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At least 1,747 records · Page 97Linked to original sources

Ecotoxicological profile of a high prevalence marine disease area in Florida's Gulf coast

Pervasive marine pollution can have devastating effects on ocean health. Polychlorinated Biphenyls (PCB), Polycyclic Aromatic Hydrocarbons (PAH), and Organochlorine Pesticides (OCP) are of particular concern given their high level of toxicity and carcinogenicity. These compounds originate from anthropogenic activity, therefore are often ubiquitous in coastal environments close to human sources. Marine turtles in coastal Florida (USA) are affected by fibropapillomatosis, a tumor-causing panzootic with highly debilitating symptoms. Despite repeated associations between fibropapillomatosis occurrence and carcinogenic pollution, the ecotoxicological status of high disease areas in the Florida Gulf has been unknown. Our study deployed passive sampling devices along a structured inshore-to-offshore coastal grid to generate the first comprehensive dataset on the concentration and diversity of oncogenic pollutants in Crystal River, Florida, where juvenile green turtles exhibit a fibropapillomatosis prevalence of 74%. Multiple OCP, PAH, and PCB compounds were detected for a total chemical concentration of 16,086.98 pg/L (Σ OCP 45.51 pg/L + Σ PAH 16,014.53 pg/L + Σ PCB 26.94 pg/L). Density and composition of carcinogenic pollution was found to be significantly lower in offshore green turtle habitats compared to inshore habitats (p=0.02), suggesting multiple potential contamination sources along the coastline. The carcinogenic compounds detected have been shown to have associations with fibropapillomatosis in other parts of the world, as well as having wider ecosystem implications. Our work contributes to the body of knowledge correlating the emerging threat of harmful ocean pollution and marine wildlife diseases.

Florida↗

Temporal, geographic, and host distribution of avian paramyxovirus 1 (Newcastle disease virus)

Newcastle disease is caused by virulent forms of avian paramyxovirus of serotype 1 (APMV-1) and has global economic importance. The disease reached panzootic proportions within two decades after first being identified in 1926 in the United Kingdom and Indonesia and still remains endemic in many countries across the world. Here we review information on the host, temporal, and geographic distribution of APMV-1 genetic diversity based on the evolutionary systematics of the complete coding region of the fusion gene. Strains of APMV-1 are phylogenetically separated into two classes (class I and class II) and further classified into genotypes based on genetic differences. Class I viruses are genetically less diverse, generally present in wild waterfowl, and are of low virulence. Class II viruses are genetically and phenotypically more diverse, frequently isolated from poultry with occasional spillovers into wild birds, and exhibit a wider range of virulence. Waterfowl, cormorants, and pigeons are natural reservoirs of all APMV-1 pathotypes, except viscerotropic velogenic viruses for which natural reservoirs have not been identified. Genotypes I and II within class II include isolates of high and low virulence, the latter often being used as vaccines. Viruses of genotypes III and IX that emerged decades ago are now isolated rarely, but may be found in domestic and wild birds in China. Containing only virulent viruses and responsible for the majority of recent outbreaks in poultry and wild birds, viruses from genotypes V, VI, and VII, are highly mobile and have been isolated on different continents. Conversely, virulent viruses of genotypes XI (Madagascar), XIII (mainly Southwest Asia), XVI (North America) and XIV, XVII and XVIII (Africa) appear to have a more limited geographic distribution and have been isolated predominantly from poultry.

Infection, Genetics and Evolution↗

Nowcasting methods for determining microbiological water quality at recreational beaches and drinking-water source waters

Nowcasts are tools used to provide timely and accurate water-quality assessments of threats to drinking-water and recreational resources from fecal contamination or cyanobacterial harmful algal blooms. They use mathematical models and techniques to provide near-real-time estimates of fecal-indicator bacteria (FIB) and cyanotoxin concentrations. Techniques include logic-based thresholds, decision trees (built with machine learning), multiple linear and binary logistic regression, artificial neural networks, and process-based deterministic models. The type of site (freshwater, marine, or river) and dependent variable (FIB or cyanotoxin) dictate which explanatory variables are used in models. Nowcast systems notify the public of associated public-health risks and can also be used to manage data for FIB models; work is ongoing to incorporate cyanotoxin models into some nowcasts. The Great Lakes NowCast in the USA has been operational since 2010 and includes 25 lake beaches and one recreational river site. Examples of other operational FIB nowcasts are described for locations in the USA and around the world. In many cases, models predicted exceedances of FIB standards with accuracies as good as or better than using the previous measured FIB concentration (persistence method). Accuracy and timeliness are vital to beach management decisions that protect public health and support the local recreation-driven economy. Nowcasts benefit the public by providing estimates of water-quality conditions in near-real-time. Managers can use nowcasts at recreational and drinking-water treatment plant sites when FIB or cyanotoxins are projected to be elevated to target sample collection, to provide near-real-time recreational advisories to the public, or to preemptively optimize drinking-water treatments or change intake options to mitigate possible adverse effects on drinking-water quality.

Journal of Microbiological Methods↗

The California Seafloor and Coastal Mapping Program – Providing science and geospatial data for California's State Waters

The California Seafloor and Coastal Mapping Program (CSCMP) is a collaborative effort to develop comprehensive bathymetric, geologic, and habitat maps and data for California's State Waters. CSCMP began in 2007 when the California Ocean Protection Council (OPC) and the National Oceanic and Atmospheric Administration (NOAA) allocated funding for high-resolution bathymetric mapping, largely to support the California Marine Life Protection Act and to update nautical charts. Collaboration and support from the U.S. Geological Survey and other partners has led to development and dissemination of one of the world's largest seafloor-mapping datasets. CSCMP provides essential science and data for ocean and coastal management, stimulates and enables research, and raises public education and awareness of coastal and ocean issues. Specific applications include: •Delineation and designation of marine protected areas •Characterization and modeling of benthic habitats and ecosystems •Updating nautical charts •Earthquake hazard assessments •Tsunami hazard assessments •Planning offshore infrastructure •Providing baselines for monitoring change •Input to models of sediment transport, coastal erosion, and coastal flooding •Regional sediment management •Understanding coastal aquifers •Providing geospatial data for emergency response

California↗

Genetic and grade and tonnage models for sandstone-hosted roll-type uranium deposits, Texas Coastal Plain, USA

The coincidence of a number of geologic and climatic factors combined to create conditions favorable for the development of mineable concentrations of uranium hosted by Eocene through Pliocene sandstones in the Texas Coastal Plain. Here 254 uranium occurrences, including 169 deposits, 73 prospects, 6 showings and 4 anomalies, have been identified. About 80 million pounds of U 3 O 8 have been produced and about 60 million pounds of identified producible U 3 O 8 remain in place. The development of economic roll-type uranium deposits requires a source, large-scale transport of uranium in groundwater, and deposition in reducing zones within a sedimentary sequence. The weight of the evidence supports a source from thick sequences of volcanic ash and volcaniclastic sediment derived mostly from the Trans-Pecos volcanic field and Sierra Madre Occidental that lie west of the region. The thickest accumulations of source material were deposited and preserved south and west of the San Marcos arch in the Catahoula Formation. By the early Oligocene, a formerly uniformly subtropical climate along the Gulf Coast transitioned to a zoned climate in which the southwestern portion of Texas Coastal Plain was dry, and the eastern portion humid. The more arid climate in the southwestern area supported weathering of volcanic ash source rocks during pedogenesis and early diagenesis, concentration of uranium in groundwater and movement through host sediments. During the middle Tertiary Era, abundant clastic sediments were deposited in thick sequences by bed-load dominated fluvial systems in long-lived channel complexes that provided transmissive conduits favoring transport of uranium-rich groundwater. Groundwater transported uranium through permeable sandstones that were hydrologically connected with source rocks, commonly across formation boundaries driven by isostatic loading and eustatic sea level changes. Uranium roll fronts formed as a result of the interaction of uranium-rich groundwater with either (1) organic-rich debris adjacent to large long-lived fluvial channels and barrier–bar sequences or (2) extrinsic reductants entrained in formation water or discrete gas that migrated into host units via faults and along the flanks of salt domes and shale diapirs. The southwestern portion of the region, the Rio Grande embayment, contains all the necessary factors required for roll-type uranium deposits. However, the eastern portion of the region, the Houston embayment, is challenged by a humid environment and a lack of source rock and transmissive units, which may combine to preclude the deposition of economic deposits. A grade and tonnage model for the Texas Coastal Plain shows that the Texas deposits represent a lower tonnage subset of roll-type deposits that occur around the world, and required aggregation of production centers into deposits based on geologic interpretation for the purpose of conducting a quantitative mineral resource assessment.

Texas↗

Noble gas data from Goldfield and Tonopah epithermal Au-Ag deposits, ancestral Cascades Arc, USA: Evidence for a primitive mantle volatile source

The He, Ne, and Ar isotopic composition of fluid inclusions in ore and gangue minerals were analyzed to determine the source of volatiles in the high-grade Goldfield and Tonopah epithermal Au-Ag deposits in southwestern Nevada, USA. Ar and Ne are mainly atmospheric, whereas He has only a minor atmospheric component. Corrected 3 He/ 4 He ratios (with atmospheric He removed) range widely from 0.05 to 35.8 times the air 3 He/ 4 He ratio (R A ), with a median of 1.43 R A . Forty-one percent of measured 3 He/ 4 He ratios are ≥4 R A , corresponding to ≥50% mantle He assuming a mantle ratio of 8 R A . These results suggest that mafic magmas were part of the magmatic-hydrothermal system underlying Goldfield and Tonopah, and that associated mantle-sourced volatiles may have played a role in ore formation. The three highest corrected 3 He/ 4 He ratios of 17.0, 23.7, and 35.8 R A indicate a primitive mantle He source and are the highest yet reported for any epithermal-porphyry system and for the Cascades arc region. Compiled 3 He/ 4 He measurements from epithermal-porphyry systems in subduction-related magmatic arcs around the world (n = 209) display a statistically significant correlation between 3 He/ 4 He and Au-Ag grade. The correlation suggests that conditions which promote higher fluid inclusion 3 He/ 4 He ratios (abundance of mantle volatiles and focused upward volatile transport) have some relation to conditions that promote higher Au-Ag grades (focused flow of metal-bearing fluids and efficient chemical traps). Results of this and previous investigations of He isotopes in epithermal-porphyry systems are consistent with the hypothesis posed in recent studies that mafic magmas serve an important function in the formation of these deposits.

Cascades Arc↗

Two-event lode-ore deposition at Butte, USA: 40Ar/39Ar and U-Pb documentation of Ag-Au-polymetallic lodes overprinted by younger stockwork Cu-Mo ores and penecontemporaneous Cu lodes

The ore-genesis model for world-class deposits of the Butte mining district, Montana, USA, is deep pre-Main Stage porphyry Cu-Mo and overlying Main Stage Ag-Zn-Cu zoned-lode deposits, both of which formed from hydrothermal fluids driven by minor volumes of rhyolitic magma. The lode-specific model is that hydrothermal processes diminished in intensity outward from district center along lode veins, synchronously forming metal zones. The accepted models are controverted by new geologic and multi-method geochronologic studies. The new data reveal the following sequence of events: (1) Thermal study of country rock indicates that the 76.9-Ma Butte Granite cooled to 350–400 °C by 4 m.y. after emplacement. (2) Five quartz porphyry rhyolite dikes were emplaced at 67–65 Ma and another at 60 Ma (SHRIMP U-Pb) into the cooled Butte Granite without resetting 40 Ar/ 39 Ar ages in country rock. (3) Fifty-eight white mica and K-feldspar samples from alteration envelopes adjacent to Ag-Au-polymetallic lodes in outer parts of the district, Zn-rich lodes in intermediate parts, and Cu-rich lodes in the district center yield 40 Ar/ 39 Ar ages of 73–70 Ma for Ag-rich lodes, 65–64 Ma for Cu-rich lodes, and complex age spectra of 69–65 Ma for Zn-rich lodes. The data show that Ag-Au-polymetallic lodes occupied cross-district fractures by about 73 Ma, forming the greater Butte mining district. At 67–65 Ma, minor quartz porphyry dikes were emplaced into central and eastern parts of the rejuvenated fracture system but without evidence of related cupola or volcanic rocks or of thermal disturbance in the country rock. At 64.5 Ma, overlapping hydrothermal cells formed two stockwork Cu-Mo domes in deep parts of the fracture system. At 65–64 Ma and closely related to late-stage stockwork Cu-Mo activity, a penecontemporaneous hydrothermal pulse formed a high-sulfidation hydrothermal plume that (1) utilized the large re-opened fractures to cannibalize and remobilize Cu from autologous, stockwork, and older Ag-Au-polymetallic lodes, (2) deposited the rich, high-sulfidation Cu lodes, and (3) mobilized metals from early Ag-Au-polymetallic veins in middle parts of the district, transported the metals outward and redeposited them, enriching early veins, especially in the intermediate Zn plus Cu areas. Metals zones in lodes of the Butte district are the result of an intensely focused, Cu-rich hydrothermal plume that variably reworked the center of significantly larger, 10 m.y. older, Ag-Au-polymetallic lodes.

Montana↗

Testing the potential role of brine reflux in the formation of sedimentary exhalative (Sedex) ore deposits

Sedimentary exhalative (sedex) ore deposits are the world’s largest Zn-Pb deposits. While the geologic processes that formed these deposits are generally well understood, the fundamental hydrologic processes that drove these massive hydrothermal systems remain an area of debate. We use numerical modeling to test an emerging hypothesis, supported by recent ore genesis research and sedex basin analysis, that brine reflux flow systems produced and drove the fluids that formed sedex deposits. A previous numerical model of brine reflux, developed to study dolomitization, is adapted to a sedimentary basin with geologic features essential for sedex formation. We simulate the flow of evaporated brines through the basin and the evolution of salinity, temperature, and flow rates, and find that modeled values for these parameters for brines discharging to the seafloor exceed previously established physiochemical thresholds for ore formation (>170 g/L, >80°C, and total discharge volumes >107 m3 per meter perpendicular to the 2D model section). Sensitivity testing of this modest-sized basin highlights the large effect that aspects of the hydrogeologic framework can have on mineralizing potential of the reflux brines. Finally, modeling alternating periods of active and inactive evaporation produces pulsed brine reflux systems capable of producing multiple deposits of different age as observed in many sedex basins. The modeling thus supports the hypothesis that seawater evaporation on the basin margin significantly inboard of sedex deposits may be responsible for their formation. Sensitivity testing suggests that numerical models with more detailed, basin-specific geologic frameworks might be useful for assessing the mineral potential of sedimentary basins.

Ore Geology Reviews↗

Mineral deposit discovery order and three-part quantitative assessments

Larger oil pools tending to be discovered earlier in an exploration play suggests the same pattern might exist for mineral deposits and could be used in predicting sizes of undiscovered deposits in mineral assessments. The volume of individual petroleum pools is highly correlated with surface projection area of pools in basins. The gradual additions to individual oil pool reserves over time adds to the appearance of larger pools being discovered earlier. Comparisons of surface projected areas of mineral deposits to their tonnages showed significant positive relationships in all 10 deposit types analyzed, suggesting that larger deposits should be discovered earlier than small deposits. Analysis of deposits consistent with three-part mineral assessments identified 9 combinations of mineral deposit types in large regions each containing multiple geological permissive tracts showing negative and 1 positive relationships of deposit size with discovery date significant at the 1% level. Twenty other tests of regions containing multiple permissive settings had either negative or positive relationships, none significantly different from those that might occur by chance. The large regions are mostly based on political boundaries. These results suggest mineral deposit discovery order is not the same as observed in oil pool exploration. The widely employed three-part quantitative mineral resource assessments are an obvious choice to benefit from patterns of declining deposit sizes with order of discovery. The 30 tests of relationships of discovery dates to deposit sizes demonstrated here were performed with deposits consistent with those in three-part assessments, but the large areas are not consistent with permissive tracts used in these assessments because they also contain substantial non-permissive geology. In 100 permissive tracts assessed with three-part assessments of multiple deposit types located throughout the world, the median number of known well-explored deposits is 1 and 90 percent of tracts report less than 9 deposits. The number of well-explored deposits in three-part assessed tracts tends to be quite small, limiting any ability to recognize a discovery order versus size relationship. In a three-part assessment of undiscovered porphyry copper deposits of South America, only 7 of 26 delineated tracts contained more than 2 known deposits and only 1 had a significant negative relationship between tonnage of known deposits and year of discovery (p = 0.04). Most predicted undiscovered deposits in this tract were expected to be under extensive unexplored post-mineralization cover, meaning the general grade and tonnage model should be applied because the discovery order process starts over. Projection of deposit sizes based on discovery order would provide a biased estimate of the undiscovered deposit sizes in this case. Thus, although a discovery order versus size relationship could exist in three-part mineral assessments, only rarely might the pattern be useful to predict sizes of undiscovered deposits.

Ore Geology Reviews↗

Petrogenesis and rare earth element mineralization of the Elk Creek carbonatite, Nebraska, USA

Although carbonatites are the primary source of the world’s rare earth elements (REEs), the processes responsible for ore-grade REE enrichment in carbonatites are still poorly understood. In this study, we present a petrologic, geochemical, and isotopic evaluation of the Elk Creek carbonatite in southeast Nebraska to constrain the origin of REE mineralization. The Elk Creek carbonatite is a multilithologic carbonatite comprised of an early apatite-dolomite carbonatite, a middle/heavy REE-enriched magnetite-dolomite carbonatite, and a late-stage light REE-enriched, barite-dolomite carbonatite, as well as a suite of breccias. Neodymium, strontium, and carbon isotopic data from the early apatite-dolomite carbonatite, ε Nd (T) = 2.3 to 3.4, 87 Sr/ 86 Sr (i) = 0.702704 to 0.702857, and δ 13 C = −3.3 to −3.4, indicate that the parental magma and REEs were derived from the mantle, and textural and chemical data suggest that hydrothermal processes played an important role in reaching ore-grade enrichment. Higher initial 87 Sr/ 86 Sr values (∼0.7041) of REE-mineralized lithologies are evidence that these fluids were derived, in part, from meteoric water that interacted with the country rock. Modeling of the C-O isotopic data reveals that some of the isotopic variation results from closed-system Rayleigh fractionation of an evolving carbonatitic magma between 300 and 500 °C, but an excursion to heavier δ 18 O is likely the result of interaction with H 2 O-CO 2 -fluids at temperatures from 400 to 100 °C. Hydrothermal dolomite has higher 87 Sr/ 86 Sr values than early-formed magmatic dolomite, consistent with metasomatism by fluids derived, in part, from a more radiogenic source such as the Precambrian-age wall rock. Rare earth element mineralization occurs primarily in fine-grained, cavity filling minerals including monazite, bastnäsite, parisite, and synchysite along with barite, dolomite, quartz, and iron oxides. We interpret the LREE enrichment at Elk Creek to be the product of hydrothermal fluids derived from the evolving carbonatite magma and fluids from the wall rock. The REEs likely became enriched in late-stage fluids from the evolving magma as well as being remobilization by the dissolution of earlier formed minerals. Middle/heavy REE-enrichment in the magnetite-dolomite carbonatite is hosted in hydrothermal dolomite and is attributed to variations in the composition of hydrothermal fluids.

Nebraska↗

A case of Te-rich low-sulfidation epithermal Au-Ag deposits in a calc-alkaline magmatic arc, NE China

Tellurium-bearing low-sulfidation epithermal Au-Ag deposits are significant producers of gold, silver, and potentially strategic elements if mineral processing methods are optimized for recovery. Although these deposits are generally related to alkaline magmatism, our study documents an unusual occurrence of Te-rich low-sulfidation epithermal systems in the North Heilongjiang Belt in northeast China that is spatially and temporally associated with calc-alkaline magmatism and tectonic extension in a continental arc‐setting. In the North Heilongjiang Belt, Te-bearing Au-Ag deposits are usually sited in dilatant zones, mostly along extensional NW structures or at their intersections with deep‐seated NE-striking faults such as the Nenjiang-Heihe and Jiayin-Mudanjiang lineaments. Of these deposits, Sandaowanzi is well‐known for its bonanza gold grades. These faults localized andesitic to rhyolitic volcano-plutonic centers that evolved from mantle‐derived mafic melts to intermediate compositions due to differentiation and crustal assimilation as documented by their mineralogy and Sr, Nd, and Pb isotope compositions. During assimilation of country rocks, fluids containing 3 He and other volatiles derived from mantle magmas displaced or mixed with external groundwater containing radiogenic 4 He derived from country rocks. In this belt, the bulk metal content of Au, Ag and Te was probably introduced by deep mantle‐derived mafic‐intermediate calc‐alkaline intrusions. However, our study does not exclude input of metals leached from underlying metasedimentary rocks and older Te‐bearing Au mineralization. The noble gas, hydrogen, oxygen and lead isotope compositions of fluid inclusions and ore minerals suggest that the deposits formed by mixing between magmatic fluids and convecting meteoric ground waters containing lead leached from surrounding country rocks. At deeper levels, isotopic evidence suggests that Au-Ag-Te (Bi) precipitated with pyrite, quartz, sericite, and carbonate minerals due to mixing with Te-rich fluids. At shallower levels, Au and Ag precipitated contemporaneously with base‐metal sulfides, hydrothermal quartz and sericite during episodic boiling as evidenced by silica morphology and mineral textures. The relatively uniform spacing of epithermal systems along NW- and NE-trending structures in the North Heilongjiang Belt was used to identify unexplored spaces within this mineral belt that are prospective for concealed low-sulfidation epithermal gold deposits. Although some of the Au-Ag deposits in this belt are enriched in Te, there is a lack of coeval alkaline igneous rocks that are commonly associated with Te-bearing gold deposits elsewhere in the world (e.g., Cripple Creek, Emperor, and Lihir Island).

North Heilongjiang Belt↗

Multivariate analysis of ATR-FTIR spectra for assessment of oil shale organic geochemical properties

In this study, attenuated total reflectance (ATR) Fourier transform infrared spectroscopy (FTIR) was coupled with partial least squares regression (PLSR) analysis to relate spectral data to parameters from total organic carbon (TOC) analysis and programmed pyrolysis to assess the feasibility of developing predictive models to estimate important organic geochemical parameters. The advantage of ATR-FTIR over traditional analytical methods is that source rocks can be analyzed in the laboratory or field in seconds, facilitating more rapid and thorough screening than would be possible using other tools. ATR-FTIR spectra, TOC concentrations and Rock–Eval parameters were measured for a set of oil shales from deposits around the world and several pyrolyzed oil shale samples. PLSR models were developed to predict the measured geochemical parameters from infrared spectra. Application of the resulting models to a set of test spectra excluded from the training set generated accurate predictions of TOC and most Rock–Eval parameters. The critical region of the infrared spectrum for assessing S1, S2, Hydrogen Index and TOC consisted of aliphatic organic moieties (2800–3000 cm −1 ) and the models generated a better correlation with measured values of TOC and S2 than did integrated aliphatic peak areas. The results suggest that combining ATR-FTIR with PLSR is a reliable approach for estimating useful geochemical parameters of oil shales that is faster and requires less sample preparation than current screening methods.

Organic Geochemistry↗

Validation of the U37K' paleotemperature proxy in the South Brazilian Bight from core-top sediments

The paleothermometer based on the alkenone unsaturation index ( U 37 K ′ "> U37K′ ) is often used to reconstruct past sea surface temperatures (SST). In the SW Atlantic Ocean, however, a limited understanding of the seasonal and depth distribution of coccolithophores, which generates the U 37 K ′ "> U37K′ signal preserved in ocean sediments, hinders accurate estimates of past regional SSTs. We analyzed 45 core-top sediment samples from the continental shelf of the South Brazilian Bight (SBB, 23 °S to 28 °S) to assess regional spatial U 37 K ′ "> U37K′ -SST gradients and improve SST estimates. The U 37 K ′ "> U37K′ data were converted to SST using six published paleotemperature equations and compared to modern observational SST data from the World Ocean Atlas (2018) data set. Data indicate that the U 37 K ′ "> U37K′ signal is produced during the austral summer and autumn when regional episodic upwelling events occur over the inner-shelf and the nutricline shoals at the slope. Our analysis of core-top data shows that SST estimates derived from most calibration equations closely align with modern observed temperatures but are skewed toward warmer months associated with upwelling-derived nutrients. Our findings underscore the importance of considering regional and seasonal biases to improve the accuracy of paleotemperature reconstructions. Understanding the factors influencing the SBB U 37 K ′ "> U37K′ signal enables a more meaningful comparison between regional paleoceanographic studies, improving our understanding of past changes in the SW Atlantic Ocean and our ability to predict regional SST response to ongoing and future warming.

South Brazilian Bight↗

Sequence stratigraphy and a revised sea-level curve for the Middle Devonian of eastern North America

The well-exposed Middle Devonian rocks of the Appalachian foreland basin (Onondaga Formation; Hamilton Group, Tully Formation, and the Genesee Group of New York State) preserve one of the most detailed records of high-order sea-level oscillation cycles for this time period in the world. Detailed examination of coeval units in distal areas of the Appalachian Basin, as well as portions of the Michigan and Illinois basins, has revealed that the pattern of high-order sea-level oscillations documented in the New York–Pennsylvania section can be positively identified in all areas of eastern North America where coeval units are preserved. The persistence of the pattern of high-order sea-level cycles across such a wide geographic area suggests that these cycles are allocyclic in nature with primary control on deposition being eustatic sea-level oscillation, as opposed to autocylic controls, such as sediment supply, which would be more local in their manifestation. There is strong evidence from studies of cyclicity and spectral analysis that these cycles are also related to Milankovitch orbital variations, with the short and long-term eccentricity cycles (100 kyr and 405 kyr) being the dominant oscillations in many settings. Relative sea-level oscillations of tens of meters are likely and raise considerable issues about the driving mechanism, given that the Middle Devonian appears to record a greenhouse phase of Phanerozoic history. These new correlations lend strong support to a revised high-resolution sea-level oscillation curve for the Middle Devonian for the eastern portion of North America. Recognized third-order sequences are: Eif-1 lower Onondaga Formation, Eif-2: upper Onondaga and Union Springs formations; Eif–Giv: Oatka Creek Formation; Giv-1: Skaneateles, Giv-2: Ludlowville, Giv-3: lower Moscow, Giv-4: upper Moscow–lower Tully, and Giv-5: middle Tully–Geneseo formations. Thus, in contrast with the widely cited eustatic curve of Johnson et al. (1985), which recognizes just one major transgressive–regressive (T–R) cycle in the early–mid Givetian (If) prior to the major late Givetian Taghanic unconformity (IIa, upper Tully–Geneseo Shale), we recognize four T–R cycles: If (restricted), Ig, Ih, and Ii. We surmise that third-order sequences record eustatic sea-level fluctuations of tens of meters with periodicities of 0.8–2 myr, while their medial-scale (fourth-order) subdivisions record lesser variations primarily of 405 kyr duration (long-term eccentricity). This high-resolution record of sea-level change provides strong evidence for high-order eustatic cycles with probable Milankovitch periodicities, despite the fact that no direct evidence for Middle Devonian glacial sediments has been found to date.

Wisconsin, Illinois, Michigan, Indiana, Kentucky, ↗

Ant-nest ichnofossils in honeycomb calcretes, Neogene Ogallala Formation, High Plains region of western Kansas, U.S.A.

Two new ant-nest trace fossils are described from calcic sandy paleosols of the Neogene Ogallala Formation in western Kansas. The ichnofossils are preserved within and below calcrete beds weathering in positive relief as carbonate-filled casts or as cavities in negative relief. Daimoniobarax ichnogenus nov. is established for burrow systems composed of vertically tiered, horizontally oriented pancake-shaped chambers connected by predominantly vertical and cylindrical shafts ~ 0.8 cm in diameter. Ichnospecies of Daimoniobarax are differentiated based on differences in the plan view outline of chambers, shaft orientation, and junctions between chambers and shafts. Daimoniobarax nephroides ichnospecies nov. is composed of an ~ 24–76 cm long vertical sequence of distinctly lobed chambers (~ 2–20 cm wide and ~ 1 cm high) arranged along sinuous to helical shafts. Chamber shape in plan view ranges from small teardrops to larger kidney- and U-shaped forms. Shafts intersect at chamber edges such that chambers appear to bud from the central shafts. Daimoniobarax nephroides is most similar to the nests of extant seed-harvester ants of the New World genus Pogonomyrmex . Such ants are specialized granivores and prefer sandy soils in arid to semi-arid grassland and desert regions. Daimoniobarax tschinkeli ichnospecies nov. is ~ 30–80 cm in vertical extent. Chambers (~ 2–30 cm wide and ~ 1 cm high) are circular to elongate or pseudopodial in plan view. Vertical shafts are straight to slightly sinuous and intersect most often toward the center of the chambers. The generalized architecture of D. tschinkeli is similar to that of the nests or nest portions of several extant ant genera, though it does not closely resemble any known modern nest. Ant ichnofossils provide valuable information on hidden biodiversity, paleohydrologic regimes, paleopedogenic processes, and paleoclimate during the time of nest occupation. Depth-related changes in chamber size and vertical spacing may also help interpret paleosurfaces and paleodepths, and serve as geopetal features.

Kansas↗

The antiquity of the Sahara Desert: New evidence from the mineralogy and geochemistry of Pliocene paleosols on the Canary Islands, Spain

The Sahara is the largest warm desert in the world, but its age has been controversial, with estimates ranging from Miocene to Holocene. Mineralogical and geochemical data show that paleosols of Pliocene to mid-Pleistocene age on Fuerteventura and Gran Canaria in the Canary Islands have developed in part from inputs of dust from Africa. These paleosols contain quartz and mica, minerals that are abundant in African dust but are rare in the basaltic rocks that dominate the Canary Islands. Trace elements with minimal mobility, Sc, Cr, Hf, Th, and Ta as well as the rare earth elements, show that paleosols have compositions that are intermediate between those of local rocks and African-derived dust. Thus, results reported here and in a recently published study by others indicate that 9 paleosols record delivery of African dust to the Canary Islands between ~4.8–2.8 Ma, ~3.0–2.9 Ma, ~2.3–1.46 Ma, and ~0.4 Ma. A long-term paleosol record of African dust input agrees with deep-sea records off the coast of western Africa that imply increased dust fluxes to the eastern Atlantic Ocean at ~4.6 Ma. It is concluded that the Sahara Desert has been in existence as an arid-region dust source, at least intermittently, for much of the Pliocene and continuing into the Pleistocene.

Canary Islands↗

Proposed stratotype for the base of the highest Cambrian stage at the first appearance datum of Cordylodus andresi, Lawson Cove section, Utah, USA

We propose a candidate for the Global Standard Stratotype-section and Point (GSSP) for the base of the highest stage of the Furongian Series of the Cambrian System. The section is at Lawson Cove in the Ibex area of Millard County, Utah, USA. The marker horizon is the first appearance datum (FAD) of the conodont Cordylodus andresi Viira et Sergeyeva in Kaljo et al. [Kaljo, D., Borovko, N., Heinsalu, H., Khazanovich, K., Mens, K., Popov, L., Sergeyeva, S., Sobolevskaya, R., Viira, V., 1986. The Cambrian-Ordovician boundary in the Baltic-Ladoga clint area (North Estonia and Leningrad Region, USSR). Eesti NSV Teaduste Akadeemia Toimetised. Geologia 35, 97-108]. At this section and elsewhere this horizon also is the FAD of the trilobite Eurekia apopsis (Winston et Nicholls, 1967). This conodont characterizes the base of the Cordylodus proavus Zone, which has been recognized in many parts of the world. This trilobite characterizes the base of the Eurekia apopsis Zone, which has been recognized in many parts of North America. The proposed boundary is 46.7 m above the base of the Lava Dam Member of the Notch Peak Formation at the Lawson Cove section. Brachiopods, sequence stratigraphy, and carbon-isotope geochemistry are other tools that characterize this horizon and allow it to be recognized in other areas. ?? 2006 Nanjing Institute of Geology and Palaeontology, CAS.

Palaeoworld↗

The seasonal cycle of diabatic heat storage in the Pacific Ocean

This study quantifies uncertainties in closing the seasonal cycle of diabatic heat storage (DHS) over the Pacific Ocean from 20??S to 60??N through the synthesis of World Ocean Circulation Experiment (WOCE) reanalysis products from 1993 to 1999. These products are DHS from Scripps Institution of Oceanography (SIO); near-surface geostrophic and Ekman currents from Earth and Space Research (ESR); and air-sea heat fluxes from Comprehensive Ocean-Atmosphere Data Set (COADS), National Centers for Environmental Prediction (NCEP), and European Center for Mid-Range Weather Forecasts (ECMWF). With these products, we compute residual heat budget components by differencing long-term monthly means from the long-term annual mean. This allows the seasonal cycle of the DHS tendency to be modeled. Everywhere latent heat flux residuals dominate sensible heat flux residuals, shortwave heat flux residuals dominate longwave heat flux residuals, and residual Ekman heat advection dominates residual geostrophic heat advection, with residual dissipation significant only in the Kuroshio-Oyashio current extension. The root-mean-square (RMS) of the differences between observed and model residual DHS tendencies (averaged over 10??latitude-by-20??longitude boxes) is <20 W m-2 in the interior ocean and <100 W m-2 in the Kuroshio-Oyashio current extension. This reveals that the residual DHS tendency is driven everywhere by some mix of residual latent heat flux, shortwave heat flux, and Ekman heat advection. Suppressing bias errors in residual air-sea turbulent heat fluxes and Ekman heat advection through minimization of the RMS differences reduces the latter to <10 W m-2 over the interior ocean and <25 W m -2 in the Kuroshio-Oyashio current extension. This reveals air-sea temperature and specific humidity differences from in situ surface marine weather observations to be a principal source of bias error, overestimated over most of ocean but underestimated near the Intertropical Convergence Zone. ?? 2005 Elsevier Ltd. All rights reserved.

Progress in Oceanography↗