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Status of groundwater quality in the Santa Barbara Study Unit, 2011: California GAMA Priority Basin Project

Groundwater quality in the 48-square-mile Santa Barbara study unit was investigated in 2011 as part of the California State Water Resources Control Board’s Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. The study unit is mostly in Santa Barbara County and is in the Transverse and Selected Peninsular Ranges hydrogeologic province. The GAMA Priority Basin Project is carried out by the U.S. Geological Survey in collaboration with the California State Water Resources Control Board and Lawrence Livermore National Laboratory. The GAMA Priority Basin Project was designed to provide a statistically unbiased, spatially distributed assessment of the quality of untreated groundwater in the primary aquifer system of California. The primary aquifer system is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health database for the Santa Barbara study unit. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the Santa Barbara study unit, not the treated drinking water delivered to consumers by water purveyors. The status assessment for the Santa Barbara study unit was based on water-quality and ancillary data collected in 2011 by the U.S. Geological Survey from 23 sites and on water-quality data from the California Department of Public Health database for January 24, 2008–January 23, 2011. The data used for the assessment included volatile organic compounds; pesticides; pharmaceutical compounds; two constituents of special interest, perchlorate and N -nitrosodimethylamine (NDMA); and naturally present inorganic constituents, such as major ions and trace elements. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used to evaluate groundwater quality for those constituents that have federal or California regulatory and non-regulatory benchmarks for drinking-water quality. For inorganic, organic, and special-interest constituents, a relative-concentration greater than 1.0 indicates a concentration greater than the benchmark and is classified as high. Inorganic constituents are classified as moderate if relative-concentrations are greater than 0.5 and less than or equal to 1.0 and are classified as low if relative-concentrations are less than or equal to 0.5. For organic and special-interest constituents, the boundary between moderate and low relative-concentrations was set at 0.1. Aquifer-scale proportion was used as the primary metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the areal percentage of the primary aquifer system with a relative-concentration greater than 1.0 for a particular constituent or class of constituents. Moderate and low aquifer-scale proportions were defined as the areal percentage of the primary aquifer system that had moderate and low relative-concentrations, respectively. Two statistical approaches—grid based and spatially weighted—were used to calculate aquifer-scale proportions for individual constituents and constituent classes. Grid-based and spatially weighted estimates were comparable in this the study (within 90-percent confidence intervals). Grid-based results were selected for use in the status assessment unless, as was observed in a few cases, a grid-based result was zero and the spatially weighted result was not zero, in which case, the spatially weighted result was used. Inorganic constituents that have human-health benchmarks were present at high relative-concentrations in 5.3 percent of the primary aquifer system and at moderate concentrations in 32 percent. High aquifer-scale proportions of inorganic constituents primarily were a result of high aquifer-scale proportions of boron (5.3 percent) and fluoride (5.3 percent). Inorganic constituents that have aesthetic-based benchmarks, referred to as secondary maximum contaminant levels, were present at high relative-concentrations in 58 percent of the primary aquifer system and at moderate concentrations in 37 percent. Iron, manganese, sulfate, and total dissolved solids were the inorganic constituents with secondary maximum contaminant levels present at high relative-concentrations. In contrast, organic and special-interest constituents that have health-based benchmarks were not detected at high relative-concentrations in the primary aquifer system. Of the 218 organic constituents analyzed, 10 were detected—9 that had human-health benchmarks. Organic constituents were present at moderate relative-concentrations in 11 percent of the primary aquifer system. The moderate aquifer-scale proportions were a result of moderate relative-concentrations of the volatile organic compounds methyl tert- butyl ether (MTBE, 11 percent) and 1,2-dichloroethane (5.6 percent). The volatile organic compounds 1,1,1-trichloroethane, 1,1-dichloroethane, bromodichloromethane, chloroform, MTBE, and perchloroethene (PCE); the pesticide simazine; and the special-interest constituent perchlorate were detected at more than 10 percent of the sites in the Santa Barbara study unit. Perchlorate was present at moderate relative-concentrations in 50 percent of the primary aquifer system. Pharmaceutical compounds and NDMA were not detected in the Santa Barbara study unit.

California↗

Evaluation of effects of changes in canal management and precipitation patterns on salinity in Biscayne Bay, Florida, using an integrated surface-water/groundwater model

Biscayne National Park, located in Biscayne Bay in southeast Florida, is one of the largest marine parks in the country and sustains a large natural marine fishery where numerous threatened and endangered species reproduce. In recent years, the bay has experienced hypersaline conditions (salinity greater than 35 practical salinity units) of increasing magnitude and duration. Hypersalinity events were particularly pronounced during April to August 2004 in nearshore areas along the southern and middle parts of the bay. Prolonged hypersaline conditions can cause degradation of water quality and permanent damage to, or loss of, brackish nursery habitats for multiple species of fish and crustaceans as well as damage to certain types of seagrasses that are not tolerant of extreme changes in salinity. To evaluate the factors that contribute to hypersalinity events and to test the effects of possible changes in precipitation patterns and canal flows into Biscayne Bay on salinity in the bay, the U.S. Geological Survey constructed a coupled surface-water/groundwater numerical flow model. The model is designed to account for freshwater flows into Biscayne Bay through the canal system, leakage of salty bay water into the underlying Biscayne aquifer, discharge of fresh and salty groundwater from the Biscayne aquifer into the bay, direct effects of precipitation on bay salinity, indirect effects of precipitation on recharge to the Biscayne aquifer, direct effects of evapotranspiration (ET) on bay salinity, indirect effects of ET on recharge to the Biscayne aquifer, and maintenance of mass balance of both water and solute. The model was constructed using the Flow and Transport in a Linked Overland/Aquifer Density Dependent System (FTLOADDS) simulator, version 3.3, which couples the two-dimensional, surface-water flow and solute-transport simulator SWIFT2D with the density-dependent, groundwater flow an solute-transport simulator SEAWAT. The model was calibrated by a trial-and-error method to fit observed groundwater heads, estimated base flow, and measured bay salinity and temperatures from 1996 to 2004, as well as the location of the freshwater-saltwater interface in the aquifer, by adjusting ET rate limiters, canal vertical hydraulic conductance, leakage rate coefficients (transition-layer thickness and hydraulic conductivity), Manning's n value, and delineation of rainfall zones. Although flow budget calculations indicate that precipitation, ET, and groundwater flux into the bay represent a small portion of the overall budget, these factors may be important in controlling salinity in some parts of the bay, for example the southern parts of the bay where the canal system is not extensively developed or controlled. The balance of precipitation and ET during the wet season generally results in a reduction of bay salinity, whereas the balance of precipitation and ET during the dry season generally results in an increase in bay salinity. During years when wet season precipitation is lower than average, for example less than 70 percent total precipitation for an average year, ET could outweigh precipitation over the bay for essentially the entire year. Hypersaline conditions are prone to occur near the end of the dry season because precipitation rates are generally lower, canal discharge rates (which are strongly correlated to precipitation rates) are also generally lower, and ET rates are higher than during the rest of the year. The hypersalinity event of 2004 followed several years of relatively low precipitation and correspondingly reduced canal structure releases and was unusually extensive, continuing into July. Thus, hypersalinity is ultimately the result of a cumulative deficit of precipitation. The model was used to test the effects of possible changes in canal flux and precipitation. Simulation results showed that by increasing, reducing, or modifying canal discharge rates, the effects on salinity in the bay were more pronounced in the northern part of the bay where there are more canals and canal-control structures. By doubling and halving precipitation, the effects on bay salinity were more pronounced in the southern part of the bay than in the northern part of the bay where there are fewer canals and canal-control structures. The model is designed to quantify factors that contribute to hypersaline conditions in Biscayne Bay and may be less appropriate for addressing other issues or examining conditions substantially different from those described in this report. Model results must be interpreted in light of model limitations, which include representation of the system and conceptual model, uncertainty in physical properties used to describe the system or processes, the scale and discretization of the system, and representation of the boundary conditions.

Florida↗

Evaluation of emerging contaminants of concern at the South District Wastewater Treatment Plant based on seasonal sampling events, Miami-Dade County, Florida, 2004

The Comprehensive Everglades Restoration Plan has identified highly treated wastewater as a possible water source for the restoration of natural water flows and hydroperiods in selected coastal areas, including the Biscayne Bay coastal wetlands. One potential source of reclaimed wastewater for the Biscayne Bay coastal wetlands is the effluent from the South District Wastewater Treatment Plant in southern Miami-Dade County. The U.S. Geological Survey, in cooperation with the Comprehensive Everglades Restoration Plan Wastewater Reuse Technology Pilot Project Delivery Team, initiated a study to assess the presence of emerging contaminants of concern in the South District Wastewater Treatment Plant influent and effluent using current wastewater-treatment methods. As part of the study, 24-hour composite and discrete samples were collected at six locations (influent at plants 1 and 2, effluent pump, reuse train, chlorine dioxide unit, and ultraviolet pilot unit) at the plant during: (1) a dry-season, low-flow event on March 2-3, 2004, with an average inflow rate of 83.7 million gallons per day; (2) a wet-season, average-flow event on July 20-21, 2004, with an average inflow rate of 89.7 million gallons per day; and (3) high-rate disinfection tests on October 5 and 20, 2004, with average flow rates of 84.1 and 119.6 million gallons per day, respectively. During these four sampling events, 26, 27, 29, and 35 constituents were detected, respectively. The following transformations in concentration were determined in the waste stream: -100 to 180 percent at the effluent pump and -100 to 85 percent at the reuse train on March 2-3, 2004, and -100 to 1,609 percent at the effluent pump and -100 to 832 percent at the reuse train on July 20-21, 2004; -100 to -37 percent at the effluent pump, -100 to -62 percent at the reuse train, -100 to -56 percent at the chlorine dioxide unit, and -100 to -40 percent at the ultraviolet pilot unit on October 5, 2004; and -100 to -4 percent at the effluent pump, -100 to 17 percent at the reuse train, -100 to -40 percent at the chlorine dioxide unit, and -100 to -14 percent at the ultraviolet pilot unit on October 20, 2004. Samples were tested for detection of household and industrial (organic) wastewater compounds, pharmaceutical compounds, antibiotic compounds, and hormones in influent. Two 'known' endocrine disrupting compounds?17 beta-estradiol (E2) and diethoxynonylphenol? and four 'suspected' endocrine-disrupting compounds?1,4-dichlorobenzene, benzophenone, tris(2-chloroethyl) phosphate, and tris(dichloroisopropyl) phosphate?were detected during these sampling events. Phenanthrene and indole showed the greatest concentration ranges and highest concentrations for the organic wastewater compounds. Acetaminophen showed the greatest concentration range and highest concentration, and warfarin showed the smallest concentration range for the pharmaceutical compounds. Sulfamethoxazole (a sulfonamide) showed the greatest concentration range and highest concentration, and sulfathiozole (also a sulfonamide) showed the smallest concentration range for the antibiotic compounds. Two hormones, 17 beta-estradiol (E2) and estrone (E1), were detected in influent. Samples were also tested for detection of organic wastewater compounds, pharmaceutical compounds, antibiotic compounds, and hormones in effluent. Indole showed the greatest concentration range and highest concentration, and triphenyl phosphate showed the smallest concentration range for the organic wastewater compounds. Dehydronifedipine showed the greatest concentration range and highest concentration, and warfarin had the smallest concentration range for the pharmaceutical compounds. Anhydro-erythromycin (a macrolide degradation product) showed the greatest concentration range, and sulfadiazine (a sulfonamide) and tetracycline showed the lowest concentration ranges for the antibiotic compounds. One hormone, 17 beta-estradiol (E2), was det

Florida↗

Determination of Baseline Periods of Record for Selected Streamflow-Gaging Stations in New Jersey for Determining Ecologically Relevant Hydrologic Indices (ERHI)

Hydrologic changes in New Jersey stream basins resulting from human activity can affect the flow and ecology of the streams. To assess future changes in streamflow resulting from human activity an understanding of the natural variability of streamflow is needed. The natural variability can be classified using Ecologically Relevant Hydrologic Indices (ERHIs). ERHIs are defined as selected streamflow statistics that characterize elements of the flow regime that substantially affect biological health and ecological sustainability. ERHIs are used to quantitatively characterize aspects of the streamflow regime, including magnitude, duration, frequency, timing, and rate of change. Changes in ERHI values can occur as a result of human activity, and changes in ERHIs over time at various stream locations can provide information about the degree of alteration in aquatic ecosystems at or near those locations. New Jersey streams can be divided into four classes (A, B, C, or D), where streams with similar ERHI values (determined from cluster analysis) are assigned the same stream class. In order to detect and quantify changes in ERHIs at selected streamflow-gaging stations, a 'baseline' period is needed. Ideally, a baseline period is a period of continuous daily streamflow record at a gaging station where human activity along the contributing stream reach or in the stream's basin is minimal. Because substantial urbanization and other development had already occurred before continuous streamflow-gaging stations were installed, it is not possible to identify baseline periods that meet this criterion for many reaches in New Jersey. Therefore, the baseline period for a considerably altered basin can be defined as a period prior to a substantial human-induced change in the drainage basin or stream reach (such as regulations or diversions), or a period during which development did not change substantially. Index stations (stations with minimal urbanization) were defined as streamflow-gaging stations in basins that contain less than 15 percent urban land use throughout the period of continuous streamflow record. A minimum baseline period of record for each stream class was determined by comparing the variability of selected ERHIs among consecutive 5-, 10-, 15-, and 20-year time increments for index stations. On the basis of this analysis, stream classes A and D were assigned a minimum of 20 years of continuous record as a baseline period and stream classes B and C, a minimum of 10 years. Baseline periods were calculated for 85 streamflow-gaging stations in New Jersey with 10 or more years of continuous daily streamflow data, and the values of 171 ERHIs also were calculated for these baseline periods for each station. Baseline periods were determined by using historical streamflow-gaging station data, estimated changes in impervious surface in the drainage basin, and statistically significant changes in annual base flow and runoff. Historical records were reviewed to identify years during which regulation, diversions, or withdrawals occurred in the drainage basins. Such years were not included in baseline periods of record. For some sites, the baseline period of record was shorter than the minimum period of record specified for the given stream class. In such cases, the baseline period was rated as 'poor'. Impervious surface was used as an indicator of urbanization and change in streamflow characteristics owing to increases in storm runoff and decreases in base flow. Percentages of impervious surface were estimated for 85 streamflow-gaging stations from available municipal population-density data by using a regression model. Where the period of record was sufficiently long, all years after the impervious surface exceeded 10 to 20 percent were excluded from the baseline period. The percentage of impervious surface also was used as a criterion in assigning qualitative ratings to baseline periods. Changes in trends of annual base fl

Scientific Investigations Report↗

An Assessment of Hydrology, Fluvial Geomorphology, and Stream Ecology in the Cardwell Branch Watershed, Nebraska, 2003-04

An assessment of the 16.3-square-mile Cardwell Branch watershed characterized the hydrology, fluvial geomorphology, and stream ecology in 2003-04. The study - performed by the U.S. Geological Survey in cooperation with the City of Lincoln, Nebraska, and the Lower Platte South Natural Resources District - focused on the 7.7-square-mile drainage downstream from Yankee Hill Reservoir. Hydrologic and hydraulic models were developed using the Hydrologic Modeling System (HEC-HMS) and River Analysis System (HEC-RAS) of the U.S. Army Corps of Engineers Hydraulic Engineering Center. Estimates of streamflow and water-surface elevation were simulated for 24-hour-duration design rainstorms ranging from a 50-percent frequency to a 0.2-percent frequency. An initial HEC-HMS model was developed using the standardized parameter estimation techniques associated with the Soil Conservation Service curve number technique. An adjusted HEC-HMS model also was developed in which parameters were adjusted in order for the model output to better correspond to peak streamflows estimated from regional regression equations. Comparisons of peak streamflow from the two HEC-HMS models indicate that the initial HEC-HMS model may better agree with the regional regression equations for higher frequency storms, and the adjusted HEC-HMS model may perform more closely to regional regression equations for larger, rarer events. However, a lack of observed streamflow data, coupled with conflicting results from regional regression equations and local high-water marks, introduced considerable uncertainty into the model simulations. Using the HEC-RAS model to estimate water-surface elevations associated with the peak streamflow, the adjusted HEC-HMS model produced average increases in water-surface elevation of 0.2, 1.1, and 1.4 feet for the 50-, 1-, and 0.2-percent-frequency rainstorms, respectively, when compared to the initial HEC-HMS model. Cross-sectional surveys and field assessments conducted between November 2003 and March 2004 indicated that Cardwell Branch and its unnamed tributary appear to be undergoing incision (the process of downcutting) (with three locations showing 2 or more feet of streambed incision since 1978) that is somewhat moderated by the presence of grade controls and vegetation along the channel profile. Although streambank failures were commonly observed, 96 percent of the surveyed cross sections were classified as stable by planar and rotational failure analysis-a disconnect that may have been the result of assumed soil properties. Two process-based classification systems each indicated that the reaches within the study area were incising and widening, and the Rosgen classification system characterized the streams as either type E6 or B6c. E6 channels are hydraulically efficient with low width-depth ratios, low to moderate sinuosity, and gentle to moderately steep slopes. B6c channels typically are incised with low width-depth ratios maintained by riparian vegetation, low bedload transport, and high washload transport. No obvious nickpoints (interruption or break in slope) were observed in the thalweg profile (line of maximum streambed descent), and the most acute incision occurred immediately downstream from bridges and culverts. Nine water-quality samples were collected between August 2003 and November 2004 near the mouth of the watershed. Sediment-laden rainfall-runoff substantially affected the water quality in Cardwell Branch, leading to greater biochemical and chemical oxygen demands as well as increased concentrations of several nutrient, bacteriological, sediment, and pesticide constituents. The storage of rainfall runoff in Yankee Hill Reservoir may prolong the presence of runoff-related constituents downstream. Across the study area, there was a lack of habitat availability for aquatic biota because of low dissolved oxygen levels and low streamflows or dry channels. In August 2003, the aquatic community near the mouth of

Scientific Investigations Report↗

Quantification and simulation of metal loading to the Upper Animas River, Eureka to Silverton, San Juan County, Colorado, September 1997 and August 1998

Drainage from abandoned and inactive mines and from naturally mineralized areas in the San Juan Mountains of southern Colorado contributes metals to the upper Animas River near Silverton, Colorado. Tracer-injection studies and associated synoptic sampling were performed along two reaches of the upper Animas River to develop detailed profiles of stream discharge and to locate and quantify sources of metal loading. One tracer-injection study was performed in September 1997 on the Animas River reach from Howardsville to Silverton, and a second study was performed in August 1998 on the stream reach from Eureka to Howardsville. Drainage in the upper Animas River study reaches contributed aluminum, calcium, copper, iron, magnesium, manganese, sulfate, and zinc to the surface-water system in 1997 and 1998. Colloidal aluminum, dissolved copper, and dissolved zinc were attenuated through a braided stream reach downstream from Eureka. Instream dissolved copper concentrations were lower than the State of Colorado acute and chronic toxicity standards downstream from the braided reach to Silverton. Dissolved iron load and concentrations increased downstream from Howardsville and Arrastra Gulch, and colloidal iron remained constant at low concentrations downstream from Howardsville. Instream sulfate concentrations were lower than the U.S. Environmental Protection Agency's secondary drinking-water standard of 250 milligrams per liter throughout the two study reaches. Elevated zinc concentrations are the primary concern for aquatic life in the upper Animas River. In the 1998 Eureka to Howardsville study, instream dissolved zinc load increased downstream from the Forest Queen mine, the Kittimack tailings, and Howardsville. In the 1997 Howardsville to Silverton study, there were four primary areas where zinc load increased. First, was the increase downstream from Howardsville and abandoned mining sites downstream from the Cunningham Gulch confluence, which also was measured during the 1998 study. The second affected reach was downstream from Arrastra Gulch, where the increase in zinc load seems related to a series of right-bank inflows with low pH Quantification and Simulation of Metal Loading to the Upper Animas River, Eureka to Silverton, San Juan County, Colorado, September 1997 and August 1998By Suzanne S. Paschke, Briant A. Kimball, and Robert L. Runkeland elevated dissolved zinc concentrations. A third increase in zinc load occurred 6,100 meters downstream from the 1997 injection site and may have been from ground-water discharge with elevated zinc concentrations based on mass-loading graphs and the lack of visible inflow in the reach. A fourth but lesser dissolved zinc load increase occurred downstream from tailings near the Lackawanna Mill. Results of the tracer-injection studies and the effects of potential remediation were analyzed using the one- dimensional stream-transport computer code OTIS. Based on simulation results, instream zinc concentrations downstream from the Kittimack tailings to upstream from Arrastra Gulch would approach 0.16 milligram per liter (the upper limit of acute toxicity for some sensitive aquatic species) if zinc inflow concentrations were reduced by 75 percent in the stream reaches receiving inflow from the Forest Queen mine, the Kittimack tailings, and downstream from Howardsville. However, simulated zinc concentrations downstream from Arrastra Gulch were higher than approximately 0.30 milligram per liter due to numerous visible inflows and assumed ground-water discharge with elevated zinc concentrations in the lower part of the study reach. Remediation of discrete visible inflows seems a viable approach to reducing zinc inflow loads to the upper Animas River. Remediation downstream from Arrastra Gulch is more complicated because ground-water discharge with elevated zinc concentrations seems to contribute to the instream zinc load.

Colorado↗

Evaluation of Ground Water Near Sidney, Western Nebraska, 2004-05

During times of drought, ground water in the Lodgepole Creek area around Sidney, western Nebraska, may be insufficient to yield adequate supplies to private and municipal wells. Alternate sources of water exist in the Cheyenne Tablelands north of the city, but these sources are limited in extent. In 2003, the U.S. Geological Survey and the South Platte Natural Resources District began a cooperative study to evaluate the ground water near Sidney. The 122-square-mile study area lies in the south-central part of Cheyenne County. with Lodgepole Creek and Sidney Draw occupying the southern and western parts of the study area and the Cheyenne Tablelands occupying most of the northern part of the study area. Twenty-nine monitoring wells were installed and then sampled in 2004 and 2005 for physical characteristics, nutrients, major ions, and stable isotopes. Some of the 29 sites also were sampled for ground-water age dating. Ground water is limited in extent in the tableland areas. Spring 2005 depths to ground water in the tableland areas ranged from 95 to 188 feet. Ground-water flow in the tableland areas primarily is northeasterly. South of a ground-water divide, ground-water flows southeasterly toward Lodgepole Creek Valley. Water samples from monitoring wells in the Ogallala Group were predominantly a calcium bicarbonate type, and those from monitoring wells in the Brule Formation were a sodium bicarbonate type. Water samples from monitoring wells open to the Brule sand were primarily a calcium bicarbonate type at shallow depths and a sodium bicarbonate type at deeper depths. Ground water in Lodgepole Creek Valley had a strong sodium signature, which likely results from most of the wells being open to the Brule. Concentrations of sodium and nitrate in ground-water samples from the Ogallala were significantly different than in water samples from the Brule and Brule sand. In addition, significant differences were seen in concentrations of calcium between water samples from the Ogallala and the Brule sand. Median concentrations of nitrate varied by aquifer-2.6 milligrams per liter (Ogallala). 2.1 milligrams per liter (Brute), and 1.3 milligrams per liter (Brule sand). The chemistry of the ground water in the study area indicates that ground water flows from recharge areas in both the tableland areas and Lodgepole Creek Valley to discharge areas beyond the study area. Recharging water that percolates into the Ogallala in the tableland areas either enters the Ogallala aquifer. flows along the Ogallala-Brule contact, or enters Brule fractures or sand. Although limited in amount, ground water flowing along the Ogallala-Brule contact or in the Brule fractures or sand appears to be the predominant means by which water moves from the tableland areas to Lodgepole Creek Valley. Apparent ground-water ages from chlorofluorocarbon and sulfur hexafluoride data generally were similar. Age of ground water for most monitoring wells located in Lodgepole Creek Valley ranged from the mid- to late 1960s to the early 1990s. Ages of ground water in samples from monitoring wells located in tableland draw areas ranged from the mid-1980s to the early 1990s. Water in the Brule (areas without known secondary permeability structures) or deeper Brule sand aquifer was substantially older than water in the Ogallala aquifer and probably was recharged between 10,000 to 30,000 years before present. The stable isotopic data indicate that the ground water in the study area probably originated from precipitation. Ground water in Lodgepole Creek and the tableland areas are similar in chemistry. However, there appears to be limited interaction between ground water within the Ogallala to the north of Sidney and Lodgepole Creek Valley. Available data indicate that although some of the ground water in the Ogallala likely flows across the Ogallala-Brule contact, most of it does not move toward Lodgepole Creek.

Nebraska↗

Groundwater-level and storage-volume changes in the Equus Beds aquifer near Wichita, Kansas, predevelopment through January 2015

Development of the Wichita well field began in the 1940s in the Equus Beds aquifer to provide the city of Wichita, Kansas, a new water-supply source. After development of the Wichita well field began, groundwater levels began to decline. Extensive development of irrigation wells that began in the 1970s also contributed to substantial groundwater-level declines. Groundwater-level declines likely enhance movement of brine from past oil and gas production near Burrton, Kansas, and natural saline water from the Arkansas River into the Wichita well field. Groundwater levels reached a historical minimum in 1993 because of drought conditions, irrigation, and the city of Wichita’s withdrawals from the aquifer. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program to ensure that Wichita’s water needs would be met through the year 2050 and beyond as part of its efforts to manage the part of the Equus Beds aquifer Wichita uses. A key component of the Integrated Local Water Supply Program was the Equus Beds Aquifer Storage and Recovery project. The Aquifer Storage and Recovery project’s goal is to store and eventually recover groundwater and help protect the Equus Beds aquifer from oil-field brine water near Burrton, Kansas, and saline water from the Arkansas River. Since 1940, the U.S. Geological Survey has monitored groundwater levels and storage-volume changes in the Equus Beds aquifer to provide data to the city of Wichita in order to better manage its water supply. Groundwater mostly flowed from west to east in the shallow and deep parts of the Equus Beds aquifer in January 2015. A large area of declines greater than 10 feet in the shallow part of the Equus Beds aquifer from predevelopment (before substantial pumpage began in the area in September 1940) to January 2015 covered most of the central part of the study area, where the city of Wichita well field is located, and extended beyond it. Groundwater-level rises of greater than 10 feet from 1993 (the historical minimum groundwater levels) to January 2015 covered most of the central part of the study area in the shallow and deep parts of the Equus Beds aquifer; rises of greater than 20 feet mostly were within the north-central part of the study area. The 1993 to January 2015 recovery of storage volume previously lost from predevelopment to 1993 was about 46 percent (55,200 acre-feet) for the central part of the study area and the percentage recovery was larger than the 31 percent (59,800 acre-feet) recovery for the entire study area. Groundwater-level rises and the larger percentage recovery of storage volume in the central part of the study area was most likely a result of the city of Wichita adopting the Integrated Local Water Supply Program strategy which reduced Wichita’s pumpage from the Equus Beds aquifer in 2014 to the smallest amount since 1940. January 2015 storage volumes were about 96 percent (3,057,000 acre-feet) and 94 percent (960,000 acre-feet) of total aquifer storage for the study area and the central part of the study area, respectively. Groundwater levels from January 2014 to January 2015 in the central part of the study area rose about 3 feet in some places, probably because Wichita reduced its withdrawals from the aquifer in 2014 by more than 50 percent. Groundwater levels probably recovered less than anticipated because of decreased recharge and net groundwater flow and increased agricultural pumpage. A volumetric water budget for the central part of the study area between 2013 and 2014 showed that the substantial decrease in total pumping (10,412 acre-feet) did not result in an increase in storage volume because it was more than offset by decreased recharge (6,502 acre-feet; artificial and from precipitation) and an even greater decrease in net groundwater flow (11,710 acre-feet).

Kansas↗

Influence of septic systems on stream base flow in the Apalachicola-Chattahoochee-Flint River Basin near Metropolitan Atlanta, Georgia, 2012

Septic systems were identified at 241,733 locations in a 2,539-square-mile (mi 2 ) study area that includes all or parts of 12 counties in the Metropolitan Atlanta, Georgia, area. Septic system percolation may locally be an important component of streamflow in small drainage basins where it augments natural groundwater recharge, especially during extreme low-flow conditions. The amount of groundwater reaching streams depends on how much is intercepted by plants or infiltrates to deeper parts of the groundwater system that flows beyond a basin divide and does not discharge into streams within a basin. The potential maximum percolation from septic systems in the study area is 62 cubic feet per second (ft 3 /s), of which 52 ft 3 /s is in the Chattahoochee River Basin and 10 ft 3 /s is in the Flint River Basin. These maximum percolation rates represent 0.4 to 5.7 percent of daily mean streamflow during the 2011–12 period at the farthest downstream gaging site (station 02338000) on the Chattahoochee River, and 0.5 to 179 percent of daily mean streamflow at the farthest downstream gaging site on the Flint River (02344350). To determine the difference in base flow between basins having different septic system densities, hydrograph separation analysis was completed using daily mean streamflow data at streamgaging stations at Level Creek (site 02334578), with a drainage basin having relatively high septic system density of 101 systems per square mile, and Woodall Creek (site 02336313), with a drainage basin having relatively low septic system density of 18 systems per square mile. Results indicated that base-flow yield during 2011–12 was higher at the Level Creek site, with a median of 0.47 cubic feet per second per square mile ([ft 3 /s]/mi 2 ), compared to a median of 0.16 (ft 3 /s)/mi 2 , at the Woodall Creek site. At the less urbanized Level Creek site, there are 515 septic systems with a daily maximum percolation rate of 0.14 ft 3 /s, accounting for 11 percent of the base flow in September 2012. At the more urban Woodall Creek site, there are 50 septic systems with an average daily maximum percolation rate of 0.0097 ft 3 /s, accounting for 5 percent of base flow in September 2012. Streamflow measurements at 133 small drainage basins (less than 5 mi2 in area) during September 2012 indicated no statistically significant difference in streamflow or specific conductance between basins having high and low density of septic systems (HDS and LDS, respectively). The median base-flow yield was 0.04 (f 3 /s)/mi 2 for HDS sites, ranging from 0 to 0.52 (ft 3 /s)/mi 2 , and 0.10 (ft 3 /s)/mi 2 for LDS sites, ranging from 0 to 0.49 (ft 3 /s)/mi 2 . A Wilcoxon rank-sum test indicated the median base-flow yields for HDS and LDS sites were not statistically different, with a p-value of 0.345. Because of the large size of the study area and associated variations in basin characteristics, data collected in September 2012 were also evaluated on the basis of the basins physical characteristics in an attempt to reduce or eliminate other basin characteristics that might affect base flow. Basins were evaluated based on geologic area, four geographic subareas, and 45-meter (147.6 ft) buffer zone; there were no statistically significant differences between median base-flow yield for HDS and LDS basins. It is probable that detection of the contribution from septic system percolation in base flow at many of the sites visited in September 2012 was obscured by a combination of the limitations of measurement accuracy and evapotranspiration. Detection of septic system percolation may also have been complicated by leaky water and sewer mains, which may have resulted in higher streamflows in LDS basins relative to HDS basins.

Georgia↗

Bathymetric contour maps, surface area and capacity tables, and bathymetric change maps for selected water-supply lakes in northeastern Missouri, 2021

Bathymetric data were collected at 12 water-supply lakes in northeastern Missouri by the U.S. Geological Survey (USGS) in cooperation with the Missouri Department of Natural Resources (MoDNR) and various local agencies, as part of a multiyear effort to establish or update the surface area and capacity tables for the surveyed lakes. The lakes were surveyed in March through May 2021. Ten of the lakes had been surveyed previously by the USGS, and the recent surveys were compared to the earlier surveys to document the changes in the bathymetric surface and capacity of the lakes. Bathymetric data were collected using a high-resolution multibeam mapping system mounted on a boat. Supplemental depth data at five of the lakes were collected in shallow areas with an acoustic Doppler current profiler on a remote-controlled boat. Data points from the various sources were exported at a gridded data resolution appropriate to each lake, either 0.82 foot, 1.64 feet, or 3.28 feet. Data outside the multibeam survey extent and greater than the surveyed water-surface elevation were obtained from data collected using aerial light detection and ranging (lidar) point cloud data. A linear enforcement technique was used to add points to the dataset in areas of sparse data (the upper ends of coves where the water was shallow or aquatic vegetation precluded data acquisition) based on surrounding multibeam and upland data values. The various point datasets were used to produce a three-dimensional triangulated irregular network surface of the lake-bottom elevations for each lake. A surface area and capacity table was produced from the three-dimensional surface for each lake showing surface area and capacity at specified lake water-surface elevations. Various quality-assurance tests were conducted to ensure quality data were collected with the multibeam, including beam angle checks and patch tests. Additional quality-assurance tests were conducted on the gridded bathymetric data from the survey, the bathymetric surface created from the gridded data, and the contours created from the bathymetric survey. If there were data from a previous bathymetric survey for a given lake, a bathymetric change map was generated from the elevation difference between the previous survey and the 2021 bathymetric survey data points. After reconciling any vertical datum disagreement between the previous survey data and the 2021 survey datum, coincident points between the surveys were identified, and a bathymetric change map was generated using the coincident point data. The mean elevation change between all repeat surveys at most lakes was positive, indicating sedimentation. Relative to previous surveys, the change in capacity at the primary spillway elevation ranged from a 7.7-percent decrease at Memphis Reservoir to a 3.9-percent increase at Old Lake (Bowling Green West). The mean bathymetric change ranged from 0.03 foot at Hazel Creek and 0.07 foot at Shelbina Lake and Bowling Green Reservoir (Jack Floyd Memorial Lake) to 0.63 at Memphis Lake (Lake Showme) and 0.88 at Memphis Reservoir. The time-averaged mean bathymetric change ranged from 0.002 foot per year at Hazel Creek Lake to 0.044 foot per year at Memphis Reservoir. The computed volumetric sedimentation rate generally ranged from 0.14 to 6.80 acre-feet per year at Shelbina Lake and Memphis Lake (Lake Showme), respectively; however, Forest Lake had a substantially larger sedimentation rate of 17.0 acre-feet per year. Some changes observed in some bathymetric change maps are believed to result from the difference in data collection equipment and techniques between the previous and present bathymetric surveys, whereas other erosional features around the perimeter of certain lakes may be the result of wave action during low-water years.

Missouri↗

Determination of study reporting limits for pesticide constituent data for the California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project, 2004–2018—Part 1: National Water Quality Schedules 2003, 2032, or 2033, and 2060

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality of groundwater resources used for public and domestic drinking water supplies in the State of California, to monitor and evaluate changes to that quality, to investigate the human and natural factors controlling water quality, and to improve the availability of comprehensive groundwater quality data and information. Between May 18, 2004, and May 3, 2018, the GAMA-PBP collected 3001 groundwater samples for analysis of pesticide constituents by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL)(note that ‘pesticide constituents’ includes parent compounds and degradates). Of these samples, 2994 were analyzed for pesticide constituents on schedules 2003, 2032, or 2033 (65 to 84 constituents), and 840 were analyzed for pesticide constituents on schedule 2060 (58 constituents). The original dataset reported by the NWQL to the USGS National Water Information System (NWIS) database contained a total of 2,688 detections of 78 pesticide constituents and 253,825 non-detections. In this original dataset, 33 percent of the 3,001 samples analyzed had reported detections of one or more pesticide constituents. This report describes the GAMA-PBP data-quality objectives for pesticide data, the procedures used to establish study reporting limits, and use of those reporting limits to censor the data from the NWQL so that the final data published by the GAMA-PBP meet these data-quality objectives. The final GAMA-PBP dataset for samples collected from May 2004 to May 2018, after censoring, had a total of 1,632 detections of 37 pesticide constituents. In the final GAMA-PBP dataset, 25 percent of the 3,001 samples analyzed had detections of one or more pesticide constituents. The presence of pesticides in groundwater is commonly evaluated by calculating detection frequencies. Detection frequencies for pesticides are sensitive to detection limits and method performance for concentrations near those limits; therefore, the two primary data quality issues addressed in the GAMA-PBP data-quality objectives for pesticides are (1) establishing criteria for classifying data from the laboratory as detections or non-detections for the purpose of data reporting by the project and (2) accounting for changes in analytical methods or method performance over time. The GAMA-PBP addresses these issues by developing study reporting limits that are used as the boundary between detections and non-detections for the reporting of GAMA-PBP results. These reporting limits are defined from method detection limits (MDLs) provided by the NWQL, unless examination of results from laboratory set blanks (LSBs) and GAMA-PBP field blanks indicates that a higher concentration censoring limit is warranted. The GAMA-PBP selected the MDL as the primary choice for defining study reporting limits for consistency with U.S. Environmental Protection Agency (EPA) guidelines for reporting detections of pesticides and other organic constituents. A five-step procedure is used to develop study reporting limits and censor the GAMA-PBP dataset accordingly. The effect of the censoring at each step is described to provide information about the relative effect of each step on the overall censoring of the dataset. Steps 1 and 2 can be implemented at the time the data are received, whereas steps 3−5 require information accumulated over an extended period. Step 1: Reject results that were most likely the result of specific contamination instances attributable to unusual field or laboratory conditions during sample collection or processing. Two such instances were identified, leading to rejection of 25 detections, which were assigned a data-quality indicator code of “Q” for “reviewed and rejected” in the NWIS database. Step 2: Use the NWQL MDLs in effect at the time each sample was analyzed as the reporting limit. A total of 506 detections were censored on this basis. Step 3: Use the maximum MDL established by the NWQL during July 2004–August 2018 (MDLmax) as the reporting limit. The rationale for using the MDLmax as the reporting limit is based primarily on the observation that the concentrations of MDLs generally increased over time. A total of 438 detections were censored on this basis. Step 4: Use the LSBs to identify periods of greater potential laboratory contamination bias and define raised reporting limits to be used during those periods. These periods were defined by using a moving average detection frequency approach. For consistency with the NWQL procedures for defining raised reporting limits on the basis of detections in LSBs, the raised reporting limits were defined as equal to three times the highest concentration measured in an LSB during the period. A total of 25 detections in groundwater samples analyzed during periods of increased laboratory contamination bias were censored. Step 5: Use the LSBs and field blanks to identify potential contamination bias from field or laboratory processes outside of the time periods identified in step 4. The NWQL protocols were used to define the MDLs from blanks analyzed outside of the periods identified in step 4. If an MDL defined from blanks was greater than the MDLmax, the MDL defined from blanks was used to censor the data. One constituent had a study reporting limit defined on this basis, and a total of 62 detections in groundwater samples were censored. As of 2019, the USGS NWIS database does not have the capability to store both the original value reported by the NWQL and the final value published by the GAMA-PBP that reflects application of the quality-control censoring described in this report. In the interim, while this capability is developed, the 1,031 results censored in steps 2−5 are blocked from public release in NWIS, and the GAMA-PBP has published the original and final values in a USGS data release accompanying this report. The entire GAMA-PBP final dataset for pesticide constituents on schedules 2003, 2032, or 2033, or on schedule 2060 is publicly available in that USGS data release, through the USGS GAMA-PBP public web portal, and through the California State Water Resources Control Board GAMA public groundwater information system.

California↗

Stormwater quality of infrastructure elements in Rapid City, South Dakota, 2016–18

As runoff flows over the land or impervious surfaces (paved streets, parking lots, and building roofs), it accumulates debris, chemicals, sediment, and other contaminants that can adversely affect water quality if the runoff discharge remains untreated. Pathogens, commonly measured using fecal indicator bacteria such as Escherichia coli , enterococci, or fecal coliform, are the most-frequent cause of water-quality impairment in rivers and streams in the United States. Rapid Creek originates in the western Black Hills area and flows east through Rapid City, South Dakota, to its mouth at the Cheyenne River. The water quality of Rapid Creek is important because the reach that flows through Rapid City is a valuable spawning area for a self-sustaining trout fishery, is actively used for recreation, and is a seasonal municipal water supply for the City of Rapid City. These uses (fishery, recreation, and water supply) are considered beneficial uses by the South Dakota Department of Environment and Natural Resources. Numerical criteria have been established for total suspended solids and Escherichia coli concentrations, among other water-quality constituents, for these beneficial uses. The objectives of this study were to improve the method by which fecal indicator bacteria and total suspended solids are quantified in the urban drainages within Rapid City and to provide information that helps identify origins of fecal indicator bacteria and total suspended solids. This information can be used in hydrologic models to estimate fecal indicator bacteria and total suspended solid loading from certain infrastructure elements in urban environments. Stormwater samples analyzed for Escherichia coli , total suspended solids, specific conductance, and pH were collected in three drainage basin flowpaths within Rapid City: Jackson, Wildwood, and the Eco Prayer Park. Data-collection activities for this study focused on upgradient urban flowpath elements during rainfall events. This approach builds upon previous stormwater assessments that characterized the water quality in urban basin outlets near the downstream end of the stormwater flowpaths. Within each flowpath group, 4–6 sites were selected to represent the various infrastructure elements of the runoff process. These elements included roof downspouts, parking lots, street curbs and gutters, open channels, underground storm sewers, and stormwater ponds or best-management practice facilities. In general, the concentrations of Escherichia coli and total suspended solids increased in the downstream direction for all flowpath sites. The wash-off process after the first flush is evident for total suspended solids and specific conductance; however, Escherichia coli concentrations did not necessarily follow the same pattern. Escherichia coli concentrations in the latter part of the runoff period were similar to or greater than the initial concentrations of the first set of samples. Stormwater-quality data were summarized by infrastructure type (roof downspout, parking lot, street curb, and channel/storm sewer) to provide information about approximate water-quality concentrations originating at the upper end of urban flowpaths. Escherichia coli and total suspended solid concentrations were lowest in samples collected from locations most isolated from human influence (roof downspouts); the median concentrations at these sites were 4 most probable number per 100 milliliters and 15 milligrams per liter, respectively. The delivery potential of fecal indicator bacteria and sediment from parking lots and street curbs was similar; median concentrations of Escherichia coli and total suspended solids were around 150–220 most probable number per 100 milliliters and 56–86 milligrams per liter, respectively. The downstream receiving channels and storm sewers where stormwater was aggregated typically contained the highest Escherichia coli concentrations (median was 1,800 most probable number per 100 milliliters), but the total suspended solid concentrations were similar to upstream elements in the flowpath (median was 69 milligrams per liter). The data collected from this study demonstrate that stormwater is contaminated with fecal indicator bacteria upon initial contact with impervious surfaces and highlight the importance of controlling the volume of stormwater discharges into receiving waterbodies via storage structures and pervious elements. Diluting stormwater with high concentrations of Escherichia coli with the receiving water’s (Rapid Creek) lower concentration of Escherichia coli is likely the primary mechanism for meeting the beneficial-use criterion threshold of 235 most probable number per 100 milliliters. Although total suspended solid concentrations in the upper parts of the basin (parking lots and street curbs) also begin at concentrations (56 to 86 milligrams per liter) above the beneficial-use criterion for Rapid Creek (53 milligrams per liter), current stormwater-control practices (storage ponds, swales, and wetlands) may be able to reduce suspended-sediment concentrations to meet this threshold.

South Dakota↗

Investigation of Ground-Water Contamination at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina

The U.S. Geological Survey and the Naval Facilities Engineering Command Southeast investigated natural and engineered remediation of chlorinated volatile organic compound ground-water contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina. The primary contaminants of interest are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. In general, the hydrogeology of Solid Waste Management Unit 12 consists of a surficial aquifer, composed of sand to clayey sand, overlain by dense clay that extends from about land surface to a depth of about 8 to 10 feet and substantially limits local recharge. During some months in the summer, evapotranspiration and limited local recharge result in ground-water level depressions in the forested area near wells 12MW-12S and 12MW-17S, seasonally reflecting the effects of evapotranspiration. Changes in surface-water levels following Hurricane Gaston in 2004 resulted in a substantial change in the ground-water levels at the site that, in turn, may have caused lateral shifting of the contaminant plume. Hydraulic conductivity, determined by slug tests, is higher along the axis of the plume in the downgradient part of the forests than adjacent to the plume, implying that there is some degree of lithologic control on the plume location. Hydraulic conductivity, hydraulic gradient, sulfur-hexafluoride measurements, and historical data indicate that ground-water flow rates are substantially slower in the forested area relative to upgradient areas. The ground-water contamination, consisting of chlorinated volatile organic compounds, extends eastward in the surficial aquifer from the probable source area near a former underground storage tank. Engineered remediation approaches include a permeable reactive barrier and phytoremediation. The central part of the permeable reactive barrier along the main axis of the contaminant plume appears to be actively removing contamination; however, ground-water contamination is moving around the southern end of the permeable reactive barrier. Changes in the contaminant concentrations along the path of ground-water transport reflect a complex variety of influences. Potential influences include dechlorination, sorption and desorption, transpirative removal by trees, lateral shifting of the plume, and the presence of zones of differing concentrations possibly reflecting one or more pulse releases of contamination from the source area. Near the source area at well 12MW-10S, volatile organic compound concentrations of cis-1,2-dichlorothene, vinyl chloride, 1,1-dichloroethane, and 1,1,1-trichloroethane continued an irregular decline, while tetrachloroethene and 1,1-dichloroethene showed marked fluctuations in concentration during 2005 and 2006. Volatile organic compound concentrations at well 12MW-03S continued to show decreasing concentrations with the June 2006 concentrations being the lowest yet recorded at that well for several volatile organic compounds. Concentration and delta carbon 13 data indicate that in the upgradient part of the plume, tetrachloroethene is being degraded to trichloroethene, which is being degraded to cis-1,2-dichloroethene, and cis-1,2-dichloroethene is accumulating faster than it is being depleted. Ground-water volatile organic compound concentrations also changed in some wells in the forested area in the midpart of the plume. Increasing tetrachloroethene and decreasing trichloroethene and 1,1-dichloroethene concentrations were observed at wells 12MW-05S and 12MW-29S, possibly reflecting a lateral shift in the axis of the contamination plume or an advancing contamination pulse. Substantial decreases in contamination occur in the forested area downgradient from well 12MW-05S. Probable major loss mechanisms in this area include evapotranspiration and sorption.

North Carolina, South Carolina↗

Ecological assessment of streams in the Powder River Structural Basin, Wyoming and Montana, 2005-06

Energy and mineral development, particularly coalbed natural gas development, is proceeding at a rapid pace in the Powder River Structural Basin (PRB) in northeastern Wyoming. Concerns about the potential effects of development led to formation of an interagency working group of primarily Federal and State agencies to address these issues in the PRB in Wyoming and in Montana where similar types of resources exist but are largely undeveloped. Under the direction of the interagency working group, an ecological assessment of streams in the PRB was initiated to determine the current status (2005–06) and to establish a baseline for future monitoring. The ecological assessment components include assessment of stream habitat and riparian zones as well as assessments of macroinvertebrate, algal, and fish communities. All of the components were sampled at 47 sites in the PRB during 2005. A reduced set of components, consisting primarily of macroinvertebrate and fish community assessments, was sampled in 2006. Related ecological data, such as habitat and fish community data collected from selected sites in 2004, also are included in this report. The stream habitat assessment included measurement of channel features, substrate size and embeddedness, riparian vegetation, and reachwide characteristics. The width-to-depth ratio (bankfull width/bankfull depth) tended to be higher at sites on the main-stem Powder River than at sites on the main-stem Tongue River and at sites on tributary streams. The streambed substrate particle size was largest at sites on the main-stem Tongue River and smallest at sites on small tributary streams such as Squirrel Creek and Otter Creek. Total vegetative cover at the ground level, understory, and canopy layers ranged from less than 40 percent at a few sites to more than 90 percent at many of the sites. A bank-stability index indicated that sites in the Tongue River drainage were less at risk of bank failure than sites on the main-stem Powder River. Macroinvertebrate communities showed similarity at the river-drainage scale. Macroinvertebrate communities at sites with mountainous headwaters and snowmelt-driven hydrology, such as Clear Creek, Crazy Woman Creek, and Goose Creek, showed similarity with communities from the main-stem Tongue River. The data also indicated similarity among sites on the main-stem Powder River and among small tributaries of the Tongue River. Data analyses using macroinvertebrate observed/expected models and multimetric indices developed by the States of Wyoming and Montana indicated a tendency toward declining biological condition in the downstream direction along the Tongue River. Biological condition for the main-stem Powder River generally improved downstream, from below Salt Creek to near the Wyoming/Montana border, followed by a general decline downstream from the border to the confluence with the Yellowstone River. The biological condition generally was not significantly different between 2005 and 2006, although streamflow was less in 2006 because of drought. Algal communities showed similarity at the river-drainage scale with slight differences from the pattern observed in the macroinvertebrate communities. Although the algal communities from Clear Creek and Goose Creek were similar to those from the main-stem Tongue River, as was true of the macroinvertebrate communities, the algal communities from Crazy Woman Creek had more similarity to those of main-stem Powder River sites than to the Tongue River sites, contrary to the macroinvertebrates. Ordination of algal communities, as well as diatom metrics including salinity and dominant taxa, indicated substantial variation at two sites along the main stem of the Powder River. Fish communities of the PRB were most diverse in the Tongue River drainage. In part due to the effects of Tongue River Reservoir, 15 species of fish were found in the Tongue River drainage that were not found in the Cheyenne, Belle Fourche, or Little Powder River drainages. The number of introduced species and relative abundance of introduced species of fish were higher in the Tongue River and other drainages than at sites on the main-stem Powder River. Although non-native species were identified in the Powder River, the native fish community is largely intact. Western silvery minnow and sturgeon chub—species of special concern—were identified only at sites on the main-stem Powder River and were most common in the Montana segment of the main stem. Fish and habitat sampling on the main-stem Powder River indicated affinity of some species for certain habitats such as pools, runs, riffles, backwaters, or shoals.

Montana, Wyoming↗

Status of groundwater quality in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010: California GAMA Priority Basin Project

Groundwater quality in the approximately 963-square-mile Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southern California in San Bernardino, Riverside, San Diego, and Imperial Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected by the U.S. Geological Survey from 52 wells (49 grid wells and 3 understanding wells) and on water-quality data from the California Department of Public Health database. The primary aquifer system was defined by the depth intervals of the wells listed in the California Department of Public Health database for the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to 1.0 indicates a concentration equal to or less than a benchmark. Relative-concentrations of organic constituents and special-interest constituents [perchlorate and N-nitrosodimethylamine (NDMA)] were classified as high (relative-concentration greater than 1.0), moderate (relative-concentration greater than 0.1 and less than or equal to 1.0), or low (relative-concentration less than or equal to 0.1). Relative-concentrations of inorganic constituents were classified as high (relative-concentration greater than 1.0), moderate (relative-concentration greater than 0.5 and less than or equal to 1.0), or low (relative-concentration less than or equal to 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifer system with a high relative-concentration for a particular constituent or class of constituents; this percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentages of the primary aquifer system with moderate and low relative-concentrations, respectively, of a constituent or class of constituents. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable to each other (within 90-percent confidence intervals) in the study unit. Inorganic constituents (one or more) with health-based benchmarks were detected at high relative-concentrations in 48 percent of the primary aquifer system and at moderate relative-concentrations in 26 percent of the primary aquifer system. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of fluoride (27 percent), arsenic (18 percent), molybdenum (16 percent), boron (10 percent), uranium (5.6 percent), gross alpha radioactivity (9.7 percent), and nitrate (2.7 percent). The inorganic constituents with secondary maximum contaminant levels (SMCLs) were detected at high relative-concentrations in 13 percent of the primary aquifer system and at moderate relative-concentrations in 39 percent. The high aquifer-scale proportion for SMCL constituents reflected high aquifer-scale proportions of total dissolved solids (TDS, 11 percent), manganese (2.8 percent), and chloride (2.8 percent). Organic constituents were not detected at high relative-concentrations in the primary aquifer system, and were present at moderate relative-concentrations in 5.0 percent, and at low relative-concentrations or were not detected in 95 percent of the primary aquifer system. Of the 148 organic constituents analyzed, 12 constituents were detected. Two organic constituents, chloroform and tetrachloroethene (PCE), were detected in more than 10 percent of samples, but were detected mostly at low relative-concentrations.

California↗

The effects of forest cover on base flow of streams in the mountainous interior of Puerto Rico, 2010

The U.S. Geological Survey, in cooperation with the Puerto Rico Department of Natural and Environmental Resources, completed a study to determine whether a relation exists between the extent of forest cover and the magnitude of base flow at two sets of paired drainage basins in the highlands of the municipalities of Adjuntas and Utuado within the mountainous interior of Puerto Rico. One set of paired basins includes the Río Guaónica and Río Tanamá, both tributaries of the Río Grande de Arecibo. The other set includes two smaller basins in the drainage basin of the Río Coabey, which is a tributary of the Río Tanamá. The paired basins in each set have similar rainfall patterns, geologic substrate, and aspect; the principal difference identified in the study is the extent of forest cover and related land uses such as the cultivation of shade and sun coffee. Data describing the hydrology, hydrogeology, and streamflow were used in the analysis. The principal objective of the study was to compare base flow per unit area among basins having different areal extents of forest cover and land uses such as shade coffee and sun coffee cultivation. Within the mountainous interior of Puerto Rico, a substantial amount of the annual rainfall (45 to 39 percent in the Rio Guaónica and Rio Tanamá, respectively) can migrate to the subsurface and later emerge as base flow in streams. The magnitude of base flow within the two sets of paired basins varies seasonally. Minimum base flows occur during the annual dry season (generally from January to March), and maximum base flows occur during the wet season (generally from August to October). During the dry season or periods of below-normal rainfall, base flow is either the primary or the sole component of streamflow. Daily mean base flow ranged from 3.2 to 20.5 cubic feet per second (ft3 /s) at the Rio Guaónica Basin, and from 4.2 to 23.0 ft3 /s at the Rio Tanamá Basin. The daily mean base flows during 2010 ranged from 0.28 to 0.98 ft3 /s at Tributary 1 and from 0.22 to 0.58 ft3 /s at Tributary 2 of the Rio Coabey. The normalized daily base flow at the Río Guaónica and Río Tanamá Basin during 2010 ranged from 1.3 to 8.1 cubic feet per second per square mile (ft3 /s)/mi2 and from 1.1 to 6.1 (ft3 /s)/mi2 , respectively. The normalized daily base flow for the basins of Tributary 1 and Tributary 2 of Río Coabey during 2010 ranged from 1.0 to 3.6 (ft3 /s)/mi2 and from 1.5 to 3.9 (ft3 /s)/mi2 , respectively. The normalized mean annual base flow is similar within the larger paired basins of Río Tanamá (2.74 [ft3 /s]/mi2 ) and Río Guaónica (3.15 [ft3 /s]/mi2 ). The mean annual base flow per unit area for both of these basins is about 79 percent of the mean annual streamflow. In the large paired basins, the proportion of Type I land use (forest patches, shade and mixed shade/sun coffee with associated cash crops) is substantially higher in Rio Guaónica Basin (81 percent) than in the Rio Tanamá Basin (59 percent), and the base flow per unit area is also higher. In the small paired basins of Rio Coabey, the proportion of Type I land use is much higher at Tributary 1 (52 percent) than at Tributary 2 (15 percent), but, in contrast to the large basins, the mean annual base flow per unit area is lower (2.22 and 2.62 [ft3 /s]/mi2 , respectively). There is no consistent relation between land use and normalized base flow between the two sets of paired basins in the study.

Scientific Investigations Report↗

Status of groundwater levels and storage volume in the Equus Beds aquifer near Wichita, Kansas, 2012 to 2014

Development of the Wichita well field in the Equus Beds aquifer in southwest Harvey County and northwest Sedgwick County began in the 1940s to supply water to the city of Wichita. The decline of water levels in the Equus Beds aquifer was noted soon after the development of the Wichita well field began. Development of irrigation wells began in the 1960s. City and agricultural withdrawals led to substantial water-level declines. Water-level declines likely enhanced movement of brines from past oil and gas activities near Burrton, Kansas, as well as natural saline water from the Arkansas River into the Wichita well field area. Large chloride concentrations may limit use, or require the treatment of water from the well field for irrigation or public supply. In 1993, the city of Wichita adopted the Integrated Local Water Supply Program to ensure an adequate water supply for the city through 2050 and manage effectively the part of the Equus Beds aquifer Wichita uses. The Integrated Local Water Supply Program uses several strategies to do this, including the Equus Beds Aquifer Storage and Recovery project. The purpose of the Aquifer Storage and Recovery project is to store water in the aquifer for later recovery, and help protect the aquifer from encroachment of a known oil-field-brine plume near Burrton and saline water from the Arkansas River. Since 1940, the U.S. Geological Survey, in cooperation with the city of Wichita, has monitored changes in the Equus Beds aquifer as part of Wichita’s effort to manage this resource effectively. Average water-level changes since predevelopment (before substantial pumpage began in the area) for winter 2012, summer 2012, winter 2013, and winter 2014 generally indicate greater declines in the central part of the study area than in either the basin storage or entire study area. In contrast, average water-level rises since 1993 for winter 2012, summer 2012, winter 2013, and winter 2014 were greater for the central part of the study area than for either the basin storage area or entire study area. This indicates the central part of the study area had more post-1993 water-level recovery than did the rest of the study area. In the central part of the study area, city water use decreased by about 40 percent, and irrigation water use increased by about 3 percent compared to pre-1993 peaks in 1992 and 1991, respectively, whereas irrigation water use outside the central part of the study area increased by about 24 percent from the pre-1993 peak in 1991. Part of the larger increase in irrigation pumpage probably was a result of drought-term and multiyear flex account permits, which were estimated to account for about 8 and 4 percent of irrigation pumpage in the study area in 2011 and 2012. There was a larger percentage storage-volume increase since 1993 in the central part of the study area than in either the basin storage area or the entire study area. Storage-volume in the central part of the study area during winter 2012, summer 2013, winter 2013, and winter 2014 recovered about 46,300 acre-feet or more compared to the storage volume in 1993. In summer 2012 and winter 2013, the storage-volume increase since 1993 was larger in the central part of the study area than in the entire study area, indicating the storage-volume increases in the central part of the study area offset decreases in storage volume in the rest of the study area. The larger increase in storage volume in the central part of the study area than in the rest of the study area probably was because of the Integrated Local Water Supply Program strategy that reduced city pumpage from the Equus Beds aquifer by about 40 percent. The current (winter 2014) storage volumes in the entire study area and the central part of the study area are about 94 and 96 percent of their respective predevelopment storage volumes or about 3,067,000 and 962,000 acre-feet, respectively.

Kansas↗

Quantifying canal leakage rates using a mass-balance approach and heat-based hydraulic conductivity estimates in selected irrigation canals, western Nebraska, 2007 through 2009

The water supply in areas of the North Platte River Basin in the Nebraska Panhandle has been designated as fully appropriated or overappropriated by the Nebraska Department of Natural Resources (NDNR). Enacted legislation (Legislative Bill 962) requires the North Platte Natural Resources District (NPNRD) and the NDNR to develop an Integrated Management Plan (IMP) to balance groundwater and surface-water supply and demand in the NPNRD. A clear understanding of the groundwater and surface-water systems is critical for the development of a successful IMP. The primary source of groundwater recharge in parts of the NPNRD is from irrigation canal leakage. Because canal leakage constitutes a large part of the hydrologic budget, spatially distributing canal leakage to the groundwater system is important to any management strategy. Surface geophysical data collected along selected reaches of irrigation canals has allowed for the spatial distribution of leakage on a relative basis; however, the actual magnitude of leakage remains poorly defined. To address this need, the U.S. Geological Survey, in cooperation with the NPNRD, established streamflow-gaging stations at upstream and downstream ends from two selected canal reaches to allow a mass-balance approach to be used to calculate daily leakage rates. Water-level and sediment temperature data were collected and simulated at three temperature monitoring sites to allow the use of heat as a tracer to estimate the hydraulic conductivity of canal bed sediment. Canal-leakage rates were estimated by applying Darcy's Law to modeled vertical hydraulic conductivity and either the estimated or measured hydraulic gradient. This approach will improve the understanding of the spatial and temporal variability of canal leakage in varying geologic settings identified in capacitively coupled resistivity surveys. The high-leakage potential study reach of the Tri-State Canal had two streamflow-gaging stations and two temperature monitoring sites along its length. Calculated leakage rates from the mass-balance approach varied from year to year and were generally dependent on local climatic conditions, and the timing and magnitude of the initial seasonal diversion into the Tri-State Canal. Leakage rates ranged from 0.98 meter per day (m/d) on June 22, 2007, to about to 0 m/d during July 2009. Drier conditions generally resulted in higher leakage rates because of reduced flow from Spottedtail Creek, lower groundwater levels near Spottedtail Creek, and no unmeasured flow entering the reach. Of the three years studied (2007-09), 2007 was the driest, and therefore had the highest canal leakage rates. The moderately low leakage potential study reach of Interstate Canal had two streamflow-gaging stations and one temperature monitoring site along its length. Excluding the leakage calculations from early May 2007, leakage rates ranged from 0.08 to 0.7 m/d. Less variability in leakage from year to year indicates that climatic conditions may have less of an effect for Interstate Canal compared to Tri-State Canal. This may be because Interstate Canal was cut into the northern edge of the North Platte alluvial valley and consequently the canal bed is well above the local groundwater table resulting in a constant (1 meter per meter [m/m]) hydraulic gradient. Interstate Canal also does not receive any captured flow that can vary substantially year to year. Two temperature monitoring sites were installed within the high-leakage potential reach of Tri-State Canal. Site TCTEMP1 was established in 2007 where the water table was well below the canal bed surface. The vertical hydraulic conductivity of the poorly sorted sand and gravel beneath site TCTEMP1 was estimated using a calibrated one-dimensional VS2DH model. Using a trial-and-error approach, the best-fit vertical hydraulic conductivity for the site TCTEMP1 model domain was 1.1 m/d. Site TCTEMP2 was established at the mouth of Spottedtail Creek where a shallow

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