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USGS2017

Comparison of amino acid racemization geochronometry with lithostratigraphy, biostratigraphy, uranium-series coral dating, and magnetostratigraphy in the Atlantic Coastal Plain of the southeastern United States

The results of an integrated study comprising litho- and biostratigraphic investigations, uranium-series coral dating, amino acid racemization in molluscs, and paleomagnetic measurements are compared to ascertain relative and absolute ages of Pleistocene deposits of the Atlantic Coastal Plain in North and South Carolina. Four depositional events are inferred for South Carolina and two for North Carolina by all methods. The data suggest that there are four Pleistocene units containing corals that have been dated at about 100,000 yr, 200,000 yr, 450,000 yr, and over 1,000,000 yr. Some conflicts exist between the different methods regarding the correlation of the younger of these depositional events between Charleston and Myrtle Beach. Lack of good uranium-series dates for the younger material at Myrtle Beach makes the correlation with the deposits at Charleston more difficult. ?? 1982.

Quaternary Research↗

USGS2005

Late Neogene and Quaternary evolution of the northern Albemarle Embayment (mid-Atlantic continental margin, USA)

Seismic surveys in the eastern Albemarle Sound, adjacent tributaries and the inner continental shelf define the regional geologic framework and provide insight into the sedimentary evolution of the northern North Carolina coastal system. Litho- and chronostratigraphic data are derived from eight drill sites on the Outer Banks barrier islands, and the Mobil #1 well in eastern Albemarle Sound. Within the study area, parallel-bedded, gently dipping Miocene beds occur at 95 to > 160 m below sea level (m bsl), and are overlain by a southward-thickening Pliocene unit characterized by steeply inclined, southward-prograding beds. The lower Pliocene unit consists of three seismic sequences. The 55–60 m thick Quaternary section unconformably overlies the Pliocene unit, and consists of 18 seismic sequences exhibiting numerous incised channel-fill facies. Shallow stratigraphy (< 40 m bsl) is dominated by complex fill patterns within the incised paleo-Roanoke River valley. Radiocarbon and amino-acid racemization (AAR) ages indicate that the valley-fill is latest Pleistocene to Holocene in age. At least six distinct valley-fill units are identified in the seismic data. Cores in the valley-fill contain a 3–6 m thick basal fluvial channel deposit that is overlain by a 15 m thick unit of interlaminated muds and sands of brackish water origin that exhibit increasing marine influence upwards. Organic materials within the interlaminated deposits have ages of 13–11 cal. ka. The interlaminated deposits within the valley are overlain by several units that comprise shallow marine sediments (bay-mouth and shoreface environments) that consist of silty, fine- to medium-grained sands containing open neritic foraminifera, suggesting that this area lacked a fronting barrier island system and was an open embayment from ∼10 ka to ∼4.5 ka. Seismic data show that initial infilling of the paleo-Roanoke River valley occurred from the north and west during the late Pleistocene and early Holocene. Later infilling occurred from the south and east and is characterized by a large shoal body (Colington Island and Shoals) and adjacent inlet fill. Establishment of a continuous barrier island system across the bay-mouth resulted in deposition of the latest phase of valley-fill, characterized by estuarine organic-rich muds.

Albemarle Embayment↗

USGS2000

Correlation of offshore seismic profiles with onshore New Jersey Miocene sediments

The New Jersey passive continental margin records the interaction of sequences and sea-level, although previous studies linking seismically defined sequences, borehole control, and global ??18O records were hindered by a seismic data gap on the inner-shelf. We describe new seismic data from the innermost New Jersey shelf that tie offshore seismic stratigraphy directly to onshore boreholes. These data link the onshore boreholes to existing seismic grids across the outer margin and to boreholes on the continental slope. Surfaces defined by age; facies, and log signature in the onshore boreholes at the base of sequences Kw2b, Kw2a, Kw1c, and Kw0 are now tied to seismic sequence boundaries m5s, m5.2s, m5.4s, and m6s, respectively, defined beneath the inner shelf. Sequence boundaries recognized in onshore boreholes and inner shelf seismic profiles apparently correlate with reflections m5, m5.2, m5.4, and m6, respectively, that were dated at slope boreholes during ODP Leg 150. We now recognize an additional sequence boundary beneath the shelf that we name m5.5s and correlate to the base of the onshore sequence Kw1b. The new seismic data image prograding Oligocene clinoforms beneath the inner shelf, consistent with the results from onshore boreholes. A land-based seismic profile crossing the Island Beach borehole reveals reflector geometries that we tie to Lower Miocene litho- and bio-facies in this borehole. These land-based seismic profiles image well-defined sequence boundaries, onlap and downlap truncations that correlate to Transgressive Systems Tracts (TST) and Highstand Systems Tracts (HST) identified in boreholes. Preliminary analysis of CH0698 data continues these system tract delineations across the inner shelf The CH0698 seismic profiles tie seismically defined sequence boundaries with sequences identified by lithiologic and paleontologic criteria. Both can now be related to global ??18O increases and attendant glacioeustatic lowerings. This integration of core, log, and seismic character of mid-Tertiary sediments across the width of the New Jersey margin is a major step in the long-standing effort to evaluate the impact of glaciouestasy on siliciclastic sediments of a passive continental margin. (C) 2000 Elsevier Science B.V. All rights reserved.

Conference Paper↗

USGS2026

Depositional interplay between the Ancestral Rocky Mountains and Ouachita–Marathon–Sonora orogenies: Insights from provenance records in the late Paleozoic Marfa Basin, West Texas, U.S.A.

The Marfa Basin in West Texas is a late Palaeozoic synorogenic depocenter associated with regional deformation linked to the Ancestral Rocky Mountains (ARM) and Ouachita–Marathon–Sonora (OMS) orogenies in southwestern Laurentia. Basin strata range in age from Middle Pennsylvanian to the middle Permian and include the Cieneguita, Alta, Pinto Canyon, Rose Mine and Mina Grande Formations. Sandstone petrography and detrital zircon (DZ) U–Pb and (U–Th)/He double dating data from these strata reveal three tectonically driven sedimentation stages: syntectonic ARM deposition, progressive OMS foredeep deposition and an orogenic transition. The Cieneguita and lower part of the Alta Formations exhibit a Mesoproterozoic DZ age signature (~1318 and ~1076 Ma age peaks) and quartzo-feldspathic sandstone compositions sourced from the adjacent ARM-related Diablo Platform basement uplift in the Middle Pennsylvanian to earliest Permian. In contrast, the upper part of the Alta Formation, as well as the Pinto Canyon and Rose Mine Formations, have peri-Gondwanan DZ age signatures, with Mesoproterozoic (~1069–1036 Ma age peaks), Neoproterozoic–Cambrian (~700–490 Ma) and Palaeozoic (~490–300 Ma) age modes and litho-quartzose sandstone compositions derived from the OMS fold-and-thrust belt and orogenic hinterland during the early to middle Permian. The lower to middle parts of the Alta Formation have alternating DZ age signatures and sandstone compositions from both ARM and OMS sources, revealing that the transition in the sediment supply occurred during the middle Wolfcampian. This transition was not characterised by source mixing, but rather by sediment interfingering alternately sourced from the Diablo Platform uplift and the advancing OMS belt. These observations are confirmed by the DZ He ages, which reveal distinct cooling histories for both source terranes. These results document a switch from ARM- to OMS-related syntectonic deposition in southwestern Laurentia during the early Permian, demonstrating that ARM-driven deformation largely preceded the continental collision along the Marathon segment of the OMS orogen.

Texas↗

USGS2016

Geochemistry and origin of metamorphosed mafic rocks from the Lower Paleozoic Moretown and Cram Hill Formations of North-Central Vermont: Delamination magmatism in the western New England appalachians

The Moretown Formation, exposed as a north-trending unit that extends from northern Vermont to Connecticut, is located along a critical Appalachian litho-tectonic zone between the paleomargin of Laurentia and accreted oceanic terranes. Remnants of magmatic activity, in part preserved as metamorphosed mafic rocks in the Moretown Formation and the overlying Cram Hill Formation, are a key to further understanding the tectonic history of the northern Appalachians. Field relationships suggest that the metamorphosed mafic rocks might have formed during and after Taconian deformation, which occurred at ca . 470 to 460 Ma. Geochemistry indicates that the sampled metamorphosed mafic rocks were mostly basalts or basaltic andesites. The rocks have moderate TiO 2 contents (1–2.5 wt %), are slightly enriched in the light-rare earth elements relative to the heavy rare earths, and have negative Nb-Ta anomalies in MORB-normalized extended rare earth element diagrams. Their chemistry is similar to compositions of basalts from western Pacific extensional basins near volcanic arcs. The metamorphosed mafic rocks of this study are similar in chemistry to both the pre-Silurian Mount Norris Intrusive Suite of northern Vermont, and also to some of Late Silurian rocks within the Lake Memphremagog Intrusive Suite, particularly the Comerford Intrusive Complex of Vermont and New Hampshire. Both suites may be represented among the samples of this study. The geochemistry of all samples indicates that parental magmas were generated in supra-subduction extensional environments during lithospheric delamination.

American Journal of Science↗

USGS1979

Petrology and stratigraphy of Paleogene nonmarine sandstones, Cascade Range, Washington

The Cascade Range of Washington north of 47? latitude is composed of probable Paleozoic and Mesozoic metamorphic rocks and Mesozoic and Tertiary plutonic rocks. Several Paleogene nonmarine arkosic sandstone units fringe and in part occur within the complex crystalline core. The early to middle Eocene Chuckanut Formation is present on the west side of the crystalline core in the western foothills of the Cascades. The early to middle Eocene Swauk Formation partially encircles the Mt. Stuart massif of the central Cascades. In the western foothills of the Cascades, between the main body of Chuckanut Formation near Bellingham and the main outcrop area of the Swauk Formation south of Mt. Stuart, many smaller bodies of arkosic sandstone have variously been referred to either the Swauk or Chuckanut Formations. The early Eocene Manastash Formation occurs locally in an area south of the Yakima River. The middle to late Eocene Chumstick Formation is mostly confined to the Chiwaukum graben within the crystalline core and is separated from the Swauk Formation on the southwest by the Leavenworth Fault. The Oligocene Wenatchee Formation unconformably over lies the Chumstick Formation near Wenatchee. The middle to late Eocene Roslyn Formation crops out north of the Yakima River and is underlain by the Teanaway Basalt which separates the Roslyn from the older Swauk Formation. The middle Eocene to early Oligocene Naches Formation forms a north-trending body that crosses the Yakima River and is in fault contact with both the Swauk and Manastash Formations. The middle to late Eocene Puget Group underlies the Quaternary deposits of the Puget Lowland southeast of Seattle on the western flank of the Cascades. The various formations are all composed predominantly of fine- to medium-grained sandstones with lesser amounts of interbedded shale, conglomerate and coal. Compositionally, the units are predominantly either feldspathic or litho-feldspathic subquartzose sandstones. Volcanic rocks are important constituents of the Puget Group, the Chumstick and Naches Formations, and the isolated arkosic bodies. The three older units, however, contain relatively less volcanic lithics to total lithics than do younger units, indicating perhaps the initiation of more widespread volcanic activity in middle Eocene time. Ratios of framework grain parameters show that the terrestrial sandstone units were derived from a mixed plutonic and tectonic source terrane of continental block tectonic provenance with an overprint of magmatic arc provenance. Modal analysis was performed on samples from the various sedimentary units to establish petrologic compositions, and to provide data with which to compare the different units and discuss clast provenance and tectonic regimen. Although the arkosic sandstones have generally uniform framework clast compositions, minor yet significant differences do exist between the units. Basal or basement-onlap portions of the units in particular are locally derived and differ markedly from the overall compositions of the individual units. Many coincidences of composition, age, structure, and bedrock indicate that the Chuckanut and Swauk may have originally been deposited as a single unit that since has been offset approximately 160 kilometers by right lateral strike slip motion starting about 48 Ma. If this hypothetical offset did occur, then major movement on the Straight Creek Fault is bracketed between about 48 Ma and Oligocene time.

Open-File Report↗

USGS1996

Sublake geologic structure from high-resolution seismic-reflection data from four sinkhole lakes in the Lake Wales Ridge, central Florida

Seismic-reflection profiles from Lake Wales, Blue Lake, Lake Letta, and Lake Apthorp located along the Lake Wales Ridge in central Florida provide local detail within the regional hydrogeologic framework as described by litho- and hydrostratigraphic cross sections. Lakes located with the mantled karst region have long been considered to be sinkhole lakes, originating from subsidence activity. High-resolution seismic- reflection data confirm this origin for these four lakes. The geologic framework of the Lake Wales Ridge has proven to be a suitable geologic setting for continuous high-resolution seismic-reflection profiling in lakes; however, the nature of the lake-bottom sediments largely controls the quality of the seismic data. In lakes with significant organic-rich bottom deposits, interpretable record was limited to areas where organic deposits were minimal. In lakes with clean, sandy bottoms, the seismic-reflection methods were highly successful in obtaining data that can be correlated with sublake subsidence features. These techniques are useful in examining sublake geology and providing a better understanding of how confining units are affected by subsidence in a region where their continuity is of significant importance to local lake hydrology. Although local geologic control around each lake generally corresponds to the regional geologic framework, local deviations from regional geologic trends occur in sublake areas affected by subsidence activity. Each of the four lakes examined represents a unique set of geologic controls and provides some degree of structural evidence of subsidence activity. Sublake geologic structures identified include: (1) marginal lake sediments dipping into bathymetric lows, (2) lateral discontinuity of confining units including sags and breaches, (3) the disruption and reworking of overlying unconsolidated siliciclastic sediments as they subside into the underlying irregular limestone surface, and (4) sublake regions where confining units appear to remain intact and unaffected by nearby subsidence activity. Each lake likely is underlain by several piping features rather than one large subsidence feature.

Florida↗

USGS2014

Porphyry copper assessment of western Central Asia

The U.S. Geological Survey conducted an assessment of resources associated with porphyry copper deposits in the western Central Asia countries of Kyrgyzstan, Uzbekistan, Kazakhstan, and Tajikistan and the southern Urals of Kazakhstan and Russia as part of a global mineral resource assessment. The purpose of the study was to (1) delineate permissive areas (tracts) for undiscovered porphyry copper deposits; (2) compile a database of known porphyry copper deposits and significant prospects; (3) where data permit, estimate numbers of undiscovered deposits within those permissive tracts; and (4) provide probabilistic estimates the amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in those undiscovered deposits. Western Central Asia, a region diverse in its geologic complexity, is situated north of the Tarim and North China tectonic blocks and sandwiched between the East European and Siberian cratons. The Ural Mountains form the western margin of the region; the southern margin is formed by the high-standing ranges that make up the Tian Shan mountain range in the border regions of Kazakhstan, Kyrgyzstan, and western China, where the effects of collisional tectonics are well displayed. The tectonic collage that makes up the core of western Central Asia is perhaps the geologically least understood part of the region. There is broad agreement that the early Paleozoic is made up of tectonically juxtaposed blocks that vary from Precambrian-cored microcontinents to magmatic arc and related complexes to subduction-related accretionary complexes. The rudiments of an incipient, contiguous single Kazakhstan block were formed by the end of the Silurian. In the middle to late Paleozoic, the block was unconformably superposed by two large, nested magmatic-arc belts, one Devonian, the other Carboniferous. Both magmatic-arc complexes were folded into a horseshoe-shaped, southeast-opening orocline in response to the final collisions of the various surrounding cratonic blocks with the Kazakhstan block. Additional deformation in the upper Cenozoic derived from the collision of India and China significantly redistributed fragments of the various mosaicked blocks, particularly in the central and southern parts of the western Central Asian region. Porphyry copper deposits are associated with many of the magmatic-arc fragments and belts throughout the geologically complex region, and economically important deposits are found in arc sequences of all Paleozoic Periods. The economically most productive arcs are Carboniferous. The assessment includes a discussion of the tectonic and geologic setting of porphyry copper deposits in western Central Asia (chapter 1), an application of remote sensing data for hydrothermal alteration mapping as a tool for porphyry copper assessment in the region (chapter 2), and a probabilistic assessment of undiscovered porphyry copper resources in four areas that represent Ordovician and Late Paleozoic (Carboniferous-Permian) magmatic arcs (chapter 3). The principal litho-tectonic terrane concept used to delineate permissive tracts was that of a magmatic arc that formed in the subduction boundary zone above a subducting plate. Eight permissive tracts are delineated on the basis of mapped and inferred subsurface distributions of igneous rocks assigned to magmatic arcs of specified age ranges that define areas where the occurrence of porphyry copper deposits within 1 kilometer of the Earth’s surface is possible. These tracts range in area from about 8,000 to 200,000 square kilometers and host 18 known porphyry copper deposits that contain about 54 million metric tons of copper. Available data included geologic maps, the distribution of significant porphyry copper occurrences and potentially related deposit types, the distribution of hydrothermal alteration patterns that are consistent with porphyry copper mineralization, and information on possible subsurface extensions of permissive rocks. On the basis of analyses of these data, the assessment team estimated a mean of 25 undiscovered porphyry copper deposits for the study area. Estimates of numbers of undiscovered deposits were combined with grade and tonnage models in a Monte Carlo simulation to yield a mean estimate of 95 million metric tons of copper in undiscovered porphyry copper deposits; this represents about twice the amount of identified porphyry copper resources (54 million metric tons). Detailed descriptions of each permissive tract, including the rationales for delineation and assessment, are given in appendixes, along with a geographic information system (GIS) that includes permissive tract boundaries, point locations of known porphyry copper deposits and significant occurrences, and hydrothermal alteration data based on analysis of remote sensing data.

Ural Mountains↗

USGS1994

Geologic framework and hydrogeologic characteristics of the Edwards Aquifer outcrop, Comal County, Texas

All of the hydrogeologic subdivisions within the Edwards aquifer outcrop in Comal County have some porosity and permeability. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; hydrogeologic subdivision III, the leached and collapsed members, undivided; and hydrogeologic subdivision II, the cyclic and marine members, undivided, of the Person Formation. The two types of porosity in the Edwards aquifer outcrop are fabric selective, which is related to depositional or diagenetic elements and typically exists in specific stratigraphic horizons; and not fabric selective, which can exist in any litho strati graphic horizon. Permeability, the capacity of porous rock to transmit water, depends on the physical properties of the rock such as pore size, shape, distribution, fissuring, and dissolution. Two faults, Comal Springs and Hueco Springs, completely, or almost completely, offset the Edwards aquifer along much of their respective traces across Comal County. Porous and permeable Edwards aquifer limestone is juxtaposed against impermeable upper confining units in these areas. These faults completely, or almost completely, offset the Edwards aquifer and are thought to be barriers or partial barriers to groundwater flow where the beds are juxtaposed. In Comal County, the Edwards aquifer is probably most vulnerable to surface contamination in the rapidly urbanizing areas on the Edwards aquifer outcrop. Possible contamination can result from spills, leakage of hazardous materials, or runoff onto the intensely faulted and fractured, karstic limestone outcrops characteristic of the recharge zone.

Texas↗

USGS2003

The chrono- and lithostratigraphic significance of the type section of the Middendorf Formation, Chesterfield County, South Carolina

The name Middendorf Formation has been widely used in the Coastal Plain of South Carolina, eastern Georgia, and southern North Carolina since 1904, despite conflicting interpretations of the age and stratigraphic relations of the unit at its type locality. Between 1995 and 1998, the U.S. Geological Survey, in cooperation with the South Carolina Department of Natural Resources, drilled three continuously cored holes to the south and to the east of the type section of the Middendorf Formation, which is located in Chesterfield County, South Carolina. In addition, two outcrops to the northeast of the type section were sampled for biostratigraphic control. The litho- and biostratigraphic relations of the units in these cores and outcrops provide significant insights into the age of the Middendorf Formation at its type locality, and how this age impacts regional correlations of the formation. A projection of formational contacts and thicknesses from downdip areas into the type locality of the Middendorf Formation indicates that the type section is most likely a facies of either the uppermost Bladen Formation (of the Black Creek Group), or the uppermost Bladen and the lowermost part of the Peedee Formations. This report documents the evidence that support this interpretation. The implication of this interpretation is that the name "Middendorf" has been applied to a variety of units throughout the southeastern United States, all of which display a similar lithology, but differ significantly in stratigraphic position and age. For these reasons, we recommend that the name Middendorf be restricted for use with strata that occur only in the vicinity of the type locality, and use of the name "Middendorf" for units elsewhere in the Coastal Plain be reconsidered.

Southeastern Geology↗

USGS1983

Hafnium isotope results from mid-ocean ridges and Kerguelen

176Hf/177Hf ratios are presented for oceanic volcanics representing both extremes of the range of mantle HfNdSr isotopic variation. Hf from critical mid-ocean ridgebasalts shows that 176Hf/177Hf does indeed have a greater variability than 143Nd/144Nd and 87Sr/86Sr in the depleted mantle. This extra variation is essentially of a random nature, and can perhaps be understood in terms of known Rb/SrSm/NdLu/Hf fractionation relationships. At the other extreme of mantle isotopic composition, 176Hf/177Hf ratios for igneous rocks from the Indian Ocean island of Kerguelen show a closely similar variation to published 143Nd/144Nd ratios for the same samples. Comparison of HfNdSr c relationships for Tristan da Cunha, Kerguelen and Samoa reveals divergences in the mantle array for ocean island magma sources, and perhaps suggests that these irregularities are largely the result of an extra component of 87Sr/86Sr variation. ?? 1983.

LITHOS↗

USGS1973

Coexisting cummingtonite and aluminous hornblende from garnet amphibolite, Boehls Butte area, Idaho, USA

Electron microprobe analyses of green hornblende and coexisting cummingtonite from garnet amphibolite show identical Fe/Mg ratios ( = 0.9). Cummingtonite is iron-magnesium silicate with very little calcium and aluminum and practically no alkalies. In contrast, the hornblende has 1.5 tetrahedral Al, 0.9 octahedral Al and a considerable amount of Ca and alkalies. Comparison with the hornblendes from the Sierra Nevada shows a higher relative amount of tschemakite molecule in the hornblendes from Idaho where pressures during the recrystallization were higher.

Idaho↗

USGS1981

Geochemistry and petrogenesis of the Laramie anorthosite complex, Wyoming

A geochemical investigation of the Laramie anorthosite complex determined that monsonite associated with the complex are characterized by positive Eu anomalies and display a regular variation in composition with distance from the monzonite/county rock contact. Anorthositic rocks have major and trace element abundance typical of similar complexes. The internal variations in the monzonite were produced by in situ fractionation and contamination. The data indicate that anorthosite and monzonite cannot be comagmatic. It is proposed that the anorthosite and monzonite of the complex evolved from two distinct magmas, and that two stages of anatectic melting contributed to the evolution of the monzonite. An initial stage of partial melting was induced by intrusion of a gabbroic anorthosite magma into the lower crust; a second partial melting event occurred after emplacement where heat from the intrusions melted country rocks resulting in extensive contamination ofthe monzonite. ?? 1981.

LITHOS↗

USGS1984

Radioactive disequilibria in mineralised fracture samples from two uranium occurrences in northern Sweden

Mineralised fractures from two uranium occurrences in northern Sweden were examined mineralogically and isotopically to establish the presence or absence of radioactive equilibrium that may indicate recent rock-water interaction processes based on the natural mobility of uranium (i.e.; during the last 0.5 Ma). The results show evidence of radioactive disequilibrium in six of the nine samples investigated. Disequilibria are attributable to solution to solid 234U recoil gain (weakly mineralised zones adjacent to the main mineralisation) and solid to solution 234U recoil loss (moderate to highly mineralised zones). The absence of significant 238U loss in the samples emphasises the reducing conditions at the sampled depths. ?? 1984.

LITHOS↗

USGS1990

The Bayan Obo iron-rare-earth-niobium deposits, Inner Mongolia, China

The plate tectonic setting, regional geology and certain aspects of the economic geology of the iron-rare-earth-niobium ore bodies at Bayan Obo, Inner Mongolia, China, were studied by a team of geologists from the Tianjin Geologic Research Academy and the U.S. Geological Survey between 1987 and 1989. These ore bodies were formed by hydrothermal replacement of Middle Proterozoic dolomite in an intra-continental rift setting. A variety of veins and/or dikes that have a carbonatitelike mineralogy cut the footwall clastic rocks and migmatites. A stockwork of veins occurs at several locations in the footwall. The hanging wall is a shale that has been converted to a K-metasomatite and has microcrystalline potassium feldspar as its principal constituent. This shale served as a sealing caprock that contained the chemical solutions that reacted with the dolomite and created the enormous concentration of mineralized rock in an 18-kilometer-long syncline. The rocks that host these ore bodies and the associated mineralized areas occur today as roof pendants in granitoid rocks of Permian age that were emplaced during a continent-to-continent collision during that period.

LITHOS↗

USGS1990

Alkaline igneous rocks of Magnet Cove, Arkansas: Mineralogy and geochemistry of syenites

Syenites from the Magnet Cove alkaline igneous complex form a diverse mineralogical and geochemical suite. Compositional zoning in primary and late-stage minerals indicates complex, multi-stage crystallization and replacement histories. Residual magmatic fluids, rich in F, Cl, CO2 and H2O, reacted with primary minerals to form complex intergrowths of minerals such as rinkite, fluorite, V-bearing magnetite, F-bearing garnet and aegirine. Abundant sodalite and natrolite formed in pegmatitic segregations within nepheline syenite where Cl- and Na-rich fluids were trapped. During autometasomatism compatible elements such as Mn, Ti, V and Zr were redistributed on a local scale and concentrated in late-stage minerals. Early crystallization of apatite and perovskite controlled the compatible behavior of P and Ti, respectively. The formation of melanite garnet also affected the behaviour of Ti, as well as Zr, Hf and the heavy rare-earth elements. Pseudoleucite syenite and garnet-nepheline syenite differentiated along separate trends, but the two groups are related to the same parental magma by early fractionation of leucite, the presumed precursor of intergrowths of K-feldspar and nepheline. The Diamond Jo nepheline syenite group defines a different differentiation trend. Sphene-nepheline syenite, alkali syenite and several miscellaneous nepheline syenites do not consistently plot with the other syenite groups or each other on element and oxide variation diagrams, indicating that they were derived from still other parental syenite magmas. Mineral assemblages indicate that relatively high f{hook};O2, at or above the fayalite-magnetite-quartz buffer, prevailed throughout the crystallization history of the syenites. ?? 1990.

LITHOS↗

USGS1990

Mineralogy and geochemistry of altered rocks associated with Lemitar carbonatites, central New Mexico, U.S.A.

The intrusion of more than 100 Cambrian-Ordovician carbonatite dikes caused minor alteration of Proterozoic granitic and mafic rocks in the Lemitar Mountains, although hematization, carbonatization and fenitization caused extensive alteration locally. Ampibolites within 15-20 m of the carbonatite dike contacts were highly altered by carbonatization. Locally the Lemitar diorite/gabbro adjacent to some carbonatites were altered in a thin, discontinuous zone by sodic-potassic fenitization. The granite at Polvadera Peak was locally altered by potassic fenitization. Most of the altered rocks have been further altered by hematization and carbonatization. The altered rocks show increases in loss on ignition and in one or more the elements Ca, K, Na and Al. Only granitic fenites in the Lemitar Mountains lost silica and some diorite/gabbro fenites gained silica. Petrologic and geochemical studies clearly indicate that the types and degree of alteration differ notably in different rock types. The fenitizing fluids were oxidizing, slightly acidic, high in volatiles (especially CO2) and possibly fairly low in alkali elements. ?? 1990.

LITHOS↗

USGS1991

Geochemical consequences of flow differentiation in a multiple injection dike (Trinity ophiolite, N. California)

A clinopyroxene-rich dike of the Trinity ophiolite sheeted-dike complex shows three different magmatic pulses, probably injected in a short period of time (no well developed chilled margin) and important variations of the clinopyroxene and plagioclase percentages between its core (highly porphyritic) and margins (aphyric). This variation, interpreted as related to a flow differentiation phenomenon (mechanical phenocryst redistribution), has important geochemical consequences. It produces increases in the FeO, MgO, CaO, Cr and Ni contents from the margin to the core, together with increases in the clinopyroxene percentage, and decreases in the SiO2, Zr, Y, Nb and REE contents together with a decrease in the percentage of the fine-grained groundmass toward the core of the dike. This mineralogical redistribution, which also affects the incompatible trace element ratios because of the difference in plagioclase and clinopyroxene mineral/liquid partition coefficients, illustrate the importance of fractionation processes outside of a magma chamber. ?? 1991.

LITHOS↗