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D.A. Vroblesky

Publications and source records attributed to D.A. Vroblesky.

30 records · Page 2Linked to original sources
USGS1997

Transport and transformations of chlorinated-solvent contamination in a saprolite and fractured rock aquifer near a former wastewater-treatment plant, Greenville, South Carolina

The transport and fate of chlorinated-ethene contamination was investigated in a fractured-rock aquifer downgradient from a wastewater-treatment plant at a gas-turbine manufacturing facility in Greenville, South Carolina. A vapor-diffusion-sampler technique, developed for this investigation, located fracture zones that discharged contaminated ground water to surface water. The distribution of chlorinated compounds and sulfate, comparison of borehole geophysical data, driller's logs, and the aquifer response to pumpage allowed subsurface contaminant-transport pathways to be delineated.The probable contaminant-transport pathway from the former aeration lagoon was southward. The probable pathway of contaminant transport from the former sludge lagoon was southward to and beneath Little Rocky Creek. South of the creek, the major pathway of contaminant transport appeared to be at a depth of approximately 80 to 107 feet below land surface. The contaminant-transport pathway from the former industrial lagoon was not readily discernible from existing data. A laboratory investigation, as well as examination of ground- water-chemistry data collected during this investigation and concentrations of chlorinated compounds collected during previous investigations,indicates that higher chlorinated compounds are being degraded to lower-chlorinated compounds in the contaminated aquifer. The approaches used in this investigation, as well as the findings, have potential application to other fractured-rock aquifers contaminated by chlorinated ethenes.

South Carolina↗
USGS1996

Influence of electron donor on the minimum sulfate concentration required for sulfate reduction in a petroleum hydrocarbon-contaminated aquifer

Fluctuations in the availability of electron donor (petroleum hydrocarbons) affected the competition between sulfate-reducing bacteria (SRB) and methanogenic bacteria (MB) for control of electron flow in a petroleum hydrocarbon-contaminated aquifer. The data suggest that abundant electron donor availability allowed MB to sequester a portion of the electron flow even when sulfate was present in sufficient concentrations to support sulfate reduction. For example, in an area of abundant electron-donor availability, SRB appeared to be unable to sequester the electron flow from MB in the presence of 1.4 mg/L sulfate. The data also suggest that when electron-donor availability was limited, SRB outcompeted MB for available substrate at a lower concentration of sulfate than when electron donor was plentiful. For example, in an area of limited electron-donor availability, SRB appeared to maintain dominance of electron flow at sulfate concentrations less than 1 mg/L. The presence of abundant electron donor and a limited amount of sulfate reduced competition for available substrate, allowing both SRB and MB to metabolize available substrates concurrently.

Environmental Science & Technology↗
USGS1996

Simulation of ground-water flow of the coastal plain aquifers in parts of Maryland, Delaware, and the District of Columbia

Geomorphic processes and the aquatic habitat of the Redwood Creek basin were studied extensively between 1973 and 1983. This volume contains 22 separate articles by 32 investigators who studied geology, major storms, timber harvesting and its role on accelerating erosion, mass movement, fluvial erosion, sediment transport and storage, stream channel response to storms and landuse, stream habitat, and stream chemistry. This research describes a rapidly eroding landscape that is sensitive to effects of both landuse and major storms.

Delaware, District of Columbia, Maryland↗
USGS1994

Hydrogeologic framework and simulation of shallow ground-water flow in the vicinity of a hazardous-waste landfill near Pinewood, South Carolina

The geologic units in the vicinity of a hazardous- waste landfill near Pinewood, S.C., were divided into hydrogeologic units on the basis of lithologic and hydrologic characteristics. A quasi-3- dimensional finite-difference ground-water-flow model was constructed to represent the hydrogeologic flamework. The simulation results indicate that if non-reactive constituents were released to the Lang Syne water-bearing zone underlying the central and western pans of the disposal area, the constituents would move in a southwesterly direction at a rate of about one-half to 7 feet per year. Contaminants could move from the Lang Syne water-bearing zone upward to the surficial aquifer, to streams, or to Lake Marion. Although these flow rates indicate that it would require at least 50 years for contaminants to travel between the disposal area and a nearby (400 ft) potential discharge area, the heterogeneity of the site hydrogeology imparts an uncertainty to the conclusion. Faster travel times cannot be ruled out if contamination enters an area having a higher hydraulic conductivity than those determined in this investigation. Faster arrival times at Lake Marion also could result if there are pathways shorter than about 400 feet between contaminated water and an area where it can discharge to the surficial aquifer or to streams. If contaminant releases were to occur on the eastern side of the ground-water mounds, near landfill section II and the southeastern part of land fill section I, initial flow directions would be toward the water-level depression in the eastern part of the facility. Ground water within water- level depression would flow downward, probably to the underlying lower Sawdust Landing water-beating zone. Movement of non-reactive constituents in the tower Sawdust Landing water-bearing zone would be southwestward toward Lake Marion at a rate of about 8 to 20 feet per year. Transport to the lake by this route could require more than 200 years.

South Carolina↗
USGS1993

Does lead affect microbial metabolism in aquifer sediments under different terminal electron accepting conditions?

High concentrations of aliphatic organic acids (∼1 mM acetate) in groundwater from a petroleum hydrocarbon‐contaminated aquifer are associated with elevated concentrations (∼30 μg/L) of lead. This pattern suggests that toxic effects of lead have contributed to the observed accumulation of organic acids. This hypothesis was tested by examining the effects of lead on carbon mineralization and organic acid accumulation in petroleum‐contaminated aquifer material incubated under different terminal electron‐accepting conditions. Lead was found to inhibit fermentation (organic acid accumulation) as well as microbial carbon mineralization (CO 2 or CH 4 production) under aerobic, nitrate‐reducing, sulfate‐reducing, and methanogenic conditions. Thus Pb does not appear to be the primary cause of organic acid accumulation at the field site. Rather, substantial accumulation of aliphatic organic acids occurred only in methanogenic microcosms, and only trace amounts of acetic acid were detected in sulfate‐reducing microcosms. This pattern parallels field observations in which high organic acid concentrations were detected in methanogenic zones, but only low concentrations of acetic acid were detected in sulfate‐reducing zones.

Geomicrobiology Journal↗
USGS1993

Distribution of volatile organic compounds in soil vapor in the vicinity of a defense fuel supply point, Hanahan, South Carolina

Two passive soil-vapor sampling techniques were used in the vicinity of a defense fuel supply point in Hanahan, South Carolina, to identify areas of potential contamination of the shallow water table aquifer by volatile organic compounds (VOC's). Both techniques involved the burial of samplers in the vadose zone and the saturated bottom sediments of nearby streams. One method, the empty-tube technique, allowed vapors to pass through a permeable membrane and accumulate inside an inverted empty test tube. A sample was extracted and analyzed on site by using a portable gas chromatograph. As a comparison to this method, an activated-carbon technique, also was used in certain areas. This method uses a vapor collector consisting of a test tube containing activated carbon as a sorbent for VOC's.

Water-Resources Investigations Report↗
USGS1992

Increased concentrations of potassium in heartwood of trees in response to groundwater contamination

The wood of tuliptrees (Liriodendron tulipifera L.) growing above groundwater contamination from a hazardous-waste landfill in Maryland contained elevated concentrations of potassium (K). The groundwater contamination also contained elevated concentrations of dissolved K, as well as arsenic (As), cadmium (Cd), chloride (Cl), iron (Fe), manganese (Mn), zinc (Zn), and organic solvents. The dissolved K is derived from disposed smoke munitions. The excess K in the tuliptrees is concentrated in the heartwood, the part of the xylem most depleted in K in trees growing outside of the contamination. These data show that the uptake and translocation of K by tuliptrees can be strongly influenced by the availability of K in groundwater contamination and suggest the utility of this species as an areal indicator of groundwater contamination. ?? 1992 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences↗
USGS1989

Hydrogeologic and chemical data for the O-Field area, Aberdeen Proving Ground, Maryland

O-Field, located at the Edgewood area of Aberdeen Proving Ground , Maryland, was periodically used for disposal of munitions, waste chemicals, and chemical-warfare agents from World War II through the 1950' s. This report includes various physical, geologic, chemical, and hydrologic data obtained from well-core, groundwater, surface water, and bottom-sediment sampling sites at and near the O-Field disposal area. The data are presented in tables and hydrographs. Three site-location maps are also included. Well-core data include lithologic logs for 11 well- cluster sites, grain-size distributions, various chemical characteristics, and confining unit characteristics. Groundwater data include groundwater chemistry, method blanks for volatile organic carbon, available data on volatile and base/neutral organics, and compilation of corresponding method blanks, chemical-warfare agents, explosive-related products, radionuclides, herbicides, and groundwater levels. Surface-water data include field-measured characteristics; concentrations of various inorganic constituents including arsenic; selected organic constituents with method blanks; detection limits of organics; and a compilation of information on corresponding acids, volatiles, and semivolatiles. Bottom- sediment data include inorganic properties and constituents; organic chemistry; detection limits for organic chemicals; a compilation of information on acids, volatiles, and semivolatiles; and method blanks corresponding to acids, volatiles, and semivolatiles. A set of 15 water- level hydrographs for the period March 1986 through September 1987 also is included in the report. (USGS)

Open-File Report↗
USGS1989

Hydrogeology of the Canal Creek area, Aberdeen Proving Ground, Maryland

Geologic and borehole geophysical logs made at 77 sites show that the hydrogeologic framework of the study area consists of a sequence of unconsolidated sediments typical of the Coastal Plain of Maryland. Three aquifers and two confining units were delineated within the study area. From the surface down, they are: (1) the surficial aquifer; (2) the upper confining unit; (3) the Canal Creek aquifer; (4) the lower confining unit; and (5) the lower confined aquifer. The aquifer materials range from fine sand to coarse sand and gravel. Clay lenses were commonly found interfingered with the sand, isolating parts of the aquifers. All the units are continuous throughout the study area except for the upper confining unit, which crops out within the study area but is absent in updip outcrops. The unit also is absent within a Pleistocene paleochannel, where it has been eroded. The surficial and Canal Creek aquifers are hydraulically connected where the upper confining unit is absent, and a substantial amount of groundwater may flow between the two aquifers. Currently, no pumping stresses are known to affect the aquifers within the study area. Under current conditions, downward vertical hydraulic gradients prevail at topographic highs, and upward gradients typically prevail near surface-water bodies. Regionally, the direction of groundwater flow in the confined aquifers is to the east and southeast. Significant water level fluctuations correspond with seasonal variations in rainfall, and minor daily fluctuations reflect tidal cycles. (USGS)

Water-Resources Investigations Report↗
USGS1989

Inorganic and organic ground-water chemistry in the Canal Creek area of Aberdeen Proving Ground, Maryland

Groundwater chemical data were collected from November 1986 through April 1987 in the first phase of a 5-year study to assess the possibility of groundwater contamination in the Canal Creek area of Aberdeen Proving Ground, Maryland. Water samples were collected from 87 observation wells screened in Coastal Plain sediments; 59 samples were collected from the Canal Creek aquifer, 18 from the overlying surficial aquifer, and 10 from the lower confined aquifer. Dissolved solids, chloride, iron, manganese, fluoride, mercury, and chromium are present in concentrations that exceed the Federal maximum contaminant levels for drinking water. Elevated chloride and dissolved-solids concentrations appear to be related from contaminant plumes but also could result from brackish-water intrusion. Excessive concentrations of iron and manganese were the most extensive water quality problems found among the inorganic constituents and are derived from natural dissolution of minerals and oxide coatings in the aquifer sediments. Volatile organic compounds are present in the Canal Creek and surficial aquifers, but samples from the lower confined aquifer do not show any evidence of contamination by inorganic or organic chemicals. The volatile organic contaminants detected in the groundwater and their maximum concentrations (in micrograms/L) include 1,1,2,2- tetrachloroethane (9,000); carbon tetrachloride (480); chloroform (460); 1,1,2-trichloroethane (80); 1,2-dichloroethane (990); 1,1-dichloroethane (3.1); tetrachloroethylene (100); trichloroethylene (1,800); 1,2-trans- dichloroethylene (1,200); 1,1-dichloroethylene (4.4); vinyl chloride (140); benzene (70); and chlorobenzene (39). On the basis of information on past activities in the study area, some sources of the volatile organic compounds include: (1) decontaminants and degreasers; (2) clothing-impregnating operations; (3) the manufacture of impregnite material; (4) the manufacture of tear gas; and (5) fuels used in garages and at the air-field. The high density of most of the detected organic compounds in free-product form would have aided their movement into the aquifers by vertical sinking. The outcrop area of the upper confining unit and an area cut by a paleochannel are most susceptible to contamination because a near-surface impermeable layer is not present. (USGS)

Water-Resources Investigations Report↗