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Breton W. Bruce

Publications and source records attributed to Breton W. Bruce.

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Continuing progress toward a national assessment of water availability and use

Executive Summary The Omnibus Public Land Management Act of 2009 (Public Law 111—11) was passed into law on March 30, 2009. Subtitle F, also known as the SECURE Water Act, calls for the establishment of a “national water availability and use assessment program” within the U.S. Geological Survey (USGS). The USGS issued the first report on the program in 2013. Program progress over the period 2013–17 is reported herein to fulfill the requirement to inform Congress on implementation of the national water availability and use assessment program, also referred to as the USGS National Water Census (the Water Census). Much work has been accomplished during 2013–17 on producing water budgets for the nation, a goal USGS outlined in its first report on program progress to Congress. The USGS has completed three geographic focus area studies and has begun three others. Work has advanced on nationwide efforts in streamflow analysis, groundwater assessment and research, evapotranspiration studies, water use, environmental water science, and drought science. The USGS works with Federal and non-Federal agencies, universities, and other organizations to ensure that the information can be aggregated with other types of water-availability and socioeconomic information, such as data on food and energy production. The USGS has also made great strides in measures for delivering data and information on the Water Census to stakeholders and the public. Much work remains to be accomplished for the Nation to have a comprehensive, ongoing Water Census. In this report, the USGS lays out activities to be accomplished in the next 5 years (2017–22), based upon current funding levels. These include selecting new focus area studies, conducting hydrologic modeling to complete water budgets for the conterminous United States, expanding groundwater modeling efforts, mapping a national classification system for environmental water science, and developing an inventory of interbasin water transfers. All of these steps are necessary in order for the Water Census to achieve the goals outlined by Congress in the SECURE Water Act.

Circular

U.S. Geological Survey National Water Census: Colorado River Basin Geographic Focus Area Study

Introduction The U.S. Geological Survey’s (USGS) concept of a national census (or accounting) of water resources has evolved over the last several decades as the Nation has experienced increasing concern over water availability for multiple competing uses. The implementation of a USGS National Water Census was described in the USGS 2007 science strategy document that identified the highest priority science topics for the decade 2007–17. In 2009, the SECURE Water Act (Public Law 111–11, subtitle F) authorized the USGS to create a Water Availability and Use Assess­ment Program for the Nation, and in 2012, the Department of the Interior WaterSMART initiative provided funding to begin implementation of the USGS National Water Census (NWC). Generally, the USGS NWC approaches water-availability assessment in terms of a “water budget.” The water-budget approach seeks to better quantify the inflows and outflows of water, as well as the change in storage volume, both nationally and at a regional scale and, by doing so, provides critical information to managers and stakeholders responsible for making water-availability decisions. The NWC has two primary components: Topical Studies and Geographic Focus Area Studies. Topical Studies do research on methods that can provide nationwide estimates of particular water-budget components at the subwatershed scale. Some examples of NWC Topical Studies include estimation of streamflow at ungaged locations; periodic quantification of evapotranspiration; and water use related to development of unconventional oil and gas. These efforts are planned to include additional topics in the future. Geographic Focus Area Studies (FASs) assess water availability and use within a defined geographic area, typically a surface-water drainage basin, to increase the understanding of factors affecting water availability in the region. In the FASs, local stakeholder input helps the USGS identify what components of the water budget are in most need of additional understanding or quantification. Focus Area Studies are planned as 3-year efforts and, typically, three FASs are ongoing in different parts of the country at any given time. The Colorado River Basin (CRB) and the Delaware and Apalachicola-Chattahoochee-Flint (ACF) River Basins were selected by the Department of the Interior for the first round of FASs because of the perceived water shortages in the basins and potential conflicts over water supply and allocations. After gathering input from numerous stakeholders in the CRB, the USGS determined that surface­-water resources in the basin were already being closely monitored and that the most important scientific contribution could be made by helping to improve estimates of four water­-budget components: evapotranspiration losses, snowpack hydrodynamics, water­-use information, and the relative importance of groundwater discharge in supporting streamflow across the basin. The purpose of this fact sheet is to provide a brief summary of the CRB FAS results as the study nears completion. Although some project results are still in the later stages of review and publication, this fact sheet provides an overall description of the work completed and cites the publications in which additional information can be found.

Arizona, California, Colorado, Nevada, New Mexico,

Progress toward establishing a national assessment of water availability and use

The Omnibus Public Land Management Act of 2009 (Public Law 111-11) was passed into law on March 30, 2009. Subtitle F, also known as the SECURE Water Act, calls for the establishment of a "national water availability and use assessment program" within the U.S. Geological Survey (USGS). A major driver for this recommendation was that national water availability and use have not been comprehensively assessed since 1978. This report fulfills a requirement to report to Congress on progress in implementing the national water availability and use assessment program, also referred to as the National Water Census. The SECURE Water Act authorized \$20 million for each of fiscal years (FY) 2009 through 2023 for assessment of national water availability and use. The first appropriation for this effort was \$4 million in FY 2011, followed by an appropriation of \$6 million in FY 2012. The National Water Census synthesizes and reports information at the regional and national scales, with an emphasis on compiling and reporting the information in a way that is useful to states and others responsible for water management and natural-resource issues. The USGS works with Federal and non-Federal agencies, universities, and other organizations to ensure that the information can be aggregated with other types of water-availability and socioeconomic information, such as data on food and energy production. To maximize the utility of the information, the USGS coordinates the design and development of the effort through the Federal Advisory Committee on Water Information. A National Water Census is a complex undertaking, particularly because there are major gaps in the information needed to conduct such an assessment. To maximize progress, the USGS engaged stakeholders in a discussion of priorities and leveraged existing studies and program activities to enhance efforts toward the development of a National Water Census.

Circular

WaterSMART-The Colorado River Basin focus-area study

Increasing demand for the limited water resources of the United States continues to put pressure on water-resource agencies to balance the competing needs of ecosystem health with municipal, agricultural, and recreational uses. In 2007, the U.S. Geological Survey (USGS) identified a National Water Census as one of six pivotal future science directions for the USGS in the following decade. The envisioned USGS National Water Census would evaluate large-scale effects of changes in land use and land cover, water use, and climate on water availability, water quality, and human and aquatic ecosystem health. The passage of the SECURE (Science and Engineering to Comprehensively Understand and Responsibly Enhance) Water Act in 2009 was a key step towards implementing the USGS National Water Census. Section 9508 of the Act authorizes a "national water availability and use assessment program" within the USGS (1) to provide a more accurate assessment of the status of the water resources of the United States; and (2) to develop the science for improved forecasts of the availability of water for future economic, energy production, and environmental uses. Initial funding for the USGS to begin working on the National Water Census came with the approval of the U.S. Department of the Interior's WaterSMART (Sustain and Manage America's Resources for Tomorrow) Initiative. The WaterSMART Initiative provides funding to the USGS, Bureau of Reclamation, and U.S. Department of Energy to achieve a sustainable water strategy to meet the Nation's water needs. WaterSMART funding also allowed the USGS to begin the national Water Availability and Use Assessment, as called for under the SECURE Water Act.

Arizona;Colorado;New Mexico;Utah

Water-Quality Assessment of the High Plains Aquifer, 1999-2004

Water quality of the High Plains aquifer was assessed for the period 1999-2004 as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. This effort represents the first systematic regional assessment of water quality in this nationally important aquifer. A stratified, nested group of studies was designed to assess linkages between the quality of water recharging the aquifer, the effect of transport through the hydrologic system on water quality, and the quality of the resource used for human consumption and agricultural applications. The stratified, nested design facilitated upscaling of monitoring results to unmonitored areas of the aquifer as well as upscaling of process understanding from local to regional scales.

Professional Paper

Use of electric logs to estimate water quality of pre-tertiary aquifers

Electric logs provide a means of estimating ground-water quality in areas where water analyses are not available. Most of the methods for interpreting these logs have been developed for the petroleum industry and are most reliable in saline aquifers (concentration of dissolved solids as sodium chloride greater than about 50,000 mg/l). The resistivity-porosity and spontaneous-potential methods were evaluated to determine if they could be applied to identify zones of fresh water (concentration of dissolved solids as sodium chloride less than 1,000 mg/l) in three potential aquifers in central Wyoming. The potential aquifers have different lithologies–sandstone, clayey sandstone, and carbonate. The two methods generally were reliable predictors of water quality in the sandstone and carbonate potential aquifers. In the clayey sandstone potential aquifer, predictions of the dissolved-solids concentration using the two methods differed by more than an order of magnitude in several cases. When the resistivity values are corrected for the presence of clay and shale as identified on a natural gamma log, the agreement between the results of the two methods improved by an average of 58 percent.

Groundwater

Ground-water quality beneath irrigated agriculture in the central High Plains aquifer, 1999-2000

In 1999 and 2000, 30 water-quality monitoring wells were installed in the central High Plains aquifer to evaluate the quality of recently recharged ground water in areas of irrigated agriculture and to identify the factors affecting ground-water quality. Wells were installed adjacent to irrigated agricultural fields with 10- or 20-foot screened intervals placed near the water table. Each well was sampled once for about 100 waterquality constituents associated with agricultural practices. Water samples from 70 percent of the wells (21 of 30 sites) contained nitrate concentrations larger than expected background concentrations (about 3 mg/L as N) and detectable pesticides. Atrazine or its metabolite, deethylatrazine, were detected with greater frequency than other pesticides and were present in all 21 samples where pesticides were detected. The 21 samples with detectable pesticides also contained tritium concentrations large enough to indicate that at least some part of the water sample had been recharged within about the last 50 years. These 21 ground-water samples are considered to show water-quality effects related to irrigated agriculture. The remaining 9 groundwater samples contained no pesticides, small tritium concentrations, and nitrate concentrations less than 3.45 milligrams per liter as nitrogen. These samples are considered unaffected by the irrigated agricultural land-use setting. Nitrogen isotope ratios indicate that commercial fertilizer was the dominant source of nitrate in 13 of the 21 samples affected by irrigated agriculture. Nitrogen isotope ratios for 4 of these 21 samples were indicative of an animal waste source. Dissolved-solids concentrations were larger in samples affected by irrigated agriculture, with large sulfate concentrations having strong correlation with large dissolved solids concentrations in these samples. A strong statistical correlation is shown between samples affected by irrigated agriculture and sites with large rates of pesticide and nitrogen applications and shallow depths to ground water.

Water-Resources Investigations Report

Quality of shallow ground water in areas of recent residential and commercial development, Wichita, Kansas, 2000

Water samples from 30 randomly distributed monitoring wells in areas of recent residential and commercial development (1960–96), Wichita, Kansas, were collected in 2000 as part of the High Plains Regional Ground-Water Study conducted by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. The samples were analyzed for about 170 water-quality constituents that included chlorofluorocarbons, physical properties, dissolved solids and major ions, nutrients and dissolved organic carbon, trace elements, pesticide compounds, and volatile organic compounds. The purpose of this report is to provide an assessment of water quality in recharge to shallow ground water underlying areas of recent residential and commercial development and to determine the relation of ground-water quality to overlying urban land use. Analyses of water from the 30 monitoring wells for chlorofluorocarbons were used to estimate apparent dates of recharge. Water from 18 wells with nondegraded and uncontaminated chlorofluorocarbon concentrations had calculated apparent recharge dates that ranged from 1979 to 1990 with an average date of 1986. Water from 14 monitoring wells (47 percent) exceeded the 500-milligrams-per-liter Secondary Maximum Contaminant Level established by the U.S. Environmental Protection Agency for dissolved solids in drinking water. The Secondary Maximum Contaminant Levels of 250 milligrams per liter for chloride and sulfate were exceeded in water from one well. The source of the largest concentrations of dissolved solids and associated ions, such as chloride and sulfate, in shallow ground water in the study area probably is highly mineralized water moving out of the Arkansas River into the adjacent, unconsolidated deposits and mixing with the dominant calcium bicarbonate water in the deposits. Concentrations of most nutrients in water from the sampled wells were small, with the exception of nitrate. Although water from the sampled wells did not have nitrate concentrations larger than the 10-milligram-per-liter Maximum Contaminant Level for drinking water, water from 50 percent of the sampled wells showed nitrate enrichment (concentrations greater than 2.0 milligrams per liter). Most trace elements in water from the sampled wells were detected only in small concentrations, and few exceeded respective water-quality standards. Twenty percent of iron concentrations, 40 percent of manganese concentrations, 3 percent of arsenic concentrations, and 13 percent of uranium concentrations exceeded respective Maximum Contaminant Levels or Secondary Maximum Contaminant Levels. A total of 47 pesticide compounds were analyzed in ground-water samples during this study. Water from 73 percent of the wells sampled had detectable concentrations of one or more of 8 of these 47 compounds. The herbicide atrazine or its degradation product deethylatrazine were detected most frequently (in water from 70 percent of the sampled wells). Metolachlor was detected in water from 10 percent of the wells, and simazine was detected in water from 30 percent of the wells sampled. Other pesticides detected included dieldrin, pendimethalin, prometon, and tebuthiuron (each in water from 3 percent of the wells). All concentrations of these compounds were less than established Maximum Contaminant Levels. A total of 85 volatile organic compounds (VOCs) were analyzed in ground-water samples during this study. Water from 43 percent of the wells had a detectable concentration of one or more VOCs. Chloroform was the most frequently detected VOC (23 percent of the wells sampled).Seven other VOCs were detected in water at frequencies of 13 percent or less in the wells sampled. Concentrations of VOCs were less than respective Maximum Contaminant Levels, except one sample with a concentration of 9.0 micrograms per liter for tetrachloroethylene (Maximum Contaminant Level of 5.0 micrograms per liter). An analysis of hydraulic gradient, flow velocity, and residence time of the ground water indicated potential recharge areas that ranged from 0.8 to 2.8 miles upgradient of monitoring-well locations. Nineteen (63 percent) of these potential recharge areas were in agricultural areas or areas in transition from agricultural to residential and (or) commercial land use at the time water sampled from the monitoring wells was recharged to the shallow ground water. The occurrence of atrazine or deethylatrazine in water from 70 percent of the monitoring wells may indicate a historical agricultural land-use relation. This agricultural relation also may affect concentrations of other water-quality constituents of possible agricultural origin such as nitrate, which generally were in excess of background concentrations in shallow ground water.

Kansas

Ground-water quality in the central High Plains aquifer, Colorado, Kansas, New Mexico, Oklahoma, and Texas, 1999

A network of 74 randomly distributed domestic water-supply wells completed in the central High Plains aquifer was sampled and analyzed from April to August 1999 as part of the High Plains Regional Ground-Water Study conducted by the U. S. Geological Survey National Water-Quality Assessment Program to provide a broad-scale assessment of the ground-water-quality in this part of the High Plains aquifer. Water properties were relatively consistent across the aquifer, with water being alkaline and well oxidized. Water was mostly of the calcium and magnesium-bicarbonate type and very hard. Sulfate concentrations in water from three wells and chloride concentration in water from one well exceeded Secondary Maximum Contaminant Levels. Fluoride concentration was equal to the Maximum Contaminant Level in one sample. Nitrate concentrations was relatively small in most samples, with the median concentration of 2.3 milligrams per liter. Dissolved organic carbon concentration was relatively low, with a median concentration of 0.5 milligram per liter. The Maximum Contaminant Level set by the U.S. Environmental Protection Agency for nitrate as nitrogen of 10 milligrams per liter was exceeded by water samples from three wells. Most samples contained detectable concentrations of the trace elements aluminum, arsenic, barium, chromium, molybdenum, selenium, zinc, and uranium. Only a few samples had trace element concentrations exceeding Maximum Contaminant Levels. Fifty-five of the samples had radon concentrations exceeding the proposed Maximum Contaminant Level of 300 picocuries per liter. The greatest radon concentrations were detected where the Ogallala Formation overlies sandstones, shales and limestones of Triassic, Jurassic, or Cretaceous age. Volatile organic compounds were detected in 9 of 74 samples. Toluene was detected in eight of those nine samples. All volatile organic compound concentrations were substantially less than Maximum Contaminant Levels. Detections of toluene may have been artifacts of the sampling and analytical processes. Pesticides were detected in 18 of the 74 water samples. None of the pesticide concentrations exceeded Maximum Contaminant Levels. The most frequently detected pesticides were atrazine and its metabolite deethylatrazine, which were detected in water from 15 and 17 wells, respectively. Most of the samples with a detectable pesticide had at least two detectable pesticides. Six of the samples had more than two detectable pesticides. Tritium concentrations was greater than 0.5 tritium unit in 10 of 51 samples, indicating recent recharge to the aquifer. Twenty-one of the samples that had nitrate concentrations greater than 4.0 milligrams per liter were assumed to have components of recent recharge. Detection of volatile organic compounds was not associated with those indicators of recent recharge, with most of volatile organic compounds being detected in water from wells with small tritium and nitrate concentrations. Detection of pesticides was associated with greater tritium or nitrate concentrations, with 16 of the 18 wells producing water with pesticides also having tritium or nitrate concentrations indicating recent recharge.

Colorado, Kansas, New Mexico, Oklahoma, Texas

Ground-water quality in Quaternary deposits of the central High Plains aquifer, south-central Kansas, 1999

Water samples from 20 randomly selected domestic water-supply wells completed in the Quaternary deposits of south-central Kansas were collected as part of the High Plains Regional Ground-Water Study conducted by the U.S. Geological Survey's National Water-Quality Assessment Program. The samples were analyzed for about 170 water-quality constituents that included physical properties, dissolved solids and major ions, nutrients and dissolved organic carbon, trace elements, pesticides, volatile organic compounds, and radon. The purpose of this study was to provide a broad overview of ground-water quality in a major geologic subunit of the High Plains aquifer. Water from five wells (25 percent) exceeded the 500-milligrams-per-liter of dissolved solids Secondary Maximum Contaminant Level for drinking water. The Secondary Maximum Contaminant Levels of 250 milligrams per liter for chloride and sulfate were exceeded in water from one well each. The source of these dissolved solids was probably natural processes. Concentrations of most nutrients in water from the sampled wells were small, with the exception of nitrate. Water from 15 percent of the sampled wells had concentrations of nitrate greater than the 10-milligram-per-liter Maximum Contaminant Level for drinking water. Water from 80 percent of the sampled wells showed nitrate enrichment (concentrations greater than 2.0 milligrams per liter), which is more than what might be expected for natural background concentrations. This enrichment may be the result of synthetic fertilizer applications, the addition of soil amendment (manure) on cropland, or livestock production. Most trace elements in water from the sampled wells were detected only in small concentrations, and few exceeded respective water-quality standards. Only arsenic was detected in one well sample at a concentration (240 micrograms per liter) that exceeded its proposed Maximum Contaminant Level (5.0 micrograms per liter). Additionally, one concentration of iron and two concentrations of manganese were larger than the Secondary Maximum Contaminant Levels of 300 and 50 micrograms per liter, respectively. Some occurrences of trace elements may have originated from human-related sources; however, the generally small concentrations that were measured probably reflect mostly natural sources for these constituents. A total of 47 pesticide compounds from several classes of herbicides and insecticides that included triazine, organophosphorus, organochlorine, and carbamate compounds and three pesticide degradation products were analyzed in ground-water samples during this study. Water from 50 percent of the wells sampled had detectable concentrations of one or more of these 47 compounds. The herbicide atrazine and its degradation product deethylatrazine were detected most frequently (in water from eight and nine wells, respectively); other pesticides detected were the insecticides carbofuran (in water from one well) and diazinon (in water from one well), and the herbicide metolachlor (in water from two wells). However, all concentrations of these compounds were small and substantially less than established Maximum Contaminant Levels. The use of pesticides in crop production probably is largely responsible for the occurrence of pesticides in the ground-water samples collected during this study. Although concentrations of detected pesticides were small (relative to established Maximum Contaminant Levels), the synergistic effect of these concentrations and long-term exposure to multiple pesticides on human health are unknown. Water samples from the Quaternary deposits were analyzed for 85 volatile organic compounds. Water from two wells (10 percent) had a detectable concentration of a volatile organic compound. Chloroform was detected at concen-trations of 0.18 and 0.25 microgram per liter, substantially less than the 100-microgram-per-liter Maximum Contaminant Level for total trihalomethanes. In general, the occurrence and detectio

Water-Resources Investigations Report

Denitrification in marine shales in northeastern Colorado

Parts of the South Platte River alluvial aquifer in northeastern Colorado are underlain by the Pierre Shale, a marine deposit of Late Cretaceous age that is <1000 m thick. Ground water in the aquifer is contaminated with NO 3 ‐ , and the shale contains abundant potential electron donors for denitrification in the forms of organic carbon and sulfide minerals. Nested piezometers were sampled, pore water was squeezed from cores of shale, and an injection test was conducted to determine if denitrification in the shale was a sink for alluvial NO 3 − and to measure denitrification rates in the shale. Measured values of NO 3 − , N 2 , NH 4 + , δ 15 N[NO 3 − ], δ 15 N[N 2 ], and δ 15 N[NH 4 + ] in the alluvial and shale pore water indicated that denitrification in the shale was a sink for alluvial NO 3 − . Chemical gradients, reaction rate constants, and hydraulic head data indicated that denitrification in the shale was limited by the slow rate of NO 3 − transport (possibly by diffusion) into the shale. The apparent in situ first‐order rate constant for denitrification in the shale based on diffusion calculations was of the order of 0.04–0.4 yr −1 , whereas the potential rate constant in the shale based on injection tests was of the order of 60 yr −1 . Chemical data and mass balance calculations indicate that organic carbon was the primary electron donor for denitrification in the shale during the injection test, and ferrous iron was a minor electron donor in the process. Flux calculations for the conditions encountered at the site indicate that denitrification in the shale could remove only a small fraction of the annual agricultural NO 3 ‐ input to the alluvial aquifer. However, the relatively large potential first‐order rate constant for denitrification in the shale indicated that the percentage of NO 3 − uptake by the shale could be considerably larger in areas where NO 3 − advection.

Colorado

Denver's urban ground-water quality: Nutrients, pesticides, and volatile organic compounds

A recent study by the U.S. Geological Survey (USGS) under the National Water-Quality Assessment (NAWQA) program characterized the ground-water quality in a part of the Denver, Colorado, metropolitan area. The study provides an assessment of water-quality conditions in an alluvial aquifer that drains into the South Platte River. Thirty wells randomly distributed in residential, commercial, and industrial land-use settings were sampled once in 1993 for a broad range of compounds. Nutrients, pesticides, and volatile organic compounds (VOC's), all of which are generally associated with human activities, frequently were detected in the urban wells sampled. Nutrients and VOC's occasionally exceeded drinking-water standards.

Fact Sheet