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Electrical properties of methane hydrate + sediment mixtures

As part of our DOE-funded proposal to characterize gas hydrate in the Gulf of Mexico using marine electromagnetic methods, a collaboration between SIO, LLNL, and USGS with the goal of measuring the electrical properties of lab-created methane (CH 4 ) hydrate and sediment mixtures was formed. We examined samples with known characteristics to better relate electrical properties measured in the field to specific gas hydrate concentration and distribution patterns. Here we discuss first-ever electrical conductivity (σ) measurements on unmixed CH 4 hydrate (Du Frane et al., 2011): 6 x 10-5 S/m at 5 °C, which is ~5 orders of magnitude lower than seawater. This difference allows electromagnetic (EM) techniques to distinguish highly resistive gas hydrate deposits from conductive water saturated sediments in EM field surveys. More recently, we performed measurements on CH 4 hydrate mixed with sediment and we also discuss those initial findings here. Our results on samples free of liquid water are important for predicting conductivity of sediments with pores highly saturated with gas hydrate, and are an essential starting point for comprehensive mixing models.

Fire in the Ice: NETL Methane Hydrate Newsletter

Possible deep-water gas hydrate accumulations in the Bering Sea

Seismic reflection images from the deep-water Aleutian and Bowers Basins of the Bering Sea contain many hundreds of acoustic Velocity-AMPlitude (VAMP) anomalies, each of which may represent a large accumulation of natural gas hydrate. Against a backdrop of essentially horizontal sedimentary reflections, the VAMP anomalies stand out as both high-amplitude bright spots and zones of vertically aligned horizon distortions. The VAMPs are interpreted as natural gas chimneys overlain by concentrated hydrate caps.

Fire in the Ice: NETL Methane Hydrate Newsletter

Gas-hydrate-bearing sand reservoir systems in the offshore of India: Results of the India National Gas Hydrate Program Expedition 02

The India National Gas Hydrate Program Expedition 02 (NGHP-02) was conducted from 3-March-2015 to 28-July-2015 off the eastern coast of India using the deepwater drilling vessel Chikyu . The primary goal of this expedition was to explore for highly saturated gas hydrate occurrences in sand reservoirs that would become targets for future production tests. The first two months of the expedition were dedicated to logging-whiledrilling (LWD) operations, with a total of 25 holes drilled and logged. The next three months were dedicated to coring operations at 10 of the most promising sites. With a total of five months of continuous field operations, the expedition was the most comprehensive dedicated gas hydrate investigation ever undertaken.

Krishna-Godavari Basin, Mahanadi Basin

Permafrost gas hydrates and climate change: Lake-based seep studies on the Alaskan north slope

The potential interactions between climate change and methane hydrate destabilization are among the most societally-relevant aspects of gas hydrates research. Massive dissociation of deep marine methane hydrates following rapid Earth warming is the most plausible explanation for carbon isotopic data that imply widespread release of microbial methane during the Late Paleocene Thermal Maximum (~55 million years ago), and massive methane hydrate degradation may have been associated with a major warming event in the Late Neoproterozoic as well. . On contemporary Earth, circumstantial evidence implies that permafrost-associated methane hydrate dissociation, possibly related to climate change, may be contributing to gas seeps in the MacKenzie Delta (Dallimore et al., 2008). Gas is also currently being released from shallow subseafloor hydrates in some areas, and transient bottom water temperature increases are sometimes known to be the destabilizing influence for these gas hydrates. Still, there is no direct evidence that gas hydrates are currently undergoing significant and systematic destabilization on contemporary Earth, that climate processes are responsible for driving any destabilization that may be occurring, or that methane released from dissociating hydrate is a substantial contributor to atmospheric methane concentrations.

Alaska

Application of RHIZON samplers to obtain high-resolution pore-fluid records during geochemical investigations of gas hydrate systems

Obtaining accurate, high-resolution profiles of pore fluid constituents is critical for characterizing the subsurface geochemistry of hydrate-bearing sediments. Tightly-constrained downcore profiles provide clues about fluid sources, fluid flow, and the milieu of chemical and diagenetic reactions, all of which are used to interpret where and why gas and gas hydrate occur in the natural environment. Because a profile’s quality is only as good as the samples from which the data are obtained, a great deal of effort has been exerted to develop extraction systems suited to various sedimentary regimes. Pore water from deeply buried sediment recovered by scientific drilling is typically squeezed with a hydraulic press (Manheim, 1966); whereas pore water in near-surface, less consolidated sediment is more efficiently pushed from the sediment using compressed gas (Reeburgh, 1967) or centrifugation.

Fire in the Ice: NETL Methane Hydrate Newsletter

Gas hydrate potential of the mid Atlantic outer continental shelf

For the last two years, the Minerals Management Service (MMS) has been studying the resource potential of gas hydrates in federal offshore lands of the Outer Continental Shelf (OCS) off the Atlantic, Gulf of Mexico, Pacific, and Alaska in collaboration with the U.S. Geological Survey (USGS), the Department of Energy (DOE), the National Oceanic and Atmospheric Administration (NOAA), the Naval Research Lab (NRL) and academia. Utilizing its extensive seismic, well, and geochemical databases, the MMS will be reporting the in-place resource numbers within the next few months. Though the methodology of the study was not prospect oriented, discrete prospects have been recognized.

Fire in the Ice: NETL Methane Hydrate Newsletter

Investigating gas hydrate as a factor in accretionary margin frontal ridge slope failures and cold seep biogeochemistry

During August 2008, a research expedition (2008-007-PGC) was carried out offshore Vancouver Island on the northern Cascadia Margin (Figure 1) to study the role of gas hydrate in slope stability and cold seep biogeochemistry. The cruise was organized by the Geological Survey of Canada (GSC) as part of the Earth Science Sector, Natural Gas Hydrate Program, Natural Resources Canada (NRCan). This international collaboration included McGill University, University of Victoria, the U.S. Geological Survey, Florida State University, and the U.S. Department of Energy.

Fire in the Ice: NETL Methane Hydrate Newsletter

Workshop summary: Physical properties of gas hydrate-bearing sediment

A wide range of particle and pore scale phenomena, often coupled, determines the macro-scale response of gas-hydrate bearing sediment to changes in mechanical, thermal, or chemical conditions. Predicting this macro-scale response is critical for applications such as optimizing the production of methane from gas-hydrate deposits, or determining the role of gas hydrates in global carbon cycling and climate change.

Fire in the Ice: NETL Methane Hydrate Newsletter

Physical property studies in the USGS GHASTLI Laboratory

One of the many challenges in studying methane hydrate is that it is unstable at typical surface pressure and temperature conditions. To enable methane hydrates and hydrate-bearing sediments to be formed, analyzed, and experimented with, the National Energy Technology Laboratory (NETL), and the U.S. Geological Survey (USGS) in Woods Hole, MA collaborated in the development of the Gas Hydrate And Sediment Test Laboratory Instrument (GHASTLI). Over the past decade, the USGS has been operating GHASTLI and collaborating in the development of new sample handling tools and procedures, in an effort to improve our ability to analyze methane hydrate in the lab. These tools will enable hydrate researchers to more confidently link field studies (for example geophysics or drilling) with theoretical and predictive studies, leading to a better understanding of the geological conditions and processes that control the growth and concentration of natural gas hydrates, how hydrates affect the properties of the host sediments, and how the hydrate-sediment system changes when hydrate dissociates and releases the previously bound gas. To date, GHASTLI has been used to measure natural samples from ODP Leg 164 (Blake Ridge off the U.S. southeast Atlantic margin), Leg 204 (Hydrate Ridge off the Pacific Northwest margin) and the Mallik well (Mackenzie Delta in northwestern Canada). Additional samples in the queue for analysis are from the Chevron Joint Industry Project Experiment in the Gulf of Mexico and most recently, from IODP Leg 311 off Vancouver Island. Several foreign nations have asked whether GHASTLI will be available to analyze samples that might be recovered during national drilling programs. The ability to perform lab testing of hydrates within sediments is one of the unique capabilities of GHASTLI that separates it from other simulators at NETL and elsewhere.

Fire in the Ice: NETL Methane Hydrate Newsletter

USGS leads United States effort in Mallik Well

This winter, in the extremely cold, far reaches of the upper Northwest Territory of Canada, there is an international consortium of researchers participating in a program to study methane hydrates. The researchers are currently drilling a 1200 m-deep production research well through the permafrost. It is one of three wells located in the Mackenzie Delta, on the shore of the Beaufort Sea. Two observation wells were drilled adjacent to the main production test well earlier this year. Research objectives for the program focus on two themes: (1) the assessment of the production and properties of gas hydrates, and (2) an assessment of the stability of continental gas hydrates given warming trends predicted by climate change models. Of particular interest is the physical response of the gas hydrate to depressurization and thermal production stimulation. Cores are being taken from the well, and scientists hope to retrieve at least 200 m of core, including all the gas hydrate-rich intervals. Once cored, the samples are transported 200 kilometers over ice roads to Inuvik. Nearly 60 researchers are examining the cores for everything from geophysical parameters to microbiological analyses.

Fire in the Ice: NETL Methane Hydrate Newsletter

Viable long-term gas hydrate testing site confirmed on the Alaska north slope

In December 2018, data acquired in a Stratigraphic Test Well drilled from the 7-11-12 pad in the western part of the Prudhoe Bay Unit, Alaska North Slope confirmed the occurrence of two high-quality reservoirs fully saturated with gas hydrate. The drilling was the initial phase of a planned, three-well program designed to conduct an extended duration test of the response to gas hydrate reservoirs to controlled depressurization. The Stratigraphic Test Well (formally “PBU Hydrate-01”) was operated by the PBU Operator BP Exploration, (Alaska), Inc. (BPXA) using the Parker 272 drilling rig (Figure 1) through a Drilling Services Agreement executed with Petrotechnical Resources of Alaska (PRA) in association with a contract between NETL and PRA. The science program executed by BPXA was developed over a two-year period through extensive discussions and scientific evaluation undertaken by NETL, the Japan, Oil, Gas, and Metals, National Corporation (JOGMEC), the U.S. Geological Survey (USGS), and PRA. The effort also benefitted greatly from the support of the Alaska Department of Natural Resources (ADNR) and the PBU Working Interest Owners (WIOs).

Alaska