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Climate change and the global redistribution of biodiversity: Substantial variation in empirical support for expected range shifts

Background Among the most widely predicted climate change-related impacts to biodiversity are geographic range shifts, whereby species shift their spatial distribution to track their climate niches. A series of commonly articulated hypotheses have emerged in the scientific literature suggesting species are expected to shift their distributions to higher latitudes, greater elevations, and deeper depths in response to rising temperatures associated with climate change. Yet, many species are not demonstrating range shifts consistent with these expectations. Here, we evaluate the impact of anthropogenic climate change (specifically, changes in temperature and precipitation) on species’ ranges, and assess whether expected range shifts are supported by the body of empirical evidence. Methods We conducted a Systematic Review, searching online databases and search engines in English. Studies were screened in a two-stage process (title/abstract review, followed by full-text review) to evaluate whether they met a list of eligibility criteria. Data coding, extraction, and study validity assessment was completed by a team of trained reviewers and each entry was validated by at least one secondary reviewer. We used logistic regression models to assess whether the direction of shift supported common range-shift expectations (i.e., shifts to higher latitudes and elevations, and deeper depths). We also estimated the magnitude of shifts for the subset of available range-shift data expressed in distance per time (i.e., km/decade). We accounted for methodological attributes at the study level as potential sources of variation. This allowed us to answer two questions: (1) are most species shifting in the direction we expect (i.e., each observation is assessed as support/fail to support our expectation); and (2) what is the average speed of range shifts? Review findings We found that less than half of all range-shift observations (46.60%) documented shifts towards higher latitudes, higher elevations, and greater marine depths, demonstrating significant variation in the empirical evidence for general range shift expectations. For the subset of studies looking at range shift rates, we found that species demonstrated significant average shifts towards higher latitudes (average = 11.8 km/dec) and higher elevations (average = 9 m/dec), although we failed to find significant evidence for shifts to greater marine depths. We found that methodological factors in individual range-shift studies had a significant impact on the reported direction and magnitude of shifts. Finally, we identified important variation across dimensions of range shifts (e.g., greater support for latitude and elevation shifts than depth), parameters (e.g., leading edge shifts faster than trailing edge for latitude), and taxonomic groups (e.g., faster latitudinal shifts for insects than plants). Conclusions Despite growing evidence that species are shifting their ranges in response to climate change, substantial variation exists in the extent to which definitively empirical observations confirm these expectations. Even though on average, rates of shift show significant movement to higher elevations and latitudes for many taxa, most species are not shifting in expected directions. Variation across dimensions and parameters of range shifts, as well as differences across taxonomic groups and variation driven by methodological factors, should be considered when assessing overall confidence in range-shift hypotheses. In order for managers to effectively plan for species redistribution, we need to better account for and predict which species will shift and by how much. The dataset produced for this analysis can be used for future research to explore additional hypotheses to better understand species range shifts.

Journal of Environmental Evidence

Effects of mining-associated lead and zinc soil contamination on native floristic quality

We assessed the quality of plant communities across a range of lead (Pb) and zinc (Zn) soil concentrations at a variety of sites associated with Pb mining in southeast Missouri, USA. In a novel application, two standard floristic quality measures, Mean Coefficient of Conservatism (Mean C) and Floristic Quality Index (FQI), were examined in relation to concentrations of Pb and Zn, soil nutrients, and other soil characteristics. Nonmetric Multidimensional Scaling and Regression Tree Analyses identified soil Pb and Zn concentrations as primary explanatory variables for plant community composition and indicated negative relationships between soil metals concentrations and both Mean C and FQI. Univariate regression also demonstrated significant negative relationships between metals concentrations and floristic quality. The negative effects of metals in native soils with otherwise relatively undisturbed conditions indicate that elevated soil metals concentrations adversely affect native floristic quality where no other human disturbance is evident.

Missouri

Ecovoltaic solar energy development effects to microclimate, temperature, and soil moisture in panel array interspaces in a warm desert

Solar energy development is increasing in warm deserts of the southwestern United States, and ecovoltaics has emerged as an approach to maintain ecosystem function within solar facilities while meeting increasing regional energy demands. The Solar Gemini Project, located in the northeastern Mojave Desert, USA, is one of largest photovoltaic facilities incorporating an ecovoltaics approach, including novel installation practices to reduce disturbance to soil and vegetation and solar tracking bifacial photovoltaic panels to maximize energy generation. To further understand the influence of the facility on environmental conditions, we compared microclimate, temperature, and soil moisture in bare soil interspaces between panel arrays inside the facility to undisturbed desert in nearby areas outside the facility from June 2023–February 2025. Our comparisons included different seasons (summer versus winter), soil depth (shallow versus deep), and facility operation (inactive versus active panels with solar-tracking). We found lower solar radiation, wind speed, and evaporative demand inside the facility compared to outside the facility, with greater differences when panels were actively tracking. When panels were active, air temperature inside and outside the facility was similar on average, but was higher inside the facility during the day and lower at night. Soil surface temperature was lower inside the facility due to panel shading in the morning and evening, whereas soil temperature (0–15 cm) was consistently higher inside the facility. Soil moisture was higher inside the facility and did not drop to the low levels observed outside the facility. In total, we found lower evaporative demand, less heat loading, and higher soil moisture inside the Gemini facility, potentially benefitting flora and fauna in the harsh desert landscape. Yet, we also found daytime increases in air and soil surface temperature inside the facility, and persistent increases to soil temperature. These findings highlight the potentially positive and negative environmental changes associated with ecovoltaics solar energy development in warm deserts and provide evidence that can inform the optimization of solar photovoltaics design and management.

Nevada

Reversible reduction of estrone to 17β-estradiol by Rhizobium, Sphingopyxis, and Pseudomonas isolates from the Las Vegas Wash

Environmental endocrine-disrupting compounds (EDCs) are a growing concern as studies reveal their persistence and detrimental effects on wildlife. Microorganisms are known to affect the transformation of steroid EDCs; however, the diversity of estrogen-degrading microorganisms and the range of transformations they mediate remain relatively little studied. In mesocosms, low concentrations of added estrone (E1) and 17β-estradiol (E2) were removed by indigenous microorganisms from Las Vegas Wash water within 2 wk. Three bacterial isolates, Rhizobium sp. strain LVW-9, Sphingopyxis sp. strain LVW-12, and Pseudomonas sp. strain LVW-PC, were enriched from Las Vegas Wash water on E1 and E2 and used for EDC transformation studies. In the presence of alternative carbon sources, LVW-9 and LVW-12 catalyzed near-stoichiometric reduction of E1 to E2 but subsequently reoxidized E2 back to E1; whereas LVW-PC minimally reduced E1 to E2 but effectively oxidized E2 to E1 after a 20-d lag. In the absence of alternative carbon sources, LVW-12 and LVW-PC oxidized E2 to E1. This report documents the rapid and sometimes reversible microbial transformation of E1 and E2 and the slow degradation of 17α-ethinylestradiol in urban stream water and extends the list of known estrogen-transforming bacteria to the genera Rhizobium and Sphingopyxis . These results suggest that discharge of steroid estrogens via wastewater could be reduced through tighter control of redox conditions and may assist in future risk assessments detailing the environmental fate of estrogens through evidence that microbial estrogen transformations may be affected by environmental conditions or growth status.

Nevada

Great lakes embryo mortality, edema, and deformities syndrome (glemeds) in colonial fish-eating birds: Similarity to chick-edema disease

Several species of colonial fish-eating birds nesting in the Great Lakes basin Includ-ing herring gulls, common terns and double-crested cormorants, have exhibited chronic impairment of reproduction. In addition to eggshell thinning caused by high levels of DDT and metabolites, the reproductive impairment is characterized by high embryonic and chick mortality , edema, growth retardation, and deformities, hence the name Great Lakes embryo mortality , edema, and deformities syndrome (GLEMEDS). The hypothesis has been advanced that GLEMEDS in colonial fish-eating birds resembles chick-edema disease of poultry and has been caused by exposure to chick- edema active compounds that have a common mode of action through the cytochrome P-448 system. Detailed evidence has been collected from the following three groups of studies on herring gulls in the lower Great Lakes during the early 1970s; Forster’s terns in Green Bay, Wisconsin in 1983; and double-crested cormorants and Caspian terns in various locations in the upper Great Lakes from 1986 onwards. It has proved difficult to establish not only the onset of the disease in the various species at various locations but also the period in which chick-edema active compounds were released. Anecdotal evidence suggested that serious egg mortality . © 1988 by Hemisphere Publishing Corporation.

Illinois, Indiana, Michigan, Wisconsin, Minnesota,

The supply and demand for pollution control: Evidence from wastewater treatment

This paper analyzes the determination of pollution control from wastewater treatment plants as an economic decision facing local or regional regulators. Pollution control is measured by plant design effluent concentration levels and is fully endogenous in a supply- and-demand model of treatment choice. On the supply side, plant costs are a function of the design treatment level of the plant, and on the demand side, treatment level is a function of both the costs of control and the regional or regulatory preferences for control. We find evidence that the economic model of effluent choice by local regulators has a good deal of explanatory power. We find evidence that wastewater treatment plant removal of biological oxygen demand (BOD) is sensitive to many local factors including the size of the treatment plant, the flow rate of the receiving water, the population density of the surrounding area, regional growth, state sensitivity to environmental issues, state income, and the extent to which the damages from pollution fall on other states. We find strong evidence that regulators are sensitive to capital costs in determining the design level of BOD effluent reduction at a plant. Thus, proposed reductions in federal subsidies for wastewater treatment plant construction are likely to have significant adverse effects on water quality.

Journal of Environmental Economics and Management

Contrasting nitrogen fate in watersheds using agricultural and water quality information

Surplus nitrogen (N) estimates, principal component analysis (PCA), and end-member mixing analysis (EMMA) were used in a multisite comparison contrasting the fate of N in diverse agricultural watersheds. We applied PCA-EMMA in 10 watersheds located in Indiana, Iowa, Maryland, Nebraska, Mississippi, and Washington ranging in size from 5 to 1254 km 2 with four nested watersheds. Watershed Surplus N was determined by subtracting estimates of crop uptake and volatilization from estimates of N input from atmospheric deposition, plant fixation, fertilizer, and manure for the period from 1987 to 2004. Watershed average Surplus N ranged from 11 to 52 kg N ha −1 and from 9 to 32% of N input. Solute concentrations in streams, overland runoff, tile drainage, groundwater (GW), streambeds, and the unsaturated zone were used in the PCA-EMMA procedure to identify independent components contributing to observed stream concentration variability and the end-members contributing to streamflow and NO 3 load. End-members included dilute runoff, agricultural runoff, benthic-processing, tile drainage, and oxic and anoxic GW. Surplus N was larger in watersheds with more permeable soils (Washington, Nebraska, and Maryland) that allowed greater infiltration, and oxic GW was the primary source of NO 3 load. Subsurface transport of NO 3 in these watersheds resulted in some removal of Surplus N by denitrification. In less permeable watersheds (Iowa, Indiana, and Mississippi), NO 3 was rapidly transported to the stream by tile drainage and runoff with little removal. Evidence of streambed removal of NO 3 by benthic diatoms was observed in the larger watersheds.

Indiana, Iowa, Maryland, Nebraska, Mississippi, Wa

Ecosystem consequences of fish parasites

In most aquatic ecosystems, fishes are hosts to parasites and, sometimes, these parasites can affect fish biology. Some of the most dramatic cases occur when fishes are intermediate hosts for larval parasites. For example, fishes in southern California estuaries are host to many parasites. The most common of these parasites, Euhaplorchis californiensis , infects the brain of the killifish Fundulus parvipinnis and alters its behaviour, making the fish 10–30 times more susceptible to predation by the birds that serve as its definitive host. Parasites like E. californiensis are embedded in food webs because they require trophic transmission. In the Carpinteria Salt Marsh estuarine food web, parasites dominate the links and comprise substantial amount of biomass. Adding parasites to food webs alters important network statistics such as connectance and nestedness. Furthermore, some free-living stages of parasites are food items for free-living species. For instance, fishes feed on trematode cercariae. Being embedded in food webs makes parasites sensitive to changes in the environment. In particular, fishing and environmental disturbance, by reducing fish populations, may reduce parasite populations. Indirect evidence suggests a decrease in parasites in commercially fished species over the past three decades. In addition, environmental degradation can affect fish parasites. For these reasons, parasites in fishes may serve as indicators of environmental impacts.

Journal of Fish Biology

Comparison of sediment and nutrient export and runoff characteristics from watersheds with centralized versus distributed stormwater management

Stormwater control measures (SCMs) are used to retain stormwater and pollutants. SCMs have traditionally been installed in a centralized manner using detention to mitigate peak flows. Recently, distributed SCM networks that treat runoff near the source have been increasingly utilized. The aim of this study was to evaluate differences among watersheds that vary in SCM arrangement by assessing differences in baseflow nutrient (NO x -N and PO 4 − ) concentrations and fluxes, stormflow export of suspended sediments and particulate phosphorus (PP), and runoff characteristics. A paired watershed approach was used to compare export between 2004 and 2016 from one forested watershed (For-MD), one suburban watershed with centralized SCMs (Cent-MD), and one suburban watershed with distributed SCMs (Dist-MD). Results indicated baseflow nitrate (NO x -N) concentrations typically exceeded 1 mg-N/L in all watersheds and were highest in Dist-MD. Over the last 10 years in Dist-MD, nitrate concentrations in both stream baseflow and in a groundwater well declined as land use shifted from agriculture to suburban. Baseflow nitrate export temporarily increased during the construction phase of SCM development in Dist-MD. This temporary pulse of nitrate may be attributed to the conversion of sediment control facilities to SCMs and increased subsurface flushing as infiltration SCMs came on line. During storm flow, Dist-MD tended to have less runoff and lower maximum specific discharge than Cent-MD for small events (<1.3 cm), but runoff responses became increasingly similar to Cent-MD with increasing precipitation (>1.3 cm). Mass export estimated during paired storm events indicated Dist-MD exported 30% less sediment and 31% more PP than Cent-MD. For large precipitation events, export of sediment and PP was similar among all three watersheds. Results suggest that distributed SCMs can reduce runoff and sediment loads during small rain events compared to centralized SCMs, but these differences become less evident for large events when peak discharge likely leads to substantial bank erosion.

Journal of Environmental Management

Mercury and drought along the Lower Carson River, Nevada: III. effects on blood and organ biochemistry and histopathology of snowy egrets and black-crowned night-herons on Lahontan Reservoir, 2002-2006

A 10-year study (1997-2006) was conducted to evaluate reproduction and health of aquatic birds in the Carson River Basin of northwestern Nevada (on the U.S. Environmental Protection Agency Natural Priorities List) due to high mercury (Hg) concentrations from past mining activities. This part of the study evaluated physiological associations with blood Hg in young snowy egrets (Egretta thula) and black-crowned night-herons (Nycticorax nycticorax), and organ biochemistry and histopathological effects in snowy egrets on Lahontan Reservoir (LR) from the period 2002-2006. LR snowy egret geometric mean total Hg concentrations (&mu;g/g ww) ranged from 1.5 to 4.8 for blood, 2.4 to 3.1 liver, 1.8 to 2.5 kidneys, 1.7 to 2.4 brain, and 20.5 to 36.4 feathers over these years. For night-herons, mean Hg for blood ranged from 1.6 to 7.4. Significant positive correlations were found between total Hg in blood and five plasma enzyme activities of snowy egrets suggesting hepatic stress. Histopathological findings revealed vacuolar changes in hepatocytes in LR snowy egrets as well as correlation of increased liver inflammation with increasing blood and tissue Hg. Hepatic oxidative effects were manifested by decreased hepatic total thiol concentration and glutathione reductase activity and elevated hepatic thiobarbituric acid-reactive substances (TBARS), a measure of lipid peroxidation. However, other hepatic changes indicated compensatory mechanisms in response to oxidative stress, including decreased oxidized glutathione (GSSG) concentration and decreased ratio of GSSG to reduced glutathione. In young black-crowned night-herons, fewer correlations were apparent. In both species, positive correlations between blood total Hg and plasma uric acid and inorganic phosphorus were suggestive of renal stress, which was supported by histopathological findings. Both oxidative effects and adaptive responses to oxidative stress were apparent in kidneys and brain. Vacuolar change and inflammation in peripheral nerves were found to correlate with blood and tissue Hg. Hg-associated effects related to the immune system included alterations in specific white blood cells and lymphoid depletion in the bursa that were correlated with blood and tissue Hg. When the number of plasma variables that differed between young snowy egrets from the LR site and the reference site were compared between wet and drought years, over twice as many variables were affected during drought years. This resulted in many more variables correlating with blood total Hg during dry than during wet years, suggesting the combination of drought and Hg was more stressful than Hg alone. Drought may have exacerbated Hg-related effects as reported previously for overall productivity. This relationship was not evident in black-crowned night-herons, although data were more limited.

Nevada

What is the (real) rate of soil health practice adoption? Making sense of three data sources

Conservation stakeholders looking to quantify the impact of their investments to increase soil health practice adoption over time often face challenges in interpreting practice adoption data due to discrepancies in language and results among data sources. Similarly, efforts to estimate environmental outcomes of practice adoption, such as water quality and greenhouse gas emissions, can vary depending on different practice adoption input data. To help make sense of different adoption data sources, we compared county-level adoption data for winter cover crops (WCC), no-till (NT), and reduced tillage (RT) in three areas of the United States with contrasting climates and production systems: central Illinois (CIL), southern Illinois (SIL), and western New York (WNY). We analyzed data available during 2015 through 2022 from the Operational Tillage Information System (OpTIS, remote sensing), US Census of Agriculture (AgCensus, a farmer survey), and, specifically in Illinois, the Illinois Soil Conservation Transect Survey (Transect, a roadside survey). The magnitude of differences between the datasets depended on the practice and geographic location. For example, OpTIS and AgCensus tillage data were much more similar in Illinois (average difference of less than 4 percentage points) compared to New York (average differences of 20 percentage points). Similarly, there was less variability and smaller differences between OpTIS and AgCensus WCC data in Illinois compared to WNY. AgCensus tended to report lower WCC adoption for Illinois and greater adoption in WNY compared to OpTIS. All data sources agreed that the rate of change in tillage practices is slow (mainly –1% to 1%) and that adoption of WCC is low (assuming linear growth, it could take nearly a century to reach 50% WCC adoption in CIL). Differences among the datasets were attributed to definitional inconsistencies for RT and NT and how WCC data were acquired. For example, the AgCensus asks if a WCC was planted, whereas OpTIS and Transect evaluate the presence of a standing WCC. Data sources also reflect different time periods (calendar years or crop years) and types of cropland assessed (corn [ Zea mays L.], soybean [ Glycine max {L.} Merr.], or all cropland). We propose two recommendations to improve interpretation and consistency: (1) a working group to harmonize definitions and protocols and develop educational materials for data users, and (2) a research effort that integrates different adoption data types and produces publicly available adoption data at HUC-10 and county scales. Such activities could help improve data access and utility for evidence-based conservation decision-making and enhance the accuracy of environmental models that rely on adoption data as input.

Journal of Soil and Water Conservation

Detection of human enteric viruses in stream water with RT-PCR and cell culture

A multiplex RT-PCR method was used to measure virus occurrence at five stream water sites that span a range of hydroclimatic, water-quality, and land-use characteristics. The performance of the molecular method was evaluated in comparison with traditional cell culture and Escherichia coli membrane filtration assays. The study incorporated multiple quality controls and included a control for virus recovery during the sampling procedure as well as controls to detect potentially false-negative and false-positive data. Poliovirus recovery ranged from 16 to 65% and was variable, even in samples collected within the same stream. All five sites were positive for viruses by both molecular and cell culture-based virus assays. Enteroviruses, reoviruses, rotaviruses, and hepatitis A viruses were detected, but the use of the quality controls proved critical for interpretation of the molecular data. All sites showed evidence of faecal contamination, and culturable viruses were detected in four samples that would have met the US Environmental Protection Agency's recommended E. coli guideline for safe recreational water.

Journal of Water and Health

Low temperature limits photoperiod control of smolting in atlantic salmon through endocrine mechanisms

We have examined the interaction of photoperiod and temperature in regulating the parr-smolt transformation and its endocrine control. Atlantic salmon juveniles were reared at a constant temperature of 10°C or ambient temperature (2°C from January to April followed by seasonal increase) under simulated natural day length. At 10°C, an increase in day length [16 h of light and 8 h of darkness (LD 16:8)] in February accelerated increases in gill Na + -K + -ATPase activity, whereas fish at ambient temperature did not respond to increased day length. Increases in gill Na + -K + -ATPase activity under both photoperiods occurred later at ambient temperature than at 10°C. Plasma growth hormone (GH), insulin-like growth factor, and thyroxine increased within 7 days of increased day length at 10°C and remained elevated for 5–9 wk; the same photoperiod treatment at 2°C resulted in much smaller increases of shorter duration. Plasma cortisol increased transiently 3 and 5 wk after LD 16:8 at 10°C and ambient temperature, respectively. Plasma thyroxine was consistently higher at ambient temperature than at 10°C. Plasma triiodothyronine was initially higher at 10°C than at ambient temperature, and there was no response to LD 16:8 under either temperature regimen. There was a strong correlation between gill Na + -K + -ATPase activity and plasma GH; correlations were weaker with other hormones. The results provide evidence that low temperature limits the physiological response to increased day length and that GH, insulin-like growth factor I, cortisol, and thyroid hormones mediate the environmental control of the parr-smolt transformation.

American Journal of Physiology - Regulatory, Integ

Instream flow assessment and economic valuation: a survey of nonmarket benefits research

Instream flow benefits for United States streams and rivers have recently been investigated by a number of resource economists. These valuation efforts differ in scope, method, and quantitative results. An assessment and review of these valuation efforts is presented. The various sources of differences in non‐market values produced by these studies are explored in some detail. The considerable difficulty of producing estimates of instream flow benefits values that consider all of the pertinent policy and technical issues is delineated in various policy contexts. Evidence is presented that indicates that the considerable policy impact of recent research on this topic is justified despite considerable variation in the magnitude of the estimates.

International Journal of Environmental Studies

Immunotoxicity of trenbolone acetate in Japanese quail

Trenbolone acetate is a synthetic androgen that is currently used as a growth promoter in many meat-exporting countries. Despite industry laboratories classifying trenbolone as nonteratogenic, data showed that embryonic exposure to this androgenic chemical altered development of the immune system in Japanese quail. Trenbolone is lipophilic, persistent, and released into the environment in manure used as soil fertilizer. This is the first study to date to assess this chemical's immunotoxic effects in an avian species. A one-time injection of trenbolone into yolks was administered to mimic maternal deposition, and subsequent effects on the development and function of the immune system were determined in chicks and adults. Development of the bursa of Fabricius, an organ responsible for development of the humoral arm of the immune system, was disrupted, as indicated by lower masse, and smaller and fewer follicles at day 1 of hatch. Morphological differences in the bursas persisted in adults, although no differences in either two measures of immune function were observed. Total numbers of circulating leukocytes were reduced and heterophil-lymphocyte ratios were elevated in chicks but not adults. This study shows that trenbolone acetate is teratogenic and immunotoxic in Japanese quail, and provides evidence that the quail immune system may be fairly resilient to embryonic endocrine-disrupting chemical-induced alterations following no further exposure posthatch.

Journal of Toxicology and Environmental Health, Pa

Uptake and distribution of organo-iodine in deep-sea corals

Understanding iodine concentration, transport, and bioavailability is essential in evaluating iodine's impact to the environment and its effectiveness as an environmental biogeotracer. While iodine and its radionuclides have proven to be important tracers in geologic and biologic studies, little is known about transport of this element to the deep sea and subsequent uptake in deep-sea coral habitats. Results presented here on deep-sea black coral iodine speciation and iodine isotope variability provides key information on iodine behavior in natural and anthropogenic environments, and its geochemical pathway in the Gulf of Mexico. Organo-iodine is the dominant iodine species in the black corals, demonstrating that binding of iodine to organic matter plays an important role in the transport and transfer of iodine to the deep-sea corals. The identification of growth bands captured in high-resolution scanning electron images (SEM) with synchronous peaks in iodine variability suggest that riverine delivery of terrestrial-derived organo-iodine is the most plausible explanation to account for annual periodicity in the deep-sea coral geochemistry. Whereas previous studies have suggested the presence of annual growth rings in deep-sea corals, this present study provides a mechanism to explain the formation of annual growth bands. Furthermore, deep-sea coral ages based on iodine peak counts agree well with those ages derived from radiocarbon ( 14 C) measurements. These results hold promise for developing chronologies independent of 14 C dating, which is an essential component in constraining reservoir ages and using radiocarbon as a tracer of ocean circulation. Furthermore, the presence of enriched 129 I/ 127 I ratios during the most recent period of skeleton growth is linked to nuclear weapons testing during the 1960s. The sensitivity of the coral skeleton to record changes in surface water 129 I composition provides further evidence that iodine composition and isotope variability captured in proteinaceous deep-sea corals is a promising geochronometer as well as an emerging tracer for continental material flux.

Journal of Environmental Radioactivity

Evaluating long-term patterns of decreasing groundwater discharge through a lake-bottom permeable reactive barrier

Identifying and quantifying groundwater exchange is critical when considering contaminant fate and transport at the groundwater/surface-water interface. In this paper, areally distributed temperature and point seepage measurements are used to efficiently assess spatial and temporal groundwater discharge patterns through a glacial-kettle lakebed area containing a zero-valent iron permeable reactive barrier (PRB). Concern was that the PRB was becoming less permeable with time owing to biogeochemical processes within the PRB. Patterns of groundwater discharge over an 8-year period were examined using fiber-optic distributed temperature sensing (FO-DTS) and snapshot-in-time point measurements of temperature. The resulting thermal maps show complex and uneven distributions of temperatures across the lakebed and highlight zones of rapid seepage near the shoreline and along the outer boundaries of the PRB. Repeated thermal mapping indicates an increase in lakebed temperatures over time at periods of similar stage and surface-water temperature. Flux rates in six seepage meters permanently installed on the lakebed in the PRB area decreased on average by 0.021 md -1 (or about 4.5 percent) annually between 2004 and 2015. Modeling of diurnal temperature signals from shallow vertical profiles yielded mean flux values ranging from 0.39 to 1.15 md -1 , with stronger fluxes generally related to colder lakebed temperatures. The combination of an increase in lakebed temperatures, declines in direct seepage, and observations of increased cementation of the lakebed surface provide in situ evidence that the permeability of the PRB is declining. The presence of temporally persistent rapid seepage zones is also discussed.

Journal of Environmental Management

Dynamics within geyser conduits, and sensitivity to environmental perturbations: insights from a periodic geyser in the El Tatio Geyser Field, Atacama Desert, Chile

Despite more than 200 years of scientific study, the internal dynamics of geyser systems remain poorly characterized. As a consequence, there remain fundamental questions about what processes initiate and terminate eruptions, and where eruptions begin. Over a one-week period in October 2012, we collected down-hole measurements of pressure and temperature in the conduit of an exceptionally regular geyser (132 s/cycle) located in the Chilean desert. We identified four stages in the geyser cycle: (1) recharge of water into the conduit after an eruption, driven by the pressure difference between water in the conduit and in a deeper reservoir; (2) a pre-eruptive stage that follows the recharge and is dominated by addition of steam from below; (3) the eruption, which occurs by rapid boiling of a large mass of water at the top of the water column, and decompression that propagates boiling conditions downward; (4) a relaxation stage during which pressure and temperature decrease until conditions preceding the recharge stage are restored. Eruptions are triggered by the episodic addition of steam coming from depth, suggesting that the dynamics of the eruptions are dominated by geometrical and thermodynamic complexities in the conduit and reservoir. Further evidence favoring the dominance of internal processes in controlling periodicity is also provided by the absence of responses of the geyser to environmental perturbations (air pressure, temperature and probably also Earth tides).

Atacama Desert