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Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada: hydrology and geochemistry

This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California , edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description , for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

Nevada↗

Geology of a zone of metamorphic core complexes in southeastern Arizona

An elongate northwest-trending zone of batholith-size metamorphic core complexes extends some 130 km from the Rincon Mountains to the Picacho Mountains in southeastern Arizona. The complexes are characterized by undeformed to gneissic granitic intrusions, gneissic to phyllonitic xenoliths and wall rocks derived mainly from Precambrian granitic rock, shallow-dipping foliation, and remarkably uniform directions of lineation. Parts of this zone have been recognized and studied extensively for more than 30 yr, but there remains a divergence of opinion about the age, depth of emplacement, and origin of the complexes. Field relations indicate that host rocks as young as or younger than Mesozoic were involved in cataclasis. K-Ar and fission-track ages indicate that the complexes were at temperatures uniformly in excess of 400°C in the middle Tertiary (20 to 30 m.y. ago) and that the bedrock between and very near the complexes was not thermally affected. Tertiary plutons characteristically associated with the high-grade metamorphic rocks are also cataclastically deformed, and stratigraphic depths to the top of metamorphic terranes were no more than 6 km and possibly less than 3 km. These and other data suggest to some that the complexes developed during intrusion of composite batholiths at shallow depth in an anisotropic stress field during the middle Tertiary. On the other hand, Rb-Sr and U-Th-Pb techniques yielded older ages (≥44 m.y.) for some samples. These and additional data suggest to others that major development of cataclasis preceded the middle Tertiary and included regional thrusting.

Arizona↗

Age of biostratigraphic horizons within the Ordovician and Silurian systems

Three samples that have a bearing on the age of horizons within the Ordovician and Silurian systems, two previously dated by the conventional K-Ar method and one by the 40 Ar/ 39 Ar total-fusion method, have been reanalysed using the 40 Ar/ 39 Ar age-spectrum method. Conventional K-Ar and total-fusion 40 Ar/ 39 Ar ages can always be questioned because of the relative ease with which the K-Ar system can be disturbed, either thermally or chemically (i.e. Dalrymple & Lanphere 1969; Clauer et al. 1982). The 40 Ar/ 39 Ar age-spectrum method has the potential for identifying disturbed K-Ar systems (i.e. Berger 1975; Harrison & McDougall 1980). The authors feel that the age-spectrum data from these samples are significant because the previous results for these samples have been questioned in recently proposed Palaeozoic time-scales because of a possible disturbance of the K-Ar isotopic system (i.e. Gale et al. 1979, 1980; Gale 1982).

Geological Society Memoir↗

An overview of the petroleum geology of the Arctic

Nine main petroleum provinces containing recoverable resources totalling 61 Bbbl liquids+269 Bbbloe of gas are known in the Arctic. The three best known major provinces are: West Siberia–South Kara, Arctic Alaska and Timan–Pechora. They have been sourced principally from, respectively, Upper Jurassic, Triassic and Devonian marine source rocks and their hydrocarbons are reservoired principally in Cretaceous sandstones, Triassic sandstones and Palaeozoic carbonates. The remaining six provinces except for the Upper Cretaceous–Palaeogene petroleum system in the Mackenzie Delta have predominantly Mesozoic sources and Jurassic reservoirs. There are discoveries in 15% of the total area of sedimentary basins ( c. 8×10 6 km 2 ), dry wells in 10% of the area, seismic but no wells in 50% and no seismic in 25%. The United States Geological Survey estimate yet-to-find resources to total 90 Bbbl liquids+279 Bbbloe gas, with four regions – South Kara Sea, Alaska, East Barents Sea, East Greenland – dominating. Russian estimates of South Kara Sea and East Barents Sea are equally positive. The large potential reflects primarily the large undrilled areas, thick basins and widespread source rocks.

Geological Society Memoir↗

Geology and petroleum potential of the Timan-Pechora Basin Province, Russia

The Timan–Pechora Basin Province represents the northeastern-most cratonic block of Eastern European Russia. More than 16 billion barrels of oil (BBO) and 40 trillion cubic feet of gas (TCFG) have been discovered in this basin. Three geological assessment units (AU) were defined for assessing the potential for undiscovered oil and gas resources. The NW Izhma Depression AU encompasses all potential structures and reservoirs in the northwestern part of the Izhma–Pechora Depression, but this part of the basin contains little source and reservoir rocks and so was not assessed quantitatively. The Main Basin Platform AU includes all structures and reservoirs that developed in the central part of the basin where the tectonic evolution and development of petroleum systems were complex. The Foredeep Basins AU includes all potential reservoirs within the thick sedimentary section of the foredeep basins developed during the Permo-Triassic Uralian Orogeny. For the Timan–Pechora Basin Province, the estimated means of undiscovered resources are 3.3 BBO, 17 TCFG and 0.3 billion barrels of natural gas liquids (BBNGL). For the areas of the AUs north of the Arctic Circle in the Timan–Pechora Basin Province, the estimated means of undiscovered resources are 1.7 BBO, 9.0 TCFG and 0.2 BBNGL. The Pechora Sea was assessed with the South Barents Sea Province and is not included in this assessment.

Pechora Basin Province↗

Geology and petroleum potential of the east Barents Sea Basins and Admiralty Arch

The US Geological Survey (USGS) recently assessed the potential for undiscovered oil and gas resources of the East Barents Basins and Novaya Zemlya Basins and Admiralty Arch Provinces as part of the USGS Circum-Arctic Resource Appraisal. These two provinces are located NE of Scandinavia and the northwestern Russian Federation, on the Barents Sea Shelf between Novaya Zemlya to the east and the Barents Platform to the west. Three assessment units (AUs) were defined in the East Barents Basins for this study – Kolguyev Terrace Assessment Unit (AU), South Barents Basin and Ludlov Saddle AU, and North Barents Basin AU. A fourth, defined as Novaya Zemlya Basins and Admiralty Arch AU, is coincident with the Novaya Zemlya basins and Admiralty Arch Province. These AUs, all lying north of the Arctic Circle, were assessed for undiscovered, technically recoverable resources resulting in total estimated mean volumes of approximately 7.4 billion barrels of crude oil, 318 trillion cubic feet of natural gas and 1.4 billion barrels of natural gas liquids.

Geological Society Memoir↗

Sedimentary successions of the Arctic Region (58–64° to 90°N) that may be prospective for hydrocarbons

A total of 143 sedimentary successions that contain, or may be prospective for, hydrocarbons were identified in the Arctic Region north of 58&ndash;64&deg;N and mapped in four quadrants at a scale of 1:11 000 000. Eighteen of these successions (12.6%) occur in the Arctic Ocean Basin, 25 (17.5%) in the passive and sheared continental margins of the Arctic Basin and 100 (70.0%) on the Circum-Arctic continents of which one (<1%) lies in the active margin of the Pacific Rim. Each succession was assigned to one of 13 tectono-stratigraphic and morphologic classes and coloured accordingly on the map. The thickness of each succession and that of any underlying sedimentary section down to economic basement, where known, are shown on the map by isopachs. Major structural or tectonic features associated with the creation of the successions, or with the enhancement or degradation of their hydrocarbon potential, are also shown. Forty-four (30.8%) of the successions are known to contain hydrocarbon accumulations, 64 (44.8%) are sufficiently thick to have generated hydrocarbons and 35 (24.5%) may be too thin to be prospective.

Geological Society Memoir↗

Geology and petroleum potential of the north and east margins of the Siberian Craton, north of the Arctic Circle

The Siberian Craton consists of crystalline rocks and superimposed Precambrian sedimentary rocks deposited in rift basins. Palaeozoic rocks, mainly carbonates, were deposited along the margins of the craton to form an outwardly younger concentric pattern that underlies an outward-thickening Mesozoic sedimentary section. The north and east margins of the Siberian Craton subsequently became foreland basins created by compressional deformation during collision with other tectonic plates. The Tunguska Basin developed as a Palaeozoic rift/sag basin over Proterozoic rifts. The geological provinces along the north and east margins of the Siberian Craton are immature with respect to exploration, so exploration-history analysis alone cannot be used for assessing undiscovered petroleum resources. Therefore, other areas from around the world having greater petroleum exploration maturity and similar geological characteristics, and which have been previously assessed, were used as analogues to aid in this assessment. The analogues included those of foreland basins and rift/sag basins that were later subjected to compression. The US Geological Survey estimated the mean undiscovered, technically recoverable conventional petroleum resources to be approximately 28 billion barrels of oil equivalent, including approximately 8 billion barrels of crude oil, 103 trillion cubic feet of natural gas and 3 billion barrels of natural gas liquids.

Siberian Craton↗

Circum-Arctic mapping project: New magnetic and gravity anomaly maps of the Arctic

New Circum-Arctic maps of magnetic and gravity anomalies have been produced by merging regional gridded data. Satellite magnetic and gravity data were used for quality control of the long wavelengths of the new compilations. The new Circum-Arctic digital compilations of magnetic, gravity and some of their derivatives have been analyzed together with other freely available regional and global data and models in order to provide a consistent view of the tectonically complex Arctic basins and surrounding continents. Sharp, linear contrasts between deeply buried basement blocks with different magnetic properties and densities that can be identified on these maps can be used, together with other geological and geophysical information, to refine the tectonic boundaries of the Arctic domain.

Geological Society Memoir↗

Geology and petroleum potential of the Arctic Alaska petroleum province

The Arctic Alaska petroleum province encompasses all lands and adjacent continental shelf areas north of the Brooks Range–Herald Arch orogenic belt and south of the northern (outboard) margin of the Beaufort Rift shoulder. Even though only a small part is thoroughly explored, it is one of the most prolific petroleum provinces in North America with total known resources (cumulative production plus proved reserves) of c . 28 BBOE. The province constitutes a significant part of a displaced continental fragment, the Arctic Alaska microplate, that was probably rifted from the Canadian Arctic margin during formation of the Canada Basin. Petroleum prospective rocks in the province, mostly Mississippian and younger, record a sequential geological evolution through passive margin, rift and foreland basin tectonic stages. Significant petroleum source and reservoir rocks were formed during each tectonic stage but it was the foreland basin stage that provided the necessary burial heating to generate petroleum from the source rocks. The lion's share of known petroleum resources in the province occur in combination structural–stratigraphic traps formed as a consequence of rifting and located along the rift shoulder. Since the discovery of the super-giant Prudhoe Bay accumulation in one of these traps in the late 1960s, exploration activity preferentially focused on these types of traps. More recent activity, however, has emphasized the potential for stratigraphic traps and the prospect of a natural gas pipeline in this region has spurred renewed interest in structural traps. For assessment purposes, the province is divided into a Platform assessment unit (AU), comprising the Beaufort Rift shoulder and its relatively undeformed flanks, and a Fold-and-Thrust Belt AU, comprising the deformed area north of the Brooks Range and Herald Arch tectonic belt. Mean estimates of undiscovered, technically recoverable resources include nearly 28 billion barrels of oil (BBO) and 122 trillion cubic feet (TCF) of nonassociated gas in the Platform AU and 2 BBO and 59 TCF of nonassociated gas in the Fold-and-Thrust Belt AU.

Alaska↗

Geology and petroleum potential of the rifted margins of the Canada Basin

Three sides of the Canada Basin are bordered by high-standing, conjugate rift shoulders of the Chukchi Borderland, Alaska and Canada. The Alaska and Canada margins are mantled with thick, growth-faulted sediment prisms, and the Chukchi Borderland contains only a thin veneer of sediment. The rift-margin strata of Alaska and Canada reflect the tectonics and sediment dispersal systems of adjacent continental regions whereas the Chukchi Borderland was tectonically isolated from these sediment dispersal systems. Along the eastern Alaska–southern Canada margin, termed herein the ‘Canning–Mackenzie deformed margin’, the rifted margin is deformed by ongoing Brooks Range tectonism. Additional contractional structures occur in a gravity fold belt that may be present along the entire Alaska and Canada margins of the Canada Basin. Source-rock data inboard of the rift shoulders and regional palaeogeographic reconstructions suggest three potential source-rock intervals: Lower Cretaceous (Hauterivian–Albian), Upper Cretaceous (mostly Turonian) and Lower Palaeogene. Burial history modelling indicates favourable timing for generation from all three intervals beneath the Alaska and Canada passive margins, and an active petroleum system has been documented in the Canning–Mackenzie deformed margin. Assessment of undiscovered petroleum resources indicates the greatest potential in the Canning–Mackenzie deformed margin and significant potential in the Canada and Alaska passive margins.

Canada Basin↗

Regional magnetic domains of the Circum-Arctic: A framework for geodynamic interpretation

We identify and discuss 57 magnetic anomaly pattern domains spanning the Circum-Arctic. The domains are based on analysis of a new Circum-Arctic data compilation. The magnetic anomaly patterns can be broadly related to general geodynamic classification of the crust into stable, deformed (magnetic and nonmagnetic), deep magnetic high, oceanic and large igneous province domains. We compare the magnetic domains with topography/bathymetry, regional geology, regional free air gravity anomalies and estimates of the relative magnetic ‘thickness’ of the crust. Most of the domains and their geodynamic classification assignments are consistent with their topographic/bathymetric and geological expression. A few of the domains are potentially controversial. For example, the extent of the Iceland Faroe large igneous province as identified by magnetic anomalies may disagree with other definitions for this feature. Also the lack of definitive magnetic expression of oceanic crust in Baffin Bay, the Norwegian–Greenland Sea and the Amerasian Basin is at odds with some previous interpretations. The magnetic domains and their boundaries provide clues for tectonic models and boundaries within this poorly understood portion of the globe.

Geological Society Memoir↗

Geology and petroleum potential of the West Greenland-East Canada Province

The US Geological Survey (USGS) assessed the potential for undiscovered oil and gas resources of the West Greenland–East Canada Province as part of the USGS Circum-Arctic Resource Appraisal programme. The province lies in the offshore area between western Greenland and eastern Canada and includes Baffin Bay, Davis Strait, Lancaster Sound and Nares Strait west of and including part of Kane Basin. A series of major tectonic events led to the formation of several distinct structural domains that are the geological basis for defining five assessment units (AU) in the province, all of which are within the Mesozoic–Cenozoic Composite Petroleum System. Potential petroleum source rocks include strata of Ordovician, Lower and Upper Cretaceous, and Palaeogene ages. The five AUs defined for this study – the Eurekan Structures AU, NW Greenland Rifted Margin AU, NE Canada Rifted Margin AU, Baffin Bay Basin AU and the Greater Ungava Fault Zone AU – encompass the entire province and were assessed for undiscovered technically recoverable resources. The mean volumes of undiscovered resources for the West Greenland–East Canada Province are 10.7×10 9 barrels of oil, 75×10 12 cubic feet of gas, and 1.7×10 9 barrels of natural gas liquids. For the part of the province that is north of the Arctic Circle, the estimated mean volumes of these undiscovered resources are 7.3×10 9 barrels of oil, 52×10 12 cubic feet of natural gas, and 1.1×10 9 barrels of natural gas liquids.

Geological Society Memoir↗

Assessment of NE Greenland: Prototype for development of Circum-ArcticResource Appraisal methodology

Geological features of NE Greenland suggest large petroleum potential, as well as high uncertainty and risk. The area was the prototype for development of methodology used in the US Geological Survey (USGS) Circum-Arctic Resource Appraisal (CARA), and was the first area evaluated. In collaboration with the Geological Survey of Denmark and Greenland (GEUS), eight ‘assessment units’ (AU) were defined, six of which were probabilistically assessed. The most prospective areas are offshore in the Danmarkshavn Basin. This study supersedes a previous USGS assessment, from which it differs in several important respects: oil estimates are reduced and natural gas estimates are increased to reflect revised understanding of offshore geology. Despite the reduced estimates, the CARA indicates that NE Greenland may be an important future petroleum province.

Geological Society Memoir↗

Geology and petroleum potential of the Lincoln Sea Basin, offshore North Greenland

A seismic refraction line crossing the Lincoln Sea was acquired in 2006. It proves the existence of a deep sedimentary basin underlying the Lincoln Sea. This basin appears to be comparable in width and depth to the Sverdrup Basin of the Canadian Arctic Islands. The stratigraphy of the Lincoln Sea Basin is modelled in analogy to the Sverdrup Basin and the Central Spitsbergen Basin, two basins between which the Lincoln Sea intervened before the onset of seafloor spreading in the Eurasian Basin. The refraction data indicates that the Lincoln Sea Basin is capped by a kilometre-thick, low-velocity layer, which is taken to indicate an uplift history similar to, or even more favourable than, the fairway part of the Sverdrup Basin. Tectonic activity in the Palaeogene is likely to constitute the major basin scale risk. We conclude that the Lincoln Sea Basin is likely to be petroliferous and contains risked resources on the order of 1×10 9 barrels of oil, to which comes an equivalent amount of (associated and nonassociated) gas.

Geological Society Memoir↗

Geology and petroleum potential of the Eurasia Basin

The Eurasia Basin petroleum province comprises the younger, eastern half of the Arctic Ocean, including the Cenozoic Eurasia Basin and the outboard part of the continental margin of northern Europe. For the USGS petroleum assessment (CARA), it was divided into four assessment units (AUs): the Lena Prodelta AU, consisting of the deep-marine part of the Lena Delta; the Nansen Basin Margin AU, comprising the passive margin sequence of the Eurasian plate; and the Amundsen Basin and Nansen Basin AUs which encompass the abyssal plains north and south of the Gakkel Ridge spreading centre, respectively. The primary petroleum system thought to be present is sourced in c . 50–44 Ma (Early to Middle Eocene) condensed pelagic deposits that could be widespread in the province. Mean estimates of undiscovered, technically recoverable petroleum resources include <1 billion barrels of oil (BBO) and about 1.4 trillion cubic feet (TCF) of nonassociated gas in Lena Prodelta AU, and <0.4 BBO and 3.4 TCF nonassociated gas in the Nansen Basin Margin AU. The Nansen Basin and Amundsen Basin AUs were not quantitatively assessed because they have less than 10% probability of containing at least one accumulation of 50 MMBOE (million barrels of oil equivalent).

Book chapter↗

A first look at the petroleum geology of the Lomonosov Ridge microcontinent, Arctic Ocean

The Lomonosov microcontinent is an elongated continental fragment that transects the Arctic Ocean between North America and Siberia via the North Pole. Although it lies beneath polar pack ice, the geological framework of the microcontinent is inferred from sparse seismic reflection data, a few cores, potential field data and the geology of its conjugate margin in the Barents–Kara Shelf. Petroleum systems inferred to be potentially active are comparable to those sourced by condensed Triassic and Jurassic marine shale of the Barents Platform and by condensed Jurassic and (or) Cretaceous shale probably present in the adjacent Amerasia Basin. Cenozoic deposits are known to contain rich petroleum source rocks but are too thermally immature to have generated petroleum. For the 2008 USGS Circum Arctic Resource Appraisal (CARA), the microcontinent was divided into shelf and slope assessment units (AUs) at the tectonic hinge line along the Amerasia Basin margin. A low to moderate probability of accumulation in the slope AU yielded fully risked mean estimates of 123 MMBO oil and 740 BCF gas. For the shelf AU, no quantitative assessment was made because the probability of petroleum accumulations of the 50 MMBOE minimum size was estimated to be less than 10% owing to rift-related uplift, erosion and faulting.

Geological Society Memoir↗

US geological survey Circum-Arctic Resource Appraisal (CARA): Introduction and summary of organization and methods

The USGS has assessed undiscovered petroleum resources in the Arctic through geological mapping, basin analysis and quantitative assessment. The new map compilation provided the base from which geologists subdivided the Arctic for burial history modelling and quantitative assessment. The CARA was a probabilistic, geologically based study that used existing USGS methodology, modified somewhat for the circumstances of the Arctic. The assessment relied heavily on analogue modelling, with numerical input as lognormal distributions of sizes and numbers of undiscovered accumulations. Probabilistic results for individual assessment units were statistically aggregated taking geological dependencies into account. Fourteen papers in this Geological Society volume present summaries of various aspects of the CARA.

Geological Society Memoir↗