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At least 19 recordsLinked to original sources
USGS2012

Ocean-atmosphere dynamics during Hurricane Ida and Nor'Ida: An application of the coupled ocean-;atmosphere–wave–sediment transport (COAWST) modeling system

The coupled ocean–atmosphere–wave–sediment transport (COAWST) modeling system was used to investigate atmosphere–ocean–wave interactions in November 2009 during Hurricane Ida and its subsequent evolution to Nor'Ida, which was one of the most costly storm systems of the past two decades. One interesting aspect of this event is that it included two unique atmospheric extreme conditions, a hurricane and a nor'easter storm, which developed in regions with different oceanographic characteristics. Our modeled results were compared with several data sources, including GOES satellite infrared data, JASON-1 and JASON-2 altimeter data, CODAR measurements, and wave and tidal information from the National Data Buoy Center (NDBC) and the National Tidal Database. By performing a series of numerical runs, we were able to isolate the effect of the interaction terms between the atmosphere (modeled with Weather Research and Forecasting, the WRF model), the ocean (modeled with Regional Ocean Modeling System (ROMS)), and the wave propagation and generation model (modeled with Simulating Waves Nearshore (SWAN)). Special attention was given to the role of the ocean surface roughness. Three different ocean roughness closure models were analyzed: DGHQ (which is based on wave age), TY2001 (which is based on wave steepness), and OOST (which considers both the effects of wave age and steepness). Including the ocean roughness in the atmospheric module improved the wind intensity estimation and therefore also the wind waves, surface currents, and storm surge amplitude. For example, during the passage of Hurricane Ida through the Gulf of Mexico, the wind speeds were reduced due to wave-induced ocean roughness, resulting in better agreement with the measured winds. During Nor'Ida, including the wave-induced surface roughness changed the form and dimension of the main low pressure cell, affecting the intensity and direction of the winds. The combined wave age- and wave steepness-based parameterization (OOST) provided the best results for wind and wave growth prediction. However, the best agreement between the measured (CODAR) and computed surface currents and storm surge values was obtained with the wave steepness-based roughness parameterization (TY2001), although the differences obtained with respect to DGHQ were not significant. The influence of sea surface temperature (SST) fields on the atmospheric boundary layer dynamics was examined; in particular, we evaluated how the SST affects wind wave generation, surface currents and storm surges. The integrated hydrograph and integrated wave height, parameters that are highly correlated with the storm damage potential, were found to be highly sensitive to the ocean surface roughness parameterization.

Ocean Modelling↗
USGS2022

Estimating the pelagic ocean’s benefits to humanity can enhance ocean governance

The human footprint on the global ocean is ever-increasing, particularly with new ways to grow food in the ocean, new technologies in marine energy production as a way to resolve climate change, and transport and commerce expanding across the ocean. Yet, human activities in the ocean have long been managed using a sectoral approach (e.g., fisheries, biodiversity protection, energy production, shipping) rather than a holistic integration of sector interactions, trade-offs, costs, and benefits. Coordination across sectors is now more critical than ever, not only because of the expanding human footprint but also because of climate change impacts on the ocean. Sustainable global ocean use can support the Blue Economy while also reversing negative climate impacts on the ocean. Advancements in science and technology, along with increasing momentum on global commitments to sound ocean governance, and science diplomacy internationally can support sustainable ocean use with accurate and timely information about the status and trends in the ocean’s ecosystem services (benefits) to society. Near-real time information about ecosystem services’ dynamics is critical to policymaking for a sustainable Blue Economy that works for nature and people in an ever-changing ocean. Here, we propose seven principles for ecosystem service assessments, essentially to international science diplomacy, for consideration by global marine policy communities.

Marine Policy↗
USGS2011

Genetic discontinuity among regional populations of Lophelia perfusa in the North Atlantic Ocean

Knowledge of the degree to which populations are connected through larval dispersal is imperative to effective management, yet little is known about larval dispersal ability or population connectivity in Lophelia pertusa, the dominant framework-forming coral on the continental slope in the North Atlantic Ocean. Using nine microsatellite DNA markers, we assessed the spatial scale and pattern of genetic connectivity across a large portion of the range of L. pertusa in the North Atlantic Ocean. A Bayesian modeling approach found four distinct genetic groupings corresponding to ocean regions: Gulf of Mexico, coastal southeastern U.S., New England Seamounts, and eastern North Atlantic Ocean. An isolation-by-distance pattern was supported across the study area. Estimates of pairwise population differentiation were greatest with the deepest populations, the New England Seamounts (average FST = 0.156). Differentiation was intermediate with the eastern North Atlantic populations (FST = 0.085), and smallest between southeastern U.S. and Gulf of Mexico populations (FST = 0.019), with evidence of admixture off the southeastern Florida peninsula. Connectivity across larger geographic distances within regions suggests that some larvae are broadly dispersed. Heterozygote deficiencies were detected within the majority of localities suggesting deviation from random mating. Gene flow between ocean regions appears restricted, thus, the most effective management scheme for L. pertusa involves regional reserve networks

Conservation Genetics↗
USGS1983

Hafnium isotope results from mid-ocean ridges and Kerguelen

176Hf/177Hf ratios are presented for oceanic volcanics representing both extremes of the range of mantle HfNdSr isotopic variation. Hf from critical mid-ocean ridgebasalts shows that 176Hf/177Hf does indeed have a greater variability than 143Nd/144Nd and 87Sr/86Sr in the depleted mantle. This extra variation is essentially of a random nature, and can perhaps be understood in terms of known Rb/SrSm/NdLu/Hf fractionation relationships. At the other extreme of mantle isotopic composition, 176Hf/177Hf ratios for igneous rocks from the Indian Ocean island of Kerguelen show a closely similar variation to published 143Nd/144Nd ratios for the same samples. Comparison of HfNdSr c relationships for Tristan da Cunha, Kerguelen and Samoa reveals divergences in the mantle array for ocean island magma sources, and perhaps suggests that these irregularities are largely the result of an extra component of 87Sr/86Sr variation. ?? 1983.

LITHOS↗
USGS2020

Step increase in eastern U.S. precipitation linked to Indian Ocean warming

A step increase in annual precipitation over the eastern U.S. in the early 1970’s commenced five decades of invigorated hydroclimate, with ongoing impacts on streamflow and water resources. Despite its far-reaching impacts, the dynamical origin of this change is unknown. Here, analyses of a century of atmospheric and oceanic data trace the dynamics to changes in the Indian Ocean. Spring and fall precipitation explain more than half the annual eastern-U.S. precipitation variance over the century, and changes in fall are predominantly responsible for the step increase. The driving mechanism is emergence of a pan-Pacific atmospheric wave emanating from deep convection over the warming Indian Ocean. Documentation of this fall teleconnection draws attention to projected anthropogenic increases in tropical oceanic heat content, and their potential impacts on hydroclimate of the midlatitudes.

Geophysical Research Letters↗
USGS2017

It is the time for oceanic seabirds: Tracking year-round distribution of gadfly petrels across the Atlantic Ocean

Aim Anthropogenic activities alter and constrain the structure of marine ecosystems with implications for wide-ranging marine vertebrates. In spite of the environmental importance of vast oceanic ecosystems, most conservation efforts mainly focus on neritic areas. To identify relevant oceanic areas for conservation, we assessed the year-round spatial distribution and spatio-temporal overlap of eight truly oceanic seabird species of gadfly petrels ( Pterodroma spp.) inhabiting the Atlantic Ocean. Location Atlantic Ocean. Methods Using tracking data (mostly from geolocators), we examined year-round distributions, the timing of life-cycle events, and marine habitat overlap of eight gadfly petrel species that breed in the Atlantic Ocean. Results We compiled 125 year-round tracks. Movement strategies ranged from non-migratory to long-distance migrant species and from species sharing a common non-breeding area to species dispersing among multiple non-breeding sites. Gadfly petrels occurred throughout the Atlantic Ocean but tended to concentrate in subtropical regions. During the boreal summer, up to three species overlapped spatio-temporally over a large area around the Azores archipelago. During the austral summer, up to four species coincided in a core area in subtropical waters around Cape Verde, and three species shared habitat over two distinct areas off Brazil. The petrels used many national Exclusive Economic Zones, although they also exploited offshore international waters. Main conclusions Tracking movements of highly mobile vertebrates such as gadfly petrels can provide a powerful tool to evaluate and assess the potential need for and location of protected oceanic areas. As more multispecies, year-round data sets are collected from wide-ranging vertebrates, researchers and managers will have greater insight into the location of biodiversity hotspots. These can subsequently inform and guide marine spatial planning efforts that account for both conservation and sustainable use of resources such as commercial fisheries.

Diversity and Distributions↗
USGS2010

Methane hydrate-bearing seeps as a source of aged dissolved organic carbon to the oceans

Marine sediments contain about 500–10,000 Gt of methane carbon1, 2, 3, primarily in gas hydrate. This reservoir is comparable in size to the amount of organic carbon in land biota, terrestrial soils, the atmosphere and sea water combined1, 4, but it releases relatively little methane to the ocean and atmosphere5. Sedimentary microbes convert most of the dissolved methane to carbon dioxide6, 7. Here we show that a significant additional product associated with microbial methane consumption is methane-derived dissolved organic carbon. We use Δ14C and δ13C measurements and isotopic mass-balance calculations to evaluate the contribution of methane-derived carbon to seawater dissolved organic carbon overlying gas hydrate-bearing seeps in the northeastern Pacific Ocean. We show that carbon derived from fossil methane accounts for up to 28% of the dissolved organic carbon. This methane-derived material is much older, and more depleted in 13C, than background dissolved organic carbon. We suggest that fossil methane-derived carbon may contribute significantly to the estimated 4,000–6,000 year age of dissolved organic carbon in the deep ocean8, and provide reduced organic matter and energy to deep-ocean microbial communities.

Nature Geoscience↗
USGS2013

USGS Arctic Ocean carbon cruise 2010: field activity H-03-10-AR to collect carbon data in the Arctic Ocean, August - September 2010

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form carbonic acid, a weak, naturally occurring acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗
USGS2013

USGS Arctic Ocean carbon cruise 2011: field activity H-01-11-AR to collect carbon data in the Arctic Ocean, August - September 2011

Carbon dioxide (CO 2 ) in the atmosphere is absorbed at the surface of the ocean by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution (Sabine and others, 2004). Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Caldeira and Wickett, 2003; Orr and others, 2005; Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO 2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats (Raven and others, 2005; Ruttiman, 2006). The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Data Series↗
USGS2010

Monitoring and assessment of ocean acidification in the Arctic Ocean-A scoping paper

Carbon dioxide (CO2) in the atmosphere is absorbed at the ocean surface by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution. Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats. The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

Open-File Report↗
USGS2013

Ocean climate indicators: A monitoring inventory and plan for tracking climate change in the north-central California coast and ocean region

The impacts of climate change, defined as increasing atmospheric and oceanic carbon dioxide and associated increases in average global temperature and oceanic acidity, have been observed both globally and on regional scales, such as in the North-central California coast and ocean, a region that extends from Point Arena to Point Año Nuevo and includes the Pacific coastline of the San Francisco Bay Area. Because of the high economic and ecological value of the region’s marine environment, the Gulf of the Farallones National Marine Sanctuary (GFNMS) and other agencies and organizations have recognized the need to evaluate and plan for climate change impacts. Climate change indicators can be developed on global, regional, and site-specific spatial scales, and they provide information about the presence and potential impacts of climate change. While indicators exist for the nation and for the state of California as a whole, no system of ocean climate indicators exist that specifically consider the unique characteristics of the California coast and ocean region. To that end, GFNMS collaborated with over 50 regional, federal, and state natural resource managers, research scientists, and other partners to develop a set of 2 ocean climate indicators specific to this region. A smaller working group of 13 regional partners developed monitoring goals, objectives, strategies, and activities for the indicators and recommended selected species for biological indicators, resulting in the Ocean Climate Indicators Monitoring Inventory and Plan. The working group considered current knowledge of ongoing monitoring, feasibility of monitoring, costs, and logistics in selecting monitoring activities and selected species.

Report↗
USGS2025

Investigating hurricane-induced salt variation across the Land-Estuary-Ocean continuum using a dynamically coupled hydrological-ocean model

Salinity variations across the Land‐Estuary‐Ocean (LEO) continuum are critical for coastal ecosystems and impact the socioeconomic benefits to local communities. However, evaluating these variations is challenging due to the complex interactions of terrestrial and oceanic processes, including river discharge, winds, tides, sea level rise, and storms. This study incorporates a salinity module into a newly developed dynamically coupled hydrological‐ocean model on the COAWST platform, which is, to the best of our knowledge, the first process‐based modeling that achieves seamless two‐way land‐ocean water and salt exchanges across the LEO continuum, facilitating simulations of landward salt input and transport. Using Hurricane Florence (2018) as a case study, we examined how various physical processes influence salinity dynamics and freshwater plume development in the Cape Fear River Estuary, North Carolina. The model simulated saltwater intrusion into freshwater wetlands upstream of the estuary and demonstrated that salinity in the estuary was initially regulated by wind‐driven water level gradients, followed by a dominant influence from significant river runoff. In the coastal ocean, runoff created a large freshwater plume that moved westward, driven by the interplay between runoff, winds, and the estuary's geomorphology. The excellent performance of the coupling approach for salinity simulation underscores the importance of the seamless transport of water and salt at the land‐ocean interface. This study demonstrates that the coupled model is a valuable tool for representing saltwater intrusion, tracking coastal pollutants, and understanding water and material exchange across the LEO continuum.

North Carolina, South Carolina↗
USGS2022

Analysis of ocean dynamics during the impact of Hurricane Matthew using ocean-atmosphere coupling

The main goal of this investigation is to improve the understanding of ocean-atmosphere coupling during hurricanes. The present work involves the integration of the ocean-atmosphere coupled components of the Coupled Ocean-Atmosphere-Wave-Sediment Transport Modeling System in the Very Short Term Prediction System (SisPI). Three experiments are performed: First, using a dynamic sea surface temperature, consistent with the daily updated atmospheric model Weather Research and Forecast (SisPI); second, using the Regional Oceanic Modeling System and third, using a dynamic coupling between the atmospheric and the oceanic models. The coupled system improves the tracks of the hurricane simulations respect to the SisPI. The use of the oceanic model allows a more detailed representation of the sea surface temperature. Using the coupled model, a more precise diurnal cycle of the surface net heat fluxes is obtained.

Cuban Journal of Meteorology (Revista Cubana de Me↗
USGS2008

Ocean forecasting in terrain-following coordinates: Formulation and skill assessment of the Regional Ocean Modeling System

Systematic improvements in algorithmic design of regional ocean circulation models have led to significant enhancement in simulation ability across a wide range of space/time scales and marine system types. As an example, we briefly review the Regional Ocean Modeling System, a member of a general class of three-dimensional, free-surface, terrain-following numerical models. Noteworthy characteristics of the ROMS computational kernel include: consistent temporal averaging of the barotropic mode to guarantee both exact conservation and constancy preservation properties for tracers; redefined barotropic pressure-gradient terms to account for local variations in the density field; vertical interpolation performed using conservative parabolic splines; and higher-order, quasi-monotone advection algorithms. Examples of quantitative skill assessment are shown for a tidally driven estuary, an ice-covered high-latitude sea, a wind- and buoyancy-forced continental shelf, and a mid-latitude ocean basin. The combination of moderate-order spatial approximations, enhanced conservation properties, and quasi-monotone advection produces both more robust and accurate, and less diffusive, solutions than those produced in earlier terrain-following ocean models. Together with advanced methods of data assimilation and novel observing system technologies, these capabilities constitute the necessary ingredients for multi-purpose regional ocean prediction systems.

Journal of Computational Physics↗
USGS2001

Regional variations in provenance and abundance of ice-rafted clasts in Arctic Ocean sediments: Implications for the configuration of late Quaternary oceanic and atmospheric circulation in the Arctic

The composition and distribution of ice-rafted glacial erratics in late Quaternary sediments define the major current systems of the Arctic Ocean and identify two distinct continental sources for the erratics. In the southern Amerasia basin up to 70% of the erratics are dolostones and limestones (the Amerasia suite) that originated in the carbonate-rich Paleozoic terranes of the Canadian Arctic Islands. These clasts reached the Arctic Ocean in glaciers and were ice-rafted to the core sites in the clockwise Beaufort Gyre. The concentration of erratics decreases northward by 98% along the trend of the gyre from southeastern Canada basin to Makarov basin. The concentration of erratics then triples across the Makarov basin flank of Lomonosov Ridge and siltstone, sandstone and siliceous clasts become dominant in cores from the ridge and the Eurasia basin (the Eurasia suite). The bedrock source for the siltstone and sandstone clasts is uncertain, but bedrock distribution and the distribution of glaciation in northern Eurasia suggest the Taymyr Peninsula-Kara Sea regions. The pattern of clast distribution in the Arctic Ocean sediments and the sharp northward decrease in concentration of clasts of Canadian Arctic Island provenance in the Amerasia basin support the conclusion that the modem circulation pattern of the Arctic Ocean, with the Beaufort Gyre dominant in the Amerasia basin and the Transpolar drift dominant in the Eurasia basin, has controlled both sea-ice and glacial iceberg drift in the Arctic Ocean during interglacial intervals since at least the late Pleistocene. The abruptness of the change in both clast composition and concentration on the Makarov basin flank of Lomonosov Ridge also suggests that the boundary between the Beaufort Gyre and the Transpolar Drift has been relatively stable during interglacials since that time. Because the Beaufort Gyre is wind-driven our data, in conjunction with the westerly directed orientation of sand dunes that formed during the last glacial maximum on the North Slope of Alaska, suggests that atmospheric circulation in the western Arctic during late Quaternary was similar to that of the present. ?? 2001 Elsevier Science B.V.

Marine Geology↗
USGS2017

Advancing coastal ocean modelling, analysis, and prediction for the US Integrated Ocean Observing System

This paper outlines strategies that would advance coastal ocean modelling, analysis and prediction as a complement to the observing and data management activities of the coastal components of the US Integrated Ocean Observing System (IOOS®) and the Global Ocean Observing System (GOOS). The views presented are the consensus of a group of US-based researchers with a cross-section of coastal oceanography and ocean modelling expertise and community representation drawn from Regional and US Federal partners in IOOS. Priorities for research and development are suggested that would enhance the value of IOOS observations through model-based synthesis, deliver better model-based information products, and assist the design, evaluation, and operation of the observing system itself. The proposed priorities are: model coupling, data assimilation, nearshore processes, cyberinfrastructure and model skill assessment, modelling for observing system design, evaluation and operation, ensemble prediction, and fast predictors. Approaches are suggested to accomplish substantial progress in a 3–8-year timeframe. In addition, the group proposes steps to promote collaboration between research and operations groups in Regional Associations, US Federal Agencies, and the international ocean research community in general that would foster coordination on scientific and technical issues, and strengthen federal–academic partnerships benefiting IOOS stakeholders and end users.

Journal of Operational Oceanography↗
USGS2022

Deep-ocean polymetallic nodules and cobalt-rich ferromanganese crusts in the global ocean: New sources for critical metals

The transition from a global hydrocarbon economy to a green energy economy and the rapidly growing middle class in developing countries are driving the need for considerable new sources of critical materials. Deep-ocean minerals, namely cobalt-rich ferromanganese crusts and polymetallic nodules, are two such new resources generating interest. Polymetallic nodules are essentially two-dimensional mineral deposits sitting on abyssal plain sediments at about 3,500–6,000 m water depths. Metals of economic interest enriched in nodules include nickel, copper, manganese, cobalt and molybdenum. Cobalt-rich ferromanganese crusts are also two-dimensional deposits forming pavements on rock outcrops on seamounts and ridges at water depths of 400–7,000 m. Metals of economic interest for crusts include cobalt, manganese, nickel, molybdenum, tellurium, platinum, vanadium and rare earth elements. A conservative estimate is that 21.1 billion dry tons of polymetallic nodules exist in the Clarion-Clipperton Zone ( CCZ ) manganese nodule field, the largest in area and tonnage of the known global nodule fields. Based on that estimate, tonnages of many critical metals in the CCZ nodules are greater than those found in global terrestrial reserves. About 7.5 billion dry tons of cobalt-rich ferromanganese crusts are estimated to occur in the Pacific Ocean Prime Crust Zone, the area with the highest tonnage of critical-metal-rich crust deposits, with many elements contained therein estimated to be greater than those found in global terrestrial reserves. Deep-ocean mining has not yet been carried out in the Exclusive Economic Zone of any nation, nor in the Areas beyond national jurisdiction, although extensive mineral exploration and environmental studies are being conducted and exploitation regulations codified, indicating that mining activities will likely begin in the near future. If deep-ocean mining follows the evolution of offshore production of petroleum, we can expect that about 35–45 per cent of the demand for critical metals will come from deep-ocean mines by 2065.

Book chapter↗
USGS1994

Zinc, copper, and lead in mid-ocean ridge basalts and the source rock control on Zn/Pb in ocean-ridge hydrothermal deposits

The contents of Zn, Cu, and Pb in mid-ocean ridge basalts (MORB) and the MORB source-rock control on Zn/Pb in ocean-ridge hydrothermal deposits are examined. The values of Zn, Cu, and Pb for submarine mid-ocean ridge basalts (MORB) are, respectively (in ppm): average MORB—75, 75, and 0.7; West Valley, Juan de Fuca Ridge (JFR)—87, 64, and 0.5; southern JFR—120 and 0.5; and 21°N, East Pacific Rise (EPR)—73, 78, and 0.5. Values of Zn/Pb range from about 100–240 and Cu/ Pb from 100–156. In this study, Zn is found to correlate positively with TiO 2 + FeO (mean square of weighted deviates, MSWD, of 1.6 for JFR basalt), and inversely with Mg number (MSWD of 3.5). Therefore, contrary to statements in the literature that Zn should be compatible in MORB, Zn is a mildly incompatible element and must be enriched in the glass phase relative to olivine as Zn does not fit into the other major phenocryst phase, plagioclase. In the source of MORB, Zn likely is most enriched in oxides: spinel, magnetite, and titanomagnetite. Copper generally does not correlate well with other elements in most MORB data examined. When differentiation is dominated by olivine, Cu has a tendency to behave incompatibly (e.g., at Mg numbers > 70), but, overall, Cu shows some tendency towards being a compatible element, particularly along the Mid-Atlantic Ridge, a behavior presumably due to separation of sulfides in which Cu (but not Zn) is markedly enriched. Copper thus may be in dispersed sulfides in the source of MORB. Ocean ridges provide important data on source-rock controls for sulfide deposits because, in sediment-starved ridges, much is known about the possible source rocks and mineralization is presently occurring. In contrast to Zn/Pb ~5 in continental hot Cl-rich brines, Zn/Pb in the hottest sediment-starved ridge black smoker hydrothermal fluids at 21 °N, EPR is about 110, similar to local MORB (145), but Cu/Pb is closer to 30, possibly due to subsurface deposition of Cu. At the JFR, the best value of Zn/Pb in the hydrothermal fluids is about 175, again similar to local MORB (240), but Cu is very low in the fluids that are at temperatures less than 300°C. The large MORB-like Zn/Pb in the hottest black-smoker fluids suggests a source-rock control for the metals that prohibits significant galena in the black-smoker deposits of sediment-starved ridges. In contrast, exhalative deposits on sediment-swamped ridges have significant galena; its presence is suggestive of Pb derivation from sediments, an origin supported by Pb isotope studies of LeHuray and colleagues in 1988.

Geochimica et Cosmochimica Acta↗