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At least 1,693 records · Page 94Linked to original sources
USGS2002

FTIR and py-GC-MS spectra of true-fern and seed-fern sphenopterids (Sydney Coalfield, Nova Scotia, Canada, Pennsylvanian)

Sphenopterid specimens from the Late Pennsylvanian of Sydney Coalfield, Canada, are investigated by FTIR and py-GC-MS techniques as part of an on-going research project into the biochemistry and chemotaxonomy of Pennsylvanian-age pteridophylls. Included in the investigation are samples of the true-fern species Oligocarpia brongniartii and Zeilleria delicatula that are preserved as naturally macerated cuticles (NMC), and the seed-fern Eusphenopteris neuropteroides that is also preserved as a compression/impression. FTIR spectra of NMC seed-fern E. neuropteroides, and fern sphenopterid O. brongniartii are very similar, except that the latter does not have aromatic bands in the 700-900 cm-1 out-of-plane region, py-GC-MS show more aromatic compounds for the seed fern than for the two true-fern sphenopterids. Another difference between seed-fern and true-fern sphenopterids is a lower ratio of CH2 to CH3 in chemically treated specimens (CTC) for the seed fern. These observations suggest slightly higher aromaticity for the seed ferns, perhaps related to some chemotaxonomic differences. Comparison of FTIR and py-GC-MS characteristics of sphenopterids and other plant groups shows that these two techniques have potential to identifying chemotaxonomic signals from Carboniferous pteridophylls in general, although more data are needed to confirm this. ?? 2002 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology↗
USGS2018

Featured collection introduction: Connectivity of streams and wetlands to downstream waters

Connectivity is a fundamental but highly dynamic property of watersheds. Variability in the types and degrees of aquatic ecosystem connectivity presents challenges for researchers and managers seeking to accurately quantify its effects on critical hydrologic, biogeochemical, and biological processes. However, protecting natural gradients of connectivity is key to protecting the range of ecosystem services that aquatic ecosystems provide. In this featured collection, we review the available evidence on connections and functions by which streams and wetlands affect the integrity of downstream waters such as large rivers, lakes, reservoirs, and estuaries. The reviews in this collection focus on the types of waters whose protections under the U.S. Clean Water Act have been called into question by U.S. Supreme Court cases. We synthesize 40+ years of research on longitudinal, lateral, and vertical fluxes of energy, material, and biota between aquatic ecosystems included within the Act's frame of reference. Many questions about the roles of streams and wetlands in sustaining downstream water integrity can be answered from currently available literature, and emerging research is rapidly closing data gaps with exciting new insights into aquatic connectivity and function at local, watershed, and regional scales. Synthesis of foundational and emerging research is needed to support science‐based efforts to provide safe, reliable sources of fresh water for present and future generations.

Journal of the American Water Resources Associatio↗
USGS2003

Comment on “Isotopic fractionation between Fe(III) and Fe(II) in aqueous solutions” by Clark Johnson et al., [Earth Planet. Sci. Lett. 195 (2002) 141–153]

In a recent contribution [1] , Johnson et al. reported the equilibrium isotope fractionation factor between dissolved Fe(II) and Fe(III) in aqueous solutions at pH=2.5 and 5.5. They suggest that because the iron isotope fractionation observed in their experiments spans virtually the entire range observed in sedimentary rocks, Fe(II)–Fe(III) aqueous speciation may play a major role in determining iron isotope variations in nature where Fe(II) and Fe(III) can become physically separated. They discounted earlier conclusions by us and others [2] ; [3] that significant equilibrium fractionation between specific coexisting Fe(II)- or Fe(III)-aqueous complexes (e.g., between aqueous Fe(II)(OH) x(aq) and Fe(II) (aq) ion) is capable of producing iron isotope contrasts that can be preserved in nature. This is an important contribution not only because the authors recognize the importance of abiotic equilibrium iron isotope fractionation in nature in contrast to previous assertions [4] , but also because it will help to focus discussion on the development and evaluation of experimental approaches that can reveal abiotic fractionation mechanisms. However, in this Comment we propose that the experiments presented in this paper cannot be interpreted as straightforwardly as Johnson et al. contend. In particular, we show that in one of their critical experiments attainment of either isotope mass balance or equilibrium was not demonstrated, and thus the results of that experiment cannot be used to calculate an Fe(II)–Fe(III) equilibrium fractionation factor.

Earth and Planetary Science Letters↗
USGS2003

Forest pathology in Hawaii

Native Hawaiian forests are characterised by a high degree of endemism, including pathogens as well as their hosts. With the exceptions of koa (Acacia koa Gray), possibly maile (Alyxia oliviformis Gaud.), and, in the past, sandalwood (Santalum spp.), forest species are of little commercial value. On the other hand, these forests are immensely important from a cultural, ecological, and evolutionary standpoint. Forest disease research was lacking during the mid-twentieth century, but increased markedly with the recognition of ohia (Metrosideros polymorpha Gaud.) decline in the 1970s. Because many pathogens are themselves endemic, or are assumed to be, having evolved with their hosts, research emphasis in natural areas is on understanding host-parasite interactions and evolutionary influences, rather than disease control. Aside from management of native forests, attempts at establishing a commercial forest industry have included importation of several species of pine, Araucaria, and Eucalyptus as timber crops, and of numerous ornamentals. Diseases of these species have been introduced with their hosts. The attacking of native species by introduced pathogens is problematic - for example, Armillaria mellea (Vahl ex Fr.) Que??l. on koa and mamane (Sophora chrysophylla (Salisb.) Seem.). Much work remains to be done in both native and commercial aspects of Hawaiian forest pathology.

New Zealand Journal of Forestry Science↗
USGS1986

Chemical qualities of water that contribute to human health in a positive way

The emphasis on harmful substances that may occur in potable waters has almost obscured the fact that important beneficial constituents are commonly present. The chemical substances in water that make positive contributions to human health act mainly in two ways: (i) nutritionally, by supplying essential macro and micro elements that the diet (excluding water) may not provide in adequate amounts (for example, Mg, I and Zn); and (ii) by providing macro and micro elements that inhibit the absorption and/or effects of toxic elements such as Hg, Pb and Cd. Specific examples of these beneficial effects will be given, also examples of harmful effects on health that may result from excessive intake of these ordinarily beneficial elements. Because concentrations of the essential macro and micro elements that occur in natural, potable waters vary greatly, depending upon their source, geographic considerations are very important in any studies attempting to relate water quality to health. In this context, the inverse relationship between hard water and cardiovascular disease will be discussed. Specific data relating hardness and Mg and Ca content of potable waters to specific geographic regions of the U.S.A. will be presented. These data show a strong positive correlation between low Mg content and decreased longevity, and between high Ca and Mg content and increased longevity. In the regions considered, increased longevity correlates strongly with decreased cardiovascular mortality, and the decreased longevity with increased cardiovascular mortality.

Science of Total Environment↗
USGS2017

Chlorine-36 and 14C chronology support a limited last glacial maximum across central Chukotka, northeastern Siberia, and no Beringian ice sheet

The Pekulney Mountains and adjacent Tanyurer River valley are key regions for examining the nature of glaciation across much of northeast Russia. Twelve new cosmogenic isotope ages and 14 new radiocarbon ages in concert with morphometric analyses and terrace stratigraphy constrain the timing of glaciation in this region of central Chukotka. The Sartan Glaciation (Last Glacial Maximum) was limited in extent in the Pekulney Mountains and dates to ???20,000 yr ago. Cosmogenic isotope ages > 30,000 yr as well as non-finite radiocarbon ages imply an estimated age no younger than the Zyryan Glaciation (early Wisconsinan) for large sets of moraines found in the central Tanyurer Valley. Slope angles on these loess-mantled ridges are less than a few degrees and crest widths are an order of magnitude greater than those found on the younger Sartan moraines. The most extensive moraines in the lower Tanyurer Valley are most subdued implying an even older, probable middle Pleistocene age. This research provides direct field evidence against Grosswald's Beringian ice-sheet hypothesis. ?? 2003 Elsevier Science (USA). All rights reserved.

Quaternary Research↗
USGS2005

Loosely bound oxytetracycline in riverine sediments from two tributaries of the Chesapeake Bay

The fate of antibiotics that bind to riverine sediment is not well understood. A solution used in geochemical extraction schemes to determine loosely bound species in sediments, 1 M MgCl 2 (pH 8), was chosen to determine loosely bound, and potentially bioavailable, tetracycline antibiotics (TCs), including oxytetracycline (5-OH tetracycline) (OTC) in sediment samples from two rivers on the eastern shore of the Chesapeake Bay. Bottom sediments were collected at sites upstream from, at, and downstream from municipal sewage-treatment plants (STPs) situated on two natural waterways, Yellow Bank Stream, MD, and the Pocomoke River, MD. Concentrations of easily desorbed OTC ranged from 0.6 to approximately 1.2 μg g -1 dry wt sediment in Yellow Bank Stream and from 0.7 to approximately 3.3 μg g -1 dry wt sediment in the Pocomoke River. Concentrations of easily desorbable OTC were generally smaller in sediment upstream than in sediment downstream from the STP in the Pocomoke River. STPs and poultry manure are both potential sources of OTC to these streams. OTC that is loosely bound to sediment is subject to desorption. Other researchers have found desorbed TCs to be biologically active compounds.

Chesapeake Bay↗
USGS2022

Conservation under uncertainty: Innovations in participatory climate change scenario planning from U.S. national parks

The impacts of climate change (CC) on natural and cultural resources are far-reaching and complex. A major challenge facing resource managers is not knowing the exact timing and nature of those impacts. To confront this problem, scientists, adaptation specialists, and resource managers have begun to use scenario planning (SP). This structured process identifies a small set of scenarios—descriptions of potential future conditions that encompass the range of critical uncertainties—and uses them to inform planning. We reflect on a series of five recent participatory CC SP projects at four US National Park Service units and derive guidelines for using CC SP to support natural and cultural resource conservation. Specifically, we describe how these engagements affected management, present a generalized CC SP approach grounded in management priorities, and share key insights and innovations that (1) fostered participant confidence and deep engagement in the participatory CC SP process, (2) shared technical information in a way that encouraged informed, effective participation, (3) contextualized CC SP in the broader picture of relevant longstanding or emerging nonclimate stressors, (4) incorporated quantitative approaches to expand analytical capacity and assess qualitative findings, and (5) translated scenarios and all their complexity into strategic action.

Conservation Science and Practice↗
USGS2018

An evaluation of three fish surveys in the San Francisco Estuary, 1995–2015

Resource managers rely on long-term monitoring surveys conducted in the San Francisco Estuary to evaluate the status and trends of resident fish populations in this important region. These surveys are potentially confounded because of the incomplete detection of individuals and species, the magnitude of which is often related to the same factors that affect fish populations. We used multistate occupancy estimators to evaluate the distribution, abundance, and detection probability of four fish species collected during 1995–2015 with three long-term surveys. Detection probabilities varied positively with fish abundance and negatively with Secchi depth. Detection varied among species and was greatest for the 20-mm Survey and least for the midwater trawl used for the midwater trawl used in the San Francisco Bay Study. Incomplete detection resulted in underestimates of occupancy and abundance across species and surveys and were greatest for the Bay Study. However, trends in occupancy and abundance of the study period appeared to be unbiased. Fish occupancy and abundance were generally related to salinity or specific conductance, day-of-the year, and water temperature, but the nature of the relations varied among surveys and species. There also was strong spatial and temporal dependence in species-specific occupancy and abundance that changed through time and were unrelated to the covariates considered. Our results suggest that managers consider incorporating methods for estimating detection and adjusting data to ensure data quality. Additionally, the strong spatio-temporal patterns in the monitoring data suggest that existing protocols may need to be modified to ensure that data and inferences reflect system-wide changes rather than changes at a specific set of non-randomly selected locations.

California↗
USGS2013

Water resources and shale gas/oil production in the Appalachian Basin: critical issues and evolving developments

Unconventional natural gas and oil resources in the United States are important components of a national energy program. While the Nation seeks greater energy independence and greener sources of energy, Federal agencies with environmental responsibilities, state and local regulators and water-resource agencies, and citizens throughout areas of unconventional shale gas development have concerns about the environmental effects of high volume hydraulic fracturing (HVHF), including those in the Appalachian Basin in the northeastern United States (fig. 1). Environmental concerns posing critical challenges include the availability and use of surface water and groundwater for hydraulic fracturing; the migration of stray gas and potential effects on overlying aquifers; the potential for flowback, formation fluids, and other wastes to contaminate surface water and groundwater; and the effects from drill pads, roads, and pipeline infrastructure on land disturbance in small watersheds and headwater streams (U.S. Government Printing Office, 2012). Federal, state, regional and local agencies, along with the gas industry, are striving to use the best science and technology to develop these unconventional resources in an environmentally safe manner. Some of these concerns were addressed in U.S. Geological Survey (USGS) Fact Sheet 2009–3032 (Soeder and Kappel, 2009) about potential critical effects on water resources associated with the development of gas extraction from the Marcellus Shale of the Hamilton Group (Ver Straeten and others, 1994). Since that time, (1) the extraction process has evolved, (2) environmental awareness related to high-volume hydraulic fracturing process has increased, (3) state regulations concerning gas well drilling have been modified, and (4) the practices used by industry to obtain, transport, recover, treat, recycle, and ultimately dispose of the spent fluids and solid waste materials have evolved. This report updates and expands on Fact Sheet 2009–3032 and presents new information regarding selected aspects of unconventional shale gas development in the Appalachian Basin (primarily Virginia, West Virginia, Maryland, Pennsylvania, Ohio, and New York). This document was prepared by the USGS, in cooperation with the U.S. Department of Energy, and reviews the evolving technical advances and scientific studies made in the Appalachian Basin between 2009 and the present (2013), addressing past and current issues for oil and gas development in the region.

Maryl;New York;Ohio;Pennsylvania;Virginia;West Vir↗
USGS2011

Natural resource mitigation, adaptation and research needs related to climate change in the Great Basin and Mojave Desert

This report synthesizes the knowledge, opinions, and concerns of many Federal and State land managers, scientists, stakeholders, and partners from a workshop, held at the University of Nevada, Las Vegas, on April 20-22, 2010. Land managers, research scientists, and resource specialists identified common concerns regarding the potential effects of climate change on public lands and natural resources in the Great Basin and Mojave Desert and developed recommendations for mitigation, adaptation, and research needs. Water and, conversely, the effects of drought emerged as a common theme in all breakout sessions on terrestrial and aquatic species at risk, managing across boundaries, monitoring, and ecosystem services. Climate change models for the southwestern deserts predict general warming and drying with increasing precipitation variability year to year. Scientists noted that under these changing conditions the past may no longer be a guide to the future in which managers envision increasing conflicts between human water uses and sustaining ecosystems. Increasing environmental stress also is expected as a consequence of shifting ecosystem boundaries and species distributions, expansion of non-native species, and decoupling of biotic mutualisms, leading to increasingly unstable biologic communities. Managers uniformly expressed a desire to work across management and agency boundaries at a landscape scale but conceded that conflicting agency missions and budgetary constraints often impede collaboration. More and better science is needed to cope with the effects of climate change but, perhaps even more important is the application of science to management issues using the methods of adaptive management based on long-term monitoring to assess the merits of management actions. Access to data is essential for science-based land management. Basic inventories, spatial databases, baseline condition assessments, data quality assurance, and data sharing were identified as top information priorities by all participants at this workshop. Optimizing the utility of ecosystem monitoring data will require standardizing monitoring protocols across agencies. Better communication among researchers and managers and cooperation through partnerships to manage resources across boundaries were emphasized as necessary for adapting to changing climatic conditions. However, even these strategies may be insufficient unless policy mandates, agency missions, and funding are coordinated at a high level.

Scientific Investigations Report↗
USGS2017

Land change monitoring, assessment, and projection (LCMAP) revolutionizes land cover and land change research

When nature and humanity change Earth’s landscapes - through flood or fire, public policy, natural resources management, or economic development - the results are often dramatic and lasting. Wildfires can reshape ecosystems. Hurricanes with names like Sandy or Katrina will howl for days while altering the landscape for years. One growing season in the evolution of drought-resistant genetics can transform semiarid landscapes into farm fields. In the past, valuable land cover maps created for understanding the effects of those events - whether changes in wildlife habitat, water-quality impacts, or the role land use and land cover play in affecting weather and climate - came out at best every 5 to 7 years. Those high quality, high resolution maps were good, but users always craved more: even higher quality data, additional land cover and land change variables, more detailed legends, and most importantly, more frequent land change information. Now a bold new initiative called Land Change Monitoring, Assessment, and Projection (LCMAP) promises to fulfill that demand. Developed at the U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center in Sioux Falls, South Dakota, LCMAP provides definitive, timely information on how, why, and where the planet is changing. LCMAP’s continuous monitoring process can detect changes as they happen every day that Landsat satellites acquire clear observations. The result will be to place near real-time information in the hands of land and resource managers who need to understand the effects these changes have on landscapes.

General Information Product↗
USGS2018

Rio Grande transboundary integrated hydrologic model and water-availability analysis, New Mexico and Texas, United States, and Northern Chihuahua, Mexico

Errata **September 28, 2018: The purpose of a USGS Open-file report (OFR) is dissemination of information that must be released immediately to fill a public need or information that is not sufficiently refined to warrant publication in one of the other USGS series. As part of that refinement process, an error was discovered in one of the input data sets of the Rio Grande Transboundary Integrated Hydrologic Model (RGTIHM) that this OFR was based upon. The error involved the assignment of storage properties to “phantom cells.” Phantom cells are required for most variants of MODFLOW that use a structured finite-difference grid when individual stratigraphic layers are represented as separate layers. Using phantom cells is a common practice that allows separate model layers to be maintained without having to combine stratigraphic layers into equivalent model layers or to use an unstructured grid. Typically, phantom cell horizontal hydraulic conductivities and storage properties are set to a small number and vertical hydraulic conductivities are set to a number large enough to allow vertical flow between the vertically adjacent layers. In the RGTIHM, the specific storage properties of the phantom cells for the upper (RGTIHM layers 3 and 4), middle (RGTIHM layers 5 and 6), and lower (RGTIHM layers 7 and 8) members of the Santa Fe Group were inadvertently assigned a value of 1 feet -1 . The revision of these specific storage values to a small number (1.0 x 10 -09 feet -1 ) required additional trial-and-error model calibration and a new sensitivity analysis. After calibration, the overall model fit remained similar to the fit described in the OFR, but the fit for many individual features such as project water available for diversions at the American Canal and Acequia Madre improved due to the reduction in flow coming from lower layers. Overall, there is still an average net depletion of groundwater flow, and the conclusions of the report are not changed. The revised average annual groundwater flow depletion simulated for the period 1953-2014 is -1,480 acre-feet/year for the entire model region, and -3,660 acre-feet/year for the portion of the model in the United States. The final version of the model will be the basis of the USGS Scientific Investigations Report that will supersede this OFR. An updated Model Archive of RGTIHM is available upon request to the USGS California Water Science Center. The corrected version of the model WAS the basis for the USGS Scientific Investigations Report that SUPERSEDED this Open-File Report.** Abstract Changes in population, agricultural development and practices (including shifts to more water-intensive crops), and climate variability are increasing demands on available water resources, particularly groundwater, in one of the most productive agricultural regions in the Southwest—the Rincon and Mesilla Valley parts of Rio Grande Valley, Doña Ana and Sierra Counties, New Mexico, and El Paso County, Texas. The goal of this study was to produce an integrated hydrological simulation model to help evaluate water-management strategies, including conjunctive use of surface water and groundwater for historical conditions, and to support long-term planning for the Rio Grande Project. This report describes model construction and applications by the U.S. Geological Survey, working in cooperation and collaboration with the Bureau of Reclamation. This model, the Rio Grande Transboundary Integrated Hydrologic Model, simulates the most important natural and human components of the hydrologic system, including selected components related to variations in climate, thereby providing a reliable assessment of surface-water and groundwater conditions and processes that can inform water users and help improve planning for future conditions and sustained operations of the Rio Grande Project (RGP) by the Bureau of Reclamation. Model development included a revision of the conceptual model of the flow system, construction of a Transboundary Rio Grande Watershed Model (TRGWM) water-balance model using the Basin Characterization Model (BCM), and construction of an integrated hydrologic flow model with MODFLOW-One-Water Hydrologic Flow Model (referred to as One Water). The hydrologic models were developed for and calibrated to historical conditions of water and land use, and parameters were adjusted so that simulated values closely matched available measurements (calibration). The calibrated model was then used to assess the use and movement of water in the Rincon Valley, Mesilla Basin, and northern part of the Conejos-Médanos Basin, with the entire region referred to as the “Transboundary Rio Grande” or TRG. These tools provide a means to understand hydrologic system response to the evolution of water use in the region, its availability, and potential operational constraints of the RGP. The conceptual model identified surface-water and groundwater inflows and outflows that included the movement and use of water both in natural and in anthropogenic systems. The groundwater-flow system is characterized by a layered geologic sedimentary sequence combined with the effects of groundwater pumping, operation of the RGP, natural runoff and recharge, and the application of irrigation water at the land surface that is captured and reused in an extensive network of canals and drains as part of the conjunctive use of water in the region. Historical groundwater-level fluctuations followed a cyclic pattern that were aligned with climate cycles, which collectively resulted in alternating periods of wet or dry years. Periods of drought that persisted for one or more years are associated with low surface-water availability that resulted in higher rates of groundwater-level decline. Rates of groundwater-level decline also increased during periods of agricultural intensification, which necessitated increasing use of groundwater as a source of irrigation water. Agriculture in the area was initially dominated by alfalfa and cotton, but since 1970 more water-intensive pecan orchards and vegetable production have become more common. Groundwater levels substantially declined in subregions where drier climate combined with increased demand, resulting in periods of reduced streamflows. Most of the groundwater was recharged in the Rio Grande Valley floor, and most of the pumpage and aquifer storage depletion was in Mesilla Basin agricultural subregions. A cyclic imbalance between inflows and outflows resulted in the modeled cyclic depletion (groundwater withdrawals in excess of natural recharge) of the groundwater basin during the 75-year simulation period of 1940–2014. Changes in groundwater storage can vary considerably from year to year, depending on land use, pumpage, and climate conditions. Climatic drivers of wet and dry years can greatly affect all inflows, outflows, and water use. Although streamflow and, to a minor extent, precipitation during inter-decadal wet-year periods replenished the groundwater historically, contemporary water use and storage depletion could have reduced the effects of these major recharge events. The average net groundwater flow-rate deficit for 1953–2014 was estimated to be about 8,990 acre-feet per year.

New Mexico, Northern Chihuahua, Texas↗
USGS2020

An integrated feasibility study of reservoir thermal energy storage in Portland, Oregon, USA

In regions with long cold overcast winters and sunny summers, Deep Direct-Use (DDU) can be coupled with Reservoir Thermal Energy Storage (RTES) technology to take advantage of pre-existing subsurface permeability to save summer heat for later use during cold seasons. Many aquifers worldwide are underlain by permeable regions (reservoirs) containing brackish or saline groundwater that has limited beneficial use due to poor water quality. We investigate the utility of these relatively deep, slow flowing reservoirs for RTES by conducting an integrated feasibility study in the Portland Basin, Oregon, USA, developing methods and obtaining results that can be widely applied to groundwater systems elsewhere. As a case study, we have conducted an economic and social cost-benefit analysis for the Oregon Health and Science University (OHSU), a teaching hospital that is recognized as critical infrastructure in the Portland Metropolitan Area. Our investigation covers key factors that influence feasibility including 1) the geologic framework, 2) heat and fluid flow modeling, 3) capital and maintenance costs, 4) the regulatory framework, and 5) operational risks. By pairing a model of building seasonal heat demand with an integrated model of RTES resource supply, we determine that the most important factors that influence RTES efficacy in the study area are operational schedule, well spacing, the amount of summer heat stored (in our model, a function of solar array size), and longevity of the system. Generally, heat recovery efficiency increases as the reservoir and surrounding rocks warm, making RTES more economical with time. Selecting a base-case scenario, we estimate a levelized cost of heat (LCOH) to compare with other sources of heating available to OHSU and find that it is comparable to unsubsidized solar and nuclear, but more expensive than natural gas. Additional benefits of RTES include energy resiliency in the event that conventional energy supplies are disrupted (e.g., natural disaster) and a reduction in fossil fuel consumption resulting in a smaller carbon footprint. Key risks include reservoir heterogeneity and a possible reduction in permeability through time due to scaling (mineral precipitation). Lastly, a map of thermal energy storage capacity for the Portland Basin yields a total of 87,000 GWh, suggesting tremendous potential for RTES in the Portland Metropolitan Area.

Oregon↗
USGS1997

Sequestration of hydrophobic organic contaminants by geosorbents

The chemical interactions of hydrophobic organic contaminants (HOCs) with soils and sediments (geosorbents) may result in strong binding and slow subsequent release rates that significantly affect remediation rates and endpoints. The underlying physical and chemical phenomena potentially responsible for this apparent sequestration of HOCs by geosorbents are not well understood. This challenges our concepts for assessing exposure and toxicity and for setting environmental quality criteria. Currently there are no direct observational data revealing the molecular-scale locations in which nonpolar organic compounds accumulate when associated with natural soils or sediments. Hence macroscopic observations are used to make inferences about sorption mechanisms and the chemical factors affecting the sequestration of HOCs by geosorbents. Recent observations suggest that HOC interactions with geosorbents comprise different inorganic and organic surfaces and matrices, and distinctions may be drawn along these lines, particularly with regard to the roles of inorganic micropores, natural sorbent organic matter components, combustion residue particulate carbon, and spilled organic liquids. Certain manipulations of sorbates or sorbent media may help reveal sorption mechanisms, but mixed sorption phenomena complicate the interpretation of macroscopic data regarding diffusion of HOCs into and out of different matrices and the hysteretic sorption and aging effects commonly observed for geosorbents. Analytical characterizations at the microscale, and mechanistic models derived therefrom, are needed to advance scientific knowledge of HOC sequestration, release, and environmental risk.

Environmental Science & Technology↗
USGS2023

A global long-term daily reanalysis of reference evapotranspiration for drought and food-security monitoring

NOAA has developed a global reference evapotranspiration (ET 0 ) reanalysis using the UN Food and Agriculture Organization formulation (FAO-56) of the Penman-Monteith equation forced by MERRA phase 2 (MERRA2) meteorological and radiative drivers. The NOAA ET 0 reanalysis is provided daily from January 1, 1980 to the near-present at a resolution of 0.5° latitude × 0.625° longitude. The reanalysis is verified against station data across southern Africa, a region presenting both significant challenges regarding hydroclimatic variability and observational quantity and quality and significant potential benefits to food-insecure populations. These data are generated from observations from the Southern African Science Service Centre for Climate Change and Adaptive Land Management (SASSCAL) network. We further verified globally against spatially distributed ET 0 derived from two reanalyses–the Global Data Assimilation System (GDAS) and Princeton Global Forcing (PGF)–and these verifications produced similar results, yet demonstrated wide regional and seasonal differences. We also present cases that verify the operational applicability of the reanalysis in long-established drought, famine, crop- and pastoral-stress metrics, and in predictability assessments of drought forecasts.

Nature Scientific Data↗
USGS2018

Navigating the field of decision analysis

Managers, policy makers, and decision makers with responsibility for environmental decisions have an extraordinarily difficult job. The systems they manage are complex (coupled human-natural systems), with many dimensions and complicated dynamics. Our knowledge of how those systems respond to management actions is often limited, so many of the decisions have to be made in the face of uncertainty. The field of decision analysis provides a comprehensive set of tools for structuring, analyzing, and making decisions. Arising initially as a way to understand and manage risk, the field has expanded in the last 80 years to cover such topics as multipleobjective trade-offs, time-dependent linked decisions, the value of information, and competition among multiple decision makers. At the same time, cognitive psychologists and behavioural economists have studied human decisions to understand when our innate processes work and when they fail. Formal decision analysis is increasingly being used in many sectors, including economic, industrial, manufacturing, agricultural, transportation, and medical sectors, by individuals, corporations, non-profits, and government agencies. Occasional application of decision analysis to environmental decisions began in the mid-1970s, but the environmental science and management world was largely unaware of decision analysis until the late 1990s and early 2000s. (A major aim of the ARC Centre of Excellence for Environmental Decisions – CEED – was to better connect decision analysis and environmental management). Today, the field of environmental decision analysis is coming of age with the maturation of a rich set of tools to help decision makers frame, analyze, and implement decisions. Sometimes the wealth of tools is daunting, but there are core principles that tie decision analysis together. To help the reader navigate this complexity, we summarize the field of decision analysis in four key messages.

Decision Point Online↗
USGS2010

The dispersion of fibrous amphiboles by glacial processes in the area surrounding Libby, Montana, USA

Mining operations began at a world-class vermiculite deposit at Vermiculite Mountain near Libby, Montana, circa 1920 and ended in 1990. Fibrous and asbestiform amphiboles intergrown with vermiculite ore are suspected to be a causative factor in an abnormally high number of cases of respiratory diseases in former mine and mill workers, and in residents of Libby. The question addressed in this report is whether some of the amphibole from Vermiculite Mountain could have been dispersed by Pleistocene glacial processes rather than by human activity after vermiculite mining began. The history of Pinedale glaciation in the Libby area provides a framework for estimating the presence and distribution of asbestiform amphiboles derived from Vermiculite Mountain and found in naturally occurring sediments of Glacial Lake Kootenai that underlie the Libby Valley area. There were two situations where sediments derived from Vermiculite Mountain were deposited into Glacial Lake Kootenai: (1) as lake-bottom sediments derived from meltwater flowing down Rainy Creek when the valley south of Vermiculite Mountain was free of ice but active ice still covered Vermiculite Mountain; and (2) as lake-bottom sediments eroded from the Rainy Creek outwash and re-deposited during a re-advance of the Purcell Trench Glacier lobe near Moyie Springs, Idaho.

Montana↗