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Use of 2D and 3D GIS in well selection and interpretation of nitrate data, central Nebraska, USA

Nonpoint-source contamination of the principal aquifers in a 7800 km2 area of central Nebraska was evaluated utilizing aquifer condition, well depth, soil type, and physiographical and land use settings. A two-dimensional geographical information system linked with a three-dimensional geological visualization and analytical program was used in the random selection of acceptable wells for the monitoring of nitrate concentrations in groundwater. Locations of existing wells were super-imposed on the three-dimensional geological block diagram and more than 200 wells randomly were selected for monitoring. The three-dimensional system also was used to show three-dimensional contours of nitrate concentrations that can be used interactively to determine the volumetric percentage of an aquifer that contains nitrate concentrations exceeding a specified threshold. The two-dimensional geographical information system was used in comparing nitrate concentrations in differing physiographical, soil, and land use settings. Preliminary results suggest that approximately 6% (volumetric) of water in the High Plains aquifer has nitrate concentrations above the US Environmental Protection Agency Maximum Contaminant Level of 10 mg 1-1 as N.

IAHS-AISH Publication

Using GIS and logistic regression to estimate agricultural chemical concentrations in rivers of the midwestern USA

Agricultural chemicals (herbicides, insecticides, other pesticides and fertilizers) in surface water may constitute a human health risk. Recent research on unregulated rivers in the midwestern USA documents that elevated concentrations of herbicides occur for 1-4 months following application in spring and early summer. In contrast, nitrate concentrations in unregulated rivers are elevated during the fall, winter and spring. Natural and anthropogenic variables of river drainage basins, such as soil permeability, the amount of agricultural chemicals applied or percentage of land planted in corn, affect agricultural chemical concentrations in rivers. Logistic regression (LGR) models are used to investigate relations between various drainage basin variables and the concentration of selected agricultural chemicals in rivers. The method is successful in contributing to the understanding of agricultural chemical concentration in rivers. Overall accuracies of the best LGR models, defined as the number of correct classifications divided by the number of attempted classifications, averaged about 66%.

IAHS-AISH Publication

Unrealistic parameter estimates in inverse modelling: A problem or a benefit for model calibration?

Estimation of unrealistic parameter values by inverse modelling is useful for constructed model discrimination. This utility is demonstrated using the three-dimensional, groundwater flow inverse model MODFLOWP to estimate parameters in a simple synthetic model where the true conditions and character of the errors are completely known. When a poorly constructed model is used, unreasonable parameter values are obtained even when using error free observations and true initial parameter values. This apparent problem is actually a benefit because it differentiates accurately and inaccurately constructed models. The problems seem obvious for a synthetic problem in which the truth is known, but are obscure when working with field data. Situations in which unrealistic parameter estimates indicate constructed model problems are illustrated in applications of inverse modelling to three field sites and to complex synthetic test cases in which it is shown that prediction accuracy also suffers when constructed models are inaccurate.

IAHS-AISH Publication

Identification of groundwater parameters at Columbus, Mississippi, using a 3D inverse flow and transport model

An extensive amount of data including hydraulic heads, hydraulic conductivities and concentrations of several solutes from controlled injections have been collected during the MADE 1 and MADE 2 experiments at a heterogeneous site near Columbus, Mississippi. In this paper the use of three-dimensional inverse groundwater models including simultaneous estimation of flow and transport parameters is proposed to help identify the dominant characteristics at the site. Simulations show that using a hydraulic conductivity distribution obtained from 2187 borehole flowmeter tests directly in the model produces poor matches to the measured hydraulic heads and tritium concentrations. Alternatively, time averaged hydraulic head maps are used to define zones of constant hydraulic conductivity to be estimated. Preliminary simulations suggest that in the case of conservative transport many, but not all, of the major plume characteristics can be explained by large-scale heterogeneity in recharge and hydraulic conductivity.

IAHS-AISH Publication

Discharges and yields of suspended sediment in the Ob' and Yenisey Rivers of Siberia

The northward-flowing rivers of Siberia deliver immense quantities of water but only relatively small quantities of sediment to the Arctic Ocean. The relatively low delivery of sediment to the ocean by these rivers is explained by the large areas of forest and swamp in their basins. In the Ob' River, sediment yields tend to increase between the headwaters and Kamen' na Obi. Further downstream, sediment yields gradually decrease. Near the mouth of the Ob' River, at Salekhard, sediment yield has remained constant at about 5.3 t km-2 year-1. In the lower Yenisey River, the already small natural sediment yield of 5.4 t km-2 year-1 has been decreased several fold by the construction of massive reservoirs on the main stem and on the tributary Angara River, and presently equals 1.8 t km-2 year-1.

IAHS-AISH Publication

Using remote sensing and GIS techniques to estimate discharge and recharge. fluxes for the Death Valley regional groundwater flow system, USA

The recharge and discharge components of the Death Valley regional groundwater flow system were defined by remote sensing and GIS techniques that integrated disparate data types to develop a spatially complex representation of near-surface hydrological processes. Image classification methods were applied to multispectral satellite data to produce a vegetation map. This map provided a basis for subsequent evapotranspiration and infiltration estimations. The vegetation map was combined with ancillary data in a GIS to delineate different types of wetlands, phreatophytes and wet playa areas. Existing evapotranspiration-rate estimates were then used to calculate discharge volumes for these areas. A previously used empirical method of groundwater recharge estimation was modified by GIS methods to incorporate data describing soil-moisture conditions, and a recharge potential map was produced. These discharge and recharge maps were readily converted to data arrays for numerical modelling codes. Inverse parameter estimation techniques also used these data to evaluate the reliability and sensitivity of estimated values.

IAHS-AISH Publication

Source, movement and age of groundwater in the upper part of the Mojave River Basin, California, USA

Water samples from wells were collected and analysed for oxygen-18, deuterium, tritium, carbon-14, and carbon-13 to determine the source, movement and age of groundwater in the upper part of the Mojave River basin. Water in the alluvial aquifer has a median deuterium composition of -66??? and contains tritium, and was recently recharged by water from the Mojave River. Water in the regional aquifer near the Mojave River, near Summit Valley, and underlying several small washes has deuterium compositions heavier than -60???. Although some water in the regional aquifer near the Mojave River contains tritium, most of this water does not contain tritium. Carbon-14 data indicate that this water was recharged less than 2400 years ago. Water in the remainder of the regional aquifer has a median deuterium composition of -84???, which is as much as 20??? lighter than the volume-weighted deuterium composition of present-day precipitation. These data show that this water was recharged under climatic conditions different from average conditions today. Carbon-14 data indicate that some water in the regional aquifer was recharged more than 20 000 years ago.Water samples from wells were collected and analyzed for oxygen-18, deuterium, tritium, carbon-14, and carbon-13 to determine the source, movement and age of groundwater in the upper part of the Mojave River basin. Water in the alluvial aquifer has a median deuterium composition of -66qq and contains tritium, and was recently recharged by water from the Mojave River. Water in the regional aquifer near the Mojave River, near Summit Valley, and underlying several small washes has deuterium compositions heavier than -60qq. Although some water in the regional aquifer near the Mojave River contains tritium, most of this water does not contain tritium. Carbon-14 data indicate that this water was recharged less than 2400 years ago. Water in the remainder of the regional aquifer has a median deuterium composition of -84qq, which is as much as 20qq lighter than the volume-weighted deuterium composition of present-day precipitation. These data show that this water was recharged under climatic conditions different from average conditions today. Carbon-14 data indicate that some water in the regional aquifer was recharged more than 20 000 years ago.

IAHS-AISH Publication

Spatial and temporal variability in nutrient concentrations in surface waters of the Chattahoochee River basin near Atlanta, Georgia, USA

Nutrient concentrations from the early 1970s through 1995 were evaluated at several sites along the Chattahoochee River and its tributaries near Atlanta, to determine general patterns and processes controlling nutrient concentrations in the river. A spatial analysis was conducted on data collected in 1994 and 1995 from an intensive nutrient study of the Chattahoochee River and its tributaries by the Georgia Department of Natural Resources, Environmental Protection Division. The 1994-1995 data show step increases in ammonium (NH4-N), nitrite plus nitrate (NO2 + NO3-N), and total-phosphorus (Tot-P) concentrations in the river. The step increases occur downstream of two wastewater treatment facilities (WWTFs) and Peachtree Creek, a small tributary inflow with degraded water quality draining a predominantly urban and industrial area. Median NO2 + NO3-N and Tot-P concentrations in the mainstem increase downstream of these inputs from 0.5 to 1 mg 1-1 and from 0.04 to 0.13 mg 1-1, respectively. NH4-N concentrations were typically low with 95% of the 2575 observations less than 0.2 mg 1-1 throughout the river system, except some high values (>1 mg 1-1) in some tributaries, particularly near the central part of Atlanta. High NH4-N concentrations are attributed to sewage discharge as they also are associated with high biological oxygen demand and faecal coliform bacteria concentrations. Nutrient concentrations vary temporally. An assessment of four sites, two mainstem and two tributaries, from 1970 to 1995 indicates a progressive increase and variability in NO2 + NO3-N concentrations during the period. The progressive increase in NO2 + NO3-N concentrations and their variability is similar to that reported for surface waters throughout the world and for which increased fertilizer usage has been attributed. Tot-P concentrations increase at mainstem sites through the middle to late 1980s and decrease markedly thereafter, due to improvements to WWTFs and a 1990 phosphate detergent ban. NH4-N concentrations, although less pronounced than Tot-P, display a similar decrease from the late 1980s to 1995 at the four sites. Tot-P concentration variability has increased at the tributary sites since 1993, although recent concentrations, on average, are the lowest since 1970 at each of the four sites.

IAHS-AISH Publication

A physically-based method for predicting peak discharge of floods caused by failure of natural and constructed earthen dams

We analyse a simple, physically-based model of breach formation in natural and constructed earthen dams to elucidate the principal factors controlling the flood hydrograph at the breach. Formation of the breach, which is assumed trapezoidal in cross-section, is parameterized by the mean rate of downcutting, k, the value of which is constrained by observations. A dimensionless formulation of the model leads to the prediction that the breach hydrograph depends upon lake shape, the ratio r of breach width to depth, the side slope ?? of the breach, and the parameter ?? = (V/ D3)(k/???gD), where V = lake volume, D = lake depth, and g is the acceleration due to gravity. Calculations show that peak discharge Qp depends weakly on lake shape r and ??, but strongly on ??, which is the product of a dimensionless lake volume and a dimensionless erosion rate. Qp(??) takes asymptotically distinct forms depending on whether ?? < < 1 or ?? > > 1. Theoretical predictions agree well with data from dam failures for which k could be reasonably estimated. The analysis provides a rapid and in many cases graphical way to estimate plausible values of Qp at the breach.

IAHS-AISH Publication

The role of near-stream riparian zones in the hydrology of steep upland catchments

Surface and subsurface waters were monitored and sampled at various topographic positions in a 40.5-ha headwater catchment to test several hypotheses of runoff generation and stream chemical and isotopic evolution during snowmelt. Transmissivity feedback was observed on the hillslopes during the melt period. Groundwater levels and stream DOC were highly correlated with stream discharge. Hysteresis in the groundwater-streamflow relation suggests that localized water flux from the riparian areas controlled the rising limb and main peak response of the melt hydrograph, whilst hillslope drainage controlled the timing and volume of the falling limb. Lateral flow from upslope positions was detected in the riparian zone.

IAHS-AISH Publication

Precipitation interpolation in mountainous regions using multiple linear regression

Multiple linear regression (MLR) was used to spatially interpolate precipitation for simulating runoff in the Animas River basin of southwestern Colorado. MLR equations were defined for each time step using measured precipitation as dependent variables. Explanatory variables used in each MLR were derived for the dependent variable locations from a digital elevation model (DEM) using a geographic information system. The same explanatory variables were defined for a 5 ?? 5 km grid of the DEM. For each time step, the best MLR equation was chosen and used to interpolate precipitation onto the 5 ?? 5 km grid. The gridded values of precipitation provide a physically-based estimate of the spatial distribution of precipitation and result in reliable simulations of daily runoff in the Animas River basin.

IAHS-AISH Publication

Numerical modelling of vertically extensive groundwater bodies in Maui, Hawaii: An alternative to perched aquifers

Groundwater in East Maui, Hawaii is traditionally described as a series of discrete aquifers perched on low-permeability units underlain by a basal lens with heads of about 2-3 m. An alternative concept, a fully saturated aquifer to as much as 1400 m elevation, was investigated using a numerical model with various horizontal hydraulic conductivity values and anisotropy ratios. Results indicate that horizontal hydraulic conductivity values between about 0.08 and 1.0 m per day and anisotropy ratios between 1:1 and 100:1 will produce simulated water tables that match observed water tables at 400-1400 m elevation. These values of hydraulic conductivity are consistent with available field data for hydraulic conductivity.Groundwater in East Maui, Hawaii is traditionally described as a series of discrete aquifers perched on low-permeability units underlain by a basal lens with heads of about 2-3 m. An alternative concept, a fully saturated aquifer to as much as 1400 m elevation, was investigated using a numerical model with various horizontal hydraulic conductivity values and anisotropy ratios. Results indicate that horizontal hydraulic conductivity values between about 0.08 and 1.0 m per day and anisotropy ratios between 1:1 and 100:1 will produce simulated water tables that match observed water tables at 400-1400 m elevation. These values of hydraulic conductivity are consistent with available field data for hydraulic conductivity.

IAHS-AISH Publication

Tracing solute mobility at the Panola Mountain Research Watershed, Georgia, USA: Variations in Na+, Cl-, and H4SiO4 concentrations

Concentration variations of sodium (N+). chloride (Cl-). and dissolved silica (H4SiO4) in rainfall, throughfall, soil water, groundwater and streamwater were evaluated at the Panola Mountain Research Watershed near Atlanta, Georgia, to determine how variations in concentrations of these solutes provide greater understanding of water quality evolution at the hillslope and catchment scales Stormwater moves rapidly to depth along preferred pathways in a deciduous forest hillslope, but the composition of the mobile unsaturated zone water in the hillslope is not reflected in compositional variations of streamwater during rainstorms. The Na+, Cl-, and H4SiO4 concentrations behave similarly in streamwater, decreasing with increasing discharge and increasing with water residence time. Consequently, the lowest flows are associated with the highest concentrations and the oldest water. Streamwater composition is most similar to groundwater and stormflow variations reflect a dilution of groundwater. Subtle differences in the relations among solute concentrations and discharge reflect different sources, especially for Cl-. For example, the residence time of groundwater, as inferred from landscape position, generally is positively related to Na+ and H4SiO4 concentrations, but not to Cl- concentrations. The Na+ and H4SiO4 are derived from mineral weathering and are continuously supplied along hydrological pathways. In contrast, Cl- is derived from atmospheric deposition and is affected only by evapotranspiration (ET) and transport. ET increases Cl- concentrations in matrix soil waters, which are subsequently transported to the saturated zone where Cl- is effectively isolated from further evaporative concentration.

IAHS-AISH Publication

Nitrate in groundwater of the midwestern United States: A regional investigation on relations to land use and soil properties

The intense application of nitrogen-fertilizer to cropland in the midwestern United States has created concern about nitrate contamination of the region's aquifers. Since 1991, the US Geological Survey has used a network of 303 wells to investigate the regional distribution of nitrate in near-surface aquifers of the midwestern United States. Detailed land use and soil data were compiled within a 2 km radius of 100 unconsolidated wells in the regional network to determine relations to nitrate concentrations in groundwater. For land use, the amount of irrigated land was directly related to nitrate concentrations in groundwater. For soils, the general water table depth and soil factors associated with rates of water movement were directly related to nitrate concentrations in groundwater.

IAHS-AISH Publication

Sources of nitrate in water from springs and the Upper Floridan aquifer, Suwannee River basin, Florida

In the Suwannee River basin of northern Florida, nitrate-N concentrations are 1.5 to 20 mg 1-1 in waters of the karstic Upper Floridan aquifer and in springs that discharge into the middle reach of the Suwannee River. During 1996-1997, fertilizers and animal wastes from farming operations in Suwannee County contributed approximately 49% and 45% of the total N input, respectively. Values of ??15N-NO3 in spring waters range from 3.9??? to 5.8???, indicating that nitrate most likely originates from a mixture of inorganic (fertilizers) and organic (animal waste) sources. In Lafayette County, animal wastes from farming operations and fertilizers contributed approximately 53% and 39% of the total N input, respectively, but groundwater near dairy and poultry farms has ??15N-NO3 values of 11.0-12.1???, indicative of an organic source of nitrate. Spring waters that discharge to the Suwannee River from Lafayette County have ??15N-NO3 values of 5.4-8.39???, which are indicative of both organic and inorganic sources. Based on analyses of CFCs, the mean residence time of shallow groundwater and spring water ranges between 8-12 years and 12-25 years, respectively.

IAHS-AISH Publication

Nutrient concentrations and fluxes in tributaries to the Swan-Canning estuary, Western Australia

In Western Australia, catchment nutrient availability on an areal basis is primarily controlled by the disposal of animal waste and the type and rate of fertilizer application, particularly in coastal areas. The coastal areas receive notably higher rainfall and have more intense horticulture and animal production than inland areas, and are undergoing rapid urbanization, particularly adjacent to the estuary. Also, the surficial aquifers on the coastal plain are generally sandy having a low nutrient retention capacity and rapidly transmit soluble and colloidal material through the subsurface. In the Swan-Canning basin, high air and soil temperatures and seasonally arid conditions cause rapid mineralization of nitrogen and phosphorus. The nutrients are subsequently available for transport during the onset of seasonal wet weather, which typically begins during the period from late April to June. In addition to the rapid mobility of nutrients in streamwater from agricultural areas during the wet season, drains in urban areas, which typically have high nutrient concentrations, also are an important source of nutrients as the drains flow directly to the estuary throughout the year.

IAHS-AISH Publication

Use of nitrogen isotopes to determine sources of nitrate contamination in two desert basins in California

Nitrogen-15/14 isotope ratios (δ 15 N) were measured in groundwater, infiltrating wastewater, and natural uncontaminated soil to determine the source of high NO 3 - concentrations in two desert basins at Fort Irwin National Training Center in the Mojave Desert. The abundance and isotopic composition of dissolved nitrogen gas were measured in some of the groundwater samples to determine the effects of denitrification on the abundance and isotopic composition of the NO 3 - . Delta 15 N-NO 3 values in groundwaters most likely to include sewage effluent ranged from about 11 to 23‰. Delta 15 N values in groundwater not near sources of sewage effluent ranged from 6 to 11‰, a range similar to that found in the overlying soils, which contain large concentrations of leachable NO 3 - presumed to be of natural origin. Some of the samples with relatively low NO 3 - concentrations and high δ 15 N values contained excess non-atmospheric nitrogen gas attributed to denitrification. These data indicate that high NO 3 - concentrations in groundwater unaffected by sewage effluent may result from leaching of naturally occurring nitrogen in desert soils, and that some of the NO 3 - may be removed by denitrification at the water table. Nitrogen-15/14 isotope ratios (δ 15 N) were measured in groundwater, infiltrating wastewater, and natural uncontaminated soil to determine the source of high NO 3 - concentrations in two desert basins at Fort Irwin National Training Center in the Mojave Desert. The abundance and isotopic composition of dissolved nitrogen gas were measured in some of the groundwater samples to determine the effects of denitrification on the abundance and isotopic composition of the NO 3 - . Delta 15 N-NO 3 values in groundwaters most likely to include sewage effluent ranged from about 11 to 23 per mil. Delta 15 N values in groundwater not near sources of sewage effluent ranged from 6 to 11 per mil, a range similar to that found in the overlying soils, which contain large concentrations of leachable NO 3 - presumed to be of natural origin. Some of the samples with relatively low NO 3 - concentrations and high δ 15 N values contained excess non-atmospheric nitrogen gas attributed to denitrification. These data indicate that high NO 3 - concentrations in groundwater unaffected by sewage effluent may result from leaching of naturally occurring nitrogen in desert soils, and that some of the NO 3 - may be removed by denitrification at the water table.

California

Image and in situ data integration to derive sawgrass density for surface flow modelling in the Everglades, Florida, USA

The US Geological Survey is building models of the Florida Everglades to be used in managing south Florida surface water flows for habitat restoration and maintenance. Because of the low gradients in the Everglades, vegetation structural characteristics are very important and greatly influence surface water flow and distribution. Vegetation density is being evaluated as an index of surface resistance to flow. Digital multispectral videography (DMSV) has been captured over several sites just before field collection of vegetation data. Linear regression has been used to establish a relationship between normalized difference vegetation index (NDVI) values computed from the DMSV and field-collected biomass and density estimates. Spatial analysis applied to the DMSV data indicates that thematic mapper (TM) resolution is at the limit required to capture land surface heterogeneity. The TM data collected close to the time of the DMSV will be used to derive a regional sawgrass density map.

IAHS-AISH Publication