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The Meteoritical Bulletin, no. 83, 1999 July

Meteoritical Bulletin No. 83 lists information for 898 newly described meteorites. These include 473 from Antarctica, 341 from the Sahara, and 22 from dry lakes in the southwestern United States. Seven of the meteorites are falls: Kunya-Urgench (H5), Lohawat (howardite), Ourique (H4), Portales Valley (H6), San Pedro de Quiles (L6), Talampaya (eucrite), and Zag (H3-6). Also included are a dozen new iron meteorites; several mesosiderites; a pallasite; several HED meteorites; several ureilites; a variety of CM, CO, CV, CR, and R chondrites; and numerous unequilibrated ordinary chondrites. All shock classifications are after Stöffler et al. (1991) and weathering grades are after Wlotzka (1993), except as noted. All italicized abbreviations refer to addresses tabulated at the end of this document.

Meteoritics & Planetary Science (MAPS)

Sedimentological and petrographic analysis of drill core FC77-1 from the flank of the central uplift, Flynn Creek impact structure, Tennessee

Drill core FC 77‐1 on the flank of the central uplift, Flynn Creek impact structure, Tennessee, contains 175 m of impact breccia lying upon uplifted Lower Paleozoic carbonate target stratigraphy. Sedimentological analysis of this 175‐m interval carbonate breccia shows that there are three distinct sedimentological units. In stratigraphic order, unit 1 (175–109 m) is an overall coarsening‐upward section, whereas the overlying unit 2 (109–32 m) is overall fining‐upward. Unit 3 (32–0 m) is a coarsening‐upward sequence that is truncated at the top by postimpact erosion. Units 1 and 3 are interpreted as debris or rock avalanches into finer sedimentary deposits within intracrater marine waters, thus producing progressively coarser, coarsening‐upward sequences. Unit 2 is interpreted to have formed by debris or rock avalanches into standing marine waters, thus forming sequential fining‐upward deposits. Line‐logging of clasts ranging from 5 mm to 1.6 m, and thin‐section analysis of selected drill core samples (including clasts < 5 mm), both show that the Flynn Creek impact breccia consists almost entirely of dolostone clasts (90%), with minor components of cryptocrystalline melt clasts, chert and shale fragments, and clastic grains. Cryptocrystalline melt clasts, which appear isotropic in thin section, are in fact made of exceedingly fine quartz crystals that exhibit micro‐Fourier transform infrared (FTIR ) and micro‐Raman spectra consistent with crystalline quartz. These cryptocrystalline melt clasts are the first melt clasts of any kind to be reported from Flynn Creek impact structure.

Tennessee

Using the potassium-argon laser experiment (KArLE) to date ancient, low-K chondritic meteorites

Several laboratories have been investigating the feasibility of in situ K-Ar dating for use in future landing planetary missions. One drawback of these laboratory demonstrations is the insufficient analogy of the analyzed analog samples with expected future targets. We present the results obtained using the K-Ar laser experiment (KArLE) on two old and K-poor chondritic samples, Pułtusk and Hvittis, as better lunar analogs. The KArLE instrument uses laser ablation to vaporize rock samples and quantifies K content by laser-induced breakdown spectroscopy (LIBS), Ar by quadrupole mass spectrometry (QMS), and ablated mass by laser profilometry. We performed 64 laser ablations on the chondrites to measure spots with a range of K 2 O and Ar content and used the data to construct isochrons to determine the chondrite formation age. The KArLE isochron ages on Pułtusk and Hvittis are 5059 ± 892 Ma and 4721 ± 793 Ma, respectively, which is within the uncertainty of published reference ages, and interpreted as the age of their formation. The uncertainty (2 σ ) on the KArLE ages obtained in this study is better than 20% (18% for Pułtusk and 17% for Hvittis). The precision, which compares our obtained ages to the reference ages, is also better than 20% (11% for Pułtusk and 4% for Hvittis). These results are encouraging for understanding the limits of this technique to measure ancient planetary samples and for guiding future improvements to the instrument.

Meteoritics & Planetary Science (MAPS)

Neutron absorption constraints on the composition of 4 Vesta

Global maps of the macroscopic thermal neutron absorption cross section of Vesta's regolith by the Gamma Ray and Neutron Detector (GRaND) on board the NASA Dawn spacecraft provide constraints on the abundance and distribution of Fe, Ca, Al, Mg, and other rock-forming elements. From a circular, polar low-altitude mapping orbit, GRaND sampled the regolith to decimeter depths with a spatial resolution of about 300 km. At this spatial scale, the variation in neutron absorption is about seven times lower than that of the Moon. The observed variation is consistent with the range of absorption for howardite whole-rock compositions, which further supports the connection between Vesta and the howardite, eucrite, and diogenite meteorites. We find a strong correlation between neutron absorption and the percentage of eucritic materials in howardites and polymict breccias, which enables petrologic mapping of Vesta's surface. The distribution of basaltic eucrite and diogenite determined from neutron absorption measurements is qualitatively similar to that indicated by visible and near infrared spectroscopy. The Rheasilvia basin and ejecta blanket has relatively low absorption, consistent with Mg-rich orthopyroxene. Based on a combination of Fe and neutron absorption measurements, olivine-rich lithologies are not detected on the spatial scales sampled by GRaND. The sensitivity of GRaND to the presence of mantle material is described and implications for the absence of an olivine signature are discussed. High absorption values found in Vesta's “dark” hemisphere, where exogenic hydrogen has accumulated, indicate that this region is richer in basaltic eucrite, representative of Vesta's ancient upper crust.

Meteoritics and Planetary Science

Abstracts of the annual Planetary Geologic Mappers Meeting, June 18-19, 2001, Albuquerque, New Mexico

The annual Planetary Geologic Mappers Meeting serves two purposes. In addition to giving mappers the opportunity to exchange ideas, experiences, victories, and problems with others, presentations are reviewed by the Geologic Mapping Subcommittee (GeMS) to provide input to the Planetary Geology and Geophysics Mapping Program review panel’s consideration of new proposals and progress reports that include mapping tasks. Funded mappers bring both oral presentation materials (slides or viewgraphs) and map products to post for review by GeMS and fellow mappers. Additionally, the annual meetings typically feature optional field trips offering earth analogs and parallels to planetary mapping problems. The 2001 Mappers Meeting, June 18-19, was convened by Tim Parker, Dave Senske, and Ken Tanaka and was hosted by Larry Crumpler and Jayne Aubele of the New Mexico Museum of Natural History and Science in Albuquerque, New Mexico. Oral presentations were given in the Museum’s Honeywell Auditorium, and maps were posted in the Sandia Room. In addition to active mappers, guests included local science teachers who had successfully competed for the right to attend and listen to the reports. It was a unique pleasure for mappers to have the opportunity to interact with and provide information to teachers responding so enthusiastically to the meeting presentation. On Sunday, June 17, Larry and Jayne conducted an optional pre-meeting field trip. The flanks of Rio Grande Rift, east and west of Albuquerque and Valles Caldera north of town presented tectonic, volcanic, and sedimentary examples of the Rift and adjoining areas analogous to observed features on Mars and Venus. The arid but volcanically and tectonically active environment of New Mexico’s rift valley enables focus on features that appear morphologically young and spectacular in satellite images and digital relief models. The theme of the trip was to see what, at orbiter resolution, "obvious" geologic features look like at lander (outcrop) scales. Trips to the top of the rift-flanking mountains (Sandia Peak, 10,600 ft) and the Valles Caldera, as well as various active spring deposits highlighted the day. After welcoming remarks from the host, Larry Crumpler, opening remarks by Tim Parker and Dave Senske and a report on mapping program status by Ken Tanaka, the mappers’ oral presentations began the morning of June 18, with a session on Venus Geologic Mapping. The afternoon continued with an exciting USGS Planetary GIS on the Web (PIGWAD) demonstration and ended with an open discussion of issues in planetary mapping. Posted maps of Venus quadrangles were viewed during the morning break. Tuesday’s Mars Geologic Mapping session began with a pep talk from Tim Parker encouraging mapping community input to the MER landing site selection committee and continued with Steve Saunders describing the potential contribution of Odyssey Mission data to the geologic mapping of Mars. A Mars map poster session was held during the morning break, and the meeting was adjourned mid-afternoon. After the mappers meeting on Tuesday, attendants were treated to a "Field trip to Mars." The Institute of Meteoritics at the University of New Mexico houses an outstanding collection of meteorites, including those that have been identified as originating from Mars. The Institute tour featured examples of most of the different lithologies exhibited by martian meteorites identified to date, as well as some of the analytical tests (scanning electron microscope) they are conducting on specimens from ALH84001. Wednesday, June 20, featured an optional post-meeting field trip to see a travertine quarry and nearby sites of travertine deposition, the Very Large Array near Socorro, and other volcanic features within the Rio Grande Rift.

New Mexico

Bleached chondrules: Evidence for widespread aqueous processes on the parent asteroids of ordinary chondrites

We present the first detailed study of a population of texturally distinct chondrules previously described by Kurat (1969), Christophe Michel-Lévy (1976), and Skinner et al. (1989) that are sharply depleted in alkalis and Al in their outer portions. These “bleached” chondrules, which are exclusively radial pyroxene and cryptocrystalline in texture, have porous outer zones where mesostasis has been lost. Bleached chondrules are present in all type 3 ordinary chondrites and are present in lower abundances in types 4–6. They are most abundant in the L and LL groups, apparently less common in H chondrites, and absent in enstatite chondrites. We used x-ray mapping and traditional electron microprobe techniques to characterize bleached chondrules in a cross section of ordinary chondrites. We studied bleached chondrules from Semarkona by ion microprobe for trace elements and H isotopes, and by transmission electron microscopy. Chondrule bleaching was the result of low-temperature alteration by aqueous fluids flowing through finegrained chondrite matrix prior to thermal metamorphism. During aqueous alteration, interstitial glass dissolved and was partially replaced by phyllosilicates, troilite was altered to pentlandite, but pyroxene was completely unaffected. Calcium-rich zones formed at the inner margins of the bleached zones, either as the result of the early stages of metamorphism or because of fluid-chondrule reaction. The mineralogy of bleached chondrules is extremely sensitive to thermal metamorphism in type 3 ordinary chondrites, and bleached zones provide a favorable location for the growth of metamorphic minerals in higher petrologic types. The ubiquitous presence of bleached chondrules in ordinary chondrites implies that they all experienced aqueous alteration early in their asteroidal histories, but there is no relationship between the degree of alteration and metamorphic grade. A correlation between the oxidation state of chondrite groups and their degree of aqueous alteration is consistent with the source of water being either accreted ices or water released during oxidation of organic matter. Ordinary chondrites were probably open systems after accretion, and aqueous fluids may have carried volatile elements with them during dehydration. Individual radial pyroxene and cryptocrystalline chondrules were certainly open systems in all chondrites that experienced aqueous alteration leading to bleaching.

Meteoritics and Planetary Science

Zoned chondrules in Semarkona: Evidence for high-and low-temperature processing

At least 15% of the low-FeO chondrules in Semarkona (LL3.0) have mesostases that are concentrically zoned in Na, with enrichments near the outer margins. We have studied zoned chondrules using electron microprobe methods (x-ray mapping plus quantitative analysis), ion microprobe analysis for trace elements and hydrogen isotopes, cathodoluminescence imaging, and transmission electron microscopy in order to determine what these objects can tell us about the environment in which chondrules formed and evolved. Mesostases in these chondrules are strongly zoned in all moderately volatile elements and H (interpreted as water). Calcium is depleted in areas of volatile enrichment. Titanium and Cr generally decrease toward the chondrule surfaces, whereas Al and Si may either increase or decrease, generally in opposite directions to one another; Mn follows Na in some chondrules but not in others; Fe and Mg are unzoned. D/H ratios increase in the water-rich areas of zoned chondrules. Mesostasis shows cathodoluminescence zoning in most zoned chondrules, with the brightest yellow color near the outside. Mesostasis in zoned chondrules appears to be glassy, with no evidence for devitrification. Systematic variations in zoning patterns among pyroxene- and olivine-rich chondrules may indicate that fractionation of low- and high-Ca pyroxene played some role in Ti, Cr, Mn, Si, Al, and some Ca zoning. But direct condensation of elements into hot chondrules, secondary melting of late condensates into the outer portions of chondrules, and subsolidus diffusion of elements into warm chondrules cannot account for the sub-parallel zoning profiles of many elements, the presence of H 2 O, or elemental abundance patterns. Zoning of moderately volatile elements and Ca may have been produced by hydration of chondrule glass without devitrification during aqueous alteration on the parent asteroid. This could have induced structural changes in the glass allowing rapid diffusion and exchange of elements between altered glass and surrounding matrix and rim material. Calcium was mainly lost during this process, and other nonvolatile elements may have been mobile as well. Some unzoned, low-FeO chondrules appear to have fully altered mesostasis.

Meteoritics and Planetary Science

The onset of metamorphism in ordinary and carbonaceous chondrites

Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by X-ray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO-rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr-rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr-rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr 3+ . Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re-enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to subdivide types 3.0 and 3.1 into types 3.00 through 3.15. On this basis, the most primitive ordinary chondrite known is Semarkona, although even this meteorite has experienced a small amount of metamorphism. Allan Hills (ALH) A77307 is the least metamorphosed CO chondrite and shares many properties with the ungrouped carbonaceous chondrite Acfer 094. Analytical problems are significant for glasses in type II chondrules, as Na is easily lost during microprobe analysis. As a result, existing schemes for chondrule classification that are based on the alkali content of glasses need to be revised.

Meteoritics and Planetary Science