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At least 1,711 records · Page 95Linked to original sources
USGS2000

Data and applications for study of the water cycle in Africa

There are a number data set development, data dissemination, and applications activities at the U.S. Geological Survey (USGS) that contribute to the study of the water cycle in Africa. Some of these stem from global change research initiatives, while others are the result of technical assistance provided to international development and humanitarian assistance projects. Data themes include topography and related hydrological derivatives, land cover, satellite rainfall estimates, and vegetation indices. Some data sets are USGS products, while others originate from cooperating agencies like NASA and NOAA and are distributed secondarily. In Africa, applications include agrometeorological estimates, drought and flood monitoring. Many of the data sets are available to the user community without charge by internet, or at cost of reproduction on CDROM and tape media.

Conference Paper↗
USGS1973

Hydrology and sediment transport, Moanalua Valley, Oahu, Hawaii

The first 2 years of intensive data collection in Moanalua Valley have resulted in some observations concerning the rainfall- runoff and rainfall-sedimentation characteristics of the basin. This initial study period has been concerned primarily with establishing a reliable hydrologic data-collection network. However, enough data have been collected to determine that rainfall within the valley shows extreme areal variations from one storm to another. An initial run on the U.S. Geological Survey small watershed model indicates some differences in basin characteristics in the two upper subregions. Results of model studies to date are encouraging. Flood routing with the Corps of Engineers' HEC-1 flood hydrograph package seems to be feasible. By preliminary estimates, the 50-year flood at gage 2282 would probably be between 5,500 and 6,000 cubic feet per second. The narrow, steep nature of Moanalua Valley results in very rapid concentration of runoff, with extremely sharp hydrograph peaks. Stream channel width ranges from about 20 feet in the headwaters to 35 feet near the downstream limit of the study area. Mean slope of the main stem is about 0.027 foot/foot.1/ Where not identified, units for slope are ft/ft. Observations indicate that the stream transports very large particles (in excess of 2 feet in diameter) quite frequently. Detached fragments from old stone-arch bridges have been marked in the channel fill for use as tracers. Only one storm has been analyzed for suspended-sediment discharge, but rough calculations indicate a possible suspended-sediment load of 12,000 tons for a storm similar to the design flow at gage 2282. This compares with a computed bedload discharge of 2,600 tons for the same flow. Accumulation in the debris basin between October 2, 1969 and July 26, 1971, as measured by level survey, was 48,000 cubic feet or about 2,900 tons.

Hawaii↗
USGS1983

U. S. GEOLOGICAL SURVEY LAND REMOTE SENSING ACTIVITIES.

USGS uses all types of remotely sensed data, in combination with other sources of data, to support geologic analyses, hydrologic assessments, land cover mapping, image mapping, and applications research. Survey scientists use all types of remotely sensed data with ground verifications and digital topographic and cartographic data. A considerable amount of research is being done by Survey scientists on developing automated geographic information systems that can handle a wide variety of digital data. The Survey is also investigating the use of microprocessor computer systems for accessing, displaying, and analyzing digital data.

Conference Paper↗
USGS2005

Evaluating water management strategies with the Systems Impact Assessment Model: SIAM version 4

Water from many of California's coastal rivers has been used for a wide variety of development ventures, including major agricultural diversions, hydropower generation, and contaminant assimilation from industry, agriculture and logging. Anthropogenic impacts often degrade water quality and decrease the quantity and quality of aquatic habitat. Reallocating streamflow away from uses that degrade water quality to uses that foster higher water quality is a critical step in restoring riverine habitat and the anadromous fish that rely on that habitat for a portion of their life cycle. Reallocation always brings with it the need to examine the economic efficiency of the proposed changes. If the dollar benefits of improving water quality are greater than the costs, the criterion of improving economic efficiency is satisfied, a fact that can be highly persuasive to decision makers contemplating reallocation. Previous related studies have examined nonmarket benefits of the Trinity River in northern California (Douglas and Taylor, 1998; Douglas and Taylor, 1999abc) but nothing of this kind had been done on the Klamath River, another system with numerous uses for and competition over water in times of drought. An economic survey is nearing completion for the mid- to lower Klamath River, including the Scott, Shasta, and Salmon Rivers, but excluding the Trinity River. This survey provides valuable insights about the magnitude of the benefits and nature of the costs of reallocating water from market uses to instream flows that improve water quality and assist in the recovery of Klamath River fish stocks. Preliminary survey results (Douglas and Johnson, 2002; Douglas and Sleeper, In Prep.) indicate that about 234,000 California, Oregon, and Nevada households made recreation trips to the Klamath River Basin 1997-1998 and that these users spent about $372 million on trip related expenditures. Clearly the prosperity of the region is closely linked to the demand for mid- and lower Klamath River Basin recreation trips. Further, respondents indicated that they would make roughly 36% more recreational trips per annum to the Klamath if the water quality and the fishery were restored to an unspoiled condition. Using two distinct types of survey data, these additional trips would yield benefits with a present value of approximately $9.6 billion (at a discount rate of 7.5%). Calculating costs to restore the fishery and raise water quality involved five major hypothetical restoration activities: (1) purchasing Klamath project farmland and environmentally sensitive forest lands, (2) allocating more water down the Trinity River to enhance the quantity and quality of Klamath flows below the confluence, (3) removing four mainstem dams along the Klamath River and losing their associated hydropower production, (4) eliminating all harvest of Klamath-Trinity fish stocks for a 12-year period including the acquisition of fishing rights from both tribal and commercial marine fishermen, and (5) operating all Klamath-Trinity fish hatcheries to restore self-reproducing stocks. In total, restoration costs were estimated to be about $1.7 to $2.3 billion. If the assumptions used in this study are valid, it is clear that the benefits ($9.6B) outweigh the costs of restoring water quality and the fishery. The apparent disparity between restoration benefits and costs for the Klamath River may suggest to some that water resources on the Klamath be reallocated to environmentally friendly nonmarket uses. The economic analysis rests in part on the information made available to the survey designers by the biological, hydrologic, and water quality data incorporated in The System Impact Assessment Model (SIAM). It is our hope that SIAM can be used to improve the river's water quality and fishery, and strengthen the important regional economy.

Open-File Report↗
USGS2010

Using land-cover change as dynamic variables in surface-water and water-quality models

Land-cover data are typically used in hydrologic modeling to establish or describe land surface dynamics. This project is designed to demonstrate the use of land-cover change data in surface-water and water-quality models by incorporating land-cover as a variable condition. The project incorporates three different scenarios that vary hydrologically and geographically: 1) Agriculture in the Plains, 2) Loon habitat in New England, and 3) Forestry in the Ozarks.

General Information Product↗
USGS2016

Science center capabilities to monitor and investigate Michigan’s water resources, 2016

Michigan faces many challenges related to water resources, including flooding, drought, water-quality degradation and impairment, varying water availability, watershed-management issues, stormwater management, aquatic-ecosystem impairment, and invasive species. Michigan’s water resources include approximately 36,000 miles of streams, over 11,000 inland lakes, 3,000 miles of shoreline along the Great Lakes (MDEQ, 2016), and groundwater aquifers throughout the State. The U.S. Geological Survey (USGS) works in cooperation with local, State, and other Federal agencies, as well as tribes and universities, to provide scientific information used to manage the water resources of Michigan. To effectively assess water resources, the USGS uses standardized methods to operate streamgages, water-quality stations, and groundwater stations. The USGS also monitors water quality in lakes and reservoirs, makes periodic measurements along rivers and streams, and maintains all monitoring data in a national, quality-assured, hydrologic database. The USGS in Michigan investigates the occurrence, distribution, quantity, movement, and chemical and biological quality of surface water and groundwater statewide. Water-resource monitoring and scientific investigations are conducted statewide by USGS hydrologists, hydrologic technicians, biologists, and microbiologists who have expertise in data collection as well as various scientific specialties. A support staff consisting of computer-operations and administrative personnel provides the USGS the functionality to move science forward. Funding for USGS activities in Michigan comes from local and State agencies, other Federal agencies, direct Federal appropriations, and through the USGS Cooperative Matching Funds, which allows the USGS to partially match funding provided by local and State partners. This fact sheet provides an overview of the USGS current (2016) capabilities to monitor and study Michigan’s vast water resources. More information regarding projects by the Michigan Water Science Center (MI WSC) is available at http://mi.water.usgs.gov/ .

Michigan↗
USGS2018

Hydrologic characteristics of freshwater mussel habitat: novel insights from modeled flows

The ability to model freshwater stream habitat and species distributions is limited by the spatially sparse flow data available from long-term gauging stations. Flow data beyond the immediate vicinity of gauging stations would enhance our ability to explore and characterize hydrologic habitat suitability. The southeastern USA supports high aquatic biodiversity, but threats, such as landuse alteration, climate change, conflicting water-resource demands, and pollution, have led to the imperilment and legal protection of many species. The ability to distinguish suitable from unsuitable habitat conditions, including hydrologic suitability, is a key criterion for successful conservation and restoration of aquatic species. We used the example of the critically endangered Tar River Spinymussel ( Parvaspina steinstansana ) and associated species to demonstrate the value of modeled flow data (WaterFALL™) to generate novel insights into population structure and testable hypotheses regarding hydrologic suitability. With ordination models, we: 1) identified all catchments with potentially suitable hydrology, 2) identified 2 distinct hydrologic environments occupied by the Tar River Spinymussel, and 3) estimated greater hydrological habitat niche breadth of assumed surrogate species associates at the catchment scale. Our findings provide the first demonstrated application of complete, continuous, regional modeled hydrologic data to freshwater mussel distribution and management. This research highlights the utility of modeling and data-mining methods to facilitate further exploration and application of such modeled environmental conditions to inform aquatic species management. We conclude that such an approach can support landscape-scale management decisions that require spatial information at fine resolution (e.g., enhanced National Hydrology Dataset catchments) and broad extent (e.g., multiple river basins).

North Carolina↗
USGS2011

Quantifying the hydrological responses to climate change in an intact forested small watershed in southern China

Responses of hydrological processes to climate change are key components in the Intergovernmental Panel for Climate Change (IPCC) assessment. Understanding these responses is critical for developing appropriate mitigation and adaptation strategies for sustainable water resources management and protection of public safety. However, these responses are not well understood and little long-term evidence exists. Herein, we show how climate change, specifically increased air temperature and storm intensity, can affect soil moisture dynamics and hydrological variables based on both long-term observation and model simulations using the Soil and Water Assessment Tool (SWAT) in an intact forested watershed (the Dinghushan Biosphere Reserve) in Southern China. Our results show that, although total annual precipitation changed little from 1950 to 2009, soil moisture decreased significantly. A significant decline was also found in the monthly 7-day low flow from 2000 to 2009. However, the maximum daily streamflow in the wet season and unconfined groundwater tables have significantly increased during the same 10-year period. The significant decreasing trends on soil moisture and low flow variables suggest that the study watershed is moving towards drought-like condition. Our analysis indicates that the intensification of rainfall storms and the increasing number of annual no-rain days were responsible for the increasing chance of both droughts and floods. We conclude that climate change has indeed induced more extreme hydrological events (e.g. droughts and floods) in this watershed and perhaps other areas of Southern China. This study also demonstrated usefulness of our research methodology and its possible applications on quantifying the impacts of climate change on hydrology in any other watersheds where long-term data are available and human disturbance is negligible.

Guangdong Province↗
USGS1955

Ground-water conditions between Oracle and Oracle Junction, Pinal County, Arizona

The development of the San Manuel copper prospect has greatly increased traffic along State Highway 77. Considerable interest in commercial possibilities along that road has resulted in a request by the Arizona State Land Department for information about the ground-water conditions between Oracle and Oracle Junction. This request came too late for information to be included in a recently completed memorandum report on the occurrence of ground water in the vicinity of Oracle, released in February 1955. These data are presented as a supplement to that report to minimized duplication of statements about the general geologic and hydrologic conditions. The necessary well data and sample descriptions that were not included in the Oracle report are shown in tables 3 and 4. The area discussed in this supplement comprises parts of Tps. 9 and 10 S., Rs. 13, 14, and 15 E., and includes about 90 square miles (fig. 3). The eastern portion overlaps part of the area covered by the earlier report.

Arizona↗
USGS2023

Assessment of conservation management practices on water quality and observed trends in the Plum Creek Basin, 2010–20

The U.S. Geological Survey and University of Wisconsin–Green Bay collected hydrologic and water-quality data to assess the effectiveness of agricultural conservation management practice (CMP) implementation at mainstem Plum Creek and west Plum Creek in northeastern Wisconsin. These two subbasins cover 88 percent of the Plum Creek Basin (Hydrologic Unit Code 12), which is a subbasin of the lower Fox River Basin. A published total maximum daily load report for the lower Fox River Basin rated Plum Creek as one of the greatest contributors of total suspended solids (TSS) and total phosphorus (TP) draining into the lower Fox River. To reduce TSS and TP exports from Plum Creek, additional cropland conservation practices and watercourse protections were applied between 2012 and 2020. To detect water-quality trends, data were collected during 2010 to 2020 at mainstem Plum Creek and 2013 to 2020 at west Plum Creek. The project used two methods to evaluate CMP effectiveness. The first method focused on evaluating water-quality changes between initial and post-CMP implementation periods during rain- or snowmelt-induced runoff events (hereafter referred to as “events”). In this approach random-forest models were developed to account for environmental factors which influence water quality. Model residuals from the two time periods were compared to determine the significance of water-quality changes associated with CMP implementation for mainstem and west Plum Creek Basins. The second method used a Weighted Regressions on Time, Discharge, and Season time-series approach to examine changes in water quality during the entire study period in mainstem Plum Creek. Results from both methods indicated there were minimal water-quality changes in TSS concentrations and flow-normalized delivery during runoff events during the 10-year period from 2010 to 2020; however, TP concentrations during low streamflow (less than 3 cubic feet per second [ft 3 /s]) may have decreased. The lack of observed improvement may be attributable to any of the following: variability in weather and hydrologic conditions, insufficient post-treatment data, additional cropland being converted to corn production, above average rainfall, streambank degradation, acute and legacy sources of phosphorus from farm fields, excessive/vulnerable manure applications and spills, and point-source discharges.

Wisconsin↗
USGS2015

Return to normal streamflows and water levels: Summary of hydrologic conditions in Georgia, 2013

The U.S. Geological Survey (USGS) South Atlantic Water Science Center (SAWSC) Georgia office, in cooperation with local, State, and other Federal agencies, maintains a long-term hydrologic monitoring network of more than 340 real-time continuous-record streamflow-gaging stations (streamgages), including 10 real-time lake-level monitoring stations, 67 real-time surface-water-quality monitors, and several water-quality sampling programs. Additionally, the SAWSC Georgia office operates more than 180 groundwater monitoring wells, 39 of which are real-time. The wide-ranging coverage of streamflow, reservoir, and groundwater monitoring sites allows for a comprehensive view of hydrologic conditions across the State. One of the many benefits of this monitoring network is that the analyses of the data provide a spatially distributed overview of the hydrologic conditions of creeks, rivers, reservoirs, and aquifers in Georgia. Streamflow and groundwater data are verified throughout the year by USGS hydrographers. Hydrologic conditions are determined by comparing the results of statistical analyses of the data collected during the current water year (WY) to historical data collected over the period of record. Changing hydrologic conditions emphasize the need for accurate, timely data to help Federal, State, and local officials make informed decisions regarding the management and conservation of Georgia’s water resources for agricultural, recreational, ecological, and water-supply needs and for use in protecting life and property. Drought conditions, persistent in the area since 2010, continued into the 2013 WY. In February 2013, Georgia was free of extreme (D3) drought conditions, as defined by the U.S. Drought Monitor, for the first time since August 2010 due to extended periods of heavy rainfall (U.S. Drought Monitor, 2013). According to the Office of the State Climatologist, the city of Savannah recorded 9.75 inches of rain in February 2013, the highest monthly total in February out of 143 years of record. Macon and Columbus also received record rainfalls in February 2013. Above-normal precipitation continued in June 2013, and the cities of Augusta and Savannah recorded the wettest June on record. In July, precipitation for the entire State of Georgia was 3.53 inches above normal (Dunkley, 2013). Above-normal rainfall from February to September 2013 increased streamflow and raised groundwater levels, and lakes and reservoirs were raised to full-pool elevations.

Georgia↗
USGS2015

Potential groundwater recharge for the State of Minnesota using the Soil-Water-Balance model, 1996-2010

Groundwater recharge is one of the most difficult components of a water budget to ascertain, yet is an important boundary condition necessary for the quantification of water resources. In Minnesota, improved estimates of recharge are necessary because approximately 75 percent of drinking water and 90 percent of agricultural irrigation water in Minnesota are supplied from groundwater. The water that is withdrawn must be supplied by some combination of (1) increased recharge, (2) decreased discharge to streams, lakes, and other surface-water bodies, and (3) removal of water that was stored in the system. Recent pressure on groundwater resources has highlighted the need to provide more accurate recharge estimates for various tools that can assess the sustainability of long-term water use. As part of this effort, the U.S. Geological Survey, in cooperation with the Minnesota Pollution Control Agency, used the Soil-Water-Balance model to calculate gridded estimates of potential groundwater recharge across Minnesota for 1996‒2010 at a 1-kilometer (0.621-mile) resolution. The potential groundwater recharge estimates calculated for Minnesota from the Soil-Water Balance model included gridded values (1-kilometer resolution) of annual mean estimates (that is, the means for individual years from 1996 through 2010) and mean annual estimates (that is, the mean for the 15-year period 1996−2010). The Soil-Water-Balance model uses a modified Thornthwaite-Mather soil-water-balance approach, with components of the soil-water balance calculated on a daily basis. A key advantage of this approach includes the use of commonly available geographic information system data layers that incorporate land cover, soil properties, and daily meteorological data to produce temporally and spatially variable gridded estimates of potential recharge. The Soil-Water-Balance model was calibrated by using a combination of parameter estimation techniques, making manual adjustments of model parameters, and using parameter values from previously published Soil-Water-Balance models. Each calibration simulation compared the potential recharge estimate from the model against base-flow estimates derived from three separate hydrograph separation techniques. A total of 35 Minnesota watersheds were selected for the model calibration. Meteorological data necessary for the model included daily precipitation, minimum daily temperature, and maximum daily temperature. All of the meteorological data were provided by the Daymet dataset, which included daily continuous surfaces of key climatological data. Land-cover data were provided by the 2001 and 2006 National Land Cover Database: the 2001 classification was used from 1994 through 2003, and the 2006 classification was used from 2004 through 2010. Soil data used in the model included hydrologic soils group and the available soil-water capacity. These soil data were obtained from the Natural Resources Conservation Service Soil Survey Geographic (SSURGO) database and the State Soil Geographic (STATSGO) database. The statewide mean annual potential recharge rate from 1996–2010 was 4.9 inches per year. Potential recharge estimates increased from west to east across Minnesota. The mean annual potential recharge estimates across Minnesota at a 1-km resolution for the overall simulation period (1996–2010) ranged from less than 0.1 to 17.8 inches per year. Some of the lowest potential recharge rates for the simulation period were in the Red River of the North Basin of northwestern Minnesota, and generally were between 1.0 and 1.5 inches per year. The highest potential recharge rates were in northeastern Minnesota and the Anoka Sand Plain in central Minnesota. Eighty-eight percent of the potential recharge rates (by grid cell) were between 2 and 8 inches per year from 1996–2010. Only about 3 percent of all the potential recharge estimates (by grid cell) were less than 2 inches per year, and 9 percent of estimates were greater than 8 inches per year. On an annual basis, however, potential recharge rates were as high as 27.2 inches per year. The highest annual mean recharge estimate across the State was for 2010, and the lowest mean recharge estimate was for 2003. Although precipitation variability partially explained the annual differences in potential recharge estimates, precipitation alone did not account for these differences, and other factors such as antecedent moisture conditions likely were important. Also, because precipitation gradients across the State can vary from year to year, the dominant land-cover class and hydrologic soil group combinations for a particular region had a large effect on the resulting potential recharge value. During 1996–2010, April had the greatest monthly mean potential recharge compared to all other months, accounting for a mean of 30 percent of annual potential recharge in this single month.

Minnesota↗
USGS2012

Reference hydrologic networks II. Using reference hydrologic networks to assess climate-driven changes in streamflow

Reference hydrologic networks (RHNs) can play an important role in monitoring for changes in the hydrological regime related to climate variation and change. Currently, the literature concerning hydrological response to climate variations is complex and confounded by the combinations of many methods of analysis, wide variations in hydrology, and the inclusion of data series that include changes in land use, storage regulation and water use in addition to those of climate. Three case studies that illustrate a variety of approaches to the analysis of data from RHNs are presented and used, together with a summary of studies from the literature, to develop approaches for the investigation of changes in the hydrological regime at a continental or global scale, particularly for international comparison. We present recommendations for an analysis framework and the next steps to advance such an initiative. There is a particular focus on the desirability of establishing standardized procedures and methodologies for both the creation of new national RHNs and the systematic analysis of data derived from a collection of RHNs.

Hydrological Sciences Journal↗
USGS2020

Time scales of arsenic variability and the role of high-frequency monitoring at three water-supply wells in New Hampshire, USA

Groundwater geochemistry, redox process classification, high-frequency physicochemical and hydrologic measurements, and climate data were analyzed to identify controls on arsenic (As) concentration changes. Groundwater was monitored in two public-supply wells (one glacial aquifer and one bedrock aquifer), and one bedrock-aquifer domestic well in New Hampshire, USA, from 2014 to 2018 to identify time scales of and controls on As concentration changes. Concentrations of As and other geochemical constituents were measured bimonthly. Specific conductance (SC), pH, dissolved oxygen, and pumping rate/water level were measured at high frequency (every 5 to 15 min). Median (and 95% confidence interval) As concentrations at the three wells were 4.1 (3.7–4.6), 18.9 (17.2–23.6), and 37.5 (30.4–42.9) μg/L. Arsenic variability in each of the three wells, in relative standard deviation, ranged from 9 to 12%. Median quarterly As concentrations were highest in all wells in the spring. The bedrock-aquifer public-supply well As concentration increased over the period of study while pumping rate decreased. In the public-supply wells, As variability was correlated with SC and pH, and As species were related to SC, pH, pumping, precipitation, and changes in redox process. Specific conductance also had a seasonal pattern in the two public-supply wells and was correlated with Na and Cl. Excess Na in water samples suggests possible ion exchange with dissolved Ca, creating more capacity to dissolve CaCO 3 from calcareous rocks, which can increase pH and in turn, As concentrations in wells. High-frequency monitoring data are cost effective to collect, which could be advantageous in other parts of the United States and in the many parts of the world where glacial aquifers are in direct contact with other water supply aquifers or where water from different aquifers have potential to mix.

New Hampshire↗
USGS2020

Trihalomethane precursors: Land use hot spots, persistence during transport, and management options

To meet drinking water regulations, rather than investing in costly treatment plant operations, managers can look for ways to improve source water quality; this requires understanding watershed sources and fates of constituents of concern. Trihalomethanes (THMs) are one of the major classes of regulated disinfection byproducts, formed when a specific fraction of the organic carbon pool—referred to as THM precursors—reacts with chorine and/or bromine during treatment. Understanding the source, fate, timing and duration of the organic compounds that react to form THMs will allow identification of targeted and effective management actions. In this study we evaluated THM precursor contributions from multiple land use categories and hydrologic contexts, including novel data for urban land uses that demonstrate strong potential to release water with high THM formation potential (THMFP; median 618 μg L −1 ): greater than storm runoff integrated across a mixed-use (1/3 natural, 2/3 agricultural) watershed (median 460 μg L −1 ), irrigation runoff from agricultural systems (357 μg L −1 ), or runoff from a natural forested (median 123 μg L −1 ) and shrubland/grassland (median 259 μg L −1 ) watersheds. While individual storm events released high THM precursor concentrations over short periods, dry season agricultural irrigation as well as urban landscapes have the potential to release water high in THM precursors for several months. Experimental bioassays and sampling along 333 miles of the California Aqueduct confirmed bioavailability and photooxidation potential of less than 10% for THM precursors, suggesting that rivers with residence times of days to weeks may act as THM precursor conduits, shuttling THM precursors from hundreds of miles away to drinking water intakes with minimal degradation. This finding has considerable implications for water managers, who may therefore consider THM precursor management strategies that target even sources located far upstream.

California↗
USGS2004

Molecular markers and their use in environmental organic geochemistry

Molecular markers are organic substances that carry information about sources of organic matter or contamination. The source/marker relation can be used to indicate the presence of a given source material (qualitative), or, under appropriate conditions, to estimate the amount of a source material (quantitative source apportionment) in the environment. Assemblages of markers can also be used as process probes. In this instance, systematic differences and/or similarities in the physical-chemical properties of markers are coupled with compositional changes in marker composition to infer the operation of natural processes. This paper provides an overview of what molecular markers are, what types of markers are present in the environment, the requirements for the use of markers, and some common applications. To illustrate how molecular markers can answer specific environmental questions, three case studies are presented. The first case study examines the impact of municipal waste on a large urban harbor (Boston Harbor). Linear alkylbenzenes (unreacted residues of linear alkylbenzenesulfonate surfactants) and coprostanol (a fecal indicator) provide information on the sources and likely transport pathways of municipal wastes in a complex hydrologic system. The marker data are also used to estimate the proportion of sewage-derived poly chlorinated biphenyls (PCBs) in polluted harbor sediments. The second case study concerns a portion of the continental shelf off southern California (Palos Verdes) where discharge of municipal wastewaters has led to extensive contamination of sediments and biota. Long-chain alkylbenzenes (surfactant residues), PCBs and the pesticide, DDT (dichlorodiphenyltrichloroethane), are used to develop sedimentation rate estimates for several time periods by molecular stratigraphy. These results, when combined with other information, allow conclusions to be drawn about the most likely transport pathway of sediments at the study site and to predict the fate of historically deposited contaminants. Finally, an investigation of a crude-oil spill in Bemidji, MN illustrates how monoaromatic hydrocarbons can be exploited as process probes, providing insights into the relative importance of different attenuation processes in a contaminated aquifer. The results show that natural attenuation of the monoaromatic hydrocarbons is occurring at this site and is dominated, not by physical and/or chemical processes, but by biodegradation.

Book chapter↗
USGS2005

Nitrogen transport and transformations in a coastal plain watershed: Influence of geomorphology on flow paths and residence times

Nitrogen transport and groundwater‐surface water interactions were examined in a coastal plain watershed in the southeastern United States. Groundwater age dates, calculated using chlorofluorocarbon and tritium concentrations, along with concentrations of nitrogen species and other redox‐active constituents, were used to evaluate the fate and transport of nitrate. Nitrate is stable only in recently recharged (<10 years) water found in the upper few meters of saturated thickness in the upland portion of a surficial aquifer. Groundwater with a residence time between 10 and 30 years typically has low nitrate and elevated excess N 2 concentrations, indications that denitrification has reduced nitrate concentrations. Groundwater older than 30 years also has low nitrate concentrations but contains little or no excess N 2 , suggesting that this water did not contain elevated concentrations of nitrate along its flow path. Nitrate transport to streams varies between first‐ and third‐order streams. Hydrologic, lithologic, and chemical data suggest that the surficial aquifer is the dominant source of flow and nitrate to a first‐order stream. Iron‐reducing conditions occur in groundwater samples from the bed and banks of the first‐order stream, suggesting that direct groundwater discharge is denitrified prior to entering the stream. However, nitrogen from the surficial aquifer is transported directly to the stream via a tile drain that bypasses these reduced zones. In the alluvial valley of a third‐order stream the erosion of a confining layer creates a much thicker unconfined alluvial aquifer with larger zones of nitrate stability. Age dating and chemical information (SiO 2 , Na/K ratios) suggest that water in the alluvial aquifer is derived from short flow paths through the riparian zone and/or from adjacent streams during high‐discharge periods.

Water Resources Research↗
USGS2011

Classifying the water table at regional to continental scales

Water tables at regional to continental scales can be classified into two distinct types: recharge-controlled water tables that are largely disconnected from topography and topography-controlled water tables that are closely tied to topography. We use geomatic synthesis of hydrologic, geologic and topographic data sets to quantify and map water-table type over the contiguous United States using a dimensionless criterion introduced by Haitjema and Mitchell-Bruker (2005), called the water-table ratio, which differentiates water-table type. Our analysis indicates that specific regions of the United States have broadly contiguous and characteristic water-table types. Water-table ratio relates to water-table depth and the potential for regional groundwater flow. In regions with recharge-controlled water tables, for example the Southwest or Rocky Mountains, USA, water-tables depths are generally greater and more variable and regional groundwater flow is generally more important as a percentage of the watershed budget. Water-table depths are generally shallow and less variable, and regional groundwater flow is limited in areas with topography-controlled water tables such as the Northeast USA. The water-table ratio is a simple but powerful criterion for evaluating regional groundwater systems over broad areas.

Geophysical Research Letters↗