous, heavy mineral sand, and regolith-hosted ion-adsorption clay deposits—currently supply global markets with the rare earth elements (REEs) and rare earth oxides (REOs) necessary to meet the technological needs of global communities. The unique properties of REEs make them useful in a wide variety of applications, such as alloys, batteries, catalysts, magnets, phosphors, and polishing compounds. Rare earth element minerals are complex in both composition and structure. Carbonate, oxide, silicate, and phosphate-type minerals contain highly variable amounts of rare earths. Most rare earth-bearing minerals contain mainly lighter rare earths, a mixture of all the rare earths, or only the heavier rare earths. Diverse technological applications require the full range of light, middle, and heavy rare earths. The production of these elements, in particular the heavy rare earths, remains highly dependent on deposits from China. Diversification of rare earth supply chains is contingent on expanded knowledge of globally distributed resources and an understanding of the degree to which those resources have been explored and evaluated. The knowledge of tectonic setting, typical rock associations, deposit morphology, and deposit genesis has led to the discovery of many conventional-type rare earth deposit types. Recent developments are anticipated to result in further discoveries that have the potential to meet the ever-expanding applications of REEs and REOs to address modern societal needs.

Book chapter↗

USGS2022

Mineral sources and transport pathways for arsenic release in a coastal watershed, USA

Metasedimentary bedrock of coastal Maine contains a diverse suite of As-bearing minerals that act as significant sources of elements found in ground and surface waters in the region. Arsenic sources in the Penobscot Formation include, in order of decreasing As content by weight: löllingite and realgar ( c. 70%), arsenopyrite, cobaltite, glaucodot, and gersdorffite (in the range of 34–45%), arsenian pyrite (<4%), and pyrrhotite (<0.15%). In the Penobscot Formation, the relative stability of primary As-bearing minerals follows a pattern where the most commonly observed highly altered minerals are pyrrhotite, realgar, niccolite, löllingite > glaucodot, arsenopyrite-cobaltian > arsenopyrite, cobaltite, gersdorffite, fine-grained pyrite, Ni-pyrite > coarse-grained pyrite. Reactions illustrate that oxidation of Fe-As disulphide group and As-sulphide minerals is the primary release process for As. Liberation of As by carbonation of realgar and orpiment in contact with high-pH groundwaters may contribute locally to elevated contents of As in groundwater, especially where As is decoupled from Fe. Released metals are sequestered in secondary minerals by sorption or by incorporation in crystal structures. Secondary minerals acting as intermediate As reservoirs include claudetite ( c. 75%), orpiment (61%), scorodite ( c. 45%), secondary arsenopyrite ( c. 46%), goethite (<4490 ppm), natrojarosite (<42 ppm), rosenite, melanterite, ferrihydrite, and Mn-hydroxide coatings. Some soils also contain Fe-Co-Ni-arsenate, Ca-arsenate, and carbonate minerals. Reductive dissolution of Fe-oxide minerals may govern the ultimate release of iron and arsenic – especially As(V) – to groundwater; however, dissolution of claudetite (arsenic trioxide) may directly contribute As(III). Processes thought to explain the release of As from minerals in bedrock include oxidation of arsenian pyrite or arsenopyrite, or carbonation of As-sulphides, and most models based on these generally rely on discrete minerals or on a fairly limited series of minerals. In contrast, in the Penobscot Formation and other metasedimentary rocks of coastal Maine, oxidation of As-bearing Fe-cobalt-nickel-sulphide minerals, dissolution (by reduction) of As-bearing secondary As and Fe hydroxide and sulphate minerals, carbonation and/or oxidation of As-sulphide minerals, and desorption of As from Fe-hydroxide mineral surfaces are all thought to be involved. All of these processes contribute to the occurrence of As in groundwaters in coastal Maine, as a result of variability in composition and in stability of the As source minerals. Arsenic contents of soils and groundwater thus reflect the predominant influence and integration of a spectrum of primary mineral reservoirs (instead of single or unique mineral reservoirs). Cycling of As through metasedimentary bedrock aquifers may therefore depend on consecutive stages of carbonation, oxidation and reductive dissolution of primary and secondary As host minerals.

Maine↗

USGS2022

Anthropogenic and natural lead isotopes in Fe-hydroxides and Fe-sulphates in a watershed associated with arsenic-enriched groundwater, Maine, USA

A survey of the natural and anthropogenic sources of lead contributing to secondary minerals in sulphidic schists associated with arsenic-enriched groundwater in Coastal Maine shows that the most likely source is natural Pb, particularly from coexisting sulphide minerals. The secondary minerals also reflect notable contributions from anthropogenic Pb. The Pb isotopes establish pathways by which Pb, and by inference As, could have been transported from As-bearing minerals (arsenian pyrite, arsenopyrite, lollingite, orpiment, arsenic oxide and others), via sulphide oxidation or carbonation reactions into multiple generations of secondary minerals (goethite, hematite, jarosite, natrojarosite and others). Lead isotopic compositions of the sulphides and secondary minerals determined by thermal ionization mass spectrometry ( n =53) range widely. Lead and As contents of the sulphides and secondary minerals overlap, and are generally positively correlated. Pyrite, the dominant sulphide in sulphidic schists associated with As-enriched groundwater in Coastal Maine, has values of 206 Pb/ 204 Pb from 18.186 to 18.391, 207 Pb/ 204 Pb from 15.617 to 15.657, 208 Pb/ 204 Pb from 38.052 to 38.210, 206 Pb/ 207 Pb from c . 1.1625 to 1.1760 and 208 Pb/ 207 Pb from c . 2.4276 to 2.4394. Mixtures of Fe-hydroxide and oxide minerals (predominantly goethite and hematite) and secondary Fe-sulphate minerals (jarosite, natrojarosite, rozenite and melanterite) in the sulphidic schists have overlapping but generally higher values of 206 Pb/ 204 Pb from 18.495 to 19.747 (one sample at 21.495), 207 Pb/ 204 Pb from 15.595 to 15.722 (one sample at 15.839), 208 Pb/ 204 Pb from 38.186 to 39.162, 206 Pb/ 207 Pb from c. 1.1860 to 1.2575 (one sample at 1.3855) and 208 Pb/ 207 Pb from c . 2.4441 to 2.4865 than the sulphides. Sulphides from Zn-Pb metal mines are somewhat less radiogenic than sulphides from the schists. Other sulphides (mostly pyrite) associated with pegmatites and granitic rocks are heterogeneous and more radiogenic than the pyrite-rich sulphidic schists. Sulphides from other regional bedrock units also have heterogeneous isotope values. Lead isotopic compositions of the sulphides from the sulphidic schists and coexisting Fe-oxides and Fe-sulphates produced by weathering and alteration overlap, but the secondary minerals extend toward more radiogenic values that broadly indicate the addition of Pb from anthropogenic origin. As a component of Pb from extensively used arsenical pesticides may also be present in the secondary minerals, the range in Pb isotope values is consistent with multiple sources: natural Pb from the schists and anthropogenic Pb (industrial and possibly from agricultural activities). Contributions from past mining activities or from other bedrock sources are not implicated.

Maine↗

USGS2021

Age and tectonic setting of the Quinebaug-Marlboro belt and implications for the history of Ganderian crustal fragments in southeastern New England, USA

Crustal fragments underlain by high-grade rocks represent a challenge to plate reconstructions, and integrated mapping, geochronology, and geochemistry enable the unravelling of the temporal and spatial history of exotic crustal blocks. The Quinebaug-Marlboro belt (QMB) is an enigmatic fragment on the trailing edge of the peri-Gondwanan Ganderian margin of southeastern New England. SHRIMP U-Pb geochronology and geochemistry indicate the presence of Ediacaran to Cambrian metamorphosed volcanic and intrusive rocks dated for the first time between ca. 540–500 Ma. The entire belt may preserve a cryptic, internal stratigraphy that is truncated by subsequent faulting. Detrital zircons from metapelite in the overlying Nashoba and Tatnic Hill Formations indicate deposition between ca. 485–435 Ma, with provenance from the underlying QMB or Ganderian crust. The Preston Gabbro (418 ± 3 Ma) provides a minimum age for the QMB. Mafic rocks are tholeiitic with trace elements that resemble arc and E-MORB sources, and samples with negative Nb-Ta anomalies are similar to arc-like rocks, but others show no negative Nb-Ta anomaly and are similar to rocks from E-MORB to OIB or backarc settings. Geochemistry points to a mixture of sources that include both mantle and continental crust. Metamorphic zircon, monazite, and titanite ages range from 400 to 305 Ma and intrusion of granitoids and migmatization occurred between 410 and 325 Ma. Age and chemistry support correlations with the Ellsworth terrane in Maine and the Penobscot arc and backarc system in Maritime Canada. The arc-rifting zone where the Mariana arc and the Mariana backarc basin converge is a possible modern analog.

Connecticut, Massachusetts, Rhode Island↗

USGS2021

Geophysical insights into Paleoproterozoic tectonics along the southern margin of the Superior Province, central Upper Peninsula, Michigan, USA

The southern margin of the Archean Superior Province in the central Upper Peninsula of Michigan was a nexus for key Paleoproterozoic tectonic events involved in the ~2.1 Ga rifting of proposed Archean supercraton Superia and subsequent assembly of Laurentia. Interpretations of the region’s tectonic history have historically been hampered by extensive Pleistocene glacial and Paleozoic sedimentary cover and a lack of appropriate geophysical data. These rifting and orogenic events formed geologic effects that are readily mappable with modern geophysical methods. New aeromagnetic and gravity data provide a critical means of mapping and interpreting the complex geological framework through cover, allowing development of significantly richer geographical and process-based perspectives on all these tectonic events. Interpretations of Precambrian contacts and structure are here, for the first time, carried >30 km eastward under Paleozoic cover. Effects of ~2.1 Ga rifting are strongly expressed geophysically, including the Dickinson Group, perhaps a unique record of the progression of rift-related sedimentation and magmatism, shown here to be a geographically extensive and largely concealed tectonic feature of the southern Superior Province. The geophysical evidence for plausible ~2.1 Ga rift-related intrusive magmatism includes a previously unrecognized swarm of northeast-striking mafic dikes cutting Archean rocks and gravity lows produced by granites. Effects of the ~1.87–1.83 Ga Penokean orogeny include gravity and magnetic gradients and pattern breaks along the Niagara fault zone suture, abundant evidence for thin-skinned thrusting and folding in the Menominee iron district, and speculative emplacement of an allochthonous sedimentary sequence in the Calumet trough. Numerous east–west trending structures imaged geophysically likely originated, or were significantly reactivated by, post-Penokean deformation. Metamorphic events at ~1.76 Ga and ~1.65 Ga may correspond to orogenies involving younger, outboard Paleoproterozoic crustal provinces recognized in southern Laurentia. For example, the previously unrecognized West Branch fault, separating the Dickinson Group from Archean rocks, is shown to be a major structure in the region, and is a proposed expression of ~1.76 Ga thick-skinned deformation. Oblique disruptions of crudely east–west striking structures have robust geophysical expressions and are speculatively connected to transpressive deformation at ~1.65 Ga. These new geophysical observations and interpretations collectively help illuminate a critical period in the tectonic evolution of Laurentia, as it transitioned from a disparate array of Archean cratons to a more coherent, growing continent.

Minnesota, Wisconsin, Michigan↗

USGS2021

Geophysical insights into Paleoproterozoic tectonics along the southern margin of the Superior Province, central Upper Peninsula, Michigan

No abstract available.

Michigan↗

USGS2018

The Mystic subterrane (partly) demystified: New data from the Farewell terrane and adjacent rocks, interior Alaska

The youngest part of the Farewell terrane in interior Alaska (USA) is the enigmatic Devonian–Cretaceous Mystic subterrane. New U-Pb detrital zircon, fossil, geochemical, neodymium isotopic, and petrographic data illuminate the origin of the rocks of this subterrane. The Devonian–Permian Sheep Creek Formation yielded youngest detrital zircons of Devonian age, major detrital zircon age probability peaks between ca. 460 and 405 Ma, and overall age spectra like those from the underlying Dillinger subterrane. Samples are sandstones rich in sedimentary lithic clasts, and differ from approximately coeval strata to the east that have abundant volcanic lithic clasts and late Paleozoic detrital zircons. The Permian Mount Dall conglomerate has mainly carbonate and chert clasts and yielded youngest detrital zircons of latest Pennsylvanian age. Permian quartz-carbonate sandstone in the northern Farewell terrane yielded abundant middle to late Permian detrital zircons. Late Triassic–Early Jurassic mafic igneous rocks occur in the central and eastern Mystic subterrane. New whole-rock geochemical and isotopic data indicate that magmas were rift related and derived from subcontinental mantle. Triassic and Jurassic strata have detrital zircon age spectra much like those of the Sheep Creek Formation, with major age populations between ca. 430 and 410 Ma. These rocks include conglomerate with clasts of carbonate ± chert and youngest detrital zircons of Late Triassic age and quartz-carbonate sandstone with youngest detrital zircons of Early Jurassic age. Lithofacies indicating highly productive oceanographic conditions (upwelling?) bracket the main part of the Mystic succession: Upper Devonian bedded barite and phosphatic Upper Devonian and Lower Jurassic rocks. The youngest part of the Mystic subterrane consists of Lower Cretaceous (Valanginian–Aptian) limestone, calcareous sandstone, and related strata. These rocks are partly coeval with the oldest parts of the Kahiltna assemblage, an overlap succession exposed along the southern margin of the Farewell terrane. Our findings support previous models suggesting that the Farewell terrane was proximal to the Alexander-Wrangellia-Peninsular composite terrane during the late Paleozoic, and further suggest that such proximity continued into (or recurred during) the Late Triassic–Early Jurassic. But middle to late Permian detrital zircons in northern Farewell require another source; the Yukon-Tanana terrane is one possibility.

Alaska↗

USGS2018

Lead and strontium isotopes as monitors of anthropogenic contaminants in the surficial environment

Book chapter↗

USGS2018

Geochemical and Pb isotopic characterization of soil, groundwater, human hair, and corn samples from the Domizio Flegreo and Agro Aversano area (Campania region, Italy)

A geochemical survey was carried out to investigate metal contamination in the Domizio Littoral and Agro Aversano area (Southern Italy) by means of soil, groundwater, human hair and corn samples. Pb isotope ratios were also determined to identify the sources of metals. Specifically, the investigation focused on topsoils ( n = 1064), groundwater ( n = 26), 25 human hair ( n = 24) and corn samples ( n = 13). Topsoils have been sampled and analysed in a previous study for 53 elements (including potentially harmful ones), and determined by ICP-MS after dissolving with aqua regia. Groundwater was analysed for 72 elements by ICP-MS and by ICP-ES. Samples of human hair were prepared and analysed for 16 elements by ICP-MS. Dried corn collected at several farms were also analysed for 53 elements by ICP-MS. The isotopic ratios of 206 Pb/ 207 Pb and 208 Pb/ 207 Pb in selected topsoil ( n = 24), groundwater ( n = 9), human hair ( n = 9) and corn ( n = 4) samples were analysed from both eluates and residues to investigate possible anthropogenic contamination and geogenic contributions. All data were processed and mapped by ArcGis software to produce interpolated maps and contamination factor maps of potentially harmful elements, in accordance with Italian Environmental Law (Legislative Decree 152/06). Results show that soil sampling sites are characterized by As, Cd, Co, Cr, Cu, Hg, Pb, Se, and Zn contents exceeding the action limits established for residential land use (RAL) and, in some cases, also the action limits for industrial land use (IAL) as established by Legislative Decree 152/06. A map of contamination factors and a map showing the degrees of contamination indicate that the areas in the municipalities of Acerra, Casoria and Giugliano have been affected by considerable anthropogenic-related pollution. To interpret the isotopic data and roughly estimate proportion of Pb from an anthropogenic source we broadly defined possible natural and anthropogenic Pb end-member fields based on literature data. For example, we summarized data for Vesuvius and Campi Flegrei volcanic rocks, gasoline, and aerosol deposits. Lead isotope data show mixing between geogenic and anthropogenic sources. Topsoil, groundwater, human hair and corn samples show a greater contribution from geogenic sources like the Yellow Tuff (from Campi Flegrei) and volcanic rocks from Mt. Vesuvius. Aerosols, fly ash and gasoline (anthropogenic sources) have also been contributors. In detail, 46% of the topsoil residues, 96% of topsoil leachates, 88% of groundwater, 90% of human hair, and 25% of corn samples indicate that > 50% percent of the lead in this area can be ascribed to anthropogenic activity.

Campania region↗

USGS2018

Shrimp U-Pb zircon and opal geochronology, isotope geochemistry, and genesis of the super large Be deposit at Spor Mountain, Utah, USA

Ongoing studies of the Spor Mountain beryllium (Be) deposit are focused on (1) characterizing the role of igneous rocks in the genesis of the ore zones, (2) determining the timing and duration of magmatic-hydrothermal events, and (3) establishing processes related to beryllium transport and accumulation. The Spor Mountain Formation (SMF) hosts the deposit, which is the largest known volcanic rock-related Be deposit in the world. Discovery of the Be deposit at Spor Mountain in the 1960s displaced beryl as the main commercial source of beryllium in the global supply chain. Technological advances in mineral processing enabled bertrandite (Be4Si2O7(OH)2) ore of variable grade and composition from Spor Mountain to compete with beryl ore derived from pegmatite. The deposit currently accounts for approximately 85% of the global beryllium mine production. The Be deposit is in the Basin and Range province of North America, which is characterized by Oligocene and Eocene calderas, extensive alkalic rhyolitic lava and ash flow tuffs, widespread uranium and fluorite occurrences, and Precambrian to Paleozoic sedimentary rocks. The SMF consists of a hydrothermally-altered, fluorite-bearing, lithic-rich (clasts of carbonate, quartzite, and older volcanic rocks) pyroclastic tuff (informal name: Be tuff member) that is overlain by altered, porphyritic, and topaz-rich rhyolite (alkali rhyolite member). The tuff encloses elongate mineralized layers containing numerous nodules that consist of calcite, chalcedony, opal, fluorite, and bertrandite (Be4Si2O7(OH)2, the main ore mineral.

Utah↗

USGS2016

Regional geologic and petrologic framework for iron oxide ± apatite ± rare earth element and iron oxide copper-gold deposits of the Mesoproterozoic St. Francois Mountains terrane, southeast Missouri, USA

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.

Missouri↗

USGS2016

Geochemistry, Nd-Pb Isotopes, and Pb-Pb Ages of the Mesoproterozoic Pea Ridge Iron Oxide-Apatite–Rare Earth Element Deposit, Southeast Missouri

Iron oxide-apatite and iron oxide-copper-gold deposits occur within ~1.48 to 1.47 Ga volcanic rocks of the St. Francois Mountains terrane near a regional boundary separating crustal blocks having contrasting depleted-mantle Sm-Nd model ages (T DM ). Major and trace element analyses and Nd and Pb isotope data were obtained to characterize the Pea Ridge deposit, improve identification of exploration targets, and better understand the regional distribution of mineralization with respect to crustal blocks. The Pea Ridge deposit is spatially associated with felsic volcanic rocks and plutons. Mafic to intermediate-composition rocks are volumetrically minor. Data for major element variations are commonly scattered and strongly suggest element mobility. Ratios of relatively immobile elements indicate that the felsic rocks are evolved subalkaline dacite and rhyolite; the mafic rocks are basalt to basaltic andesite. Granites and rhyolites display geochemical features typical of rocks produced by subduction. Rare earth element (REE) variations for the rhyolites are diagnostic of rocks affected by hydrothermal alteration and associated REE mineralization. The magnetite-rich rocks and REE-rich breccias show similar REE and mantle-normalized trace element patterns. Nd isotope compositions (age corrected) show that: (1) host rhyolites have ɛ Nd from 3.44 to 4.25 and T DM from 1.51 to 1.59 Ga; (2) magnetite ore and specular hematite rocks display ɛ Nd from 3.04 to 4.21 and T DM from 1.6 to 1.51 Ga, and ɛ Nd from 2.23 to 2.81, respectively; (3) REE-rich breccias have ɛ Nd from 3.04 to 4.11 and T DM from 1.6 to 1.51 Ga; and (4) mafic to intermediate-composition rocks range in ɛ Nd from 2.35 to 3.66 and in T DM from 1.66 to 1.56. The ɛ Nd values of the magnetite and specular hematite samples show that the REE mineralization is magmatic; no evidence exists for major overprinting by younger, crustal meteoric fluids, or by externally derived Nd. Host rocks, breccias, and magnetite ore shared a common origin from a similar source. Lead isotope ratios are diverse: (1) host rhyolite has 206 Pb/ 204 Pb from 24.261 to 50.091; (2) Pea Ridge and regional galenas have 206 Pb/ 204 Pb from 16.030 to 33.548; (3) REE-rich breccia, magnetite ore, and specular hematite rock are more radiogenic than galena; (4) REE-rich breccias have high 206 Pb/ 204 Pb (38.122–1277.61) compared to host rhyolites; and (5) REE-rich breccias are more radiogenic than magnetite ore and specular-hematite rock, having 206 Pb/ 204 Pb up to 230.65. Radiogenic 207 Pb/ 206 Pb age estimates suggest the following: (1) rhyolitic host rocks have ages of ~1.50 Ga, (2) magnetite ore is ~1.44 Ga, and (3) REE-rich breccias are ~1.48 Ga. These estimates are broadly consistent and genetically link the host rhyolite, REE-rich breccia, and magnetite ore as being contemporaneous. Alteration style and mineralogical or textural distinctions among the magnetite-rich rocks and REE-rich breccias do not correlate with different isotopic sources. In our model, magmatic fluids leached metals from the coeval felsic rocks (rhyolites), which provided the metal source reflected in the compositions of the REE-rich breccias and mineralized rocks. This model allows for the likelihood of contributions from other genetically related felsic and intermediate to more mafic rocks stored deeper in the crust. The deposit thus records an origin as a magmatic-hydrothermal system that was not affected by Nd and Pb remobilization processes, particularly if these processes also triggered mixing with externally sourced metal-bearing fluids. The Pea Ridge deposit was part of a single, widespread, homogeneous mixing system that produced a uniform isotopic composition, thus representing an excellent example of an igneous-dominated system that generated coeval magmatism and REE mineralization. Geochemical features suggest that components in the Pea Ridge deposit originated from sources in an orogenic margin. Basaltic magmatism produced by mantle decompression melting provided heat for extracting melts from the middle or lower crust. Continual addition of mafic magmas to the base of the subcontinental lithosphere, in a back-arc setting, remelted calc-alkaline rocks enriched in metals that were stored in the crust. The St. Francois Mountains terrane is adjacent to the regional T DM line (defined at a value of 1.55 Ga) that separates ~1600 Ma basement to the west, from younger basements to the east. Data for Pea Ridge straddle the T DM values proposed for the line. The Sm-Nd isotope system has been closed since formation of the deposit and the original igneous signatures have not been affected by cycles of alteration or superimposed mineralizing events. No evidence exists for externally derived Nd or Sm. The source region for metals within the Pea Ridge deposit had a moderate compositional variation and the REE-rich breccias and mineralized rocks are generally isotopically homogeneous. The Pea Ridge deposit thus constitutes a distinctive isotopic target for use as a model in identifying other mineralized systems that may share the same metal source in the St. Francois Mountains terrane and elsewhere in the eastern Granite-Rhyolite province.

Missouri↗

USGS2016

Beryllium—A critical mineral commodity—Resources, production, and supply chain

Beryllium is a lightweight metallic element used in a wide variety of specialty and industrial applications. As a function of its unique chemical and physical properties, such as a high stiffness-to-weight ratio, resistance to temperature extremes, and high thermal conductivity, beryllium cannot be easily replaced by substitute materials in applications where combinations of these properties make it the material of choice. Because the number of beryllium producers is limited and the use of substitute materials in specific defense-related applications that are vital to national security is inadequate, several studies have categorized beryllium as a critical and strategic material. This categorization has led to the United States Government recommending that beryllium be stockpiled for use in the event of a national emergency. As of December 31, 2015, the National Defense Stockpile inventory of hot-pressed beryllium metal powder, structured beryllium metal powder, and vacuum-cast beryllium metal totaled 78 metric tons (t). The U.S. Geological Survey (USGS) Mineral Resources Program supports research on the occurrence, quality, quantity, and availability of mineral resources vital to the economy and national security. The USGS, through its National Minerals Information Center (NMIC), collects, analyzes, and disseminates information on more than 90 nonfuel mineral commodities from more than 180 countries. This fact sheet provides information on the production, consumption, supply chain, geology, and resource availability of beryllium in a global context.

Fact Sheet↗

USGS2016

Pb-Sr isotopic and geochemical constraints on sources and processes of lead contamination in well waters and soil from former fruit orchards, Pennsylvania, USA: A legacy of anthropogenic activities

Isotopic discrimination can be an effective tool in establishing a direct link between sources of Pb contamination and the presence of anomalously high concentrations of Pb in waters, soils, and organisms. Residential wells supplying water containing up to 1600 ppb Pb to houses built on the former Mohr orchards commercial site, near Allentown, PA, were evaluated to discern anthropogenic from geogenic sources. Pb (n = 144) and Sr (n = 40) isotopic data and REE (n = 29) data were determined for waters from residential wells, test wells (drilled for this study), and surface waters from pond and creeks. Local soils, sediments, bedrock, Zn-Pb mineralization and coal were also analyzed (n = 94), together with locally used Pb-As pesticide (n = 5). Waters from residential and test wells show overlapping values of 206 Pb/ 207 Pb, 208 Pb/ 207 Pb and 87 Sr/ 86 Sr. Larger negative Ce anomalies (Ce/Ce*) distinguish residential wells from test wells. Results show that residential and test well waters, sediments from residential water filters in water tanks, and surface waters display broad linear trends in Pb isotope plots. Pb isotope data for soils, bedrock, and pesticides have contrasting ranges and overlapping trends. Contributions of Pb from soils to residential well waters are limited and implicated primarily in wells having shallow water-bearing zones and carrying high sediment contents. Pb isotope data for residential wells, test wells, and surface waters show substantial overlap with Pb data reflecting anthropogenic actions (e.g., burning fossil fuels, industrial and urban processing activities). Limited contributions of Pb from bedrock, soils, and pesticides are evident. High Pb concentrations in the residential waters are likely related to sediment build up in residential water tanks. Redox reactions, triggered by influx of groundwater via wells into the residential water systems and leading to subtle changes in pH, are implicated in precipitation of Fe oxyhydroxides, oxidative scavenging of Ce(IV), and desorption and release of Pb into the residential water systems. The Pb isotope features in the residences and the region are best interpreted as reflecting a legacy of industrial Pb present in underlying aquifers that currently supply the drinking water wells.

Pennsylvania↗

USGS2015

Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy

This investigation focused on topsoils ( n = 122) and vertical profiles ( n = 6) distributed over an area of 250 km 2 in the eastern-central Peloritani Mountains, northeastern Sicily. Georeferenced concentration of 53 elements (including potentially harmful ones), determined by ICP-MS after an aqua regia leach, were used to produce geochemical maps by means of a GIS-aided spatial interpolation process. Results show that there are two distinct areas: the larger, located between the Fiumendinisi, Budali and Ali villages, and the other between C. Postlioni and Femmina Morta, which contain anomalous As (up to 727 mg/kg), Sb (up to 60 mg/kg), Ag (up to 1 mg/kg) and Au (up to 0.1 mg/kg) concentrations. Most of the investigated areas have high contamination levels for As, Zn, Sb, and Pb that exceed the threshold values (As = 20 mg/kg, Zn = 150 mg/kg, Sb = 10 mg/kg and Pb = 100 mg/kg) established for soils by the Italian Environmental Law ( Decreto Legislativo 2006 , number 152). The isotopic ratios of 206 Pb/ 207 Pb and 208 Pb/ 207 Pb have been measured in selected soils on both leaches [using 1M HNO 3 –1.75M HCl (50:50)] and residues thereof. Soil leach reflects possible anthropogenic contamination, whereas soil residues indicate geogenic contributions. Results suggest that most of contamination in the soils is related to the presence of sulphide and sulphosalt rock-forming minerals in the surveyed area. The soil fraction contains a Pb value >1600 mg/kg and has ratios of 1.1695 for 206 Pb/ 207 Pb and 2.4606 for 208 Pb/ 207 Pb. Only one soil leach isotopic composition could reflect possible anthropogenic contamination. The correlation among As, Zn, Pb contents v. Pb isotopic signatures of 206 Pb/ 207 Pb indicates that surface and deep soils collected from profiles are dominated by geogenic compositions.

Peloritani Mountains, Sicily↗

USGS2015

Geochemical and mineralogical characteristics of REE in granite-derived regolith: a model for the Southeast United States

Rare earth element (REE) ion-adsorption clay deposits are of global economic importance because they currently supply a significant portion of the world’s annual production of both light (LREE) and heavy REE (HREE). There is considerable ambiguity regarding the origin of this deposit type: The main criteria include the presence of large, generally granitic, igneous suites; long periods of intense weathering with little subsequent erosion; and evidence for mobility of REE within the regolith. Granitic rocks of the southeastern United States have been subjected to a long history of chemical weathering, comparable to that of South China, an area which contains many REE clay deposits. Detailed comparisons of weathered bedrock-soil profiles for large masses of granitic rocks as exemplified by the Stewartsville, Striped Rock, and Liberty Hill plutons, USA, indicate that REE are mobile within many regolith profiles and locally can attain grades comparable to mined deposits of South China. Primary accessory mineralogy, modal content, and element redistribution as a result of weathering are identified as distinguishing factors in mobility-related enrichment of REE in the regolith profiles. Only limited geochemical separation of REE was observed within profiles, which suggests the importance of source rock composition and mineralogy in the initial distribution of extractable REE in the regolith. Retention of extractable HREE was favored over LREE, Th and U within most of the studied profiles.

Conference Paper↗

USGS2015

REE enrichment in granite-derived regolith deposits of the southeast United States: Prospective source rocks and accumulation processes

The Southeastern United States contains numerous anorogenic, or A-type, granites, which constitute promising source rocks for REE-enriched ion adsorption clay deposits due to their inherently high concentrations of REE. These granites have undergone a long history of chemical weathering, resulting in thick granite-derived regoliths, akin to those of South China, which supply virtually all heavy REE and Y, and a significant portion of light REE to global markets. Detailed comparisons of granite regolith profiles formed on the Stewartsville and Striped Rock plutons, and the Robertson River batholith (Virginia) indicate that REE are mobile and can attain grades comparable to those of deposits currently mined in China. A REE-enriched parent, either A-type or I-type (highly fractionated igneous type) granite, is thought to be critical for generating the high concentrations of REE in regolith profiles. One prominent feature we recognize in many granites and mineralized regoliths is the tetrad behaviour displayed in REE chondrite-normalized patterns. Tetrad patterns in granite and regolith result from processes that promote the redistribution, enrichment, and fractionation of REE, such as late- to post- magmatic alteration of granite and silicate hydrolysis in the regolith. Thus, REE patterns showing tetrad effects may be a key for discriminating highly prospective source rocks and regoliths with potential for REE ion adsorption clay deposits.

Conference Paper↗