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J.F. Sullivan

Publications and source records attributed to J.F. Sullivan.

3 recordsLinked to original sources

Effects of the flood of 1993 on the chemical characteristics of bed sediments in the Upper Mississippi River

Concentrations of pollutants stored in the surficial bed sediments in the navigation pools of the Upper Mississippi River showed a general decrease after the record flood of 1993. Percent clay and total organic carbon in the surficial sediments decreased as a result of an increase in the proportion of coarser sediment. Decreases in pollutant concentration may have been a result of the dilution by coarser and relatively less polluted sediment that was mobilized and transported into the Upper Mississippi River from its tributaries or from mainstem locations upstream but outside of the sampling area.

Water, Air, & Soil Pollution↗

A comparison of solids collected in sediment traps and automated water samplers

Sediment traps are being used in some pollution monitoring programs in the USA to sample suspended solids for contaminant analyses. This monitoring approach assumes that the characteristics of solids obtained in sediment traps are the same as those collected in whole-water sampling devices. We tested this assumption in the upper Mississippi River, based on the inorganic particle-size distribution (determined with a laser particle-analyzer) and volatile matter content of solids (a Surrogate for organic matter). Cylindrical sediment traps (aspect ratio 3) were attached to a rigid mooring device and deployed in a flowing side channel in Navigation Pool 7 of the upper Mississippi River. On each side of the mooring device, a trap was situated adjacent to a port of an autosampler that collected raw water samples hourly to form 2-d composite samples. Paired samples (one trap and one raw water, composite sample) were removed from each end of the mooring device at 2-d intervals during the 30-d study period and compared. The relative particle collection efficiency of paired samples did not vary temporally. Particle-size distributions of inorganic solids from sediment traps and water samples were not significantly different. The volatile matter content of solids was lesser in sediment traps (mean, 9.5%) than in corresponding water samples (mean, 22.7%). This bias may have been partly due to under-collection of phytoplankton (mainly cyanobacteria), which were abundant in the water column during the study. The poisoning of water samplers and sediment traps in the mooring device did not influence the particle-size distribution or total solids of samples. We observed a small difference in the amount of organic matter collected by water samplers situated at opposite ends of the mooring device.

Hydrobiologia↗

Effects of the lampricide 3-trifluoromethyl-4-nitrophenol on dissolved oxygen in aquatic systems

The effects of the lampricide 3-trifluoromethyl-4-nitrophenol (TFM) on dissolved oxygen and other water- quality characteristics were evaluated in a series of test chambers under selected combinations of water, sediment, TFM, and exposure to sunlight. Concentrations of TFM gradually decreased over time, especially in the presence of sediment and sunlight. The lampricide did not directly cause a reduction in dissolved oxygen concentration, but appeared to inhibit photosynthetic production of oxygen during daylight. Dissolved oxygen concentrations were significantly reduced by the presence of TFM in chambers exposed to sunlight. Concentrations of total ammonia were significantly higher in chambers with sediment than in those without sediment. In chambers that contained river water and were exposed to sunlight, ammonia concentrations were low because of either oxidation by the elevated dissolved oxygen concentrations or the assimilation of nutrients by algae. The observed changes in dissolved oxygen and ammonia because of the presence of TFM were subtle, but statistically significant.

Technical Report↗