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Biomarker similarities between the saline lacustrine Eocene Green River and the Paleoproterozoic Barney Creek Formations

The Paleoproterozoic Barney Creek Formation, which is currently interpreted as a restricted, deep marine paleoenvironment, plays a disproportionate role in our understanding of Proterozoic ocean chemistry and the rise of complex life. The Barney Creek Formation hosts several unusual biomarker features, specifically its methylhopane and carotenoid signatures. Herein, we demonstrate that the saline lacustrine Eocene Green River Formation shares a similar distribution of methylhopanes and carotenoids, which is characteristic of saline lacustrine organic matter more generally. These distinct methylhopane and carotenoid patterns are not observed together in marine organic matter of any geologic age. These results imply a saline lacustrine depositional environment for the Barney Creek Formation, which agrees with earlier but now abandoned depositional models of this formation. As a result, models of Proterozoic ocean chemistry and emergence of complex life that rely on a marine Barney Creek Formation should be re-examined. Alternatively, if Paleoproterozoic marine biomarker signatures resemble those of younger saline lacustrine systems, then this must be recognized to accurately interpret geologic biomarker and paleoenvironmental records.

Colorado, Utah↗

Modelling the enigmatic Late Pliocene Glacial Event - Marine Isotope Stage M2

The Pliocene Epoch (5.2 to 2.58 Ma) has often been targeted to investigate the nature of warm climates. However, climate records for the Pliocene exhibit significant variability and show intervals that apparently experienced a cooler than modern climate. Marine Isotope Stage (MIS) M2 (~ 3.3 Ma) is a globally recognisable cooling event that disturbs an otherwise relatively (compared to present-day) warm background climate state. It remains unclear whether this event corresponds to significant ice sheet build-up in the Northern and Southern Hemisphere. Estimates of sea level for this interval vary, and range from modern values to estimates of 65 m sea level fall with respect to present day. Here we implement plausible M2 ice sheet configurations into a coupled atmosphere–ocean climate model to test the hypothesis that larger-than-modern ice sheet configurations may have existed at M2. Climate model results are compared with proxy climate data available for M2 to assess the plausibility of each ice sheet configuration. Whilst the outcomes of our data/model comparisons are not in all cases straight forward to interpret, there is little indication that results from model simulations in which significant ice masses have been prescribed in the Northern Hemisphere are incompatible with proxy data from the North Atlantic, Northeast Arctic Russia, North Africa and the Southern Ocean. Therefore, our model results do not preclude the possibility of the existence of larger ice masses during M2 in the Northern or Southern Hemisphere. Specifically they are not able to discount the possibility of significant ice masses in the Northern Hemisphere during the M2 event, consistent with a global sea-level fall of between 40 m and 60 m. This study highlights the general need for more focused and coordinated data generation in the future to improve the coverage and consistency in proxy records for M2, which will allow these and future M2 sensitivity tests to be interrogated further.

Global and Planetary Change↗

The Far-Field imprint of the late Paleozoic Ice Age, its demise, and the onset of a dust-house climate across the Eastern Shelf of the Midland Basin, Texas

The late Paleozoic is a period of pronounced climatic and tectonic change, characterized by the onset and disappearance of continental-scale glaciers across polar Gondwana, the formation of Pangea, and widespread large igneous province volcanism. The low-latitude equatorial tropics are assumed to be places of persistent warm and wet climatic conditions throughout the Phanerozoic, which through intense silicate weathering, exert a major influence on Earth’s climate via the consumption of atmospheric carbon through carbonic hydrolytic weathering, formation of clay minerals and deliverability of alkalinity to ocean basins. Here we investigate the late Paleozoic sedimentary record of the Eastern Shelf of the Midland Basin in order to refine the climatic and provenance record of this region. The Eastern Shelf of the Midland Basin was situated within the equatorial tropics throughout the late Paleozoic and was connected to the open ocean through a network of fluvial systems that drained into the marine Midland Basin. We present new U-Pb zircon geochronology (19 samples, 2591 analyses) and sedimentary petrography (11 samples, 5800 grain counts), which we integrate with previously published paleobotany, paleosol chemistry and clay mineralogy to provide a holistic climate and tectonic record from this region. We observe major changes in sedimentary processes that we attribute to the formation of Pangea, eustatic changes linked to a dynamic high-latitude glaciation and teleconnections with low latitude hydrology, and a long-term shift in the Earth climate system all of which result in a dynamic sediment provenance history. Late Pennsylvanian and earliest Permian deposits are enriched in zircons with local affinity and interpreted to reflect local uplift and repeat incision across the basin margin, the latter a result of glacioeustatic forcing during an “everwet” climate. A major paleoenvironmental shift occurs in the late early Permian, which is reflected by the transition from fluvial to mixed fluvial-aeolian and ultimately aeolian dominant sedimentation by the late Permian. The transition from fluvial to aeolian dominant sedimentation is accompanied by a change in clay chemistry, sedimentary rock textual maturity, paleosol morphology and a threefold increase in Paleozoic zircons in the mid to late Permian strata. Widespread loess deposits across equatorial Pangea during the Permian have been used to argue for the possibility of equatorial glaciers situated in highland settings during the early Permian. Conversely, our data suggest initiation of a substantial component of aeolian deposition across the field areas, which is coincident with widespread ice loss across high latitude Gondwana, and ultimately highlights the teleconnections between high latitude glaciation and the low latitude hydrologic cycle.

Texas↗

Paralytic shellfish toxins associated with Arctic Tern mortalities in Alaska

Harmful algal blooms produce biotoxins that can injure or kill fish, wildlife, and humans. These blooms occur naturally but have intensified in many locations globally due to recent climatic changes, including ocean warming. Such changes are especially pronounced in northern regions, where the effects of paralytic shellfish toxins (PSTs) on marine wildlife are of growing concern. In Alaska, seabird mortality events have increased in frequency, magnitude, and duration since 2015 alongside anomalously high ocean temperatures. Although starvation has been implicated as the apparent cause of death in many of these die-offs, saxitoxin (STX) and other PSTs have been identified as possible contributing factors. Here, we describe a mortality event at a nesting colony of Arctic Terns ( Sterna paradisaea ) near Juneau, Alaska in 2019 and report elevated concentrations of PSTs in bird, forage fish, and mussel samples. Concentrations of STX and other PSTs in tern tissues (2.5–51.2 µg 100g −1 STX-equivalents [STX-eq]) were of similar magnitude to those reported from other PST-induced bird die-offs. We documented high PST concentrations in blue mussels (>11,000 µg 100g −1 STX-eq; Mytilus edulis spp.) collected from nearby beaches, as well as in forage fish (up to 494 µg 100g −1 STX-eq) retrieved from Arctic Tern nests, thereby providing direct evidence of PST exposure via the terns’ prey. At maximum concentrations measured in this study, a single 5 g Pacific Sand Lance ( Ammodytes personatus ) could exceed the median lethal STX dose (LD 50 ) currently estimated for birds, offering strong support for PSTs as a likely source of tern mortality. In addition to describing this localized bird mortality event, we used existing energetics data from adult and nestling Arctic Terns to calculate estimated cumulative daily PST exposure based on ecologically relevant concentrations in forage fish. Our estimates revealed potentially lethal levels of PST exposure even at relatively low (≤30 ug 100g −1 STX-eq) toxin concentrations in prey. These findings suggest that PSTs present a significant hazard to Arctic Terns and other northern seabirds and should be included in future investigations of avian mortality events as well as assessments of population health.

Alaska↗

Late Hesperian plains formation and degradation in a low sedimentation zone of the northern lowlands of Mars

The plains materials that form the martian northern lowlands suggest large-scale sedimentation in this part of the planet. The general view is that these sedimentary materials were transported from zones of highland erosion via outflow channels and other fluvial systems. The study region, the northern circum-polar plains south of Gemini Scopuli on Planum Boreum, comprises the only extensive zone in the martian northern lowlands that does not include sub-basin floors nor is downstream from outflow channel systems. Therefore, within this zone, the ponding of fluids and fluidized sediments associated with outflow channel discharges is less likely to have taken place relative to sub-basin areas that form the other northern circum-polar plains surrounding Planum Boreum. Our findings indicate that during the Late Hesperian sedimentary deposits produced by the erosion of an ancient cratered landscape, as well as via sedimentary volcanism, were regionally emplaced to form extensive plains materials within the study region. The distribution and magnitude of surface degradation suggest that groundwater emergence from an aquifer that extended from the Arabia Terra cratered highlands to the northern lowlands took place non-catastrophically and regionally within the study region through faulted upper crustal materials. In our model the margin of the Utopia basin adjacent to the study region may have acted as a boundary to this aquifer. Partial destruction and dehydration of these Late Hesperian plains, perhaps induced by high thermal anomalies resulting from the low thermal conductivity of these materials, led to the formation of extensive knobby fields and pedestal craters. During the Early Amazonian, the rates of regional resurfacing within the study region decreased significantly; perhaps because the knobby ridges forming the eroded impact crater rims and contractional ridges consisted of thermally conductive indurated materials, thereby inducing freezing of the tectonically controlled waterways associated with these features. This hypothesis would explain why these features were not completely destroyed. During the Late Amazonian, high-obliquity conditions may have led to the removal of large volumes of volatiles and sediments being eroded from Planum Boreum, which then may have been re-deposited as thick, circum-polar plains. Transition into low obliquity ~5. myr ago may have led to progressive destabilization of these materials leading to collapse and pedestal crater formation. Our model does not contraindicate possible large-scale ponding of fluids in the northern lowlands, such as for example the formation of water and/or mud oceans. In fact, it provides a complementary mechanism involving large-scale groundwater discharges within the northern lowlands for the emplacement of fluids and sediments, which could have potentially contributed to the formation of these bodies. Nevertheless, our model would spatially restrict to surrounding parts of the northern plain either the distribution of the oceans or the zones within these where significant sedimentary accumulation would have taken place. ?? 2010 Elsevier Inc.

Icarus↗

Modeling groundwater-level responses to multiple stresses using transfer-function models and wavelet analysis in a coastal aquifer system

In coastal aquifers, dynamic stresses such as climate forcings, groundwater withdrawals, and ocean tidal fluctuations cause nonlinear responses to groundwater levels. Such responses to the stresses impact groundwater resources and related flooding and infrastructure risks at multiple scales. We used time-series models such as transfer-function models and wavelet analysis to quantify the relative contribution of these stresses to groundwater-level fluctuation in wells from the unconfined and confined aquifers in an Atlantic coastal aquifer. Climate forcings, such as precipitation and temperature, explained most of the groundwater-level variation for wells in the unconfined aquifer, whereas groundwater withdrawals were the dominant driver of groundwater levels for wells in the confined aquifer. The impact of groundwater withdrawals also was detected in several wells in the unconfined aquifer. Although the influence of ocean tides on groundwater levels commonly is observed in coastal aquifers, we found that daily groundwater withdrawals can obscure the semi-diurnal coherence signal of the two series. The magnitude of groundwater-level fluctuation that could be explained solely by tides was minor compared to that explained by climate or withdrawal stresses. Transfer-function modeling showed seasonal withdrawals from wells in confined aquifers had a significant, yet heterogeneous influence on groundwater levels in coastal aquifers, which highlights climate and withdrawals as key compounding stresses in coastal hydrology. This study demonstrates the value of time-series approaches to advance characterization of groundwater systems in areas with limited hydrogeologic parameter information.

Virginia↗

Geophysical modeling of the northern Appalachian Brompton-Cameron, Central Maine, and Avalon terranes under the New Jersey Coastal Plain

A regional terrane map of the New Jersey Coastal Plain basement was constructed using seismic, drilling, gravity and magnetic data. The Brompton-Cameron and Central Maine terranes were coalesced as one volcanic island arc terrane before obducting onto Laurentian, Grenville age, continental crust in the Taconian orogeny [Rankin, D.W., 1994. Continental margin of the eastern United States: past and present. In: Speed, R.C., (Ed.), Phanerozoic Evolution of North American Continent-Ocean Transitions. DNAG Continent-Ocean Transect Volume. Geological Society of America, Boulder, Colorado, pp. 129-218]. Volcanic island-arc rocks of the Avalon terrane are in contact with Central Maine terrane rocks in southern Connecticut where the latter are overthrust onto the Brompton-Cameron terrane, which is thrust over Laurentian basement. Similarities of these allochthonous island arc terranes (Brompton-Cameron, Central Maine, Avalon) in lithology, fauna and age suggest that they are faulted segments of the margin of one major late Precambrian to early Paleozoic, high latitude peri-Gondwana island arc designated as "Avalonia", which collided with Laurentia in the early to middle Paleozoic. The Brompton Cameron, Central Maine, and Avalon terranes are projected as the basement under the eastern New Jersey Coastal Plain based on drill core samples of metamorphic rocks of active margin/magmatic arc origin. A seismic reflection profile across the New York Bight traces the gentle dipping (approximately 20 degrees) Cameron's Line Taconian suture southeast beneath allochthonous Avalon and other terranes to a 4 sec TWTT depth (approximately 9 km) where the Avalonian rocks are over Laurentian crust. Gentle up-plunge (approximately 5 degrees) projections to the southwest bring the Laurentian Grenville age basement and the drift-stage early Paleozoic cover rocks to windows in Burlington Co. at approximately 1 km depth and Cape May Co. at approximately 2 km depths. The antiformal Shellburne Falls and Chester domes and Chain Lakes-Pelham dome-Bronson Hill structural trends, and the synformal Connecticut Valley-Gaspe structural trend can be traced southwest into the New Jersey Coastal Plain basement. A Mesozoic rift basin, the "Sandy Hook basin", and associated eastern boundary fault is identified, based upon gravity modeling, in the vicinity of Sandy Hook, New Jersey. The thickness of the rift-basin sedimentary rocks contained within the "Sandy Hook basin" is approximately 4.7 km, with the basin extending offshore to the east of the New Jersey coast. Gravity modeling indicates a deep rift basin and the magnetic data indicates a shallow magnetic basement caused by magnetic diabase sills and/or basalt flows contained within the rift-basin sedimentary rocks. The igneous sills and/or flows may be the eastward continuation of the Watchung and Palisades bodies. ?? 2004 Elsevier Ltd. All rights reserved.

Journal of Geodynamics↗

Paleozoic magmatism and porphyry Cu-mineralization in an evolving tectonic setting in the North Qilian Orogenic Belt, NW China

The NWW-striking North Qilian Orogenic Belt records the Paleozoic accretion–collision processes in NW China, and hosts Paleozoic Cu–Pb–Zn mineralization that was temporally and spatially related to the closure of the Paleo Qilian-Qinling Ocean. The Wangdian Cu deposit is located in the eastern part of the North Qilian Orogenic Belt, NW China. Copper mineralization is spatially associated with an altered early Paleozoic porphyritic granodiorite, which intruded tonalites and volcaniclastic rocks. Alteration zones surrounding the mineralization progress outward from a potassic to a feldspar-destructive phyllic assemblage. Mineralization consists mainly of quartz-sulfide stockworks and disseminated sulfides, with ore minerals chalcopyrite, pyrite, molybdenite, and minor galena and sphalerite. Gangue minerals include quartz, orthoclase, biotite, sericite, and K-feldspar. Zircon LA-ICPMS U–Pb dating of the ore-bearing porphyritic granodiorite yielded a mean 206 Pb/ 238 U age of 444.6 ± 7.8 Ma, with a group of inherited zircons yielding a mean U–Pb age of 485 ± 12 Ma, consistent with the emplacement age (485.3 ± 6.2 Ma) of the barren precursor tonalite. Rhenium and osmium analyses of molybdenite grains returned model ages of 442.9 ± 6.8 Ma and 443.3 ± 6.2 Ma, indicating mineralization was coeval with the emplacement of the host porphyritic granodiorite. Rhenium concentrations in molybdenite (208.9–213.2 ppm) suggest a mantle Re source. The tonalities are medium-K calc-alkaline. They are characterized by enrichment of light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), depletion of heavy rare-earth elements (HREEs) and high-field-strength elements (HFSEs), and minor negative Eu anomalies. They have ε Hf ( t ) values in the range of +3.6 to +11.1, with two-stage Hf model ages of 0.67–1.13 Ga, suggesting that the ca. 485 Ma barren tonalites were products of arc magmatism incorporating melts from the mantle wedge and the lithosphere. In contrast, the 40-m.y.-younger ore-bearing porphyritic granodiorite is sub-alkaline and peraluminous. They are enriched in LREEs and LILEs, depleted in HFSEs, and show weak negative Eu anomalies. They display ε Hf ( t ) values of captured or inherited zircons in the range of +8.5 to +10.0, and younger two-stage Hf model ages of 0.78 Ga and 0.86 Ga, similar to those of ca. 485 Ma tonalite. The ca. 445 Ma zircons have ε Hf ( t ) values of −2.1 to +9.9, with two-stage Hf model ages of 0.75–1.27 Ga. Moreover, they have relatively high oxygen fugacity than that of the precursor barren tonalite. The ca. 445 Ma magmas at Wangdian thus formed in a subduction setting, and incorporated melts from the subduction-modified lithosphere that had previously been enriched by additions of chalcophile and siderophile element-rich materials by the earlier magmatism and metasomatism during the Paleo Qilian-Qinling Ocean subduction event.

North Qilian Orogenic Belt↗

Petrologic constraints on the thermal structure of the Cascades arc

Primitive late Cenozoic basaltic lavas from the Cascades volcanic arc near latitude 46°N comprise two distinct compositional groups. Group I includes samples with low Ba/Nb (<20) and other compositional similarities to oceanic island and MORB lavas from within-plate settings. In contrast, Group II exhibits enrichment of Ba and large-ion lithophile elements (LILE) and depletion of Nb and high-field strength elements (HFSE) as seen commonly in calcalkalic lavas from other volcanic arcs. Lavas of both groups are widely distributed across the transect, and Group I lavas are found as much as 30–40 km trenchward of stratovolcanoes that define the High Cascades ‘volcanic front (VF)’. The most primitive lavas are sparsely porphyritic, have elevated Ni, Cr, and Mg#, high calculated magmatic temperatures (1200–1300 °C), and lack evidence of shallow (crustal level) storage and crystallization. Compositions of parental liquids were calculated for each primitive sample on the premise of Fe–Mg equilibrium with mantle peridotite. Assuming that such magmas ascended rapidly from accumulation zones in the mantle, we estimate P and T of segregation. We infer that (a) Group I magmas ascended from systematically greater depths (∼50–70 km) than Group II (∼30–50 km), implying the possible existence of compositional stratification in the mantle wedge; (b) Group I basalts show the least evidence for slab-derived contributions in their sources despite their apparently greater segregation depths (approaching the locus of the Cascadia slab beneath the frontal arc region); (c) Group II lavas with the strongest slab compositional signature have temperatures far exceeding the wet peridotite solidus at high pressure; and (d) the inferred thermal structure of the mantle wedge is very warm, implying a significant component of mantle upwelling and convection. Group I lavas are interpreted as decompression melts from this mantle, and their compositions suggest that their source was little modified by slab-derived contributions. We speculate that melting to produce Group II magmas occurs in the shallow mantle, possibly in response to heating by hot ascending Group I magmas. If true, it seems unlikely that the slab-like signal in Group II lavas can be attributed to modern slab inputs; rather, we postulate that this signature may reflect melting of lithospheric mantle domains containing a ‘stored’ slab-derived component inherited from earlier stages of Cascadia subduction. This scenario differs from the standard paradigm for subduction zones (SZs), and stresses the importance of convecting asthenospheric mantle in driving arc magmatism, particularly in warm subduction zones where slab fluid contributions likely are minimal. In contrast, because tectonic conditions in more typical volcanic arcs favor subduction of cooler, less dehydrated oceanic lithosphere, slab-derived fluids may promote extensive flux-melting in the wedge. Such melts may dominate the magmatic output and mask wedge contributions. The Cascade arc thus provides rarely afforded insights into arc magma genesis.

British Columbia, California, Oregon, Washington↗

Origins and nature of large explosive eruptions in the lower East Rift Zone of Kīlauea volcano, Hawaii: Insights from ash characterization and geochemistry

Several powerful explosive eruptions have taken place in the populated lower East Rift Zone of Kīlauea within the past ∼750 years. These have created distinctive landforms, including a tephra rim enclosing Puʻulena Crater immediately south of the Puna Geothermal Venture power station, a tuff cone at Kapoho Crater near the eastern cape of the Island of Hawaiʻi, and a set of littoral cones, the Sand Hill in Nānāwale, where the 1840 lava flow poured into the ocean. Kapoho Crater tuff cone is the largest of these recent pyroclastic features. Mineral, glass, and melt inclusion analyses of tuff cone ash and later fissure-related scoriaceous materials also found within the crater indicate slightly evolved basaltic magmas (1120–1130 °C) that are compositionally similar to parts of the effusive lower East Rift Zone eruptions in 1955 and 2018. Tuff cone magmas were stored at depths of ∼2.5–3.5 km and had pre-eruptive volatile contents (0.5–0.8 wt% H 2 O, 280–340 ppm CO 2 , 1400–1800 ppm S) similar to other Kīlauea eruptions (e.g., 1959, 1960), suggesting that internal magma properties were unlikely to account for the unusual explosiveness of this eruption. Tephra componentry, grain-size analyses, and field observations confirm that the cone grew during a phreatomagmatic eruption mostly of vitric ash, probably where a fissure opened across the coastline or shallow ocean floor nearby. Supporting this hypothesis is the identification of at least two genera of marine diatoms within tuff cone strata. Sand Hill littoral cone ash is also vitric like that of Kapoho Crater, but distinctly coarser with abundant fluidal ejecta represented. In contrast, the Puʻulena Crater eruption deposited lithic ash and related blocks with minor juvenile magmatic contribution; a phreatomagmatic eruption that was dominantly phreatic. Differences in eruption styles are related to unique mechanics that tephra analyses help us interpret. While powerful explosive eruptions in the lower East Rift Zone are rare, they present a definite future hazard for inhabitants in this part of Hawaii.

Hawaii↗

Perspectives on chemical oceanography in the 21st century: Participants of the COME ABOARD Meeting examine aspects of the field in the context of 40 years of DISCO

The questions that chemical oceanographers prioritize over the coming decades, and the methods we use to address these questions, will define our field's contribution to 21st century science. In recognition of this, the U.S. National Science Foundation and National Oceanic and Atmospheric Administration galvanized a community effort (the Chemical Oceanography MEeting: A BOttom-up Approach to Research Directions, or COME ABOARD) to synthesize bottom-up perspectives on selected areas of research in Chemical Oceanography. Representing only a small subset of the community, COME ABOARD participants did not attempt to identify targeted research directions for the field. Instead, we focused on how best to foster diverse research in Chemical Oceanography, placing emphasis on the following themes: strengthening our core chemical skillset; expanding our tools through collaboration with chemists, engineers, and computer scientists; considering new roles for large programs; enhancing interface research through interdisciplinary collaboration; and expanding ocean literacy by engaging with the public. For each theme, COME ABOARD participants reflected on the present state of Chemical Oceanography, where the community hopes to go and why, and actionable pathways to get there. A unifying concept among the discussions was that dissimilar funding structures and metrics of success may be required to accommodate the various levels of readiness and stages of knowledge development found throughout our community. In addition to the science, participants of the concurrent Dissertations Symposium in Chemical Oceanography (DISCO) XXV, a meeting of recent and forthcoming Ph.D. graduates in Chemical Oceanography, provided perspectives on how our field could show leadership in addressing long-standing diversity and early-career challenges that are pervasive throughout science. Here we summarize the COME ABOARD Meeting discussions, providing a synthesis of reflections and perspectives on the field.

Marine Chemistry↗

The role of pH up-regulation in response to nutrient-enriched, low-pH groundwater discharge

Coral reefs and their ecosystems are threatened by both global stressors, including increasing sea-surface temperatures and ocean acidification (OA), and local stressors such as land-based sources of pollution that can magnify the effects of OA. Corals can physiologically control the chemistry of their internal calcifying fluids (CF) and can thereby regulate their calcification process. Specifically, increasing aragonite saturation state in the CF (Ω CF ) may allow corals to calcify even under external low saturation conditions. Questions remain regarding the physiological processes that govern the CF chemistry and how they change in response to multiple stressors. To address this knowledge gap, the boron δ 11 B and B/Ca were analyzed in tropical corals, Porites lobata, collected at submarine groundwater seeps impacted by the release of treated wastewater in west Maui, Hawai'i, to document the interactions between high nutrient / low pH seep water on CF carbonate chemistry. Results show substantial up-regulation of pH and dissolved inorganic carbon (DIC) with respect to seawater in P. lobata corals collected from within the wastewater impacted area at Kahekili Beach Park compared to the control site at Olowalu Beach. The Ω CF was 9 to 10 times higher than ambient seawater Ω, and 13 to 26% higher than in corals from the control site and from values previously observed in tropical Porites spp. corals. Such elevated up-regulation suggests that corals exposed to nutrient-enriched, low pH effluent sustain CF supersaturated with respect to aragonite, possibly as an internal coping mechanism to combat multiple stressors from land-based sources of pollution. This elevated up-regulation has implications to coral vulnerability to future climate- and ocean-change.

Hawaii↗

The origin of neap-spring tidal cycles

The origin of oceanic tides is a basic concept taught in most introductory college-level sedimentology/geology, oceanography, and astronomy courses. Tides are typically explained in the context of the equilibrium tidal theory model. Yet this model does not take into account real tides in many parts of the world. Not only does the equilibrium tidal model fail to explicate amphidromic circulation, it also does not explain diurnal tides in low latitude positions. It likewise fails to explain the existence of tide-dominated areas where neap-spring cycles are synchronized with the 27.32-day orbital cycle of the Moon (tropical month), rather than with the more familiar 29.52-day cycle of lunar phases (synodic month). Both types of neap-spring cycles can be recognized in the rock record. A complete explanation of the origin of tides should include a discussion of dynamic tidal theory. In the dynamic tidal model, tides resulting from the motions of the Moon in its orbit around the Earth and the Earth in its orbit around the Sun are modeled as products of the combined effects of a series of phantom satellites. The movement of each of these satellites, relative to the Earth's equator, creates its own tidal wave that moves around an amphidromic point. Each of these waves is referred to as a tidal constituent. The geometries of the ocean basins determine which of these constituents are amplified. Thus, the tide-raising potential for any locality on Earth can be conceptualized as the result of a series of tidal constituents specific to that region. A better understanding of tidal cycles opens up remarkable opportunities for research on tidal deposits with implications for, among other things, a more complete understanding of the tidal dynamics responsible for sediment transport and deposition, changes in Earth-Moon distance through time, and the possible influences tidal cycles may exert on organisms. ?? 2006 Elsevier B.V. All rights reserved.

Marine Geology↗

Far field tsunami simulations of the 1755 Lisbon earthquake: Implications for tsunami hazard to the U.S. East Coast and the Caribbean

The great Lisbon earthquake of November 1st, 1755 with an estimated moment magnitude of 8.5-9.0 was the most destructive earthquake in European history. The associated tsunami run-up was reported to have reached 5-15??m along the Portuguese and Moroccan coasts and the run-up was significant at the Azores and Madeira Island. Run-up reports from a trans-oceanic tsunami were documented in the Caribbean, Brazil and Newfoundland (Canada). No reports were documented along the U.S. East Coast. Many attempts have been made to characterize the 1755 Lisbon earthquake source using geophysical surveys and modeling the near-field earthquake intensity and tsunami effects. Studying far field effects, as presented in this paper, is advantageous in establishing constraints on source location and strike orientation because trans-oceanic tsunamis are less influenced by near source bathymetry and are unaffected by triggered submarine landslides at the source. Source location, fault orientation and bathymetry are the main elements governing transatlantic tsunami propagation to sites along the U.S. East Coast, much more than distance from the source and continental shelf width. Results of our far and near-field tsunami simulations based on relative amplitude comparison limit the earthquake source area to a region located south of the Gorringe Bank in the center of the Horseshoe Plain. This is in contrast with previously suggested sources such as Marqu??s de Pombal Fault, and Gulf of C??diz Fault, which are farther east of the Horseshoe Plain. The earthquake was likely to be a thrust event on a fault striking ~ 345?? and dipping to the ENE as opposed to the suggested earthquake source of the Gorringe Bank Fault, which trends NE-SW. Gorringe Bank, the Madeira-Tore Rise (MTR), and the Azores appear to have acted as topographic scatterers for tsunami energy, shielding most of the U.S. East Coast from the 1755 Lisbon tsunami. Additional simulations to assess tsunami hazard to the U.S. East Coast from possible future earthquakes along the Azores-Iberia plate boundary indicate that sources west of the MTR and in the Gulf of Cadiz may affect the southeastern coast of the U.S. The Azores-Iberia plate boundary west of the MTR is characterized by strike-slip faults, not thrusts, but the Gulf of Cadiz may have thrust faults. Southern Florida seems to be at risk from sources located east of MTR and South of the Gorringe Bank, but it is mostly shielded by the Bahamas. Higher resolution near-shore bathymetry along the U.S. East Coast and the Caribbean as well as a detailed study of potential tsunami sources in the central west part of the Horseshoe Plain are necessary to verify our simulation results. ?? 2008 Elsevier B.V.

Marine Geology↗

Understanding processes controlling sediment transports at the mouth of a highly energetic inlet system (San Francisco Bay, CA)

San Francisco Bay is one of the largest estuaries along the U.S. West Coast and is linked to the Pacific Ocean through the Golden Gate, a 100 m deep bedrock inlet. A coupled wave, flow and sediment transport model is used to quantify the sediment linkages between San Francisco Bay, the Golden Gate, and the adjacent open coast. Flow and sediment transport processes are investigated using an ensemble average of 24 climatologically derived wave cases and a 24.8 h representative tidal cycle. The model simulations show that within the inlet, flow and sediment transport is tidally dominated and driven by asymmetry of the ebb and flood tides. Peak ebb velocities exceed the peak flood velocities in the narrow Golden Gate channel as a result of flow convergence and acceleration. Persistent flow and sediment gyres at the headland tips are formed that limit sediment transfer from the ebb-tidal delta to the inlet and into the bay. The residual transport pattern in the inlet is dominated by a lateral segregation with a large ebb-dominant sediment transport (and flow) prevailing along the deeper north side of the Golden Gate channel, and smaller flood dominant transports along the shallow southern margin. The seaward edge of the ebb-tidal delta largely corresponds to the seaward extent of strong tidal flows. On the ebb-tidal delta, both waves and tidal forcing govern flow and sediment transport. Wave focusing by the ebb-tidal delta leads to strong patterns of sediment convergence and divergence along the adjacent Ocean Beach.

California↗

A Sr-Nd isotopic study of sand-sized sediment provenance and transport for the San Francisco Bay coastal system

A diverse suite of geochemical tracers, including 87 Sr/ 86 Sr and 143 Nd/ 144 Nd isotope ratios, the rare earth elements (REEs), and select trace elements were used to determine sand-sized sediment provenance and transport pathways within the San Francisco Bay coastal system. This study complements a large interdisciplinary effort (Barnard et al., 2012) that seeks to better understand recent geomorphic change in a highly urbanized and dynamic estuarine-coastal setting. Sand-sized sediment provenance in this geologically complex system is important to estuarine resource managers and was assessed by examining the geographic distribution of this suite of geochemical tracers from the primary sources (fluvial and rock) throughout the bay, adjacent coast, and beaches. Due to their intrinsic geochemical nature, 143 Nd/ 144 Nd isotopic ratios provide the most resolved picture of where sediment in this system is likely sourced and how it moves through this estuarine system into the Pacific Ocean. For example, Nd isotopes confirm that the predominant source of sand-sized sediment to Suisun Bay, San Pablo Bay, and Central Bay is the Sierra Nevada Batholith via the Sacramento River, with lesser contributions from the Napa and San Joaquin Rivers. Isotopic ratios also reveal hot-spots of local sediment accumulation, such as the basalt and chert deposits around the Golden Gate Bridge and the high magnetite deposits of Ocean Beach. Sand-sized sediment that exits San Francisco Bay accumulates on the ebb-tidal delta and is in part conveyed southward by long-shore currents. Broadly, the geochemical tracers reveal a complex story of multiple sediment sources, dynamic intra-bay sediment mixing and reworking, and eventual dilution and transport by energetic marine processes. Combined geochemical results provide information on sediment movement into and through San Francisco Bay and further our understanding of how sustained anthropogenic activities which limit sediment inputs to the system (e.g., dike and dam construction) as well as those which directly remove sediments from within the Bay, such as aggregate mining and dredging, can have long-lasting effects

California↗

Sediment transport in the San Francisco Bay Coastal System: An overview

The papers in this special issue feature state-of-the-art approaches to understanding the physical processes related to sediment transport and geomorphology of complex coastal-estuarine systems. Here we focus on the San Francisco Bay Coastal System, extending from the lower San Joaquin-Sacramento Delta, through the Bay, and along the adjacent outer Pacific Coast. San Francisco Bay is an urbanized estuary that is impacted by numerous anthropogenic activities common to many large estuaries, including a mining legacy, channel dredging, aggregate mining, reservoirs, freshwater diversion, watershed modifications, urban run-off, ship traffic, exotic species introductions, land reclamation, and wetland restoration. The Golden Gate strait is the sole inlet connecting the Bay to the Pacific Ocean, and serves as the conduit for a tidal flow of ~ 8 x 109 m 3 /day, in addition to the transport of mud, sand, biogenic material, nutrients, and pollutants. Despite this physical, biological and chemical connection, resource management and prior research have often treated the Delta, Bay and adjacent ocean as separate entities, compartmentalized by artificial geographic or political boundaries. The body of work herein presents a comprehensive analysis of system-wide behavior, extending a rich heritage of sediment transport research that dates back to the groundbreaking hydraulic mining-impact research of G.K. Gilbert in the early 20th century.

California↗

Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean↗