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Well logging with californium-252

Californium 252 is an isotopic neutron source that has only recently become available for experimental well logging. One curie of 252Cf emits 4.4 x 109 neutrons per second by spontaneous fission, 300 times the emission rate of any other one curie radioisotopic source. California 252 has several other advantages as a high yield source for well logging: very small physical size, low gamma and heat emission, and expected low cost relative to other sources. A 50-millicurie 252Cf source fabricated at the Savannah River Laboratory was made available by the U. S. Atomic Energy Commission to the U. S. Geological Survey for a feasibility study on well logging. The nuclear and physical characteristics of this source and some of the health physics aspects of its use in the field are discussed. The source was used to make epithermal neutron logs, which are compared with logs made with plutonium beryllium and americium beryllium sources in the same well. The high neutron flux available from 252Cf permitted the use of longer than usual spacing while maintaining a high count rate and excellent sensitivity. In addition, continuous activation logs were made utilizing a spacing of 5. 5 feet from the source to detector. Aluminum 28 was identified as the chief radioisotope contributing to the log response. This new technique may provide a log more closely related to clay content than the natural gamma log. Stationary irradiation experiments were also carried out in boreholes, and sodium 24 and manganese 56 were readily produced and identified. Suggestions for additional research on logging applications and problems resulted from this feasibility study. Potential well logging applications not investigated include the activation of temporary depth markers and the use of stable tracers that can be activated at the site or in the well. The high neutron yield of californium 252 will facilitate in situ activation analysis for many elements as an aid to exploration for oil, water, and other minerals.

Conference Paper

Populations of concern

Climate change is already causing, and is expected to continue to cause, a range of health impacts that vary across different population groups in the United States. The vulnerability of any given group is a function of its sensitivity to climate change related health risks, its exposure to those risks, and its capacity for responding to or coping with climate variability and change. Vulnerable groups of people, described here as populations of concern, include those with low income, some communities of color, immigrant groups (including those with limited English proficiency), Indigenous peoples, children and pregnant women, older adults, vulnerable occupational groups, persons with disabilities, and persons with preexisting or chronic medical conditions. Planners and public health officials, politicians and physicians, scientists and social service providers are tasked with understanding and responding to the health impacts of climate change. Collectively, their characterization of vulnerability should consider how populations of concern experience disproportionate, multiple, and complex risks to their health and well-being in response to climate change. Some groups face a number of stressors related to both climate and non-climate factors. For example, people living in impoverished urban or isolated rural areas, floodplains, coastlines, and other at-risk locations are more vulnerable not only to extreme weather and persistent climate change but also to social and economic stressors. Many of these stressors can occur simultaneously or consecutively. Over time, this “accumulation” of multiple, complex stressors is expected to become more evident1 as climate impacts interact with stressors associated with existing mental and physical health conditions and with other socioeconomic and demographic factors.

Report

Results from the Department of the Interior Strategic Sciences Group Technical Support for the 2018 Kīlauea Eruption

On May 3, 2018 Hawai'i’s Kīlauea volcano erupted, ultimately covering 35 square kilometers (13.5 square miles) of land in lava, destroying over 700 homes in multiple subdivisions, and displacing over 2500 residents in the Puna District on the southeast flank of the volcano. Simultaneously, Kīlauea’s summit experienced its largest collapse in 200 years, with a total of 500 meters (1,640 feet) subsidence and tens of earthquakes each day rattling surrounding communities. These simultaneous events impacted residential, agricultural, business, tourist, and scientific areas. Hawai'i Volcanoes National Park closed, slowing tourism and the local economy. The building housing the United States Geological Survey (USGS) Hawai'ian Volcano Observatory also closed, displacing scientists responsible for monitoring the erupting volcano. The eruption lasted 107 days, one of the longest eruptions in recent history in lower Puna. Throughout the eruption, uncertainty regarding the duration of the event, its extent, and total damage remained high. This uncertainty led to social tensions and fatigue across the affected community, responders, and local officials. At the direction of the USGS Director, serving as the Science Advisor to the Secretary of the of the Interior, the Department of the Interior (DOI, hereafter also referred to as “the Department”) Strategic Sciences Group (SSG) convened a multidisciplinary group of 13 experts in Hilo, Hawai'i, on July 17-19, 2018. The SSG was charged with considering the cascading short- and long-term social, economic, and environmental consequences of the 2018 Kīlauea eruption to DOI resources, employees, and facilities as well as to the surrounding communities. Established in 2012, the SSG is designed to complement ongoing response efforts by providing strategic science to identify potential social, environmental, and economic consequences and potential interventions during a crisis event affecting Departmental resources. This activation of the SSG was funded by the USGS. It was the first official activation of the SSG since it supported Hurricane Sandy recovery in 2013 and provided the unique opportunity to test new methods, including bolstering the social science expertise on the team and interacting directly with stakeholders before, during, and after deployment. The SSG Kīlauea Team developed three scenarios focused on 1) the impacts of continued seismicity and deformation at the summit; 2) vog (volcanic smog); and 3) the eruption in the lower East Rift Zone. Across all scenarios, areas of concern included human health (physical and mental); biosecurity (for example, protecting threatened and endangered species); infrastructure (impacts caused by seismic activity, vog, and lava); communications (internal and public-facing); long-term planning (related to tourism, access, housing); and ongoing needs for community engagement and empowerment. The SSG Kīlauea Team identified 59 potential actions for mitigation. Highlights of these actions were delivered to stakeholders during briefings in August and September 2018. Examples of potential actions included: ● Seize opportunities to develop new partnerships within and outside of DOI to address facilities issues caused by seismic damage and park closure. ● Educate community members and new workers to increase early detection of invasive species and establish new wash stations to address biosecurity threats to the park posed by more frequent commuting from new temporary Hilo locations. ● Create a "vog officer" position to ensure coordination and consistency in communication about vog hazards across federal, state, and county agencies. It is important to note that the potential actions are suggestions and are not intended to be prescriptive. The SSG uses “blue sky thinking” when developing these potential actions to encourage creative approaches to problem solving. In some cases, some of the suggested potential actions derived by the SSG are actions that were already underway, or already under consideration and helped to affirm 3 activities by different stakeholders. In other cases, the actions may be new ideas. Some were applicable to immediate response, while others are more relevant to long-term recovery. This report details the results from the July 2018 activation of the SSG. It includes background on Kīlauea and the 2018 eruption, an overview of SSG methodology, and a complete list of the potential actions to mitigate cascading consequences identified by the SSG. Importantly, Appendix 4 includes several rapidly assembled “issue papers” on a variety of topics for consideration for recovery and future preparedness and response activities. This report is designed to be used by both the Department and more broadly by partners, including the Federal Emergency Management Agency, Hawai'i County, Hawai'i Department of Health, and the Hawai'i Emergency Management Agency.

Hawaii

Water, water everywhere, but every drop unique: Emerging challenges in the science to understand the role of contaminants in management of drinking water supplies

The protection and management of water resources continues to be challenged by multiple and ongoing factors such as shifts in demographic, social, economic, and public health requirements. Physical limitations placed on access to potable supplies include natural and human-caused factors such as aquifer depletion, aging infrastructure, saltwater intrusion, floods, and drought. These factors, although varying in magnitude, spatial extent, and timing, can exacerbate the potential for contaminants of concern (CECs) to be present in sources of drinking water, infrastructure, premise plumbing and associated tap water. This monograph examines how current and emerging scientific efforts and technologies increase our understanding of the range of CECs and drinking water issues facing current and future populations. It is not intended to be read in one sitting, but is instead a starting point for scientists wanting to learn more about the issues surrounding CECs. This text discusses the topical evolution CECs over time (Section 1), improvements in measuring chemical and microbial CECs, through both analysis of concentration and toxicity (Section 2) and modeling CEC exposure and fate (Section 3), forms of treatment effective at removing chemical and microbial CECs (Section 4), and potential for human health impacts from exposure to CECs (Section 5). The paper concludes with how changes to water quantity, both scarcity and surpluses, could affect water quality (Section 6). Taken together, these sections document the past 25 years of CEC research and the regulatory response to these contaminants, the current work to identify and monitor CECs and mitigate exposure, and the challenges facing the future.

GeoHealth

Quantifying the visual-sensory landscape qualities that contribute to cultural ecosystem services using social media and LiDAR

Landscapes are increasingly recognized for providing valuable cultural ecosystem services with numer- ous non-material benefits by serving as places of rest, relaxation, and inspiration that ultimately improve overall mental health and physical well-being. Maintaining and enhancing these valuable benefits through targeted management and conservation measures requires understanding the spatial and tem- poral determinants of perceived landscape values. Content contributed through mobile technologies and the web are emerging globally, providing a promising data source for localizing and assessing these land- scape benefits. These georeferenced data offer rich in situ qualitative information through photos and comments that capture valued and special locations across large geographic areas. We present a novel method for mapping and modeling landscape values and perceptions that leverages viewshed analysis of georeferenced social media data. Using a high resolution LiDAR (Light Detection and Ranging) derived digital surface model, we are able to evaluate landscape characteristics associated with the visual- sensory qualities of outdoor recreationalists. Our results show the importance of historical monuments and attractions in addition to specific environmental features which are appreciated by the public. Evaluation of photo-image content highlights the opportunity of including temporally and spatially vari- able visual-sensory qualities in cultural ecosystem services (CES) evaluation like the sights, sounds and smells of wildlife and weather phenomena.

North Carolina

Tritium and plutonium in waters from the Bering and Chukchi Seas

During the summer of 1993, seawater in the Bering and Chukchi Seas was sampled on a joint Russian-American cruise [BERPAC] of the RV Okean to determine concentrations of tritium, 239Pu and 240Pu. Concentrations of tritium were determined by electrolytic enrichment and liquid scintilation counting. Tritium levels ranged up to 420 mBq L-1 showed no evidence of inputs other than those attribute atmospheric nuclear weapons testing. Plutonium was recovered from water samples by ferric hydroxide precipitation, and concentrations were determined by thermal ionization mass spectrometry. 239+240Pu concentrations ranged from <1 to 5.5 [mu]Bq L-1. These concentrations are lower than those measured in water samples from other parts of the ocean during the mid-1960's to the late 1980's. The 240Pu:239Pu ratios, although associated with large uncertainties, suggest that most of the plutonium is derived from world-wide fallout. As points of comparison, the highest concentrations of tritium and plutonium observed here were about five orders of magnitude lower than the maximum permissible concentrations allowed in water released to the off-site environs from licensed nuclear facilities in the United States. This study and others sponsored by the International Atomic Energy Agency and the Office of Naval Research's Arctic Nuclear Waste Assessment Program are providing data for the assessment of potential radiological impacts in the Arctic regions associated with nuclear waste disposal by the former Soviet Union.

Health Physics

Sorption of 99m Tc radiopharmaceutical compounds by soils

Study of the sorption of 99mTc radiopharmaceutical compounds by soils has assessed the fate of these compounds in the event of a surface spill and examined the potential of these compounds as hydrologic tracers. Sorption from deionized water, filtered Missouri River water, and artificial seawater by five surface soils was investigated. For all water types, the Tc radiopharmaceutical compounds showed greater sorption than the uncomplexed pertechnetate. The most lipophilic complexes showed the highest sorption on soils.

Health Physics

Biota dose assessment of small rodents sampled near breccia pipe uranium mines in the Grand Canyon watershed

The biotic exposure and uptake of radionuclides and potential health effects due to breccia pipe uranium mining in the Grand Canyon watershed are largely unknown. This paper describes the use of the RESRAD-BIOTA dose model to assess exposure of small rodents (n = 11) sampled at three uranium mine sites in different stages of ore production (active and postproduction). Rodent tissue and soil concentrations of naturally occurring uranium (234U, 235U, and 238U), thorium (228Th, 230Th, and 232Th), and radium (226Ra) radioisotopes were used in the dose model. The dose assessment results indicated that the potential internal, external, and total doses to rodents were below the US Department of Energy’s biota dose standard of 1 mGy d−1. As expected, tissue concentrations of 238U, 234U, and 230Th were in approximate equilibrium; however, 226Ra results in tissue were 1.25 to 5.75 times greater than 238U, 234U, and 230Th tissue results for 10 out of 11 samples. Soil at the three sites also displayed 226Ra enrichment, so it is likely that the 226Ra enrichment in the rodents was from soil via typical activities (i.e., burrowing, incidental ingestion, bathing, etc.) or by dietary uptake of translocated 226Ra. The results suggest that 226Ra is more mobile in this environment and bioaccumulates in these rodent species (e.g., in bones via the bloodstream). Internal dose accounting suggests that 226Ra is the radionuclide of most concern for rodent exposure and health.

Grand Canyon

An assessment of radon in groundwater in New York State

Abstract: A set of 317 samples collected from wells throughout New York State (excluding Long Island) from 2003 through 2008 was used to assess the distribution of radon gas in drinking water. Previous studies have documented high concentrations of radon in groundwater from granitic and metamorphic bedrock, but there have been only limited characterizations of radon in water from sedimentary rock and unconsolidated sand-and-gravel deposits in New York. Approximately 8% of the samples from bedrock wells exceed 89 Bq L -1 (eight times the proposed regulatory limit), but only 2% of samples from sand-and-gravel wells exceed 44 Bq L -1 . Specific metamorphic and sedimentary rock formations in New York are associated with the high radon concentrations, indicating that specific areas of New York could be targeted with efforts to reduce the risk of exposure to radon in groundwater. Additionally, radon in groundwater from the sand-and-gravel aquifers was found to be directly correlated to radon in indoor air when assessed by county.

New York

Geochemical and radiological characterization of soils from former radium processing sites

Soil samples were collected from former radium processing sites in Denver, CO, and East Orange, NJ. Particle-size separations and radiochemical analyses of selected samples showed that while the greatest contents of both 226Ra and U were generally found in the finest (< 45 ??m) fraction, the pattern was not always of progressive increase in radionuclide content with decreasing particle size. Leaching tests on these samples showed a large portion of the 225Ra and U to be soluble in dilute hydrochloric acid. Radon-emanation coefficients measured for bulk samples of contaminated soil were about 20%. Recovery of residual uranium and vanadium, as an adjunct to any remedial action program, appears unlikely due to economic considerations.

Health Physics

A direct correlation among indoor Rn, soil gas Rn and geology in the Reading Prong near Boyertown, Pennsylvania

We feel that this study suggests a relationship among geology, soil gas Rn and the potential for indoor Rn accumulation in this portion of the Reading Prong. There are deviations from a perfect correlation but these are related to inhomogeneities in the geologic environment and perhaps variations in construction techniques of homes in the area. This study also demonstrates that several analyses in a small area may be necessary to adequately determine the Rn distribution for a particular geologic unit. That scale would be determined by the complexity of the local geology. Where no discrete source of elevated Rn supply is found for dwellings having a significant Rn accumulation, the implication is that overall gross permeability may be sufficient to supply Rn from a larger volume of soil and rock.

Health Physics

Recognition of microclimate zones through radon mapping, Lechuguilla Cave, Carlsbad Caverns National Park, New Mexico

Radon concentrations range from <185 to 3,515 Bq m-3 throughout Lechuguilla Cave, Carlsbad Caverns National Park, New Mexico. Concentrations in the entrance passages and areas immediately adjacent to these passages are controlled by outside air temperature and barometric pressure, similar to other Type 2 caves. Most of the cave is developed in three geographic branches beneath the entrance passages; these areas maintain Rn levels independent of surface effects, an indication that Rn levels in deep, complex caves or mines cannot be simply estimated by outside atmospheric parameters. These deeper, more isolated areas are subject to convective ventilation driven by temperature differences along the 477-m vertical extent of the cave. Radon concentrations are used to delineate six microclimate zones (air circulation cells) throughout the cave in conjunction with observed airflow data. Suspected surface connections contribute fresh air to remote cave areas demonstrated by anomalous Rn lows surrounded by higher values, the presence of mammalian skeletal remains, CO2 concentrations and temperatures lower than the cave mean, and associated surficial karst features.

Health Physics

Contribution of 222Rn in domestic water supplies to 222Rn in indoor air in Colorado homes

The contribution of 222Rn from domestic water wells to indoor air was investigated in a study of 28 houses near Conifer, CO. Air concentrations determined by alpha-track detectors (ATDs) and continuous radon monitors were compared with the predictions of a single-cell model. In many of the houses, the water supply was shown to contribute significantly to levels of indoor 222Rn. The data from the ATD study were augmented with a continuous monitoring study of a house near Lyons, CO. The well water in that house has the highest known concentration of 222Rn in water yet reported (93 MBq m-3). The temporal pattern in the indoor 222Rn concentration corresponds to water-use records. In general, it is difficult to quantify the proportion of indoor radon attributable to water use. Several lines of evidence suggest that the single-cell model underestimates this proportion. Continuous- monitoring data, although useful, are impractical due to the cost of the equipment. We propose a protocol for 222Rn measurement based on three simultaneous integrating radon detectors that may help estimate the proportion of indoor 222Rn derived from the water supply.

Health Physics

Relationships between 222Rn dissolved in ground water supplies and indoor 222Rn concentrations in some Colorado front range houses

Indoor 222Rn concentrations were measured in 37 houses with alpha track detectors placed in water-use rooms near water sources (bathrooms, laundry rooms, and kitchens) and in non-water-use living rooms, dining rooms, and bedrooms away from water sources. Results show that relative contributions of 222Rn to indoor air from water use are insignificant when soil-gas concentrations are high but become increasingly important as the ratio of 222Rn-in-water:222Rn-in-soil gas increases. High soil-gas 222Rn concentrations may mask 222Rn contributions from water even when waterborne 222Rn concentrations are as high as 750 kBq m-3. Ground water in Precambrian Pikes Peak granite averages 340 kBq m-3222Rn, vs. 170 kBq m-3 in Precambrian migmatite, but average 222Rn concentrations in soil gas are also lower in migmatite. Because the ratio of 222Rn-in- water:222Rn-in-soil gas may be consistently higher for houses in migmatite than in Pikes Peak granite, indoor air in houses built on migmatite may have a greater relative contribution from water use even though average 222Rn concentrations in the water are lower. Continuous monitoring of 222Rn concentrations in air on 15-min intervals also indicates that additions to indoor concentrations from water use are significant and measurable only when soil-gas concentrations are low and concentrations in water are high. When soil-gas concentrations were mitigated to less than 150 Bq m-3 in one house, water contributes 20-40% of the annual indoor 222Rn concentration in the laundry room (222Rn concentration in water of 670 kBq m-3). Conversely, when the mitigation system is inactive, diurnal fluctuations and other variations in the soil-gas 222Rn contribution swamp the variability due to water use in the house. Measurable variations in indoor concentrations from water use were not detected in one house despite a low soil-gas contribution of approximately 150 Bq m-3 because waterborne 222Rn concentrations also are low (80 kBq m-3). This result suggests that 222Rn concentrations in water near the recommended EPA limit in drinking water of 11 kBq m-3 may not contribute measurable amounts of 222Rn to indoor air in most houses.

Health Physics

222Rn variations in Mystery Cave, Minnesota

222Rn concentrations and meteorological parameters were measured at 4- h intervals over a 2-y period in Mystery Cave, southeastern Minnesota. Continuous radon monitors and meteorological sensors connected to data loggers were installed at several locations along commercial tour routes. 222Rn concentrations ranged as high as 25 kBq m-3 in summer and 20 kBq m-3 in winter. Average winter concentrations were lower than summer by at least a factor of two. Seasonal radon variations were correlative with outside air temperatures. During the winter, radon concentrations were observed to fluctuate periodically by factors of 20 or more in under 24 h. Both the long- and short-term variations are correlative with temperature- induced mixing of cave air with surface air.

Health Physics

Wildlife disease and environmental health in Alaska

Environmental health is defined by connections between the physical environment, ecological health, and human health. Current research within the U.S. Geological Survey (USGS) recognizes the importance of this integrated research philosophy, which includes study of disease and pollutants as they pertain to wildlife and humans. Due to its key geographic location and significant wildlife resources, Alaska is a critical area for future study of environmental health.

Alaska