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Preface: Marine gas hydrate reservoir systems along the eastern continental margin of India: Results of the National Gas Hydrate Program Expedition 02

The 2015 India National Gas Hydrate Program (NGHP) Expedition 02 was conducted to obtain new information on the occurrence of gas hydrate systems and to advance the understanding of geologic controls on the formation of gas hydrate accumulations in the offshore of India. The ultimate goal of the NGHP effort is to assess the energy resource potential of marine gas hydrates in India. The Guest Editors for this special thematic issue of the Journal of Marine and Petroleum Geology (JMPG) have worked with more than 100 scientists and engineers to prepare the 45 individual reports included in this special issue to address the operational and technical contributions of the NGHP-02 Expedition. This thematic issue on natural gas hydrates in the offshore of India is built on the foundation of five previous JMPG thematic issues that focused on the scientific results of other marine gas hydrate expeditions. These foundational contributions include: (1) the “Scientific Results of the 2005 USDOE-Chevron JIP Drilling for Methane Hydrates Objectives in the Gulf of Mexico” (Volume 25, Issue 9, November 2008), (2) the “Resource and Hazard Implications of Gas Hydrates in the Northern Gulf of Mexico: Results of the 2009 Joint Industry Project Leg II Drilling Expedition” (Volume 34, Issue 1, June 2012), (3) the “Scientific Results of the Second Gas Hydrate Drilling Expedition in the Ulleung Basin (UBGH2), East Sea of Korea” (Volume 47, November 2013), (4) “Geologic Implications of Gas Hydrates in the Offshore of India: Results of the National Gas Hydrate Program Expedition 01” (Volume 58, Part A, December 2014), and (5) “Gas Hydrate Drilling in Eastern Nankai” (Volume 66, Part 2, September 2015). The NGHP-02 Expedition was conducted from 03-March- 2015 to 28-July- 2015 off the eastern coast of India. The first two months of the expedition were dedicated to establishing 25 new research sites that featured the drilling of a dedicated downhole logging hole at each site. The next three months of the NGHP-02 Expedition were dedicated to sediment coring and other downhole measurement operations at 10 of the sites established during the expedition’s first phase. The results of downhole logging, coring and formation pressure testing operations during NGHP-02 have confirmed the presence of large, highly concentrated gas hydrate accumulations in coarse-grained, sand-rich depositional systems throughout large portions of the Krishna-Godavari Basin. Post expedition research and reporting efforts included collaborative analysis of the unprecedented number of shipboard acquired data sets and core samples obtained during NGHP-02. The presentation of the scientific results of the NGHP-02 Expedition has culminated in the publication of the NGHP Expedition 02 Scientific Results Volume, which is represented by this Special Issue of the Journal of Marine and Petroleum Geology. This Special Issue features a series of four reports that summarize the operational and scientific results of NGHP-02 Expedition that are presented in the 41 technical reports included this Special Issue. The first summary report, “India National Gas Hydrate Program Expedition 02: Operational and Technical Summary,” focuses on reviewing the tools and operational procedures for the NGHP-02 Expedition that led to the acquisition of an unprecedented amount of high-quality downhole logging and core data from numerous pore-filling, fracture-filling, and sediment-displacement type gas hydrate occurrences. The summary report titled “India National Gas Hydrate Program Expedition 02 Summary of Scientific Results: Gas Hydrate Systems Along the Eastern Continental Margin of India” documents gas hydrate occurrences discovered during the NGHP-02 Expedition and examines geologic controls on the gas hydrate systems along the Eastern Continental Margin of India.

Journal of Marine and Petroleum Geology

Scientific results of the Second Gas Hydrate Drilling Expedition in the Ulleung Basin (UBGH2)

As a part of Korean National Gas Hydrate Program, the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2) was conducted from 9 July to 30 September, 2010 in the Ulleung Basin, East Sea, offshore Korea using the D/V Fugro Synergy. The UBGH2 was performed to understand the distribution of gas hydrates as required for a resource assessment and to find potential candidate sites suitable for a future offshore production test, especially targeting gas hydrate-bearing sand bodies in the basin. The UBGH2 sites were distributed across most of the basin and were selected to target mainly sand-rich turbidite deposits. The 84-day long expedition consisted of two phases. The first phase included logging-while-drilling/measurements-while-drilling (LWD/MWD) operations at 13 sites. During the second phase, sediment cores were collected from 18 holes at 10 of the 13 LWD/MWD sites. Wireline logging (WL) and vertical seismic profile (VSP) data were also acquired after coring operations at two of these 10 sites. In addition, seafloor visual observation, methane sensing, as well as push-coring and sampling using a Remotely Operated Vehicle (ROV) were conducted during both phases of the expedition. Recovered gas hydrates occurred either as pore-filling medium associated with discrete turbidite sand layers, or as fracture-filling veins and nodules in muddy sediments. Gas analyses indicated that the methane within the sampled gas hydrates is primarily of biogenic origin. This paper provides a summary of the operational and scientific results of the UBGH2 expedition as described in 24 papers that make up this special issue of the Journal of Marine and Petroleum Geology.

East Sea Of Korea;Ulleung Basin

Organic metamorphism in the Lower Mississippian-Upper Devonian Bakken shales. Part 1: Rock-Eval pyrolysis and vitrinite reflectance

Detailed organic geochemistry has been performed on a large number of Lower Mississippian-Upper Devonian Bakken shales from the North Dakota portion of the Williston Basin, and 28 oils mainly from Mississippian Madison Group rocks from different basinal areas. Here we report results of Rock-Eval pyrolysis and vitrinite reflectance ( R o ) analyses. Variable paleoheat flows in the Williston Basin caused the threshold of intense hydrocarbon generation to occur at different depths in different basinal areas. In higher paleogeothermal gradient basinal areas, this event occurred at depths of 7,650-8,000 ft, and at 10,000 ft or deeper in lower paleogeothermal gradient areas of the Basin. Distinct organic metamorphic imprints in Williston Basin sediments were also caused by extreme, but variable, paleoheat flows in the basin, as well as secondary migration of crude oils from deep basinal source areas. The high paleoheat flows are postulated as being due to a Late Cretaceous - Paleocene aborted rift event. Only a small volume of Bakken shales in restricted areas of the Williston Basin was responsible for the oil found reservoired in Mississippian Madison Group rocks. However, this small shale volume has been responsible for a relatively large amount of crude oil. R o profiles in the Tertiary through Middle Jurassic rocks in the Williston Basin had steep, linear R o versus depth gradients, with strong reversals of R o values occurring in the Lower Jurassic rocks. The lower Mesozoic through Paleozoic rocks of the Basin had strongly suppressed R o values compared to the values in the Tertiary through Middle Jurassic rocks. This was especially true of the R o values in the Bakken shales. This R o suppression was due to a change in organic matter (OM) type from oxygen-rich terrestrially derived OM in the younger rocks, to a hydrogen-rich marine derived OM in the deeper, older rocks. The threshold of intense oil generation (TIHG) occurred in the Bakken shales of the Williston Basin at R o values somewhere between 0.9 and 1.7% (best estimate 0.9), as would be read in oxygen-rich OM. Much higher burial temperatures (and consequently R o values) than usually held to be necessary were required for both the TIHG as well as mainstage hydrocarbon generation in the Bakken shales. These results are most likely applicable in general to source rocks with hydrogen-rich OM. The data of this study have major implications to petroleum exploration as well as to petroleum resource assessment.

Journal of Petroleum Geology

Oceanic methane hydrate: The character of the Blake Ridge hydrate stability zone, and the potential for methane extraction

Oceanic methane hydrates are mineral deposits formed from a crystalline 'ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by 'freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.Oceanic methane hydrates are mineral sits formed from a crystalline `ice' of methane and water in sea-floor sediments (buried to less than about 1 km) in water depths greater than about 500 m; economic hydrate deposits are probably restricted to water depths of between 1.5 km and 4 km. Gas hydrates increase a sediment's strength both by `freezing' the sediment and by filling the pore spaces in a manner similar to water-ice in permafrost. Concentrated hydrate deposits may be underlain by significant volumes of methane gas, and these localities are the most favourable sites for methane gas extraction operations. Seismic reflection records indicate that trapped gas may blow-out naturally, causing large-scale seafloor collapse. In this paper, we consider both the physical properties and the structural integrity of the hydrate stability zone and the associated free gas deposits, with special reference to the Blake Ridge area, SE US offshore, in order to help establish a suitable framework for the safe, efficient, and economic recovery of methane from oceanic gas hydrates. We also consider the potential effects of the extraction of methane from hydrate (such as induced sea-floor faulting, gas venting, and gas-pocket collapse). We assess the ambient pressure effect on the production of methane by hydrate dissociation, and attempt to predict the likelihood of spontaneous gas flow in a production situation.

Journal of Petroleum Geology

India National Gas Hydrate Program Expedition 02 summary of scientific results: Numerical simulation of reservoir response to depressurization

The India National Gas Hydrate Program Expedition 02 (NGHP-02) discovered gas hydrate at high saturation in sand reservoirs at several sites in the deepwater Bay of Bengal. To assess the potential response of those deposits to scientific depressurization experiments, comprehensive geologic models were constructed to enable numerical simulation for two sites. Both sites (NGHP-02-09 and NGHP-02-16) feature thick sequences of thinly-interbedded reservoir and non-reservoir facies at sub-seafloor depths of less than 300 m and sub-sea depths of 2,400 m or more. These settings pose significant challenges to current modeling capabilities. First, the thinly-bedded reservoir architecture complicates the determination of basic reservoir parameters from both log and core data due to measurement resolution issues. Secondly, the fine-scale variation in sediment properties imparts great contrasts in key parameters over very short distances, creating high gradients at multiple scales and varying orientations that necessitate careful design of high-definition simulation grids. Thirdly, the deposits include internal sources of water, as well as a range of complex boundary conditions, including variable permeability within the overlying mud-rich “seals”, that complicate reservoir depressurization. Lastly, because of the unique combination of great water depth and relatively shallow sub-seafloor depth, models designed to maximize the dissociation rate impose large pressure drawdowns on relatively low-strength sediments. This condition renders the proper evaluation and integration of the geomechanical response to hydrate dissociation critical. In this report, we review the history of gas hydrate reservoir simulation, discuss methods for creating geologic input models, and summarize the key findings and implications of the collaborative NGHP-02 numerical simulation effort. Together, the studies confirm the viability of the modeled accumulations for scientific testing and identify key challenges related to the selection of specific test sites and the design of test wells.

Journal of Marine and Petroleum Geology

National Gas Hydrate Program expedition 02: Identification of gas hydrate prospects in the Krishna-Godavari Basin, offshore India

After completing the first expedition of India's National Gas Hydrate Program (NGHP-01) in 2006, it was concluded that for the next expedition (National Gas Hydrate Program 02; NGHP-02), a new drill site review effort should focus on identifying potential deep-water offshore gas hydrate accumulations in sand dominated depositional environments. Therefore, geological and geophysical data analysis and 3D seismic data interpretation along with associated seismic modeling were carried out in three areas of the Krishna-Godavari Basin: Areas B, C, and E. Conventional petroleum exploration approaches of seismic amplitude evaluation were adapted to prospect for potential sand-rich depositional systems within the gas hydrate stability zone. Subsequently, these prospective areas were further assessed through the geological and geophysical evaluation of depositional setting, gas sources, and gas migration pathways. In Area B, prospecting focused on a large anticlinal structure with a prominent bottom-simulating reflector and several key horizons that indicated evidence for potential sand-hosted hydrate occurrences. In Area C, the prospects were distributed throughout various settings within a very large deep-water channel-levee-fan system with complex indications of potential gas hydrate occurrence in sand-prone seismic facies. In Area E, prospects were associated with high amplitude events within inferred channel-levee sequences. Based on the pre-expedition/onboard drill-site evaluation, the 22 most promising sites in the Krishna-Godavari Basin were identified and prioritized to investigate and delineate a total of 17 identified gas hydrate prospects. This paper describes the geo-scientific studies carried out prior to NGHP-02 for site identification, evaluation and prioritization. An important outcome of this study is the identification of two potentially producible gas hydrate systems inferred to host significant quantity of gas hydrate in stratigraphic-structural traps.

Journal of Marine and Petroleum Geology

India National Gas Hydrate Program Expedition 02 Summary of Scientific Results: Gas hydrate systems along the eastern continental margin of India

The primary objectives of the India National Gas Hydrate Program Expedition 02 (NGHP-02) were to obtain new data on the occurrence of gas hydrate systems and to advance the understanding of the controls on the formation of gas hydrate accumulations in the offshore of India. In accordance with the ultimate overall goal of the NGHP effort to assess the energy resource potential of marine gas hydrates in India, particular focus was placed on the exploration and evaluation of gas hydrate occurrences at high saturations in sand-rich systems. NGHP-02 operations were conducted from 3-March-2015 to 28-July-2015 off the eastern coast of India and included logging while drilling (LWD) operations at 25 locations, and coring and wireline logging operations at 10 locations, in the Krishna-Godavari and Mahanadi Basins. The formation of highly concentrated gas hydrate accumulations, which are more suitable for energy extraction, requires the presence of relatively coarse-grained sediments with porosity needed to support the migration and accumulation of gas, and the nucleation of gas hydrate. The results of downhole logging, coring and formation pressure testing operations during NGHP-02 have confirmed the presence of extensive sand-rich depositional systems throughout the deepwater portions of the Krishna-Godavari and Mahanadi Basins. Two areas of Krishna-Godavari Basin, referred to as Areas B and C, contain substantial gas hydrate accumulations in sand-rich systems and therefore represent ideal candidate sites for future gas hydrate production testing. This summary and technical report includes a comprehensive synthesis of the geologic, geophysical, geochemical, and physical property data acquired during NGHP-02 as it relates to the controls on gas hydrate occurrence, particularly with regards to sand-hosted accumulations. In the Mahanadi Basin, despite the confirmation of extensive reservoir capacity, gas supply at the NGHP-02 sites was insufficient to charge the reservoirs with gas hydrates. In the Krishna-Godavari Basin, extensive reservoir systems were confirmed with sediment grain-sizes ranging from coarse-silts to gravels. These reservoirs range from fully- to partially filled with gas hydrate. The gas is determined to be from only microbial sources, and in part migrated into the reservoirs from deeper systems. The controls on gas hydrate occurrence are complex and varied; and include substantial reservoir heterogeneity and sufficient permeability throughout the reservoirs and seals that allowed pervasive fluid flow into and through the hydrate-bearing systems. These discoveries are the most significant confirmation of the exploration approach that focuses on direct detection of hydrate reservoirs supported by comprehensive petroleum systems analyses.

Journal of Marine and Petroleum Geology

Numerical simulations of depressurization-induced gas production from an interbedded turbidite gas hydrate-bearing sedimentary section in the offshore India: Site NGHP-02-16 (Area-B)

The recent National Gas Hydrate Program Expedition 02 (NGHP-02) identified the existence of gas hydrate-bearing sand reservoirs at a number of sites in the offshore of India including Site NGHP-02-16 in Area-B of the Krishna-Godavari Basin. The architecture of that gas hydrate accumulation is characterized by thin, gas hydrate-bearing, high quality sand layers interbedded with mud layers within a turbidite interval. The lowest gas hydrate-bearing layer contacting a thinly-interbedded saline aquifer designates the base of the gas hydrate stability zone (BGHSZ). The proximity of the BGHSZ and the average temperature around 20oC make the reservoir a favorable target for hydrate destabilization by means of the depressurization method. The results of the reservoir simulations indicate high gas production potential from this marine gas hydrate deposit with manageable concomitant water production using a well completion design that hydraulically isolates layers with water-saturated sands. Using a detailed geological input model, the predicted cumulative gas rates reach 3.1 x 104 m3/day (1.1 mmscf/day) after 90 days of continuous depressurization and demonstrate sustained production rates of 3.0 x 104 m3/day (1.0 mmscf/day) after 5 years of production. The interbedded nature of this gas hydrate occurrence promotes the development of horizontal dissociation interfaces between gas hydrate-bearing sand and mud layers. As a result, non-uniform gas production along the horizontal interfaces becomes a primary determinant of reservoir performance. Simulation cases have been executed to determine the impact of the uncertainty in in situ reservoir permeability and the manner in which intrinsic permeability dynamically changes during dissociation in response to the imposed effective stress increase. The cases where effective permeability is initially low and compaction is highly sensitive to stress result in the least favorable production predictions.

Journal of Marine and Petroleum Geology

An international code comparison study on coupled thermal, hydrologic and geomechanical processes of natural gas hydrate-bearing sediments

Geologic reservoirs containing gas hydrate occur beneath permafrost environments and within marine continental slope sediments, representing a potentially vast natural gas source. Numerical simulators provide scientists and engineers with tools for understanding how production efficiency depends on the numerous, interdependent (coupled) processes associated with potential production strategies for these gas hydrate reservoirs. Confidence in the modeling and forecasting abilities of these gas hydrate reservoir simulators (GHRSs) grows with successful comparisons against laboratory and field test results, but such results are rare, particularly in natural settings. The hydrate community recognized another approach to building confidence in the GHRS: comparing simulation results between independently developed and executed computer codes on structured problems specifically tailored to the interdependent processes relevant for gas hydrate-bearing systems. The United States Department of Energy, National Energy Technology Laboratory (DOE/NETL), sponsored the first international gas hydrate code comparison study, IGHCCS1, in the early 2000s. IGHCCS1 focused on coupled thermal and hydrologic processes associated with producing gas hydrates from geologic reservoirs via depressurization and thermal stimulation. Subsequently, GHRSs have advanced to model more complex production technologies and incorporate geomechanical processes into the existing framework of coupled thermal and hydrologic modeling. This paper contributes to the validation of these recent GHRS developments by providing results from a second GHRS code comparison study, IGHCCS2, also sponsored by DOE/NETL. IGHCCS2 includes participants from an international collection of universities, research institutes, industry, national laboratories, and national geologic surveys. Study participants developed a series of five benchmark problems principally involving gas hydrate processes with geomechanical components. The five problems range from simple geometries with analytical solutions to a representation of the world’s first offshore production test of methane hydrates, which was conducted with the depressurization method off the coast of Japan. To identify strengths and limitations in the various GHRSs, study participants submitted solutions for the benchmark problems and discussed differing results via teleconferences. The GHRSs evolved over the course of IGHCCS2 as researchers modified their simulators to reflect new insights, lessons learned, and suggested performance enhancements. The five benchmark problems, final sample solutions, and lessons learned that are presented here document the study outcomes and serve as a reference guide for developing and testing gas hydrate reservoir simulators.

Journal of Marine and Petroleum Geology

Comparison of the physical and geotechnical properties of gas-hydrate-bearing sediments from offshore India and other gas-hydrate-reservoir systems

The sediment characteristics of hydrate-bearing reservoirs profoundly affect the formation, distribution, and morphology of gas hydrate. The presence and type of gas, porewater chemistry, fluid migration, and subbottom temperature may govern the hydrate formation process, but it is the host sediment that commonly dictates final hydrate habit, and whether hydrate may be economically developed. In this paper, the physical properties of hydrate-bearing regions offshore eastern India (Krishna-Godavari and Mahanadi Basins) and the Andaman Islands, determined from Expedition NGHP-01 cores, are compared to each other, well logs, and published results of other hydrate reservoirs. Properties from the hydrate-free Kerala-Konkan basin off the west coast of India are also presented. Coarser-grained reservoirs (permafrost-related and marine) may contain high gas-hydrate-pore saturations, while finer-grained reservoirs may contain low-saturation disseminated or more complex gas-hydrates, including nodules, layers, and high-angle planar and rotational veins. However, even in these fine-grained sediments, gas hydrate preferentially forms in coarser sediment or fractures, when present. The presence of hydrate in conjunction with other geologic processes may be responsible for sediment porosity being nearly uniform for almost 500 m off the Andaman Islands. Properties of individual NGHP-01 wells and regional trends are discussed in detail. However, comparison of marine and permafrost-related Arctic reservoirs provides insight into the inter-relationships and common traits between physical properties and the morphology of gas-hydrate reservoirs regardless of location. Extrapolation of properties from one location to another also enhances our understanding of gas-hydrate reservoir systems. Grain size and porosity effects on permeability are critical, both locally to trap gas and regionally to provide fluid flow to hydrate reservoirs. Index properties corroborate more advanced consolidation and triaxial strength test results and can be used for predicting behavior in other NGHP-01 regions. Pseudo-overconsolidation is present near the seafloor and is underlain by underconsolidation at depth at some NGHP-01 locations.

Journal of Marine and Petroleum Geology

Physical properties of sediment from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

This study characterizes cored and logged sedimentary strata from the February 2007 BP Exploration Alaska, Department of Energy, U.S. Geological Survey (BPXA-DOE-USGS) Mount Elbert Gas Hydrate Stratigraphic Test Well on the Alaska North Slope (ANS). The physical-properties program analyzed core samples recovered from the well, and in conjunction with downhole geophysical logs, produced an extensive dataset including grain size, water content, porosity, grain density, bulk density, permeability, X-ray diffraction (XRD) mineralogy, nuclear magnetic resonance (NMR), and petrography. This study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate. Gas hydrate (GH) occurs in three unconsolidated, coarse silt to fine sand intervals within the Paleocene and Eocene beds of the Sagavanirktok Formation: Unit D-GH (614.4 m-627.9 m); unit C-GH1 (649.8 m-660.8 m); and unit C-GH2 (663.2 m-666.3 m). These intervals are overlain by fine to coarse silt intervals with greater clay content. A deeper interval (unit B) is similar lithologically to the gas-hydrate-bearing strata; however, it is water-saturated and contains no hydrate. In this system it appears that high sediment permeability (k) is critical to the formation of concentrated hydrate deposits. Intervals D-GH and C-GH1 have average "plug" intrinsic permeability to nitrogen values of 1700 mD and 675 mD, respectively. These values are in strong contrast with those of the overlying, gas-hydrate-free sediments, which have k values of 5.7 mD and 49 mD, respectively, and thus would have provided effective seals to trap free gas. The relation between permeability and porosity critically influences the occurrence of GH. For example, an average increase of 4% in porosity increases permeability by an order of magnitude, but the presence of a second fluid (e.g., methane from dissociating gas hydrate) in the reservoir reduces permeability by more than an order of magnitude.

Alaska

Hydro-bio-geomechanical properties of hydrate-bearing sediments from Nankai Trough

Natural hydrate-bearing sediments from the Nankai Trough, offshore Japan, were studied using the Pressure Core Characterization Tools (PCCTs) to obtain geomechanical, hydrological, electrical, and biological properties under in situ pressure, temperature, and restored effective stress conditions. Measurement results, combined with index-property data and analytical physics-based models, provide unique insight into hydrate-bearing sediments in situ. Tested cores contain some silty-sands, but are predominantly sandy- and clayey-silts. Hydrate saturations S h range from 0.15 to 0.74, with significant concentrations in the silty-sands. Wave velocity and flexible-wall permeameter measurements on never-depressurized pressure-core sediments suggest hydrates in the coarser-grained zones, the silty-sands where S h exceeds 0.4, contribute to soil-skeletal stability and are load-bearing. In the sandy- and clayey-silts, where S h < 0.4, the state of effective stress and stress history are significant factors determining sediment stiffness. Controlled depressurization tests show that hydrate dissociation occurs too quickly to maintain thermodynamic equilibrium, and pressure–temperature conditions track the hydrate stability boundary in pure-water, rather than that in seawater, in spite of both the in situ pore water and the water used to maintain specimen pore pressure prior to dissociation being saline. Hydrate dissociation accompanied with fines migration caused up to 2.4% vertical strain contraction. The first-ever direct shear measurements on never-depressurized pressure-core specimens show hydrate-bearing sediments have higher sediment strength and peak friction angle than post-dissociation sediments, but the residual friction angle remains the same in both cases. Permeability measurements made before and after hydrate dissociation demonstrate that water permeability increases after dissociation, but the gain is limited by the transition from hydrate saturation before dissociation to gas saturation after dissociation. In a proof-of-concept study, sediment microbial communities were successfully extracted and stored under high-pressure, anoxic conditions. Depressurized samples of these extractions were incubated in air, where microbes exhibited temperature-dependent growth rates.

Journal of Marine and Petroleum Geology

Permeability anisotropy and relative permeability in sediments from the National Gas Hydrate Program Expedition 02, offshore India

Gas and water permeability through hydrate-bearing sediments essentially governs the economic feasibility of gas production from gas hydrate deposits. Characterizing a reservoir’s permeability can be difficult because even collocated permeability measurements can vary by 4-5 orders of magnitude, due partly to differences between how various testing methods inherently measure permeability in different directions and at different scales. This study uses a customized flow anisotropy cell to investigate geomechanical and hydrological properties of hydrate-bearing sediments focusing on permeability anisotropy (i.e., horizontal, kh, to vertical, kv, permeability ratio) and relative permeability. Two cores recovered during India’s National Gas Hydrate Program Expedition 02 (NGHP-02) are tested in this study. Near in situ effective vertical stress, ~ 2MPa, the permeability anisotropy is approximately kh/kv = 1.86 for the “seal core” (from a fine-grained non-reservoir overburden sedimentary section) and kh/kv = 4.24 for the gas hydrate reservoir score with tetrahydrofuran (THF) hydrate saturation Sh = 0.8. Permeability anisotropy increases exponentially with effective vertical stress, as described by kh/kv = α(σv/MPa)^β, with α = 1.6, β = 0.22 for seal sediment and α = 3, β = 0.5 for THF hydrate-bearing sediment. Results imply the measured permeability from permeameter tests with vertical flow may underestimate the reservoir’s flow performance, which is mainly horizontal (radial) toward a vertical well. Hydrates in sediment increase the gas-entry pressure and residual water saturation, but decrease the water retention curve’s shape factor (m), resulting in a steeper curve. Distributions of available pore space sizes for flow in sediment with and without THF hydrate (Sh = 0.8) follow a log-normal distribution. Hydrate formation decreases the apparent mean pore size from ~10 µm to ~2 µm, without evidently changing the pore size distribution's standard deviation. Gas hydrate dissociation increases effective permeability and relative permeability to gas.

Journal of Marine and Petroleum Geology

2D micromodel study of clogging behavior of fine-grained particles associated with gas hydrate production in NGHP-02 gas hydrate reservoir sediments

Fine-grained particles (fines) commonly coexist with coarse-grained sediments that host gas hydrate. These fines can be mobilized by liquid and gas flow during gas hydrate production. Once mobilized, fines can clog pore throats and reduce reservoir permeability. Even where particle sizes are smaller than pore-throat sizes, clogs can form due to clusters of fines. For certain types of fines, particularly swelling clays, cluster sizes depend on pore-fluid chemistry, which changes as pore-fluid freshens during gas hydrate dissociation. Fines can also be concentrated by a moving gas/liquid interface, increasing the chances of pore-throat clogging regardless of fines type. To test the relative significance of these clogging mechanisms, 2D micromodel experiments have been conducted with different pore-throat widths (20, 40, 60 and 100 m), single-phase pore-fluids (deionized water and 2M-sodium-chloride solution), and moving gas/liquid interfaces on specimens from Sites NGHP-02-09 and NGHP-02-16 (NGHP-02: National Gas Hydrate Program Expedition 02) as well as a selection of pure fines (silica silt, mica, calcium carbonate, diatoms, kaolin, and bentonite). Clogging depended on the ratio of particle-to-pore throat size, and also on pore-fluid chemistry because the pore-fluid chemistry changes effectively increased or decreased the fines cluster size relative to the pore-throat width. These interactions can be predicted based on the fines electrical sensitivity (defined by Jang and Santamarina, 2016). The fine-grained sediment component (grain size < 75 m) from the primary gas hydrate reservoir layers at Sites NGHP-02-09 and -16 show clogging via blocking or size exclusion (sieving) due to the large particles. Clogs also formed due to bridging or blocking by clusters of the smaller particles. Clogging generally occurred for pore-water sediment concentrations so low (0.2% by mass or less), that it was difficult to resolve the enhanced clogging in the presence of the gas/liquid meniscus.

Bay of Bengal

India National Gas Hydrate Program Expedition 02 summary of scientific results: Evaluation of natural gas hydrate-bearing pressure cores

India’s National Gas Hydrate Program (NGHP) Expedition-02 was conducted in 2015 with the goal of investigating numerous locations that had been determined to be prospective for gas hydrate at high saturation in sand-rich reservoirs. Initial logging while drilling data revealed extensive sand-rich gas hydrate occurrences at multiple drill sites in two broad areas. These sites were further investigated through the acquisition and analyses of pressure cores designed to document 1) gas hydrate occurrence within the reservoirs; 2) the petrophysical nature of the reservoir and associated seals, in their native state as well as during and after the dissociation of gas hydrate; 3) the geomechanical nature of the reservoir and seals; and 4) the geochemical nature of reservoir fluids. The cores were initially evaluated at sea, and select subsamples were transferred for more extensive analyses at specialized laboratories both in Japan and in the United States. The samples encompassed a wide range of gas hydrate saturation (from 0 to 100%) within reservoir sediments ranging from sandy silts to gravels, providing opportunities to extend and refine insights into the nature of gas hydrate reservoirs gained in previous programs. Select findings and implications of this coordinated pressure-core evaluation program are reported in numerous papers within the NGHP-02 Special Thematic Volume and are summarized here with respect to the following issues: the evaluation and mitigation of core disturbance, the assessment of gas hydrate occurrence and saturation, the geomechanics and petrophysics of both reservoirs and “seals” in situ, and the potential dynamic geomechanical and petrophysical behavior of reservoir and seals during production.

Journal of Marine and Petroleum Geology

India National Gas Hydrate Program Expedition-02: Operational and technical summary

The India National Gas Hydrate Program is being steered by the government of India's Ministry of Petroleum and Natural Gas (MoPNG) with participation of Directorate General of Hydrocarbons (DGH), Oil and Natural Gas Corporation Limited (ONGC), and the National Oil Companies and Research Institutes of India. The India National Gas Hydrate Program Expedition 01 (NGHP-01) established the presence of gas hydrate in the Krishna Godavari (KG) and Mahanadi Basins and in the offshore area of the Andaman Sea Basin. However, the gas hydrates discovered during NGHP-01 were mainly distributed as fracture-filling material in fine-grained clay-rich sediments. The India National Gas Hydrate Program Expedition 02 (NGHP-02) was carried out with an objective to discover gas hydrate in sand-rich sediment along the eastern offshore margin of India. ONGC planned and executed NGHP-02 on the behalf of the MoPNG. NGHP-02 started on March 3, 2015 and was completed on July 28, 2015 (total 147 days) using the Japanese scientific Drilling Vessel Chikyu (D/V Chikyu). During NGHP-02, 42 holes at 25 sites were drilled, cored, and/or surveyed with downhole logging tools. These sites were located in four areas along the eastern margin of India and formally named Area A (Mahanadi Basin, three sites), Area B (northern part of the KG-Basin, twelve sites), Area C (central part of the KG-Basin, six sites), and Area E (southern part to the KG-Basin, four sites). All 25 sites established during NGHP-02 were first drilled and logged with logging-while-drilling (LWD) tools and an additional 17 holes were then drilled and/or cored with conventional coring tools (HPCS/ESCS) or pressure coring tools (PCTB). Wireline logging was conducted in 10 holes and formation tests using a dual packer Modular Formation Dynamics Tester (MDT) tool were carried out in two holes. The onboard science team used the laboratory facilities on the D/V Chikyu to examine and analyse the physical properties, geochemistry, and sedimentology of all the cores collected during the expedition. Core samples were also analysed in additional post-expedition shore-based studies conducted in numerous domestic and international gas hydrate research laboratories. The NGHP-02 sediment cores were archived at the National Gas Hydrate Core Repository in Mumbai (India), which is associated with the ONGC Gas Hydrate Research and Technology Centre (GHRTC). The necessary data for characterizing the occurrence of gas hydrate, such as interstitial water chlorinities, core-derived gas chemistry, physical and sedimentological properties, thermal images of the recovered cores, pressure core and downhole measured logging data (LWD and/or conventional wireline log data), were obtained from most of the drill sites established during NGHP-02. Almost all the drill sites yielded evidence for the occurrence of gas hydrate; however, the inferred in situ concentration of gas hydrate varied substantially from site to site. For the most part, the interpretation of downhole logging data, core thermal images, interstitial water analyses, and pressure core images from the sites established during NGHP-02 indicate that the occurrence of concentrated gas hydrate is mostly associated with coarser grained (sand-rich) sediments. This paper presents the operational and technical summary of NGHP-02. NGHP-02 started on March 3, 2015 and was completed on July 28, 2015 (total 147 days) using the Japanese scientific Drilling Vessel Chikyu (D/V Chikyu). During NGHP-02, 42 holes at 25 sites were drilled, cored, and/or surveyed with downhole logging tools. These sites were located in four areas along the eastern margin of India and formally named Area A (Mahanadi Basin, three sites), Area B (northern part of the KG-Basin, twelve sites), Area C (central part of the KG-Basin, six sites), and Area E (southern part to the KG-Basin, four sites). All 25 sites established during NGHP-02 were first drilled and logged with logging-while-drilling (LWD) to

Journal of Marine and Petroleum Geology