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E. R. Landa

Publications and source records attributed to E. R. Landa.

At least 19 recordsLinked to original sources
USGS2018

Application of synchrotron methods to assess the uptake of roadway-derived Zn by earthworms in an urban soil

The impact of human activities on biogeochemical cycles in terrestrial environments is nowhere more apparent than in urban landscapes. Trace metals, collected on roadways and transported by storm water, may contaminate soils and sediments associated with storm water management systems. These systems will accumulate metals and associated sediments may reach toxic levels for terrestrial and aquatic organisms using the retention basins as habitat. The fate and bioavailability of these metals once deposited is poorly understood. Here we present results from a dose-response experiment that examines the application of synchrotron X-ray fluorescence methods (μ-SXRF) to test the hypothesis that earthworms will bio-accumulate Zn in a roadway-dust contaminated soil system providing a potential pathway for roadway contaminants into the terrestrial food web, and that the storage and distribution of Zn will change with the level of exposure reflecting the micronutrient status of Zn. Lumbricus friendi was exposed to Zn-bearing roadway dust amended to a field soil at six target concentrations ranging from background levels (45 mg/kg Zn) to highly contaminated levels (460 mg/kg Zn) designed to replicate the observed concentration range in storm-water retention basin soils. After a 30 day exposure, Zn storage in the intestine is positively correlated with dose and there is a change in the pattern of Zn storage within the intestine. This relationship is only clear when μ-SXRF Zn map data is coupled with a traditional toxicological approach, and suggests that the gut concentration in L. friendi is a better indicator of Zn bioaccumulation and storage than the total body burden.

Mineralogical Magazine↗
USGS2018

Physician/chemist/geologist Charles Thomas Jackson's life of conflict and controversy

After a brief medical career, Charles Thomas Jackson (1805–1880) began work as a consulting chemist and geologist in Boston. He served as State Geologist in Maine, Rhode Island, and New Hampshire from 1837 to 1844, and completed geologica l surveys of those States. In 1847, he was appointed United States Geologist to undertake a survey of the public lands of the Lake Superior region of Michigan. This survey was beset by strife, and Jackson was forced to resign in 1849. But he was already embroiled in the even larger “ether controversy,” which pitted Jackson against his former student, Boston dentist William T.G. Morton, each of whom claimed to be the discoverer of ether anaesthesia. The confrontation was prolonged, dramatic, and the focus of a 1944 Hollywood motion picture. In the end, Morton emerged the apparent victor, but the personal toll on both men was severe. Jackson was committed to a Massachusetts insane asylum in 1873 and died there seven years later. Despite a personality that his modern biographers have described as “irritable,” “eccentric,” and “paranoid,” Jackson made significant contributions to the early science of geology in the United States.

Journal of Geological Education↗
USGS2018

Soil science and geology: Connects, disconnects and new opportunities in geoscience education

Despite historical linkages, the fields of geology and soil science have developed along largely divergent paths in the United States during much of the mid- to late- twentieth century. The shift in recent decades within both disciplines to greater emphasis on environmental quality issues and a systems approach has created new opportunities for collaboration and cross-training. Because of the importance of the soil as a dynamic interface between the hydrosphere, biosphere, atmosphere, and lithosphere, introductory and advanced soil science classes are now being taught in a number of earth and environmental science departments. The National Research Council's recent report, Basic Research Opportunities in Earth Science, highlights the soil zone as part of the land surface-to-groundwater "critical zone" requiring additional investigation. To better prepare geology undergraduates to deal with complex environmental problems, their training should include a fundamental understanding of the nature and properties of soils. Those undergraduate geology students with an interest in this area should be encouraged to view soil science as a viable earth science specialty area for graduate study. Summer internships such as those offered by the National Science Foundation-funded Integrative Graduate Education, Research, and Training (IGERT) programs offer geology undergraduates the opportunity to explore research and career opportunities in soil science.

Journal of Geoscience Education↗
USGS2011

Alfred P. Dachnowski and the scientific study of peats

Botanist Alfred Paul Dachnowski (1875–1949) was a major contributor to efforts at mapping organic soils in the United States during the early 20th century. He began his career at The Ohio State University, and spent most of his professional life at the U.S. Department of Agriculture in Washington, DC. His work spanned a diversity of topics, including bog ecology and the ecosystem services provided by wetlands, the mapping and chemical characterization of peat, and the commercial applications of peat. We present a biography and overview of his work. Dachnowski is best known today for the peat sampler that bears his name. The details of its operation are described here, and its place in modern peat studies is discussed.

Soil Survey Horizons↗
USGS2010

Zinc isotopic composition of particulate matter generated during the combustion of coal and coal + tire-derived fuels

Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ(66)Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ(66)Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, -0.48‰ for coal and -0.81‰ for coal+TDF. The δ(66)Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ(66)Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process.

Environmental Science & Technology↗
USGS2009

Impacts of weathered tire debris on the development of Rana sylvatica larvae

Highway runoff has the potential to negatively impact receiving systems including stormwater retention ponds where highway particulate matter can accumulate following runoff events. Tire wear particles, which contain about 1% Zn by mass, make up approximately one-third of the vehicle derived particulates in highway runoff and therefore may serve as a stressor to organisms utilizing retention ponds as habitat. In this study, we focused on the potential contribution of tire debris to Zn accumulation by Rana sylvatica larvae and possible lethal or sublethal impacts resulting from exposure to weathered tire debris during development. Eggs and larvae were exposed to aged sediments (containing either ZnCl 2 or tire particulate matter, both providing nominal concentrations of 1000 mg Zn kg −1 ) through metamorphosis. Water column Zn was elevated in both the ZnCl 2 and tire treatments relative to the control treatment, indicating that aging allowed Zn leaching from tire debris to occur. Tissue Zn was also elevated for the ZnCl 2 and tire treatments indicating that Zn in the treatments was available for uptake by the amphibians. Exposure to both ZnCl 2 and tire treatments increased the time for larvae to complete metamorphosis in comparison with controls. We also observed that the longer the organisms took to complete metamorphosis, the smaller their mass at metamorphosis. Our results indicate that Zn leached from aged tire debris is bioavailable to developing R. sylvatica larvae and that exposure to tire debris amended sediments can result in measurable physiological outcomes to wood frogs that may influence population dynamics.

Chemosphere↗
USGS2009

Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine

Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c 11 to m 3 Carboniferous coals, mercury contents range from 0.02 to 3.5 ppm (whole-coal dry basis). Mercury is well correlated with pyritic sulfur (0.01 to 3.2 wt.%), with an r 2 of 0.614 (one outlier excluded). Sulfides in these samples show enrichment of minor constituents in late-stage pyrite formed as a result of interaction of coal with hydrothermal fluids. Mine water sampled at depth and at surface collection points does not show enrichment of trace metals at harmful levels, indicating pyrite stability at subsurface conditions. Four samples of coal exposed in the defunct open-cast Nikitovka mercury mines in Gorlovka have extreme mercury contents of 12.8 to 25.5 ppm. This coal was formerly produced as a byproduct of extracting sandstone-hosted cinnabar ore. Access to these workings is unrestricted and small amounts of extreme mercury-rich coal are collected for domestic use, posing a limited human health hazard. More widespread hazards are posed by the abandoned Nikitovka mercury processing plant, the extensive mercury mine tailings, and mercury enrichment of soils extending into residential areas of Gorlovka.

Donbas mines↗
USGS2008

Cardiopulmonary responses of intratracheally instilled tire particles and constituent metal components

Tire and brake wear particles contain transition metals, and contribute to near-road PM. We hypothesized that acute cardiopulmonary injury from respirable tire particles (TP) will depend on the amount of soluble metals. Respirable fractions of two types of TP (TP1 and TP2) were analyzed for water and acid-leachable metals using ICP-AES. Both TP types contained a variety of transition metals, including zinc (Zn), copper (Cu), aluminum, and iron. Zn and Cu were detected at high levels in water-soluble fractions (TP2 > TP1). Male Wistar Kyoto rats (12–14 wk) were intratracheally instilled, in the first study, with saline, TP1 or TP2 (5 mg/kg), and in the second study, with soluble Zn, Cu (0.5 μ mol/kg), or both. Pulmonary toxicity and cardiac mitochondrial enzymes were analyzed 1 d, 1 wk, or 4 wk later for TP and 4 or 24 h later for metals. Increases in lavage fluid markers of inflammation and injury were observed at d 1 (TP2 > TP1), but these changes reversed by wk 1. No effects on cardiac enzymes were noted with either TP. Exposure of rats to soluble Zn and Cu caused marked pulmonary inflammation and injury but temporal differences were apparent (Cu effects peaked at 4 h and Zn at 24 h). Instillation of Zn, Cu, and Zn+ Cu decreased the activity of cardiac aconitase, isocitrate dehydrogenase, succinate dehydrogenase, cytochrome-c-oxidase and superoxide dismutase suggesting mitochondrial oxidative stress. The observed acute pulmonary toxicity of TP could be due to the presence of water soluble Zn and Cu. At high concentrations these metals may induce cardiac oxidative stress.

Inhalation Toxicology↗
USGS2006

Role of microbial iron reduction in the dissolution of iron hydroxysulfate minerals

Iron-hydroxysulfate minerals can be important hosts for metals such as lead, mercury, copper, zinc, silver, chromium, arsenic, and selenium and for radionuclides such as 226Ra. These mineral-bound contaminants are considered immobilized under oxic conditions. However, when anoxic conditions develop, the activities of sulfate- or iron-reducing bacteria could result in mineral dissolution, releasing these bound contaminants. Reduction of structural sulfate in the iron-hydroxysulfate mineral jarosite by sulfate-reducing bacteria has previously been demonstrated. The primary objective of this work was to evaluate the potential for anaerobic dissolution of the iron-hydroxysulfate minerals jarosite and schwertmannite at neutral PH by iron-reducing bacteria. Mineral dissolution was tested using a long-term cultivar, Geobacter metallireducens strain GS-15, and a fresh isolate Geobacter sp. strain ENN1, previously undescribed. ENN1 was isolated from the discharge site of Shadle Mine, in the southern anthracite coalfield of Pennsylvania, where schwertmannite was the predominant iron-hydroxysulfate mineral. When jarosite from Elizabeth Mine (Vermont) was provided as the sole terminal electron acceptor, resting cells of both G. metallireducens and ENN1 were able to reduce structural Fe(III), releasing Fe+2, SO4-2, and K+ ions. A lithified jarosite sample from Utah was more resistant to microbial attack, but slow release of Fe+2 was observed. Neither bacterium released Fe+2 from poorly crystalline synthetic schwertmannite. Our results indicate that exposure of jarosite to iron-reducing conditions at neutral pH is likely to promote the mobility of hazardous constituents and should therefore be considered in evaluating waste disposal and/or reclamation options involving jarosite-bearing materials.

Journal of Geophysical Research G: Biogeosciences↗
USGS2006

From agricultural geology to hydropedology: Forging links within the twenty-first-century geoscience community

Despite historical linkages, the fields of geology and soil science have developed along largely divergent paths in the United States during much of the mid- to late-twentieth century. The shift in recent decades within both disciplines, towards greater emphasis on environmental-quality issues and a systems approach, has created new opportunities for collaboration and cross-training. Because of the importance of the soil as a dynamic interface between the hydrosphere, biosphere, atmosphere and lithosphere, introductory and advanced soil-science classes are now taught in a number of Earth and environmental science departments. The National Research Council's recent report, Basic Research Opportunities in Earth Science, highlights the soil zone as part of the land surface to groundwater 'critical zone' requiring additional investigation. To better prepare geology undergraduates to deal with complex environmental problems, their training should include a fundamental understanding of the nature and properties of soils. Those undergraduate geology students with an interest in this area should be encouraged to view soil science as a viable Earth-science specialty area for graduate study. ?? The Geological Society of London 2006.

Geological Society Special Publication↗
USGS2005

The soil physics contributions of Edgar Buckingham

During 1902 to 1906 as a soil physicist at the USDA Bureau of Soils (BOS), Edgar Buckingham originated the concepts of matric potential, soil–water retention curves, specific water capacity, and unsaturated hydraulic conductivity ( K ) as a distinct property of a soil. He applied a formula equivalent to Darcy's law (though without specific mention of Darcy's work) to unsaturated flow. He also contributed significant research on quasi-empirical formulas for K as a function of water content, water flow in capillary crevices and in thin films, and scaling. Buckingham's work on gas flow in soils produced paradigms that are consistent with our current understanding. His work on evaporation elucidated the concept of self-mulching and produced sound and sometimes paradoxical generalizations concerning conditions that favor or retard evaporation. Largely overshadowing those achievements, however, is that he launched a theory, still accepted today, that could predict transient water content as a function of time and space. Recently discovered documents reveal some of the arguments Buckingham had with BOS officials, including the text of a two-paragraph conclusion of his famous 1907 report on soil water, and the official letter documenting rejection of that text. Strained interpersonal relations motivated the departure of Buckingham and other brilliant physicists (N.E. Dorsey, F.H. King, and Lyman Briggs) from the BOS during 1903 to 1906. Given that Buckingham and his BOS colleagues had been rapidly developing the means of quantifying unsaturated flow, these strained relations probably slowed the advancement of unsaturated flow theory.

Soil Science Society of America Journal↗
USGS2004

Tire-wear particles as a source of zinc to the environment

Tire-tread material has a zinc (Zn) content of about 1 wt %. The quantity of tread material lost to road surfaces by abrasion has not been well characterized. Two approaches were used to assess the magnitude of this nonpoint source of Zn in the U.S. for the period 1936−1999. In the first approach, tread-wear rates from the automotive engineering literature were used in conjunction with vehicle distance-driven data from the U.S. Department of Transportation to determine Zn releases. A second approach calculated this source term from the volume of tread lost during lifetime tire wear. These analyses showed that the quantity of Zn released by tire wear in the mid-1990s was of the same magnitude as that released from waste incineration. For 1999, the quantity of Zn released by tire wear in the U.S. is estimated to be 10 000−11 000 metric tons. A specific case study focused on Zn sources and sinks in an urban−suburban watershed (Lake Anne) in the Washington, DC, metropolitan area for a time period of the late 1990s. The atmospheric flux of total Zn (wet deposition) to the watershed was 2 μg/cm 2 /yr. The flux of Zn to the watershed estimated from tire wear was 42 μg/cm 2 /yr. The measured accumulation rate of total Zn in age-dated sediment cores from Lake Anne was 27 μg/cm 2 /yr. These data suggest that tire-wear Zn inputs to urban−suburban watersheds can be significantly greater than atmospheric inputs, although the watershed appears to retain appreciable quantities of vehicular Zn inputs.

Environmental Science & Technology↗
USGS2004

Sorption of 99m Tc radiopharmaceutical compounds by soils

Study of the sorption of 99mTc radiopharmaceutical compounds by soils has assessed the fate of these compounds in the event of a surface spill and examined the potential of these compounds as hydrologic tracers. Sorption from deionized water, filtered Missouri River water, and artificial seawater by five surface soils was investigated. For all water types, the Tc radiopharmaceutical compounds showed greater sorption than the uncomplexed pertechnetate. The most lipophilic complexes showed the highest sorption on soils.

Health Physics↗
USGS2004

Albert H. Munsell: A sense of color at the interface of art and science

The color theory conceived and commercialized by Albert H. Munsell (1858-1918) has become a universal part of the lexicon of soil science. An American painter noted for his seascapes and portraits, he had a long-standing interest in the description of color. Munsell began studies aimed at standardizing color description, using hue, value, and chroma scales, around 1898. His landmark treatise, "A Color Notation," was published in 1905. Munsell died about 30 years before his color charts came into wide-spread use in soil survey programs in the United States. Dorothy Nickerson, who began her career as secretary and laboratory assistant to Munsell's son, and later spent 37 years at USDA as a color-science specialist, did much to adapt the Munsell Color System to soil-color usage. The legacy of color research pioneered by A.H. Munsell is honored today by the Munsell Color Science Laboratory established in 1983 at the Rochester Institute of Technology.

Soil Science↗
USGS2003

Mobilization of radionuclides from uranium mill tailings and related waste materials in anaerobic environments

Specific extraction studies in our laboratory have shown that iron and manganese oxide- and alkaline earth sulfate minerals are important hosts of radium in uranium mill tailings. Iron- and sulfate-reducing bacteria may enhance the release of radium (and its analog barium) from uranium mill tailings, oil field pipe scale [a major technologically enhanced naturally occurring radioactive material (TENORM) waste], and jarosite (a common mineral in sulfuric acid processed-tailings). These research findings are reviewed and discussed in the context of nuclear waste forms (such as barium sulfate matrices), radioactive waste management practices, and geochemical environments in the Earth's surficial and shallow subsurface regions.

Journal of Radioanalytical and Nuclear Chemistry↗
USGS2001

Sulfate-reducing bacteria release barium and radium from naturally occurring radioactive material in oil-field barite

Scale and sludge deposits formed during oil production can contain elevated levels of Ra, often coprecipitated with barium sulfate (barite). The potential for sulfate-reducing bacteria to release 226 Ra and Ba (a Ra analog) from oil-field barite was evaluated. The concentration of dissolved Ba increased when samples containing pipe scale, tank sludge, or oil-field brine pond sediment were incubated with sulfate-reducing bacteria Desulfovibrio sp., Str LZKI, isolated from an oil-field brine pond. However, Ba release was not stoichiometric with sulfide production in oil-field samples, and <0.1% of the Ba was released. Potential for the release of 226Ra was demonstrated, and the 226 Ra release associated with sulfate-reducing activity was predictable from the amount of Ba released. As with Ba, only a fraction of the 226Ra expected from the amount of sulfide produced was released, and most of the Ra remained associated with the solid material.

Geomicrobiology Journal↗
USGS2000

Geochemical investigations by the U.S. Geological Survey on uranium mining, milling, and environmental restoration

Recent research by the U.S. Geological Survey has characterized contaminant sources and identified important geochemical processes that influence transport of radionuclides from uranium mining and milling wastes. 1) Selective extraction studies indicated that alkaline earth sulfates and hydrous ferric oxides are important hosts of 226 Ra in uranium mill tailings. The action of sulfate-reducing and ironreducing bacteria on these phases was shown to enhance release of radium, and this adverse result may temper decisions to dispose of uranium mill tailings in anaerobic environments. 2) Field studies have shown that although surface-applied sewage sludge/wood chip amendments aid in revegetating pyritic spoil, the nitrogen in sludge leachate can enhance pyrite oxidation, acidification of groundwater, and the consequent mobilization of metals and radionuclides. 3) In a U.S. Environmental Protection Agencyfunded study, three permeable reactive barriers consisting of phosphate-rich material, zero-valent iron, or amorphous ferric oxyhydroxide have been installed at an abandoned uranium upgrader facility near Fry Canyon, UT. Preliminary results indicate that each of the permeable reactive barriers is removing the majority of the uranium from the groundwater. 4) Studies on the geochemistry of rare earth elements as analogues for actinides such as uranium and thorium in acid mine drainage environments indicate high mobility under acid-weathering conditions but measurable attenuation associated with iron and aluminum colloid formation. Mass balances from field and laboratory studies are being used to quantify the amount of attenuation. 5) A field study in Colorado demonstrated the use of 234 U/ 238 U isotopic ratio measurements to evaluate contamination of shallow groundwater with uranium mill effluent.

Utah↗