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Flood-formed dunes in Athabasca Valles, Mars: Morphology, modeling, and implications

Estimates of discharge for martian outflow channels have spanned orders of magnitude due in part to uncertainties in floodwater height. A methodology of estimating discharge based on bedforms would reduce some of this uncertainty. Such a methodology based on the morphology and granulometry of flood-formed ('diluvial') dunes has been developed by Carling (1996b, in: Branson, J., Brown, A.G., Gregory, K.J. (Eds.), Global Continental Changes: The Context of Palaeohydrology. Geological Society Special Publication No. 115, London, UK, 165-179) and applied to Pleistocene flood-formed dunes in Siberia. Transverse periodic dune-like bedforms in Athabasca Valles, Mars, have previously been classified both as flood-formed dunes and as antidunes. Either interpretation is important, as they both imply substantial quantities of water, but each has different hydraulic implications. We undertook photoclinometric measurements of these forms, and compared them with data from flood-formed dunes in Siberia. Our analysis of those data shows their morphology to be more consistent with dunes than antidunes, thus providing the first documentation of flood-formed dunes on Mars. Other reasoning based on context and likely hydraulics also supports the bedforms' classification as dunes. Evidence does not support the dunes being aeolian, although a conclusive determination cannot be made with present data. Given the preponderance of evidence that the features are flood-formed instead of aeolian, we applied Carling's (1996b, in: Branson, J., Brown, A.G., Gregory, K.J. (Eds.), Global Continental Changes: The Context of Palaeohydrology. Geological Society Special Publication No. 115, London, UK, 165-179) dune-flow model to derive the peak discharge of the flood flow that formed them. The resultant estimate is approximately 2??106 m3/s, similar to previous estimates. The size of the Athabascan dunes' in comparison with that of terrestrial dunes suggests that these martian dunes took at least 1-2 days to grow. Their flattened morphology implies that they were formed at high subcritical flow and that the flood flow that formed them receded very quickly. ?? 2004 Elsevier Inc. All rights reserved.

Icarus

A primer on the geological occurrence of gas hydrate

This paper is part of the special publication Gas hydrates: relevance to world margin stability and climatic change (eds J.P. Henriet and J. Mienert).Natural gas hydrates occur world-wide in polar regions, usually associated with onshore and offshore permafrost, and in sediment of outer continental and insular margins. The total amount of methane in gas hydrates probably exceeds 1019 g of methane carbon. Three aspects of gas hydrates are important: their fossil fuel resource potential; their role as a submarine geohazard; and their effects on global climate change. Because gas hydrates represent a large amount of methane within 2000 m of the Earth's surface, they are considered to be an unconventional, unproven source of fossil fuel. Because gas hydrates are metastable, changes of pressure and temperature affect their stability. Destabilized gas hydrates beneath the sea floor lead to geological hazards such as submarine slumps and slides, examples of which are found world-wide. Destabilized gas hydrates may also affect climate through the release of methane, a 'greenhouse' gas, which may enhance global warming and be a factor in global climate change.

Geological Society Special Publication

Evidence for faulting related to dissociation of gas hydrate and release of methane off the southeastern United States

This paper is part of the special publication Gas hydrates: relevance to world margin stability and climatic change (eds J.P. Henriet and J. Mienert). An irregular, faulted, collapse depression about 38 x 18 km in extent is located on the crest of the Blake Ridge offshore from the south- eastern United States. Faults disrupt the sea floor and terminate or sole out about 40-500 m below the sea floor at the base of the gas hydrate stable zone, which is identified from the location of the bottom simulating reflection (BSR). Normal faults are common but reverse faults and folds also are widespread. Folds commonly convert upward into faults. Sediment diapirs and deposits of sediments that were erupted onto the sea floor are also present. Sea-floor depressions at faults may represent locations of liquid/gas vents. The collapse was probably caused by overpressures and by the decoupling of the overlying sediments by gassy muds that existed just beneath the zone of gas hydrate stability.

Blake Ridge

Late Neogene sedimentary facies and sequences in the Pannonian Basin, Hungary

This paper is part of the special publication No.156, The Mediterranean basins: Tertiary extension within the Alpine Orogen. (eds B.Durand, L. Jolivet, F.Horvath and M.Seranne). Detailed sedimentological, facies and numerical cycle analysis, combined with magnetostratigraphy, have been made in a number of boreholes in the Pannonian Basin, in order to study the causes of relative water-level changes and the history of the basin subsidence. Subsidence and infilling of the Pannonian Basin, which was an isolated lake at that time occurred mainly during the Late Miocene and Pliocene. The subsidence history was remarkably different in the individual sub-basins: early thermal subsidence was interrupted in the southern part of the basin, while high sedimentation rate and continuous subsidence was detected in the northeastern sub-basin. Three regional unconformities were detected in the Late Neogene Pannonian Basin fill, which represent 0.5 and 7.5 Ma time spans corresponding to single and composite unconformities. Consequently two main sequences build up the Late Neogene Pannonian Basin fill: a Late Miocene and a Pliocene one. Within the Late Miocene sequence there are smaller sedimentary cycles most probably corresponding to climatically driven relative lake-level changes in the Milankovitch frequency band. Considering the periods, the estimated values for precession and eccentricity in this study (19 and 370 ka) are close to the usually cited ones. In the case of obliquity the calculated period (71 ka) slightly deviates from the generally accepted number. Based on the relative amplitudes of oscillations, precession (sixth order) and obliquity (fifth order) cycles had the most significant impact on the sedimentation. Eccentricity caused cycles (fourth order) are poorly detectable in the sediments. The longer term (third order) cycles had very slight influence on the sedimentation pattern. Progradation, recorded in the Late Miocene sequence, correlates poorly in time within the basin. The dominant controls of this process probably were changes of basin subsidence rate and the very high sedimentation rate. The slow, upward trend of silt and sand bed thickness as well as that of the grain size also reflects the local progradation.

Geological Society Special Publication

Crustal extension along a rooted system of imbricate low-angle faults: Colorado River extensional corridor, California and Arizona

The upper 10 to 15 km of crystalline crust in the 100-km-wide Colorado River extensional corridor of mid-Tertiary age underwent extension along an imbricate system of gently dipping normal faults. Detachment faults cut gently down-section eastward in the direction of tectonic transport from a headwall breakaway, best expressed in the Old Woman Mountains, California. Successively higher and more distal allochthons are displaced farther from the headwall, some as much as tens of kilometres. The basal fault(s) cut initially to depths of 10 to 15 km, the palaeothickness of a tilted allochthonous slab of basement rocks above the Chemehuevi-Whipple Mountains detachment fault(s). Hanging wall blocks tilt consistently toward the headwall as shown by dips of capping Tertiary strata and of originally horizontal Proterozoic diabase dykes. Block tilts and the degree of extension increase northeastward across much of the corridor. The faults are interpreted as rooting under the unbroken Hualapai Mountains and Colorado Plateau on the down-dip side of the corridor in Arizona. Slip on faults at all exposed levels of the crust was unidirectional, and totals an estimated 50 km. These data and inferences support the concept that the crust in California moved out from under Arizona along a rooted, normal-slip shear system. Brittle thinning above the sole faults affected the entire upper crust, and in places wholly removed it along the central part of the corridor. Upwarp exposed metamorphic core complexes in footwall domes.

Geological Society Special Publication

Evolution of the western part of the Coast plutonic–metamorphic complex, South-Eastern Alaska, USA: A summary

The western Cordillera of North America extends for over 6000 km from the tip of Baja California to the Alaska Range. It includes a wide variety of metamorphic and plutonic terrains, but none is more spectacular scenically or geologically than the Coast plutonic-metamorphic complex (Brew & Ford 1984) of western Canada and south-eastern Alaska. This report briefly describes the evolution of the western part of the complex, integrating information from the deformational, plutonic and metamorphic events. Most of the original studies are reported by the authors in U.S. Geological Survey Circular numbers 733, 751, 823-B, 868, 939, 945, 967 and 978, and are not cited specifically here. This summary does not contain either a comprehensive bibliography or a comparison of the metamorphic histories of south-eastern Alaska with the adjacent parts of British Columbia. The Coast plutonic-metamorphic complex is here divided into three major elements: the western metamorphic, the central granitic and the eastern metamorphic zones (Fig. 1). The western metamorphic belt is extremely long (900 km), and narrow (7–25 km). It consists of regional dynamothermally and regional thermally metamorphosed rocks with mineral assemblages ranging from prehnite-pumpellyite to upper amphibolite facies, scattered mesozonal to epizonal granitic bodies, and a few concentrically zoned mafic-ultramafic masses. The metamorphic grade and the amount of deformation increase from south-west to north-east, culminating at, or slightly to the north-east of, the ‘great tonalite sill’: a remarkable 700-km-long, 3- to 25-km-wide vertical to northeast-dipping belt of mostly syntectonic plutons of approximately the same age, composition and structural

Alaska

Deep-sea ostracode shell chemistry (Mg:Ca ratios) and late Quaternary Arctic Ocean history

The magnesium:calcium (Mg:Ca) and strontium:calcium (Sr:Ca) ratios were investigated in shells of the benthic ostracode genus Krithe obtained from 64 core-tops from water depths of 73 to 4411 m in the Arctic Ocean and Nordic seas to determine the potential of ostracode shell chemistry for palaeoceanographic study. Shells from the Polar Surface Water (−1 to −1.5°C) had Mg:Ca molar ratios of about 0.006–0.008; shells from Arctic Intermediate Water (+0.3 to +2.0°C) ranged from 0.09 to 0.013. Shells from the abyssal plain and ridges of the Nansen, Amundsen and Makarov basins and the Norwegian and Greenland seas had a wide scatter of Mg:Ca ratios ranging from 0.007 to 0.012 that may signify post-mortem chemical alteration of the shells from Arctic deep-sea environments below about 1000 m water depth. There is a positive correlation ( r 2 = 0.59) between Mg:Ca ratios and bottom-water temperature in Krithe shells from Arctic and Nordic seas from water depths <900 m. Late Quaternary Krithe Mg:Ca ratios were analysed downcore using material from the Gakkel Ridge (water depths 3047 and 3899 m), the Lomonosov Ridge (water depth 1051 m) and the Amundsen Basin (water depth 4226 m) to test the core-top Mg:Ca temperature calibration. Cores from the Gakkel and Lomonosov ridges display a decrease in Mg:Ca ratios during the interval spanning the last glacial/deglacial transition and the Holocene, perhaps related to a decrease in bottom water temperatures or other changes in benthic environments.

Geological Society Special Publication

Iron and manganese oxide mineralization in the Pacific

Iron, manganese, and iron-manganese deposits occur in nearly all geomorphologic and tectonic environments in the ocean basins and form by one or more of four processes: (1) hydrogenetic precipitation from cold ambient seawater, (2) precipitation from hydrothermal fluids, (3) precipitation from sediment pore waters that have been modified from bottom water compositions by diagenetic reactions in the sediment column and (4) replacement of rocks and sediment. Iron and manganese deposits occur in five forms: nodules, crusts, cements, mounds and sediment-hosted stratabound layers. Seafloor oxides show a wide range of compositions from nearly pure iron to nearly pure manganese end members. Fe/Mn ratios vary from about 24 000 (up to 58% elemental Fe) for hydrothermal seamount ironstones to about 0.001 (up to 52% Mn) for hydrothermal stratabound manganese oxides from active volcanic arcs. Hydrogenetic Fe-Mn crusts that occur on most seamounts in the ocean basins have a mean Fe/Mn ratio of 0.7 for open-ocean seamount crusts and 1.2 for continental margin seamount crusts. Fe-Mn nodules of potential economic interest from the Clarion-Clipperton Zone have a mean Fe/Mn ratio of 0.3, whereas the mean ratio for nodules from elsewhere in the Pacific is about 0.7. Crusts are enriched in Co, Ni and Pt and nodules in Cu and Ni, and both have significant concentrations of Pb, Zn, Ba, Mo, V and other elements. In contrast, hydrothermal deposits commonly contain only minor trace metal contents, although there are many exceptions, for example, with Ni contents up to 0.66%, Cr to 1.2%, and Zn to 1.4%. Chondrite-normalized REE patterns generally show a positive Ce anomaly and abundant ΣREEs for hydrogenetic and mixed hydrogenetic-diagenetic deposits, whereas the Ce anomaly is negative for hydrothermal deposits and ΣREE contents are low. However, the Ce anomaly in crusts may vary from strongly positive in East Pacific crusts to slightly negative in West Pacific crusts, which may reflect the redox conditions of seawater. The concentration of elements in hydrogenetic Fe-Mn crusts depends on a wide variety of water column and crust surface characteristics, whereas concentration of elements in hydrothermal oxide deposits depends of the intensity of leaching, rock types leached, and precipitation of sulphides at depth in the hydrothermal system.

Geological Society Special Publication

Sediment delivery to the Gulf of Alaska: Source mechanisms along a glaciated transform margin

Sediment delivery to the Gulf of Alaska occurs via four areally extensive deepwater fans, sourced from grounded tidewater glaciers. During periods of climatic cooling, glaciers cross a narrow shelf and discharge sediment down the continental slope. Because the coastal terrain is dominated by fjords and a narrow, high-relief Pacific watershed, deposition is dominated by channellized point-source fan accumulations, the volumes of which are primarily a function of climate. The sediment distribution is modified by a long-term tectonic translation of the Pacific plate to the north along the transform margin. As a result, the deep-water fans are gradually moved away from the climatically controlled point sources. Sets of abandoned channels record the effect of translation during the Plio-Pleistocene.

Geological Society Special Publication

Ordovician K-bentonites in the Argentine Precordillera: Relations to Gondwana margin evolution

Ordovician K-bentonites have now been recorded from >20 localities in the vicinity of the Argentine Precordillera. Most occur in the eastern thrust belts, in the San Juan Limestone and the overlying the Gualcamayo Formation, but a few ash beds are known also from the central thrust belts. The oldest occur in the middle Arenig I. victoriae lunatus graptolite ( Oe. evae conodont) Zone, and the youngest in the middle Llanvirn P. elegans ( P. suecicus ) Zone. Mineralogical characteristics, typical of other Ordovician K-bentonites, include a matrix of illite/smectite mixed-layer clay and a typical felsic volcanic phenocryst assemblage: biotite, beta-form quartz, alkali and plagioclase feldspar, apatite, and zircon, with lesser amounts of hornblende, clinopyroxene, titanite and Fe-Ti oxides. The proportions of the mineral phases and variations in their crystal chemistry are commonly unique to individual (or small groups of) K-bentonite beds. Glass melt inclusions preserved in quartz are rhyolitic in composition. The sequence is unique in its abundance of K-bentonite beds, but a close association between the Precordillera and other Ordovician sedimentary basins cannot be established. The ash distribution is most consistent with palaeogeographical reconstructions in which early Ordovician drifting of the Precordillera occurred in proximity to one or more volcanic arcs, and with eventual collision along the Andean margin of Gondwana during the mid-Ordovician Ocloyic event of the Famatinian orogeny. The Puna-Famatina terrane northeast of the Precordillera might have served as the source of the K-bentonite ashes, possibly in concert with active arc magmatism on the Gondwana plate itself.

Geological Society Special Publication

Geology of the Sierra de Fiambala, northwestern Argentina: Implications for Early Palaeozoic Andean tectonics

Field mapping in conjunction with structural, metamorphic, and geochronological data document the tectono-thermal history of exhumed deep crustal rocks in the Sierra de Fiambalá, NW Argentina. The range consists of two structural blocks distinguished by different metasedimentary sequences and different grades of metamorphism. Orthogneiss and paragneiss in the northern structural block may have a Precambrian history. Greenschist- to amphibolite-facies metamorphism, intrusion, and injection migmatization affected all rocks at 540–550 Ma. A subsequent event in the Late Cambrian to Ordovician ( c. 515 to 470 Ma) involved amphibolite- to granulite-facies metamorphism, mafic intrusion, and deformation, followed by cooling through mid-Palaeozoic time. The emplacement of Carboniferous (325–350 Ma) post-tectonic granites caused reheating and retrogression that was strongest toward the northeast part of the range. The Cambrian, Ordovician, and Carboniferous events in the Sierra de Fiambalá were of regional extent as indicated by temporal correlations with events reported for other deep crustal rocks of the northern Sierras Pampeanas. Correlations between periods of intrusion and high-grade metamorphism in the northern Sierras Pampeanas and volcanic-sedimentary events in the adjacent supracrustal exposures confirm that rocks in the northern Sierras Pampeanas formed at deep (10–25 km) structural levels in the early Palaeozoic continental margin of Gondwana.

Geological Society Special Publication

Depositional facies and sequence stratigraphy of a Lower Carboniferous bryozoan-crinoidal carbonate ramp in the Illinois Basin, mid-continent USA

The Lower Carboniferous Fort Payne and Ullin Formations in the Illinois Basin form the transgressive and highstand systems tracts that were deposited in a carbonate ramp setting. During deposition of the Ullin Limestone, biotic communities dominated by fenestrate bryozoans and echinoderms (primarily crinoids) proliferated, possibly in response to global tectonic, biological, and oceanographic events that affected bathymetry and nutrient supply. The Fort Payne Formation consists of a dark grey-brown, siliceous and argillaceous lime mudstone in the lower part (transgressive systems tract) and a very fine-grained wackestone to packstone with rare mud mounds in the upper part (early highstand), and was deposited in an outer ramp to basinal environment. During deposition of the lower Ullin Limestone (mostly early highstand), bryozoan-crinoidal build-ups accreted both laterally and vertically into several relatively large carbonate banks, which were partly surrounded by siliceous Fort Payne sea. Bryozoans (primarily fenestrates) were especially prevalent during the late stage of bank development and formed mud-free bioherms up to 120 m thick. In places, carbonate mud mounds also formed during the early stage of bank deposition. Bioherm development declined during deposition of the upper Ullin Limestone (late highstand), and a broad, storm-dominated carbonate ramp was established that became the site for widespread deposition of bryozoan-crinoidal sandwaves. Gradual shallowing led to ooid formation at the end of Ullin deposition. This sequence was terminated by a relative rise in sea level that resulted in deposition of the transgressive facies of the lower part of the overlying Salem Limestone. The depositional style and the nature of skeletal material of the Fort Payne and Ullin Formations are similar to those of cool-water carbonates. A deep-water setting along with upwelling of cool, nutrient-rich oceanic waters may have been responsible for the proliferation of bryozoans and crinoids at this time. The deep-water setting and abundant nutrient supply also may have restricted the formation of ooids and proliferation of shallow-water calcareous organisms.

Geological Society Special Publication

The northern Sacramento Mountains, southwest United States. Part II: Exhumation history and detachment faulting

Thermochronologic and thermobarometric data reveal the timing, distribution and intensity of thermal events associated with detachment faulting in the Sacramento Mountains metamorphic core complex. In the northwest Sacramento Mountains, cooling rates of c. 100°C Ma −1 are associated with Late Cretaceous plutonism followed by cooling of the crust by thermal conduction. Post-Late Cretaceous cooling slowed to c. 1–6°C Ma −1 . Finally, the region records average cooling rates of 38–53°C Ma −1 between c. 20 and 15 Ma. In contrast, the thermal profile of the northeast Sacramento Mountains is dominated by syntectonic Tertiary plutonism followed by very rapid cooling. A granodioritic suite intruded at c. 680°C and c. 3 kbar at c. 20 Ma, records cooling to <100°C by c. 15 Ma. Such rapid cooling and exhumation suggests that unroofing by tectonic denudation was the driving mechanism for the final cooling. The similarity of the miocene cooling profiles between these two areas clearly suggests that the Sacramento Mountains experienced a regional cooling event associated with tectonic unroofing driven by regional Miocene crustal extension. Estimates of the initial angle of the Sacramento Mountains detachment fault using palaeothermal gradients suggest that it was active at a dip of 25°.

Geological Society Special Publication

Prodigious polyphyly in imperilled freshwater pearly-mussels (Bivalvia: Unionidae): a phylogenetic test of species and generic designations

Unionid bivalves or freshwater pearly-mussels (Unionoidea: Unionidae) serve as an exemplary system for examining many of the problems facing systematists and conservation biologists today. Most of the species and genera were described in the late 1800s and early 1900s, but few phylogenetic studies have been conducted to test conventional views of species and classification. Pearly-mussels of Gulf Coastal drainages of the southeastern United States from the Escambia (southern Alabama to Florida) to the Suwannee Rivers (Florida) are a unique fauna comprised of approximately 100 species, with about 30 endemic to the region. In this study, mitochondrial cytochrome c oxidase subunit I and 16S rRNA gene sequences were used to test the monophyly and to estimate evolutionary relationships of five unionid species representing three different genera. The molecular phylogenies depict all three genera as polyphyletic. The prodigious polyphyly exhibited within unionids is due to incorrect notions of homology and false assumptions about missing anatomical data. In contrast, the molecular phylogeny provides evidence to support the recognition of all five unionid species as distinct evolutionary entities. Furthermore, molecular genealogical evidence supports the elevation of Quincuncina infucata (Conrad) of the Suwannee River to species level, for which Q. kleiniana (Lea) is available.

Geological Society Special Publication

Seismic evidence for a mantle source for mid-Proterozoic anorthosites and implications for models of crustal growth

Voluminous anorthosite intrusions are common in mid-Proterozoic crust. Historically, two end-member models have been proposed for the origin of these anorthosites. In the first model anorthosites derive from fractionation of a mantle source leaving a residue of metagabbro in the lower crust; in the second model anorthosites are the product of partial melting of the lower crust with residual pyroxene and high-grade minerals (i.e. a pyroxenitic and/or metapelitic lower crust). Although a general consensus has developed that the first model provides the best fit to petrological and geochemical constraints, the sparse evidence for mafic and ultramafic counterparts to the anorthosites leaves the issue still unresolved. We use the absolute P-wave velocity and the ratio between P- and S-wave velocities ( V P / V S ) to infer the composition of the lower crust beneath the Marcy Anorthosite (New York State, USA). Seismic refraction data reveal a lower crust 20 km thick, where V P and V P /V S range from top to bottom between 7.0 km s −1 and 7.2 ± 0.1 and 1.84 km s −1 and 1.81 ± 0.02, respectively. Laboratory measurements on rock samples indicate that these seismic properties are typical of plagioclase-rich rocks. Magmatic underplating of basaltic melts is a mechanism to form plagioclase-rich bulk composition for the Grenville crust. At the bottom of the lower crust, increase of P-wave velocity, slight decrease of V P / V S ratios and the presence of a low-reflective seismic Moho are additional observations supporting crustmantle interactions related to magmatic underplating. High P-wave velocity (8.6 km s −1 ) in the upper mantle may indicate that the ultramafic portion (e.g. pyroxenites) of the underplated magma has become eclogite. High average P-wave velocity (6.7 km s −1 ) and V P / V S (1.81), and the exceptional abundance of anorthosites-norites-troctolites among the rocks exposed at the surface, indicate that the Grenville Proterozoic crust may have a unique plagioclase-rich bulk composition. We suggest magmatic underplating, occurring either over a wide time span or with separate syn- and post-collisional magmatic pulses, as being a major crust-forming mechanism operating in mid-Proterozoic time.

Geological Society Special Publication

Volatiles in basaltic glasses from a subglacial volcano in northern British Columbia (Canada): Implications for ice sheet thickness and mantle volatiles

Dissolved H 2 O, CO 2 , S and Cl concentrations were measured in glasses from Tanzilla Mountain, a 500 m-high, exposed subglacial volcano from the Tuya-Teslin region, north central British Columbia, Canada. The absence of a flat-topped subaerial lava cap and the dominance of pillows and pillow breccias imply that the Tanzilla Mountain volcanic edifice did not reach a subaerial eruptive phase. Lavas are dominantly tholeiitic basalt with minor amounts of alkalic basalt erupted at the summit and near the base. Tholeiites have roughly constant H 2 O (c.0.56 ± 0.07 wt%), CO 2 (<30 ppm), S ( 980+ or -30 ppm) and Cl ( 200+ or -20 ppm) concentrations. Alkalic basalts have higher and more variable volatile concentrations that decrease with increasing elevation (0.62-0.92 wt% H2O, <30 ppm CO 2 , 870-1110 ppm S and 280-410 ppm Cl) consistent with eruptive degassing. Calculated vapour saturation pressures for the alkalic basalts are 36 to 81 bars corresponding to ice thicknesses of 400 to 900 m. Maximum calculated ice thickness (c. 1 km) is at the lower end of the range of predicted maximum Fraser glaciation (c. 1-2 km), and may indicate initiation of volcanism during the waning stages of glaciation. Temporal evolution from tholeiitic to alkalic compositions may reflect compositional gradients within a melting column, instead of convective processes within a stratified magma chamber. The mantle source region for the subglacial volcanoes is enriched in incompatible elements similar to that for enriched mid-oceanic ridge basalt (e.g. Endeavour Ridge) and does not contain residual amphibole. Thus, metasomatic enrichment most likely reflects small degree partial melts rather than hydrous fluids.

Geological Society Special Publication

Subglacial volcanic features beneath the West Antarctic Ice Sheet interpreted from aeromagnetic and radar ice sounding

The West Antarctic Ice Sheet (WAIS) flows through the volcanically active, late Cenozoic West Antarctic rift system. Active subglacial volcanism and a vast (>106 km3) extent of subglacial volcanic structures have been interpreted from aerogeophysical surveys over central West Antarctica in the past decade, combined with results from 1960s and 1970s aeromagnetic profiles over the WAIS. Modelling of magnetic anomalies constrained by radar ice sounding shows volcanic sources at the base of the ice throughout large areas, whose subglacially erupted hyaloclastite edifices have been eroded by moving ice, as in Iceland. The 1800 m-high divide of the WAIS is underlain by the 400 km-long volcanic Sinuous Ridge, which rises above sea level; most hyaloclastite edifices there have also been glacially removed, indicating migration of the ice divide through time. Northeast of the divide of the WAIS there is a 400-nT positive magnetic anomaly over the shallowest, most rugged bedrock topography (elevation +380 m above sea level), probably comprising subaerially erupted flows erupted when the Sinuous Ridge area was deglaciated. Uplift of the Sinuous Ridge may have forced the advance of the WAIS. Other aspects of the subglacial volcanism in Antarctica can be observed in Iceland and have a direct bearing on our understanding of the subglacial conditions of the WAIS and its dynamics.

Geological Society Special Publication

Distinguishing palagonitized from pedogenically-altered basaltic Hawaiian tephra: Mineralogical and geochemical criteria

Palagonitization is a common, but imperfectly defined process that greatly modifies the physical and chemical properties of glassy basaltic tephra deposited in subaquatic/subglacial environments on Earth and perhaps Mars. It also results in textures and mineralogies that are distinct from other forms of (mainly pedogenic) low temperature alteration. Specifically, the process of palagonitization (1) initially results in the formation of 'palaginitized glass', a quasi- or nano-crystalline, rind-like material that contains smectite, as well as lesser amounts of other clays (e.g. serpentine), and (2) eventually results in consolidation of tephra, mediated through the accretion of palagonitized glass and later- formed authigenic cements. Conversely, pedogenic weathering of glassy basaltic tephra is characterized by disaggregation of tephra, and formation of a wide range of pedogenic products, including layer silicates (although not primarily smectite), short-range-order aluminosilicates and oxyhydroxides, whose composition reflects the intensity of the weathering environment. These mineralogical and textural properties can be readily recognized through a variety of techniques including electron microscopy/microprobe analysis, reflectance spectroscopy, X-ray diffraction and soil chemistry. Analyses of samples collected from the summit regions of Kilauea and Mauna Kea volcanoes on the island of Hawaii are presented here in order to illustrate differences between palagonitization and pedogenic weathering of glassy basaltic tephra. In the young Hawaiian tephras studied, palagonitization has occurred in response to hydrothermal activity shortly after deposition. Although some, non-hydrothermally affected tephras may eventually become palagonitized, those that have been strongly desilicated by intense pedogenic weathering will probably never become palagonitized.

Geological Society Special Publication