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Lynne S. Fahlquist

Publications and source records attributed to Lynne S. Fahlquist.

6 recordsLinked to original sources
USGS2015

Global patterns and environmental controls of perchlorate and nitrate co-occurrence in arid and semi-arid environments

Natural perchlorate (ClO 4 − ) is of increasing interest due to its wide-spread occurrence on Earth and Mars, yet little information exists on the relative abundance of ClO 4 − compared to other major anions, its stability, or long-term variations in production that may impact the observed distributions. Our objectives were to evaluate the occurrence and fate of ClO 4 − in groundwater and soils/caliche in arid and semi-arid environments (southwestern United States, southern Africa, United Arab Emirates, China, Antarctica, and Chile) and the relationship of ClO 4 − to the more well-studied atmospherically deposited anions NO 3 − and Cl − as a means to understand the prevalent processes that affect the accumulation of these species over various time scales. ClO 4 − is globally distributed in soil and groundwater in arid and semi-arid regions on Earth at concentrations ranging from 10 −1 to 10 6 μg/kg. Generally, the ClO 4 − concentration in these regions increases with aridity index, but also depends on the duration of arid conditions. In many arid and semi-arid areas, NO 3 − and ClO 4 − co-occur at molar ratios (NO 3 − /ClO 4 − ) that vary between ∼10 4 and 10 5 . We hypothesize that atmospheric deposition ratios are largely preserved in hyper-arid areas that support little or no biological activity (e.g. plants or bacteria), but can be altered in areas with more active biological processes including N 2 fixation, N mineralization, nitrification, denitrification, and microbial ClO 4 − reduction, as indicated in part by NO 3 − isotope data. In contrast, much larger ranges of Cl − /ClO 4 − and Cl − /NO 3 − ratios indicate Cl − varies independently from both ClO 4 − and NO 3 − . The general lack of correlation between Cl − and ClO 4 − or NO 3 − implies that Cl − is not a good indicator of co-deposition and should be used with care when interpreting oxyanion cycling in arid systems. The Atacama Desert appears to be unique compared to all other terrestrial locations having a NO 3 − /ClO 4 − molar ratio ∼10 3 . The relative enrichment in ClO 4 − compared to Cl − or NO 3 − and unique isotopic composition of Atacama ClO 4 − may reflect either additional in-situ production mechanism(s) or higher relative atmospheric production rates in that specific region or in the geological past. Elevated concentrations of ClO 4 − reported on the surface of Mars, and its enrichment with respect to Cl − and NO 3 − , could reveal important clues regarding the climatic, hydrologic, and potentially biologic evolution of that planet. Given the highly conserved ratio of NO 3 − /ClO 4 − in non-biologically active areas on Earth, it may be possible to use alterations of this ratio as a biomarker on Mars and for interpreting major anion cycles and processes on both Mars and Earth, particularly with respect to the less-conserved NO 3 − pool terrestrially.

Geochimica et Cosmochimica Acta↗
USGS2015

The quality of our Nation's waters: Water quality in the Mississippi embayment-Texas coastal uplands aquifer system and Mississippi River Valley alluvial aquifer, south-central United States, 1994-2008

About 8 million people rely on groundwater from the Mississippi embayment—Texas coastal uplands aquifer system for drinking water. The Mississippi River Valley alluvial aquifer also provides drinking water for domestic use in rural areas but is of primary importance to the region as a source of water for irrigation. Irrigation withdrawals from this aquifer are among the largest in the Nation and play a key role in the economy of the area, where annual crop sales total more than $7 billion. The reliance of the region on both aquifers for drinking water and irrigation highlights the importance of long-term management to sustain the availability and quality of these resources.

Alabama, Arkansas, Kentucky, Louisiana, Mississipp↗
USGS2014

Factors affecting public-supply well vulnerability in two karst aquifers

Karst aquifers occur in a range of climatic and geologic settings. Nonetheless, they are commonly characterized by their vulnerability to water-quality impairment. Two karst aquifers, the Edwards aquifer in south-central Texas and the Upper Floridan aquifer in western Florida, were investigated to assess factors that control the movement of contaminants to public-supply wells (PSWs). The geochemistry of samples from a selected PSW or wellfield in each aquifer was compared with that from nearby monitoring wells and regional PSWs. Geochemistry results were integrated with age tracers, flow modeling, and depth-dependent data to refine aquifer conceptual models and to identify factors that affect contaminant movement to PSWs. The oxic Edwards aquifer is vertically well mixed at the selected PSW/wellfield, although regionally the aquifer is geochemically variable downdip. The mostly anoxic Upper Floridan aquifer is affected by denitrification and also is geochemically variable with depth. In spite of considerable differences in geology and hydrogeology, the two aquifers are similarly vulnerable to anthropogenic contamination. Vulnerability in studied PSWs in both aquifers is strongly influenced by rapid karst flowpaths and the dominance of young (<10 years) groundwater. Vulnerability was demonstrated by the frequent detection of similar constituents of concern in both aquifers (nitrate, atrazine, deethylatrazine, tetrachloroethene, and chloroform). Specific consideration of water-quality protection efforts, well construction and placement, and aquifer response times to land-use changes and contaminant loading are discussed, with implications for karst groundwater management.

Ground Water↗
USGS2011

Simulations of groundwater flow and particle-tracking analysis in the zone of contribution to a public-supply well in San Antonio, Texas

In 2006, a public-supply well in San Antonio, Texas, was selected for intensive study to assess the vulnerability of public-supply wells in the Edwards aquifer to contamination by a variety of compounds. A local-scale, steady-state, three-dimensional numerical groundwater-flow model was developed and used in this study to evaluate the movement of water and solutes from recharge areas to the selected public-supply well. Particle tracking was used to compute flow paths and advective traveltimes throughout the model area and to delineate the areas contributing recharge and zone of contribution for the selected public-supply well. The local-scale model grid has a finer vertical discretization than do previous regional Edwards aquifer models and incorporates refined parameter zones corresponding with multiple (10) hydrogeologic units representing the Edwards aquifer. In the Edwards aquifer, high matrix porosity and permeability likely are overshadowed by high permeability developed in structurally influenced karstic conduit systems that transmit water into, through, and out of the aquifer system. The complexity of the aquifer system in the local-scale study area is further increased by numerous faults with varying vertical displacements. The extensive faulting results in the juxtaposition of hydrogeologic units with differing hydraulic properties and has appreciable effects on groundwater flow in the Edwards aquifer. The local-scale model simulations use the MODFLOW Hydrogeologic-Unit Flow Package and include two hydrogeologic units with high hydraulic conductivities (one or more orders of magnitude higher than for the other simulated hydrogeologic units) that are intended to simulate fast flow paths attributable to karst features. The two &ldquo;conduit&rdquo; hydrogeologic units of the Edwards aquifer represent the lower 8 meters of the leached and collapsed members and the Kirschberg evaporite member of the Edwards Group. The MODFLOW Horizontal-Flow Barrier Package was used to simulate faults in the local-scale model. The assumption was made that the degree to which a fault acts as a barrier to groundwater flow is proportional to the fault displacement. The final calibrated hydraulic-conductance values ranged from 0.01 to 0.2 per day for fault displacements ranging from 0 to more than 100 percent of the total aquifer thickness. The calibrated steady-state simulation generally reproduces the spatial distribution of measured water-level altitudes. Simulated water-level altitudes were within 9.0 meters of measured water-level altitudes at 74 of the 84 wells used as targets for the local-scale model for the calibrated steady-state simulation. The overall mean absolute difference between simulated and measured water-level altitudes is 4.2 meters, and the mean algebraic difference is 1.9 meters. The simulated springflow for San Antonio Springs was 7.7 percent greater and for San Pedro Springs was 4.2 percent less than the median measured springflow. Simulated tritium concentrations were within 0.14 tritium units of measured tritium concentrations for 11 of the 13 local-scale study tritium observations from the 10 local-scale study wells used to calibrate the steady-state local-scale model, with a mean absolute difference between simulated and measured tritium concentrations of 0.11 tritium units and a mean algebraic difference of -0.04 tritium units. Simulated tritium concentrations in the selected public-supply well during November 2007 were within 0.09 tritium units of the measured concentrations, with the exception of the shallowest observation from the well. The steady-state simulation water budget indicates that recharge occurring in the local-scale study area accounts for 31.8 percent of the sources of water to the Edwards aquifer in the local-scale model area and that inflow through the model boundaries contributes 68.2 percent. Most of the flow into the local-scale model area through the model boundaries occurs through the western and southern boundaries, 58.2 and 39.6 percent, respectively. The largest discharges from the Edwards aquifer in the local-scale model area are boundary outflow (71.4 percent) and withdrawals by wells (24.9 percent). Most of the flow out of the local-scale model area through the model boundaries occurs through the southern and eastern boundaries, 54.2 and 39.6 percent, respectively. The simulated zones of contribution for the selected public-supply well, Timberhill well nest, and Zarzamora well nest extend to the north, northeast, and northwest from each site in the confined zone of the aquifer into the recharge zone, where all recharge to the aquifer occurs. The area contributing recharge for the selected public-supply well has the greatest extent. The area contributing recharge for the Timberhill well nest encompasses approximately the western one-half of the area contributing recharge for the selected public-supply well, and that for the Zarzamora well nest encompasses approximately the eastern two-thirds of the area contributing recharge for the selected public-supply well. Simulated particle ages ranged from less than 1 day to more than 1,900 years in the 10 local-scale study wells (13 local-scale study tritium observations) used to calibrate the local-scale model. The simulated mean particle ages for the tritium observations representing selected well depths (shallow, intermediate, and deep) ranged from 2.5 to 15 years. The minimum (youngest) mean particle ages for the selected public-supply well and the Timberhill monitoring wells were for the intermediate well depth, while the youngest mean particle age for the Zarzamora monitoring wells was for the intermediate and deep well depth. The maximum (oldest) mean particle ages for the selected public-supply well and the Zarzamora monitoring wells were for the shallow well depth. The mean of simulated particle ages for tritium observations representing well depths open to the simulated conduit hydrogeologic units was 3.8 years, whereas the mean of simulated particle ages for tritium observations representing well depths not open to the simulated conduit hydrogeologic units was 9.6 years. The effect of short-circuit pathways, for example karst conduits, in the flow system on the movement of young water to the selected public-supply well could greatly alter contaminant arrival times compared to what might be expected from advection in a system without short circuiting. In a forecasting exercise, the simulated concentrations showed rapid initial response at the beginning and end of chemical input, followed by more gradual response as older water moved through the system. The nature of karst groundwater flow, where flow predominantly occurs via conduit flow paths, could lead to relatively rapid water quality responses to land-use changes. Results from the forecasting exercise indicate that timescales for change in the quality of water from the selected public-supply well could be on the order of a few years to decades for land-use changes that occur over days to decades, which has implications for source-water protection strategies that rely on land-use change to achieve water-quality objectives.

Texas↗
USGS2006

Ground-water quality beneath irrigated cropland of the northern and southern High Plains aquifer, Nebraska and Texas, 2003-04

A study of the quality of ground water beneath irrigated cropland was completed for the northern and southern High Plains aquifer. Ground-water samples were collected from 30 water-table monitoring wells in the northern agricultural land-use (NAL) study area in Nebraska in 2004 and 29 water-table monitoring wells in the southern agricultural land-use (SAL) study area in Texas in 2003. The two study areas represented different agricultural and hydrogeologic settings. The primary crops grown in the NAL study area were corn and soybeans, and the primary crop in the SAL study area was cotton. Overall, pesticide and fertilizer application rates were larger in the NAL study area. Also, precipitation and recharge rates were greater in the NAL study area, and depths to water and evapotranspiration rates were greater in the SAL study area. Ground-water quality beneath irrigated cropland was different in the two study areas. Nitrate concentrations were larger and pesticide detections were more frequent in the NAL study area. Nitrate concentrations in NAL samples ranged from 1.96 to 106 mg/L (milligrams per liter) as nitrogen, with a median concentration of 10.6 mg/L. Water in 73 percent of NAL samples had at least one pesticide or pesticide degradate detected. Most of the pesticide compounds detected (atrazine, alachlor, metolachlor, simazine, and degradates of those pesticides) are applied to corn and soybean fields. Nitrate concentrations in SAL samples ranged from 0.96 to 21.6 mg/L, with a median of 4.12 mg/L. Water in 24 percent of SAL samples had at least one pesticide or pesticide degradate detected. The pesticide compounds detected were deethylatrazine (a degradate of atrazine and propazine), propazine, fluometuron, and tebuthiuron. Most of the pesticides detected are applied to cotton fields. Dissolved-solids concentrations were larger in the SAL area and were positively correlated with both nitrate and chloride concentrations, suggesting a combination of human and natural sources. Dissolved-solids concentrations in NAL samples ranged from 272 to 2,160 mg/L, with a median of 442 mg/L, and dissolved solids in SAL samples ranged from 416 to 3,580 mg/L, with a median of 814 mg/L.

Nebraska, Texas↗