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Kirk P. Smith

Publications and source records attributed to Kirk P. Smith.

At least 37 records · Page 2Linked to original sources

Water-quality trends in the Scituate reservoir drainage area, Rhode Island, 1983-2012

The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. Water-quality and streamflow data collected at 37 surface-water monitoring stations in the Scituate Reservoir drainage area, Rhode Island, from October 2001 through September 2012, water years (WYs) 2002-12, were analyzed to determine water-quality conditions and constituent loads in the drainage area. Trends in water quality, including physical properties and concentrations of constituents, were investigated for the same period and for a longer period from October 1982 through September 2012 (WYs 1983-2012). Water samples were collected and analyzed by the Providence Water Supply Board, the agency that manages the Scituate Reservoir. Streamflow data were collected by the U.S. Geological Survey. Median values and other summary statistics for pH, color, turbidity, alkalinity, chloride, nitrite, nitrate, total coliform bacteria, Escherichia coli ( E. coli ), and orthophosphate were calculated for WYs 2003-12 for all 37 monitoring stations. Instantaneous loads and yields (loads per unit area) of total coliform bacteria and E. coli , chloride, nitrite, nitrate, and orthophosphate were calculated for all sampling dates during WYs 2003-12 for 23 monitoring stations with streamflow data. Values of physical properties and concentrations of constituents were compared with State and Federal water-quality standards and guidelines and were related to streamflow, land-use characteristics, varying classes of timber operations, and impervious surface areas. Tributaries in the Scituate Reservoir drainage area for WYs 2003-12 were slightly acidic (median pH of all stations equal to 6.1) and contained low median concentrations of chloride (22 milligrams per liter [mg/L]), nitrate (0.01 mg/L as nitrogen), nitrite (0.001 mg/L as nitrogen), and orthophosphate (0.02 milligrams per liter as phosphorus [mg/L as P]). Turbidity and alkalinity values also were low with medians of 0.57 nephelometric turbidity units and 5.1 mg/L as calcium carbonate, respectively. Total coliform bacteria and E. coli were detected in most samples from all stations, but median concentrations were generally low-43 colony-forming units per 100 milliliters (mL) and 15 colony-forming units per 100 milliliters, respectively. Median values of several physical properties and median concentrations of several constituents correlated positively with the percentages of developed land and negatively with the percentages of forest cover in the drainage areas above the monitoring stations. Median concentrations of chloride correlated positively with the percentages of impervious land use in the subbasins of monitoring stations, likely reflecting the effects of deicing compounds applied to roadways during winter maintenance. Median concentrations of alkalinity also correlated positively with the percentage of impervious land use, which may be related to the deterioration of fabricated structures containing calcium carbonate. Median values of color correlated positively with the percentage of wetland area in the subbasins of monitoring stations, reflecting the natural sources of color in tributaries. Streamflows were negatively correlated with turbidity and concentrations of total coliform bacteria and E. coli, possibly reflecting seasonal patterns in which relatively high values of these properties and constituents occur during warmer low-flow conditions late in the water year. Similar seasonal patterns were observed for pH, alkalinity, and color. Negative correlations between concentrations of chloride and streamflow also were significant, indicating that deicing salts from roadways and other impervious surfaces that lack direct connection to the tributaries are likely infiltrating to the groundwater and discharging to some of the tributaries late in the water year. While salt-laden runoff directly enters some of the tributaries at roadway crossings, most of the roadway runoff infiltrates into the adjacent berms throughout the drainage area. Statistically significant correlations were not identified between various degrees of tree-canopy reduction caused by timber operations in the subbasins and median values or concentrations of water-quality properties. Loads and yields of chloride, nitrate, nitrite, orthophosphate, and bacteria varied at monitoring stations in the Scituate Reservoir drainage area in WYs 2003-12. Loads generally were greater at stations in the Barden Reservoir and the Regulating Reservoir Subbasins that have larger drainage areas than in subbasins with smaller drainage areas. Subbasin yields of fecal-indicator bacteria and orthophosphate generally were largest in the Westconnaug Reservoir Subbasin, and subbasin yields for chloride, nitrate, and nitrite were largest in the Moswansicut Reservoir Subbasin in the northeastern part of the drainage area. Upward trends in pH were identified for nearly half of the monitoring stations for WYs 1983-2012 and may reflect regional reductions in acid precipitation. Many upward trends in alkalinity also were identified for both the WYs 1983-2012 and for WYs 2003-12 periods and are likely related to the natural weathering of structures containing concrete or, in some cases, the application of lime or fertilizers on agriculture lands. Significant trends in chloride concentrations at most stations during WYs 1983-2012 were upward; however, results for WYs 2003-12 substantiate few significant upward trends and, in a few cases, downward trends were identified in several tributary drainage areas.

Rhode Island↗

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2012

Streamflow and concentrations of sodium and chloride estimated from records of specific conductance were used to calculate loads of sodium and chloride during water year (WY) 2012 (October 1, 2011, through September 30, 2012), for tributaries to the Scituate Reservoir, Rhode Island. Streamflow and water-quality data used in the study were collected by the U.S. Geological Survey (USGS) or the Providence Water Supply Board (PWSB). Streamflow was measured or estimated by the USGS following standard methods at 23 streamgages; 14 of these streamgages were equipped with instrumentation capable of continuously monitoring water level, specific conductance, and water temperature. Water-quality samples were collected at 37 sampling stations by the PWSB and at 14 continuous-record streamgages by the USGS during WY 2012 as part of a long-term sampling program; all stations were in the Scituate Reservoir drainage area. Water-quality data collected by the PWSB were summarized by using values of central tendency and used, in combination with measured (or estimated) streamflows, to calculate loads and yields (loads per unit area) of selected water-quality constituents for WY 2012. The largest tributary to the reservoir (the Ponaganset River, which was monitored by the USGS) contributed a mean streamflow of about 26 cubic feet per second (ft 3 /s) to the reservoir during WY 2012. For the same time period, annual mean1 streamflows measured (or estimated) for the other monitoring stations in this study ranged from about 0.40 to about 17 ft 3 /s. Together, tributaries (equipped with instrumentation capable of continuously monitoring specific conductance) transported about 1,100,000 kilograms (kg) of sodium and 1,900,000 kg of chloride to the Scituate Reservoir during WY 2012; sodium and chloride yields for the tributaries ranged from 8,700 to 51,000 kilograms per square mile (kg/mi 2 ) and from 14,000 to 87,000 kg/mi 2 , respectively. At the stations where water-quality samples were collected by the PWSB, the median of the median chloride concentrations was 19 milligrams per liter (mg/L), median nitrite concentration was 0.002 mg/L as nitrogen (N), median nitrate concentration was less than 0.01 mg/L as N, median orthophosphate concentration was 0.06 mg/L as phosphorus, and median concentrations of total coliform and Escherichia coli (E. coli) bacteria were 43 and 16 colony forming units per 100 milliliters (CFU/100mL), respectively. The medians of the median daily loads (and yields) of chloride, nitrite, nitrate, orthophosphate, and total coliform and E. coli bacteria were 200 kilograms per day (kg/d) (71 kilograms per day per square mile (kg/d/mi 2 )); 15 grams per day (g/d) (5.4 grams per day per square mile (g/d/mi 2 )); 100 g/d (38 g/d/mi 2 ); 500 g/d (260 g/d/mi 2 ); 4,300 million colony forming units per day (CFUx10 6 /d) (1,500 CFUx10 6 /d/mi 2 ); and 1,000 CFUx10 6 /d (360 CFUx10 6 /d/mi 2 ), respectively.

Rhode Island↗

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2011

Streamflow and concentrations of sodium and chloride estimated from records of specific conductance were used to calculate loads of sodium and chloride during water year (WY) 2011 (October 1, 2010, to September 30, 2011), for tributaries to the Scituate Reservoir, Rhode Island. Streamflow and water-quality data used in the study were collected by the U.S. Geological Survey (USGS) or the Providence Water Supply Board (PWSB). Streamflow was measured or estimated by the USGS following standard methods at 23 streamgages; 14 of these streamgages were also equipped with instrumentation capable of continuously monitoring water level, specific conductance, and water temperature. Water-quality samples also were collected at 37 sampling stations by the PWSB and at 14 continuous-record streamgages by the USGS during WY 2011 as part of a long-term sampling program; all stations were in the Scituate Reservoir drainage area. Water-quality data collected by PWSB are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields (loads per unit area) of selected water-quality constituents for WY 2011. The largest tributary to the reservoir (the Ponaganset River, which was monitored by the USGS) contributed a mean streamflow of about 37 cubic feet per second (ft 3 /s) to the reservoir during WY 2011. For the same time period, annual mean 1 streamflows measured (or estimated) for the other monitoring stations in this study ranged from about 0.5 to about 21 ft 3 /s. Together, tributaries (equipped with instrumentation capable of continuously monitoring specific conductance) transported about 1,600,000 kg (kilograms) of sodium and 2,600,000 kg of chloride to the Scituate Reservoir during WY 2011; sodium and chloride yields for the tributaries ranged from 9,800 to 53,000 kilograms per square mile (kg/mi 2 ) and from 15,000 to 90,000 kg/mi 2 , respectively. At the stations where water-quality samples were collected by the PWSB, the median of the median chloride concentrations was 20.0 milligrams per liter (mg/L), median nitrite concentration was 0.002 mg/L as nitrogen (N), median nitrate concentration was 0.01 mg/L as N, median orthophosphate concentration was 0.07 mg/L as phosphorus, and median concentrations of total coliform and Escherichia coli (E. coli) bacteria were 33 and 23 colony forming units per 100 milliliters (CFU/100mL), respectively. The medians of the median daily loads (and yields) of chloride, nitrite, nitrate, orthophosphate, and total coliform and E. coli bacteria were 230 kilograms per day (kg/d) (80 kilograms per day per square mile (kg/d/mi 2 )); 10 grams per day (g/d) (6.3 grams per day per square mile (g/d/mi 2 )); 110 g/d (29 g/d/mi 2 ); 610 g/d (270 g/d/mi 2 ); 4,600 million colony forming units per day (CFUx10 6 /d) (2,500 CFUx10 6 /d/mi 2 ); and 1,800 CFUx10 6 /d (810 CFUx10 6 /d/mi 2 ), respectively.

Rhode Island↗

Water-quality conditions, and constituent loads and yields in the Cambridge drinking-water source area, Massachusetts, water years 2005–07

The source water area for the drinking-water supply of the city of Cambridge, Massachusetts, encompasses major transportation corridors, as well as large areas of light industrial, commercial, and residential land use. Because of ongoing development in the drinking-water source area, the Cambridge water supply has the potential to be affected by a wide variety of contaminants. The U.S. Geological Survey (USGS) has monitored surface-water quality in the Hobbs Brook and Stony Brook Basins, which compose the drinking-water source area, since 1997 (water year 1997) through continuous monitoring and discrete sample collection and, since 2004, through systematic collection of streamwater samples during base-flow and stormflow conditions at five primary sampling stations in the drinking-water source area. Four primary sampling stations are on small tributaries in the Hobbs Brook and Stony Brook Basins; the fifth primary sampling station is on the main stem of Stony Brook and drains about 93 percent of the Cambridge drinking-water source area. Water samples also were collected at six secondary sampling stations, including Fresh Pond Reservoir, the final storage reservoir for the raw water supply. Storm runoff and base-flow concentrations of calcium (Ca), chloride (Cl), sodium (Na), and sulfate (SO 4 ) were estimated from continuous records of streamflow and specific conductance for six monitoring stations, which include the five primary sampling stations. These data were used to characterize current water-quality conditions, estimate loads and yields, and describe trends in Cl and Na in the tributaries and main-stem streams in the Hobbs Brook and Stony Brook Basins. These data also were used to describe how streamwater quality is affected by various watershed characteristics and provide information to guide future watershed management. Water samples were analyzed for physical properties and concentrations of Ca, Cl, Na, and SO 4 , total nitrogen (TN), total phosphorus (TP), caffeine, and a suite of 59 polar pesticides. Values of physical properties and constituent concentrations varied widely, particularly in samples from tributaries. Median concentrations of Ca, Cl, Na, and SO4 in samples collected in the Hobbs Brook Basin (39.8, 392, 207, and 21.7 milligrams per liter (mg/L), respectively) were higher than those for the Stony Brook Basin (17.8, 87.7, 49.7, and 14.7 mg/L, respectively). These differences in major ion concentrations are likely related to the low percentages of developed land and impervious area in the Stony Brook Basin. Concentrations of dissolved Cl and Na in samples, and those estimated from continuous records of specific conductance (particularly during base flow), often were greater than the U.S. Environmental Protection Agency (USEPA) secondary drinking-water guideline for Cl (250 mg/L), the chronic aquatic-life guideline for Cl (230 mg/L), and the Commonwealth of Massachusetts, Executive Office of Energy and Environmental Affairs drinking-water guideline for Na (20 mg/L). Mean annual flow-weighted concentrations of Ca, Cl, and Na were generally positively correlated with the area of roadway land use in the subbasins. Correlations between mean annual concentrations of Ca and SO 4 in base flow and total roadway, total impervious, and commercial-industrial land uses were statistically significant. Concentrations of TN (range of 0.42 to 5.13 mg/L in all subbasins) and TP (range of 0.006 to 0.80 mg/L in all subbasins) in tributary samples did not differ substantially between the Hobbs Brook and Stony Brook Basins. Concentrations of TN and TP in samples collected during water years 2004–07 exceeded proposed reference concentrations of 0.57 and 0.024 mg/L, in 94 and 56 percent of the samples, respectively. Correlations between annual flow-weighted concentrations of TN and percentages of recreational land use and water-body area were statistically significant; however, no significant relation was found between TP and available land-use information. The volume of streamflow affected water-quality conditions at the primary sampling stations. Turbidity and concentrations of TP were positively correlated with streamflow. In contrast, concentrations of major ions were negatively correlated with streamflow, indicating that these constituents were diluted during stormflows. Concentrations of TN were not correlated with streamflow. Twenty-five pesticides and caffeine were detected in water samples collected in the drinking-water source area and in raw water collected from the Cambridge water-treatment facility intake at the Fresh Pond Reservoir. Imidacloprid, norflurazon, and siduron were the most frequently detected pesticides with the frequency of detections ranging from about 24 to 41 percent. Caffeine was detected in about 37 percent of water samples at concentrations ranging from 0.003 to 1.82 micrograms per liter (μg/L). Although some of the detected pesticides degrade rapidly, norflurazon and siduron are relatively stable and are able to immigrate though the serial reservoir system. Concentrations of 2,4-D, carbaryl, imazaquin, MCPA (2-methyl-4-chlorophenoxyacetic acid), metsulfuron-methyl, norflurazon, siduron, and caffeine were detected more frequently in stormflow samples than in base-flow samples. Concentrations of pesticides did not exceed USEPA drinking-water guidelines or other health standards and were several orders of magnitude less than the lethal exposure level established for several fish species common to the drinking-water source area. Imidacloprid, an insecticide, was the only pesticide with a concentration exceeding available long-term aquatic-life guidelines. Several pesticides correlated significantly with the amount of recreational, residential, and commercial area in the tributary subbasins. Mean annual base-flow concentrations of caffeine correlated significantly with parking-lot land use. For most tributaries, about 70 percent of the annual loads of Ca, Cl, Na, and SO 4 were associated with base flow. Upward temporal trends in annual loads of Cl and Na were identified on the basis of data for water years 1998 to 2008 for the outlet of the Cambridge Reservoir in the Hobbs Brook Basin; however, similar trends were not identified for the main stem of Stony Brook downstream from the reservoir. The proportions of the TN load attributed to base flow and stormflow were similar in each tributary. In contrast, more than 83 percent of the TP loads in the tributaries and about 73 percent of the TP load in main stem of Stony Brook were associated with stormflow. Mean annual yields of Ca, Cl, Na, and SO 4 in the Stony Brook Reservoir watershed, which represents most of the drinking-water source area, were 14, 85, 46, and 9 metric tons per square kilometer, respectively. Mean annual yields among the individual tributary subbasins varied extensively. Mean annual yields for the respective constituents increased with an increase in roadway and parking-lot area in the tributary subbasins. Mean annual yields of TN in the tributary subbasins ranged from about 740 to more than 1,200 kilograms per square kilometer and exceeded the yield for the main stem of Stony Brook at USGS station 01104460 upstream from the Stony Brook Reservoir. Mean annual yields estimated for the herbicides 2,4-D and imidacloprid ranged from 34 to 310 grams per square kilometer (g/km 2 ) and 3 to 170 g/km 2 , respectively. Annual loads for 2,4-D were entirely associated with stormflow. The largest annual load for imidacloprid was estimated for the main stem of Stony Brook; however, the highest annual yield for this pesticide, as well as for benomyl, carbaryl, metalaxyl, and propiconazole, was estimated for a tributary to the Stony Brook Reservoir that drains largely residential and recreational areas. Mean annual yields for the herbicide siduron ranged from 6.9 to 35 g/km 2 with most of the loads associated with stormflow. Mean annual yields for the insecticide diuron ranged from 2.1 to 4.4 g/km 2 . Annual yields of caffeine ranged from 11 to 410 g/km 2 .

Massachusetts↗

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2010

Streamflow and water-quality data were collected by the U.S. Geological Survey (USGS) or the Providence Water Supply Board (PWSB), Rhode Island's largest drinking-water supplier. Streamflow was measured or estimated by the USGS following standard methods at 23 streamgages; 14 of these stations were also equipped with instrumentation capable of continuously monitoring specific conductance and water temperature. Streamflow and concentrations of sodium and chloride estimated from records of specific conductance were used to calculate loads of sodium and chloride during water year (WY) 2010 (October 1, 2009, to September 30, 2010). Water-quality samples also were collected at 37 sampling stations by the PWSB and at 14 monitoring stations by the USGS during WY 2010 as part of a long sampling program; all stations are in the Scituate Reservoir drainage area. Waterquality data collected by PWSB are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields (loads per unit area) of selected water-quality constituents for WY 2010. The largest tributary to the reservoir (the Ponaganset River, which was monitored by the USGS) contributed a mean streamflow of about 39 cubic feet per second (ft 3 /s) to the reservoir during WY 2010. For the same time period, annual mean streamflows measured (or estimated) for the other monitoring stations in this study ranged from about 0.7 to 27 ft 3 /s. Together, tributary streams (equipped with instrumentation capable of continuously monitoring specific conductance) transported about 1,500,000 kilograms (kg) of sodium and 2,500,000 kg of chloride to the Scituate Reservoir during WY 2010; sodium and chloride yields for the tributaries ranged from 11,000 to 66,000 kilograms per square mile (kg/mi 2 ) and from 18,000 to 110,000 kg/mi 2 , respectively. At the stations where water-quality samples were collected by the PWSB, the median of the median chloride concentrations was 20.2 milligrams per liter (mg/L), median nitrite concentration was 0.002 mg/L as nitrogen (N), median nitrate concentration was 0.01 mg/L as N, median orthophosphate concentration was 0.06 mg/L as phosphorus, and median concentrations of total coliform and Escherichia coli (E. coli) bacteria were 93 and 16 colony forming units per 100 milliliters (CFU/100mL), respectively. The medians of the median daily loads (and yields) of chloride, nitrite, nitrate, orthophosphate, and total coliform and E. coli bacteria were 170 kg/d (73 kg/d/mi 2 ), 11 g/d (5.3 g/d/mi 2 ), 74 g/d (39 g/d/mi 2 ), 340 g/d (170 g/d/mi 2 ), 5,700 million colony forming units per day (CFUx106/d) (2,300 CFUx106/d/mi 2 ), and 620 CFUx106/d (440 CFUx106/d/mi 2 ), respectively.

Open-File Report↗

Surface-water, water-quality, and meteorological data for the Cambridge, Massachusetts, drinking-water source area, water years 2007-08

Records of water quantity, water quality, and meteorological parameters were continuously collected from three reservoirs, two primary streams, and five subbasin tributaries in the Cambridge, Massachusetts, drinking-water source area during water years 2007-08 (October 2006 through September 2008). Water samples were collected during base-flow conditions and storms in the Cambridge Reservoir and Stony Brook Reservoir drainage areas and analyzed for dissolved calcium, sodium, chloride, and sulfate; total nitrogen and phosphorus; and polar pesticides and metabolites. Composite samples of stormwater also were analyzed for concentrations of total petroleum hydrocarbons and suspended sediment in one subbasin in the Stony Brook Reservoir drainage basin. These data were collected to assist watershed administrators in managing the drinking-water source area and to identify potential sources of contaminants and trends in contaminant loading to the water supply. Monthly reservoir contents for the Cambridge Reservoir ranged from about 30 to 95 percent of capacity during water years 2007-08. Monthly reservoir contents for the Stony Brook Reservoir ranged from about 47 to 91 percent of capacity during water years 2007-08, while the monthly reservoir storage values for Fresh Pond Reservoir were maintained at greater than 92 percent of capacity. If the average water demand by the city of Cambridge is assumed to be 15 million gallons per day, the volume of water released from the Stony Brook Reservoir to the Charles River during water years 2007-08 represents an annual surplus of about 107 and 94 percent, respectively. The annual precipitation total of about 47 in (inches) recorded at the Cambridge reservoir during water year 2007 was about 5 to 21 percent lower than recorded totals for the previous four water years, whereas the annual precipitation total of about 62 in. during water year 2008 was about 5 to 32 percent higher than recorded totals for water years 2002-07. In general, most monthly mean specific-conductance values for water year 2007 for U.S. Geological Survey (USGS) stations on the two primary streams and four subbasin tributaries in the Cambridge, Massachusetts, drinking-water source area were below the previous median monthly values and often were below the previous minimum monthly values for available data since water year 1997. The annual mean specific-conductance value for Fresh Pond Reservoir during water year 2007 was 483 (u or mu)S/cm (microsiemens per centimeter), which was lower than the prior three water years. The monthly mean specific-conductance values for streamflow for Hobbs Brook below the Cambridge Reservoir for December through July 2008 were greater than the 75th percentile for historical data since water year 1997. These relatively high values were caused by the inflow of high specific conductance water from the tributaries when the reservoir water level was low at the onset of winter. Increased rainfall in the watershed beginning in February 2008 caused monthly mean specific-conductance values for Hobbs Brook to decrease to about 700 (u or mu)S/cm by the end of the water year. Monthly mean specific-conductance values for many of the other USGS stations were higher than historical values for several months during the winter of water year 2008. The large amount of rainfall in the watershed also caused the monthly mean specific conductance at these stations to decline to near-median values or to values within the interquartile range for available historical data. The annual mean specific conductance for Fresh Pond Reservoir during water year 2008 was 497 (u or mu)S/cm, slightly greater than the corresponding value for the prior year. Water samples were collected in nearly all of the subbasins in the Cambridge drinking-water source area and from Fresh Pond during the study period. Discrete water samples were collected during base-flow conditions with an antecedent dry period of at least 3 days. Composite sampl

Cambridge, Massachusetts↗

Effectiveness of catch basins equipped with hoods in retaining gross solids and hydrocarbons in highway runoff, Southeast Expressway, Boston, Massachusetts, 2008-09

Stormwater mobilizes litter and other debris along the roadway where it is transported to the highway drainage systems. Initial treatment for stormwater runoff typically is provided by catch basins in highway settings. Modification of catch basins to include hoods that cover the catch-basin outlet is intended to enhance catch-basin performance by retaining floatable debris and various hydrophobic organic compounds that tend to float on the water surface within the sump of the catch basin. The effectiveness of six deep-sump off-line catch basins equipped with hoods in reducing the mass of gross solids greater than 0.25 inches in diameter and concentrations of oil and grease (OG) and total petroleum hydrocarbons (TPH) was examined along the Southeast Expressway, in Boston, Massachusetts. Two deep-sump catch basins were equipped with cast-iron hoods. Three were equipped with molded plastic hoods, known as an Eliminator, and a single catch basin was equipped with a fiberglass anti-siphoning hood, known as a Snout. Samples of gross solids greater than 0.25 inches in diameter, excluding gravel and metallic materials, were routinely collected for a 6-month period from a collection structure mounted at the end of each catch-basin outlet pipe. After about 6 months, all floatable, saturated low-density and high-density solids were removed from each catch basin. In addition to the collection of samples of gross solids, samples of sump water from five catch basins and flow-weighted composite samples of stormwater from the outlet of one catch basin were collected and analyzed for concentrations of OG and TPH. A mass balance approach was used to assess the effectiveness of each catch basin equipped with a hood in retaining gross solids. The effectiveness of the deep-sump catch basins fitted with one of three types of hoods in retaining gross solids ranged from 27 to 52 percent. From 45 to 90 percent of the gross solids collected from the catch-basin sumps were composed of materials made of high-density plastics that did not float in water, and as a result, the effect that the catch-basin hoods had on these materials likely was marginal. The effectiveness for the deep-sump hooded catch basins, excluding the mass of high-density materials identified in the solids collected from the outlet pipe and the sump of the catch basins, ranged from 13 to 38 percent. The effectiveness for each catch basin, based solely on the material that remained floating at the end of the monitoring period, was less than 11 percent; however, these values likely underestimate the effectiveness of the hooded catch basins because much of the low-density material collected from the sumps may have been retained as floatable material before it was saturated and settled during non-storm conditions. The effectiveness of the catch basins equipped with hoods in reducing gross solids was not greatly different among the three types of hoods tested in this study. Concentrations of OG and TPH collected from the water surface of the catch-basins varied from catch basin to catch basin and were similar to concentrations of flow-weighted composite samples collected during storms. Comparisons indicate concentrations of OG and TPH in flow-weighted composite samples collected at the outlet of a catch basin equipped with an Eliminator hood were not substantially different from concentrations of the respective constituents in flow-weighted composite samples collected during a previous study from catch basins containing cast-iron hoods in the same study area. The similarity between these flow-weighted concentrations and the concentrations of the respective constituents in a vertical profile sample collected from the catch-basin sump indicates that OG and TPH are emulsified in the sump of each catch basin during storms and circumvent the hoods.

Massachusetts↗

Streamflow, water quality, and constituent loads and yields, Scituate Reservoir drainage area, Rhode Island, water year 2009

Streamflow and water-quality data were collected by the U.S. Geological Survey (USGS) or the Providence Water Supply Board (PWSB), Rhode Island's largest drinking-water supplier. Streamflow was measured or estimated by the USGS following standard methods at 23 streamgage stations; 13 of these stations were also equipped with instrumentation capable of continuously monitoring specific conductance and water temperature. Streamflow and concentrations of sodium and chloride estimated from records of specific conductance were used to calculate loads of sodium and chloride during water year (WY) 2009 (October 1, 2008, to September 30, 2009). Water-quality samples also were collected at 37 sampling stations by the PWSB and at 14 monitoring stations by the USGS during WY 2009 as part of a long-term sampling program; all stations are in the Scituate Reservoir drainage area. Water-quality data collected by PWSB are summarized by using values of central tendency and are used, in combination with measured (or estimated) streamflows, to calculate loads and yields (loads per unit area) of selected water-quality constituents for WY 2009. The largest tributary to the reservoir (the Ponaganset River, which was monitored by the USGS) contributed a mean streamflow of about 27 cubic feet per second (ft3/s) to the reservoir during WY 2009. For the same time period, annual mean1 streamflows measured (or estimated) for the other monitoring stations in this study ranged from about 0.50 to 17 ft3/s. Together, tributary streams (equipped with instrumentation capable of continuously monitoring specific conductance) transported about 1,400,000 kilograms (kg) of sodium and 2,200,000 kg of chloride to the Scituate Reservoir during WY 2009; sodium and chloride yields for the tributaries ranged from 10,000 to 64,000 kilograms per square mile (kg/mi2) and from 15,000 to 110,000 kg/mi2, respectively. At the stations where water-quality samples were collected by the PWSB, the median of the median chloride concentrations was 21.7 milligrams per liter (mg/L), median nitrite concentration was 0.001 mg/L as N, median nitrate concentration was 0.02 mg/L as N, median orthophosphate concentration was 0.09 mg/L as P, and median concentrations of total coliform and Escherichia coli (E. coli) bacteria were 61 and 16 colony forming units per 100 milliliters (CFU/100 mL), respectively. The medians of the median daily loads (and yields) of chloride, nitrite, nitrate, orthophosphate, and total coliform and E. coli bacteria were 190 kg/d (61 kg/d/mi2), 12 g/d (4.5 g/d/mi2), 93 g/d (32 g/d/mi2), 420 g/d (290 g/d/mi2), 6,200 million colony forming units per day (CFU?106/d) (2,600 CFU?106/d/mi2), and 1,100 CFU?106/d (340 CFU?106/d/mi2), respectively. 1The arithmetic mean of the individual daily mean discharges for the year noted or for the designated period.

Open-File Report↗

Quality of stormwater runoff discharged from Massachusetts highways, 2005-07

The U.S. Geological Survey (USGS), in cooperation with U.S. Department of Transportation Federal Highway Administration and the Massachusetts Department of Transportation, conducted a field study from September 2005 through September 2007 to characterize the quality of highway runoff for a wide range of constituents. The highways studied had annual average daily traffic (AADT) volumes from about 3,000 to more than 190,000 vehicles per day. Highway-monitoring stations were installed at 12 locations in Massachusetts on 8 highways. The 12 monitoring stations were subdivided into 4 primary, 4 secondary, and 4 test stations. Each site contained a 100-percent impervious drainage area that included two or more catch basins sharing a common outflow pipe. Paired primary and secondary stations were located within a few miles of each other on a limited-access section of the same highway. Most of the data were collected at the primary and secondary stations, which were located on four principal highways (Route 119, Route 2, Interstate 495, and Interstate 95). The secondary stations were operated simultaneously with the primary stations for at least a year. Data from the four test stations (Route 8, Interstate 195, Interstate 190, and Interstate 93) were used to determine the transferability of the data collected from the principal highways to other highways characterized by different construction techniques, land use, and geography. Automatic-monitoring techniques were used to collect composite samples of highway runoff and make continuous measurements of several physical characteristics. Flowweighted samples of highway runoff were collected automatically during approximately 140 rain and mixed rain, sleet, and snowstorms. These samples were analyzed for physical characteristics and concentrations of 6 dissolved major ions, total nutrients, 8 total-recoverable metals, suspended sediment, and 85 semivolatile organic compounds (SVOCs), which include priority polyaromatic hydrocarbons (PAHs), phthalate esters, and other anthropogenic or naturally occurring organic compounds. The distribution of particle size of suspended sediment also was determined for composite samples of highway runoff. Samples of highway runoff were collected year round and under various dry antecedent conditions throughout the 2-year sampling period. In addition to samples of highway runoff, supplemental samples also were collected of sediment in highway runoff, background soils, berm materials, maintenance sands, deicing compounds, and vegetation matter. These additional samples were collected near or on the highways to support data analysis. There were few statistically significant differences between populations of constituent concentrations in samples from the primary and secondary stations on the same principal highways (Mann-Whitney test, 95-percent confidence level). Similarly, there were few statistically significant differences between populations of constituent concentrations for the four principal highways (data from the paired primary and secondary stations for each principal highway) and populations for test stations with similar AADT volumes. Exceptions to this include several total-recoverable metals for stations on Route 2 and Interstate 195 (highways with moderate AADT volumes), and for stations on Interstate 95 and Interstate 93 (highways with high AADT volumes). Supplemental data collected during this study indicate that many of these differences may be explained by the quantity, as well as the quality, of the sediment in samples of highway runoff. Nonparametric statistical methods also were used to test for differences between populations of sample constituent concentrations among the four principal highways that differed mainly in traffic volume. These results indicate that there were few statistically significant differences (Mann-Whitney test, 95-percent confidence level) for populations of concentrations of most total-recoverable metals

Scientific Investigations Report↗

Hydrologic, Water-Quality, and Meteorological Data for the Cambridge, Massachusetts, Drinking-Water Source Area, Water Year 2006

Records of water quantity, water quality, and meteorological parameters were continuously collected from three reservoirs, two primary streams, and four subbasin tributaries in the Cambridge, Massachusetts, drinking-water source area during water year 2006 (October 2005 through September 2006). Water samples were collected during base-flow conditions and storms in the subbasins of the Cambridge Reservoir and Stony Brook Reservoir drainage areas and analyzed for dissolved calcium, sodium, chloride, and sulfate; total nitrogen and phosphorus; and polar pesticides and metabolites. These data were collected to assist watershed administrators in managing the drinking-water source area and to identify potential sources of contaminants and trends in contaminant loading to the water supply. Monthly reservoir contents for the Cambridge Reservoir varied from about 59 to 98 percent of capacity during water year 2006, while monthly reservoir contents for the Stony Brook Reservoir and the Fresh Pond Reservoir was maintained at greater than 83 and 94 percent of capacity, respectively. If water demand is assumed to be 15 million gallons per day by the city of Cambridge, the volume of water released from the Stony Brook Reservoir to the Charles River during the 2006 water year is equivalent to an annual water surplus of about 127 percent. Recorded precipitation in the source area was about 16 percent greater for the 2006 water year than for the previous water year and was between 12 and 73 percent greater than for any recorded amount since water year 2002. The monthly mean specific-conductance values for all continuously monitored stations within the drinking-water source area were generally within the range of historical data collected since water year 1997, and in many cases were less than the historical medians. The annual mean specific conductance of 738 uS/cm (microsiemens per centimeter) for water discharged from the Cambridge Reservoir was nearly identical to the annual mean specific conductance for water year 2005 which was 737 uS/cm. However, the annual mean specific conductance at Stony Brook near Route 20 in Waltham (U.S. Geological Survey (USGS) station 01104460), on the principal tributary to the Stony Brook Reservoir, and at USGS station 01104475 on a smaller tributary to the Stony Brook Reservoir were about 15 and 13 percent lower, respectively, than the previous annual mean specific conductances of 538 and 284 uS/cm, respectively for water year 2005. The annual mean specific conductance for Fresh Pond Reservoir decreased from 553 uS/cm in the 2005 water year to 514 uS/cm in the 2006 water year. Water samples were collected in nearly all of the subbasins in the Cambridge drinking-water source area and from Fresh Pond during water year 2006. Discrete water samples were collected during base-flow conditions with an antecedent dry period of at least 4 days. Composite samples, consisting of as many as 100 subsamples, were collected by automatic samplers during storms. Concentrations of most dissolved constituents were generally lower in samples of stormwater than in samples collected during base flow; however, the average concentration of total phosphorus in samples of stormwater were from 160 to 1,109 percent greater than the average concentration in water samples collected during base-flow conditions. Concentrations of total nitrogen in water samples collected during base-flow conditions and composite samples of stormwater at USGS stations 01104415, 01104460, and 01104475 were similar, but mean concentrations of total nitrogen in samples of stormwater differed by about 0.5 mg/L (milligrams per liter) from those in water samples collected during base-flow conditions at U.S. Geological Survey stations 01104433 and 01104455. In six water samples, measurements of pH were lower than the U.S. Environmental Protection Agency (USEPA) national recommended freshwater quality criteria and the USEPA secondary drinking water-standa

Open-File Report↗

Distribution and migration of ordnance-related compounds and oxygen and hydrogen stable isotopes in ground water near Snake Pond, Sandwich, Massachusetts

Explosive compounds, such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), and the propellant compound perchlorate are present in ground water near Snake Pond, a ground-water flow-through glacial kettle pond in the glacial sand and gravel aquifer on western Cape Cod near Camp Edwards on the Massachusetts Military Reservation. The contaminants originate from the J-3 Range ordnance training and testing area. Ground-water samples were collected at 10 sites near the pond to determine the paths of the contaminants as they underflow or completely or partially discharge into the pond. Water-quality profiles were developed for sites on opposite ends of a 200-foot-long intermittent island near the northern, upgradient end of the pond by collecting water samples from two temporary drive-point borings. RDX was detected at both locations between 60 and 90 feet below the pond level. The highest RDX concentration was 0.99 micrograms per liter. Perchlorate was detected at only one location on the island, between 95 and 100 feet below the pond level at a concentration of 0.61 micrograms per liter. Profiles of oxygen and hydrogen stable isotopes were developed for seven sites spaced 300 to 600 feet apart along the southern, downgradient shore of the pond. A transition from heavier to lighter oxygen and hydrogen isotopes was observed at an altitude of about -50 feet. This transition most likely is the boundary between evaporation-affected pond water that is seeping into the aquifer and ground water that has passed beneath the pond. RDX was not detected in the ground-water samples collected south of the pond. Perchlorate was detected only in one sample from a shallow depth in one boring. The results of these analyses indicate that the J-3 Range plume contains low concentrations of RDX and perchlorate (less than 1 microgram per liter) as it passes beneath the northern end of Snake Pond. Results of ground-water-flow modeling indicate that ground water containing these low levels of RDX and perchlorate discharges into the pond south of the island. If the contaminated ground water should travel as far as the southern shore of the pond, it would be overlain near the shore by a zone of pond water seeping into the aquifer that is about 100 feet thick.

Massachusetts↗

Hydrologic, Water-Quality, and Meteorological Data for the Cambridge, Massachusetts, Drinking-Water Source Area, Water Year 2005

Records of water quantity, water quality, and meteorological parameters were continuously collected from three reservoirs, two primary streams, and four subbasin tributaries in the Cambridge, Massachusetts, drinking-water source area during water year 2005 (October 2004 through September 2005). Water samples were collected during base-flow conditions and storms in the subbasins of the Cambridge Reservoir and Stony Brook Reservoir drainage areas and analyzed for selected elements, organic constituents, suspended sediment, and Escherichia coli bacteria. These data were collected to assist watershed administrators in managing the drinking-water source area and to identify potential sources of contaminants and trends in contaminant loading to the water supply. Monthly reservoir capacities for the Cambridge Reservoir varied from about 59 to 98 percent during water year 2005, while monthly reservoir capacities for the Stony Brook Reservoir and the Fresh Pond Reservoir were maintained at capacities greater than 84 and 96 percent, respectively. Assuming a water demand of 15 million gallons per day by the city of Cambridge, the volume of water released from the Stony Brook Reservoir to the Charles River during the 2005 water year is equivalent to an annual water surplus of about 119 percent. Recorded precipitation in the source area for the 2005 water year was within 2 inches of the total annual precipitation for the previous 2 water years. The monthly mean specific conductances for the outflow of the Cambridge Reservoir were similar to historical monthly mean values. However, monthly mean specific conductances for Stony Brook near Route 20, in Waltham (U.S. Geological Survey station 01104460), which is the principal tributary feeding the Stony Brook Reservoir, were generally higher than the medians of the monthly mean specific conductances for the period of record. Similarly, monthly mean specific conductances for a small tributary to Stony Brook (U.S. Geological Survey station 01104455) were generally higher than the medians of the monthly mean specific conductances for the period of record. The annual mean specific conductance for Fresh Pond Reservoir increased from 514 microsiemens per centimeter (?S/cm) in the 2004 water year to 553 ?S/cm for the 2005 water year. Water samples were collected from four tributaries during base-flow and stormflow conditions in December 2004, and July, August, and September 2005 and analyzed for suspended sediment, 6 major dissolved ions, total nitrogen, total phosphorus, 8 total metals, 18 polyaromatic hydrocarbons (PAHs), 61 pesticides and metabolites, and Escherichia coli bacteria. Concentrations for most dissolved constituents in samples of stormwater were generally lower than the concentrations observed in samples collected during base flow; however, concentrations of total phosphorus, PAHs, suspended sediment, and some total recoverable metals were substantially greater in stormwater samples. Concentrations of dissolved chloride and total recoverable manganese in water samples collected during base-flow conditions from three tributaries exceeded the U.S. Environmental Protection Agency (USEPA) secondary drinking water standards of 250 and 0.05 milligrams per liter (mg/L), respectively. Concentrations of total recoverable manganese exceeded the secondary drinking water standard in samples of stormwater from each tributary. Concentrations of total recoverable iron in water samples exceeded the (USEPA) secondary drinking water standard of 0.3 mg/L periodically in water samples collected at (USEPA) stations 01104415, 01104455, and 01104475, and consistently in all water samples collected at USGS station 01104433. Concentrations of Escherichia coli bacteria in water samples collected during base flow ranged from 4 to 1,400 colony-forming units per 100 milliliters (col/100mL). Concentrations of Escherichia coli bacteria in composite samples of stormwater ranged between 1,700 to 43,000 c

Open-File Report↗

Characteristics of and Areas Contributing Recharge to Public-Supply Springs in Massachusetts

The geohydrologic and physical characteristics were determined for 28 public-supply springs, 27 of which are in western Massachusetts. Discharge ranged from zero at various small intermittent springs to more than 240 gallons per minute at Waubeeka Springs in Williamstown, Massachusetts. To determine the annual variability of spring discharge, discharge from 12 springs was measured during different seasonal conditions from June 2001 to November 2002, and the discharge from Red Mill Spring in Clarksburg, Massachusetts was recorded continuously from April 2002 to November 2002. The area contributing recharge to each spring was delineated on the basis of the geohydrologic conditions determined from reconnaissance investigations; these areas ranged from 0.010 to 0.682 square mile. Ground-water recharge, estimated on the basis of average discharge and the areas contributing recharge, ranged from 0.5 to 24.4 inches per year. High ground-water recharge rates for some of the high-discharge springs indicate that the areas contributing recharge for these springs may be too small. Detailed water-table mapping in the vicinity of two low-discharge springs indicates that the area contributing recharge to some of the smaller springs may be smaller than the area indicated by reconnaissance investigation. Monthly flow durations and low flow statistics were determined for the index streamflow-gaging stations for a 25-year period from 1976 to 2000. Annual hydrographs were prepared for each index station from median streamflows at the 50-percent monthly flow duration, normalized by drainage area. A median monthly flow of 1 ft3/s/mi2 was used to split hydrographs into a high-flow period (November?May), and a low-flow period (June?October). The hydrographs were used to classify index stations into groups with similar median monthly flow durations. Index stations were divided into four regional groups, roughly paralleling the coast, to characterize streamflows for November to May; and into two groups, on the basis of base-flow index and percentage of sand and gravel in the contributing area, for June to October.

Water-Resources Investigations Report↗

Effectiveness of three best management practices for highway-runoff quality along the Southeast Expressway, Boston, Massachusetts

Best management practices (BMPs) near highways are designed to reduce the amount of suspended sediment and associated constituents, including debris and litter, discharged from the roadway surface. The effectiveness of a deep-sumped hooded catch basin, three 2-chambered 1,500-gallon oil-grit separators, and mechanized street sweeping in reducing sediment and associated constituents was examined along the Southeast Expressway (Interstate Route 93) in Boston, Massachusetts. Repeated observations of the volume and distribution of bottom material in the oil-grit separators, including data on particle-size distributions, were compared to data from bottom material deposited during the initial 3 years of operation. The performance of catch-basin hoods and the oil-grit separators in reducing floating debris was assessed by examining the quantity of material retained by each structural BMP compared to the quantity of material retained by and discharged from the oil-grit separators, which received flow from the catch basins. The ability of each structural BMP to reduce suspended-sediment loads was assessed by examining (a) the difference in the concentrations of suspended sediment in samples collected simultaneously from the inlet and outlet of each BMP, and (b) the difference between inlet loads and outlet loads during a 14-month monitoring period for the catch basin and one separator, and a 10-month monitoring period for the second separator. The third separator was not monitored continuously; instead, samples were collected from it during three visits separated in time by several months. Suspended-sediment loads for the entire study area were estimated on the basis of the long-term average annual precipitation and the estimated inlet and outlet loads of two of the separators. The effects of mechanized street sweeping were assessed by evaluating the differences between suspended-sediment loads before and after street sweeping, relative to storm precipitation totals, and by comparing the particle-size distributions of sediment samples collected from the sweepers to bottom-material samples collected from the structural BMPs. A mass-balance calculation was used to quantify the accuracy of the estimated sediment-removal efficiency for each structural BMP. The ability of each structural BMP to reduce concentrations of inorganic and organic constituents was assessed by determining the differences in concentrations between the inlets and outlets of the BMPs for four storms. The inlet flows of the separators were sampled during five storms for analysis of fecal-indicator bacteria. The particle-size distribution of bottom material found in the first and second chambers of the separators was similar for all three separators. Consistent collection of floatable debris at the outlet of one separator during 12 storms suggests that floatable debris were not indefinitely retained. Concentrations of suspended sediment in discrete samples of runoff collected from the inlets of the two separators ranged from 8.5 to 7,110 mg/L. Concentrations of suspended sediment in discrete samples of runoff collected from the outlets of the separators ranged from 5 to 2,170 mg/L. The 14-month sediment-removal efficiency was 35 percent for one separator, and 28 percent for the second separator. In the combined-treatment system in this study, where catch basins provided primary suspended-sediment treatment, the separators reduced the mass of the suspended sediment from the pavement by about an additional 18 percent. The concentrations of suspended sediment in discrete samples of runoff collected from the inlet of the catch basin ranged from 32 to 13,600 mg/L. Concentrations of suspended sediment in discrete samples of runoff collected from the outlet of the catch basin ranged from 25.7 to 7,030 mg/L. The sediment-removal efficiency for individual storms during the 14-month monitoring period for the deep-sumped hooded catch basin was 39 percent. The concentrations of 29 inorganic constituents in bottom sediments were typically higher for the size fraction less than 0.062 mm in diameter. Concentrations of total organic carbon (TOC) were similar for the size fraction less than 0.062 mm in diameter and the fraction greater than 2.00 mm in diameter. Concentrations of total polyaromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were larger in the fraction greater than 2.00 mm in diameter than in the size fractions less than 2.00 mm in diameter. Since PAHs and PCBs are commonly associated with TOC (including organically coated sediment), it is believed that the PCB and PAH concentrations in the solid fraction less than 0.062 mm in diameter were similar to the concentrations in the solid fraction greater than 2.00 mm in diameter, if not greater because of the effects of the surface area. The estimated annual suspended-sediment load for the entire study area was about 29,000 kg. Approximately 24,000 kg discharged directly to Malibu Beach and Tenean Beach embayments, and the remaining 5,000 kg discharged to the land surface. These loads do not include an estimated 2,000 kg of suspended sediment retained by the five oil-grit separators in the area. Mechanized street sweepers were used on the pavement three times during the study. Samples of sweepings were collected each time for the analysis of particle size. The first mechanized street sweeping had no observable effect on subsequent storm loads of suspended sediment. Following the second sweeping, a net increase of the suspended-sediment load was observed at one station and a net decrease of the suspended-sediment load was observed at the second station. These effects, however, were only temporary. The third time the highway was swept was after continuous monitoring was terminated. The particle-size distribution in sweeper samples for the size fraction less than 4 mm in diameter was similar to the particle-size distribution in bottom sediment in the catch basin. The concentration of particles greater than 0.5 mm in diameter was higher in sweeper samples than in samples from the separators, so the sweepers were successful in removing the larger particles. Because the highway lacks curbing that would provide a physical boundary to trap debris and sediment, and the equipment was inefficient in trapping particles less than 0.062 mm in diameter, pavement sweeping provided few water-quality benefits for the Southeast Expressway. The primary factor controlling the efficiency of each structural BMP in removing suspended sediment was retention time. Examination of constituent-sediment relations suggests that the retention time for many highway-related constituents was short; these constituents either were dissolved and not subject to treatment by simple gravity separation, or were associated with particles less than 0.062 mm in diameter, which commonly passed through the BMPs. Thus, the potential effectiveness of the separators and the catch basins to reduce loads of inorganic and organic constituents was much less than their ability to reduce loads of suspended sediment. The average relative percent difference (RPD) between concentrations of trace metals in stormwater samples from the inlets and the outlets of the separators ranged from 15 to 30 percent. The average RPD for concentrations of organic constituents was commonly less than about 10 percent and negative in several cases. The separators did not affect the concentrations of dissolved solids as they passed through their chambers. The average RPD between the event mean concentrations for trace metals in samples collected from the inlet and outlet of the catch basin during storms was about 25 percent. The average RPD for concentrations of organic constituents was typically less than 20 percent and even negative in several cases, except for oil and grease, which was near 30 percent. The observed ranges of the RPDs for both types of BMPs were probably larger than the actual ranges because the particle-size and concentration of suspended sediment sampled in the BMP inflows during the four storms introduced a bias in favor of higher concentrations. Concentrations of fecal and Enterococci bacteria were found throughout the storms at the inlets of the two continuously monitored separators; this result indicated that the pavement washoff process was inefficient or that there was a continuous source of bacteria in the drainage area. The efficiency of the structural BMPs tested in this study in reducing fecal-indicator bacteria concentrations was not quantified; each BMP chamber is likely to retain a quantity of fecal-indicator bacteria proportional to its storage volume after a storm. Removal of bacteria from the BMP is dependent on how well the bacteria survive until the next storm and the potential for bacterial export during the next storm.

Massachusetts↗