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At least 1,675 records · Page 93Linked to original sources
USGS2011

Deep scientific drilling in the San Andreas Fault Zone

A deep scientific drilling experiment in San Andreas fault zone would provide data essential to understanding the structure, composition, mechanical behavior, and physical state of an active, major plate-boundary fault. Toward this end, we are working with an international team of scientists and engineers to propose a long-term, integrated program of surface-based geological and geophysical investigations and deep drilling along the San Andreas fault system. Prior to drilling, a suite of comparative geodynamic models will be developed incorporating detailed investigations of geology, crustal structure, geophysical environment, hydrology, seismotectonics, and fault-movement history at each of the candidate sites. These studies will have a major impact on our understanding of the structure and physical properties of the San Andreas fault system and will form a critical framework for applying the knowledge gained in a deep San Andreas borehole to other segments of the fault and other tectonic environments.

California, Nevada↗
USGS2007

Electrical activity during the 2006 Mount St. Augustine volcanic eruptions

By using a combination of radio frequency time-of-arrival and interferometer measurements, we observed a sequence of lightning and electrical activity during one of Mount St. Augustine's eruptions. The observations indicate that the electrical activity had two modes or phases. First, there was an explosive phase in which the ejecta from the explosion appeared to be highly charged upon exiting the volcano, resulting in numerous apparently disorganized discharges and some simple lightning. The net charge exiting the volcano appears to have been positive. The second phase, which followed the most energetic explosion, produced conventional-type discharges that occurred within plume. Although the plume cloud was undoubtedly charged as a result of the explosion itself, the fact that the lightning onset was delayed and continued after and well downwind of the eruption indicates that in situ charging of some kind was occurring, presumably similar in some respects to that which occurs in normal thunderstorms.

Alaska↗
USGS2016

The Water-Quality Partnership for National Parks—U.S. Geological Survey and National Park Service, 1998–2016

The U.S. Geological Survey (USGS) and the National Park Service (NPS) work together through the USGS–NPS Water-Quality Partnership to support a broad range of policy and management needs related to high-priority water-quality issues in national parks. The program was initiated in 1998 as part of the Clean Water Action Plan, a Presidential initiative to commemorate the 25th anniversary of the Clean Water Act. Partnership projects are developed jointly by the USGS and the NPS. Studies are conducted by the USGS and findings are used by the NPS to guide policy and management actions aimed at protecting and improving water quality. The National Park Service manages many of our Nation’s most highly valued aquatic systems across the country, including portions of the Great Lakes, ocean and coastal zones, historic canals, reservoirs, large rivers, high-elevation lakes and streams, geysers, springs, and wetlands. So far, the Water-Quality Partnership has undertaken 217 projects in 119 national parks. In each project, USGS studies and assessments ( http://water.usgs.gov/nps_partnership/pubs.php ) have supported science-based management by the NPS to protect and improve water quality in parks. Some of the current projects are highlighted in the NPS Call to Action Centennial initiative, Crystal Clear, which celebrates national park water-resource efforts to ensure clean water for the next century of park management ( http://www.nature.nps.gov/water/crystalclear/ ). New projects are proposed each year by USGS scientists working in collaboration with NPS staff in specific parks. Project selection is highly competitive, with an average of only eight new projects funded each year out of approximately 75 proposals that are submitted. Since the beginning of the Partnership in 1998, 189 publications detailing project findings have been completed. The 217 studies have been conducted in 119 NPS-administered lands, extending from Denali National Park and Preserve in Alaska to Everglades National Park in Florida, and from Acadia National Park in the Northeast to park lands in Hawaii and Pacific Island territories in the West. Project goals range from periodic stream monitoring, to determining the occurrence and concentrations of contaminants and the potential for them to exceed human health or aquatic life criteria, to conducting interpretive studies to evaluate the effect(s) on or vulnerability of national park resources to visitor usage and other natural and anthropogenic activities.

Fact Sheet↗
USGS2000

Consequences of slow growth for 230Th/U dating of Quaternary opals, Yucca Mountain, NV, USA

Thermal ionization mass-spectrometry 234U/238U and 230Th/238U data are reported for uranium-rich opals coating fractures and cavities within the silicic tuffs forming Yucca Mountain, NV, the potential site of a high-level radioactive waste repository. High uranium concentrations (up to 207 ppm) and extremely high 230Th/232Th activity ratios (up to about 106) make microsamples of these opals suitable for precise 230Th/U dating. Conventional 230Th/U ages range from 40 to greater than 600 ka, and initial 234U/238U activity ratios between 1.03 and 8.2. Isotopic evidence indicates that the opals have not experienced uranium mobility; however, wide variations in apparent ages and initial 234U/238U ratios for separate subsamples of the same outermost mineral surfaces, positive correlation between ages and sample weights, and negative correlation between 230Th/U ages and calculated initial 234U/238U are inconsistent with the assumption that all minerals in a given subsample was deposited instantaneously. The data are more consistent with a conceptual model of continuous deposition where secondary mineral growth has occurred at a constant, slow rate up to the present. This model assumes that individual subsamples represent mixtures of older and younger material, and that calculations using the resulting isotope ratios reflect an average age. Ages calculated using the continuous-deposition model for opals imply average mineral growth rates of less than 5 mm/m.y. The model of continuous deposition also predicts discordance between ages obtained using different radiometric methods for the same subsample. Differences in half-lives will result in younger apparent ages for the shorter-lived isotope due to the greater influence of younger materials continuously added to mineral surfaces. Discordant 14C, 230Th/U and U-Pb ages obtained from outermost mineral surfaces at Yucca Mountain support this model. (C) 2000 Elsevier Science B.V. All rights reserved.

Chemical Geology↗
USGS2018

“Naturalness” in designated Wilderness: Long-term changes in non-native plant dynamics on campsites, Boundary Waters, Minnesota

Wilderness areas in the United States are preserved for their untrammeled naturalness and opportunities for unconfined recreation. The Boundary Waters Canoe Area Wilderness has these qualities, but long-term recreation visitation pressures on campsites can cause significant ecological changes. This article explores changes on campsites, specifically examining non-native plant ecology over 3 decades. The research replicates a 1982 study analyzing vegetation composition and cover on campsites and environmentally paired controls. Camping activities have removed substantial tree cover on campsites, altering their ecological conditions and perceived wilderness character. Over the span of 32 years, the number of non-native plant species found on campsites has not risen, although their mean relative cover has increased significantly and they have spread to more sites. Of the 23 non-native herbs and grasses found on the campsites, only Cirsium arvense is considered a noxious weed by the state of Minnesota. Other noninvasive, non-native plants fall into a gray area in the context of "naturalness" for an area protected as Wilderness because they provide some positive ecological services even as they degrade wilderness character. Thus, wilderness managers face a difficult challenge in coping with the long-term impacts of visitor use on wilderness conditions and character.

Minnesota↗
USGS2017

Use of fish telemetry in rehabilitation planning, management, and monitoring in Areas of Concern in the Laurentian Great Lakes

Freshwater ecosystems provide many ecosystem services; however, they are often degraded as a result of human activity. To address ecosystem degradation in the Laurentian Great Lakes, Canada and the United States of America established the Great Lakes Water Quality Agreement (GLWQA). In 1987, 43 highly polluted and impacted areas were identified under the GLWQA as having one or more of 14 Beneficial Use Impairments (BUIs) to the physical and chemical habitat for fish, wildlife and humans, and were designated as Areas of Concern (AOC). Subnational jurisdictions combined with local stakeholders, with support from federal governments, developed plans to remediate and restore these sites. Biotelemetry (the tracking of animals using electronic tags) provides information on the spatial ecology of fish in the wild relevant to habitat management and stock assessment. Here, seven case studies are presented where biotelemetry data were directly incorporated within the AOC Remedial Action Plan (RAP) process. Specific applications include determining seasonal fish–habitat associations to inform habitat restoration plans, identifying the distribution of pollutant-indicator species to identify exposure risk to contamination sources, informing the development of fish passage facilities to enable fish to access fragmented upstream habitats, and assessing fish use of created or restored habitats. With growing capacity for fish biotelemetry research in the Great Lakes, we discuss the strengths and weaknesses of incorporating biotelemetry into AOC RAP processes to improve the science and practice of restoration and to facilitate the delisting of AOCs.

Great Lakes↗
USGS2018

Science support for evaluating natural recovery of polychlorinated biphenyl concentrations in fish from Crab Orchard Lake, Crab Orchard National Wildlife Refuge, Illinois

Introduction Crab Orchard Lake in southern Illinois is one of the largest and most popular recreational lakes in the state. Construction of the nearly 7,000-acre reservoir in the late 1930s created employment opportunities through the Works Progress Administration, and the lake itself was intended to supply water, control flooding, and provide recreational opportunities for local communities (Stall, 1954). In 1942, the Department of War appropriated or purchased more than 20,000 acres of land around Crab Orchard Lake and constructed the Illinois Ordnance Plant, which manufactured bombs and anti-tank mines during World War II. After the war, an Act of Congress transferred the property to the U.S. Department of the Interior. Crab Orchard National Wildlife Refuge was established on August 5, 1947, for the joint purposes of wildlife conservation, agriculture, recreation, and industry. Production of explosives continued, but new industries also moved onsite. More than 200 tenants have held leases with Crab Orchard National Wildlife Refuge and have operated a variety of manufacturing plants (electrical components, plated metal parts, ink, machined parts, painted products, and boats) on-site. Soils, water, and sediments in several areas of the refuge were contaminated with hazardous substances from handling and disposal methods that are no longer acceptable environmental practice (for example, direct discharge to surface water, use of unlined landfills). Polychlorinated biphenyl (PCB) contamination at the refuge was identified in the 1970s, and a PCB-based fish-consumption advisory has been in effect since 1988 for Crab Orchard Lake. The present advisory covers common carp ( Cyprinus carpio ) and channel catfish ( Ictalurus punctatus ); see Illinois Department of Public Health (2017). Some of the most contaminated areas of the refuge were actively remediated, and natural ecosystem recovery processes are expected to further reduce residual PCB concentrations in the lake. The U.S. Fish and Wildlife Service sought technical support to understand environmental drivers of current (2017) PCB residues in fish tissue and patterns in PCB residues through time to inform the fish-consumption advisory for Crab Orchard Lake. This project is planned in two phases (Tasks 1 and 2); the first phase is included in this report. Task 1, reported here, includes a review of existing literature and a brief overview focused on environmental and biochemical/physiological processes that drive PCB residues in fish tissue. This review specifically targets processes that are relevant for freshwater lacustrine environments such as those at Crab Orchard Lake. In addition to discussions of environmental fate, metabolism, and accumulation of PCBs, this review includes a brief scientifically based explanation of approaches used to establish fish-consumption advisories. A planned second task (Task 2) will include a compilation and summary of existing data on PCB residues in fish tissue samples from Crab Orchard Lake. This summary will also place Crab Orchard Lake data in a broader geographic context through a comparison with fish data from other Midwestern lakes. When Task 1 and Task 2 are complete, resource managers will have (a) a synthesis of existing literature that characterizes the processes influencing the fate of residual PCBs remaining in systems such as Crab Orchard Lake, (b) a summary of natural PCB attenuation processes for use in risk communication with the public, and (c) a summary of existing data on PCBs in fish tissues from Crab Orchard Lake, including exploratory plots of tissue residues through time. Overall, this project will provide data to help resource managers better understand the ecological and public health consequences of residual PCBs in Crab Orchard Lake.

Illinois↗
USGS2020

Evaluating the potential role of bioactive chemicals on the distribution of invasive Asian carp upstream and downstream from river mile 278 in the Illinois waterway

Two non-native carp species have invaded the Illinois Waterway and are a threat to Great Lakes ecosystems. Poor water quality in the upper Illinois Waterway, may be a factor contributing to the stalling of the carp population front near river mile 278. In 2015, the U.S. Geological Survey collected 4 sets of water samples from two sites upstream and 4 sites downstream from river mile 278, and one tributary. Each sample was analyzed for up to 649 unique parameters of which 287 were detected including 96 pesticides, 62 pharmaceuticals, 39 wastewater indicator compounds, 29 metals, 19 volatile organic compounds (VOCs), six disinfection by-products (DBPs), five hormones, and five carboxylic acids. Potential for bioactivity was estimated by comparing chemical concentrations to aquatic life or human health criteria and to in-vitro bioactivity screening results in the U.S EPA ToxCast™ database. The resulting hazard quotients and exposure-activity ratios (EARs) are toxicity indexes, that can be used to rank potential bioactivity of individual chemicals and chemical mixtures. This analysis indicates that several bioactive chemicals (BCs) including: carbendazim, 2,4-D, metolachlor, terbuthylazine, and acetochlor (pesticides); 1,4-dioxane (VOC); metformin, diphenhydramine, sulfamethoxazole, tramadol, fexofenadine, and the anti-depressants (pharmaceuticals); bisphenol A, 4-nonylphenol, galaxolide, 4-tert-octylphenol (wastewater indicator chemical); lead and boron (metals); and estrone (hormone) all occur in the upper Illinois Waterway at concentrations that produce elevated EARs values and may be adversely affecting carp reproduction and health. The clear differences in water quality upstream and downstream from river mile 278 with higher contaminant concentrations and potential bioactivity upstream could represent a barrier to carp range expansion.

Illinois↗
USGS2018

Reconnaissance of mixed organic and inorganic chemicals in private and public supply tapwaters at selected residential and workplace sites in the United States

Safe drinking water at the point-of-use (tapwater, TW) is a United States public health priority. Multiple lines of evidence were used to evaluate potential human health concerns of 482 organics and 19 inorganics in TW from 13 (7 public supply, 6 private well self-supply) home and 12 (public supply) workplace locations in 11 states. Only uranium (61.9 μg L –1 , private well) exceeded a National Primary Drinking Water Regulation maximum contaminant level (MCL: 30 μg L –1 ). Lead was detected in 23 samples (MCL goal: zero). Seventy-five organics were detected at least once, with median detections of 5 and 17 compounds in self-supply and public supply samples, respectively (corresponding maxima: 12 and 29). Disinfection byproducts predominated in public supply samples, comprising 21% of all detected and 6 of the 10 most frequently detected. Chemicals designed to be bioactive (26 pesticides, 10 pharmaceuticals) comprised 48% of detected organics. Site-specific cumulative exposure–activity ratios (∑ EAR ) were calculated for the 36 detected organics with ToxCast data. Because these detections are fractional indicators of a largely uncharacterized contaminant space, ∑ EAR in excess of 0.001 and 0.01 in 74 and 26% of public supply samples, respectively, provide an argument for prioritized assessment of cumulative effects to vulnerable populations from trace-level TW exposures.

Environmental Science & Technology↗
USGS2023

Predicted aquatic exposure effects from a national urban stormwater study

A multi-agency study of 438 organic and 62 inorganic chemicals measured in urban stormwater during 50 total runoff events at 21 sites across the United States demonstrated that stormwater discharges can generate localized, aquatic exposures to extensive contaminant mixtures, including organics suspected to cause adverse aquatic-health effects. The aggregated risks to multiple aquatic trophic levels (fish, invertebrates, plants) of the stormwater mixture exposures, which were documented in the national study, were explored herein by calculating cumulative ratios of organic-contaminant in vitro exposure–activity cutoffs (∑ EAR ) and health-benchmark-weighted cumulative toxicity quotients (∑ TQ ). Both risk assessment approaches indicated substantial (moderate to high) risk for acute adverse effects to aquatic organisms across multiple trophic levels (fish, macroinvertebrates, non-vascular/vascular plants) at or near stormwater discharge points across the United States. The results are interpreted as potential orders of magnitude underestimates of actual aquatic risk in stormwater control wetlands or in the immediate vicinity of such discharges to surface-water receptors, because the 438 organic-compound analytical space assessed in this study is orders of magnitude less than the 350 000 parent compounds estimated to be in current commercial use globally and the incalculable chemical-space of potential metabolites and degradates.

Environmental Science: Water Research and Technolo↗
USGS2000

The Midway sequence: A Timiskaming-type, pull-apart basin deposit in the western Wawa subprovince, Minnesota

The Midway sequence is an assemblage of subaerially deposited clastic and volcanic rocks that forms a narrow wedge within Neoarchean greenstone of the western Wawa subprovince of the Superior Province. Volcanic conglomerate in the Midway sequence contains clasts of stratigraphically older greenstone, together with clasts of a distinctive hornblende-phyric trachyandesite that is not represented among the older greenstone flows. The trachyandesite forms flows and pyroclastic units that are interbedded with lenticular deposits of volcanic conglomerate in a manner interpreted to indicate approximately coeval volcanism and alluvial fan - fluvial sedimentation within a linear, restricted, and tectonically active depocentre. The Midway sequence unconformably overlies greenstone on one side and is bounded by a regional-scale, strike-slip fault on the other. Structural analyses show that the Midway sequence was deposited after an early, precleavage folding event (D 1 ) in greenstone, but before the regional metamorphic cleavage-forming D 2 deformation. Lithologic and structural attributes are consistent with deposition in a strike-slip "pull-apart" basin. The stratigraphic and structural characteristics of the Midway sequence are generally similar to those of the Timiskaming Group and Timiskaming-type rocks in Canada, and more specifically to those of the Shebandowan Group in the Thunder Bay district. This similarity implies that the latest Archean tectonic and magmatic history of the western Wawa subprovince may have been nearly synchronous over great distances.

Minnesota↗
USGS2018

Prevalence of seismic rate anomalies preceding volcanic eruptions in Alaska

Seismic rate increases often precede eruptions at volcanoes worldwide. However, many eruptions occur without such precursors. Additionally, identifying seismic rate increases near volcanoes with high levels of background seismicity is non-trivial and many periods of elevated seismicity occur without ensuing eruptions, limiting their usefulness for forecasting in some cases. Although these issues are commonly known, efforts to quantify them are limited. In this study, we consistently apply a common statistical tool, the β-statistic, to seismically monitored eruptions in Alaska of various styles to determine the overall prevalence of seismic rate anomalies immediately preceding eruptions. We find that 6 out of 20 (30%) eruptions have statistically significant precursory seismic rate increases. Of these 6 eruptions, 3 of them occur at volcanoes with relatively felsic compositions, repose periods >15 years, and VEI ≥ 3. Overall, our results confirm that seismic rate increases are common prior to larger eruptions at long dormant, “closed-system” volcanoes, but uncommon preceding smaller eruptions at more frequently active, “open-system” volcanoes with more mafic magmas. We also explore the rate of other anomalies not precursory to eruptions and investigate their origins. Some of these non-eruptive anomalies can be explained by aftershocks of regional seismic events, magmatic activity that did not lead to eruption, or unrest at other nearby volcanoes. Some open-system volcanoes have high non-eruptive anomaly rates and low pre-eruptive anomaly rates and are thus not amenable to forecasting based on earthquake catalogs. In this study, we find that 31% of anomalies lead to eruption. With continued calibration at more volcanoes, the β-statistic that we apply may be used more broadly to analyze future periods of seismic unrest at other volcanoes, properly placing such episodes into the context of the long-term background rate. These results may be useful for informing future eruption forecasts around the world, and the statistical tool may aid volcano observatories in identifying future seismic rate anomalies under changing network conditions.

Alaska↗
USGS2017

Deep-sea coral research and technology program: Alaska deep-sea coral and sponge initiative final report

Deep-sea coral and sponge ecosystems are widespread throughout most of Alaska’s marine waters. In some places, such as the central and western Aleutian Islands, deep-sea coral and sponge resources can be extremely diverse and may rank among the most abundant deep-sea coral and sponge communities in the world. Many different species of fishes and invertebrates are associated with deep-sea coral and sponge communities in Alaska. Because of their biology, these benthic invertebrates are potentially impacted by climate change and ocean acidification. Deepsea coral and sponge ecosystems are also vulnerable to the effects of commercial fishing activities. Because of the size and scope of Alaska’s continental shelf and slope, the vast majority of the area has not been visually surveyed for deep-sea corals and sponges. NOAA’s Deep Sea Coral Research and Technology Program (DSCRTP) sponsored a field research program in the Alaska region between 2012–2015, referred to hereafter as the Alaska Initiative. The priorities for Alaska were derived from ongoing data needs and objectives identified by the DSCRTP, the North Pacific Fishery Management Council (NPFMC), and Essential Fish Habitat-Environmental Impact Statement (EFH-EIS) process. This report presents the results of 15 projects conducted using DSCRTP funds from 2012-2015. Three of the projects conducted as part of the Alaska deep-sea coral and sponge initiative included dedicated at-sea cruises and fieldwork spread across multiple years. These projects were the eastern Gulf of Alaska Primnoa pacifica study, the Aleutian Islands mapping study, and the Gulf of Alaska fish productivity study. In all, there were nine separate research cruises carried out with a total of 109 at-sea days conducting research. The remaining projects either used data and samples collected by the three major fieldwork projects or were piggy-backed onto existing research programs at the Alaska Fisheries Science Center (AFSC).

NOAA Technical Memorandum↗
USGS2019

Accuracy of methods for reporting inorganic element concentrations and radioactivity in oil and gas wastewaters from the Appalachian Basin, U.S. based on an inter-laboratory comparison.

Accurate and precise analyses of oil and gas (O&G) wastewaters and solids ( e.g. , sediments and sludge) are important for the regulatory monitoring of O&G development and tracing potential O&G contamination in the environment. In this study, 15 laboratories participated in an inter-laboratory comparison on the chemical characterization of three O&G wastewaters from the Appalachian Basin and four solids impacted by O&G development, with the goal of evaluating the quality of data and the accuracy of measurements for various analytes of concern. Using a variety of different methods, analytes in the wastewaters with high concentrations ( i.e. , >5 mg L −1 ) were easily detectable with relatively high accuracy, often within ±10% of the most probable value (MPV). In contrast, often less than 7 of the 15 labs were able to report detectable trace metal(loid) concentrations ( i.e. , Cr, Ni, Cu, Zn, As, and Pb) with accuracies of approximately ±40%. Despite most labs using inductively coupled plasma mass spectrometry (ICP-MS) with low instrument detection capabilities for trace metal analyses, large dilution factors during sample preparation and low trace metal concentrations in the wastewaters limited the number of quantifiable determinations and likely influenced analytical accuracy. In contrast, all the labs measuring Ra in the wastewaters were able to report detectable concentrations using a variety of methods including gamma spectroscopy and wet chemical approaches following Environmental Protection Agency (EPA) standard methods. However, the reported radium activities were often greater than ±30% different to the MPV possibly due to calibration inconsistencies among labs, radon leakage, or failing to correct for self-attenuation. Reported radium activities in solid materials had less variability (±20% from MPV) but accuracy could likely be improved by using certified radium standards and accounting for self-attenuation that results from matrix interferences or a density difference between the calibration standard and the unknown sample. This inter-laboratory comparison illustrates that numerous methods can be used to measure major cation, minor cation, and anion concentrations in O&G wastewaters with relatively high accuracy while trace metal(loid) and radioactivity analyses in liquids may often be over ±20% different from the MPV.

Appalachian Basin↗
USGS2019

Cyclic lava effusion during the 2018 eruption of Kīlauea Volcano

Lava flows present a recurring threat to communities on active volcanoes, and volumetric eruption rate is one of the primary factors controlling flow behavior and hazard. The timescales and driving forces of eruption rate variability, however, remain poorly understood. In 2018, a highly destructive eruption occurred on the lower flank of Kīlauea Volcano, Hawaiʻi, where the primary vent exhibited dramatic cyclic eruption rates on both short (minutes) and long (tens of hours) timescales. We use multiparameter data to show that the short cycles were driven by shallow outgassing, while longer cycles were pressure-driven surges in magma supply triggered by summit caldera collapse events 40 km upslope. The results provide a clear link between eruption rate fluctuations and their driving processes in the magmatic system.

Hawaii↗
USGS1998

Ecological relationship between freshwater sculpins (Genus cottus) and beach-spawning sockeye salmon (Oncorhynchus nerka) in Iliamna Lake, Alaska

The interaction between two sculpin species, Cottus cognatus and Cottus aleuticus, and island beach spawning sockeye salmon (Oncorhynchus nerka) was examined in Iliamna Lake, Alaska. We conclude that sculpins actively move to specific spawning beaches and that the initiation of their movements precedes the start of spawning. Sculpin predation on sockeye eggs is positively dependent on sculpin size and on the state of the eggs (fresh versus water hardened), with the largest sculpins able to consume nearly 50 fresh eggs at a single feeding and 130 over a 7-day period. The number of sculpins in sockeye nests is greatest at the beginning of the spawning run, lowest in the middle, and high again at the end, with peak numbers of over 100 sculpins per nest (1 m2). We discuss the results in terms of energy flow of marine-derived nutrients into an oligotrophic system and in terms of the coevolution of sockeye spawning behavior and the predatory behavior of sculpins.

Canadian Journal of Fisheries and Aquatic Sciences↗
USGS2007

Comparison of fate and transport of isoxaflutole to atrazine and metolachlor in 10 Iowa rivers

Isoxaflutole (IXF), a newer low application rate herbicide, was introduced for weed control in corn (Zea mays) to use as an alternative to widely applied herbicides such as atrazine. The transport of IXF in streamwater has not been well-studied. The fate and transport of IXF and two of its degradation products was studied in 10 Iowa rivers during 2004. IXF rapidly degrades to the herbicidally active diketonitrile (DKN), which degrades to a biologically inactive benzoic acid (BA) analogue. IXF was detected in only four, DKN in 56, and BA in 43 of 75 samples. The concentrations of DKN and BA were approximately 2 orders of magnitude less than those of the commonly detected triazine and acetamide herbicides and their degradation products. Concentrations of IXF, DKN, and BA were highest during the May through June postplanting period. The concentration ratio of BA/DKN was similar to the deethylatrazine/atrazine ratio with smaller ratios occurring during May and June. The relative temporal variation of DKN and BA was similar to that observed for atrazine and deethylatrazine. This study shows that low application rate herbicides can have similar temporal transport patterns in streamwater as compared to more widely applied herbicides but at lower concentrations.

Iowa↗
USGS2005

New Perspectives on Ancient Mars

Mars was most active during its first billion years. The core, mantle, and crust formed within ∼50 million years of solar system formation. A magnetic dynamo in a convecting fluid core magnetized the crust, and the global field shielded a more massive early atmosphere against solar wind stripping. The Tharsis province became a focus for volcanism, deformation, and outgassing of water and carbon dioxide in quantities possibly sufficient to induce episodes of climate warming. Surficial and near-surface water contributed to regionally extensive erosion, sediment transport, and chemical alteration. Deep hydrothermal circulation accelerated crustal cooling, preserved variations in crustal thickness, and modified patterns of crustal magnetization.

Science↗