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At least 1,747 records · Page 97Linked to original sources

Survival of spotted salamander eggs in temporary woodland ponds of coastal Maryland

Temporary ponds on the Atlantic Coastal Plain in maryland were characterized according to water chemistry, rain input, phytoplankton, zooplankton and use by the spotted salamander Ambystoma maculatum during March-October 1983-1984. Neither the number of egg masses per unit of pond surface (abundance) nor the survival of spotted salamander embryos was significantly correlated (P>0.05) with pond pH. Rainfall during May-July significantly increased the hydrogen ion concentration of 5 of 11 ponds evaluated for the impact of rainfall during the previous 48h and the previous week. Survival of egg masses transferred among eight ponds with pH3.66-4.45 and one pond with pH5.18 was significantly reduced (P<or=0.05) only at pH 3.66. Embryonic survival was negatively correlated (P<or=0.05) with the concentration of aluminium in the pond water. The abundance of egg masses was positively correlated (P<or=0.05) with water temperature and magnesium concentration, and total chlorophyll during the larval period. Yearly variability of pond characteristics (e.g. water chemistry, pond longevity) and amphibian reproduction make it difficult to determine the effects of acidic deposition on the spotted salamander. At the present time, pond longevity, water temperature and possibly, oxygen content, seem more important to spotted salamander reproduction than chemical changes caused by annual acidic deposition.

Environmental Pollution↗

Nutrient exchange across the sediment-water interface in the Potomac River estuary

The flux of ammonia, phosphate, silica and radon-222 from Potomac tidal river and estuary sediments is controlled by processes occurring at the sediment-water interface and within surficial sediment. Calculated diffusive fluxes range between 0·6 and 6·5 mmol m −2 day −1 for ammonia, 0·020 and 0·30 mmol m −2 day −1 for phosphate, and 1·3 and 3·8 mmol m −2 day −1 for silica. Measured in situ fluxes range between 1 and 21 mmol m −2 day −1 for ammonia, 0·1 and 2·0 mmol m −2 day −1 for phosphate, and 2 and 19 mmol m −2 day −1 for silica. The ratio of in situ fluxes to diffusive fluxes (flux enhancement) varied between 1·6 and 5·2 in the tidal river, between 2·0 and 20 in the transition zone, and from 1·3 to 5·1 in the lower estuary. The large flux enhancements from transition zone sediments are attributed to macrofaunal irrigation. Nutrient flux enhancements are correlated with radon flux enhancements, suggesting that fluxes may originate from a common region and that nutrients are regenerated within the upper 10–20 cm of the sediment column. The low fluxes of phosphate from tidal viver sediments reflect the control benthic sediment exerts on phosphorus through sorption by sedimentary iron oxyhydroxides. In the tidal river, benthic fluxes of ammonia and phosphate equal one-half and one-third of the nutrient input of the Blue Plains sewage treatment plant. In the tidal Potomac River, benthic sediment regeneration supplies a significant fraction of the nutrients utilized by primary producers in the water column during the summer months.

Maryland, Virginia↗

Bottom stress estimates and sand transport on northern California inner continental shelf

Measurements of velocities and light transmission in the bottom boundary layer on the continental shelf off northern California demonstrate the importance of storms in the transport of sediment along the coast and offshore in this region. Time-series estimates of bottom stress obtained from a combined wave-current bottom boundary layer model in which wave and current measurements from the Geoprobe tripod were used as input show high stress values of 10 dynes cm −2 during two distinct storm events in early February and early March, 1991. These stresses induce significant offshore sediment transport, achieving maximum values of about 0.5 g cm −1 s −1 . The net transport over the entire measurement period from 30 January 1991 to 13 March 1991 was along the coast toward the north and offshore. This transport pattern explains slow migration of low amplitude, broad crescentic dunes along and across this portion of the inner continental shelf.

California↗

A model of the productivity of the mallard duck

This paper describes a stochastic computer model that simulates recruitment of the mallard ( Anas platyrhynchos ) under different habitat conditions and management scenarios. The model incorporates several environmental phenomena and biological relations that affect mallard recruitment. Major events include arrival of mallards in the spring, daily survival of hens, initiation of nests, selection of nest sites, survival of nests until hatching, and survival of broods until fledging. The model was originally developed as a tool for synthesizing the results of research. Subsequently, we applied the model to a variety of management situations. We also describe the sources of estimates used in the model, evaluate its sensitivity to input parameters, and review some practical applications.

Ecological Modelling↗

Animal population dynamics: Identification of critical components

There is a growing interest in the use of population dynamics models in environmental risk assessment and the promulgation of environmental regulatory policies. Unfortunately, because of species and areal differences in the physical and biotic influences on population dynamics, such models must almost inevitably be both complex and species- or site-specific. Given the emormous variety of species and sites of potential concern, this fact presents a problem; it simply is not possible to construct models for all species and circumstances. Therefore, it is useful, before building predictive population models, to discover what input parameters are of critical importance to the desired output. This information should enable the construction of simpler and more generalizable models. As a first step, it is useful to consider population models as composed to two, partly separable classes, one comprising the purely mechanical descriptors of dynamics from given demographic parameter values, and the other describing the modulation of the demographic parameters by environmental factors (changes in physical environment, species interactions, pathogens, xenobiotic chemicals). This division permits sensitivity analyses to be run on the first of these classes, providing guidance for subsequent model simplification. We here apply such a sensitivity analysis to network models of mammalian and avian population dynamics.

Ecological Modelling↗

Comparison of alternative spatial resolutions in the application of a spatially distributed biogeochemical model over complex terrain

Spatially distributed biogeochemical models may be applied over grids at a range of spatial resolutions, however, evaluation of potential errors and loss of information at relatively coarse resolutions is rare. In this study, a georeferenced database at the 1-km spatial resolution was developed to initialize and drive a process-based model (Forest-BGC) of water and carbon balance over a gridded 54976 km2 area covering two river basins in mountainous western Oregon. Corresponding data sets were also prepared at 10-km and 50-km spatial resolutions using commonly employed aggregation schemes. Estimates were made at each grid cell for climate variables including daily solar radiation, air temperature, humidity, and precipitation. The topographic structure, water holding capacity, vegetation type and leaf area index were likewise estimated for initial conditions. The daily time series for the climatic drivers was developed from interpolations of meteorological station data for the water year 1990 (1 October 1989-30 September 1990). Model outputs at the 1-km resolution showed good agreement with observed patterns in runoff and productivity. The ranges for model inputs at the 10-km and 50-km resolutions tended to contract because of the smoothed topography. Estimates for mean evapotranspiration and runoff were relatively insensitive to changing the spatial resolution of the grid whereas estimates of mean annual net primary production varied by 11%. The designation of a vegetation type and leaf area at the 50-km resolution often subsumed significant heterogeneity in vegetation, and this factor accounted for much of the difference in the mean values for the carbon flux variables. Although area wide means for model outputs were generally similar across resolutions, difference maps often revealed large areas of disagreement. Relatively high spatial resolution analyses of biogeochemical cycling are desirable from several perspectives and may be particularly important in the study of the potential impacts of climate change.

Ecological Modelling↗

Evaluation of Baltazor known geothermal resources area, Nevada

By virtue of the Geothermal Steam Act of 1970, the U.S. Geological Survey is required to appraise geothermal resources of the United States prior to competitive lease sales. This appraisal involves coordinated input from a variety of disciplines, starting with reconnaissance geology and geophysics. This paper describes how the results of several geophysical methods used in KGRA evaluation were interpreted by the authors, two geophysicists, involved with both the Evaluation Committee and the research program responsible for obtaining and interpreting the geophysical data to be used by the committee. ?? 1979.

Geothermics↗

Fluid inclusion gas chemistry as a potential minerals exploration tool: Case studies from Creede, CO, Jerritt Canyon, NV, Coeur d'Alene district, ID and MT, southern Alaska mesothermal veins, and mid-continent MVT's

Recent advances in instrumentation now permit quantitative analysis of gas species from individual fluid inclusions. Fluid inclusion gas data can be applied to minerals exploration empirically to establish chemical (gas composition) signatures of the ore fluids, and conceptually through the development of genetic models of ore formation from a framework of integrated geologic, geochemical, and isotopic investigations. Case studies of fluid inclusion gas chemistry from ore deposits representing a spectrum of ore-forming processes and environments are presented to illustrate both the empirical and conceptual approaches. We consider epithermal silver-gold deposits of Creede, Colorado, Carlin-type sediment-hosted disseminated gold deposits of Jerritt Canyon, Nevada, metamorphic silver-base-metal veins of the Coeur d'Alene district, Idaho and Montana, gold-quartz veins in accreted terranes of southern Alaska, and the mid-continent base-metal sulfide deposits of Mississippi Valley-Type (MVT's). Variations in gas chemistry determine the redox state of the ore fluids, provide compositional input for gas geothermometers, characterize ore fluid chemistry (e.g., CH 4 CO 2 , H 2 SSO 2 , CO 2 /H 2 S, organic-rich fluids, gas-rich and gas-poor fluids), identify magmatic, meteoric, metamorphic, shallow and deep basin fluids in ore systems, locate upwelling plumes of magmatic-derived volatiles, zones of boiling and volatile separation, interfaces between contrasting fluids, and important zones of fluid mixing. Present techniques are immediately applicable to exploration programsas empirical studies that monitor fluid inclusion gas threshold concentration levels, presence or absence of certain gases, or changes in gas ratios. We suggest that the greater contribution of fluid inclusion gas analysis is in the integrated and comprehensive chemical dimension that gas data impart to genetic models, and in the exploration concepts based on processes and environments of ore formation derived from these genetic models.

Journal of Geochemical Exploration↗

Sources and fractionation processes influencing the isotopic distribution of H, O and C in the Long Valley hydrothermal system, California, U.S.A.

The isotopic ratios of H, O and C in water within the Long Valley caldera, California reflect input from sources external to the hydrothermal reservoir. A decrease in δD in precipitation of 0.5‰ km −1 , from west to east across Long Valley, is caused by the introduction of less fractionated marine moisture through a low elevation embayment in the Sierra Nevada Mountain Range. Relative to seasonal fluctuations in precipitation (−158 to −35‰.), δD ranges in hot and cold surface and groundwaters are much less variable (−135 to −105‰.). Only winter and spring moisture, reflecting higher precipitation rates with lighter isotopic signatures, recharge the hydrological system. The hydrothermal fluids are mixtures of isotopically heavy recharge (δD = − 115‰, δ 18 O = − 15‰) derived from the Mammoth embayment, and isotopically lighter cold water (δD = −135‰, δ 18 O = −18‰). This cold water is not representative of current local recharge. The δ 13 C values for dissolved carbon in hot water are significantly heavier (− 7 to − 3‰) than in cold water (−18 to −10‰) denoting a separate hydrothermal origin. These δ 13 C values overlie the range generally attributed to magmatic degassing of CO 2 . However, δ 13 C values of metamorphosed Paleozoic basement carbonates surrounding Long Valley fall in a similar range, indicating that hydrothermal decarbonization reactions are a probable source of CO 2 . The δ 13 C and δ 18 O values of secondary travertime and vein calcite indicate respective fractionation with CO 2 and H 2 O at temperatures approximating current hydrothermal conditions.

California↗

Large-scale distribution of metal contamination in the fine-grained sediments of the Clark Fork River, Montana, U.S.A.

Historic discharges from the mining and smelting complex at the head-waters of the Clark Fork River have resulted in elevated Ag, Cd, Cu, Pb and Zn concentrations in the <60 μm fraction of both bed and flood-plain sediments of the river. Processes affecting the trends in longitudinal distributions of these metals were investigated by repeated sampling over a 380 km river reach between August 1986 and July 1989. At the most upstream site, bed-sediment metal concentrations were enriched 18–115 times above least enriched tributaries, depending on the metal. All metals decreased exponentially with distance downstream away from mining. The exponential model predicts that elevated metal concentrations should occur over 550 km downstream, in Lake Pend Oreille. Longitudinal trends, obvious on a scale of hundreds of kilometers, were obscured by small-scale spatial variability when shorter stretches of the river were considered. Longitudinal dispersion appeared to be controlled largely by physical dilution with less-contaminated sediments. Evidence suggests that erosion of contaminated flood-plains contributes to metal contamination in the bed sediments. Tributary input appeared to have little influence on the large-scale, downstream distribution of metals; however, it did contribute to local variability in bed-sediment metal concentrations. Association of metals with specific mineral grains, as well as variability in total organic C and Fe concentration, appeared also to contribute to variability. Some year-to-year variability in bed-sediment metal concentrations was observed, however, trends in longitudinal dispersion were not significantly different between at least two of the years sampled.

Montana↗

Gas buildup in Lake Nyos, Cameroon: The recharge process and its consequences

The gases dissolved in Lake Nyos, Cameroon, were quantified recently (December 1989 and September 1990) by two independent techniques: in-situ measurements using a newly designed probe and laboratory analyses of samples collected in pre-evacuated stainless steel cylinders. The highest concentrations of CO 2 and CH 4 were 0.30 mol/kg and 1.7 mmol/kg, respectively, measured in cylinders collected 1 m above lake bottom. Probe measurements of in-situ gas pressure at three different stations showed that horizontal variations in total dissolved gas were negligible. Total dissolved-gas pressure near the lake bottom is 1.06 MPa (10.5 atm), 50% as high as the hydrostatic pressure of 2.1 MPa (21 atm). Comparing the CO 2 profile constructed from the 1990 data to one obtained in May 1987 shows that CO 2 concentrations have increased at depths to below 150 m. Based on these profiles, the average rate of CO 2 input to bottom waters was 2.6 × 10 8 mol/a. Increased deep-water temperatures require an average heat flow of 0.32 MW into the hypolimnion over the same time period. The transport rates of CO 2 , heat, and major ions into the hypolimnion suggest that a low-temperature reservoir of free CO 2 exists a short distance below lake bottom and that convective cycling of lake water through the sediments is involved in transporting the CO 2 into the lake from the underlying diatreme. Increased CH 4 concentrations at all depths below the oxycline and a high 14 C content (41% modern) in the CH 4 4 m above lake bottom show that much of the CH 4 is biologically produced within the lake. The CH 4 production rate may vary with time, but if the CO 2 recharge rate remains constant, CO 2 saturation of the entire hypolimnion below 50 m depth would require ∼140a, given present-day concentrations.

Lake Nyos↗

The General Ensemble Biogeochemical Modeling System (GEMS) and its applications to agricultural systems in the United States: Chapter 18

The General Ensemble Biogeochemical Modeling System (GEMS) was es in individual models, it uses multiple site-scale biogeochemical models to perform model simulations. Second, it adopts Monte Carlo ensemble simulations of each simulation unit (one site/pixel or group of sites/pixels with similar biophysical conditions) to incorporate uncertainties and variability (as measured by variances and covariance) of input variables into model simulations. In this chapter, we illustrate the applications of GEMS at the site and regional scales with an emphasis on incorporating agricultural practices. Challenges in modeling soil carbon dynamics and greenhouse emissions are also discussed.

Book chapter↗

Does geomorphology determine vulnerability of mangrove coasts to sea-level rise?

The greatest climate-based threat to coastlines worldwide is sea-level rise. We tested the hypothesis that tropical coasts fringed by mangroves and receiving high inputs of terrigenous sediment are less vulnerable to sea-level rise than biogenic systems dependent upon peat formation for vertical land development. An analysis of published data spanning a range of geomorphic settings showed that mineral accretion was a poor predictor of vulnerability to rising sea level. We additionally compared two oceanic island systems representing two extremes along this sediment gradient to further examine controls on elevation dynamics in minerogenic versus biogenic mangrove systems. Minerogenic systems characterized by intermediate to high rates of mineral sedimentation (Pacific high islands in Micronesia) were not better buffered against sea-level rise because of high subsidence rates. Peat-forming systems (Caribbean low islands in Belize) kept pace with relative sea-level rise (combined ocean and land movements) because of subsurface expansion driven by root matter accumulation. The data were not consistent with the paradigm that tropical coastlines characterized by peat-forming mangroves are generally more vulnerable to sea-level rise compared to minerogenic systems; however, they are not necessarily equally sensitive to the same external and internal forces controlling soil elevations. Our findings demonstrate that reliance on surface accretion data alone can lead to an inaccurate evaluation of coastal vulnerability and why all surface and subsurface land movements must be considered in relation to local sea-level trends to assess risk of submergence. Recognition of such differences is essential to proper management of tropical coastlines to ensure their resilience in the face of future sea-level rise.

Book chapter↗

Hydrology and biogeochemistry linkages

This chapter provides an overview of the linkages between hydrology and biogeochemistry in terrestrial and aquatic systems. Selected topics include hydrological pathways on drainage basin slopes, mountain environments, within-river (or in-stream) processes, wetlands, groundwater (and groundwater–surface water interactions), and lakes. Beginning from catchment headwaters, This chapter introduces mechanisms delivering water from hillslopes to stream channels, highlighting the relative importance of biogeochemical processes along hydrological pathways. It considers processes affecting components of the water budget, including snow formation and ablation processes, and interactions with the soil below snow cover and during snowmelt. It presents the concept of nutrient spiraling and the importance of temperature and stream flow variability on biogeochemistry, as well as groundwater–surface water interactions through hyporheic and riparian zones. This chapter contrasts important processes in hydrologically isolated wetlands with those temporally connected to streams and rivers. It addresses stream and groundwater inputs, stratification, and within-lake processes, interactions with sediments, and a discussion about limiting nutrients. This chapter presents information about typical reactions controlled by hydrological pathways, lithology (mineralogy) and biota, the importance of residence time in biogeochemical evolution, and linkages between groundwater Acidic atmospheric deposition

Book chapter↗

Coastal wetlands: A synthesis

This book and this synthesis address the pressing need for better management of coastal wetlands worldwide because these wetlands are disappearing at an alarming rate; in some countries the loss is 70%–80% in the last 50 years. Managing requires understanding. Although our understanding of the functioning of coastal wetland ecosystems has grown rapidly over the past decade, still much remains to be learned and understood. We have gained insight into the roles of geomorphic processes, hydrologic dynamics, biotic feedback, and disturbance agents in creating and molding a variety of coastal wetland ecosystems across climatic gradients. The variety is expressed not so much in the more obvious differences in vegetation cover, but rather how physical processes both facilitate and constrain a diversity of plant and animal communities. At one level, coastal wetlands are the product of tidal forces and freshwater inputs at the margin of continents. At another level, the plants control the water currents in the tidal creeks draining the wetlands by generating a tidal current asymmetry that controls sediment transport and results in a deep tidal creek surrounded by shallow vegetated wetlands. The vegetation also influences the physics of water and sediment through several other processes including biofilms, bioturbation of sediments, the buffeting of currents and waves, organic enrichment of sediments, and the closing of nutrient cycles. Few ecosystems provide us with so many clear examples of such feedback controls. What we do understand about the structure and functioning of coastal wetlands should provide the theoretical underpinnings for effective management in protecting them for their many contributions to ecosystem goods and services. What we do not understand should compel us to focus our attention and energies toward seeking optimal solutions to some of the most perplexing and urgent problems facing natural resource management.

Book chapter↗

lasertram: A Python library for time resolved analysis of laser ablation inductively coupled plasma mass spectrometry data

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) data has a wide variety of uses in the geosciences for in-situ chemical analysis of complex natural materials. Improvements to instrument capabilities and operating software have drastically reduced the time required to generate large volumes of data relative to previous methodologies. Raw data from LA-ICP-MS, however, is in counts per unit time (typically counts per second), not elemental concentrations and converting these count ratesto concentrations requires additional processing. For complex materials where the ablated volume may contain a range of material compositions, a moderate amount of user input is also required if appropriate concentrations are to be accurately calculated. In geologic materials such as glasses and minerals that potentially have numerous heterogeneities (e.g., microlites or other inclusions) within them, this is typically determiningwhether the total ablation signal should be filtered to remove these heterogeneities. This necessitates that the LA-ICP-MS data processing pipeline is one that is not automated, but is also designed to enable rapid and efficient processing of large volumes of data. Here we introduce , a Python library for the time resolved analysis of LA-ICP-MS data. We outline its mathematical theory, code structure, and provide an example of how it can be used to provide the time resolved analysis necessitated by LA-ICP-MS data of complex geologic materials. Throughout the pipeline we show how metadata and data are incrementally added to the objects created such that virtually any aspect of an experiment may be interrogated and its quality assessed. We also show, that when combined with other Python libraries for building graphical user interfaces, it can be utilized outside of a pure scripting environment. can be found at https://doi.org/10.5066/P1DZUR3Z

Applied Computing and Geosciences↗

Statistical approaches for modeling correlated grade and tonnage distributions and applications for mineral resource assessments

Correlations between grade and tonnage exist in mineral resource data compiled from published reports, but they are not always addressed during quantitative assessment of undiscovered mineral resources. Failure to account for correlated grade and tonnage distributions can result in geologically unrealistic assessment results. Current software tools simulate univariate ore tonnage and multivariate resource grades of undiscovered deposits independently. As a result, analysts are forced to rely on ad-hoc solutions to minimize the correlation issues by: 1) creating subsets of data with restricted criteria; 2) truncating grade and tonnage distributions; and 3) testing model robustness using exploratory data analysis. While these methods represent pragmatic solutions, the statistical solutions presented here provide additional options to address real correlations in grade and tonnage data used for mineral resource assessments. We present a modified version of the MapMark4 package in R that introduces two alternatives for modeling grade and tonnage distributions, consisting of a multivariate solution that accounts for correlations between ore tonnage and metal grades and an empirical solution that utilizes simple random sampling with replacement to reproduce coupled grades and tonnages from the input data. We present simulations for contained ore and metal for three case studies representing tungsten skarn, komatiite-hosted nickel, and sediment-hosted carbonate amagmatic zinc-lead (Mississippi Valley-type) deposits. Employing the methods presented here yields quantitative mineral resource assessment results that more closely reflect the empirical distributions of grades and tonnages observed in nature and expands the applicability of these tools for ongoing critical mineral resource assessments.

Applied Computing and Geosciences↗

Extracting data from maps: Lessons learned from the artificial intelligence for critical mineral assessment competition

The U.S. Geological Survey (USGS), Defense Advanced Projects Research Agency (DARPA), NASA Jet Propulsion Laboratory (JPL), and MITRE ran a 12-week machine learning competition aimed at accelerating development of AI tools for critical mineral assessments. The Artificial Intelligence for Critical Mineral Assessment Competition solicited innovative solutions for two challenges: 1) automated georeferencing of historical maps, and 2) automated feature extraction from historical maps. Competitors used a new dataset of historical map images to train, validate, and evaluate their models. Automated georeferencing pipelines attained a median root-mean square error of 1.1 km. Prompt-based extraction (i.e., with user input) of polygons, polylines, and points from geologic maps yielded median F1-scores of 0.77, 0.56, 0.35, respectively. Geologic maps pose numerous challenges for AI workflows because they vary significantly. However, despite its short duration, the competition yielded promising results that have since spurred further innovation in this area and led to the development of new AI tools to semi-automate key, time-consuming parts of the assessment workflow.

Applied Computing and Geosciences↗