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At least 19 recordsLinked to original sources
USGS1990

Monitoring long-term effects of offshore oil and gas development along the Southern California outer continental shelf and slope: Background environmental conditions in the Santa Maria Basin

Potential environmental impacts of materials discharged from oil and gas development and production platforms off the coast of southern California (Santa Maria Basin) are being monitored during an ongoing, long-term (fiveyear) field program. The study combines hypothesis testing of platform effects with basic research on the structure and dynamics of the regional ecosystem over a time series encompassing both seasonal and repeated annual scales. Oceanographic features and processes that are being measured focus on the benthos and include biological community indices and species abundances for hard-bottom and soft-bottom (macroinfauna and meiofauna) assemblages; levels and distributions of trace metals and hydrocarbons in bottom sediments, suspended particulates, animal tissues, and pore waters; water currents and otherphysical-oceanographicfeatures; various sedimentological properties (sediment grain size, total organic carbon, shear strength, distribution of mineral types, radioisotope profiles, and degrees of sediment mixing as a result of bioturbation); sediment and pollutant-transport processes; and animal-sediment-pollutant interactions. Synoptic measurement of these different environmental variables over the extended sampling period provides an opportunity to examine long-term variability in the benthic environment with respect to both natural and anthropogenic causes. Efforts to distinguish between natural variability and low-level cumulative impacts of drilling are given special attention. Results obtained during the first two years of sampling provide a basis for beginning to understand environmental processes and relations important in detecting and interpreting any subsequent impacts caused by drilling activities in this complex and productive region of the California outer continental shelf and slope. Background chemical, physical, and biological data generated during this period demonstrate that impacts of discharges from oil and gas operations should be detectable, if they occur, and should be distinguishable from natural environmental variability. Small inputs of barium and petroleum hydrocarbons have been detected and appear to be associated with the minor drilling activities that have occurred in the area thus far, however, these initial inputs have not led to any noticeable biological impacts. These initial results are hopefully of value for two reasons: (1) in providing a summary of basic chemical, physical, and biological features of the benthic environment within the Santa Maria Basin; and (2) in presenting information on research strategies that should be considered in designing studies dealing with similar resource-management problems in other parts of the world.

California↗
USGS2013

Mobile Bay

Mobile Bay is the largest bay found in Alabama’s coastal area (Handley et al., 2007). It was named an Estuary of National Significance in 1995 under the U.S. Environmental Protection Agency’s (EPA) National Estuary Program (NEP), and its Comprehensive Conservation Management Plan was completed in 2002. Mobile Bay is 1,070 km 2 (413 miles 2 ) in area and 51 km (32 miles) long, making it the sixth largest estuary in the continental United States (Mobile Bay NEP, 2008). Its ecosystem provides habitat for more than 300 species of birds, 310 species of fish, 68 species of reptiles, 57 species of mammals, 40 species of amphibians, and 15 species of shrimp (Mobile Bay NEP, 1997). Mobile Bay lies between the Mississippi and Atlantic Flyways (Mobile Bay NEP, 2003). Commercial and residential development and industrial use is heavy in the Mobile Bay area. Although local growth and industrial markets support the Mobile Bay area economy, the resulting environmental damage to the very ecosystem upon which they depend remains a threat to the environment, economy, and population. The Mobile Bay ecosystem boasts high biological diversity and productivity and supports many freshwater and saltwater species of recreational and commercial importance. The great diversity of Mobile Bay reflects the diversity of Alabama, which is home to the largest number of different plant and animal species of all states east of the Mississippi River (Stein, 2002), and is bolstered by the unique climate and geographic conditions surrounding the bay. Freshwater inflow from the Mobile-Tensaw River Delta, ranging from 60,000 to 3,700,000 gallons per second (Wallace, 1996), mixes with saltwater from the Gulf of Mexico, which enters Mobile Bay via wind and tides (Burgan and Engle, 2006). Because of the unique conditions surrounding Mobile Bay, including shallow waters, a dynamic climate, and artificial hydrologic modifications—such as the construction of the Mobile Bay Causeway in the 1920s, which serves as an unintentional barrier between Delta waters north of the Causeway and saline waters south of the Causeway, the salinity of Mobile Bay is highly variable. Mobile Bay receives an average of 165 cm (65 inches) of rain per year from tropical storms, summer thunderstorms, and winter cold fronts (Stout et al., 1998). The climate and geography that have made Mobile Bay so rich in resources have also contributed to the threats surrounding its ecosystem. The extensive amount of rain in Mobile Bay creates large amounts of runoff, polluting the waters with fertilizers, chemicals, sediment, oil, trash, and sewage (Mobile Bay NEP, 1997). Tourism, ecotourism, recreational and commercial fishing, recreational boating, shipping, and chemical, pulp, and paper production are significant industries in Mobile Bay and the surrounding areas. Despite the approximate \$3 billion and 55,000 jobs these industries bring into the community (Alabama Tourism Department, 2010), the growth, development, and environmental stress they create are major threats to the Mobile Bay ecosystem. Among the nation’s states, Alabama ranks fifth in number of different species (144 endemic species), second in number of extinctions that have already occurred (90 extinct species) and fourth in number of species at risk for extinction (14.8% at risk out of 4,533 total species; Stein, 2002). Twenty-one of these threatened and endangered species are found in Mobile Bay, whose brackish waters provide a nursery area for many species of vertebrates and invertebrates. Some of these species include the Alabama sturgeon, Gulf sturgeon, heavy pigtoe mussel, inflated heel-splitter mussel, West Indian manatee, Alabama beach mouse, Perdido beach mouse, Alabama red-bellied turtle, gopher tortoise, Kemp’s ridley sea turtle, green sea turtle, loggerhead sea turtle, eastern indigo snake, flatwoods salamander, piping plover, red-cockaded woodpecker, and wood stork. Habitat loss underlies the decline of some bird species in Mobile Bay, and large mammals such as the red wolf, Florida panther, and Florida black bear are no longer found in the area. However, some rare species, such as the swallow-tailed kite, sandhill crane, and gopher tortoise can still be found (Duke and Kruczynski, 1992). The value of wetlands in Mobile Bay and the rest of the Gulf of Mexico is still being investigated. Although various monetary valuations of wetlands exist, critics remark that undervaluation of wetlands is inevitable (Mobile Bay NEP, 2008) and that estimates often do not place appropriate value on ecological services (Mitsch and Gosselink, 2000). Additionally, many estimates account only for anthropogenic values. One estimate concludes that one acre of wetlands performs \$3,000 worth of water purification each year (Mobile Bay NEP, 1997). With more than 76,890 hectares (190,000 acres) of wetlands in the Mobile Bay area, that equates to a value exceeding one-half billion dollars every year. Tourism, fishing, boating, production, and shipping are significant industries in the Mobile Bay area. More than 90% of fish landed in recreational and commercial fishing in the bay depend on bay habitat, including wetlands, for life requirements (Mobile Bay NEP, 1997). The Port of Mobile is Alabama’s only ocean-ship port (Mobile Bay NEP, 2008). Baldwin County, on the eastern side of the bay, experienced a population increase of 75% from 1990 to 2007, with an 89% increase in housing units (Mobile Bay NEP, 2008). Development and industry support the Mobile Bay economy, but they depend on the continued health, sustainability, and production of the water and living resources of the Mobile Bay ecosystem. Wetland loss, along with other forms of environmental degradation, remains a threat to the Mobile Bay ecosystem and Mobile Bay’s socioeconomic foundation.

Alabama↗
USGS1999

Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

A variety of elements and organic compounds have entered the environment as a result of human activities. Such substances find their way to aquatic sediments from direct discharges to waterways, atmospheric emissions, and runoff. Some of these chemicals are known to harm fish or wildlife, either by direct toxicity, by reducing viability, or by limiting reproductive success. In aquatic systems, sediments become the eventual sink for most of these chemicals. Analyzing the sediments provides a first step in a chemical inventory that can lead to an assessment of potential biological impacts (Kennicutt and others, 1994). Many elements (iron, aluminum, calcium, and others) enter the environment from the natural weathering of rock. Additional amounts of elements have been contributed by human activities such as mining, metals production and processing, fossil fuel combustion, municipal waste incineration, and transportationrelated sources. The environmental presence of some elements, such as lead and mercury, is almost entirely due to human activity. Lead is often associated with the use of leaded gasoline and from the manufacture and disposal of lead storage batteries. Mercury was used historically in a variety of industrial processes and as a pesticide. Nriagu and Pacyna (1998) concluded that human activity is the “most important element in the global biogeochemical cycling of the trace metals.” The number of organic compounds in existence and their total production has more than tripled in the last century. Many of these compounds enter the environment directly as pesticides; others are inadvertently discharged. Some organic compounds have natural sources. Three general classes of organic compounds will be discussed: organochlorine compounds, polyaromatic hydrocarbons, and phthalates. Almost all organochlorine compounds are manmade. Many are pesticides that were used widely in the 1950s–60s (DDT and chlordanes, for example). Use of most organochlorine pesticides was restricted or banned in the United States in the 1970s–80s. Polychlorinated biphenyls (PCBs) are also organochlorine compounds; they were used for a variety of applications, but most commonly as insulators in electrical transformers and other equipment. In general, organochlorine compounds degrade very slowly in the environment and therefore, are routinely found in environmental samples, despite the fact that they are no longer used in the United States. They are hydrophobic that is they do not dissolve readily in water and, in aquatic systems, are almost exclusively associated with sediments or tissue. Because these compounds cause a variety of adverse health effects in wildlife, the U.S. Environmental Protection Agency (USEPA) has listed many as priority pollutants. Organochlorine compounds also have been implicated as endocrine disrupters— chemicals that can interfere with the normal function of hormones. Polyaromatic hydrocarbons (PAHs) are found in sediments throughout the world (Hites and others, 1980). Their presence is thought to be primarily anthropogenic. PAHs occur naturally in petroleum products and also are produced during combustion. They enter the environment from fuel spills, tar coatings, coal and other fossil fuel usage, road dust, and from the atmospheric deposition of combustion products (Prahl and others, 1984; Wakeham and others, 1980). Urban areas often have high concentrations of PAHs because of transportation-related sources (vehicle exhaust, paving materials, and releases of fuel or oil). Natural sources, such as forest fires, may contribute small amounts of PAHs. Several PAHs are known carcinogens (benzo[a]pyrene, for example); 16 are listed as USEPA priority pollutants. Phthalate compounds are often associated with urban areas. They are used in a wide variety of industrial applications and in inks, adhesives, resins, and as plasticizers (chemicals that increase the flexibility of plastics). In aquatic systems, phthalates are found mostly in sediments where they degrade very slowly. Phthalates are thought to be endocrine disrupters; Jobling and others (1995) found that some phthalates were weakly estrogenic. USEPA considers some phthalates to be possible carcinogens. This report describes the results of a reconnaissance survey of elements and organic compounds found in bed sediment and fish tissue in streams of the Tualatin River Basin. The basin is in northwestern Oregon to the west of the Portland metropolitan area (fig. 1). The Tualatin River flows for about 80 miles, draining an area of about 712 square miles, before it enters the Willamette River. Land use in the basin changes from mostly forested in the headwaters, to mixed forest and agriculture, to predominately urban. The basin supports a growing population of more than 350,000 people, most of whom live in lower parts of the basin. Water quality in the Tualatin River and its tributaries is expected to be affected by the increasing urbanization of the basin.

Oregon↗
USGS1965

Present and Future Water Supply for Mammoth Cave National Park, Kentucky

The increase in the number of visitors during the past several years at Mammoth Cave National Park has rendered the present water supply inadequate. Emergency measures were necessary during August 1962 to supplement the available supply. The Green River is the largest potential source of water supply for Mammoth Cave. The 30-year minimum daily discharge is 40 mgd (million gallons per day) . The chemical quality is now good, but in the past the river has been contaminated by oil-field-brine wastes. By mixing it with water from the existing supply, Green River water could be diluted to provide water of satisfactory quality in the event of future brine pollution. The Nolin River is the next largest potential source of water (minimum releases from Nolin Reservoir, 97-129 mgd). The quality is satisfactory, but use of this source would require a 8-mile pipeline. The present water supply comes from springs draining a perched aquifer in the Haney Limestone Member of the Golconda Formation on Flint Ridge. Chemical quality is excellent but the minimum observed flow of all the springs on Flint Ridge plus Bransford well was only 121,700 gpd (gallons per day). This supply is adequate for present needs but not for future requirements; it could be augmented with water from the Green River. Wet Prong Buffalo Creek is the best of several small-stream supplies in the vicinity of Mammoth Cave. Minimum flow of the creek is probably about 300,000 gpd and the quality is good. The supply is about 5 miles from Mammoth Cave. This supply also may be utilized for a future separate development in the northern part of the park. The maximum recorded yield of wells drilled into the basal ground water in the Ste. Genevieve and St. Louis Limestone is 36 gpm (gallons per minute). Larger supplies may be developed if a large underground stream is struck. Quality can be expected to be good unless the well is drilled too far below the basal water table and intercepts poorer quality water at a lower level. This source of supply might be used to augment the present supply, but locating the trunk conduits might be difficult. Water in alluvium adjacent to the Green River and perched water in the Big Clifty Sandstone Member of the Golconda Formation and Girkin Formation have little potential as a water supply.

Water Supply Paper↗
USGS1981

Environmental geologic studies on the southeastern United States Atlantic Outer Continental Shelf, 1977-1978

This report is a summary of the second year of marine environmental research activities by the U.S. Geological Survey (USGS) on the southeaster U.S. Atlantic Continental Margin, in accordance with with Memorandum of Understanding (MOU) AA551-MU8-13 between the USGS and the Bureau of Land Management (BLM). The report covers studies whose fieldwork was conducted during the period from 1 October 1977 to 30 September 1978. The results of the first year of study are reported in Popenoe (1978a and b) and as U.S. Department of Commerce NTIS report PB 300-820. The purpose of these investigations is to provide basic geologic and oceanographic data to the BLM Outer Continental Shelf (OCS) Marine Environmental Studies Program in support of management decisions which relate to possible development of oil and gas resources of the continental shelf. The objectives of the USGS-BLM geologic research program for fiscal year 1978 (FY-78) were 1) to determine the sedimentation rates and processes on the upper slope and inner Blake Plateau; 2) to determine the distribution, areal extent, and vertical characteristics of geological features supportive of biological communities; 3) to monitor the transport of bottom sediment across the OCS, evaluate its possible effect on pollutant transfer along the seabed and the potential of sediment as a pollutant sink, determine the implications of erosion/deposition on pipeline emplacement, and aid the interpretation of chemical, biological, and physical data; 4) to determine the concentration levels of chosen trace metals and silica in three chemically defined fractions of the suspended particulate matter (seston); 5) to study the shelf edge and slope near areas of oil and gas interest, and the northern portion of the Blake Plateau for evidence of slope instability and other geologic hazards, and 6) to determine the depth and rate of sediment mixing caused by large storms and/or by benthic organisms and where possible to estimate the rate of active sediment accumulation.

Atlantic Outer Continental Shelf↗
USGS1991

Chemical contamination and physical characteristics of sediments in the upper Great Lakes connecting channels 1985

Contamination of sediments by toxic organic substances and heavy metals was widespread throughout the connecting channels of the upper Great Lakes in 1985. Sediments at 250 stations in the connecting channels were analyzed for total PCBs, oil and grease, phenols, total cyanide, total volatile solids, mercury, cadmium, chromium, cobalt, copper, lead, nickel, and zinc, and the results were evaluated according to U.S. EPA guidelines for polluted sediments. Sediments were most heavily contaminated near industrialized areas, although some areas more than 40 km downstream from known point sources of pollution were moderately contaminated by oil and metals.

Report↗
USGS1967

Reconnaissance of the chemical quality of surface waters of the Neches River basin, Texas

The kinds and quantities of minerals dissolved in the surface water of the Neches River basin result from such environmental factors as geology, streamflow patterns and characteristics, and industrial influences. As a result of high rainfall in the basin, much of the readily soluble material has been leached from the surface rocks and soils. Consequently, the water in the streams is usually low in concentrations of dissolved minerals and meets the U.S. Public Health Service drinking-water standards. In most streams the concentration of dissolved solids is less than 250 ppm (parts per million). The Neches River drains an area of about 10,000 square miles in eastern Texas. From its source in southeast Van Zandt County the river flows in a general southeasterly direction and empties into Sabine Lake, an arm of the Gulf of Mexico. In the basin the climate ranges from moist subhumid to humid, and the average annual rainfall ranges from 46 inches is the northwest to more than 52 inches in the southeast. Annual runoff from the basin has averaged 11 inches; however, runoff rates vary widely from year to year. The yearly mean discharge of the Neches River at Evadale has ranged from 994 to 12,720 cubic feet per second. The rocks exposed in the Neches River basin are of the Quaternary and Tertiary Systems and range in age from Eocene to Recent. Throughout most of the basin the geologic formations dip generally south and southeast toward the gulf coast. The rate of dip is greater than that of the land surface; and as a result, the older formations crop out to the north of the younger formations. Water from the outcrop areas of the Wilcox Group and from the older formations of the Claiborne Group generally has dissolved-solids concentrations ranging from 100 to 250 ppm; water from the younger formations has concentrations less than 100 ppm. The northern half of the basin has soft water, with less than 60 ppm hardness. The southern half of .the basin has very soft water, usually with less than 30 ppm hardness. The chloride concentrations are less than 20 ppm in surface water in the southern half of the basin and usually range from 20 to 100 ppm in the northern half of the basin. Concentrations greater than 100 ppm are found only where pollution is occurring. The Neches River basin has an abundance of surface water, but uneven distribution of runoff makes storage projects necessary to provide dependable water supplies. The principal existing reservoirs, with the exception of Striker Creek Reservoir, contain water of excellent quality. Chemical-quality data for the Striker Creek drainage area indicate that its streams are affected by .the disposal of brines associated with oil production. Sam Rayburn Reservoir began impounding water in 1965. The water impounded should prove of acceptable quality for most uses, but municipal and industrial wastes released into the Angelina River near Lufkin may have a degrading effect on the quality of the water, especially during extended periods of low flows. Water available for storage at the many potential reservoir sites will be of good quality; but, if the proposed salt-water barrier is to impound acceptable water, the disposal of oilfield brine into Pine Island Bayou should be discontinued.

Water Supply Paper↗
USGS1963

Geology and ground-water resources of Winkler County, Texas

Winkler County, in west Texas, is adjacent to the southeast corner of New Mexico. Most of the county lies in the Pecos Valley; the remainder, in the northeastern part of the county, is part of the Llano Estacado, or the High Plains. Its principal industries are those related to the production and refining of oil, but ranching also is an important occupation. The county has an arid to semiarid climate, an area of about 887 square miles, and a population of about 12,000 in 1957. The principal fresh-water-bearing formations in Winkler County are the Cenozoic alluvium, which mantles the surface of most of the county, and the Santn Rosa sandstone of Late Triassic age. The alluvium is saturated at a depth ranging from a few feet below the land surface to about 150 feet, and the water is under water-table conditions. The Santa Rosa sandstone is fully saturated throughout most of the county, the water occurring under both unconfined (water-table) and confined (artesian) conditions. The underlying older formations contain water too highly mineralized for most uses, but they are important because water from these underlying beds, which is produced with the oil, is a source of pollution to the fresh-water aquifers. The formations also are a source of water to waterflooding projects for the secondary recovery of oil. The alluvium is replenished chiefly by precipitation, throughout the county. The sand-dune area in the eastern part is the most favorable area of natural recharge. The Santa Rosa sandstone is recharged through the alluvium where the two formations are in contact. Infiltration of saline water, which with oil and waste water has been produced from industrial plants, has been taking place through surface earthen pits. About 18 mgd (million gallons per day) of saline water was being produced from the many oil fields throughout the county during August 1957, and almost all this water was placed in surface pits. The Hendrick oil field alone produced about 14.5 mgd during that month, and an estimated 800,000 acre-feet from 1937 to 1957. About 20 million acre-feet of fresh water is stored in the explored groundwater aquifers of Winkler County, of which an estimated 5 to 7 million acrefeet can be practicably recovered. A daily average of about 8.2 million gallons (9,200 acre-feet per year) of fresh water was used in the county during 1956. Public and industrial use accounted for about 6.8 mgd; irrigation, domestic, and stock uses accounted for 1.4 mgd. Projects engaged in the secondary recovery of oil were the largest consumers, using an average of about 3 mgd of fresh water and about 2.7 mgd of saline water during 1956. Water wells drilled in the deep trough of Cenozoic alluvium south of Wink may yield 1,000 gpm (gallons per minute) or more. A pumping test of the alluvium in that area indicated a coefficient of transmissibility of about 25,000 gpd (gallons per day) per foot. Wells, other than windmill wells, drawing water from thinner sections of alluvium in the rest of the county yield between 100 and 300 gpm. Most of the wells in the Santa Rosa sandstone yield 30-400 gpm. Two municipal wells at Kermit that tap the Santa Rosa sandstone were tested at 1,200 and 1,875 gpm. The large yield of these wells probably results from the presence of fractures in the structurally deformed aquifer. Pumping tests in the Kermit area indicate that locally a full section of the Santa Rosa sandstone has an average coefficient of transmissibility of about 25,000 gpd per foot and a coefficient of storage of about 0.0003. The transmissibility in two other tested areas is much less. The chemical quality of the water in the principal aquifers is generally acceptable for industry and for public supply. About two-thirds of the samples collected from fresh-water wells had a dissolved-solids content of less than 1,000 ppm (parts per million) ; however, some samples in a few areas were hard and were high in fluoride and silica. Samples from wells in polluted areas contained dissolved solids ranging from about 1,400 to 71,100 ppm. Two comprehensive analyses of water samples from the Rustler formation showed a dissolved-solids content of 18,400 ppm. and 157,000 ppm. In most of the water produced with the oil in the Hendrick oil field, the content of dissolved solids ranged from about 4,000 to about 10,000 ppm. The water produced with the oil in the rest of the oil fields in Winkler County was mainly brine.

Water Supply Paper↗
USGS1979

Ecological and physiological/toxicological effects of petroleum on aquatic birds: A summary of research activities FY76 through FY78

Oil and gas development and exploration in marine coastal areas and the Great Lakes will result in unavoidable spills of polluting oil. Although large oil spills may kill thousands of birds and stimulate much public concern, the bulk of oil that reaches aquatic environmentS released in the course of normal operations, with a total input into the world's oceans estimated at 6 million metric tons per year. The effects of sublethal low-level oil pollution may be more deleterious to bird populations over the long term than the spectacular bird kills resulting from oil spills. The physiological and ecological effects of oil on waterbirds were examined in a series of laboratory and field experiments, including studies of the effects of oiling on hatchability of eggs; the effects of an oil-contaminated diet on physiological condition, reproduction, and survival; and the accumulation of oil in body tissues. Chemical methodology was developed in support of these studies.

FWS/OBS↗
USGS1999

Multi-year persistence of oil mousse on high energy beaches distant from the Exxon Valdez spill origin

For at least 5 yr after the Exxon Valdez spill, relatively unweathered oil mousse has persisted on the exposed rocky shores of Shelikof Strait 500 km from Prince William Sound, Alaska. Previously it was thought that oil would be rapidly removed from such geomorphic settings by wave action. Oil mousse persists at sites in Katmai National Park and Preserve (NP&P) where it was stranded high in the intertidal zone under a lag of large boulders. These boulders armor the beach, preventing waves from disturbing the substrate and its included oil. Weathering of this stranded mousse has been slight – mousse sampled in 1989, 1992 and 1994 show negligible changes in polynuclear aromatic hydrocarbons compared to 11-day old Exxon Valdez crude. The preservation of this oil is due to its transport as mousse boli whose interiors largely escape weathering, followed by its sheltering in the interstices of boulder-armored beaches. The transport of mousse may allow for the long distance dispersal of less weathered, and hence still toxic oil. Our findings suggest that the low ecological sensitivity ratings previously applied to exposed, rocky shorelines need to be modified. The biological threat posed by oil stranded on the Katmai NP&P coast probably is slight because of its small amount and sequestered state. However, it still possesses the ability to be chemically toxic and could be released through disturbance of the armoring boulders by unusually high wave events.

Alaska↗
USGS1974

Simulated effects of oil-shale development on the hydrology of Piceance basin, Colorado

The Piceance and Yellow Creeks drainage area is about 900 square miles (2,330 square kilometres) and is referred to as the Piceance basin, or simply as the basin. The surface-water and ground-water systems in the Piceance basin are intimately related. The annual volume of runoff from the basin (Piceance and Yellow Creeks) is estimated to be 15,650 acre-feet (19.2 cubic hectometres). About 80 percent of the annual runoff is supplied by ground-water discharge. Runoff from the basin is affected by irrigation diversions and consumptive use by crops, native vegetation, and evporation. Streamflow depletions resulting from irrigation are estimated to be 4,800 acre-feet (5.9 cubic hectometres) per year. In the absence of irrigation, the mean annual runoff from the basin would be 20,450 acre-feet (25.2 cubic hectometres). The period of lowest flow normally occurs during spring and summer when irrigation diversions are greatest. Peak flows from snowmelt and thunderstorms also occur during this period. A regional analysis, using the index-flood method, was made to estimate flood frequencies in the absence of irrigation diversions for the gaging stations Piceance Creek at White River and Yellow Creek near White River. The estimated mean annual floods are 800 cubic feet per second (22.7 cubic metres per second) for Piceance Creek and 390 cubic feet per second (11.0 cubic metres per second) for Yellow Creek. The peak flow observed during the 5 years of record on Piceance Creek at White River was 407 cubic feet per second (11.5 cubic metres per second) or about one-half the estimated mean annual flood. Yellow Creek is only slightly affected by irrigation diversions and the peak flow for the single year of record was 468 cubic feet per second (13.3 cubic metres per second). Irrigation return flows and ground-water discharge affect the quality of surface water in the Piceance basin. The concentration of dissolved solids ranges from less than 500 milligrams per litre in the upper reaches to more than 5,000 milligrams per litre in the lower reaches of Piceance Creek and from about 700 to 3,000 milligrams per litre in Yellow Creek. Water quality decreases in the downstream direction due to ground-water discharge from the Green River and Uinta Formations. The ground-water system in the basin consists of two principal aquifers separated by the Mahogany zone in the Green River Formation. Recharge to the aquifers occurs mainly from snowmelt along the basin margins above 7,000 feet (2,130 metres) altitude. Ground water flows from the basin margins toward the north-central part of the basin where it is discharged in Piceance and Yellow Creek valleys as evapotranspiration and streamflow. Recharge and discharge from the aquifer system are estimated to average 26,100 acre-feet (32.2 cubic hectometres) annually. About 20 percent of the recharge is discharged in Yellow Creek drainage. Estimates of the volume of water in storage in the aquifers range from 2.5 to 25 million acre-feet (3,100 to 31,000 cubic hectometres). Sodium minerals in the aquifer below the Mahogany zone are actively being dissolved by ground water. The Mahogany zone impedes the flow of water between the aquifers and large chemical differences have developed. Water in the upper aquifer generally has less than 2,000 millgrams per litre dissolved solids while that in the lower aquifer exceeds 30,000 milligrams per litre dissolved solids in the northern part of the basin. Digital models were used to simulate the hydrologic system. A watershed model was adapted to the drainage above the gage on Piceance Creek below Ryan Gulch to evaluate the possible effects of precipitation changes on the hydrologic system due to the introduction of atmospheric pollutants from oil-shale development or cloud seeding. A 10-percent decrease and 10- and 20-percent increases in the October to May precipitation were examined. It was found that each 10-percent change in precipitation results in a 40-percent change in ground-water recharge. The model study indicates that a 10-percent decrease in October-May precipitation results in a 30-percent decrease in mean annual runoff while 10-and 20-percent increases in precipitation result in 40- and 85 percent increases in mean annual runoff. A digital model of the ground-water system was used to evaluate the effects of mine dewatering on the hydrologic system. Hypothetical mines in oil-shale lease tracts C-a and C-b were considered. Both mines were assumed to be in the Mahogany zone and to be 4 square miles (5.2 square kilometres) in area. Dewatering of the mines was assumed to occur simultaneously for a period of 30 years. For the hypothetical dewatering scheme simulated, the model study indicates that the mine in tract C-a will not produce enough water to meet the demand for processing and disposal of oil shale while the mine in tract C-b will produce water in excess of the demand. The concentration of dissolved solids of the water discharged from the mines may not exceed 5,000 milligrams per litre for the hypothetical dewatering scheme considered. Dewatering the hypothetical mines will only slightly affect groundwater discharge in the Yellow Creek drainage. However, after 30 years of dewatering, the model indicates that ground-water discharge will cease in a 10-mile (16-kilometre) reach of Piceance Creek near tract C-b. The decrease in ground-water discharge in this reach could cause an increase in the concentration of dissolved solids in the downstream reach of Piceance Creek. After 30 years of dewatering, the hydraulic head in the aquifers is decreased in 75 percent of the basin area and about 500,000 acre-feet (620 cubic hectometres) of water are removed from storage in the aquifers. It is concluded that oil-shale development will have significant effects on the surface- and ground-waters systems in the Piceance basin.

Colorado↗
USGS1972

Chemical quality of water in the Walnut River basin, south-central Kansas

Improper disposal of oil-field brine and other wastes has adversely affected the naturally diverse chemical quality of much of the water in the Walnut River basin, south-central Kansas. The basin is an area of about 2,000 square miles in the shape of a rough triangle with its apex toward the south. The Whitewater River, a principal tributary, and the Walnut River below its junction with the Whitewater River flow southward toward the Arkansas River along courses nearly coincident with the contact of the Chase and overlying Sumner Groups of Permian age. The courses of many minor tributaries are parallel to a well-developed joint system in the Permian rock. Thick interbedded limestone and shale of the Chase Group underlie the more extensive, eastern part of the basin. Natural waters are dominantly of the calcium bicarbonate type. Shale and subordinate strata of limestone, gypsum, and dolomite of the Sumner Group underlie the western part of the basin. Natural waters are dominantly of the calcium sulfate type. Inflow from most east-bank tributaries dilutes streamflow of the Walnut River; west-bank tributaries, including the Whitewater River, contribute most of the sulfate. Terrace deposits and alluvial fill along the stream channels are assigned to the Pleistocene and Holocene Series. Calcium bicarbonate waters are common as a result of the dissolution of nearly ubiquitous fragments of calcareous rock, but the chemical quality of the water in the discontinuous aquifers depends mainly on the quality of local recharge. Concentrations of dissolved solids and of one or more ions in most well waters exceeded recommended maximums for drinking water. Nearly all the ground water is hard to very hard. High concentrations of sulfate characterize waters from gypsiferous aquifers; high concentrations of chloride characterize ground waters affected by drainage from oil fields. Extensive fracture and dissolution of the Permian limestones facilitated pollution of ground water by oil-field brine and migration of the polluted water into adjacent areas. Ground water containing more than 1,000 mg/o=l (milligrams per liter) dissolved solids .and more than 100 mg/o=l chloride is common near oil fields but is exceptional elsewhere. The concentration of nitrate in about 25 percent of the sampled well waters exceeded the recommended maximum for drinking water. High concentrations of nitrate generally were associated with shallow aquifers, local sources of organic pollution, and stagnation. Sodium and chloride are the principle ionic constituents of oil-field brine but are minor constituents of natural surface waters or shallow ground water in the basin. The ratios of the concentrations of sodium to chloride in brine from different oil fields varied within a narrow range from a mean of 0.52. Concentrations of chloride exceeding 50 mg/o=l in streamflow and 100 mg/l in ground water generally signified the presence of oil-field brine if the sodium-chloride ratios were less than 0.60. Higher sodium-chloride ratios characterized relatively rare occurrences of high concentrations of the ions that might have originated in evaporite minerals or in sewage. The concentration of chloride during low flow of the major streams generally increased, and the sodium-chloride ratio decreased, in a downstream direction from about 0.65 near the headwaters to about 0.51, which is characteristic of oil-field brine. The changes were most abrupt where polluted ground-water effluent augmented low streamflow adjacent to old oil fields. With increased direct runoff, the sodium-chloride ratio normally increased, and these ions constituted a smaller percentage of the dissolved-solids load. Annual runoff .decreased progressively from above normal to below normal during water years 1962-64. Higher concentrations .of the ions in streamflow persisted for longer periods during the periods of low runoff

Water Supply Paper↗
USGS1984

Animals as indicators of ecosystem responses to air emissions

With existing and proposed air-quality regulations, ecological disasters resulting from air emissions such as those observed at Copperhill, Tennessee, and Sudbury, Ontario, are unlikely. Current air-quality standards, however, may not protect ecosystems from subacute and chronic exposure to air emissions. The encouragement of the use of coal for energy production and the development of the fossil-fuel industries, including oil shales, tar sands, and coal liquification, point to an increase and spread of fossil-fuel emissions and the potential to influence a number of natural ecosystems. This paper reviews the reported responses of ecosystems to air-borne pollutants and discusses the use of animals as indicators of ecosystem responses to these pollutants. Animal species and populations can act as important indicators of biotic and abiotic responses of aquatic and terrestrial ecosystems. These responses can indicate long-term trends in ecosystem health and productivity, chemical cycling, genetics, and regulation. For short-term trends, fish and wildlife also serve as monitors of changes in community structure, signaling food-web contamination, as well as providing a measure of ecosystem vitality. Information is presented to show not only the importance of animals as indicators of ecosystem responses to air-quality degradation, but also their value as air-pollution indices, that is, as air-quality-related values (AQRV), required in current air-pollution regulation.

Environmental Management↗
USGS2012

Evaluating the accotink creek restoration project for improving water quality, in-stream habitat, and bank stability

Increased urbanization results in a larger percentage of connected impervious areas and can contribute large quantities of stormwater runoff and significant quantities of debris and pollutants (e.g., litter, oils, microorganisms, sediments, nutrients, organic matter, and heavy metals) to receiving waters. To improve water quality in urban and suburban areas, watershed managers often incorporate best management practices (BMPs) to reduce the quantity of runoff as well as to minimize pollutants and other stressors contained in stormwater runoff. It is well known that land-use practices directly impact urban streams. Stream flows in urbanized watersheds increase in magnitude as a function of impervious area and can result in degradation of the natural stream channel morphology affecting the physical, chemical, and biological integrity of the stream. Stream bank erosion, which also increases with increased stream flows, can lead to bank instability, property loss, infrastructure damage, and increased sediment loading to the stream. Increased sediment loads may lead to water quality degradation downstream and have negative impacts on fish, benthic invertebrates, and other aquatic life. Accotink Creek is in the greater Chesapeake Bay and Potomac watersheds, which have strict sediment criteria. The USEPA (United States Environmental Protection Agency) and USGS (United States Geological Survey) are investigating the effectiveness of stream restoration techniques as a BMP to decrease sediment load and improve bank stability, biological integrity, and in-stream water quality in an impaired urban watershed in Fairfax, Virginia. This multi-year project continuously monitors turbidity, specific conductance, pH, and water temperature, as well as biological and chemical water quality parameters. In addition, physical parameters (e.g., pebble counts, longitudinal and cross sectional stream surveys) were measured to assess geomorphic changes associated with the restoration. Data from the pre-construction and initial post-construction phases are presented in this report. ?? 2007 ASCE.

Conference Paper↗
USGS1993

Hydrocarbons in oil residues on beaches of islands of Prince William Sound, Alaska

Aliphatic and aromatic hydrocarbons were measured on oil residues from beaches on six islands in Prince William Sound, Alaska. In addition to altered products from the Exxon Valdez oil spill of 1989, we also found, at two widely separated locations, residues that are similar to each other but chemically distinct from the spilled oil. Terpanes, steranes, monoaromatic steranes, and carbon isotopic compositions of total extracts were most useful in correlating the altered products of the spilled oil. These same parameters revealed that the two non-Valdez samples are likely residues of oil originally produced in California. The results indicate that oil residues currently on the beaches of this estuary have at least two quite different origins.

Marine Pollution Bulletin↗
USGS1965

Reconnaissance of the chemical quality of surface waters of the Sabine River Basin, Texas and Louisiana

The Sabine River basin has an abundant supply .of surface water of excellent quality. The basin area of 9,700 square miles receives an average of about 48 inches of rainfall per year, of which about 13 inches flows to the Gulf of Mexico. Variations in the chemical quality of the surface waters in the Sabine River basin are caused principally by areal differences in geology and runoff; but industrial influences, particularly the disposal of oil-field brines, affect the quality in limited areas. Water having the least dissolved solids is found in the lower part of the basin, where rainfall is greatest. Water having higher values of hardness are found in the area of Cretaceous limestone, chalk, and marl in the northwestern part of the basin. Chloride concentrations are generally low except where streams are polluted by oil-field brines and localized natural saline inflow. Existing reservoirs in the basin contain water of excellent quality, and water to be stored in proposed reservoirs should be excellent.

Water Supply Paper↗
USGS2004

Molecular markers and their use in environmental organic geochemistry

Molecular markers are organic substances that carry information about sources of organic matter or contamination. The source/marker relation can be used to indicate the presence of a given source material (qualitative), or, under appropriate conditions, to estimate the amount of a source material (quantitative source apportionment) in the environment. Assemblages of markers can also be used as process probes. In this instance, systematic differences and/or similarities in the physical-chemical properties of markers are coupled with compositional changes in marker composition to infer the operation of natural processes. This paper provides an overview of what molecular markers are, what types of markers are present in the environment, the requirements for the use of markers, and some common applications. To illustrate how molecular markers can answer specific environmental questions, three case studies are presented. The first case study examines the impact of municipal waste on a large urban harbor (Boston Harbor). Linear alkylbenzenes (unreacted residues of linear alkylbenzenesulfonate surfactants) and coprostanol (a fecal indicator) provide information on the sources and likely transport pathways of municipal wastes in a complex hydrologic system. The marker data are also used to estimate the proportion of sewage-derived poly chlorinated biphenyls (PCBs) in polluted harbor sediments. The second case study concerns a portion of the continental shelf off southern California (Palos Verdes) where discharge of municipal wastewaters has led to extensive contamination of sediments and biota. Long-chain alkylbenzenes (surfactant residues), PCBs and the pesticide, DDT (dichlorodiphenyltrichloroethane), are used to develop sedimentation rate estimates for several time periods by molecular stratigraphy. These results, when combined with other information, allow conclusions to be drawn about the most likely transport pathway of sediments at the study site and to predict the fate of historically deposited contaminants. Finally, an investigation of a crude-oil spill in Bemidji, MN illustrates how monoaromatic hydrocarbons can be exploited as process probes, providing insights into the relative importance of different attenuation processes in a contaminated aquifer. The results show that natural attenuation of the monoaromatic hydrocarbons is occurring at this site and is dominated, not by physical and/or chemical processes, but by biodegradation.

Book chapter↗
USGS1977

Impact of estuarine pollution on birds

Pollution of estuaries affects bird populations indirectly through changes in habitat and food supply. The multi-factor pollution of Chesapeake Bay has resulted in diminution of submerged aquatic plants and consequent change in food habits of the canvasback duck. Although dredge-spoil operations can improve wildlife habitat, they often result in its demise. Pollution of estuaries also affects birds directly, through chemical toxication, which may result in outright mortality or in reproductive impairment. Lead from industrial sources and roadways enters the estuaries and is accumulated in tissues of birds. Lead pellets deposited in estuaries as a result of hunting are consumed by ducks with sufficient frequency .to result m large annual die-offs from lead poisoning. Fish in certain areas, usually near industrial sources, may contain levels of mercury high enough to be hazardous to birds that consume them. Other heavy metals are present in estuarine birds, but their significance is poorly known. Oil exerts lethal or sublethal effects on birds by oiling their feathers, oiling eggs and young by contaminated parents, and by ingestion of oil-contaminated food. Organochlorine chemicals, of both agricultural and industrial origin, travel through the food chains and reach harmful levels in susceptible species of birds in certain estuarine ecosystems. Both outright mortality and reproductive impairment have occurred.

Book chapter↗