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At least 19 recordsLinked to original sources

Inhibition of calcite precipitation by natural organic material: Kinetics, mechanism, and thermodynamics

The inhibition of calcite precipitation by natural organic material (NOM) in solutions seeded with calcite was investigated using a pH-stat system. Experiments were carried out using three NOMs with different physical/chemical properties. For each of the materials, inhibition was found to be more effective at lower carbonate/calcium ratios and lower pH values. The reduction in the precipitation rate could be explained by a Langmuir adsorption model using a conditional equilibrium constant. By identification of the type of site on the NOM molecules that is involved in the adsorption reaction, the "conditional" equilibrium constants obtained at different solution compositions converged to a single "nonconditional" value. The thermodynamic data determined at 25??C and 1 atm suggest that the interaction between NOM molecules and the calcite surface is chemisorptive in nature and that adsorption is an endothermic reaction driven by the entropy change. The greatest degree of inhibition was observed for the NOM with the highest molecular weight and aromatic carbon content. For a given type of NOM, the degree of inhibition of calcite precipitation was dictated by the balance between the enthalpy change and the entropy change of the adsorption reaction. ?? 2005 American Chemical Society.

Environmental Science & Technology

Biorecovery of gold

Recovery of ionic and metallic gold (Au) from a wide variety of solutions by selected species of bacteria, yeasts, fungi, algae, and higher plants is documented. Gold accumulations were up to 7.0 g/kg dry weight (DW) in various species of bacteria, 25.0 g/kg DW in freshwater algae, 84.0 g/kg DW in peat, and 100.0 g/kg DW in dried fungus mixed with keratinous material. Mechanisms of accumulation include oxidation, dissolution, reduction, leaching, and sorption. Uptake patterns are significantly modified by the physicochemical milieu. Crab exoskeletons accumulate up to 4.9 g Au/kg DW; however, gold accumulations in various tissues of living teleosts, decapod crustaceans, and bivalve molluscs are negligible.

Indian Journal of Experimental Biology

Velocity-porosity relations in carbonate and siliciclastic subduction zone input materials

The mechanical, physical, and frictional properties of incoming materials play an important role in subduction zone structure and slip behavior because these properties influence the strength of the accretionary wedge and megathrust plate boundary faults. Incoming sediment sections often show an increase in compressional wave speed (Vp) and a decrease in porosity with depth due to consolidation. These relations allow seismic-velocity models to be used to elucidate properties and conditions at depth. However, variations in these properties are controlled by lithology and composition as well as cementation and diagenesis. We present an analysis of shipboard measurements of Vp and porosity on incoming sediment cores from International Ocean Discovery Program (IODP) expeditions at the Hikurangi Margin, Nankai Trough, Aleutian Trench, Middle America Trench, and Sunda Trench. Porosity for these samples ranges from 5% to 85% and Vp ranges from 1.5 to 6 km/s. Vp-porosity relations developed by Erikson & Jarrad (1998), https://doi.org/10.1029/98JB02128 and Hoffman & Tobin (2004) https://10.2973/odp.proc.sr.190196.355.2004, with a critical porosity of ∼30%, can represent carbonate-poor (<50 wt% CaCO3), mainly hemipelagic, incoming sediment regardless of the margin. But these relations tend to underestimate porosity in incoming sediments with carbonate content greater than 50 wt%, which appear to have a critical porosity of between 45% and 50%. This discrepancy will lead to inaccuracy in estimates of fluid budget and overpressure in subduction zones. The velocity-porosity relation in carbonate sediments is non-unique due to the complexity that results from the greater susceptibility of carbonate rocks to diagenetic processes.

Geochemistry, Geophysics, Geosystems

Material properties and triggering mechanisms of an andesitic lava dome collapse at Shiveluch Volcano, Kamchatka, Russia, revealed using the finite element method

Shiveluch volcano (Kamchatka, Russia) is an active andesitic volcano with a history of explosive activity, dome extrusion, and structural collapse during the Holocene. The most recent major (> 1 km 3 ) dome collapse occurred in November 1964, producing a ~ 1.5 km 3 debris avalanche that traveled over 15 km from the vent and triggered a phreatic explosion followed by a voluminous (~ 0.8 km 3 ) eruption of juvenile pyroclastic material. Seismic records suggest that the collapse was likely triggered by a magnitude 5.1 earthquake associated with the ascent of magma into the edifice. The geomechanical properties of the pre-1964 dome are unknown; accordingly, the mechanics of the collapse are poorly understood. This project employs numerical slope stability modeling using the finite element method to constrain probable ranges of geomechanical properties for the materials involved in the collapse, considering earthquake loading as the most likely triggering mechanism. Model results show good agreement with the 1964 collapse geometry considering Geological Strength Index and horizontal pseudo-static seismic coefficient ranges of 30–60 and 0.05–0.15 g, respectively, representing variably fractured and altered dome rocks under moderate earthquake loading, confirming that ground acceleration alone could have triggered the dome collapse. Deep-seated rotational sliding is the dominant failure mode, but local extension within the dome during failure appears to play an important role in the development of the collapse. The findings of this work allow for better forward modeling of potential future collapses, the results of which can be incorporated into regional hazard and risk assessments.

Shiveluch Volcano

Discussion of “Case study: Oso, Washington, landslide of March 22, 2014-Material properties and failure mechanism” by Timothy D. Stark, Ahmed K. Baghdady, Oldrich Hungr, and Jordan Aaron

The original paper discusses factors that may have contributed to the occurrence and long runout of a disastrous landslide near the community of Oso, Washington, on March 22, 2014. The paper reinforces a prior finding that the long runout likely resulted from liquefaction of wet colluvium that was rapidly loaded by landslide debris impinging from upslope ( Iverson et al. 2015 ). However, the original paper proposes a landslide geometry and chronology that differ from those presented in previous reports, and these differences have implications for interpreting the landslide’s mechanics. The paper also includes factual errors as well as misrepresentations that result from selective inclusion and exclusion of findings previously reported by others. The purposes of this discussion are to place the original paper in context and to rectify some of its mistakes.

Washington

Submarine sliver in North Kona: A window into the early magmatic and growth history of Hualalai Volcano, Hawaii

Two manned submersible dives examined the Hualalai Northwest rift zone and an elongate ridge cresting at 3900 mbsl during a 2002 JAMSTEC cruise. The rift zone flank at dive site S690 (water depth 3412&ndash;2104 m) is draped by elongated and truncated pillow lavas. These olivine-rich tholeiitic lavas are compositionally indistinguishable from those examined further south along the bench, except that they span a wider range in dissolved sulfur content (200&ndash;1400 ppm). The elongate ridge investigated in dive S692, located at the base of the bench, is a package of distinct lithologic units containing volcaniclastic materials, glassy pillow breccias, and lava blocks; these units contain a range of compositions including tholeiitic basalt, transitional basalt, and hawaiite. The textures, compositions, and stratigraphic relationships of materials within the elongate ridge require that a variety of transport mechanisms juxtaposed materials from multiple eruptions into individual beds, compacted them into a coherent package of units, and brought the package to its present depth 10 km from the edge of the North Kona slump bench. Sulfur-rich hawaiite glasses at the base of the elongate ridge may represent the first extant representatives of juvenile alkalic volcanism at Hualalai. They are geochemically distinct from shield tholeiite and post-shield alkalic magmas, but may be related to transitional basalt by high-pressure crystal fractionation of clinopyroxene. Tholeiitic glasses that compose the majority of the exposed outcrop are similar to Mauna Kea tholeiites and other Hualalai tholeiites, but they differ from younger basalts in having greater incompatible element enrichments and higher CaO for a given MgO. These differences could arise from small extents of partial melting during the transition from alkalic to shield stage magmatism. Low sulfur contents of most of the volcaniclastic tholeiites point to early emergence of Hualalai above sea level relative to the development of the midslope slump bench.

Hawai'i

Mechanical properties of simulated Mars materials: gypsum-rich sandstones and lapilli tuff

Observations by the Mars Exploration Rover (MER) Opportunity, and other recent studies on diagenesis in the extensive equatorial layered deposits on Mars, suggest that the likely lithologies of these deposits are gypsum-rich sandstones and tuffaceous sediments (for example, Murchie and others, 2009; Squyres and others, 2012; Zimbelman and Scheidt, 2012). Of particular interest is how the diagenesis history of these sediments (degree of cementation and composition) influences the strength and brittle behavior of the material. For instance, fractures are more common in lower porosity materials under strain, whereas deformation bands, characterized by distributed strain throughout a broader discontinuity in a material, are common in higher porosity sedimentary materials. Such discontinuities can either enhance or restrict fluid flow; hence, failure mode plays an important role in determining the mechanics of fluid migration through sediments (Antonellini and Aydin, 1994; 1995; Taylor and Pollard, 2000; Ogilvie and Glover, 2001). As part of a larger study to characterize processes of fault-controlled fluid flow in volcaniclastic and gypsum-rich sediments on Mars, we have completed a series of laboratory experiments to focus on how gypsum clast content and degree of authigenic cementation affects the strength behavior of simulated Mars rocks. Both axial deformation and hydrostatic pressure tests were done at room temperature under dry conditions.

Open-File Report

Distribution of oceanic and continental leads in the Arabian-Nubian Shield

New common lead data for feldspar, whole-rock, and galena samples from the Arabian-Nubian Shield, together with data from previous work, can be divided into two main groups. Group I leads have oceanic (mantle) characteristics, whereas group II leads have incorporated a continental-crustal component of at least early Proterozoic age. The group I leads are found in rocks from the Red Sea Hills of Egypt and the western and southern parts of the Arabian Shield. Group II leads are found in rocks from the northeastern and eastern parts of the Arabian Shield, as well as from the southeastern Shield near Najran. They are also found in rocks to the south in Yemen, to the east in Oman, and to the west at Aswan, Egypt. This distribution of data suggests that the Arabian-Nubian Shield has an oceanic core flanked by rocks that have developed, at least in part, from older continental material. Two mechanisms are suggested by which this older lead component could have been incorporated into the late Proterozoic rocks, and each may have operated in different parts of the Shield. The older lead component either was derived directly from an underlying early Proterozoic basement or was incorporated from subducted pelagic sediments or sediments derived from an adjacent continent. New U-Pb zircon data indicate the presence of an early Proterozoic basement southeast of Jabal Dahul in the eastern Arabian Shield. These data, together with 2,000-Ma-old zircons from the Al Amar fault zone, verify the implication of the common lead data that at least a part of the eastern Arabian Shield has an older continental basement. Because continental margins are particularly favorable locations for development of ore deposits, these findings may have important economic implications, particularly for tin, tungsten, and molybdenum exploration. ?? 1983 Springer-Verlag.

Contributions to Mineralogy and Petrology

Arsenic in ground water in selected parts of southwestern Ohio, 2002-03

Arsenic concentrations were measured in 57 domestic wells in Preble, Miami, and Shelby Counties, in southwestern Ohio. The median arsenic concentration was 7.1 ?g/L (micrograms per liter), and the maximum was 67.6 ?g/L. Thirty-seven percent of samples had arsenic concentrations greater than the U.S. Environmental Protection Agency drinking-water standard of 10 ?g/L. Elevated arsenic concentrations (>10 ?g/L) were detected over the entire range of depths sampled (42 to 221 feet) and in each of three aquifer types, Silurian carbonate bedrock, glacial buried-valley deposits, and glacial till with interbedded sand and gravel. One factor common in all samples with elevated arsenic concentrations was that iron concentrations were greater than 1,000 ?g/L. The observed correlations of arsenic with iron and alkalinity are consistent with the hypothesis that arsenic was released from iron oxides under reducing conditions (by reductive dissolution or reductive desorption). Comparisons among the three aquifer types revealed some differences in arsenic occurrence. For buried-valley deposits, the median arsenic concentration was 4.6 ?g/L, and the maximum was 67.6 ?g/L. There was no correlation between arsenic concentrations and depth; the highest concentrations were at intermediate depths (about 100 feet). Half of the buried-valley samples were estimated to be methanic. Most of the samples with elevated arsenic concentrations also had elevated concentrations of dissolved organic carbon and ammonia. For carbonate bedrock, the median arsenic concentration was 8.0 ?g/L, and the maximum was 30.7 ?g/L. Arsenic concentrations increased with depth. Elevated arsenic concentrations were detected in iron- or sulfate-reducing samples. Arsenic was significantly correled with molybdenum, strontium, fluoride, and silica, which are components of naturally ocurring minerals. For glacial till with interbedded sand and gravel, half of the samples had elevated arsenic concentrations. The median was 11.4 ?g/L, and the maximum was 27.6 ?g/L. At shallow depths (<100 feet), this aquifer type had higher arsenic and iron concentrations than carbonate bedrock. It is not known whether these observed differences among aquifer types are related to variations in (1) arsenic content of the aquifer material, (2) organic carbon content of the aquifer material, (3) mechanisms of arsenic mobilization (or uptake), or (4) rates of arsenic mobilization (or uptake). A followup study that includes solid-phase analyses and geochemical modeling was begun in 2004 in northwestern Preble County.

Scientific Investigations Report

Geochemical balance of a small watershed and its geomorphic implications

A detailed input-output study of a small forested watershed draining the Wissahickon Formation in the Piedmont of Maryland revealed that chemical solution is five times as effective in removing material as is mechanical erosion. Solution weathering removes 16.9 tons/sq mi/yr of material compared with 3.2 tons/sq mi/yr by mechanical erosion. Plant activity during the growing season increased the concentration of silica, bicarbonate, calcium, and potassium, thus increasing total dissolved solids by one-third. Autumn leaf fall also caused a short-term increase of these ions. Rainfall does not simply dilute floodwaters as the concentration of sulfate, potassium, and calcium increases whereas silica and bicarbonate decrease in concentration during a flood cycle. Our data suggest that during the first half of a flood cycle, both the flood water and the dissolved solids in it come from an area in and immediately adjacent to the flood plain. The weathering model derived from our study suggests that on a long-term basis approximately one-half of the erosion of the Pond Branch watershed is caused by chemical solution of the silicate minerals kaolinite, vermiculite, biotite, and oligoclase. This contrasts to short-term ratio of solutional to mechanical weathering of five to one.

Maryland

Damage amplification during repetitive seismic waves in mechanically loaded rocks

Cycles of stress build-up and release are inherent to tectonically active planets. Such stress oscillations impart strain and damage, prompting mechanically loaded rocks and materials to fail. Here, we investigate, under uniaxial conditions, damage accumulation and weakening caused by time-dependent creep (at 60, 65, and 70% of the rocks’ expected failure stress) and repeating stress oscillations (of ± 2.5, 5.0 or 7.5% of the creep load), simulating earthquakes at a shaking frequency of ~ 1.3 Hz in volcanic rocks. The results show that stress oscillations impart more damage than constant loads, occasionally prompting sample failure. The magnitudes of the creep stresses and stress oscillations correlate with the mechanical responses of our porphyritic andesites, implicating progressive microcracking as the cause of permanent inelastic strain. Microstructural investigation reveals longer fractures and higher fracture density in the post-experimental rock. We deconvolve the inelastic strain signal caused by creep deformation to quantify the amount of damage imparted by each individual oscillation event, showing that the magnitude of strain is generally largest with the first few oscillations; in instances where pre-existing damage and/or the oscillations’ amplitude favour the coalescence of micro-cracks towards system scale failure, the strain signal recorded shows a sharp increase as the number of oscillations increases, regardless of the creep condition. We conclude that repetitive stress oscillations during earthquakes can amplify the amount of damage in otherwise mechanically loaded materials, thus accentuating their weakening, a process that may affect natural or engineered structures. We specifically discuss volcanic scenarios without wholesale failure, where stress oscillations may generate damage, which could, for example, alter pore fluid pathways, modify stress distribution and affect future vulnerability to rupture and associated hazards.

Scientific Reports

Preliminary examination of lunar samples: Part A: a petrographic and chemical description of samples from the lunar highlands

More than four-fifths of the surface of the Moon consists of a profoundly cratered irregular surface designated terra or highlands by analogy with the terrestrial continents. These terra regions have much higher albedos than the physiographically lower and much smoother mare regions. The difference in albedo can now be ascribed to a fundamental difference in the chemical and mineralogical character of these two regions. Lunar samples from landing sites in the mare regions and high-resolution photographs taken from lunar orbit have shown that the lunar maria are underlain by extensive lava flows. Isotopic dating of samples from four mare regions (refs. 7-1 to 7-4) indicate that mare volcanism covered a time span of 600 million years, beginning approximately 3.7 billion years ago. The intensely cratered character of terra regions is due to both the greater antiquity of these parts of the Moon and the higher flux of incoming objects that hit the Moon during very early lunar history (ref. 7-5). In contrast with the mare region, the origin of the underlying material of the terra is not easily inferred from physiographic criteria. The surface manifestations of early plutonic or extrusive igneous activity &mdash; if indeed they ever existed &mdash; were erased from the terra regions by the intense early bombardment of the lunar surface. Some portions of the highlands may be exceptions to this generalization; in particular, large craters such as Ptolemaeus, Hipparchus, Albategnius, and Alphonsus. The regions bounded by these craters are much smoother than the typical densely cratered highlands. These regions are generally assumed to be physiographic lows that have, in some way, been filled by younger material. The nature of the material and the mechanism by which it was introduced into the basins are not well understood. On the basis of rather detailed studies of the physiographic and albedo characteristics of the basin material, it has been suggested (ref. 7-6) that the filling of the highland basins was a result of volcanic processes similar to those which filled the large mare basins. Some highland basins also contain hilly, hummocky regions that bear no relation to large crater rims or crater ejecta. These regions have been interpreted as extrusive igneous features formed by viscous, silicic, igneous liquids (ref. 7-6).

Book chapter

Assessing patterns of annual change to permafrost bluffs along the North Slope coast of Alaska using high-resolution imagery and elevation models

Coastal permafrost bluffs at Barter Island, on the North Slope, Beaufort Sea Coast of Alaska are among the most rapidly eroding along Alaska’s coast, having retreated up to 132 m between 1955 and 2015. Here we quantify rates and patterns of change over a single year using very-high resolution orthophotomosaics and co-registered surface elevation models derived from a survey-grade form of structure-from-motion photogrammetry from a fixed-wing, manned aircraft. The resulting elevation models were validated with over 10,000 ground check points and found that 95% agreed to within 20 cm, before accounting for real differences in the ground surface due to seasonality, vegetation, and checkpoint acquisition errors. This data set provides the most detailed and accurate measurements of coastal change to date along the Alaskan coast and the method is scaleable to more extensive coastlines. Between July 2014 and July 2015, the bluffs retreated an average of 1.3 m, and a maximum of 8.1 m, with an associated net volume loss of 38,100 ± 300 m3 (1.3 m3/m). This average retreat over this single year was slightly less than the 60-year mean rate of change of -1.5±0.1 m/yr, suggesting the 2014-2015 year represented relatively typical to slightly below average conditions. Most of the bluff material (70%) was lost during the 3 summer months (July to Sept) of 2014 and the remaining 30% between the late-summer and following winter-spring. The pattern of change was predominantly landward retreat of the top of the bluffs, removal of the debris apron and subsequent niching at the base of the bluffs during mid to late summer (July to Sept) followed by erosion of the bluff face and deposition of debris at the base of the bluff through the remainder of the year (Sept to the following July). Drivers of the observed change are likely a combination of thermal erosion on the bluff face throughout the summer and episodic thermo-mechanical removal of material, niching, and undercutting of the base associated with high-water levels driven by low-pressure storms and westerly winds. These patterns and high rates of change are believed to be broadly representative of coastal permafrost bluffs found along many high-latitude coastlines worldwide.

Alaska

A viscoelastic damage model with applications to stable and unstable fracturing

A viscoelastic damage rheology model is presented that provides a generalization of Maxwell viscoelasticity to a non-linear continuum mechanics framework incorporating material degradation and recovery, transition from stable to unstable fracturing and gradual accumulation of non-reversible deformation. The model is a further development of the damage rheology framework of Lyakhovsky et al. for evolving effective elasticity. The framework provides a quantitative treatment for macroscopic effects of evolving distributed cracking with local density represented by an intensive state variable. The formulation, based on thermodynamic principles, leads to a system of kinetic equations for the evolution of damage. An effective viscosity inversely proportional to the rate of damage increase is introduced to account for gradual accumulation of irreversible deformation due to dissipative processes. A power-law relation between the damage variable and elastic moduli leads to a non-linear coupling between the rate of damage evolution and the damage variable itself. This allows the model to reproduce a transition from stable to unstable fracturing of brittle rocks and the Kaiser effect. 3-D numerical simulations based on the model formulation for homogeneous and heterogeneous materials account for the main features of rock behaviour under large strain. The model coefficients are constrained, using triaxial laboratory experiments with low-porosity Westerly granite and high-porosity Berea sandstone samples.

Geophysical Journal International

Fuel treatment impacts on estimated wildfire carbon loss from forests in Montana, Oregon, California, and Arizona

Using forests to sequester carbon in response to anthropogenically induced climate change is being considered across the globe. A recent U.S. executive order mandated that all federal agencies account for sequestration and emissions of greenhouse gases, highlighting the importance of understanding how forest carbon stocks are influenced by wildfire. This paper reports the effects of the most common forest fuel reduction treatments on carbon pools composed of live and dead biomass as well as potential wildfire emissions from six different sites in four western U.S. states. Additionally, we predict the median forest product life spans and uses of materials removed during mechanical treatments. Carbon loss from modeled wildfire-induced tree mortality was lowest in the mechanical plus prescribed fire treatments, followed by the prescribed fire-only treatments. Wildfire emissions varied from 10&ndash;80 Mg/ha and were lowest in the prescribed fire and mechanical followed by prescribed fire treatments at most sites. Mean biomass removals per site ranged from approximately 30&ndash;60 dry Mg/ha; the median lives of products in first use varied considerably (from <10 to >50 years). Our research suggests most of the benefits of increased fire resistance can be achieved with relatively small reductions in current carbon stocks. Retaining or growing larger trees also reduced the vulnerability of carbon loss from wildfire. In addition, modeled vulnerabilities to carbon losses and median forest product life spans varied considerably across our study sites, which could be used to help prioritize treatment implementation.

California, Oregon, Montana, Arizona

Sand resources, regional geology, and coastal processes of the Chandeleur Islands Coastal System: An evaluation of the Breton National Wildlife Refuge

Breton National Wildlife Refuge, the Chandeleur Islands chain in Louisiana, provides habitat and nesting areas for wildlife and is an initial barrier protecting New Orleans from storms. The U.S. Geological Survey (USGS) in partnership with the University of New Orleans Pontchartrain Institute for Environmental Sciences undertook an intensive study that included (1) an analysis of island change based on historical maps and remotely sensed shoreline and topographic data; (2) a series of lidar surveys at 3- to 4-month intervals after Hurricane Katrina to determine barrier island recovery potential; (3) a discussion of sea level rise and effects on the islands; (4) an analysis of sea floor evolution and sediment dynamics in the refuge over the past 150 years; (5) an assessment of the local sediment transport and sediment resource availability based on the bathymetric and subbottom data; (6) a carefully selected core collection effort to groundtruth the geophysical data and more fully characterize the sediments composing the islands and surrounds; (7) an additional survey of the St. Bernard Shoals to assess their potential as a sand resource; and (8) a modeling study to numerically simulate the potential response of the islands to the low-intensity, intermediate, and extreme events likely to affect the refuge over the next 50 years. Results indicate that the islands have become fragmented and greatly diminished in subaerial extent over time: the southern islands retreating landward as they reorganize into subaerial features, the northern islands remaining in place. Breton Island, because maintenance of the Mississippi River-Gulf Outlet (MRGO) outer bar channel requires dredging, is deprived of sand sufficient to sustain itself. Regional sediment transport trends indicate that large storms are extremely effective in transporting sand and controlling the shoreline development and barrier island geometry. Sand is transported north and south from a divergent zone near Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands’ sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5–6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 × 10 6 m 3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain from a centralized sand source that will ultimately enhance the ability of the islands to naturally build backbarrier marsh, dunes, and a continuous sandy shoreline. Barrier island sediment nourishment should be executed with the understanding that gulf shoreline erosion is inevitable but that island area can be maintained and enhanced during retreat (thus significantly prolonging the life of the island chain) with strategic sand placement.

Louisiana

Late Pleistocene-Holocene cataclysmic eruptions at Nevado de Toluca and Jocotitlan volcanoes, central Mexico

This field guide describes a five day trip to examine deposits of Late Pleistocene-Holocene cataclysmic eruptions at Nevado de Toluca and Jocotitlan volcanoes in central Mexico. We will discuss the stratigraphy, petrology, and sedimentological characteristics of these deposits which provide insights into the eruptive history, type of volcanic activity, and transport and emplacement mechanisms of pyroclastic materials. These parameters will allow us to discuss the kinds of hazards and the risk that they pose to populations around these volcanoes. The area to be visited is tectonically complex thus we will also discuss the location of the volcanoes with respect to the tectonic environment. The first four days of the field trip will be dedicated to Nevado de Toluca Volcano (19 degrees 09'N; 99 degrees 45'W) located at 23 km. southwest of the City of Toluca, and is the fourth highest peak in the country, reaching an elevation of 4,680 meters above sea level (m.a.s.l.). Nevado de Toluca is an andesitic-dacitic stratovolcano, composed of a central vent excavated upon the remains of older craters destroyed by former events. Bloomfield and Valastro, (1974, 1977) concluded that the last cycle of activity occurred nearly equal 11,600 yr. ago. For this reason Nevado de Toluca has been considered an extinct volcano. Our studies, however, indicate that Nevado de Toluca has had at least two episodes of cone destruction by sector collapse as well as several explosive episodes including plinian eruptions and dome-destruction events. These eruptions occurred during the Pleistocene but a very young eruption characterized by surge and ash flows occurred ca. 3,300 yr. BP. This new knowledge of the volcano's eruptive history makes the evaluation of its present state of activity and the geological hazards necessary. This is important because the area is densely populated and large cities such as Toluca and Mexico are located in its proximity.

Brigham Young University Geology Studies