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At least 19 recordsLinked to original sources
USGS1993

Pressure increases, the formation of chromite seams, and the development of the ultramafic series in the Stillwater Complex, Montana

This paper explores the hypothesis that chromite seams in the Stillwater Complex formed in response to periodic increases in total pressure in the chamber. Total pressure increased because of the positive δ V of nucleation of CO 2 bubbles in the melt and their subsequent rise through the magma chamber, during which the bubbles increased in volume by a factor of 4–6. By analogy with the pressure changes in the summit chambers of Kilauea and Krafla volcanoes, the maximum variation was 0⋅2–0⋅25 kbar, or 5–10% of the total pressure in the Stillwater chamber. An evaluation of the likelihood of fountaining and mixing of a new, primitive liquid that entered the chamber with the somewhat more evolved liquid already in the chamber is based upon calculations using observed and inferred velocities and flow rates of basaltic magmas moving through volcanic fissures. The calculations indicate that hot, dense magma would have oozed, rather than fountained into the chamber, and early mixing of the new and residual magmas that could have resulted in chromite crystallizing alone did not take place.

Journal of Petrology↗
USGS2000

Rhyolite themobarometry and the shallowing of the magma reservoir, Coso volcanic field, California

The compositionally bimodal Pleistocene Coso volcanic field is located at the western margin of the Basin and Range province ∼60 km north of the Garlock fault. Thirty-nine nearly aphyric high-silica rhyolite domes were emplaced in the past million years: one at 1 Ma from a transient magma reservoir, one at ∼0·6 Ma, and the rest since ∼0·3 Ma. Over the past 0·6 My, the depth from which the rhyolites erupted has decreased and their temperatures have become slightly higher. Pre-eruptive conditions of the rhyolite magmas, calculated from phenocryst compositions using the two-oxide thermometer and the Al-in-hornblende barometer, ranged from 740°C and 270 MPa (2·7 kbar; ∼10 km depth) for the ∼0·6 Ma magma, to 770°C and 140 MPa (1·4 kbar; ∼5·5 km) for the youngest (∼0·04 Ma) magma. Results are consistent with either a single rhyolitic reservoir moving upward through the crust, or a series of successively shallower reservoirs. As the reservoir has become closer to the surface, eruptions have become both more frequent and more voluminous.

California↗
USGS2015

Coupled interactions between volatile activity and Fe oxidation state during arc crustal processes

Arc magmas erupted at the Earth’s surface are commonly more oxidized than those produced at mid-ocean ridges. Possible explanations for this high oxidation state are that the transfer of fluids during the subduction process results in direct oxidation of the sub-arc mantle wedge, or that oxidation is caused by the effect of later crustal processes, including protracted fractionation and degassing of volatile-rich magmas. This study sets out to investigate the effect of disequilibrium crustal processes that may involve coupled changes in H 2 O content and Fe oxidation state, by examining the degassing and hydration of sulphur-free rhyolites. We show that experimentally hydrated melts record strong increases in Fe 3+ /∑Fe with increasing H 2 O concentration as a result of changes in water activity. This is relevant for the passage of H 2 O-undersaturated melts from the deep crust towards shallow crustal storage regions, and raises the possibility that vertical variations in f O 2 might develop within arc crust. Conversely, degassing experiments produce an increase in Fe 3+ /∑Fe with decreasing H 2 O concentration. In this case the oxidation is explained by loss of H 2 as well as H 2 O into bubbles during decompression, consistent with thermodynamic modelling, and is relevant for magmas undergoing shallow degassing en route to the surface. We discuss these results in the context of the possible controls on f O 2 during the generation, storage and ascent of magmas in arc settings, in particular considering the timescales of equilibration relative to observation as this affects the quality of the petrological record of magmatic f O 2 .

Journal of Petrology↗
USGS2003

Kilauea east rift zone magmatism: An episode 54 perspective

On January 29 30, 1997, prolonged steady-state effusion of lava from Pu'u'O'o was briefly disrupted by shallow extension beneath Napau Crater, 1 4 km uprift of the active Kilauea vent. A 23-h-long eruption ( episode 54 ) ensued from fissures that were overlapping or en echelon with eruptive fissures formed during episode 1 in 1983 and those of earlier rift zone eruptions in 1963 and 1968. Combined geophysical and petrologic data for the 1994 1999 eruptive interval, including episode 54 , reveal a variety of shallow magmatic conditions that persist in association with prolonged rift zone eruption. Near-vent lava samples document a significant range in composition, temperature and crystallinity of pre-eruptive magma. As supported by phenocryst liquid relations and Kilauea mineral thermometers established herein, the rift zone extension that led to episode 54 resulted in mixture of near-cotectic magma with discrete magma bodies cooled to ≤1100°C. Mixing models indicate that magmas isolated beneath Napau Crater since 1963 and 1968 constituted 32 65% of the hybrid mixtures erupted during episode 54 . Geophysical measurements support passive displacement of open-system magma along the active east rift conduit into closed-system rift -reservoirs along a shallow zone of extension. Geophysical and petrologic data for early episode 55 document the gradual flushing of episode 54 related magma during magmatic recharge of the edifice.

Hawaii↗
USGS2021

Proportions, timing, and re-equilibration progress during the 1959 Summit Eruption of Kīlauea: An example of magma mixing processes operating during OIB petrogenesis

Petrographic and chemical analysis of scoria samples collected during the 1959 Kīlauea summit eruption illustrates the progress of thermal and chemical homogenization of the melts, and the gradual growth and/or re-equilibration of olivine phenocrysts, over the course of the eruption. Glass compositions show that thermal equilibration was largely complete within the span of the eruption, whereas chemical homogenization was a work in progress. The olivine phenocryst population, known to contain conspicuous antecrystic components, is also hybrid within the euhedral population. The bulk of the olivine reached the level of the erupting magma on November 18–19, 1959. Zoning patterns in olivine phenocrysts show that initially unzoned grains developed normal zoning by the end of the eruption. Reverse zoning in relatively Fe-rich olivine phenocrysts (interpreted as cognate to the stored magma) was progressively eliminated from November 21 to December 19, 1959, by diffusive re-equilibration between crystals and melt. Toward the end of the eruption, the only olivine composition in direct contact with the melt was Fo 84–86 , with the original rim compositional heterogeneity gone in 4–5 weeks’ time. Activity in December 1959 differed from that in November, as high fountaining events were more closely spaced and almost all samples were picritic, with bulk MgO ≥16·5 wt%. Three different levels were in play during the 1959 eruption: a deep source for high-MgO melts and forsteritic (Fo 87–89 ) olivines, an intermediate source for the bulk of the stored magma, and a shallower source for the most differentiated magma. This model is consistent with geophysical, petrological and chemical observations. Comparison of the 1959 eruption with results from older explosive deposits suggests that stored and recharge melts and olivine from the deeper parts of Kīlauea’s plumbing are similar in composition to those observed or inferred in the 1959 eruption, so they behave similarly during extrusive and explosive periods alike.

Hawaii↗
USGS2020

Petrologic insights into rift zone magmatic interactions from the 2011 eruption of Kīlauea Volcano, Hawaiʻi

The high frequency of historical eruptions at Kīlauea Volcano presents an exceptional opportunity to address fundamental questions related to the transport, storage, and interaction of magmas within rift zones. The Nāpau Crater area on Kīlauea’s East Rift Zone (ERZ) experienced nine fissure eruptions within 50 years (1961–2011). Most of the magma intruded during these frequent eruptions remained stored within the rift zone, creating a potential magma mixing depot within the ERZ. The superbly monitored and sampled 2011 eruption (Puʻu ʻŌʻō episode 59) presents an extraordinary opportunity to evaluate magma mixing processes within the ERZ. Whole-rock, glass, and olivine compositions were determined, not only for lava from the 2011 eruption, but also for a new suite of Nāpau Crater area samples from the 1963, 1965, 1968, 1983, and 1997 eruptions, as well as the previously undocumented 1922 eruption. Whole-rock XRF data revealed two geochemically distinct magma batches for episode 59: one less evolved (∼6·6 wt % MgO, 0·46 wt % K2O) than the other (∼6·2 wt % MgO, 0·58 wt % K2O). Episode 59 lava is remarkably aphyric (∼0·1 vol. % phenocrysts), making use of mineralogy to identify parent magma affinities problematic. Linear compositional trends of whole-rock major and trace elements, and reversely zoned olivine crystals indicate episode 59 lavas underwent magma mixing. Least squares regression calculations and plots of major and trace element data, were used to evaluate whether the episode 59 samples are products of mixing summit-derived magma with residual magma from previous Nāpau Crater area eruptions. The regression results and trace element ratios are inconsistent with previously proposed mixing scenarios, but they do support mixing between summit-derived magma and residual magma from the 1983 and 1997 Nāpau Crater area eruptions. These magmas were stored in physically and chemically distinct pods at depths of 1·6–3·0 km prior to mixing with new magma intruded from the summit to produce the episode 59 lava. One pod contained a fractionated equivalent of 1983 lava, and the other a hybrid of compositions similar to 1983 and 1997 lavas. The petrology of episode 59 lava demonstrates that magmas from two previous eruptions (1983 and 1997) were available to mix with magma intruded from the summit region. This study clarifies the pre-eruptive history of the mixed episode 59 lava, and elucidates the evolution of the volcano's magmatic system in a region of frequent eruptions.

Hawaii↗
USGS1968

Mineral equilibria in the system nepheline-alkali feldspar-plagioclase and their petrological significance

The purpose of this work is a theoretical consideration of equilibrium conditions in the system nepheline - alkali feldspar - plagioclase - alkali chloride aqueous solution based on the thermodynamic treatment of experimental data (Orville, 1963; Iiyama et al., 1963; Debron et al., 1961) for particular systems. The excess thermodynamic functions (Z E , S E , H E , V E ) of solid solutions were calculated for it. These data enable us to derive the diagrams of isotherms for the distribution of sodium components between nepheline and alkali feldspar ; between plagioclase and alkali feldspar ; and among plagioclase , nepheline , and alkali feldspar for the temperature range 400-1000° C. In order to check the calculated diagrams we analysed the minerals from the binary and ternary assemblages of the systems nepheline $ alkali feldspar $ plagioclase from various igneous massifs of nepheline syenites of the world. Temperatures obtained from different geothermometers were found to coincide satisfactorily.

Journal of Petrology↗
USGS2010

Dacite petrogenesis on mid-ocean ridges: Evidence for oceanic crustal melting and assimilation

Whereas the majority of eruptions at oceanic spreading centers produce lavas with relatively homogeneous mid-ocean ridge basalt (MORB) compositions, the formation of tholeiitic andesites and dacites at mid-ocean ridges (MORs) is a petrological enigma. Eruptions of MOR high-silica lavas are typically associated with ridge discontinuities and have produced regionally significant volumes of lava. Andesites and dacites have been observed and sampled at several locations along the global MOR system; these include propagating ridge tips at ridge-transform intersections on the Juan de Fuca Ridge and eastern Gal??pagos spreading center, and at the 9??N overlapping spreading center on the East Pacific Rise. Despite the formation of these lavas at various ridges, MOR dacites show remarkably similar major element trends and incompatible trace element enrichments, suggesting that similar processes are controlling their chemistry. Although most geochemical variability in MOR basalts is consistent with low-pressure fractional crystallization of various mantle-derived parental melts, our geochemical data for MOR dacitic glasses suggest that contamination from a seawater-altered component is important in their petrogenesis. MOR dacites are characterized by elevated U, Th, Zr, and Hf, low Nb and Ta concentrations relative to rare earth elements (REE), and Al2O3, K2O, and Cl concentrations that are higher than expected from low-pressure fractional crystallization alone. Petrological modeling of MOR dacites suggests that partial melting and assimilation are both integral to their petrogenesis. Extensive fractional crystallization of a MORB parent combined with partial melting and assimilation of amphibole-bearing altered crust produces a magma with a geochemical signature similar to a MOR dacite. This supports the hypothesis that crustal assimilation is an important process in the formation of highly evolved MOR lavas and may be significant in the generation of evolved MORB in general. Additionally, these processes are likely to be more common in regions of episodic magma supply and enhanced magma-crust interaction such as at the ends of ridge segments. ?? The Author 2010. Published by Oxford University Press. All rights reserved.

Journal of Petrology↗
USGS2001

Garnet granulite xenoliths from the Northern Baltic shield: The underplated lower crust of a palaeoproterozoic large igneous province

Garnet granulite facies xenoliths hosted in Devonian lamprophyres from the Kola Peninsula are interpreted to represent the high-grade metamorphic equivalents of continental flood tholeiites, emplaced into the Baltic Shield Archaean lower crust in early Proterozoic time. Geochronological data and similarities in major and trace element geochemistry suggest that the xenoliths formed during the same plume-related magmatic event that created a widespread Palaeoproterozoic large igneous province (LIP) at 2·4–2·5 Ga. They are, thus, the first samples of the lower crust of a Palaeoproterozoic LIP to be studied in petrological detail. The suite includes mafic granulites (gar + cpx + rutile ± plag ± opx ± phlog ± amph), felsic granulites (plag + gar + cpx + rutile ± qtz ± Kspar ± phlog ± amph) and pyroxenites (± phlog ± amph), but mafic garnet granulites predominate. Although some samples are restites, there is no evidence for a predominance of magmatic cumulates, as is common for Phanerozoic lower-crustal xenolith suites. Metasediments are also absent. Phlogopite and/or amphibole occur in xenoliths of all types and are interpreted to be metasomatic in origin. The K-rich metasomatic event occurred at ∼2·0 Ga, and led to substantial enrichment in Rb, K, LREE/HREE, Th/U, Th/Pb and, to a lesser extent, Nb and Ti. The fluids responsible for this metasomatism were probably derived from a second plume that arrived beneath the region at this time. Evidence for partial melting of mafic crust exists in the presence of migmatitic granulites. The timing of migmatization overlaps that of metasomatism, and it is suggested that migmatization was facilitated by the metasomatism. The metamorphism, metasomatism and migmatization recorded in the Kola granulite xenoliths may be representative of the processes responsible for converting Archaean LIP-generated proto-continents into continental crust.

Elovy Island, Kandalaksha Gulf, Kola Peninsula, Wh↗
USGS2001

Eruptive stratigraphy of the Tatara-San Pedro complex, 36°S, sourthern volcanic zone, Chilean Andes: Reconstruction method and implications for magma evolution at long-lived arc volcanic centers

The Quaternary Tatara–San Pedro volcanic complex (36°S, Chilean Andes) comprises eight or more unconformity-bound volcanic sequences, representing variably preserved erosional remnants of volcanic centers generated during ∼930 ky of activity. The internal eruptive histories of several dominantly mafic to intermediate sequences have been reconstructed, on the basis of correlations of whole-rock major and trace element chemistry of flows between multiple sampled sections, but with critical contributions from photogrammetric, geochronologic, and paleomagnetic data. Many groups of flows representing discrete eruptive events define internal variation trends that reflect extrusion of heterogeneous or rapidly evolving magma batches from conduit–reservoir systems in which open-system processes typically played a large role. Long-term progressive evolution trends are extremely rare and the magma compositions of successive eruptive events rarely lie on precisely the same differentiation trend, even where they have evolved from similar parent magmas by similar processes. These observations are not consistent with magma differentiation in large long-lived reservoirs, but they may be accommodated by diverse interactions between newly arrived magma inputs and multiple resident pockets of evolved magma and/or crystal mush residing in conduit-dominated subvolcanic reservoirs. Without constraints provided by the reconstructed stratigraphic relations, the framework for petrologic modeling would be far different. A well-established eruptive stratigraphy may provide independent constraints on the petrologic processes involved in magma evolution—simply on the basis of the specific order in which diverse, broadly cogenetic magmas have been erupted. The Tatara–San Pedro complex includes lavas ranging from primitive basalt to high-SiO 2 rhyolite, and although the dominant erupted magma type was basaltic andesite (∼52–55 wt % SiO 2 ) each sequence is characterized by unique proportions of mafic, intermediate, and silicic eruptive products. Intermediate lava compositions also record different evolution paths, both within and between sequences. No systematic long-term pattern is evident from comparisons at the level of sequences. The considerable diversity of mafic and evolved magmas of the Tatara–San Pedro complex bears on interpretations of regional geochemical trends. The variable role of open-system processes in shaping the compositions of evolved Tatara–San Pedro complex magmas, and even some basaltic magmas, leads to the conclusion that addressing problems such as arc magma genesis and elemental fluxes through subduction zones on the basis of averaged or regressed reconnaissance geochemical datasets is a tenuous exercise. Such compositional indices are highly instructive for identifying broad regional trends and first-order problems, but they should be used with extreme caution in attempts to quantify processes and magma sources, including crustal components, implicated in these trends.

Andes Mountains, Tatara-San Pedro Volcanic Complex↗
USGS2011

Molybdenite saturation in silicic magmas: Occurrence and petrological implications

We identified molybdenite (MoS 2 ) as an accessory magmatic phase in 13 out of 27 felsic magma systems examined worldwide. The molybdenite occurs as small (< 20 µm) triangular or hexagonal platelets included in quartz phenocrysts. Laser-ablation inductively coupled plasma mass spectrometry analyses of melt inclusions in molybdenite-saturated samples reveal 1–13 ppm Mo in the melt and geochemical signatures that imply a strong link to continental rift basalt–rhyolite associations. In contrast, arc-associated rhyolites are rarely molybdenite-saturated, despite similar Mo concentrations. This systematic dependence on tectonic setting seems to reflect the higher oxidation state of arc magmas compared with within-plate magmas. A thermodynamic model devised to investigate the effects of T , f O 2 and f S 2 on molybdenite solubility reliably predicts measured Mo concentrations in molybdenite-saturated samples if the magmas are assumed to have been saturated also in pyrrhotite. Whereas pyrrhotite microphenocrysts have been observed in some of these samples, they have not been observed from other molybdenite-bearing magmas. Based on the strong influence of f S 2 on molybdenite solubility we calculate that also these latter magmas must have been at (or very close to) pyrrhotite saturation. In this case the Mo concentration of molybdenite-saturated melts can be used to constrain both magmatic f O 2 and f S 2 if temperature is known independently (e.g. by zircon saturation thermometry). Our model thus permits evaluation of magmatic f S 2 , which is an important variable but is difficult to estimate otherwise, particularly in slowly cooled rocks.

Journal of Petrology↗
USGS2005

Volcán Popocatépetl, Mexico. Petrology, magma mixing, and immediate sources of volatiles for the 1994- Present eruption

Volcán Popocatépetl has been the site of voluminous degassing accompanied by minor eruptive activity from late 1994 until the time of writing (August 2002). This contribution presents petrological investigations of magma erupted in 1997 and 1998, including major-element and volatile (S, Cl, F, and H 2 O) data from glass inclusions and matrix glasses. Magma erupted from Popocatépetl is a mixture of dacite (65 wt % SiO 2 , two-pyroxenes + plagioclase + Fe–Ti oxides + apatite, ∼3 wt % H 2 O, P = 1·5 kbar, f O 2 = ΔNNO + 0·5 log units) and basaltic andesite (53 wt % SiO 2 , olivine + two-pyroxenes, ∼3 wt % H 2 O, P = 1–4 kbar). Magma mixed at 4–6 km depth in proportions between 45:55 and 85:15 wt % silicic:mafic magma. The pre-eruptive volatile content of the basaltic andesite is 1980 ppm S, 1060 ppm Cl, 950 ppm F, and 3·3 wt % H 2 O. The pre-eruptive volatile content of the dacite is 130 ± 50 ppm S, 880 ± 70 ppm Cl, 570 ± 100 ppm F, and 2·9 ± 0·2 wt % H 2 O. Degassing from 0·031 km 3 of erupted magma accounts for only 0·7 wt % of the observed SO 2 emission. Circulation of magma in the volcanic conduit in the presence of a modest bubble phase is a possible mechanism to explain the high rates of degassing and limited magma production at Popocatépetl.

Journal of Petrology↗
USGS1983

Structure and petrology of the La Perouse gabbro intrusion, Fairweather Range, southeastern Alaska

The middle Tertiary La Perouse gabbro intrusion occurs in a Mesozoic metamorphic terrane (Chugach terrane) in the Fairweather Range, southeastern Alaska. The intrusion is 12 km wide and 27 km long, and has an exposed cumulate layering thickness of about 6000 m. The contact consists of biotite and hornblende gneiss of the granulite facies, which forms a discontinuous belt as much as 200 m wide. The outer contact of the zone is a fault, along which it is in contact with regionally metamorphosed biotite schist and amphibolite of the amphibolite facies. This fault seems to be a peripheral fault along which the intrusion was uplifted to its present level. The layering in the intrusion forms an asymmetrical funnel that is elongate northwestward and is structurally deepest at the southeast end near Mount La Perouse where the layering has inward dips of as much as 85°. Although the region was probably under compression at the time the gabbro was intruded, there is evidence that the intrusion's extremely sunken form is due not to tectonism but instead to subsidence from magmatic loading at high temperatures that continued after solidification. This tectonism was probably related to the interaction between the north-moving Pacific oceanic plates and the North American continent during the Tertiary. This interaction, which involved long-term right-lateral movement with a compressional component, and possibly minor subduction, on the site of the Fairweather fault, may have controlled the mode of magmatic intrusion and possibly the production of magma at depth, but does not appear to have significantly deformed the intrusion.

Journal of Petrology↗
USGS1991

Petrology of lower crustal and upper mantle xenoliths from the Cima Volcanic Field, California

Basaltic rocks of the Cima volcanic field in the southern Basin and Range province contain abundant gabbro, pyroxenite, and peridotite xenoliths. Composite xenoliths containing two or more rock types show that upper-mantle spinel peridotite was enriched by multiple dike intrusions in at least three episodes; the mantle was further enriched by intergranular and shear-zone melt infiltration in at least two episodes. The oldest dikes, now metamorphosed, are Cr-diopside websterite. Dikes of intermediate age are most abundant at Cima and consist of igneous-textured websterite and two-pyroxene gabbro and microgabbro of tholeiitic or calcalkalic parentage. The youngest dikes are igneous-textured clinopyroxenite, gabbro, and olivine microgabbro of alkalic parentage. The dikes in peridotite are interpreted as parts of a system of conduits through which tholeiitic (or calcalkalic) and alkalic magmas fed lower-crustal intrusions, which are represented by abundant xenoliths of the same igneous rock types as observed in the dikes. Mineral assemblages of dikes in peridotite indicate that an enriched uppermost mantle zone no thicker than 15 km could have been sampled. Because of their high densities, the gabbros and pyroxenites can occupy the zone immediately above the present Moho (modeled on seismic data as 10-13 km thick, with V p 6.8 km/s) only if their seismic velocities are reduced by the joints, partial melts, and fluid inclusions that occur in them. Alternatively, these xenoliths may have been derived entirely from beneath the Moho, in which case the Moho is not the local crust-mantle boundary.

Journal of Petrology↗
USGS2024

Depths in a day - A new era of rapid-response Raman-based barometry using fluid inclusions

Rapid-response petrological monitoring is a major advance for volcano observatories, allowing them to build and validate models of plumbing systems that supply eruptions in near-real-time. The depth of magma storage has recently been identified as high-priority information for volcanic observatories, yet this information is not currently obtainable via petrological monitoring methods on timescales relevant to eruption response. Fluid inclusion barometry (using micro-thermometry or Raman spectroscopy) is a well-established petrological method to estimate magma storage depths and has been proposed to have potential as a rapid-response monitoring tool, although this has not been formally demonstrated. To address this deficiency, we performed a near-real-time rapid-response simulation for the September 2023 eruption of Kīlauea, Hawaiʻi. We show that Raman-based fluid inclusion barometry can robustly determine reservoir depths within a day of receiving samples — a transformative timescale that has not previously been achieved by petrological methods. Fluid inclusion barometry using micro-thermometric techniques has typically been limited to systems with relatively deep magma storage (>0.4 g/cm 3 or >7 km) where measurements of CO 2 density are easy and accurate because the CO 2 fluid homogenizes into the liquid phase. Improvements of the accuracy of Raman spectroscopy measurements of fluids with low CO 2 density over the past couple of decades has enabled measurements of fluid inclusions from shallower magmatic systems. However, one caveat of examining shallower systems is that the fraction of H 2 O in the fluid may be too high to reliably convert CO 2 density to pressure. To test the global applicability of rapid response fluid inclusion barometry, we compiled a global melt inclusion dataset (>4000 samples) and calculate the fluid composition at the point of vapor saturation (⁠X H 2 O⁠ ). We show that fluid inclusions in crystal-hosts from mafic compositions (<57 wt. % SiO 2 ) — likely representative of magmas recharging many volcanic systems worldwide — trap fluids with X H 2 O low enough to make fluid inclusion barometry useful at many of the world’s most active and hazardous mafic volcanic systems (e.g., Iceland, Hawaiʻi, Galápagos Islands, East African Rift, Réunion, Canary Islands, Azores, Cabo Verde).

Hawaii↗
USGS1988

Petrology of ultramafic xenoliths from Loihi Seamount, Hawaii

Ultramafic xenoliths were recovered in four alkalic lava flows from Loihi Seamount at depths between 2200 and 1400m. No xenolith bearing flows were sampled near the summit despite a concentrated dredge program. The flows, three of alkalic basalt and one of basanite, contain common olivine megacrysts and small xenoliths of dunite, rarer harzburgite, and a single wehrlite. Olivine megacrysts as large as 8 mm are Fo 84–88 6 and contain magnesiochromite inclusions with 1·1–3·5 wt.% TiO 2 Dunite contains Fo 83 5–88·5 olivine, magnesiochromite with l·5–6·9 wt.% TiO 2 (avg. 3·2 wt.%), and extremely rare chrome-rich diopside. The wehrlite contains euhedral Fo 85 9 olivine and magnesiochromite with 1·9–4·7 wt.% TiO 2 poikilitically enclosed in chrome-rich diopside (Wo 45 4 En 48 0 Fs 6·6 ).Most of the olivine megacrysts, dunite, and the wehrlite are cumulates of Loihi alkalic lavas that accumulated in a magma storage zone located at least 16km below sea level. The rarity of dunite related to tholeiitic magmas supports the interpretation that the alkalic lavas at Loihi generally predate the tholeiitic lavas. The harzburgite xenoliths have cataclastic textures and contain Fo 89 5–92 6 olivine, enstatite (Wo 2 0–2·7 En 90·0–88 7 Fe 8·0–8·6 ), Cr-rich endiopside (Wo 43 4–44 5 En 52 0–50 0 Fs 4 6–4 5 ), and translucent red-brown magnesiochromite. The harzburgite xenoliths, which have 2-pyroxene temperatures of 1066 ± 35°C, originated in the uppermost mantle in a region of high strain rate, probably near the boundary between the mantle and the overlying ocean crust. The presence of upper mantle xenoliths indicates that the magma storage zone is located below the base of the ocean crust within the uppermost mantle.

Journal of Petrology↗
USGS1992

Petrology of the Caribou Mountain Pluton, Klamath Mountains, California

The Caribou Mountain pluton is a small trondhjemitic body that intruded semipelitic schist of the Stuart Fork terrane in late Middle Jurassic to Early Cretaceous time. Its emplacement followed the intrusion of an adjoining body of hornblende quartz diorite called the Middle Fork pluton and the mode of its emplacement was as an asymmetric ballooning diapir (Davis, 1963), as shown by concentric foliation, radial late-stage dikes, foliated enclaves, and folded blocks of schlieren-banded tonalite. Coarse-grained hornblende-bearing trondhjemite is the dominant rock type in the Caribou Mountain pluton, and it is called the ‘main trondhjemite’. It was followed by medium-grained ‘late trondhjemite’ and by late-stage trondhjemitic and granodioritic dikes. All the trondhjemitic rock types are characterized by low alkali contents, high light rare earth elements, low initial 87 Sr/ 86 Sr, and low δ 18 O. However, the late trondhjemite has higher Na 2 O and a higher initial 87 Sr/ 86 Sr value than the main trondhjemite, and the two units cannot be related by fractional crystallization. The late granodioritic dikes are richer in Ba, Rb, Y, and Sc than the late trondhjemite and probably reflect assimilation of Stuart Fork metasedimentary rocks by late-stage trondhjemitic magma. Mafic enclaves in the main trondhjemite contain xenocrysts of quartz and plagioclase derived from the host by magma mixing. The enclaves have K 2 O, Ba, and Rb contents similar to, or higher than those of the host rocks. Their rare earth element (REE) patterns display strong middle REE enrichment caused by accumulation of hornblende, probably as the result of filter pressing. The main trondhjemite cannot be derived from Middle Fork magma because the initial 87 Sr/ 86 Sr of the Middle Fork pluton is lower than that of the trondhjemite. The absence of parental mafic magmas of appropriate composition suggests that the Caribou Mountain trondhjemitic magmas formed by partial melting of an amphibolitic source rock compositionally similar to low-K tholeiite.

California↗
USGS1982

Petrology and trace element geochemistry of the Honolulu volcanics, Oahu: Implications for the oceanic mantle below Hawaii

The Honolulu Volcanics comprises small volume, late-stage (post-erosional) vents along rifts cutting the older massive Koolau tholeütic shield on Oahu, Hawaii. Most of these lavas and tuff of the Honolulu Volcanics have geochemical features expected of near-primary magmas derived from a peridotite source containing Fo 87–89 olivine; e. g. 100 Mg/(Mg + Fe 2+ ) >65, >250 p. p. m. Ni, and presence of ultramafic mantle xenoliths at 18 of the 37 vents. Consequently, the geochemistry of the alkali olivine basalt, basanite, nephelinite and nepheline melilitite lavas and tuff of the Honolulu Volcanics have been used to deduce the composition of their mantle source and the conditions under which they were generated by partial melting in the mantle. Compositional trends in 30 samples establish that the magmas were derived by partial melting of a garnet (<10 per cent) Iherzolite source, which we infer to have been carbon-bearing, from analogy with experimental results. This source was isotopically homogeneous (Sr, Lanphere & Dalrymple, 1980; Pb, Sun, 1980; Nd, Roden et al ., 1981), and we infer that the source was compositionally uniform in all major-element oxides except TiO 2 , in compatible trace elements (Sc, V, Cr, Mn, Co and Ni), and in highly incompatible trace elements (P, Th, La, Ce). However, the source appears to have been heterogeneous in TiO 2 , Zr, Hf, Nb, and Ta, elements that were not strongly incompatible during partial melting. Some nepheline melilitite samples may be derived from a source with distinct Sc and heavy-rare-earth-elements (REE) abundances, or which had a phase or phases controlling the distribution of these elements. The relatively limited abundance range for several elements, such as Ti, Zr, Nb, is partly a consequence of the low degrees of melting inferred for the series (2 per cent for nepheline melilitite, 11 per cent for alkali olivine basalt), which failed to exhaust the source in minor residual phases. We infer that these residual phases probably included phlogopite, amphibole, and another Ti-rich phase (an oxide?), but not apatite.

Journal of Petrology↗