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At least 19 recordsLinked to original sources

Riverine pesticide trends in the United States: Assessing a decade of national-scale monitoring

Pesticides in freshwater systems can compromise water availability by degrading water quality, with implications for human health and aquatic life. Despite recognition of the need for national-scale monitoring and analysis, few studies have documented long-term trends in surface water pesticide contamination across the US. This study addresses that need by analyzing temporal trends and acute and chronic benchmark exceedances for aquatic life and human health from 81 river sites sampled from 2013 to 2022 using an analytical method targeting 80 pesticides. The majority (79%) of single site and pesticide combinations had too few pesticide detections to estimate trends. When detections were more frequent, increasing trends in concentration were twice as common as decreasing trends. Increasing pesticide concentrations were common in primary drainages of the Mississippi River Basin. Aquatic life benchmarks were exceeded by 19 pesticides, and exceedances were geographically widespread, with both acute and chronic aquatic life benchmark exceedances at 62% of sites. The herbicides atrazine and metolachlor and the insecticide imidacloprid were identified as the greatest threats to surface water availability based on their trends and aquatic life benchmark exceedances. These findings demonstrate the need for continued monitoring and trend analysis, driver investigation, and management strategies to protect freshwater resources.

conterminous United States

Hydrous heating experiments at 130°C yield insights into the occurrence of hydrogen sulfide and light alkanes in natural gas reservoirs

Improved understanding of the origin of produced volatiles from conventional reservoirs and unconventional source rocks is critical for petroleum exploration and production. A series of hydrous heating experiments using two immature Type II siliciclastic source rocks, Pennsylvanian Turner Mine shale (TMS) and Devonian New Albany Shale (NAS), at 130 °C over one to two years were conducted to assess gas generation at low temperature. Elemental sulfur (ES) was added to the NAS samples to evaluate the role of sulfur on thermochemical sulfate reduction (TSR). The produced volatile composition was investigated in situ using Raman spectroscopy at the end of the heating experiments. Results show that the two source rocks yield different types and concentrations of volatiles. Only CH 4 and CO 2 were detected following hydrous heating of the TMS source rock in contrast to CH 4 , C 2 H 6 , C 3 H 8 , and CO 2 which were observed in experiments using NAS. Variations in the produced volatiles are likely the result of compositional differences within the respective source rock organic matter. Experiments involving ES show strong H 2 S signals that are likely due to the formation of H 2 S from the reaction of ES with water at 130 °C. H 2 S signals correlate with a greater relative concentration of CH 4 and CO 2 compared to experiments where ES was not added, on a time-normalized basis. The correlation between the presence of H 2 S and an increase in CH 4 and CO 2 concentration could indicate the occurrence of TSR. Here we propose that H 2 S in siliciclastic shale can be generated in the presence of ES at low temperatures via both disproportionation of ES into H 2 S and SO 4 2– , and TSR. Our findings from this study provide experimental evidence that may aid efforts to interpret the origin of H 2 S in low-temperature sedimentary basins.

Pennsylvania

Detection of viral, bacterial, and protozoan pathogens and microbial source tracking markers in paired large- and small-volume water samples

When sampling for waterborne microbes, researchers may need to diverge from recommended sample volumes due to logistical constraints, novel targets, or challenging matrices, with little guidance about the potential impact on results. In field studies, we measured bacteria, viruses, and protozoa (15 quantitative polymerase chain reaction assays) in paired large- and small-volume samples to evaluate method performance and relevant factors. Concordance between methods was low. Large-volume ultrafiltration yielded more detections than small-volume sampling, especially for pathogens in groundwater. Greater microbial concentrations were associated with more frequent detections in small-volume samples and greater concordance between paired samples. Large-volume samples appeared to be more susceptible to diminished sensitivity from complex sample matrices. In laboratory studies, recovery of microbes was poorer for large- than small-volume methods, although large-volume methods more reliably detected low-concentration targets. Large-volume samples were less stable than small-volume samples during storage. Overall, large-volume sampling was superior for detecting pathogens but may underestimate concentrations; small-volume sampling was more prone to false negatives but was adequate when concentrations were relatively high, like we observed for microbial source tracking in surface waters.

Wisconsin

Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment

Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.

ACS ES&T Water

Comparative screening of private, public, and bottled drinking water in vitro bioactivity

This study compares in vitro bioactivity profiles of extracts from private tapwater (51 samples), public tapwater (143 samples), and bottled water (31 samples), using high-throughput, multiplex, transcription factor screening. Of 48 biological end points tested, 25 showed significant (≥50% above the field blank) activity. Frequently detected (≥10% of samples) bioactivities (in decreasing order) included xenobiotic metabolism (pregnane X receptor [ PXR ], aryl hydrocarbon receptor [ AhR ]), antioxidant response (antioxidant response element-binding nuclear factor erythroid 2-related factor 2 [ NRF2 ], activator protein 1 [ AP-1 ]), endocrine signaling (estrogen receptor [ ER ], peroxisome proliferator-activated receptor [ PPAR ]), and metals response (metals response element [ MRE ]). Significant bioactivities were observed across all drinking water supplies, with some statistical differences identified. Bioactivities were moderately to strongly correlated with several individual exposure and corresponding benchmark- or activity-weighted metrics, particularly for disinfection byproducts. Significant (α = 0.05) but weak correlations between measured bioactivity resemblance patterns and those of the inorganic–organic exposure, toxicity-quotient (TQ), and exposure-activity-ratio (EAR) resemblance matrices suggest that key drivers of observed drinking water bioactivity were not captured by the extensive, targeted exposure assessment. Results highlight the need for effects-based monitoring combined with improved exposure analysis to better assess health risks from low-level contaminant mixtures in drinking water.

ES&T Water

Naegleria fowleri detected in Grand Teton National Park hot springs

The free-living thermophilic amoeba Naegleria fowleri ( N. fowleri ) causes the highly fatal disease primary amoebic meningoencephalitis. The environmental conditions that are favorable to the growth and proliferation of N. fowleri are not well-defined, especially in northern regions of the United States. In this study, we used culture-based methods and multiple molecular approaches to detect and analyze N. fowleri and other Naegleria spp. in water, sediment, and biofilm samples from five hot spring sites in Grand Teton National Park, Wyoming, U.S.A. These results provide the first detections of N. fowleri in Grand Teton National Park and provide new insights into the distribution of pathogenic N. fowleri and other nonpathogenic Naegleria spp. in natural thermal water systems in northern latitudes.

Wyoming

Detection of Naegleria fowleri in thermally impacted recreational waters of western United States national parks

Naegleria fowleri is a thermophilic free-living amoeba (FLA) and the causative agent of primary amoebic meningoencephalitis, posing public health risks in warm freshwater environments. This multiyear, multiagency study surveyed 40 thermally impacted recreational waters across five western United States national parks and recreation areas–Yellowstone National Park, Grand Teton National Park, Olympic National Park, Newberry National Volcanic Monument, and Lake Mead National Recreation Area–to assess N. fowleri presence, concentration, and associated environmental conditions. A total of 185 water samples were analyzed by qPCR and Sanger sequencing, revealing widespread detection of N. fowleri in 34% of samples with positive detections from Lake Mead, Yellowstone, and Grand Teton hot springs and thermally impacted waters, with concentrations ranging from 4.9 to 115.7 cells/L. Multiple codetections of N. fowleri with nonpathogenic species including Naegleria australiensis were identified, suggesting they may inhabit similar ecological niches in the natural systems in contrast to engineered systems. These findings indicate that N. fowleri is present in thermally impacted areas across the western United States and underscore the use of enhanced monitoring, public awareness, and risk management strategies in thermally influenced recreational waters.

Arizona, Nevada, Oregon, Washington, Wyoming

Concentration dependency of PFOS bioaccumulation by freshwater benthic algae

Although perfluorooctanesulfonic acid (PFOS) has been voluntarily phased out, it remains the most abundant and frequently detected PFAS compound in biota worldwide. A deeper understanding of how PFOS enters the aquatic food web at the energetic base is needed to better characterize and predict the general patterns of PFAS trophic transfer. Research on bioaccumulation by primary producers remains limited. Because diatoms (Bacillariophyta) are often dominant constituents of aquatic biofilms, we exposed freshwater benthic diatoms ( Mayamaea atomus ) to a range of PFOS concentrations (0.01–100 μg/L) for 7 days in a controlled laboratory experiment to investigate PFAS bioaccumulation patterns. We quantified PFOS in water and algal matrices using liquid chromatography-tandem mass spectrometry and calculated bioconcentration factors (BCFs). Log PFOS concentrations in diatoms increased linearly with log 10 exposure concentration, corresponding to a sublinear relationship in arithmetic space. Consequently, BCF values decreased, from 4,831 to 174 L/kg, with increasing PFOS exposure, indicating concentration-dependent bioaccumulation consistent with higher-order organisms (e.g., Crustacea, Mollusca, Chordata). This pattern complicates the use of BCF for predictive purposes and may lead to mis-estimations of risk. Even as PFOS declines in the environment, algae will likely continue to accumulate and transfer PFOS and other PFAS to higher trophic levels.

ACS ES&T Water

Metal release from manganese nodules in anoxic seawater and implications for deep-sea mining dewatering operations

The potential mining of deep-sea polymetallic nodules has been gaining increasing attention due to their enrichment in metals essential for a low-carbon future. To date, there have been few scientific studies concerning the geochemical consequences of dewatered mining waste discharge into the pelagic water column, which can inform best practices in future mining operations. Here, we report the results of laboratory incubation experiments that simulate mining discharge into anoxic waters such as those that overlie potential mining sites in the North Pacific Ocean. We find that manganese nodules are reductively dissolved, with an apparent activation energy of 42.8 kJ mol –1 , leading to the release of associated metals in the order manganese > nickel > copper > cobalt > cadmium > lead. The composition of trace metals released during the incubation allows us to estimate a likely trace metal budget from the simulated dewatering waste plume. These estimates suggest that released cobalt and copper are the most enriched trace metals within the plume, up to ∼15 times more elevated than the background seawater. High copper concentrations can be toxic to marine organisms. Future work on metal toxicity to mesopelagic communities could help us better understand the ecological effects of these fluxes of trace metals.

ACS ES&T Water

Predictive modeling reveals elevated conductivity relative to background levels in freshwater tributaries within the Chesapeake Bay watershed, USA

Elevated conductivity (i.e., specific conductance or SC) causes osmotic stress in freshwater aquatic organisms and may increase the toxicity of some contaminants. Indices of benthic macroinvertebrate integrity have declined in urban areas across the Chesapeake Bay watershed (CBW), and more information is needed about whether these declines may be due to elevated conductivity. A predictive SC model for the CBW was developed using monitoring data from the National Water Quality Portal. Predictor variables representing SC sources were compiled for nontidal reaches across the CBW. Random forests modeling was conducted to predict SC at four time periods (1999–2001, 2004–2006, 2009–2011, and 2014–2016), which were then compared to a national data set of background SC to quantify departures from background SC. Carbonate geology, impervious cover, forest cover, and snow depth were the most important variables for predicting SC. Observations and modeled results showed snow depth amplified the effect of impervious cover on SC. Elevated SC was predicted in two-thirds of reaches in the CBW, and these elevated conditions persisted over time in many areas. These results can be used in stressor identification assessments to prioritize future monitoring and to determine where management activities could be implemented to reduce salinization.

Chesapeake Bay watershed

Methylmercury stable isotopes: New insights on assessing aquatic food web bioaccumulation in legacy impacted regions

Through stable isotope measurements of total mercury (HgT), identification of crucial processes and transformations affecting different sources of mercury (Hg) has become possible. However, attempting to use HgT stable isotopes to track bioaccumulation of Hg sources among different food web compartments can be challenging, if not impossible, when tissues have varying methylmercury (MeHg) contents. We measured HgT and MeHg stable isotope ratios within the lower Fox River to examine how these values differed across the food web and if isotope values in biota were influenced by legacy contamination. We showed that seston, invertebrates, and fish had a large range of δ 202 HgT (−0.74 to 0.15 ‰, n = 11) due to varying MeHg contents in tissues but a commonly conserved MeHg isotope value (δ 202 MeHg ave = 0.01 ± 0.12 ‰, 1 standard deviation, n = 11). We also examined some mathematical approaches to estimate the MeHg isotope values, which were mostly comparable to measured MeHg isotope values in the Fox River, with some exceptions. In this study, we observed that the MeHg isotope values can elucidate links between different food web compartments and provide insight on aquatic Hg cycling that can be masked by the sole use of HgT isotopes in contaminated sites.

Wisconsin

Rapid implementation of high-frequency wastewater surveillance of SARS-CoV-2

There have been over 507 million cases of COVID-19, the disease caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), resulting in 6 million deaths globally. Wastewater surveillance has emerged as a valuable tool in understanding SARS-CoV-2 burden in communities. The National Wastewater Surveillance System (NWSS) partnered with the United States Geological Survey (USGS) to implement a high-frequency sampling program. This report describes basic surveillance and sampling statistics as well as a comparison of SARS-CoV-2 trends between high-frequency sampling 3–5 times per week, referred to as USGS samples, and routine sampling 1–2 times per week, referred to as NWSS samples. USGS samples provided a more nuanced impression of the changes in wastewater trends, which could be important in emergency response situations. Despite the rapid implementation time frame, USGS samples had similar data quality and testing turnaround times as NWSS samples. Ensuring there is a reliable sample collection and testing plan before an emergency arises will aid in the rapid implementation of a high-frequency sampling approach. High-frequency sampling requires a constant flow of information and supplies throughout sample collection, testing, analysis, and data sharing. High-frequency sampling may be a useful approach for increased resolution of disease trends in emergency response.

ES&T: Water

A universal method for the simultaneous determination of environmental pollutants in marine biological samples: Per- and polyfluoroalkyl substances and antibiotics as a case study

Conventional detection technologies for environmental contaminants have primarily focused on providing accurate qualitative and quantitative evaluations for single pollutant types, leading to increased costs and an inability to satisfy the growing demand for detecting a broader spectrum of pollutants. Here, we introduced a novel analytical method to simultaneously measure the concentration levels of diverse environmental pollutants, characterized by their distinct properties, across complex biological samples. Per- and polyfluoroalkyl substances (PFAS) and antibiotics were used as a case study due to their frequency of detection in the environment and known impacts Our method harnesses the salting-out effect of sodium chloride on proteins within the muscle tissues of 178 marine species, which significantly reduces the addition of extraneous substances, mitigates matrix interference, and avoids reliance on solid-phase extraction or dispersive extraction agents. The method provides a simultaneous pretreatment for the detection of several compounds, with detection limits from 0.002 to 0.41 ng/g dry weight, which are substantially lower than conventional methods. Overall, this method streamlines efficiency, decreases costs, lessens matrix effects, and sets a solid groundwork for future applications in the concurrent detection of a broader spectrum of environmentally pertinent pollutants with varied characteristics.

ACS ES&T Water

Toward ecosystem accounts for Rwanda: Tracking 25 years of change in potential supply and flows of ecosystem services

1. Rwanda, a small but rapidly developing central African nation, has undertaken development of natural capital accounts to better inform its economic development through the World Bank’s Wealth Accounting and Valuation of Ecosystem Services (WAVES) Partnership. In this paper, we develop ecosystem service (ES) models to quantify the physical supply components of ecosystem accounts in Rwanda from 1990 to 2015. 2. We applied the InVEST carbon storage, sediment delivery ratio, and annual and seasonal water yield models to map changes in potential ES supply nationwide. We also quantified flows of sediment and water to 96 hydroelectric dam, irrigation dam, and water treatment plant sites. 3. Over a 25-year period, we found declines in all ES, which were most strongly driven by conversion of forests to cropland. Declines were most pronounced from 1990 to 2000 and 2010 to 2015; ES were relatively stable from 2000 to 2010. From 2010 to 2015, over 42% of Rwanda’s water-use sites (representing 17% of the nation’s hydroelectric generation capacity and 69% of its water treatment capacity) had increases in sediment export and quick flow greater than the national average. 4. Our results quantify nationwide ES trends, their implications for key water-dependent industries, and the importance of protected areas in safeguarding ES potential supply and flows in Rwanda. They also provide data that can be integrated with existing land, water, and economic accounts for Rwanda, as well as a baseline to inform development strategies that better link economic and environmental goals.

People and Nature

Hydrogeology, ground-water quality, and source of ground water causing water-quality changes in the Davis well field at Memphis, Tennessee

An investigation was conducted by the U.S. Geological Survey from 1992 to 1994 to collect and interpret hydrogeologic and water-quality data to determine the source of ground water causing water-quality changes in water from wells screened in the Memphis aquifer in the Davis well field at Memphis, Tennessee. Water-quality changes in aquifers used for water supply are of concern because these changes can indicate a potential for contamination of the aquifers by downward leakage from near-surface sources. The water-quality changes at the Davis well field were detected by Memphis Light, Gas and Water Division, which has periodically sampled and analyzed water from many of the 14 production wells since the well field began operation in 1971. Memphis Light, Gas and Water Division analyzed the water samples primarily for hardness, alkalinity, chloride, ulfate, and iron. Results of the e analy es and results of more recent (1992) analyse of water samples by the U.S. Geological Survey indicate that the quality of water from eight of the production wells has changed since the well field began operation. For example, from 1972 to 1991, hardness of water from one well has increased from 90 to 292 milligrams per liter (224 percent). The confining unit, which separates the fluvial deposits aquifer from the Memphis aquifer in the area of the well field, is relatively thick and contains many clay layers. However, a test hole drilled for one of five shallow wells installed in the alluvial aquifer in the Mississippi Alluvial Plain just west of the well field indicated that the confining unit separating the alluvial aquifer from the Memphis aquifer locally is absent. Differences in hydrauLic head between the alluvial and fluvial deposits aquifers and the Memphis aquifer favor downward leakage of ground water. Thus, the absence of the confining unit beneath the Mississippi Alluvial Plain just west of the well field provides a direct pathway for water in the alluvial aquifer to enter the Memphis aquifer. Comparison of selected water-quality properties and major inorganic and trace element constituent concentrations in samples from the alluvial, fluvial deposits, and Memphis aquifers indicates that the source of ground water causing waterquality changes at the Davis well field is the alluvial aquifer west of the well field . The presence of tritium and chlorofluorocarbons in water from wells screened in the Memphis aquifer in the western part of the well field indicates that relatively young (post-1940) water from the alluvial aquifer has entered the Memphis aquifer. NETPATH geochemical model code was used to mix waters from the alluvial aquifer with water from the Memphis aquifer using chloride as a conservative tracer. The resulting models indicated that a mixture containing 3 percent alluvial aquifer water mixed with 97 percent unaffected Memphis aquifer water would produce the chloride concentration measured in water from the Memphis aquifer well most affected by water-quality changes. NETPATH also was used to calculate mixing percentages of alluvial and Memphis aquifer Abstract waters based on changes in the concentrations of selected dissolved major inorganic and trace element constituents that define the dominant reactions that occur during mixing. These models indicated that a mixture containing 18 percent alluvial aquifer water and 82 percent unaffected Memphis aquifer water would produce the major constituent and trace element concentrations measured in water from the Memphis aquifer well most affected by water-quality changes. However, these model simulations predicted higher dissolved methane concentrations than were measured in water samples from the Memphis aquifer wells.

Tennessee

Analysis of provisioning ecosystem services and perceptions of climate change for indigenous communities in the Western Himalayan Gurez Valley, Pakistan

Climate change is a significant threat to people living in mountainous regions. It is essential to understand how montane communities currently depend especially on the provisioning ecosystem services (ES) and the ways in which climate change will impact these services, so that people can develop relevant adaptation strategies. The ES in the Gurez Valley, in the Western Himalayas of Pakistan, provide a unique opportunity to explore these questions. This understudied area is increasingly exposed not only to climate change but also to the overexploitation of resources. Hence, this study aimed to (a) identify and value provisioning ES in the region; (b) delineate indigenous communities’ reliance on ES based on valuation; and (c) measure the perceptions of indigenous communities of the impact of climate change on the ES in Gurez Valley. Semi-structured interviews and focus group discussions were used to classify the provisioning ES by using the ‘Common International Classification on Ecosystem Services’ (CICES) table and applying the ‘Total Economic Valuation (TEV)’ Framework. Results indicate that the indigenous communities are highly dependent on ES, worth 6730 ± 520 USD/Household (HH)/yr, and perceive climate change as a looming threat to water, crops, and rearing livestock ESS in the Gurez Valley. The total economic value of the provisioning ES is 3.1 times higher than a household’s average income. Medicinal plant collection is a significant source of revenue in the Valley for some households, i.e., worth 766 ± 134.8 USD/HH/yr. The benefits of the sustainable use of ES and of climate change adaptation and mitigation, are culturally, economically, and ecologically substantial for the Western Himalayans.

Gurez Valley, Himalaya

Hydrologic, water operations, reservoir temperature, river temperature, sediment transport, habitat, and fish population modeling for the Trinity River Water Management Plan

Humboldt County is developing a Water Management Plan that will describe a range of proposed annual releases from Trinity Reservoir consistent with the 1959 water delivery contract between Humboldt County and the U.S. Bureau of Reclamation (Reclamation). The 1959 contract states that Reclamation shall release not less than an annual quantity of 50,000 acre-feet into the Trinity River for the beneficial use of Humboldt County and other downstream users (Contract Water). The Water Management Plan will outline how Contract Water should be released for the benefit of fisheries in the Trinity River and lower Klamath River, with the primary goal of expanding a harvestable surplus of Tribal, recreational, and commercial fisheries. A set of annual Contract Water release scenarios were developed during five workshops conducted in 2022 and 2023 with interested parties including Humboldt County, state and federal resource agencies, tribal representatives, Reclamation, and the U.S. Department of the Interior Solicitor’s office. A suite of modeling and technical tools was used to analyze annual conditions with and without Contract Water releases. This Modeling Report describes the modeling tools used to assess Contract Water release scenarios, including CalSim II, HEC-5Q, RBM10, sediment transport models, Chinook Salmon habitat models, and the Stream Salmonid Simulator. Results from all models are summarized to provide a comparative overview of modeled release scenarios to modeled baseline conditions. Mean annual Contract Water release scenarios ranged from 50,000 acre-feet to 170,000 acre-feet, and varied in timing, magnitude, and duration, though all releases were made between October and April. As shown in Table ES-1, a key finding of this modeling report is Contract Water releases that had the greatest modeled increase in Chinook Salmon abundance relative to baseline conditions included those that released 50,000 acre-feet in the fall period from October through December as pulse flows or baseflows, and those that released 170,000 acre-feet from October through April as a combination of pulse flows and baseflows. Modeled beneficial effects on populations were primarily due to either (1) increases in habitat area during the spawning life stage in October through December, which decreased redd superimposition (e.g., the process of a later arriving spawner building a redd on top of an existing redd) and improved egg survival, or (2) increases in flow during the fry emergence and juvenile rearing life stage in March through April, which increased the fry and parr carrying capacity (e.g., the upper limit for the number of fry or parr that a habitat unit can support) of individual habitat units. Another key finding of this report is all Contract Water scenarios that released at least 50,000 acre-feet annually from Trinity Reservoir had similar effects on Trinity Reservoir storage, Central Valley Project (CVP) storage, CVP contract water deliveries, and Sacramento River water temperatures. Whether these scenarios were released annually as a fall baseflow, fall pulse flow, spring pulse flow, or spring baseflow, they all resulted in similar storage patterns in Trinity Reservoir – an annual reduction in storage relative to the baseline that was relatively small in wetter years and larger in drier years. As a result of lower Trinity Storage levels, Trinity River Division (TRD) exports to the CVP were reduced. Because the timing of exports is similar each year, reaching a peak in July through September, the reduction to exports occurred at the same time each year, independent of Contract Water release timing, resulting in similar storage, CVP delivery, and water temperature effects in the Sacramento River basin portion of the CVP. The water temperature effects on the Sacramento River were limited to the months of July and August, relatively minor, and were primarily attributed to changes in storage, release magnitude, and release temperature from Lake Shasta, and not due explicitly to inflows from the TRD.

California

The sensitivity of ecosystem service models to choices of input data and spatial resolution

Although ecosystem service (ES) modeling has progressed rapidly in the last 10–15 years, comparative studies on data and model selection effects have become more common only recently. Such studies have drawn mixed conclusions about whether different data and model choices yield divergent results. In this study, we compared the results of different models to address these questions at national, provincial, and subwatershed scales in Rwanda. We compared results for carbon, water, and sediment as modeled using InVEST and WaSSI using (1) land cover data at 30 and 300 m resolution and (2) three different input land cover datasets. WaSSI and simpler InVEST models (carbon storage and annual water yield) were relatively insensitive to the choice of spatial resolution, but more complex InVEST models (seasonal water yield and sediment regulation) produced large differences when applied at differing resolution. Six out of nine ES metrics (InVEST annual and seasonal water yield and WaSSI) gave similar predictions for at least two different input land cover datasets. Despite differences in mean values when using different data sources and resolution, we found significant and highly correlated results when using Spearman's rank correlation, indicating consistent spatial patterns of high and low values. Our results confirm and extend conclusions of past studies, showing that in certain cases (e.g., simpler models and national-scale analyses), results can be robust to data and modeling choices. For more complex models, those with different output metrics, and subnational to site-based analyses in heterogeneous environments, data and model choices may strongly influence study findings.

Applied Geography