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J. N. Aleinikoff

Publications and source records attributed to J. N. Aleinikoff.

At least 37 records · Page 2Linked to original sources

P-T-t paths and differential Alleghanian loading and uplift of the Bronson Hill terrane south central New England

Late Paleozoic U-Pb ages of sphene and 40 Ar/ 39 Ar cooling ages of amphibole and muscovite from rocks of the Bronson Hill terrane in Connecticut and central Massachusetts reflect a late Paleozoic (Alleghanian) overprint on Acadian metamorphic rocks. Prograde Alleghanian sphenes crystallized during the Late Pennsylvanian, and eliminate the possibility that amphibole ages reflect delayed Permian cooling from Devonian Acadian metamorphism. Fourteen new amphibole ages from Connecticut form a north-to-south trend of decreasing age from 294 to 245 Ma, while in Massachusetts four new amphibole ages together with three others from the literature produce a random Carboniferous pattern. Seven new muscovite ages support existing data indicating uniform cooling throughout the Bronson Hill terrane through ∼350°C in the Early Triassic. The rate of Permian cooling defined by amphibole-muscovite pairs increases from ∼4°C/my in northern Connecticut to ∼50°C/my near Long Island Sound. Hinged loading and hinged but delayed exhumation in the southern part of the Bronson Hill terrane (with the hinge in central Connecticut) explain these ages and cooling rates as well as a southerly increasing metamorphic field gradient. One-dimensional thermal modeling indicates that loading of Bronson Hill rocks must have begun by the Late Mississippian. The time of peak Alleghanian metamorphic temperature decreases southward from Early Permian in northern Connecticut to Late Permian to the south. These results demonstrate that the metamorphic effects of the Alleghanian orogeny are not restricted to the Avalon terrane of southeastern New England. On the contrary, the Alleghanian orogeny reset 40 Ar/ 39 Ar mineral ages, recrystallized minerals, partially melted felsic rocks, and transposed fabrics at least as far west as the Bronson Hill terrane in south-central New England.

American Journal of Science↗

U-Pb geochronology of zircon and polygenetic titanite from the Glastonbury Complex, Connecticut, USA: An integrated SEM, EMPA, TIMS, and SHRIMP study

U-Pb ages for zircon and titanite from a granodioritic gneiss in the Glastonbury Complex, Connecticut, have been determined using both isotope dilution thermal ionization mass spectrometry (TIMS) and the sensitive high resolution ion microprobe (SHRIMP). Zircons occur in three morphologic populations: (1) equant to stubby, multifaceted, colorless, (2) prismatic, dark brown, with numerous cracks, and (3) elongate, prismatic, light tan to colorless. Cathodoluminescence (CL) imaging of the three populations shows simple concentric oscillatory zoning. The zircon TIMS age [weighted average of 207Pb/206Pb ages from Group 3 grains-450.5 ?? 1.6 Ma (MSWD=1.11)] and SHRIMP age [composite of 206Pb/238 U age data from all three groups-448.2 ?? 2.7 Ma (MSWD = 1.3)], are interpreted to suggest a relatively simple crystallization history. Titanite from the granodioritic gneiss occurs as both brown and colorless varieties. Scanning electron microscope backscatter (BSE) images of brown grains show multiple cross-cutting oscillatory zones of variable brightness and dark overgrowths. Colorless grains are unzoned or contain subtle wispy or very faint oscillatory zoning. Electron microprobe analysis (EMPA) clearly distinguishes the two populations. Brown grains contain relatively high concentrations of Fe2O3, Ce2O3 (up to ~ 1.5 wt.%), Nb2O5, and Zr. Cerium concentration is positively correlated with total REE + Y concentration, which together can exceed 3.5 wt.%. Oscillatory zoning in brown titanite is correlated with variations in REE concentrations. In contrast, colorless titanite (both as discrete grains and overgrowths on brown titanite) contains lower concentrations of Y, REE, Fe2O3, and Zr, but somewhat higher Al2O3 and Nb2O5. Uranium concentrations and Th/U discriminate between brown grains (typically 200-400 ppm U; all analyses but one have Th/U between about 0.8 and 2) and colorless grains (10-60 ppm U; Th/U of 0-0.17). In contrast to the zircon U-Pb age results, SHRIMP U-Pb data from titanite indicate multiple growth episodes. In brown grains, oscillatory zoned cores formed at 443 ?? 6 Ma, whereas white (in BSE) cross-cutting zones are 425 ?? 9 Ma. Colorless grains and overgrowths on brown grains yield an age of 265 ?? 8 Ma (using the Total Pb method) or 265 ?? 5 Ma (using the weighted average of the 206Pb/238U ages). However, EMPA chemical data identify zoning that suggests that this colorless titanite may preserve three growth events. Oscillatory zoned portions of brown titanite grains are igneous in origin; white cross-cutting zones probably formed during a previously unrecognized event that caused partial dissolution of earlier titanite and reprecipitation of a slightly younger generation of brown titanite. Colorless titanite replaced and grew over the magmatic titanite during the Permian Alleghanian orogeny. These isotopic data indicate that titanite, like zircon, can contain multiple age components. Coupling SHRIMP microanalysis with EMPA and SEM results on dated zones as presented in this study is an efficient and effective technique to extract additional chronologic ?? 2002 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

U-Pb zircon geochronology of the Paleoproterozoic Tagragra de Tata inlier and its Neoproterozoic cover, western Anti-Atlas, Morocco

New U-Pb zircon data obtained by sensitive high resolution ion microprobe (SHRIMP) from the Tagragra de Tata inlier in the western Anti-Atlas, Morocco establish Paleoproterozoic ages for the basement schists, granites, and metadolerites, and a Neoproterozoic age for an ignimbrite of the Ouarzazate Series in the cover sequence. The age of interbedded felsic metatuff in the metasedimentary and metavolcanic sequence of the basement schists is 2072 ?? 8 Ma. This date represents: (1) the first reliable age from the metasedimentary and metavolcanic sequence; (2) the oldest reliable age for the basement of the Anti-Atlas; (3) the first date on the timing of deposition of the sediments on the northern edge of the Paleoproterozoic West African craton; (4) a lower age limit on deformation during the Eburnean orogeny; and (5) the first date obtained from the non-granitic Paleoproterozoic basement of Morocco. Ages of 2046 ?? 7 Ma (Targant granite) and 2041 ?? 6 Ma (Oudad granite) support earlier interpretations of a Paleoproterozoic Eburnean igneous event in the Anti-Atlas. The granites post-date the Eburnean D1 deformation event in the Paleoproterozoic schist sequence, and place a ???2046 Ma limit on short-lived Eburnean deformation in the area. Cross-cutting metadolerite is 2040 ?? 6 Ma; this is the first date from a metadolerite in the western Anti-Atlas. All of the dolerites in the area post-date emplacement of the two granites and the new age constrains the onset of late- or post-Eburnean extension. Ignimbrite of the Ouarzazate Series, immediately above the Paleoproterozoic basement is 565 ?? 7 Ma. This Neoproterozoic age agrees with ages of similar volcanic rocks elsewhere from the Ouarzazate Series. The date also agrees with the ages of associated hypabyssal intrusions, and marks the second and final stage of Pan-African orogenic activity in the western Anti-Atlas. ?? 2002 Elsevier Science B.V. All rights reserved.

Precambrian Research↗

Stratigraphy, geochronology, and accretionary terrane settings of two Bronson Hill arc sequences, northern New England

The Ammonoosuc Volcanics, Partridge Formation, and the Oliverian and Highlandcroft Plutonic Suites of the Bronson Hill anticlinorium (BHA) in axial New England are widely accepted as a single Middle to Late Ordovician magmatic arc that was active during closure of Iapetus. Mapping and U–Pb dating indicate, however, that the BHA contains two volcano-sedimentary-intrusive sequences of probable opposite subduction polarity, here termed the Ammonoosuc and Quimby sequences. The Ammonoosuc sequence is defined by the Middle Ordovician Ammonoosuc Volcanics near Littleton, N.H., the type area, northeast to Milan, N.H., and Oquossoc, Me.; it also includes black slate of the Partidge Formation ( C. bicornis zone graptolites, ∼457 Ma). Related metamorphosed intrusive are the tonalitic Joslin Turn pluton (469±2 Ma), the Cambridge Black granitic pluton (468±3 Ma), and gabbro, tonalite (467±4 Ma), and sheeted diabase of the Chickwolnepy instructions. These intrusives cut lowermost Ammonoosuc (therefore >469 Ma). Probable uppermost Ammonoosuc is dated at 465±6 and 461±8 Ma. Successively below the Ammonoosuc are the Dead River and Hurricane Mountain Formations (flysch and melange), and the Jim Pond Formation (484±5 Ma) and Boil Mountain Complex (both ophiolite), which are structurally underlain by the Neoproterozoic(?) Chain Lakes massif. The Quimby sequence is defined by the Lower Silurian(?) to Upper Ordovician Quimby Formation, composed of bimodal volcanics (443±4 Ma) and sulfidic shale and graywacke that lie conformably to unconformably above the Ammonoosuc Volcanics and Partridge Formation. Also in the Quimby sequence are several granitic to sparsely gabbroic plutons of the Highlandcroft (441–452 Ma) and Oliverian (435–456 Ma) Plutonic Suites, which intrude the Dead River, Ammonoosuc and Partridge, but not the Quimby Formation. Based on faunal, paleolatitude, and isotropic data, the Ammonoosuc sequence and its correlative and underlying sequences formed off the southern Laurentian margin, but northwest of the principal Iapetan suture, or Red Indian line (RIL). The Boil Mountain–Jim Pond–Hurricane Mountain sequence was ramped northwestward over the Chain Lakes massif at ∼475 Ma, on the basal Boil Mountain surface. This obduction probably occurred slightly before obduction on the Baie Verte–Brompton surface (BBL), farther NW, over the Laurentian margin, and was followed by Dead River flysch sedimentation, which ended with the abrupt onset of Ammonoosuc-sequence arc magmatism at ∼470 Ma. Ammonoosuc eruptions probably ended at ∼460 Ma, when Iapetus closed along the Red Indian line. During a following magmatic hiatus of ∼3–5 m.y., now represented by portions of the Partridge Formation that overlie the Ammonoosuc Volcanics, subduction polarity reversed, and subduction resumed below the northwest-dipping Brunswick subduction complex (BSC) of New Brunswick, Canada. Quimby-sequence magmatism (∼456–435 Ma) on the the newly accreted Laurentian margin occurred above the BSC, whose footwall is now buried to the southeast by mainly Silurian clastic sediments of the Merrimack–Fredericton trough, deposited in the “Fredericton Sea”. In Silurian to Early Devonian time, the NW-dipping BSC footwall was paired with a SE-dipping subduction zone that produced arc magmas of the Coastal Volcanic belt, built on the composite Avalon and adjacent peri-Avalonian terranes. Orogen-normal extension produced by rapid rollback of both subduction zones narrowed the Fredericton Sea, produced the Central Maine and Connecticut Valley–Gaspé basins, and culminated in the Acadian orogeny when the sea completely closed in Early Devonian time.

Maine, New Hampshire↗

U-Pb geochronology of zircon and monazite from Mesoproterozoic granitic gneisses of the northern Blue Ridge, Virginia and Maryland, USA

Mesoproterozoic granitic gneisses comprise most of the basement of the northern Blue Ridge geologic province in Virginia and Maryland. Lithology, structure, and U-Pb geochronology have been used to subdivide the gneisses into three groups. The oldest rocks, Group 1, are layered granitic gneiss (1153 ?? 6 Ma), hornblende monzonite gneiss (1149 ?? 19 Ma), porphyroblastic granite gneiss (1144 ?? 2 Ma), coarse-grained metagranite (about 1140 Ma), and charnockite (>1145 Ma?). These gneisses contain three Proterozoic deformational fabrics. Because of complex U-Pb systematics due to extensive overgrowths on magmatic cores, zircons from hornblende monzonite gneiss were dated using the sensitive high-resolution ion microprobe (SHRIMP), whereas all other ages are based on conventional U-Pb geochronology. Group 2 rocks are leucocratic and biotic varieties of Marshall Metagranite, dated at 1112??3 Ma and 1111 ?? 2 Ma respectively. Group 3 rocks are subdivided into two age groups: (1) garnetiferous metagranite (1077 ?? 4 Ma) and quartz-plagioclase gneiss (1077 ?? 4 Ma); (2) white leucocratic metagranite (1060 ?? 2 Ma), pink leucocratic metagranite (1059 ?? 2), biotite granite gneiss (1055 ?? 4 Ma), and megacrystic metagranite (1055 ?? 2 Ma). Groups 2 and 3 gneisses contain only the two younger Proterozoic deformational fabrics. Ages of monazite, seprated from seven samples, indicate growth during both igneous and metamorphic (thermal) events. However, ages obtained from individual grains may be mixtures of different age components, as suggested by backscatter electron (BSE) imaging of complexly zoned grains. Analyses of unzoned monazite (imaged by BSE and thought to contain only one age component) from porphyroblastic granite gneiss yield ages of 1070, 1060, and 1050 Ma. The range of ages of monazite (not reset to a uniform date) indicates that the Grenville granulite event at about 1035 Ma did not exceed about 750??C. Lack of evidence for 1110 Ma growth of monazite in porphyroblastic granite gneiss suggests that the Short Hill fault might be a Grenvillian structure that was reactivated in the Paleozoic. The timing of Proterozoic deformations is constrained by crystallization ages of the gneissic rocks. D1 occurred between about 1145 and 1075 Ma (or possibly between about 1145 and 1128 Ma). D2 and D3 must be younger than about 1050 Ma. Ages of Mesoproterozoic granitic rocks of the northern Blue Ridge are similar to rocks in other Grenville terranes of the eastern USA, including the Adirondacks and Hudson Highlands. However, comparisons with conventional U-Pb ages of granulite-grade rocks from the central and southern Appalachians may be specious because these ages may actually be mixtures of ages of cores and overgrowths.

Precambrian Research↗

Isotopic evidence for the sources of Cretaceous and tertiary granitic rocks, east-central Alaska: Implications for the tectonic evolution of the Yukon-Tanana terrane

Magnetotelluric traverses across the southern Yukon-Tanana terrane (YTT) reveal the presence of a thick conductive layer (or layers) beneath Paleozoic crystalline rocks. These rocks have been interpreted to be flysch of probable Mesozoic age, on the basis of the occurrence of Jurassic-Cretaceous flysch in the Kahiltna assemblage and Gravina-Nutzotin belt flanking the YTT to the southwest and southeast, respectively. The Pb, Nd, Sr, and O isotopes in Cretaceous and Tertiary granitic rocks that crop out throughout the YTT were measured to determine if these rocks do in fact contain a component of flysch. Previous limited analyses indicated that the Pb isotopes of the granitic rocks could be a mixture of radiogenic Pb derived from Paleozoic crystalline rocks of the YTT with an increasing component of relatively nonradiogenic Pb with decreasing age. Our Nd, Sr, and O data, along with additional Pb isotope data, eliminate flysch as a likely source and strongly suggest that the nonradiogenic end-member was derived from mafic rocks, either directly from mantle magma or by melting of mafic crust. The lack of a sedimentary component in the granitic plutons suggests either that the plutons did not incorporate significant amounts of flysch during intrusion or that the conductive layer beneath the YTT crystalline rocks is not flysch.

Alaska↗

SHRIMP U-Pb geochronology of volcanic rocks, Belt Supergroup, western Montana: Evidence for rapid deposition of sedimentary strata

New sensitive high resolution ion microprobe (SHRIMP) U–Pb zircon analyses from two tuffs and a felsic flow in the middle and upper Belt Supergroup of northwestern Montana significantly refine the age of sedimentation for this very thick (15-20 km) Middle Proterozoic stratigraphic sequence. In ascending stratigraphic order, the results are (1) 1454 ± 9 Ma for a tuff in the upper part of the Helena Formation at Logan Pass, Glacier National Park; (2) 1443 ± 7 Ma for a regionally restricted porphyritic rhyolite to quartz latite flow of the Purcell Lava in the Yaak River region; and (3) 1401 ± 6 Ma for a tuff in the very thin transition zone between the Bonner Quartzite and Libby Formation, west of the town of Libby. Combining these ages with those previously published by other workers for ca. 1470-Ma sills in the lower Belt in Montana and Canada indicates that all but the uppermost Belt strata (about 1700 m) were deposited over a period of about 70 million years, considerably reducing the time span from longstanding estimates ranging from 250 to 600 million years. Calculated sediment accumulation rates between dated samples indicates rapid, but not unreasonable, values for early Belt strata, with decreasing rates through time. These ages also suggest the inadequacy of previously published paleomagnetic data to resolve Belt Supergroup chronology at an appropriate level of accuracy.</>

Montana↗

Late Quaternary loess in northeastern Colorado: Part II - Pb isotopic evidence for the variability of loess sources

Loess in eastern Colorado covers an estimated 14 000 km 2 , and is the westernmost part of the North American midcontinent loess province. Stratigraphic studies indicate there were two periods of loess deposition in eastern Colorado during late Quaternary time. The first period spanned ca. 20 000 to 12 000 14 C yr B.P. (ca. 20–14 ka) and correlates reasonably well with the culmination and retreat of Pinedale glaciers in the Colorado Front Range during the last glacial maximum. The second period of loess deposition occurred between ca. 11 000 and 9000 14 C yr B.P. This interval may be Holocene or may correlate with a hypothesized Younger Dryas glacial advance in the Colorado Front Range. Sedimentologic, mineralogic, and geochemical data indicate that as many as three sources could have supplied loess in eastern Colorado. These sources include glaciogenic silt (derived from the Colorado Front Range) and two bedrock sources, volcaniclastic silt from the White River Group, and clays from the Pierre Shale. The sediment sources imply a generally westerly paleowind during the last glacial maximum. New carbon isotope data, combined with published faunal data, indicate that the loess was probably deposited on a cool steppe, implying a last glacial maximum July temperature depression, relative to the present, of at least 5–6 °C. Overall, loess deposition in eastern Colorado occurred mostly toward the end of the last glacial maximum, under cooler and drier conditions, with generally westerly winds from more than one source.

Geological Society of America Bulletin↗

Stratigraphic and structural implications of conodont and detrital zircon U-Pb ages from metamorphic rocks of the Coldfoot terrane, Brooks Range, Alaska

New paleontologic and isotopic data from the Emma Creek and Marion Creek schists of the Coldfoot terrane, Arctic Alaska superterrane, central Brooks Range, suggest Devonian and possibly younger ages of deposition for their sedimentary protoliths. Conodonts from marble of the Emma Creek schist, intruded by a roughly 392 Ma orthogneiss, are late Lochkovian (early Early Devonian, between about 408 and 396 Ma) and Silurian to Devonian at two other locations. Spherical to oblong detrital zircons from quartz-mica schist of the overlying Marion Creek schist yield mostly discordant U—Pb data suggestive of provenance ages of 3.0, 2.0–1.8, and 1.5–1.4 Ga; however, several euhedral grains of zircon from Marion Creek quartz-mica schist have concordant U—Pb ages from 370 to 360 Ma. The Marion Creek schist in our study area therefore is at least 26 m.y. younger than the Emma Creek schist. The age data imply that the protolith of the Emma Creek schist is age correlative with Devonian carbonate rocks in the Hammond and North Slope terranes, whereas the Marion Creek schist is age correlative with Upper Devonian and Lower Mississippian clastic sedimentary rocks of the Endicott Group in the Endicott Mountains terrane and shale and carbonate units in the De Long Mountains and Sheenjek River terranes. Consequently, tectonic models restoring the entire Coldfoot terrane beneath partly or wholly coeval rocks of the Hammond, Endicott Mountains, De Long Mountains, and Sheenjek River terranes of the Arctic Alaska superterrane require revision. Alternative reconstructions, including restoration of the Coldfoot terrane inboard of the Endicott Mountains terrane or outboard of the De Long Mountains and Sheenjek River terranes are plausible but require either larger amounts of shortening than previously suggested or indicate problematic facies relations.

Journal of Geophysical Research B: Solid Earth↗

Middle Proterozoic age for the Montpelier Anorthosite, Goochland terrane, eastern Piedmont, Virginia

Uranium-lead dating of zircons from the Montpelier Anorthosite confirms previous interpretations, based on equivocal evidence, that the Goochland terrane in the eastern Piedmont of Virginia contains Grenvillian basement rocks of Middle Proterozoic age. A very few prismatic, elongate, euhedral zircons, which contain 12–29 ppm uranium, are interpreted to be igneous in origin. The vast majority of zircons are more equant, subangular to anhedral, contain 38–52 ppm uranium, and are interpreted to be metamorphic in origin. One fraction of elongate zircon, and four fragments of a very large zircon (occurring in a nelsonite segregation) yield an upper intercept age of 1045 ± 10 Ma, interpreted as the time of anorthosite crystallization. Irregularly shaped metamorphic zircons are dated at 1011 ± 2 Ma (weighted average of the 207 Pb/ 206 Pb ages). The U-Pb isotopic systematics of metamorphic titanite were reset during the Alleghanian orogeny at 297 ± 5 Ma. These data provide a minimum age for gneisses of the Goochland terrane that are intruded by the anorthosite. Middle Proterozoic basement rocks of the Goochland terrane may be correlative with those in the Shenandoah massif of the Blue Ridge tectonic province, as suggested by similarities between the Montpelier Anorthosite and the Roseland anorthosite. Although the areal extent of Middle Proterozoic basement and basement-cover relations in the eastern Piedmont remain unresolved, results of this investigation indicate that the Goochland terrane is an internal massif of Laurentian crust rather than an exotic accreted terrane.

Geological Society of America Bulletin↗

Isotopic tracers of gold deposition in Paleozoic limestones, southern Nevada

Strontium isotopic analyses of barren and mineralized Paleozoic carbonate rocks show that hydrothermal fluids added radiogenic strontium (87Sr) to the mineralized zones. At Bare Mountain, samples collected from mineralized areas have ??87Srt values (per mil deviation from primary marine values) ranging from +3.0 to +23.0 (mean of this log-normal distribution is +7.0), whereas unmineralized carbonate rocks have ??87Srt values of -0.6 to +2.9 (mean of +1.07??1.03). In other ranges (Striped Hills, Spring Mountains, and ranges in the vicinity of Indian Springs Valley), ??87Srt values of the unmineralized carbonate rocks are even lower and virtually indistinguishable from primary marine values. This correlation of elevated ??87Srt values with mineralized zones provided a useful technique for assessing the mineral potential of the Paleozoic basement beneath Yucca Mountain, and may find broader use in mineral exploration in the Basin and Range province as a whole.

Conference Paper↗

Devonian volcanogenic massive sulfide deposits and occurrences, southern Yukon-Tanana Terrace, eastern Alaska Range, Alaska

A belt of volcanogenic massive sulfide deposits extends for over 150 km along the southern margin of the Yukon-Tanana terrane of the eastern Alaska Range. Located north of the Denali fault, the Yukon-Tanana terrane forms a major basement unit in east-central Alaska. The volcanogenic massive sulfide deposits are primarily in the Jarvis Creek Glacier subterrane, one of the highest structural-stratigraphic levels of the Yukon-Tanana terrane. The Jarvis Creek Glacier subterrane consists of a volcanogenic massive sulfide-bearing metavolcanic rock member and a metasedimentary rock member. The volcanogenic massive sulfide deposits and enclosing metavolcanic and metasedimentary schists exhibit two periods of regional metamorphism and penetrative deformation: an older, Early Cretaceous, amphibolite facies event and a younger, mid-Cretaceous lower greenschist facies event.From northwest to southeast, the major volcanogenic massive sulfide districts are the Bonnifield, Trident Glacier, and Delta. The Bonnifield district contains massive sulfide deposits in metavolcanic and metasedimentary rocks that are correlated with the Jarvis Creek Glacier subterrane. The 25-km-long, northwest-trending Trident Glacier district contains several occurrences consisting of massive pyrrhotite and lesser pyrite, minor chalcopyrite with or without sphalerite, and galena and arsenopyrite in south-dipping massive sulfide pods, lenses, and stringers that parallel the foliation of the enclosing schists. Host-rock protoliths were mainly andesite, dacite, rhyodacite tuffs and flows, shale, and limestone, with lesser quartz-rich keratophyre flows and tuffs, volcanic graywacke, and siltstone.The Delta district contains at least 35 deposits in an 800-km 2 area. Thirty-one of the deposits define four mineral trends, 5 to 32 km long, that are subparallel to the west-northwest-striking, southwest-dipping structures and lithologies. The deposits consist of layers and zones containing varying amounts of massive to disseminated pyrite and pyrrhotite, and lesser amounts of chalcopyrite, galena, sphalerite, and arsenopyrite. The larger deposits range between 1.0 and 12.4 million metric tons with combined grades of 5.6 percent total metal (Cu, Pb, Zn), and Ag and Au contents of 56 and 1.9 g/metric ton, respectively. Hostrock protoliths are similar to those found in the Trident Glacier district, but some of the deposits are spatially associated with diorite or gabbro sills that exhibit lower greenschist facies metamorphism and deformation.Sulfur isotope values of 26 pyrrhotite separates from the Trident Glacier district occurrences average 7.7 per mil, the mean value of seven pyrite separates is 8.1 per mil. Forty-one Delta district pyrite separates average 5.9 per mil and ranges of values of the four northwest-trending trends overlap. The relative consistency of sulfur isotope values of iron-bearing sulfides in the Trident Glacier district, and the apparent lithologic relationship of isotope values in the Delta district, may reflect original-rock sulfur isotope values. Alternatively, the 34 S-enriched values may have resulted from the addition of reduced seawater sulfate to the hydrothermal fluid. The sulfide accumulations are interpreted as kuroko-like deposits that formed along a Devonian continental margin igneous arc. Deeper level portions of the arc are exposed in structurally lower levels of the Yukon-Tanana terrane to the north and contain metamorphosed granodiorite and granite plutons of Devonian to Mississippian age. U-Pb isotope data from zircons from metavolcanic rocks hosting the sulfide bodies indicate an age of about 370 Ma. The 207 Pb/ 204 Pb ratios for sulfides from the three districts are similar and indicate lead was in part derived from first-cycle sediments that were eroded largely from Precambrian crystalline rocks. The 207 Pb/ 204 Pb ratios from feldspars in Devonian metavolcanic rocks are similar to those in sulfides and indicate incorporation of radiogenic Precambrian lead into the Devonian magmas. A Precambrian crystalline source for detritus in metasedimentary rocks is indicated by locally abundant quartzite containing approximately 2.3 Ga zircons which were derived from the Hudsonian-age block of the Canadian Shield in southern British Columbia.Cretaceous greenschist facies retrogressive metamorphism and intense penetrative deformation is indicated by reequilibration of U-Pb isotope ratios, metamorphic Rb-Sr mineral isochrons, and K-Ar biotite and muscovite ages of 110 to 115 Ma. The data indicate that the mid-Cretaceous retrogressive metamorphism and associated intense deformation occurred during the accretion of the Yukon-Tanana terrane to Alaska.

Economic Geology↗

Lead isotopic evidence for the origin of Paleo- and Mesoproterozoic rocks of the Colorado Province, U.S.A.

Lead isotopic ratios of K-feldspars and whole-rocks from 1.7- and 1.4-Ga plutonic rocks of the Colorado Province are relatively non-radiogenic for 207Pb 204Pb, plotting below the average crust model curve of Stacey and Kramers (1975), indicating that the terrane was derived primarily from juvenile, mantle material. Slightly more radiogenic ratios in the northern part of the terrane, near the Archean Wyoming Province, suggest minor inclusion of an older component. The data from 1.7-Ga plutons plot in a broad field suggesting two episodes of re-equilibration with whole-rock Pb, probably related to heating events in the Mesoproterozoic (1.4 Ga) and Cretaceous (70 Ma). Possible differences in calculated whole-rock Th U, coupled with slight Pb isotopic variations, along the north-south transect suggest either a terrane boundary through central Colorado (near Salida and Gunnison), or fundamental differences in source rocks (metasedimentary vs. metavolcanic). UPb analyses of multigrain splits of detrital zircons from quartzites throughout the Colorado Province have failed to identify Archean detritus. The oldest 207Pb 206Pb ages found (in two samples of quartzite from northern Colorado) are about 2.0 Ga (perhaps derived from rocks of the Trans-Hudson orogen), in contrast to 2.75-Ga detrital zircon in a Paleoproterozoic quartzite from the southern part of the Wyoming Province. While we are not yet able to discern if these ages are true provenance ages or mixtures of Archean and Paleoproterozoic components, the absence of easily recognizable Archean zircons supports other isotopic data and a conclusion that most of the Paleoproterozoic crust of the Colorado Province was ultimately derived from a juvenile (at 1.8 Ga) mantle reservoir. ?? 1993.

Precambrian Research↗

The Mount Evans batholith in the Colorado Front Range: Revision of its age and reinterpretation of its structure

The Mount Evans batholith, in the central Front Range of Colorado, is composed of a main phase of massive to conspicuously foliated monzogranite and granodiorite and undeformed aplite and pegmatite. The Mount Evans batholith was previously considered to be part of the 1.7 Ga Routt Plutonic Suite. New U-Pb zircon ages on four samples (granodiorite, monzogranite, and granite), however, indicate that the batholith was emplaced at 1,442 ± 2 Ma and belongs to the Berthoud Plutonic Suite. Most of the batholith has igneous textures and structures, except in the vicinity of the Idaho Springs-Ralston shear zone where those features are tectonically recrystallized and foliated. Foliation elsewhere in the batholith is a flow structure. Zircons in two granodiorite samples, collected near the shear zone (just south of the Colorado Mineral Belt), are reversely discordant by about 0.8%-2.1%, with a considerable spread in 207 Pb/ 206 Pb ages. Many of the zircons from these samples contain apatite, K-feldspar, and quartz inclusions that appear to replace zircon along cracks and imperfections from rim to core. We suggest that these inclusions formed during a Laramide ore-forming event and incorporated Early and Middle Proterozoic radiogenic lead scavenged from the country rock. The excess radiogenic lead caused the scatter and reverse discordance in the data. The Mount Evans batholith is anomalous in composition and structure compared to most other 1.4 Ga plutons of the southwestern United States. The differences probably reflect different sources of partial melting; the specific tectonic setting where rocks of such disparate origin are temporally and spatially juxtaposed is not understood.

Colorado↗

Do ages of authigenic K-feldspar date the formation of Mississippi valley-type Pb-Zn deposits, central and southeastern United States?: Pb isotopic evidence

Pb concentrations and isotopic compositions have been determined for authigenic over-growths and detrital cores of K-feldspar from Cambrian sedimentary rocks in Texas, Tennessee, and Pennsylvania (referred to as group 1) and southeastern Missouri (referred to as group 2). Overgrowths and cores were separated by abrasion and analyzed separately. In three group 1 samples, cores have Pb isotopic ratios similar to initial ratios in K-feldspar from nearby Middle Proterozoic basement rocks ( 206 Pb/ 204 Pb =16.7-17.0). Pb ratios in overgrowths are radiogenic ( 206 Pb/ 204 Pb up to 19.3) and mostly are distinct from those in ore deposits in the southern Appalachians. Pb isotopic data for two samples of K-feldspar from southeastern Missouri are scattered; in one sample, cores and overgrowths contain radiogenic Pb, suggesting at least two periods of authigenic replacement, in agreement with petrographic evidence. Proterozoic material must still be present because 40 Ar/ 39 Ar stepwise analysis of a total (cores plus overgrowths) sample yields incremental ages ranging from about 500 to 750 Ma. The disparity in Pb isotopic ratios of group 1 overgrowths and Pb in nearby Mississippi Valley-type deposits implies that the regional authigenic K-feldspar event was not synchronous with ore deposition in the southeastern United States. In contrast, Pb isotopic ratios from group 2 authigenic K-feldspar are similar to ratios in ores of southeastern Missouri, suggesting a genetic relation in late Paleozoic time.

Geology↗

Trondhjemitic, 1.35-1.31 Ga gneisses of the Mount Holly Complex of Vermont: evidence for an Elzevirian event in the Grenville Basement of the United States Appalachians

A newly recognized suite of trondhjemite–tonalite and dacitic gneiss forms a 10 km wide belt of rocks within the Mount Holly Complex in the central part of the Green Mountain massif of Vermont. Field relationships and chemistry indicate that these gneisses are calc-alkaline, volcanic, and hypabyssal plutonic rocks older than the Middle Proterozoic regional deformation that affected the Mount Holly Complex. U–Pb zircon dates indicate ages as great as 1.35 Ga for crystallization of the volcanic protoliths and for intrusion of crosscutting trondhjemite. Tonalitic plutonism continued until 1.31 Ga.Map-scale contacts between the trondhjemitic–tonalitic–dacitic gneisses and the paragneiss sequence of the Mount Holly Complex are sharp, suggesting that the volcanic rocks of the trondhjemite–tonalite suite underlie the paragneiss units and do not intrude them. These relationships suggest that the trondhjemite–tonalite suite is either considerably older than, and unconformable beneath, the paragneiss cover rocks or represents a volcanic edifice slightly older than the deposition of the sedimentary precursor to the paragneiss units. The paragneiss and tonalite–trondhjemite gneisses are both intruded by younger granitoids that were intruded at about 1.25 Ga during strong dynamothermal metamorphism.The trondhjemitic gneisses of the Mount Holly Complex of Vermont have high Al 2 O 3 and low Yb contents and light rare-earth element enrichment patterns that are more characteristic of continental than oceanic volcanic arcs. The Mount Holly intrusives and volcanics may have formed during 1.35–1.31 Ga ensialic volcanic-arc activity, contemporaneous with ensimatic arc activity during the early part of the Elzevirian phase of the Grenville orogeny. In Vermont, later deformation and granite intrusion at about 1.25 Ga coincide with the major pulse of the Elzevirian orogeny and associated trondhjemitic plutonism in the Central Metasedimentary Belt of eastern Canada.

Vermont↗

UPb ages of zircon rims: A new analytical method using the air-abrasion technique

We present a new technique for directly dating, by conventional techniques, the rims of zircons. Several circumstances, such as a xenocrystic or inherited component in igneous zircon and metamorphic overgrowths on igneous cores, can result in grains with physically distinct age components. Pneumatic abrasion has been previously shown by Krogh to remove overgrowths and damaged areas of zircon, leaving more resistant and isotopically less disturbed parts available for analysis. A new abrader design, which is capable of very gently grinding only tips and interfacial edges of even needle-like grains, permits easy collection of abraded material for dating. Five examples demonstrate the utility of the “dust-collecting” technique, including two studies that compare conventional, ion microprobe and abrader data. Common Pb may be strongly concentrated in the outermost zones of many zircons and this Pb is not easily removed by leaching (even in weak HF). Thus, the benefit of removing only the outermost zones (and avoiding mixing of age components) is somewhat compromised by the much higher common Pb contents which result in less precise age determinations. A very brief abrasion to remove the high common Pb zones prior to collection of material for dating is selected.

Chemical Geology: Isotope Geoscience Section↗