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At least 1,729 records · Page 96Linked to original sources

The record of major quaternary sea-level changes in a large coastal plain estuary, Chesapeake Bay, Eastern United States

Seismic-reflection surveys of the Chesapeake Bay, combined with geologic mapping and analysis of boreholes on the Delmarva Peninsula, provide evidence of at least three generations of the Susquehanna River system and three generations of the Chesapeake Bay. The evidence for ancient courses of the Susquehanna River is preserved as three distinct paleochannels, and evidence for ancient versions of the Chesapeake Bay is preserved as three sets of paleochannel fill beneath the bay and three generations of barrier-spit deposits on the southern Delmarva Peninsula. The paleochannels represent relative sea-level minima and the channel-fill and barrier-spit deposits represents relative sea-level maxima. A history of three major marine transgressions is recorded in the stratigraphy preserved in the filled paleochannels and in the overlying barrier-spit complexes: three systematic progressions from fluvial to estuarine to bay or nearshore marine environments. This sea-level record seems to be compatible with the saw-toothed pattern of the marine oxygen-isotope record and with the concept of glacial-interglacial terminations. It also seems to have a climax character in which most of the preserved evidence is related to the largest terminations and to the extreme sea-level positions that bound those terminations. The three paleochannel-fill and barrier-spit complexes appear to correspond to oxygen-isotope stages 1,5, and either 7 or 11; the three related paleochannels correspond to stages 2, 6, and either 8 or 12.

Delaware, Maryland, Virginia↗

Moment tensor solutions estimated using optimal filter theory for 51 selected earthquakes, 1980-1984

The 51 global events that occurred from January 1980 to March 1984, which were chosen by the convenors of the Symposium on Seismological Theory and Practice, have been analyzed using a moment tensor inversion algorithm (Sipkin). Many of the events were routinely analyzed as part of the National Earthquake Information Center's (NEIC) efforts to publish moment tensor and first-motion fault-plane solutions for all moderate- to large-sized (mb>5.7) earthquakes. In routine use only long-period P-waves are used and the source-time function is constrained to be a step-function at the source (??-function in the far-field). Four of the events were of special interest, and long-period P, SH-wave solutions were obtained. For three of these events, an unconstrained inversion was performed. The resulting time-dependent solutions indicated that, for many cases, departures of the solutions from pure double-couples are caused by source complexity that has not been adequately modeled. These solutions also indicate that source complexity of moderate-sized events can be determined from long-period data. Finally, for one of the events of special interest, an inversion of the broadband P-waveforms was also performed, demonstrating the potential for using broadband waveform data in inversion procedures. ?? 1987.

Physics of the Earth and Planetary Interiors↗

Coarse-grained deltaic sedimentation in the Miocene Cuyama strike-slip basin, California Coast Ranges

The Cuyama basin, located in the southern Coast Ranges of California southwest of the San Andreas fault, developed early in the history of the San Andreas transform system. The Miocene marine basin formed in a transtensional setting along a dextral strike-slip fault of the transform system following Oligocene non-marine basin formation in an extensional setting. The lower and middle Miocene Vaqueros Formation in the northwestern part of the basin, which represents the first of two transgressive-regressive cycles, is described here in terms of nine facies in two broad facies groups. The 400-m-thick Soda Lake Shale Member (of the Vaqueros) comprises deep-basin and starved-basin facies. A thin transgressive facies occurs locally at the base of the formation. The overlying Painted Rock Sandstone Member (of the Vaqueros), which is more than 2200 m thick and consists mostly of coarse-grained sandstone and pebbly sandstone, constitutes a delta complex of prodelta, slope channel, delta front, tide-influenced distributary channel, interdistributary bay, and fluvial channel facies. The basinal depositional system consisted of turbidite mud and sand, and hemipelagic and pelagic sediments of the basinal facies deposited in a rapidly subsiding basin. The delta depositional system consisted of the delta complex facies that prograded into the deep basin and had a steep prodelta slope that extended to bathyal depths. The delta is inferred to be a mixed fluvial-wave-dominated fan delta, analogous in its delta-front morphology and processes to a fjord delta, in which coarse sediment delivered to the delta front by braided streams was transported down the prodelta slope into deep water by sediment gravity flows. Transgression and rapid deepening of the basin in the early Miocene coincided with rapid tectonic subsidence. Deepening culminated with deposition of a starved-basin facies or condensed section at the time of maximum transgression, which was followed by the beginning of a regression and basin shallowing. The overall basin history and geometry of the northwestern Cuyama basin are typical of strike-slip basins. The initial rapid subsidence to bathyal depths at rates of more than 500 m/m.y. in the early Miocene is interpreted to be a result of extension at the releasing bend of a dextral strike-slip fault.

California↗

Mediterranean undercurrent sandy contourites, Gulf of Cadiz, Spain

The Pliocene—Quaternary pattern of contourite deposits on the eastern Gulf of Cadiz continental slope results from an interaction between linear diapiric ridges that are perpendicular to slope contours and the Mediterranean undercurrent that has flowed northwestward parallel to the slope contours and down valleys between the ridges since the late Miocene opening of the Strait of Gibraltar. Coincident with the northwestward decrease in undercurrent speeds from the Strait there is the following northwestward gradation of sediment facies associations: (1) upper slope facies, (2) sand dune facies on the upstream mid-slope terrace, (3) large mud wave facies on the lower slope, (4) sediment drift facies banked against the diapiric ridges, and (5) valley facies between the ridges. The southeastern sediment drift facies closest to Gibraltar contains medium-fine sand beds interbedded with mud. The adjacent valley floor facies is composed of gravelly, shelly coarse to medium sand lags and large sand dunes on the valley margins. Compared to this, the northwestern drift contains coarse silt interbeds and the adjacent valley floors exhibit small to medium sand dunes of fine sand. Further northwestward, sediment drift grades to biogenous silt near the Faro Drift at the Portuguese border. Because of the complex pattern of contour-parallel and valley-perpendicular flow paths of the Mediterranean undercurrent, the larger-scale bedforms and coarser-grained sediment of valley facies trend perpendicular to the smaller-scale bedforms and finer-grained contourite deposits of adjacent sediment drift facies. The bottom-current deposits of valleys and the contourites of the Cadiz slope intervalley areas are distinct from turbidite systems. The valley sequences are not aggradational like turbidite channel—levee complexes, but typically exhibit bedrock walls against ridges, extensive scour and fill into adjacent contourites, transverse bedform fields and bioclastic lag deposits. Both valley and contourite deposits exhibit reverse graded bedding and sharp upper bed contacts in coarse-grained layers, low deposition rates, and a regional pattern of bedform zones, textural variation, and compositional gradation. The surface sandy contourite layer of 0.2–1.2 m thickness that covers the Gulf of Cadiz slope has formed during the present Holocene high sea level because high sea level results in maximum water depth over the Gibraltar sill and full development of the Mediterranean undercurrent. The late Pleistocene age of the mud underlying the surface sand sheet correlates with the age of the last sea-level lowstand and apparent weak Mediterranean undercurrent development. Thus, the cyclic deposition of sand or mud layers and contourite or drape sequences appear to be related to late Pliocene and Quaternary sea-level changes and Mediterranean water circulation patterns. Since its Pliocene origin, the contourite sequence has had low deposition rates of < 5 cm/1000y on the upper slope and < 13 cm/1000y in the middle slope sediment drift.

Gulf of Cadiz↗

A rapid geochemical spectrophotometric determination of tungsten with dithiol

1-g sample is decomposed with nitric and hydrofluoric acids, and after evaporation of the solution to dryness the residue is dissolved in concentrated hydrochloric acid. A clear aliquot is treated with stannous chloride to inhibit interferences. The blue tungsten dithiol complex is developed at a temperature of 85° over a half-hour period. The complex is extracted into 2 ml of heptane and the tungsten is determined spectrophotometrically with a sensitivity of 0.5 ppm. Fifty samples per man-day can be analysed in this manner.

Talanta↗

Tectonics of Antarctica

Antarctica consists of large and wholly continental east Antarctica and smaller west Antarctica which would form large and small islands, even after isostatic rebound, if its ice cap were melted. Most of east Antarctica is a Precambrian Shield, in much of which charnockites are characteristic. The high Transantarctic Mountains, along the Ross and Weddell Seas, largely follow a geosyncline of Upper Precambrian sedimentary rocks that were deformed, metamorphosed and intruded by granitic rocks during Late Cambrian or Early Ordovician time. The rocks of the orogen were peneplained, then covered by thin and mostly continental Devonian-Jurassic sediments, which were intruded by Jurassic diabase sheets and overlain by plateau-forming tholeiites. Late Cenozoic doming and block-faulting have raised the present high mountains. Northeastern Victoria Land, the end of the Transantarctic Mountains south of New Zealand, preserves part of a Middle Paleozoic orogen. Clastic strata laid unconformably upon the Lower Paleozoic plutonic complex were metamorphosed at low grade, highly deformed and intruded by Late Devonian or Early Carboniferous granodiorites. The overlying Triassic continental sedimentary rocks have been broadly folded and normal-faulted. Interior west Antarctica is composed of miogeosynclinal clastic and subordinate carbonate rocks which span the Paleozoic Era and which were deformed, metamorphosed at generally low grade, and intruded by granitic rocks during Early Mesozoic time and possibly during other times also. Patterns of orogenic belts, if systematic, cannot yet be defined; but fragmentation and rotation of crustal blocks by oroclinal folding and strike-slip faulting can be suggested. The Ellsworth Mountains, for example, consist of Cambrian-Permian metasedimentary rocks that strike northward toward the noncorrelative and latitudinally striking Mesozoic terrane of the Antarctic Peninsula in one direction and southward toward that of the Lower Paleozoic: terrane of the Transantarctic Mountains in the other; the three regions may be separated by great strike-slip faults. The Antarctic Peninsula in west Antarctica, south of South America, consists of metavolcanic and metasedimentary rocks intruded by Late Cretaceous quartz diorite. The pre-granitic rocks are of Jurassic and Early Cretaceous ages wherever they have been dated by fossils, although some crystalline complexes may be older. The S-shape of the peninsula may represent oroclinal bending within Cenozoic time as part of a motion system in which a narrow continental bridge between South America and Antarctica was deformed and ruptured. Perhaps this bridge lagged behind as the larger continental plates drifted into the Pacific Ocean Basin.

Tectonophysics↗

Surface faults in the gulf coastal plain between Victoria and Beaumont, Texas

Displacement of the land surface by faulting is widespread in the Houston-Galveston region, an area which has undergone moderate to severe land subsidence associated with fluid withdrawal (principally water, and to a lesser extent, oil and gas). A causative link between subsidence and fluid extraction has been convincingly reported in the published literature. However, the degree to which fluid withdrawal affects fault movement in the Texas Gulf Coast, and the mechanism(s) by which this occurs are as yet unclear. Faults that offset the ground surface are not confined to the large (>6000-km 2 ) subsidence “bowl” centered on Houston, but rather are common and characteristic features of Gulf Coast geology. Current observations and conclusions concerning surface faults mapped in a 35,000-km 2 area between Victoria and Beaumont, Texas (which area includes the Houston subsidence bowl) may be summarized as follows: (1) Hundreds of faults cutting the Pleistocene and Holocene sediments exposed in the coastal plain have been mapped. Many faults lie well outside the Houston-Galveston region; of these, more than 10% are active, as shown by such features as displaced, fractured, and patched road surfaces, structural failure of buildings astride faults, and deformed railroad tracks. (2) Complex patterns of surface faults are common above salt domes. Both radial patterns (for example, in High Island, Blue Ridge, Clam Lake, and Clinton domes) and crestal grabens (for example, in the South Houston and Friendswood-Webster domes) have been recognized. Elongate grabens connecting several known and suspected salt domes, such as the fault zone connecting Mykawa, Friendswood-Webster, and Clear Lake domes, suggest fault development above rising salt ridges. (3) Surface faults associated with salt domes tend to be short (<5 km in length), numerous, curved in map view, and of diverse trend. Intersecting faults are common. In contrast, surface faults in areas unaffected by salt diapirism are frequently mappable for appreciable distances (>10 km), occur singly or in simple grabens, have gently sinuous traces, and tend to lie roughly parallel to the ENE-NE “coastwise” trend common to regional growth faults identified in subsurface Tertiary sediments. (4) Evidence to support the thesis that surface scarps are the shallow expression of faults extending downward into the Tertiary section is mostly indirect, but nonetheless reasonably convincing. Certainly the patterns of crestal grabens and radiating faults mapped on the surface above salt domes are more than happenstance; analogous fault patterns have been documented around these structures at depth. Similarly, some of the long surface faults not associated with salt domes seem to have subsurface counterparts among known regional growth faults documented through well logs and seismic data. Correlations between surface scarps and faults offsetting subsurface data are not conclusive because of the large vertical distances (1900- 3800 m) involved in making the most of the inferred connections. Nevertheless, the large number of successful correlations - in trend, movement sense, and position - suggests that many surface scarps represent merely the most recent displacements on faults formed during the Tertiary. (5) Upstream-facing fault scarps in this region of low relief can be significant impediments to streams. Locally, both abandoned, mud-filled Pleistocene distributary channels and, more commonly, Holocene drainage lines still occupied by perennial streams reflect the influence of faulting on their development. Some bend sharply near faults and have tended to flow along or pond against the base of scarps; others meander within topographically expressed grabens. Such evidence for Quaternary displacement of the ground surface is widespread in the Texas Gulf coast. In the general, however, streams in areas now offset by faulting show no disruption of their courses where they cross fault scarps. Such scarps are probably very young, and where they can be demonstrated to partly or wholly predate fluid withdrawal, very recent natural fault activity is indicated. (6) Early aerial photographs (1930) of the entire region and topographic maps (1915-16 surveys) of Harris County (Houston and vicinity) show that many faults had already displaced the land surface at a time when appreciable pressure declines in subjacent strata were localized to relatively few areas of large-scale pumping. Prehistoric faulting of the land surface, as noted above, appears to have affected much of the Texas Gulf Coast. (7) A relation between groundwater extraction and current motion on active faults is suspected because of the increased incidence of ground failure in the Houston-Galveston subsidence bowl. This argument is weakened somewhat by recognition of numerous surface faults, some of them active today, far beyond the periphery of the strongly subsiding area. Moreover, tilt beam records from two monitored faults in northwest Houston and accounts of fault damage from local residents demonstrate a complex, episodic nature of fault creep which can only partially be correlated with groundwater production. Nevertheless, although specific mechanisms are in doubt, the extraction of groundwater from shallow (<800-m) sands is probably a major factor in contributing to current displacement of the ground surface in the Houston-Galveston region. Within this large area, the number of faults recognizable from aerial photographs has increased at least tenfold between 1930 and 1970. Elsewhere in the Texas Gulf Coast only a moderate increase has been noted, some of which is possibly attributable to oil and gas production. Surface fault density in the Houston-Galveston region is far greater than in any other area of the Texas Gulf Coast investigated to date. A plausible explanation for these differences is that large overdrafts of groundwater over an extended period of time in the Houston-Galveston region have stimulated fault activity there. Throughout the Texas Gulf Coast, however, a natural contribution to fault motion remains a distinct possibility.

Texas↗

The pyramid system for multiscale raster analysis

Geographical research requires the management and analysis of spatial data at multiple scales. As part of the U.S. Geological Survey's global change research program a software system has been developed that reads raster data (such as an image or digital elevation model) and produces a pyramid of aggregated lattices as well as various measurements of spatial complexity. For a given raster dataset the system uses the pyramid to report: (1) mean, (2) variance, (3) a spatial autocorrelation parameter based on multiscale analysis of variance, and (4) a monofractal scaling parameter based on the analysis of isoline lengths. The system is applied to 1-km digital elevation model (DEM) data for a 256-km2 region of central California, as well as to 64 partitions of the region. PYRAMID, which offers robust descriptions of data complexity, also is used to describe the behavior of topographic aspect with scale. ?? 1993.

Computers & Geosciences↗

Rotational reflectance properties of Arkoma Basin dispersed vitrinite: Insights for understanding reflectance populations in high thermal maturity regions

Analysis and interpretation of dispersed vitrinite reflectance data in regions of high thermal maturity (> 2% vitrinite reflectance) have been equivocal partly because of an increase in width and complexity of reflectance histograms with increasing mean reflectance. Such complexity is illustrated by random reflectance ( R ran ) data from the Arkoma Basin that display a linear increase in standard deviation of R ran with an increase in mean R ran from 1 to 5%. Evaluating how much of the dispersion in these data is the result of vitrinite anisotropy and how much is the result of mixing of kerogen populations by sedimentary processes and/or sampling procedures has been problematic. Automated collection of reflectance data during polarizer rotation provides preliminary data for solution of this problem. Rotational reflectance data collected from a subset of Arkoma Basin samples reveal positive, linear relationships among maximum ( R ′ max ), random ( R ran ), rotational ( R rot ), and minimum ( R ′ min ) reflectance, as well as a systematic increase in bireflectance ( R ′ max – R ′ min ) with increasing reflectance. R ′ max and R rot display lower standard deviations and narrower, more nearly unimodal histograms than R ran and R ′ min , suggesting that R ′ max and R rot are superior (less ambiguous) indices of thermal maturity. These data patterns are inferred to be mostly an indication of increasing vitrinite anisotropy with increasing thermal maturity, suggesting that the linear covariance observed between mean R ran and standard deviation in dispersed organic data sets from regions of high thermal maturity may be explained mostly as the result of increasing vitrinite anisotropy with increasing thermal maturity.

Arkansas, Oklahoma↗

Studies of angiospermous woods in Australian brown coal by nuclear magnetic resonance and analytical pyrolysis: new insight into early coalification

Many Tertiary coals contain abundant fossilized remains of angiosperms, which commonly dominated the ancient peat-swamp environments; modern analogs of such swamps can be found in tropical and subtropical regions of the world. Comparisons of angiospermous wood from Australian brown coal with similar wood buried in modern peat swamps of Indonesia have provided some new insights into coalification reactions. These comparisons were made by using solid-state 13 C nuclear magnetic resonance (NMR) techniques and pyrolsis-gas chromatography-mass spectrometry (py-gc-ms). These two modern techniques are especially suited for detailed structural evaluation of the complex macromolecules in coal. The earliest transformation (peatification) of organic matter in angiospermous wood is the degradation and removal of cellulosic components and the concomitant selective preservation of lignin-derived components. The angiospermous lignin that becomes enriched in wood as a result of cellulose degradation also is modified by coalification reactions; this modification, however, does not involve degradation and removal of the lignin. Rather, the early coalification process transforms the lignin phenols (guiacyl and syringyl) to eventually yield the aromatic structures typically found in brown coal. One such transformation, which is determined from NMR data, involves the cleavage of aryl-ether bonds that link guaiacyl and syringyl units in lignin, and this transformation leads to the formation of free lignin phenols. Another transformation, which is also determined from the NMR data, involves the loss of methoxyl groups, probably via demethylation, to produce catechol-like structures. Coincident with ether-cleavage and demethylation, the aromatic rings derived from lignin phenols become more carbon-substituted and cross linked, as determined by dipolar-dephasing NMR studies. This cross linking is probably responsible for preventing the lignin phenols, which are freed from the lignin macromolecule by ether cleavage, from being removed from the coal by dissolution. Pyrolysis data suggest that the syringyl units are altered more readily than are guaiacyl units, and this difference in resistance leads to an enrichment of the guaiacyl units in fossil angiospermous woods. Many of the coalification reactions noted above occur to some degree in all angiospermous fossil wood examined; however, some significant differences are observed in the degree of coalification of the fossil wood samples from the same burial depth in the brown coal. These differences indicate that the depth and duration of burial are probably not entirely responsible for the variations in degree of coalification. Different rates of degradation in peat may have contributed to the variations in the apparent degree of coalification; some woods may have been altered more rapidly at the peat stage than others. Although preliminary, this systematic study of botanically related wood in peat and coal results in a more detailed differentiation of coalification reactions than have previous investigations. The combined use of solid-state 13 C NMR and py-gc-ms has facilitated this detailed insight into the coalification of angiospermous wood.

International Journal of Coal Geology↗

Evolution and petroleum geology of Amlia and Amukta intra-arc summit basins, Aleutian Ridge

Amlia and Amukta Basins are the largest of many intra-arc basins formed in late Cenozoic time along the crest of the Aleutian Arc. Both basins are grabens filled with 2-5 km of arc-derived sediment. A complex system of normal faults deformed the basinal strata. Although initial deposits of late Micocene age may be non-marine in origin, by early Pliocene time, most of the basinfill consisted of pelagic and hemipelagic debris and terrigenous turbidite deposits derived from wavebase and subaerial erosion of the arc's crestal areas. Late Cenozoic volcanism along the arc commenced during or shortly after initial subsidence and greatly contributed to active deposition in Amlia and Amukta Basins. Two groups of normal faults occur: major boundary faults common to both basins and 'intra-basin' faults that arise primarily from arc-parallel extension of the arc. The most significant boundary fault, Amlia-Amukta fault, is a south-dipping growth fault striking parallel to the trend of the arc. Displacement across this fault forms a large half-graben that is separated into the two depocentres of Amlia and Amukta Basins by the formation of a late Cenozoic volcanic centre, Seguam Island. Faults of the second group reflect regional deformation of the arc and offset the basement floor as well as the overlying basinal section. Intra-basin faults in Amlia Basin are predominantly aligned normal to the trend of the arc, thereby indicating arc-parallel extension. Those in Amukta basin are aligned in multiple orientations and probably indicate a more complex mechanism of faulting. Displacement across intra-basin faults is attributed to tectonic subsidence of the massif, aided by depositional loading within the basins. In addition, most intra-basin faults are listric and are associated with high growth rates. Although, the hydrocarbon potential of Amlia and Amukta Basins is difficult to assess based on existing data, regional considerations imply that an adequate thermal history conducive to hydrocarbon generation has prevailed during the past 6-5 my. The possibility for source rocks existing in the lower sections of the basins is suggested by exposures of middle and upper Miocene carbonaceous mudstone on nearby Atka Island and the implication that euxinic conditions may have prevailed during the initial formation of the basins. Large structures have evolved to trap migrating hydrocarbons, but questions remain concerning the preservation of primary porosity in a sedimentary section rich in reactive volcaniclastic debris. ?? 1987.

Marine and Petroleum Geology↗

Hydrocarbon gas seeps of the convergent Hikurangi margin, North Island, New Zealand

Two hydrocarbon gas seeps, located about 13 km apart, have distinctive molecular and isotopic compositions. These seeps occur within separate tectonic melange units of narrow parallel trending and structurally complex zones with incorporated upper Cretaceous and Palaeogene passive continental margin deposits which are now compressively deformed and imbricated along the convergent Hikurangi margin of North Island, New Zealand. At Brookby Station within the Coastal High, the seeping hydrocarbon gas has a methane/ethane ratio of 48 and ??13C and ??D values of methane of -45.7 and -188???, respectively (relative to the PDB and SMOW standards). Within the complex core of the Elsthorpe Anticline at Campbell Station seep, gas has a methane/ethane ratio of about 12000, and the methane has ??13C and ??D values of -37.4 and -170???, respectively. The source of the gases cannot be positively identified, but the gases probably originate from the thermal decomposition of organic matter in tectonically disturbed upper Cretaceous and/or lower Tertiary sedimentary rocks of passive margin affinity and reach the surface by migration along thrust faults associated with tectonic melange. The geochemical differences between the two gases may result from differences in burial depths of similar source sediment. ?? 1989.

Marine and Petroleum Geology↗

Regional and local networks of horizontal control, Cerro Prieto geothermal area

The Cerro Prieto geothermal area in the Mexicali Valley 30 km southeast of Mexicali, Baja California, is probably deforming due to (1) the extraction of large volumes of steam and hot water, and (2) active tectonism. Two networks of precise horizontal control were established in Mexicali Valley by the U.S. Geological Survey in 1977 - 1978 to measure both types of movement as they occur. These networks consisted of (1) a regional trilateration net brought into the mountain ranges west of the geothermal area from survey stations on an existing U.S. Geological Survey crustal-strain network north of the international border, and (2) a local net tied to stations in the regional net and encompassing the area of present and planned geothermal production. Survey lines in this net were selected to span areas of probable ground-surface movements in and around the geothermal area. Electronic distance measuring (EDM) instruments, operating with a modulated laser beam, were used to measure the distances between stations in both networks. The regional net was run using a highly precise long-range EDM instrument, helicopters for transportation of men and equipment to inaccessible stations on mountain peaks, and a fixed wing airplane flying along the line of sight. Precision of measurements with this complex long-range system approached 0-2 ppm of line length. The local net was measured with a medium-range EDM instrument requiring minimal ancillary equipment. Precision of measurements with this less complex system approached 3 ppm for the shorter line lengths. The detection and analysis of ground-surface movements resulting from tectonic strains or induced by geothermal fluid withdrawal is dependent on subsequent resurveys of these networks. ?? 1979.

Geothermics↗

The Geysers-Clear Lake geothermal area, California - An updated geophysical perspective of heat sources

The Geysers-Clear Lake geothermal area encompasses a large dry-steam production area in The Geysers field and a documented high-temperature, high-pressure, water-dominated system in the area largely south of Clear Lake, which has not been developed. Both systems have been extensively studied with geophysical techniques, drilling, and geological mapping during the past 20 years. An updated view is presented of the geological/geophysical complexities of the crust in The Geysers-Clear Lake region in order to address key unanswered questions about the heat source and tectonics. Early geophysical interpretations used a gravity low centered in the area between Clear Lake and The Geysers to suggest that a large magma chamber existed at depths starting at about 7 km. This first-order assumption of a large magma chamber expressed in the gravity data was used as a guide in subsequent geophysical and geological interpretations. Drill-hole temperature evidence is strongly suggestive of a shallow, hot-intrusive body, but in this paper the complexities are documented of the geological and geophysical data sets that make it difficult to pinpoint the location of “magma” or hot, solidified intrusive material. Forward modeling, multidimensional inversions, and ideal body analysis of the gravity data, new electromagnetic sounding models, and arguments made from other geophysical data sets suggest that many of the geophysical anomalies have significant contributions from rock property and physical state variations in the upper 7 km and not from ”magma“ at greater depths. Regional tectonic and magmatic processes are analyzed to develop an updated scenario for pluton emplacement that differs substantially from earlier interpretations. In addition, a rationale is outlined for future exploration for geothermal resources in The Geysers-Clear Lake area.

Geothermics↗

Aquatic photolysis: photolytic redox reactions between goethite and adsorbed organic acids in aqueous solutions

Photolysis of mono and di-carboxylic acids that are adsorbed onto the surface of the iron oxyhydroxide (goethite) results in an oxidation of the organic material and a reduction from Fe(III) to Fe(II) in the iron complex. There is a subsequent release of Fe2+ ions into solution. At constant light flux and constant solution light absorption, the factors responsible for the degree of photolytic reaction include: the number of lattice sites that are bonded by the organic acid; the rate of acid readsorption to the surface during photolysis; the conformation and structure of the organic acid; the degree of oxidation of the organic acid; the presence or absence of an ??-hydroxy group on the acid, the number of carbons in the di-acid chain and the conformation of the di-acid. The ability to liberate Fe(III) at pH 6.5 from the geothite lattice is described by the lyotropic series: tartrate>citrate> oxalate > glycolate > maleate > succinate > formate > fumarate > malonate > glutarate > benzoate = butanoate = control. Although a larger amount of iron is liberated, the series is almost the same at pH 5.5 except that oxalate > citrate and succinate > maleate. A set of rate equations are given that describe the release of iron from the goethite lattice. It was observed that the pH of the solution increases during photolysis if the solutions are not buffered. There is evidence to suggest the primary mechanism for all these reactions is an electron transfer from the organic ligand to the Fe(III) in the complex. Of all the iron-oxyhydroxide materials, crystalline goethite is the least soluble in water; yet, this study indicates that in an aqueous suspension, iron can be liberated from the goethite lattice. Further, it has been shown that photolysis can occur in a multiphase system at the sediment- water interface which results in an oxidation of the organic species and release of Fe2+ to solution where it becomes available for further reaction. ?? 1993.

Journal of Photochemistry and Photobiology A: Chem↗

Application of models to conservation planning for terrestrial birds in North America

Partners in Flight (PIF), a public–private coalition for the conservation of land birds, has developed one of four international bird conservation plans recognized under the auspices of the North American Bird Conservation Initiative (NABCI). Partners in Flight prioritized species most in need of conservation attention and set range-wide population goals for 448 species of terrestrial birds. Partnerships are now tasked with developing spatially explicit estimates of the distribution, and abundance of priority species across large ecoregions and identifying habitat acreages needed to support populations at prescribed levels. The PIF Five Elements process of conservation design identifies five steps needed to implement all bird conservation at the ecoregional scale. Habitat assessment and landscape characterization describe the current amounts of different habitat types and summarize patch characteristics, and landscape configurations that define the ability of a landscape to sustain healthy bird populations and are a valuable first step to describing the planning area before pursuing more complex species-specific models. Spatially linked database models, landscape-scale habitat suitability models, and statistical models are viable alternatives for predicting habitat suitability or bird abundance across large planning areas to help assess conservation opportunities, design landscapes to meet population objectives, and monitor change in habitat suitability or bird numbers over time. Bird conservation in the United States is a good example of the use of models in large-scale wildlife conservation planning because of its geographic extent, focus on multiple species, involvement of multiple partners, and use of simple to complex models. We provide some background on the recent development of bird conservation initiatives in the United States and the approaches used for regional conservation assessment and planning. We focus on approaches being used for landscape characterization and assessment, and bird population response modeling.

Book chapter↗

Interactions among hydrogeomorphology, vegetation, and nutrient biogeochemistry in floodplain ecosystems

Hydrogeomorphic, vegetative, and biogeochemical processes interact in floodplains resulting in great complexity that provides opportunities to better understand linkages among physical and biological processes in ecosystems. Floodplains and their associated river systems are structured by four dimensional gradients of hydrogeomorphology: longitudinal, lateral, vertical, and temporal components. These four dimensions create dynamic hydrologic and geomorphologic mosaics that have a large imprint on the vegetation and nutrient biogeochemistry of floodplains. Plant physiology, population dynamics, community structure, and productivity are all very responsive to floodplain hydrogeomorphology. The strength of this relationship between vegetation and hydrogeomorphology is evident in the use of vegetation as an indicator of hydrogeomorphic processes. However, vegetation also influences hydrogeomorphology by modifying hydraulics and sediment entrainment and deposition that typically stabilize geomorphic patterns. Nitrogen and phosphorus biogeochemistry commonly influence plant productivity and community composition, although productivity is not limited by nutrient availability in all floodplains. Conversely, vegetation influences nutrient biogeochemistry through direct uptake and storage as well as production of organic matter that regulates microbial biogeochemical processes. The biogeochemistries of nitrogen and phosphorus cycling are very sensitive to spatial and temporal variation in hydrogeomorphology, in particular floodplain wetness and sedimentation. The least studied interaction is the direct effect of biogeochemistry on hydrogeomorphology, but the control of nutrient availability over organic matter decomposition and thus soil permeability and elevation is likely important. Biogeochemistry also has the more documented but indirect control of hydrogeomorphology through regulation of plant biomass. In summary, the defining characteristics of floodplain ecosystems are determined by the many interactions among physical and biological processes. Conservation and restoration of the valuable ecosystem services that floodplains provide depends on improved understanding and predictive models of interactive system controls and behavior.

Book chapter↗

1.13 – Emerging contaminants

Since the Industrial Revolution, a diversity of large-scale chemical innovations has impacted aquatic systems in urban environments. Beginning in the 1990s, there has been a growing scientific interest and public awareness of the effects of the chemicals used in domestic, commercial, industrial, and agricultural applications, referred to in this article as ‘emerging contaminants’ (ECs), on ecosystem and human health. The growing global population and its increasing demands on water supplies in conjunction with climate-induced changes in hydrologic regimes place stress on freshwater resources, resulting in a greater reliance on reuse of reclaimed municipal wastewater treatment plant (WWTP) effluents to meet human and environmental needs. WWTP effluents are a major source of ECs, and it is important to have an understanding of the chemical composition of the reclaimed water, because many ECs are biologically active and the effects of chronic exposure to low concentration complex mixtures are unknown. Several classes of ECs that have been shown to be widespread in the aquatic environment are discussed in this chapter, including surfactants, complexing agents, fragrances, antimicrobials, industrial chemicals, pharmaceuticals, natural and synthetic estrogens, and disinfection byproducts. All of these compounds are biologically active via a variety of modes of action, and can occur in aquatic systems at concentrations ranging from <0.001 to >100 μg l −1 .

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