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USGS2012

Persistence of soil organic matter in eroding versus depositional landform positions

Soil organic matter (SOM) processes in dynamic landscapes are strongly influenced by soil erosion and sedimentation. We determined the contribution of physical isolation of organic matter (OM) inside aggregates, chemical interaction of OM with soil minerals, and molecular structure of SOM in controlling storage and persistence of SOM in different types of eroding and depositional landform positions. By combining density fractionation with elemental and spectroscopic analyses, we showed that SOM in depositional settings is less transformed and better preserved than SOM in eroding landform positions. However, which environmental factors exert primary control on storage and persistence of SOM depended on the nature of the landform position considered. In an annual grassland watershed, protection of SOM by physical isolation inside aggregates and chemical association of organic matter (complexation) with soil minerals, as assessed by correlation with radiocarbon concentration, were more effective in the poorly drained, lowest-lying depositional landform positions, compared to well-drained landform positions in the upper parts of the watershed. Results of this study demonstrated that processes of soil erosion and deposition are important mechanisms of long-term OM stabilization.

Journal of Geophysical Research: Biogeosciences↗

USGS2010

Multiobjective sampling design for parameter estimation and model discrimination in groundwater solute transport

Sampling design for site characterization studies of solute transport in porous media is formulated as a multiobjective problem. Optimal design of a sampling network is a sequential process in which the next phase of sampling is designed on the basis of all available physical knowledge of the system. Three objectives are considered: model discrimination, parameter estimation, and cost minimization. For the first two objectives, physically based measures of the value of information obtained from a set of observations are specified. In model discrimination, value of information of an observation point is measured in terms of the difference in solute concentration predicted by hypothesized models of transport. Points of greatest difference in predictions can contribute the most information to the discriminatory power of a sampling design. Sensitivity of solute concentration to a change in a parameter contributes information on the relative variance of a parameter estimate. Inclusion of points in a sampling design with high sensitivities to parameters tends to reduce variance in parameter estimates. Cost minimization accounts for both the capital cost of well installation and the operating costs of collection and analysis of field samples. Sensitivities, discrimination information, and well installation and sampling costs are used to form coefficients in the multiobjective problem in which the decision variables are binary (zero/one), each corresponding to the selection of an observation point in time and space. The solution to the multiobjective problem is a noninferior set of designs. To gain insight into effective design strategies, a one-dimensional solute transport problem is hypothesized. Then, an approximation of the noninferior set is found by enumerating 120 designs and evaluating objective functions for each of the designs. Trade-offs between pairs of objectives are demonstrated among the models. The value of an objective function for a given design is shown to correspond to the ability of a design to actually meet an objective.

Water Resources Research↗

USGS1992

Effects of acidic deposition on the erosion of carbonate stone - experimental results from the U.S. National Acid Precipitation Assessment Program (NAPAP)

One of the goals of NAPAP-sponsored research on the effects of acidic deposition on carbonate stone has been to quantify the incremental effects of wet and dry deposition of hydrogen ion, sulfur dioxide and nitrogen oxides on stone erosion. Test briquettes and slabs of freshly quarried Indiana limestone and Vermont marble have been exposed to ambient environmental conditions in a long-term exposure program. Physical measurements of the recession of test stones exposed to ambient conditions at an angle of 30?? to horizontal at the five NAPAP materials exposure sites range from ~15 to ~30?? ??m yr-1 for marble, and from ~25 to ~45 ??m yr -1 for limestone, and are approximately double the recession estimates based on the observed calcium content of run-off solutions from test slabs. The difference between the physical and chemical recession measurements is attributed to the loss of mineral grains from the stone surfaces that are not measured in the run-off experiments. The erosion due to grain loss does not appear to be influenced by rainfall acidity, however, preliminary evidence suggests that grain loss may be influenced by dry deposition of sulfur dioxide between rainfall events. Chemical analyses of the run-off solutions and associated rainfall blanks suggest that ~30% of erosion by dissolution can be attributed to the wet deposition of hydrogen ion and the dry deposition of sulfur dioxide and nitric acid between rain events. The remaining ~70% of erosion by dissolution is accounted for by the solubility of carbonate stone in rain that is in equilibrium with atmospheric carbon dioxide ('clean rain'). These results are for marble and limestone slabs exposed at an angle of 30?? from horizontal. The relative contribution of sulfur dioxide to chemical erosion is significantly enhanced for stone slabs having an inclination of 60?? or 85??. The dry deposition of alkaline particulate material has a mitigating effect at the two urban field exposure sites at Washington, DC, and Steubenville, OH.

Conference Paper↗

USGS2019

Case studies in groundwater contaminant fate and transport

A case study of groundwater contamination is a detailed study of a single site contaminated with a chemical or mixture that is known to be a problem at many sites. The goal of case studies is to provide insights into the physical, chemical, and biological processes controlling migration, natural attenuation, or remediation of common groundwater contaminants. Ideally, processes occurring at a case study site are representative of other sites so that knowledge gained from these intensive studies can be applied at thousands of sites where fewer data are available. Several characteristics of case studies contribute to their value. First, they may have tens to hundreds of monitoring wells, compared to fewer than ten wells at some contaminated sites. Second, some case studies continue for many years or even decades, providing insights into temporal progression of slow processes. Third, analytical methods prohibitively expensive for routine use or under development may be tested at case study sites. Finally, the ongoing characterization typical of case study sites builds a foundation of knowledge that facilitates sophisticated experimental design and testing of new methods. This article is divided into sections based on the contaminant type because the chemical and biological processes required for remediation vary for each contaminant. Most importantly, some contaminants can be biodegraded whereas metals and radionuclides cannot be destroyed but can be immobilized or rendered less toxic. The emphasis is on case studies of natural processes that control the fate and transport of contaminants in groundwater rather than on active remediation methods. The principles learned from these studies may form the basis for design of remedial strategies. The organic contaminants are divided into: petroleum hydrocarbons, fuel oxygenates, coal tar and wastes from manufactured gas plants, and chlorinated solvents. The inorganic contaminants covered are metals and radionuclides, arsenic, and nitrate. Case studies of mixed waste plumes from landfills are also described. Experimental sites where contaminants have been introduced into an aquifer as an emplaced source or a controlled release may not meet the above definition of case studies, but some are included because the overall goal is to impart lessons learned from detailed field studies. It is impossible to cover all case studies in this short format. Conversely, focusing on one or two does not convey the breadth of research results in entire range of case studies. Instead, the strategy is to describe the evolution of knowledge for each contaminant class while providing citations of relevant case studies. Much of the progress in understanding of the fate of contaminants in groundwater is based on laboratory studies; thus whenever possible, papers that included both field and laboratory results have been included among the citations. Two topics of growing importance have not been covered. These are the fate of pharmaceuticals in groundwater and discharge of contaminant plumes to surface water. These topics merit coverage in the future as knowledge grows and case studies increase in number.

Environmental Science↗

USGS2020

Inventory and analysis of groundwater resources: Theodore Roosevelt National Park, North Dakota

Industrial and commercial developments in western North Dakota potentially could affect the sources of water that contribute to wells, spring flow, and seeps within Theodore Roosevelt National Park. Without basic water resources data, accurately predicting the effects of water withdrawals and water quality concerns related to industrial and commercial developments near the park would be challenging. Water resources in the park include surface water and groundwater. The Little Missouri River and its tributaries cross all three Theodore Roosevelt National Park units and are the primary surface-water features in the park. Groundwater resources include well discharges, springs, and seeps. The geology and hydrogeology of Theodore Roosevelt National Park are defined by the surrounding Williston Basin. Four aquifers are sources of groundwater to the park: unconsolidated aquifers including alluvial systems, the upper Fort Union aquifer, the lower Fort Union aquifer, and the Fox Hills-lower Hell Creek aquifer. Data used for wells, springs, seeps, and water quality in this report were compiled from the U.S. Geological Survey National Water Information System or from the North Dakota State Water Commission. An inventory of 16 wells was completed for sites within the boundaries of the park. In addition to well data, an inventory of 11 springs and seeps was completed. The groundwater-quality analysis had two objectives: (1) to characterize the groundwater chemistry in aquifers underlying the park and (2) to spatially map selected physical properties and chemical constituents of interest. Groundwater-quality data from the North Dakota State Water Commission were summarized, mapped, and used to characterize groundwater for each aquifer in the study area. Spatial concentration distribution maps were constructed for selected physical properties and chemical constituents using summary statistics and exceedances. Piper diagrams were used to classify and characterize groundwater for each aquifer. Future research to help fill data gaps in water resources information for Theodore Roosevelt National Park, including recommendations from previous studies, consists of the following: (1) evaluating the variability in discharge from springs and seeps in comparison to changes in precipitation or other recharge sources, (2) evaluating flow control measures for flowing artesian wells, (3) completing a water rights review, and (4) performing routine water-quality monitoring for wells and springs.

North Dakota↗

USGS2010

Modeling hexavalent chromium reduction in groundwater in field-scale transport and laboratory batch experiments

A plausible and consistent model is developed to obtain a quantitative description of the gradual disappearance of hexavalent chromium (Cr(VI)) from groundwater in a small-scale field tracer test and in batch kinetic experiments using aquifer sediments under similar chemical conditions. The data exhibit three distinct timescales. Fast reduction occurs in well-stirred batch reactors in times much less than 1 hour and is followed by slow reduction over a timescale of the order of 2 days. In the field, reduction occurs on a timescale of the order of 8 days. The model is based on the following hypotheses. The chemical reduction reaction occurs very fast, and the longer timescales are caused by diffusion resistance. Diffusion into the secondary porosity of grains causes the apparent slow reduction rate in batch experiments. In the model of the field experiments, the reducing agent, heavy Fe(II)-bearing minerals, is heterogeneously distributed in thin strata located between larger nonreducing sand lenses that comprise the bulk of the aquifer solids. It is found that reducing strata of the order of centimeters thick are sufficient to contribute enough diffusion resistance to cause the observed longest timescale in the field. A one-dimensional advection/dispersion model is formulated that describes the major experimental trends. Diffusion rates are estimated in terms of an elementary physical picture of flow through a stratified medium containing identically sized spherical grains. Both reduction and sorption reactions are included. Batch simulation results are sensitive to the fraction of reductant located at or near the surface of grains, which controls the amount of rapid reduction, and the secondary porosity, which controls the rate of slow reduction observed in batch experiments. Results of Cr(VI) transport simulations are sensitive to the thickness and relative size of the reducing stratum. Transport simulation results suggest that nearly all of the reductant must be located in the reducing stratum. Within this context and as long as there is adequate reductive capacity present, the transport simulation results are insensitive to the parameters important for the batch simulations. The results illustrate how a combination of field measurements and batch laboratory studies can be used to improve predictive modeling of contaminant transport.

Water Resources Research↗

USGS2010

Hydrology of the North Cascades region, Washington: 2. A proposed hydrometeorological streamflow prediction method

On the basis of a linear relationship between winter (October-April) precipitation and annual runoff from a drainage basin (Rasmussen and Tangborn, 1976) a physically reasonable model for predicting summer (May-September) streamflow from drainages in the North Cascades region was developed. This hydrometeorological prediction method relates streamflow for a season beginning on the day of prediction to the storage (including snow, ice, soil moisture, and groundwater) on that day. The spring storage is inferred from an input-output relationship based on the principle of conservation of mass: spring storage equals winter precipitation on the basin less winter runoff from the basin and less winter evapotranspiration, which is presumed to be small. The method of prediction is based on data only from the years previous to the one for which the prediction is made, and the system is revised each year as data for the previous year become available. To improve the basin storage estimate made in late winter or early spring, a short-season runoff prediction is made. The errors resulting from this short-term prediction are used to revise the storage estimate and improve the later prediction. This considerably improves the accuracy of the later prediction, especially for periods early in the summer runoff season. The optimum length for the test period appears to be generally less than a month for east side basins and between 1 and 2 months for those on the west side of the Cascade Range. The time distribution of the total summer runoff can be predicted when this test season is used so that on May 1 monthly streamflow for the May-September season can be predicted. It was found that summer precipitation and the time of minimum storage are two error sources that were amenable to analysis. For streamflow predictions in seasons beginning in early spring the deviation of the subsequent summer precipitation from a long-period average will contribute up to 53% of the prediction error. This contribution decreases to nearly zero during the summer and then rises slightly for late summer predictions. The reason for the smaller than expected effect of summer precipitation is thought to be due to the compensating effect of increased evaporative losses and increased infiltration when precipitation is greater than normal during the summer months. The error caused by the beginning winter month (assumed to be October in this study) not coinciding with the time of minimum storage was examined; it appears that October may be the best average beginning winter month for most drainages but that a more detailed study is needed. The optimum beginning of the winter season appears to vary from August to October when individual years are examined. These results demonstrate that standard precipitation and runoff measurements in the North Cascades region are adequate for constructing a predictive hydrologic model. This model can be used to make streamflow predictions that compare favorably with current multiple regression methods based on mountain snow surveys. This method has the added advantages of predicting the space and time distributions of storage and summer runoff.

Washington↗

USGS2021

Paleozoic and Mesozoic tectonic events west of the Waterbury Dome: Results of new mapping in the western Connecticut Highlands

This field trip highlights the results of recent U.S. Geological Survey (USGS) bedrock geologic mapping in four 7.5 min quadrangles in the western Connecticut highlands near Southbury, Connecticut, USA. The rocks are broadly within what Rodgers (1985) called the Hartland and Gneiss Dome belts of the Connecticut Valley Synclinorium ( Rodgers, 1985 ; Fig. 1 ), the latter of which is now known as the Connecticut Valley–Gaspe Trough (Hibbard et al., 2006). The mapping occurred over two intervals: 2003–2005 and 2016–present. In the first, the goal was a detailed map of the early Mesozoic Pomperaug basin, which overlaps the four quadrangles. Portions of the basin had been separately mapped during the statewide 7.5 min quadrangle mapping campaign spanning the 1950s–1970s, resulting in an inaccurate depiction of the basin on the 1985 state geologic map ( Rodgers, 1985 ). A new map of the basin was proposed in part to benefit an ongoing project by the USGS Connecticut Water Science Center to determine the contributions of natural and artificial contaminants to a public water-supply well in Woodbury, Connecticut, under the National Water-Quality Assessment (NAWQA) Program ( Starn and Brown, 2007) . The NAWQA project was partially funded by the Pomperaug River Watershed Coalition, which also provided logistical support to the geologic mapping project. Mapping of the basin was also a high priority for the Connecticut State Geologist at the time (Ralph Lewis, 2002, pers. comm.). The mapping resulted in an NEIGC (New England Intercollegiate Geologic Conference) field guide ( Burton et al., 2005) and a 1:12,000-scale USGS open-file map ( Burton, 2006) and was funded by the USGS National Cooperative Geologic Mapping Program (NCGMP). The second phase of the mapping began in 2016 after the discovery of elevated levels of uranium and arsenic in domestic water wells in the igneous and metamorphic rocks that surround the sedimentary and volcanic rocks of the Pomperaug basin ( Flanagan and Brown, 2017) . Structural measurements in the surrounding crystalline rocks were made during Pomperaug basin mapping to better understand the tectonic setting, but a revision of the crystalline map units on Rodgers’ 1985 geologic map was not attempted. Nonetheless, discrepancies were noted between the new mapping and the 1985 map, particularly within the two northern quadrangles of Woodbury and Roxbury, which were originally mapped by Gates (1954) and Gates (1959) , respectively. Based on these discrepancies, a new NCGMP project was proposed to remap the Woodbury and Roxbury 7.5 min quadrangles, commencing in the fall of 2016. The expected USGS product will be a two-quadrangle, 1:24,000-scale Scientific Investigations Map (SIM). This field guide is not meant as a comprehensive review of all of the geologic research done in this area of Connecticut; rather, it looks at previous bedrock geologic mapping from the perspective of new and recent mapping in the four-quadrangle area and discusses the structural, stratigraphic, and nomenclatural revisions necessary for the next revision of the state geologic map.

Connecticut↗

USGS2010

An initial SPARROW model of land use and in-stream controls on total organic carbon in streams of the conterminous United States

Watersheds play many important roles in the carbon cycle: (1) they are a site for both terrestrial and aquatic carbon dioxide (CO2) removal through photosynthesis; (2) they transport living and decomposing organic carbon in streams and groundwater; and (3) they store organic carbon for widely varying lengths of time as a function of many biogeochemical factors. Using the U.S. Geological Survey (USGS) Spatially Referenced Regression on Watershed Attributes (SPARROW) model, along with long-term monitoring data on total organic carbon (TOC), this research quantitatively estimates the sources, transport, and fate of the long-term mean annual load of TOC in streams of the conterminous United States. The model simulations use surrogate measures of the major terrestrial and aquatic sources of organic carbon to estimate the long-term mean annual load of TOC in streams. The estimated carbon sources in the model are associated with four land uses (urban, cultivated, forest, and wetlands) and autochthonous fixation of carbon (stream photosynthesis). Stream photosynthesis is determined by reach-level application of an empirical model of stream chlorophyll based on total phosphorus concentration, and a mechanistic model of photosynthetic rate based on chlorophyll, average daily solar irradiance, water column light attenuation, and reach dimensions. It was found that the estimate of in-stream photosynthesis is a major contributor to the mean annual TOC load per unit of drainage area (that is, yield) in large streams, with a median share of about 60 percent of the total mean annual carbon load in streams with mean flows above 500 cubic feet per second. The interquartile range of the model predictions of TOC from in-stream photosynthesis is from 0.1 to 0.4 grams (g) carbon (C) per square meter (m-2) per day (day-1) for the approximately 62,000 stream reaches in the continental United States, which compares favorably with the reported literature range for net carbon fixation by phytoplankton in lakes and streams. The largest contributors per unit of drainage area to the mean annual stream TOC load among the terrestrial sources are, in descending order: wetlands, urban lands, mixed forests, agricultural lands, evergreen forests, and deciduous forests . It was found that the SPARROW model estimates of TOC contributions to streams associated with these land uses are also consistent with literature estimates. SPARROW model calibration results are used to simulate the delivery of TOC loads to the coastal areas of seven major regional drainages. It was found that stream photosynthesis is the largest source of the TOC yields ( about 50 percent) delivered to the coastal waters in two of the seven regional drainages (the Pacific Northwest and Mississippi-Atchafalaya-Red River basins ), whereas terrestrial sources are dominant (greater than 60 percent) in all other regions (North Atlantic, South Atlantic-Gulf, California, Texas-Gulf, and Great Lakes).

Conterminous United States↗

USGS2022

Submarine landslide susceptibility mapping in recently deglaciated terrain, Glacier Bay, Alaska

Submarine mass wasting events have damaged underwater structures and propagated waves that have inundated towns and affected human populations in nearby coastal areas. Susceptibility to submarine landslides can be pronounced in degrading cryospheric environments, where existing glaciers can provide high volumes of sediment, while cycles of glaciation and ice-loss can damage and destabilize slopes. Despite their contribution to potential tsunami hazard, submarine landslides can be difficult to study because of limited access and data collection in underwater environments. Here we present a method to quantify and map the submarine landslide susceptibility of sediment-covered slopes in Glacier Bay, Glacier Bay National Park and Preserve, Alaska, using multibeam-sonar bathymetric digital elevation models (DEMs) and historical maps of glacial extents over the last ∼250 years. After mapping an inventory of >7,000 landslide scarps in submarine sediments, we filtered the inventory by size to account for limitations in DEM resolution and spatial scales relevant to tsunami hazards. We then assessed landslide concentration, accounting for the age of the initial exposure of submarine slopes by deglaciation. We found a positive correlation between landslide concentration and deglaciation age, which we interpreted as a mean landslide accumulation rate over the period of record. Local deviations from this rate indicated differences in susceptibility. Additionally, we accounted for some of the effect of material and morphometric properties by estimating the submarine bedrock-sediment distribution using a morphometric model and assessing the relationship between slope angle and landslide incidence. Finally, we supplemented our susceptibility assessment with a geomorphic component based on the propensity of active submarine fans and deltas to produce landslides. Thus, our map of submarine landslide susceptibility incorporates three components: age-adjusted landslide concentration, slope angle, and geomorphology. We find that areas of mapped high susceptibility correlate broadly with areas of high sediment input and availability, locations of fans and deltas, and steep sediment-covered glacially carved fjords and troughs. Areas of high submarine landslide susceptibility in Glacier Bay moderately correspond with locations of known high-hazard subaerial slopes, but more research on submarine and subaerial landslides in degrading cryospheric environments would be beneficial to better understand landslide and tsunami hazards.

Alaska↗

USGS2019

Evaluation of multiple laboratory performance and variability in analysis of recreational freshwaters by a rapid Escherichia coli qPCR method (Draft Method C)

There is interest in the application of rapid quantitative polymerase chain reaction (qPCR) methods for recreational freshwater quality monitoring of the fecal indicator bacteria Escherichia coli ( E. coli ). In this study we determined the performance of 21 laboratories in meeting proposed, standardized data quality acceptance (QA) criteria and the variability of target gene copy estimates from these laboratories in analyses of 18 shared surface water samples by a draft qPCR method developed by the U.S. Environmental Protection Agency (EPA) for E. coli . The participating laboratories ranged from academic and government laboratories with more extensive qPCR experience to “new” water quality and public health laboratories with relatively little previous experience in most cases. Failures to meet QA criteria for the method were observed in 24% of the total 376 test sample analyses. Of these failures, 39% came from two of the “new” laboratories. Likely factors contributing to QA failures included deviations in recommended procedures for the storage and preparation of reference and control materials. A master standard curve calibration model was also found to give lower overall variability in log 10 target gene copy estimates than the delta-delta Ct (ΔΔCt) calibration model used in previous EPA qPCR methods. However, differences between the mean estimates from the two models were not significant and variability between laboratories was the greatest contributor to overall method variability in either case. Study findings demonstrate the technical feasibility of multiple laboratories implementing this or other qPCR water quality monitoring methods with similar data quality acceptance criteria but suggest that additional practice and/or assistance may be valuable, even for some more generally experienced qPCR laboratories. Special attention should be placed on providing and following explicit guidance on the preparation, storage and handling of reference and control materials.

Water Research↗

USGS2016

Comparative use of side and main channels by small-bodied fish in a large, unimpounded river

Ecological theory and field studies suggest that lateral floodplain connectivity and habitat heterogeneity provided by side channels impart favourable habitat conditions for lotic fishes, especially fluvial fishes dependent on large patches of shallow, slow velocity habitats for some portion of their life cycle. However, anthropogenic modification of large, temperate floodplain rivers has led to extensive channel simplification and side-channel loss. Highly modified rivers consist of simplified channels in contracted, less dynamic floodplains. Most research examining the seasonal importance of side channels for fish assemblages in large rivers has been carried out in heavily modified rivers, where side-channel extents are substantially reduced from pre-settlement times, and has often overlooked small-bodied fishes. Inferences about the ecological importance of side channels for small-bodied fishes in large rivers can be ascertained only from investigations of large rivers with largely intact floodplains. The Yellowstone River, our study area, is a rare example of one such river. We targeted small-bodied fishes and compared their habitat use in side and main channels in two geomorphically distinct types of river bends during early and late snowmelt runoff, and autumn base flow. Species compositions of side and main channels differed throughout hydroperiods concurrent with the seasonal redistribution of the availability of shallow, slow current-velocity habitats. More species of fish used side channels than main channels during runoff. Additionally, catch rates of small fishes were generally greater in side channels than in main channels and quantitative assemblage compositions differed between channel types during runoff, but not during base flow. Presence of and access to diverse habitats facilitated the development and persistence of diverse fish assemblages in our study area. Physical dissimilarities between side and main channels may have differentially structured the side- and main-channel fish assemblages during runoff. Patches of shallow, slow current-velocity (SSCV) habitats in side channels were larger and had slightly slower water velocities than SSCV habitat patches in main channels during runoff, but not during base flow. Our findings establish a baseline importance of side channels to riverine fishes in a large, temperate river without heavy anthropogenic modification. Establishing this baseline contributes to basic fluvial ecology and provides empirical justification for restoration efforts that reconnect large rivers with their floodplains.

Montana↗

USGS2011

Hydrological mobilization of mercury and dissolved organic carbon in a snow-dominated, forested watershed: Conceptualization and modeling

The mobilization of mercury and dissolved organic carbon (DOC) during snowmelt often accounts for a major fraction of the annual loads. We studied the role of hydrological connectivity of riparian wetlands and upland/wetland transition zones to surface waters on the mobilization of Hg and DOC in Fishing Brook, a headwater of the Adirondack Mountains, New York. Stream water total mercury (THg) concentrations varied strongly (mean = 2.25 ± 0.5 ng L −1 ), and the two snowmelt seasons contributed 40% (2007) and 48% (2008) of the annual load. Methyl mercury (MeHg) concentrations ranged up to 0.26 ng L −1 , and showed an inverse log relationship with discharge. TOPMODEL‐simulated saturated area corresponded well with wetland areas, and the application of a flow algorithm based elevation‐above‐creek approach suggests that most wetlands become well connected during high flow. The dynamics of simulated saturated area and soil storage deficit were able to explain a large part of the variation of THg concentrations (r 2 = 0.53 to 0.72). In contrast, the simulations were not able to explain DOC variations and DOC and THg concentrations were not correlated. These results indicate that all three constituents, THg, MeHg, and DOC, follow different patterns at the outlet: (1) the mobilization of THg is primarily controlled by the saturation state of the catchment, (2) the dilution of MeHg suggests flushing from a supply limited pool, and (3) DOC dynamics follow a pattern different from THg dynamics, which likely results from differing gain and/or loss processes for THg and/or DOC within the Fishing Brook catchment.

New York↗

USGS2025

Predation of Lost River and Shortnose Suckers by piscivorous colonial waterbirds in the Upper Klamath Basin: An analysis of predation effects in 2024

The recovery of endangered fish requires an understanding of the sources of mortality that regulate population dynamics. We estimated avian predation rates on passive integrated transponder tagged (PIT) adult and juvenile Lost River Suckers ( Deltistes luxatus ), Shortnose Suckers ( Chasmistes brevirostris ), Klamath Largescale Suckers ( C. snyderi ), and juvenile Chinook Salmon ( Oncorhynchus tshawytscha ) by breeding colonies of American White Pelicans ( Pelecanus erythrorhynchos ), Doublecrested Cormorants ( Nannopterum auritum ), Caspian Terns ( Hydroprogne caspia ), California Gulls ( Larus californicus ), Ring-billed Gulls ( L. delawarensis ), Great Blue Herons ( Ardea herodias ), Great Egrets ( A. alba ), and Black-crowned Night Herons ( Nycticorax nycticorax ) in the Upper Klamath Basin (UKB) in 2024. Results from 2024 contribute to a long-term (2009–2023) avian predation dataset in the UKB. The largest numbers of pelicans (1,422 breeding adults), terns (610 adults), and gulls (3,872) were nesting on islands in Clear Lake Reservoir. The largest number of cormorants (787 adults) were on an island in Sheepy Lake, and the largest numbers of herons (450 adults) were at arboreal sites adjacent to Upper Klamath Lake. Predation rate estimates in 2024 were highly variable depending on the fish species, ageclass (juvenile, adult), waterbody (Upper Klamath Lake, Clear Lake Reservoir, Sheepy Lake, Tule Lake), and release or reencounter date for juveniles (spring/summer or fall/winter). Results indicated that avian predation rates were the highest on wild and hatchery juvenile suckers. An estimated 19.4% (95% credible interval = 15.7–24.0) of Sucker Assisted Rearing Program (SARP) hatchery fish, released or reencountered during the spring and summer, were consumed by the colonies included in the study. Predation was also appreciable on wild juvenile suckers in Clear Lake Reservoir (13.4% [9.9–17.7]) and SARP juvenile suckers released or reencountered in Upper Klamath Lake in the fall/winter (11.2% [9.6 13.2]). Predation rate estimates on adult suckers were significantly lower than those of juvenile suckers, with predation ranging from 0.3% (0.2–0.7) to 2.6% (1.9–3.5) in adult Lost River Suckers in Upper Klamath Lake and adult Shortnose Suckers-Klamath Largescale Suckers in Clear Lake Reservoir, respectively. Predation rate estimates on juvenile Chinook Salmon, which were released in fall/winter, were 2.9% (2.2–3.6). Pelican (312 adults) and cormorant (301 adults) colonies in Upper Klamath Lake, however, were not scanned for fish PIT tags following breeding season, resulting in minimum estimates of predation on UKB fishes (both suckers and Chinook Salmon) in 2024. Future research could examine what biotic and abiotic factors best explain variation in predation and to what degree predation limits sucker survival using the long-term dataset that has been complied to date.

California, Oregon↗

USGS2009

Using nitrate dual isotopic composition (δ15N and δ18O) as a tool for exploring sources and cycling of nitrate in an estuarine system: Elkhorn Slough, California

Nitrate (NO 3 − ) concentrations and dual isotopic composition ( δ 15 N and δ 18 O) were measured during various seasons and tidal conditions in Elkhorn Slough to evaluate mixing of sources of NO 3 − within this California estuary. We found the isotopic composition of NO 3 − was influenced most heavily by mixing of two primary sources with unique isotopic signatures, a marine (Monterey Bay) and terrestrial agricultural runoff source (Old Salinas River). However, our attempt to use a simple two end‐member mixing model to calculate the relative contribution of these two NO 3 − sources to the Slough was complicated by periods of nonconservative behavior and/or the presence of additional sources, particularly during the dry season when NO 3 − concentrations were low. Although multiple linear regression generally yielded good fits to the observed data, deviations from conservative mixing were still evident. After consideration of potential alternative sources, we concluded that deviations from two end‐member mixing were most likely derived from interactions with marsh sediments in regions of the Slough where high rates of NO 3 − uptake and nitrification result in NO 3 − with low δ 15 N and high δ 18 O values. A simple steady state dual isotope model is used to illustrate the impact of cycling processes in an estuarine setting which may play a primary role in controlling NO 3 − isotopic composition when and where cycling rates and water residence times are high. This work expands our understanding of nitrogen and oxygen isotopes as biogeochemical tools for investigating NO 3 − sources and cycling in estuaries, emphasizing the role that cycling processes may play in altering isotopic composition.

California↗

USGS1997

Wetland losses related to fault movement and hydrocarbon production, southeastern Texas coast

Time series analyses of surface fault activity and nearby hydrocarbon production from the southeastern Texas coast show a high correlation among volume of produced fluids, timing of fault activation, rates of subsidence, and rates of wetland loss. Greater subsidence on the downthrown sides of faults contributes to more frequent flooding and generally wetter conditions, which are commonly reflected by changes in plant communities {e.g., Spartina patens to Spartina alterniflora) or progressive transformation of emergent vegetation to open water. Since the 1930s and 1950s, approximately 5,000 hectares of marsh habitat has been lost as a result of subsidence associated with faulting. Marsh- es have expanded locally along faults where hydrophytic vegetation has spread into former upland areas. Fault traces are linear to curvilinear and are visible because elevation differences across faults alter soil hydrology and vegetation. Fault lengths range from 1 to 13.4 km and average 3.8 km. Seventy-five percent of the faults visible on recent aerial photographs are not visible on photographs taken in the 1930's, indicating relatively recent fault movement. At least 80% of the surface faults correlate with extrapolated subsurface faults; the correlation increases to more than 90% when certain assumptions are made to compensate for mismatches in direction of displacement. Coastal wetlands loss in Texas associated with hydrocarbon extraction will likely increase where production in mature fields is prolonged without fiuid reinjection.

Texas↗

USGS2014

Understanding the hydrologic sources and sinks in the Nile Basin using multisource climate and remote sensing data sets

In this study, we integrated satellite-drived precipitation and modeled evapotranspiration data (2000–2012) to describe spatial variability of hydrologic sources and sinks in the Nile Basin. Over 2000–2012 period, 4 out of 11 countries (Ethiopia, Tanzania, Kenya, and Uganda) in the Nile Basin showed a positive water balance while three downstream countries (South Sudan, Sudan, and Egypt) showed a negative balance. Gravity Recovery and Climate Experiment (GRACE) mass deviation in storage data analysis showed that at annual timescales, the Nile Basin storage change is substantial while over longer time periods, it is minimal (<1% of basin precipitation). We also used long-term gridded runoff and river discharge data (1869–1984) to understand the discrepancy in the observed and expected flow along the Nile River. The top three countries that contribute most to the flow are Ethiopia, Tanzania, and Kenya. The study revealed that ∼85% of the runoff generated in the equatorial region is lost in an interstation basin that includes the Sudd wetlands in South Sudan; this proportion is higher than the literature reported loss of 50% at the Sudd wetlands alone. The loss in runoff and flow volume at different sections of the river tend to be more than what can be explained by evaporation losses, suggesting a potential recharge to deeper aquifers that are not connected to the Nile channel systems. On the other hand, we also found that the expected average annual Nile flow at Aswan is greater (97 km 3 ) than the reported amount (84 km 3 ). Due to the large variations of the reported Nile flow at different locations and time periods, the study results indicate the need for increased hydrometeorological instrumentation of the basin. The study also helped improve our understanding of the spatial dynamics of water sources and sinks in the Nile Basin and identified emerging hydrologic questions that require further attention.

Water Resources Research↗

USGS1996

An 84-kyr paleomagnetic record from the sediments of Lake Baikal, Siberia

We have conducted a paleomagnetic study of sediment cores obtained from the Selenga prodelta region of Lake Baikal, Russia. This record, which spans approximately the last 84 kyr, contributes to a better understanding of the nature of geomagnetic field behavior in Siberia and is a useful correlation and dating tool. We demonstrate that the Lake Baikal sediments are recording variations in the geomagnetic field. The directional record displays secular variation behavior with a geomagnetic excursion at 20 ka and additional excursions appearing as large-amplitude secular variation at 41, 61, and 67 ka. Smoothing of the geomagnetic excursion behavior occurs in Lake Baikal sediments owing to the intermediate sedimentation rate (13 cm kyr −1 ). The Lake Baikal relative paleointensity record correlates to absolute paleointensity data for the last 10 kyr and to relative paleointensity records from the Mediterranean Sea and Indian Ocean for the last 84 kyr. This correlation suggests a strong global (i.e., dipole) component to these records and further supports the reliability of sediments as recorders of relative geomagnetic paleointensity. We show that a relative geomagnetic intensity stratigraphy has a potential resolution of 7 kyr by correlating continental and marine records. The geomagnetic intensity stratigraphy helps constrain the age of the difficult to date Lake Baikal sediments.

Journal of Geophysical Research B: Solid Earth↗