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R.P. Christian

Publications and source records attributed to R.P. Christian.

6 recordsLinked to original sources

Reconnaissance geochemical exploration for gold in the Ad Darb area, Kingdom of Saudi Arabia

Geochemical data were analyzed for 244 wadi-sediment samples in an attempt to locate gold exploration targets in late Proterozoic metasedimentary and metavolcanic rocks in the Ad Darb area of the southern Arabian Shield. The target was gold mineralization in high-alumina alteration zones of the type that occurs in the Carolina Slate Belt, eastern United States. Such a target was sought in the Ad Darb area because of the known presence of kyanite in schist of the Sabya formation, which was interpreted to be a possible indicator of late Proterozoic high-alumina hydrothermal activity in the region. Overall, metal values in the wadi-sediment samples are low. The known kyanite mineral occurrence is marked by anomalous gold and tin in three minus-80-mesh samples. The low values of the metals do not justify further exploration for the sought deposit type in the immediate vicinity, although the signature of anomalous elements in the wider region is comparable to the signature known in the Carolina Slate Belt, and is permissive of the interpretation that a diffuse hydrothermal system operated in the region during the late Proterozoic. A large concentration of polymetallic anomalies (gold, arsenic, copper, antimony, tin, tungsten, and lead) is outlined in the northeastern part of the survey area on the basis of panned-concentrate samples. The source of the concentration is unknown, and further investigations are recommended. Recommended low-priority investigation of the source of lead and zinc anomalies in the western part of the survey area would be justified as part of a larger program designed to evaluate the mineral potential of the entire belt of Sabya formation rock.

Open-File Report

Geology and mineralization at the Ishmas Kabir gold prospect, Ishmas gold district, Kingdom of Saudi Arabia

Ishmas Kabir ancient gold mine is located approximately 60 km southeast of the city of Ranyah and 9 km northwest of Jabal Ishmas in the southwestern part of the Ishmas gold district. The mine workings are located near the eastern edge of a flat plain covered by eolian sand and drained by Wadi Bishah. Two elongate dumps, 75 m wide and 530 m long (combined length), comprise the workings. Rising 4 m above the plain, they are prominent features in this area of low relief. Core drilling (1,023 m total depth drilled) was conducted to define the extent of potential gold occurrences at the prospect. The two northeasternmost of the four holes drilled unequivocally intersected the gold-bearing main vein zone. Drill hole 1, the northeasternmost hole drilled, passed through significant lengths of altered wall rocks + quartz veins containing > 100 ppb Au (threshold value). The average gold concentration of all intercepts in drill holes 1 through 4 is 278 ppb; the total length of drill core that assayed above the gold threshold value is 13.46 m. The highest gold concentration (1,620 ppb) reported in geochemical assay results was obtained from a 0.33 m length of core in drill hole 1. Gold-intercept occurrences are not economic in the rocks drilled; no further deep drilling is recommended at this time. Gold concentrations in samples obtained from mine dumps are much higher than in drill-core samples. Samples collected by earlier workers assayed 3-7 g/t, and tonnage estimates of mine spoil have been estimated to be as high as 120,000 tons. A possible sampling bias in earlier studies may favor larger gold-enriched, samples relative to samples from quartz tailings. Further work at Ishmas Kabir should be limited to defining gold resource potential in the dumps and in the oxidized, near-surface quartz-vein system. Primary gold at the Ishmas Kabir gold prospect occurs with quartz veins and associated sericite + pyrite alteration hosted by quartz diorite and mafic dikes. The highest gold concentrations both in dumps (earlier studies) and drill core (this investigation) are found with limonite + hematite in breccia zones, in stringer veins, and in sericitic alteration envelopes surrounding quartz veins. Secondary gold is significant in this system and attests to the importance of oxidizing, acidic solutions. Quartz veins intersected by drill holes are surrounded by mylonite schist. Quartz and carbonate veins less than 5 mm thick are boudined, whereas thick quartz veins (£ 1.2 m) have disrupted and brecciated margins; mylonitized country rock envelops quartz-vein fragments. Sulfide mineralization associated with vein formation predates this rock-deformation event. Contemporaneous brittle and ductile deformation of quartz veins and country rocks occurred during the Nabitah orogeny. Supergene gold enrichment took place much later.

Open-File Report

Residence of silver in mineral deposits of the Thunder Mountain caldera complex, Central Idaho, U.S.A.

Silver is an accessory element in gold, antimony, and tungsten deposits of the caldera complex. Most of the deposits are economically of low grade and genetically of xenothermal or epithermal character. Their gold- and silver-bearing minerals are usually disseminated, fine grained, and difficult to study. Sparsely disseminated pyrite and arsenoprite are common associates. Identified silver minerals are: native silver and electrum; the sulfides acanthite, argentite (the latter always inverted to acanthite), and members of the Silberkies group; the sulfosalts matildite, miargyrite, pyrargyrite, argentian tetrahedrite, and unnamed Ag-Sb-S and Ag-Fe-Sb-S minerals; the telluride hessite and the selenide naumannite; halides of the cerargyrite group; and the antimonate stetefeldtite. Suspected silver minerals include the sulfide uytenbogaardtite and the sulfosalts andorite, diaphorite, and polybasite. Electrum, acanthite, and argentian tetrahedrite are common, though nowhere abundant. The other silver minerals are rare. Silver is present as a minor element in the structure of some varieties of other minerals. These include arsenopyrite, chalcopyrite, chalcostibite, covelline, digenite, galena, sphalerite, and stibnite. The search for adventitious Ag in most of these minerals has been cursory. The results merely indicate that elemental silver is not confined to discrete silver minerals and is, therefore, an additional complication for the recovery of silver-bearing material from some deposits. Silver occurs cryptically in some plants of the region. At Red Mountain, for example, the ashed sapwood of Douglas-fir (Pseudotsuga menziesii) contains 2 to 300 ppm Ag. Silver in the ashed wood is roughly 100 times as abundant as it is in soil. The phenomenon, useful in biogeochemical exploration, deserves the attention of mineralogists. ?? 1987 Springer-Verlag.

Mineralogy and Petrology

Semimicro chemical and x-ray fluorescence analysis of lunar samples

Major and selected minor elements were determined in seven whole rock fragments, five portions of pulverized lunar rock, and the lunar soil. Three different rock types were represented: vesicular, fine-grained basaltic rocks; medium- to coarse-grained, vuggy gabbroic rocks; and breccia. The ranges (in percent) for the major constituents of the lunar samples are: SiO 2 , 38 to 42; Al 2 O 3 , 8 to 14; total iron as FeO, 15 to 20; MgO, 6 to 8; CaO, 10 to 12; Na 2 O, 0.5 to 1; K 2 O, 0.05 to 0.4; TiO 2 , 8 to 13; MnO, 0.2 to 0.3; and Cr 2 O 3 , 0.2 to 0.4. The high reducing capacity of the samples strongly suggests the presence of Ti(III).

Science

The determination of nanogram amounts of Chromium in urine by x-ray fluorescence spectroscopy

Nanogram amounts of chromium can be extracted as oxinate into chloform. By treatment of the chloroform layer 3 M hydrochloric acid, oxinates of other elements and excess of reagent are removed, leaving a chloroform solution of the chromium chelate only. This solution is concentrated and transferred to the top of a small brass rod acting as sample holder. The intensity of the X-ray fluorescence of the Cr Kα line is measured with curved crystal optics. Chromium amounts greater than 5 ng can be detected. The application of the procedure to the analysis of the chromium content of urine is demonstrated.

Analytica Chimica Acta