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USGS1996

Plan for assessment of the occurrence, status, and distribution of volatile organic compounds in aquifers of the United States

The occurrence of volatile organic compounds (VOCs) in water is of national concern because of their relatively high aqueous solubility, mobility, and persistence, because many are known or suspected carcinogens, because of their widespread use, and because they have been found in drinking-water supplies. Because of this national concern, VOCs were selected for National investigation (hereafter termed "National Synthesis") by the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program in 1994. The broad goals of this National Synthesis are to: (1) describe current water- quality conditions with respect to VOCs; (2) define trends, or lack of trends, in VOCs in surface and ground water; and (3) identify, describe, and explain causal relations among the occurrence and distribution of VOCs in surface water and ground water, and natural and human factors. The National Synthesis of VOCs in ground water has three objectives: (1) to describe their occurrence, status, and distribution; (2) to determine relations among VOCs in shallow ground water and natural and human factors; and (3) to determine, compare, and contrast the occurrence, transformation, transport, and fate of selected VOCs in the hydrologic cycle for several regionally or nationally important aquifer systems. The description of VOC occurrence, status, and distribution in ground water focuses on major aquifers of the United States. Occurrence describes the presence or absence of VOCs, their frequency of occurrence, and their ranges of concentrations. Status compares the concentrations of VOCs detected in relation to water-quality regulations or advisories, such as Maximum Contaminant Levels, Proposed Maximum Contaminant Levels, Maximum Contaminant Level Goals, and Health Advisories. Distribution describes the variability of VOCs in ground water, areally and by depth. This report describes the study design for conducting such an assessment. The assessment focuses on aquifers, or parts of aquifers, that are currently used or have the potential to be used as sources of water supplies, using data collected as part of local, State, and Federal ground-water monitoring programs since 1985. Assessment by aquifer and comparison of results among aquifers will be completed for those aquifers for which adequate spatial or depth-related data are available. Assessment of VOCs in aquifers also will be completed at regional and national scales. A set of criteria for well-network design, well construction, sample-collection methods, and methods of laboratory analysis must be met before VOC data are used for assessment. An appropriate well-network design will provide a generally unbiased, random, equal-area distribution of sampling sites throughout the aquifer, or part of the aquifer, of interest. Well-construction information must be sufficient to ensure that the hydrogeologic unit (or units) represented by the water level measured and the hydrologic unit (or units) contributing water to the well are known. In addition, the well construction and pumping equipment in the well need to be of a type that are not likely to affect concentrations of VOCs in the water sample. VOC data will be considered suitable for use in the occurrence assessment if nationally accepted methods for collection and analysis were used and if the quantitation level for VOC analytes was less than about 5 micrograms per liter; laboratory analysis was done by a laboratory certified by the U.S. Environ- mental Protection Agency; and the sample was collected from untreated (raw) water at or near the well head before being held in a pressure tank or holding tank.

Open-File Report↗

USGS2009

Development of a Watershed Boundary Dataset for Mississippi

The U.S. Geological Survey, in cooperation with the Mississippi Department of Environmental Quality, U.S. Department of Agriculture-Natural Resources Conservation Service, Mississippi Department of Transportation, U.S. Department of Agriculture-Forest Service, and the Mississippi Automated Resource Information System, developed a 1:24,000-scale Watershed Boundary Dataset for Mississippi including watershed and subwatershed boundaries, codes, names, and drainage areas. The Watershed Boundary Dataset for Mississippi provides a standard geographical framework for water-resources and selected land-resources planning. The original 8-digit subbasins (hydrologic unit codes) were further subdivided into 10-digit watersheds and 12-digit subwatersheds - the exceptions are the Lower Mississippi River Alluvial Plain (known locally as the Delta) and the Mississippi River inside levees, which were only subdivided into 10-digit watersheds. Also, large water bodies in the Mississippi Sound along the coast were not delineated as small as a typical 12-digit subwatershed. All of the data - including watershed and subwatershed boundaries, hydrologic unit codes and names, and drainage-area data - are stored in a Geographic Information System database.

Open-File Report↗

USGS1979

Ground-water quality in Bannock, Bear Lake, Caribou, and part of Power counties, southeastern Idaho

This report provides information about the current quality of ground waters in southeastern Idaho and discusses the natural and manmade environmental controls on that quality. This information will be useful in planning and monitoring the development and use of the ground-water resources of southeastern Idaho. The southeastern corner of Idaho, as described in this report, encompasses an area of about 4,000 mil in Bannock, Bear Lake, Caribou, and part of Power Counties. The popu- lation of the area in 1975, based on best estimates by the Idaho Division of Budget, Policy Planning, and Coordination (1976) was 75,200. About 80 percent of the population is in and near the city of Pocatello, which is the second largest population center in the State. Pocatello's economy depends largely on manufacturing and industrial processing, which includes chemicalfertilizer plants. The econ- omy in the rural areas depends largely on agriculture--both dry and irrigated farming are practiced. Mining is important and expected to dominate the economy in the eastcentral part of the area in the future. Natural resources include phosphate ore, which makes up about 35 percent of the U.S. reserves (U.S. Department of Interior and U.S. Department of Agriculture, 1977); ground water, which mostly underlies the several intermontane valleys that dissect the area; and hot springs, which indicate that geothermal energy sources may underlie part of the area. Also, current (1978) speculation is that petroleum reserves may be present in the vicinity of Bear Lake. Development of more sprink- ler-irrigated lands, increases in population, and growth of phosphate mining are expected to place stress on the ground-water resources, both in quality and quantity. The purpose of this report is to present the results of a study whose primary objectives were (1) to provide current waterquality data representative of the water in several different aquifers (water- bearing formations) in the study area, and (2) to relate these data to natural and manmade environmental controls. The wells sampled during this study establish a quasi-network, which could be resampled in the future to document and analyze changes (if any) in ground-water quality. Based on this information, planners and water managers could better understand the causeand-effect relations controlling water quality and could better manage land and water-resource development. The report is designed for ease of reading and presentation. It uses maps, tables, and abbreviated text to describe geology, hydrology, and ground-water quality and how they are interrelated. Some practical ways for improving water quality are discussed for the benefit of individual water users. The field data collected in making the study are contained in the Data Section of this report. The authors gratefully acknowledge the many individual well owners, municipal officials, and private industries that provided well information and allowed access to their properties and collection of water samples. Without their help, this work could not have been done. Water samples were collected at 103 well sites. Waterlevel measurements were made at 98 of these sites during July, August, and September of 1976. This study was made by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. A similar study is being made (1978) in north Idaho. Other studies are planned, specifically to obtain ground-water-quality data in areas where land and water-resource development is expected or accelerating.

Idaho↗

USGS2008

Providing Data and Modeling to Help Manage Water Supplies

The Sonoma County Water Agency (SCWA) and other local water purveyors have partnered with the U.S. Geological Survey (USGS) to assess hydrologic conditions and to quan-tify the county-wide interconnections between surface water and ground water. Through this partnership, USGS scientists have completed assessments of the geohydrology and geochemistry of the Sonoma and Alexander Valley ground-water basins. Now, the USGS is constructing a detailed ground-water flow model of the Santa Rosa Plain. It will be used to help identify strategies for surface-water/ground-water management and help to ensure long-term viability of the water supply. The USGS is also working with the SCWA to help meet future demand in the face of possible new restrictions on its main source of water, the Russian River. SCWA draws water from the alluvial aquifer underlying and adjacent to the Russian River and may want to extend riverbank filtration facilities to new areas. USGS scientists are conducting research to charac-terize riverbank filtration processes and changes in water quality during reduced river flows.

Fact Sheet↗

USGS2019

A Generalized Additive Model approach to evaluating water quality: Chesapeake Bay Case Study

Nutrient-reduction efforts have been undertaken in recent decades to mitigate the impacts of eutrophication in coastal and estuarine systems worldwide. To track progress in response to one of these efforts we use Generalized Additive Models (GAMs) to evaluate a diverse suite of water quality constituents over a 32-year period in the Chesapeake Bay, an estuary on the east coast of the United States. Model development included selecting a GAM structure to describe nonlinear seasonally-varying changes over time, incorporating hydrologic variability via either river flow or salinity, and using interventions to model method or laboratory changes suspected to impact data. This approach, transferable to other systems, allows for evaluation of water quality data in a statistically rigorous way, while being suitable for application to many sites and variables. This enables consistent generation of annual updates, while providing a tool for developing insights to a range of management- and research-focused questions.

Chesapeake Bay↗

USGS2007

Groundwater noble gas, age, and temperature signatures in an Alpine watershed: Valuable tools in conceptual model development

Bedrock groundwater in alpine watersheds is poorly understood, mainly because of a scarcity of wells in alpine settings. Groundwater noble gas, age, and temperature data were collected from springs and wells with depths of 3–342 m in Handcart Gulch, an alpine watershed in Colorado. Temperature profiles indicate active groundwater circulation to a maximum depth (aquifer thickness) of about 200 m, or about 150 m below the water table. Dissolved noble gas data show unusually high excess air concentrations (>0.02 cm 3 STP/g, ΔNe > 170%) in the bedrock, consistent with unusually large seasonal water table fluctuations (up to 50 m) observed in the upper part of the watershed. Apparent 3 H/ 3 He ages are positively correlated with sample depth and excess air concentrations. Integrated samples were collected from artesian bedrock wells near the trunk stream and are assumed to approximate flow‐weighted samples reflecting bedrock aquifer mean residence times. Exponential mean ages for these integrated samples are remarkably consistent along the stream, four of five being from 8 to 11 years. The tracer data in combination with other hydrologic and geologic data support a relatively simple conceptual model of groundwater flow in the watershed in which (1) permeability is primarily a function of depth; (2) water table fluctuations increase with distance from the stream; and (3) recharge, aquifer thickness, and porosity are relatively uniform throughout the watershed in spite of the geological complexity of the Proterozoic crystalline rocks that underlie it.

Water Resources Research↗

USGS2017

Geophysical data collected during the 2014 minute 319 pulse flow on the Colorado River below Morelos Dam, United States and Mexico

Geophysical methods were used to monitor infiltration during a water release, referred to as a “pulse flow,” in the Colorado River delta in March and April 2014. The pulse flow was enabled by Minute 319 of the 1944 United States–Mexico Treaty concerning water of the Colorado River. Fieldwork was carried out by the U.S. Geological Survey and the Centro de Investigación Científica y de Educación Superior de Ensenada as part of a binational effort to monitor the hydrologic effects of the pulse flow along the limitrophe (border) reach of the Colorado River and into Mexico. Repeat microgravity measurements were made at 25 locations in the southern limitrophe reach to quantify aquifer storage change during the pulse flow. Observed increases in storage along the river were greater with distance to the south, and the amount of storage change decreased away from the river channel. Gravity data at four monitoring well sites indicate specific yield equal to 0.32±0.05. Electromagnetic induction methods were used at 12 transects in the limitrophe reach of the river along the United States– Mexico border, and farther south into Mexico. These data, which are sensitive to variation in soil texture and water content, suggest relatively homogeneous conditions. Repeat direct-current resistivity measurements were collected at two locations to monitor groundwater elevation. Results indicate rapid groundwater-level rise during the pulse flow in the limitrophe reach and smaller variation at a more southern transect. Together, these data are useful for hydrogeologic characterization and hydrologic model development. Electronic data files are provided in the accompanying data release (Kennedy and others, 2016a).

Arizona, Baja California, California↗

USGS2026

Emergent headwater types for watershed monitoring, research, and planning

Headwaters—that is headwater streams and the watersheds they drain—strongly influence water quality, ecosystem services, and hydrologic connectivity, yet remain poorly mapped, monitored, and understood at large spatial scales. Using available spatial data to classify headwater “types” could therefore enhance the utility of sparse monitoring data to advance research and watershed planning—and help update literature-based perceptual models of headwaters as steep, forested, and minimally disturbed watersheds. Here, we analyze headwaters across the contiguous United States to quantify how their attributes (climate, topography, land cover, soils) vary regionally and differ from their downstream watersheds. Our analysis (a) identified seven dominant headwater types with distinct combinations of biophysical and climatic attributes and (b) revealed systematic contrasts with downstream watersheds, with strongest differences in attributes representing potential flowpath depth. Our findings offer a transferable framework for classifying, modeling, and managing these critical yet understudied components of the hydrologic network.

conterminous United States↗

USGS2010

Database of groundwater levels and hydrograph descriptions for the Nevada Test Site area, Nye County, Nevada

A database containing water levels measured from wells in and near areas of underground nuclear testing at the Nevada Test Site since 1941 was developed. The database provides information for each well including well construction, borehole lithology, units contributing water to the well, and general site remarks. Water-level information provided in the database includes measurement source, status, method, accuracy, and specific water-level remarks. Additionally, the database provides hydrograph narratives that document the water-level history and describe and interpret the water-level hydrograph for each well. Water levels in the database were quality assured and analyzed. Multiple conditions were assigned to each water‑level measurement to describe the hydrologic conditions at the time of measurement. General quality, temporal variability, regional significance, and hydrologic conditions are attributed to each water-level measurement.

Nevada↗

USGS2013

Laboratory evaluation of the Level TROLL 100 manufactured by In-Situ Inc.: results of pressure and temperature tests

The Level TROLL 100 manufactured by In-Situ Inc. was evaluated by the U.S. Geological Survey (USGS) Hydrologic Instrumentation Facility (HIF) for conformance to the manufacturer’s accuracy specifications for measuring pressure throughout the device’s operating temperature range. The Level TROLL 100 is a submersible, sealed, water-level sensing device with an operating pressure range equivalent to 0 to 30 feet of water over a temperature range of −20 to 50 degrees Celsius (°C). The device met the manufacturer’s stated accuracy specifications for pressure within its temperature-compensated operating range of 0 to 50 °C. The device’s accuracy specifications did not meet established USGS requirements for primary water-stage sensors used in the operation of streamgages, but the Level TROLL 100 may be suitable for other hydrologic data-collection applications. As a note, the Level TROLL 100 is not designed to meet USGS accuracy requirements. Manufacturer accuracy specifications were evaluated, and the procedures followed and the results obtained are described in this report. USGS accuracy requirements are routinely examined and reported when instruments are evaluated at the HIF.

Open-File Report↗

USGS1978

Hydrologic data for the Copper Basin area, a potential mining area in Yavapai County, Arizona

Large low-grade ore bodies have been discovered in Copper Basin, and a large copper-mining operation is anticipated in the near future. Hydrologic data are being collected to provide the data base necessary to determine the effects of a potential mining operation on the water resources of the area. The area of potential depletion or contamination of water supplies is the 50-square-mile alluvial slope downgradient from Copper Basin. In the Copper Basin area the streams generally are dry, except for the perennial flow in a 3-mile-long reach of Kirkland Creek, where the base flow ranges from about 1 to 3 cubic feet per second. The water in the alluvium, which is more than 1,000 feet thick in places, generally is under unconfined conditions. The direction of ground-water movement is generally southwesterly toward Skull Valley Wash and Kirkland Creek. The depth to water in wells ranges from less than 10 to 675 feet below the land surface. Near the center of the area, test wells penetrate a clay confining bed at the base of the alluvium and an underlying sequence of volcanic rocks, which is more than 1,000 feet thick and contains water under confined conditions. Pump tests indicate that the confining bed forms a barrier between the water in the alluvium and the water in the volcanic rocks and that, initially, pumping from the volcanic rocks would not affect the water level in the alluvium. The areal extent of the volcanic sequence is not known.

Arizona↗

USGS1980

Quality of water in the Black River near Dunn, North Carolina, and ground-water levels adjacent to the river prior to channel excavation in 1978-79

During 1976-79 data were collected at three sites on the Black River, near Dunn, North Carolina, to define water-quality and other hydrologic conditions prior to channel excavation. Samples collected over a range in flow from 1.2 to 900 cubic feet per second contained 1 to 81 mg/L (milligrams per liter) of suspended sediment, 37 to 108 mg/L of dissolved solids, and 0.21 to 1.0 mg/L of total nitrogen. Water-level fluctuations in wells located within 100 feet of the Black River were almost identical with those of the stream.

North Carolina↗

USGS1982

Selected climatic characteristics of the southeastern Uinta Basin, Utah and Colorado

The southeastern Uinta Basin in Utah and Colorado contains large reserves of oil shale, the mining of which could affect the area 's water resources. Climatic characteristics of the area, which were evaluated as one phase of a comprehensive hydrologic study, are presented to help provide the means of evaluating the impact of mining on the area 's water resources. Data for precipitation , air temperature, and evaporation obtained by the U.S. Geological Survey from October 1974 to September 1978, and similar short-term data obtained by other Federal agencies at sites in and near the study area, were tabulated and adjusted to a 1941-70 base period. For all sites with incomplete records for 1941-70, the data were adjusted by relating them to concurrent data collected at one or more long-term National Oceanic and Atmospheric Administration sites. Maps were prepared showing areal variance for normal annual precipitation, normal annual air temperature, and normal annual pan evaporation.. The normal annual precipitation ranges from less than 8 inches for altitudes under 5,000 feet to more than 20 inches above 9,000 feet. The normal annual air temperature ranges from 37 to 47 degrees Fahrenheit and varies inversely with altitude and latitude. The normal annual pan evaporation ranges from 42 to 60 inches and varies directly with normal annual air temperature. Although not mapped, it is shown that the normal April 1 water content of the snowpack increases from about 5 inches at 7,000 feet to about 11 inches at 9,000 feet. In addition, the year-to-year and within-year variances of some climatic characteristics are illustrated. The standard error of estimate when relating normal annual precipitation to altitude is 17%, which is equivalent to the standard error when relating the average for 5 years of observed record at a site to the long-term mean at the site. Thus, it appears that additional observation points would not improve areal coverage unless the observation sites were continued for 5 years or longer. (USGS)

Colorado, Utah↗

USGS2004

Simulation of runoff and wetland storage in the Hamden and Lonetree watershed sites within the Red River of the North Basin, North Dakota and Minnesota

Re-establishment of wetlands has been promoted by various groups to control future floods in the Red River of the North Basin in North Dakota and Minnesota. Therefore, a study was conducted to simulate runoff and wetland storage in the Hamden and Lonetree watershed sites in the Red River of the North Basin. Data from geographic information system analyses, collected weather data, additional historic weather data, and geomorphology were used in a wetlands hydrologic model to simulate precipitation accumulation, snowmelt, evapotranspiration, soil infiltration, seepage to ground water, surface runoff, and streamflow. Simulated daily mean water volumes for the soil and wetlands in the Hamden and Lonetree watershed sites showed that the soils of the two sites stored as much water as the wetlands throughout most of the simulation period. Total simulated runoff for the Hamden watershed site for the period of record was reduced about 38 percent by increasing the Bisson Lake spillage threshold from 0.009 to 0.60. The additional simulated storage at the larger spillage threshold led to reductions in simulated runoff. Simulated daily mean streamflows for the Hamden watershed site at a Bisson Lake spillage threshold of 0.60 were less than those simulated for the same day at a Bisson Lake spillage threshold of 0.009. However, the peak streamflows simulated for June 2000 and April 2001 at a spillage threshold of 0.60 were about the same as those simulated at a spillage threshold of 0.009. Simulated runoff during flood conditions in April and June 2000 and March and April 2001 was reduced 1 to 6 percent for an increased spillage threshold. Total runoff for the period of record was reduced about 31 percent for the increased spillage threshold. Simulation results indicate total streamflow from a flood event may be reduced by wetland storage, but peak streamflows during a flood event may not be affected substantially.

Scientific Investigations Report↗

USGS1983

Limnological study of Shasta Lake, Shasta County, California, with emphasis on the effects of the 1977 drought

An intensive limnological study of Shasta Lake was made in conjunction with the California Department of Water Resources during the 1977 drought. Water-quality data were collected from March 1977 through September 1978 at six lake stations and four lake tributary stations. Data collected during and after the drought were compared. Lake water quality is described as a function of lake morphometry, climate, hydrology, and reservoir hydraulics. Results indicate Shasta Lake is a warm monomictic lake. Tributary inflow to the lake and outflow through the dam generate density currents which promote mixing at depth and the development of an extensive metalimnion. During the drought, record low lake levels resulted in the exposure of an extensive nearshore sediment zone. Resuspended sediments caused a deterioration of water quality. The most notable effects, in comparison with post-drought conditions, were decreased light penetration, increased dissolved-solids concentration and specific conductance, decreased dissolved-oxygen concentrations, and elevated nutrient levels. A hypolimnetic anoxic condition was observed at the upstream stations of the lake. (USGS)

Water-Resources Investigations Report↗

USGS1985

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper↗

USGS2014

Hydroclimatic regimes: a distributed water-balance framework for hydrologic assessment, classification, and management

Runoff-based indicators of terrestrial water availability are appropriate for humid regions, but have tended to limit our basic hydrologic understanding of drylands – the dry-subhumid, semiarid, and arid regions which presently cover nearly half of the global land surface. In response, we introduce an indicator framework that gives equal weight to humid and dryland regions, accounting fully for both vertical (precipitation + evapotranspiration) and horizontal (groundwater + surface-water) components of the hydrologic cycle in any given location – as well as fluxes into and out of landscape storage. We apply the framework to a diverse hydroclimatic region (the conterminous USA) using a distributed water-balance model consisting of 53 400 networked landscape hydrologic units. Our model simulations indicate that about 21% of the conterminous USA either generated no runoff or consumed runoff from upgradient sources on a mean-annual basis during the 20th century. Vertical fluxes exceeded horizontal fluxes across 76% of the conterminous area. Long-term-average total water availability (TWA) during the 20th century, defined here as the total influx to a landscape hydrologic unit from precipitation, groundwater, and surface water, varied spatially by about 400 000-fold, a range of variation ~100 times larger than that for mean-annual runoff across the same area. The framework includes but is not limited to classical, runoff-based approaches to water-resource assessment. It also incorporates and reinterprets the green- and blue-water perspective now gaining international acceptance. Implications of the new framework for several areas of contemporary hydrology are explored, and the data requirements of the approach are discussed in relation to the increasing availability of gridded global climate, land-surface, and hydrologic data sets.

Hydrology and Earth System Sciences↗

USGS2018

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer. Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers. Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Idaho↗