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Map showing outcrops of basaltic rocks of early Quaternary and Tertiary age, Basin and Range province, Southern California

This map report is one of a series of geologic and hydrologic maps covering all or parts of States within the Basin and Range province of the western United States. The map reports contain detailed information on subjects that characterize the geohydrology of the province, including the ground-water hydrology/ ground-water quality, surface distribution of selected rock types, tectonic conditions, areal geophysics, Pleistocene lakes and marshes, and mineral and energy resources. This is a part of the U.S. Geological Survey's program for geologic and hydrologic evaluation of the province to identify prospective regions for further study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984). This map was prepared from published geologic maps and reports utilizing the project guidelines defined in Sargent and Bedinger (1984). As used in this study, basaltic rocks include basaltic andesite and basalt. The map shows the known occurrences of basaltic rocks largely of Tertiary age. Locally, however, where basalts of Quaternary age were not differentiated from those of Tertiary age, the younger basalts have been included on the map. The Description of Map Units includes the geologic and, if available, radiometric age; lithology; thickness where available; and sources of data for the basaltic units in outlined and numbered areas within the counties of the study area. No information was available on the rock outcrops that are unnumbered. The listed radiometric ages do not necessarily represent the entire age range of a unit.

California↗

Mineral resource potential map of the James River Face Wilderness, Bedford and Rockbridge counties, Virginia

The rocks in the James River Face Wilderness are shales and quartzites that overlie a meta-igneous basement. They are folded into a large southwestward-plunging anticline that is cut off on the east and south by an extensive thrust fault that brings old basement rocks over the younger sedimentary rocks. Geochemical studies of stream sediments, soils, and rocks do not reveal any unusually high metal concentrations, but a large resource of metallurgical-grade quartzite and shale suitable for structural clay products and lightweight aggregate is in the wilderness. Antietam (Erwin) Quartzite has been quarried at three sites in the wilderness as raw material for silicon used in the manufacture of ferrosilicon. Other uses included crushed rock for concrete aggregate, road metal, and railroad ballast, and sand for cement and mortar. Potential uses include ganister for silica brick and specialty sands such as filter and furnace sand. Firing tests on samples of shale from the Harpers (Hampton) Formation show that it could be used for the manufacture of brick and as lightweight aggregate. Of marginal economic interest are heavy-mineral layers in the basal Unicoi (Weverton) Formation.

Virginia↗

Origin of a South Texas roll-type deposit; II, Sulfide petrology and sulfur isotope studies

Petrologic and sulfur isotopic studies have been carried out on drill core samples from a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, Webb County, south Texas. Epigenetic iron disulfide minerals formed in two distinct stages. The first stage involved sulfidization of the host rock by sulfide (H 2 S, HS-)-bearing solutions that emanated from a fault about 1.5 km downdip from and subparallel to the orebody. Pyrite was the dominant iron disulfide mineral formed from this fault sulfide. The isotopic composition (delta 34 S) of first-stage iron disulfide is quite heavy (>0 per mil), in part because the fault-derived H 2 S was isotopically heavy. The development of the second-stage sulfides was related to processes that formed the uranium roll. Iron disulfide minerals produced during this second stage commonly occur as rims around the first-stage sulfides. The rims are exclusively marcasite in and adjacent to ore, but the pyrite content in these rims increases with increasing distance from ore. The sulfur of the second-stage sulfides in the vicinity of the roll front is isotopically light (--25 to --40 per mil). The virtual absence of organic carbon in the host sand precludes a bacterial origin for the ore-stage iron disulfide minerals and, therefore, eliminates bacterial metabolism as the mechanism for isotopic fractionation. Instead, the sulfur source for ore-stage sulfides was preore (first stage) sulfides, remobilized via partial oxidation to soluble metastable sulfur oxyanions.

Texas↗

Some aspects of the origin of the Ironwood iron-formation of Michigan and Wisconsin

The Ironwood iron-formation of the Gogebic Range of Michigan and Wisconsin is made up of several rock types, each of which is characterized by a different iron-rich mineral: hematite, magnetite, pyrite, iron carbonate, or iron silicate (minnesotaite, stilpnomelane). Where the Ironwood iron-formation is relatively unaltered the Plymouth, Norrie, and Anvil members consist of wavy-bedded magnetite and silicate-rich rocks, whereas the Yale and Pence members consist of even-bedded carbonate, silicate, magnetite, and pyrite-rich rocks. These rock types represent primary facies of the iron-formation that were deposited under differing physical and chemical conditions during a period of continuous iron-rich sedimentation. Animikie sedimentation in the Gogebic district began with the deposition of sandstone and dolomitic limestone in a shallow sea advancing over a low-lying land mass of lower Precambrian granite and green-stone. Continued advance of the sea, with effective separation of clastic material near shore, permitted the dominantly chemical sedimentation of the iron- formation in somewhat deeper water. The development of an off-shore basin with partially restricted circulation would have facilitated such deposition. Minor fluctuations in the physical and chemical conditions within the depositional environment are reflected in the differing facies of the iron-formation. Deposition of the iron and silica-rich chemical sediments was terminated by increased tectonism and the deposition of the thick sequence of slates and graywackes of the Tyler formation.

Michigan, Wisconsin↗

Fluid inclusions and biomarkers in the Upper Mississippi Valley zinc-lead district; implications for the fluid-flow and thermal history of the Illinois Basin

The Upper Mississippi Valley zinc-lead district is hosted by Ordovician carbonate rocks at the northern margin of the Illinois Basin. Fluid inclusion temperature measurements on Early Permian sphalerite ore from the district are predominantly between 90?C and I50?C. These temperatures are greater than can be explained by their reconstructed burial depth, which was a maximum of approximately 1 km at the time of mineralization. In contrast to the temperatures of mineral formation derived from fluid inclusions, biomarker maturities in the Upper Mississippi Valley district give an estimate of total thermal exposure integrated over time. Temperatures from fluid inclusions trapped during ore genesis with biomarker maturities were combined to construct an estimate of the district's overall thermal history and, by inference, the late Paleozoic thermal and hydrologic history of the Illinois Basin. Circulation of groundwater through regional aquifers, given sufficient flow rates, can redistribute heat from deep in a sedimentary basin to its shallower margins. Evidence for regional-scale circulation of fluids is provided by paleomagnetic studies, regionally correlated zoned dolomite, fluid inclusions, and thermal maturity of organic matter. Evidence for igneous acti vity contemporaneous with mineralization in the vicinity of the Upper Mississippi Valley district is absent. Regional fluid and heat circulation is the most likely explanation for the elevated fluid inclusion temperatures (relative to maximum estimated burial depth) in the Upper Mississippi Valley district. One plausible driving mechanism and flow path for the ore-forming fluids is groundwater recharge in the late Paleozoic Appalachian-Ouachita mountain belt and northward flow through the Reelfoot rift and the proto- Illinois Basin to the Upper Mississippi Valley district. Warm fluid flowing laterally through Cambrian and Ordovician aquifers would then move vertically upward through the fractures that control sphalerite mineralization in the Upper Mississippi Valley district. Biomarker reactant-product measurements on rock extracts from the Upper Mississippi Valley district define a relatively low level ofthermal maturity for the district, 0.353 for sterane and 0.577 for hopane. Recently published kinetic constants permit a time-temperature relationship to be determined from these biomarker maturities. Numerical calculations were made to simulate fluid heat flow through the fracture-controlled ore zones of the Thompson-Temperly mine and heat transfer to the adjacent rocks where biomarker samples were collected. Calculations that combine the fluid inclusion temperatures and the biomarker constraints on thermal maturity indicate that the time interval during which mineralizing fluids circulated through the Upper Mississippi Valley district is on the order of 200,000 years. Fluid inclusion measurements and thermal maturities from biomarkers in the district reflect the duration of peak temperatures resulting from regional fluid circulation. On the basis of thermal considerations, the timing of fluorite mineralization in southern Illinois, and the northward-decreasing pattern of fluorine enrichment in sediments, we hypothesize that the principal flow direction was northward through the Cambrian and Ordovician aquifers of the Illinois Basin. A basin-scale flow system would result in mass transport (hydrocarbon migration, transport of metals in solution) and energy (heat) transport, which would in turn drive chemical reactions (for example, maturation of organic matter, mineralization, diagenetic reactions) within the Illinois Basin and at its margins.

Bulletin↗

Bedrock geologic map of the Woodstock quadrangle, Grafton County, New Hampshire

The bedrock geology of the Woodstock 7.5-minute quadrangle consists of highly deformed metasedimentary rocks of the Central Maine trough, including the Silurian Rangeley and Perry Mountain Formations and the Devonian Littleton Formation. The central, northern, and eastern parts of the quadrangle are underlain by the oldest rocks in the area, the Rangeley Formation. In the southwest and south-central part of the quadrangle, metaturbidites of the Perry Mountain Formation and subsequent Littleton Formation overly the Rangeley Formation in a deformed F 1 synform, herein informally called the Bagley Brook basin. The metasedimentary rocks were intruded by widespread syn- to post-tectonic granitoids of the Devonian New Hampshire Plutonic Suite and minor post-metamorphic Jurassic-Cretaceous mafic dikes of the White Mountain Plutonic-Volcanic Suite. The metasedimentary rocks were affected by at least two episodes of deformation in the Devonian Acadian orogeny. The dominant regional foliation is second-generation (S 2 /D 2 ) and formed during the development of sillimanite-muscovite mineral assemblages. Large bodies of the Early Devonian Kinsman Granodiorite intruded the metasedimentary rocks semi-concordantly during D 2 deformation. Dikes of the Late Devonian Concord Granite cut the Kinsman Granodiorite and the metasedimentary rocks and were emplaced either syn- or post-D 2 . The map pattern in the Rangeley Formation is dominated by northeast to northwest trending, moderately to steeply north-dipping F 2 and F 3 folds. Map-scale F 1 folds are defined by the Bagley Brook basin. Previous division of Rangeley Formation stratigraphy in this region into “upper” and “lower” parts was not corroborated by 1:24,000-scale mapping of lithodemic units, and rocks previously mapped as part of the Smalls Falls and Madrid Formations are here reassigned to the Rangeley Formation. Some rocks previously mapped as the lower part of the Littleton Formation are now assigned to the Perry Mountain Formation. The Littleton Formation on this map is approximately equivalent to rocks previously mapped as the upper part of the same formation. Steeply dipping fractures in the quadrangle show a preferred northeast orientation, consistent with subsurface fracture orientations in the well fields near Mirror Lake. Jurassic-Cretaceous mafic dikes and normal faults show preferred northeast orientations, similar to the fractures, suggesting that the extensional stress field that controlled dike orientation during the Mesozoic also produced the dominant brittle fabrics in the area.

New Hampshire↗

Proterozoic metamorphism and uplift history of the north-central Laramie Mountains, Wyoming, USA

The Laramie Mountains of south-eastern Wyoming contain two metamorphic domains that are separated by the 1.76 Ga. Laramie Peak shear zone (LPSZ). South of the LPSZ lies the Palmer Canyon block, where apatite U-Pb ages are c. 1745 Ma and the rocks have undergone Proterozoic kyanite-grade Barrovian metamorphism. In contrast, in the Laramie Peak block, north of the shear zone, the U-Pb apatite ages are 2.4-2.1 Ga, the granitic rocks are unmetamorphosed and supracrustal rocks record only low-T amphibolite facies metamorphism that is Archean in age. Peak mineral assemblages in the Palmer Canyon block include (a) quartz-biotite-plagioclase-garnet-staurolite-kyanite in the pelitic schists; (b) quartz-biotite-plagioclase-low-Ca amphiboles-kyanite in Mg-Al-rich schists, and locally (c) hornblende-plagioclase-garnet in amphibolites. All rock types show abundant textural evidence of decompression and retrograde re-equilibration. Notable among the texturally late minerals are cordierite and sapphirine, which occur in coronas around kyanite in Mg-Al-rich schists. Thermobarometry from texturally early and late assemblages for samples from different areas within the Palmer Canyon block define decompression from > 7 kbar to < 3 kbar. The high-pressure regional metamorphism is interpreted to be a response to thrusting associated with the Medicine Bow orogeny at c. 1.78-1.76 Ga. At this time, the north-central Laramie Range was tectonically thickened by as much as 12 km. This crustal thickening extended for more than 60 km north of the Cheyenne belt in southern Wyoming. Late in the orogenic cycle, rocks of the Palmer Canyon block were uplifted and unroofed as the result of transpression along the Laramie Peak shear zone to produce the widespread decompression textures. The Proterozoic tectonic history of the central Laramie Range is similar to exhumation that accompanied late-orogenic oblique convergence in many Phanerozoic orogenic belts.

Journal of Metamorphic Geology↗

Partially melted granodiorite and related rocks ejected from Crater Lake caldera, Oregon

Blocks of medium-grained granodiorite to 4 m, and minor diabase, quartz diorite, granite, aplite and granophyre, are common in ejecta of the ∼6,900 yr BP caldera-forming eruption of Mount Mazama. The blocks show degrees of melting from 0–50 vol%. Because very few have adhering juvenile magma, it is thought that the blocks are fragments of the Holocene magma chamber’s walls. Primary crystallisation of granodiorite produced phenocrystic pl + hyp + aug + mt + il + ap + zc, followed by qz + hb + bt + alkali feldspar (af). Presence of fluid inclusions in all samples implies complete crystallisation before melting. Subsolidus exchange with meteoric hydrothermal fluids before melting is evident in δ 18 O values of −3.4–+4.9‰ for quartz and plagioclase in partially melted granodiorites (fresh lavas from the region have δ 18 O values of +5.8–+7.0‰); δ 18 O values of unmelted granodiorites from preclimatic eruptive units suggest hydrothermal exchange began between ∼70 and 24 ka. Before eruption, the granitic rocks equilibrated at temperatures, estimated from Fe–Ti oxide compositions, of up to ∼1000°C for c . 10 2 –10 4 years at a minimum pressure of 100–180 MPa. Heating caused progressive breakdown or dissolution of hb, af, bt, and qz, so that samples with the highest melt fractions have residual pl + qz and new or re-equilibrated af + hyp + aug + mt + il in high-silica rhyolitic glass (75–77% SiO 2 ). Mineral compositions vary systematically with increasing temperature. Hornblende is absent in rocks with Fe–Ti oxide temperatures >870°C, and bt above 970°C. Oxygen isotope fractionation between qz, pl, and glass in partially fused granodiorite also is consistent with equilibration at T ≥900°C (Δ 18 O qz-pl = +0.7±0.5‰). Element partitioning between glass and crystals reflects the large fraction of refractory pl, re-equilibration of af and isolation or incomplete dissolution of accessory phases. Ba and REE contents of analysed glass separates can be successfully modelled by observed degrees of partial melting of granodiorite, but Rb, Sr and Sc concentrations cannot. Several samples have veins of microlite-free glass 1–5 mm thick that are compositionally and physically continuous with intergranular melt and which apparently formed after the climactic eruption began. Whole-rock H 2 O content, microprobe glass analysis sums near 100% and evidence for high temperature suggest liquids in the hotter samples were nearly anhydrous. The occurrence of similar granodiorite blocks at all azimuths around the 8 × 10 km caldera implies derivation from one pluton. Compositional similarity between granodiorite and pre-Mazama rhyodacites suggests that the pluton may have crystallised as recently as 0.4 Ma; compositional data preclude crystallisation from the Holocene chamber. The history of crystallisation, hydrothermal alteration, and remelting of the granitic rocks may be characteristic of shallow igneous systems in which the balance between hydrothermal cooling and magmatic input changes repeatedly over intervals of 10 4 –10 6 years.

Oregon↗

Geologic and aeromagnetic maps and mineral resource potential survey of the Blackjack Springs Wilderness, Vilas County, Wisconsin

The mineral resource potential of the Blackjack Springs Wilderness in the Nicolet National Forest, Vilas County, Wisc., was evaluated in 1982. No bedrock exposures are known in or near the wilderness. Geophysical data and regional geologic relations suggest that the area consists mostly of recrystallized and deformed mafic volcanic rocks and associated mafic intrusives of Early Proterozoic age. The only identified mineral resources in the Blackjack Springs Wilderness are sand and gravel, but these commodities are abundant regionally. While the occurrence of stratabound massive-sulfide (cooper-zinc-lead) and (or) magmatic sulfide (copper and (or) nickel)-type deposits are possible in the wilderness, their occurrence is not probable.

Wisconsin↗

Partially melted granodiorite and related rocks ejected from Crater Lake caldera, Oregon

Blocks of medium-grained granodiorite to 4 m, and minor diabase, quartz diorite, granite, aplite and granophyre, are common in ejecta of the ∼6,900 yrBP calderaforming eruption of Mount Mazama. The blocks show degrees of melting from 0–50 vol%. Because very few have adhering juvenile magma, it is thought that the blocks are fragments of the Holocene magma chamber's walls. Primary crystallisation of granodiorite produced phenocrystic pl + hyp + aug + mt + il + ap + zc, followed by qz + hb + bt + alkali feldspar (af). Presence of fluid inclusions in all samples implies complete crystallisation before melting. Subsolidus exchange with meteoric hydrothermal fluids before melting is evident in δ 18 O values of −3·4+4·9‰ for quartz and plagioclase in partially melted granodiorites (fresh lavas from the region have δ 18 O values of +5·8−+7·0‰); δ 18 O values of unmelted granodiorites from preclimatic eruptive units suggest hydrothermal exchange began between ∼70 and 24 ka. Before eruption, the granitic rocks equilibrated at temperatures, estimated from Fe-Ti oxide compositions, of up to ∼1000°C for c. 10 2 –10 4 years at a minimum pressure of 100-180 MPa. Heating caused progressive breakdown or dissolution of hb, af, bt, and qz, so that samples with the highest melt fractions have residual pl + qz and new or re-equilibrated af + hyp + aug + mt + il in high-silica rhyolitic glass (75-77% SiO 2 ). Mineral compositions vary systematically with increasing temperature. Hornblende is absent in rocks with Fe-Ti oxide temperatures >870°C, and bt above 970°C. Oxygen isotope fractionation between qz, pl, and glass in partially fused granodiorite also is consistent with equilibration at T≥900°C (Δ 18 O qz.pl = +0·7 ± 0·5‰). Element partitioning between glass and crystals reflects the large fraction of refractory pl, re-equilibration of af and isolation or incomplete dissolution of accessory phases. Ba and REE contents of analysed glass separates can be successfully modelled by observed degrees of partial melting of granodiorite, but Rb, Sr and Sc concentrations cannot. Several samples have veins of microlite-free glass 1–5 mm thick that are compositionally and physically continuous with intergranular melt and which apparently formed after the climactic eruption began. Whole-rock H 2 O content, microprobe glass analysis sums near 100% and evidence for high temperature suggest liquids in the hotter samples were nearly anhydrous. The occurrence of similar granodiorite blocks at all azimuths around the 8 × 10 km caldera implies derivation from one pluton. Compositional similarity between granodiorite and pre-Mazama rhyodacites suggests that the pluton may have crystallised as recently as 0·4 Ma; compositional data preclude crystallisation from the Holocene chamber. The history of crystallisation, hydrothermal alteration, and remelting of the granitic rocks may be characteristic of shallow igneous systems in which the balance between hydrothermal cooling and magmatic input changes repeatedly over intervals of 10 4 -10 6 years.

Oregon↗

Ground-water resources in the tri-state region adjacent to the Lower Delaware River

The purpose of this report is to appraise and evaluate the groundwater resources of a tri-state region adjacent to the lower Delaware River that is centered around Philadelphia, Pa., and Camden, N. J., and includes Wilmington, Del., and Trenton, N.J. Specifically, the region includes New Castle County, Del.; Burlington, Camden, Gloucester, Mercer, and Salem Counties in New Jersey; and Bucks, Chester, Delaware, Montgomery, and Philadelphia Counties in Pennsylvania. The peculiar advantages of ground water, such as its availability in many places without the necessity for expensive pipelines and its relatively uniform temperature and quality, make it an especially valuable resource in an industrial area. Large, readily available supplies of good, fresh water have contributed substantially to the recent rapid industrial growth of the lower Delaware River basin and will be vital to its continued prosperity. The major part of these supplies is drawn from the streams passing through the region, but very large quantities of ground water also are used. The region is divided almost equally by the Fall Line, which extends in a southwesterly direction along the general course of the Delaware River from Trenton, N.J., to Wilmington, Del., and beyond. Northwest of the Fall Line is a region of consolidated rocks in which ground water occurs mainly in cracks, crevices, and openings created or enlarged by weathering. The capacity of the various geologic formations to yield water depends largely upon the degree to which they have been fractured and weathered. The yield of individual wells in this part of the region is generally small to moderate and not readily predictable. Ground water in this part of the region is generally low in dissolved minerals and suitable for many uses without treatment. Southeast of the Fall Line lie the unconsolidated rocks of the Coastal Plain. Ground water occurs in these rocks largely in the pore spaces between the individual mineral grains. The major formations and the principal aquifers are rather uniform in their water-bearing characteristics over large areas. The yield of individual wells is moderate to very large and may be predicted with a reasonable degree of assurance. Sufficient quantities of ground water are available in most places for all ordinary purposes. The chemical quality of the ground water from the Coastal Plain aquifers is generally acceptable for most uses, but objectionable quantities of iron or other minerals are found in some places, and some waters have a low pH and are corrosive. More than 40 distinct geologic formations occur in the region. They range in age from Precambrian to Recent. Nearly all will yield some water to wells. However, only about a dozen yield water freely enough to be considered major aquifers. Of these, the sands of the Raritan and Magothy formations have been developed most intensively, and the Cohansey sand appears to have the greatest capacity for additional development. The present withdrawal of ground water in the region is estimated to average more than 200 mgd, of which more than half is drawn from the aquifers in the Raritan and Magothy formations. It is estimated that additional supplies of ground water, aggregating more than 1 billion gallons a day, can be developed within the region. Furthermore, substantial additional quantities can be developed outside the region for use within it if the need should ever arise. Induced recharge from the Delaware River supplies a substantial portion of the total water drawn from the Raritan and Magothy formations. In some areas, the quality of the water from these aquifers is approaching that of the river. Increased withdrawals of water from wells along the river will tend to increase induced recharge. Thus, the maintenance of a good quality of water in the river, which is desirable for many other reasons, is imperative if the quality of the ground-water supply is to be maintained. The proposed deepening of the Delaware River channel from Philadelphia to Trenton will greatly increase the opportunity for the interchange of water between the river and the adjacent aquifers. Whether this will be beneficial or detrimental to the ground-water supplies will depend upon the quality of the water in that reach of the river. If an acceptable quality of river water is maintained, the groundwater resources of the region will be augmented. If salt water from the ocean or excessive contamination from other sources should render the river water undesirable as a source of recharge, actual and potential ground-water supplies aggregating about 250 mgd would be endangered. The danger of salt-water encroachment into the aquifers normally yielding fresh water may limit the optimum yield of some of the most important aquifers in the region. Encroachment may come either from salt water in the surface-water bodies of the region or from parts of the aquifers, normally containing salt water. The protection of ground-water supplies against salt-water encroachment can be maintained only by constant vigilance, careful distribution of the pumping from the aquifers, regular sampling of outpost wells in exposed localities, and adjustment of rates of pumping in the light of changing conditions. The maximum beneficial utilization of the ground-water resources cannot be accomplished in haphazard fashion. It must be planned and controlled on the basis of sound, current information about the hydrology of the various aquifers. Continued and, in some areas, intensified investigations of the ground-water resources of the region should form the basis for such planning and control.

New Jersey, Pennsylvania, Delaware↗

Crystallization history of Kilauea Iki lava lake as seen in drill core recovered in 1967-1979

Kilauea Iki lava lake formed during the 1959 summit eruption, one of the most picritic eruptions of Kilauea Volcano in the twentieth century. Since 1959 the 110 to 122 m thick lake has cooled slowly, developing steadily thickening upper and lower crusts, with a lens of more molten lava in between. Recent coring dates, with maximum depths reached in the center of the lake, are: 1967 (26.5 m). 1975 (44.2 m), 1976 (46.0 m) and 1979 (52.7 m). These depths define the base of the upper crust at the time of drilling. The bulk of the core consists of a gray, olivine-phyric basalt matrix, which locally contains coarser-grained diabasic segregation veins. The most important megascopic variation in the matrix rock is its variation in olivine content. The upper 15 m of crust is very olivine-rich. Abundance and average size of olivine decrease irregularly downward to 23 m; between 23 and 40 m the rock contains 5-10% of small olivine phenocrysts. Below 40 m. olivine content and average grainsize rise sharply. Olivine contents remain high (20-45%, by volume) throughout the lower crust, except for a narrow (< 6 m) olivine depleted zone near the basalt contact. Petrographically the olivine phenocrysts in Kilauea Iki can be divided into two types. Type 1 phenocrysts are large (1-12 mm long), with irregular blocky outlines, and often contain kink bands. Type 2 crystals are relatively small (0.5-2 mm in length), euhedral and undeformed. The variations in olivine content of the matrix rock are almost entirely variations in the amount of type 1 olivines. Sharp mineral layering of any sort is rare in Kilauea Iki. However, the depth range 41-52 m is marked by the frequent occurrence of steeply dipping (70??-90??) bands or bodies of slightly vuggy olivine-rich rock locally capped with a small cupola of segregation-vein material. In thin section there is clear evidence for relative movement of melt and crystals within these structures. The segregation veins occur only in the upper crust. The most widely distributed (occurring from 4.5-59.4 m) are thin veins (most < 5 cm thick), which cut the core at moderate angles and appear to have been derived from the immediately adjacent wall-rock by filter pressing. There is also a series of thicker (0.1-1.5 m) segregation veins, which recur every 2-3 m, between 20 and 52 m. These have subhorizontal contacts and appear, from similarities in thickness and spacing, to correlate between drill holes as much as 100 m apart. These large veins are not derived from the adjacent wallrock: their mechanism of formation is still problematical. The total thickness of segregation veins in Kilauea Iki is 3-6 m in the central part of the lake, corresponding to 6-11% of the upper crust. Whole-rock compositions for Kilauea Iki fall into two groups: the matrix rock ranges from 20-7.5% MgO, while the segregation veins all contain between 6.0 and 4.5% MgO. There are no whole-rock compositions of intermediate MgO content. Samples from < 12 m show eruption-controlled chemistry. Below that depth, matrix rock compositions have higher Al2O3, TiO2 and alkalies, and lower CaO and FeO, at a given MgO content than do the eruption pumices. The probable causes of this are assimilation of low-melting components from foundered crust, plus removal of olivine, plus removal of minor augite, for rocks with MgO contents of < 8.0%. Given the observed rate of growth of the upper crust, one can infer that significant removal of the type 1 olivine phenocrysts from the upper part of the lake began in 1963 and ceased sometime prior to 1972. The process. probably gravitative settling, appears to have been inhibited earlier by gas streaming from the lower part of the lens of melt. The olivine cumulate zone, which extends into the upper crust, contains relatively few (25-40%) olivine crystals, few of which actually touch each other. The diffuseness of the cumulate zone raises the possibility that the crystals were coated with a relatively visous boundary layer

Bulletin Volcanologique↗

Thermochronology of Cretaceous batholithic rocks in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

The thermochronology for several suites of Mesozoic metamorphic and plutonic rocks collected throughout the northern Peninsular Ranges batholith (PRB) was studied as part of a collaborative isotopic study to further our understanding of the magmatic and tectonic history of southern California. These sample suites include: a traverse through the plutonic rocks across the northern PRB ( N = 29), a traverse across a central structural and metamorphic transition zone of mainly metasedimentary rocks at Searl ridge ( N = 20), plutonic samples from several drill cores ( N = 7) and surface samples ( N = 2) from the Los Angeles Basin, a traverse across the Eastern Peninsular Ranges mylonite zone ( N = 6), and a suite of plutonic samples collected across the northern PRB ( N = 13) from which only biotite 40 Ar/ 39 Ar ages were obtained. These geochronologic data help to characterize five major petrologic, geochemical, and isotopic zonations of the PRB (western zone, WZ; western transition zone, WTZ; eastern transition zone, ETZ; eastern zone, EZ; and upper-plate zone, UPZ). Apparent cooling rates were calculated using U-Pb zircon (zr) and titanite (sphene) ages; 40 Ar/ 39 Ar ages from hornblende (hbl), biotite (bi), and K-feldspar (Kf); and apatite fission-track (AFT) ages from the same samples. The apparent cooling rates across the northern PRB vary from relatively rapid in the west (zr-hbl ~210 °C/m.y.; zr-bio ~160 °C/m.y.; zr-Kf ~80 °C/m.y.) to less rapid in the central (zr-hb ~280 °C/m.y.; zr-bio ~90 °C/m.y.; zr-Kf ~60 °C/m.y.) and eastern (zr-hbl ~185 °C/m.y.; zr-bio ~180 °C/m.y.; zr-Kf ~60 °C/m.y.) zones. An exception in the eastern zone, the massive San Jacinto pluton, appears to have cooled very rapidly (zr-bio ~385 °C/m.y.). Apparent cooling rates for the UPZ samples are consistently slower in comparison (~25–45 °C/m.y.), regardless of which geochronometers are used. Notable characteristics of the various ages from different dating methods include: (1) Zircon ages indicate a progressive younging of magmatic activity from west to east between ca. 125 and 90 Ma. (2) Various geochronometers were apparently affected by emplacement of the voluminous (ETZ and EZ) La Posta–type plutons emplaced between 99 and 91 Ma. Those minerals affected include K-feldspar in the western zone rocks, biotite and K-feldspar in the WTZ rocks, and white mica and K-feldspar in rocks from Searl ridge. (3) The AFT ages record the time the rocks cooled through the AFT closure temperature (~100 °C in these rocks), likely due to exhumation. Throughout most of the northern traverse, the apatite data indicate the rocks cooled relatively quickly through the apatite partial annealing zone (PAZ; from ~110 °C to 60 °C) and remained at temperatures less than 60 °C as continued exhumation cooled them to present-day surface temperatures. The ages indicate that the western “arc” terrane of the WZ was being uplifted and cooled at ca. 91 Ma, during or shortly after intrusion of the 99–91 Ma La Posta–type plutons to the east. Uplift and cooling occurred later, between ca. 70 Ma and ca. 55 Ma, in the central WTZ, ETZ, and EZ rocks, possibly as upwarping in response to events in the UPZ. The UPZ experienced differential exhumation at ca. 50–35 Ma: Cooling on the western edge was taking place at about the same time or shortly after cooling in the younger samples in the ETZ and EZ, whereas on the east side of the UPZ, the rocks cooled later (ca. 35 Ma) and spent a prolonged time in the apatite PAZ compared to most northern traverse samples. Apparent cooling rates from Los Angeles Basin drill core samples of plutonic rocks show that four are similar to the WTZ thermal histories, and two are similar to the WTZ histories, indicating that the eastern part of the Los Angeles Basin area is underlain by mainly western zone PRB rocks. Thermal histories revealed by samples from Searl ridge indicate that the WTZ magmatism intruded the metasedimentary rocks prior to their deformation and metamorphism at ca. 97 Ma. Both low-grade schists and metasandstones of the western side of the ridge and high-grade gneisses of the eastern side of the ridge have thermal histories consistent with eastern zone rocks—suggesting a temporal/thermal relationship between the western transition zone and the eastern zones. Limited ages from six samples across the Eastern Peninsular Ranges mylonite zone (EPRMZ) indicate that this zone underwent cooling after emplacement of the youngest UPZ rocks at 85 Ma, suggesting that thrusting along the EPRMZ was either coeval with emplacement of the UPZ plutonic rocks or occurred shortly afterwards (~10–15 m.y.). Alternatively, the EPRMZ thrusting may have occurred at temperatures under ~180 °C at yet a later date. The geochronology presented here differs slightly from previous studies for similar rocks exposed across the middle and southern portions of the PRB, in that our data define a relatively smooth progression of magmatism from west to east, and the transition from western, oceanic-arc plutonism to eastern, continental arc plutonism is interpreted to have occurred at ca. 99–97 Ma and not at ca. 105 Ma.

Book chapter↗

Uranium in surface waters and sediments affected by historical mining in the Denver West 1:100,000 Quadrangle, Colorado

Geochemical sampling of 82 stream waters and 87 stream sediments within mountainous areas immediately west of Denver, Colorado, was conducted by the U.S. Geological Survey in October 1994. The primary purpose was to evaluate regionally the effects of geology and past mining on the concentration and distribution of uranium. The study area contains uranium- and thorium-rich bedrock, numerous noneconomic occurrences of uranium minerals, and several uranium deposits of variable size and production history. During the sampling period, local streams had low discharge and were more susceptible to uranium-bearing acid drainage originating from historical mines of base- and precious-metal sulfides. Results indicated that the spatial distribution of Precambrian granites and metamorphic rocks strongly influences the concentration of uranium in stream sediments. Within-stream transport increases the dispersion of uranium- and thorium rich mineral grains derived primarily from granitic source rocks. Dissolved uranium occurs predominantly as uranyl carbonate complexes, and concentrations ranged from less than 1 to 65 micrograms per liter. Most values were less than 5 micrograms per liter, which is less than the current drinking water standard of 30 micrograms per liter and much less than locally applied aquatic-life toxicity standards of several hundred micrograms per liter. In local streams that are affected by uranium-bearing acid mine drainage, dissolved uranium is moderated by dilution and sorptive uptake by stream sediments. Sorbents include mineral alteration products and chemical precipitates of iron- and aluminum-oxyhydroxides, which form where acid drainage enters streams and is neutralized. Suspended uranium is relatively abundant in some stream segments affected by nearby acid drainage, which likely represents mobilization of these chemical precipitates. The 234U/238U activity ratio of acid drainage (0.95-1.0) is distinct from that of local surface waters (more than 1.05), and this distinctive isotopic composition may be preserved in iron-oxyhydroxide precipitates of acid drainage origin. The study area includes a particularly large vein-type uranium deposit (Schwartzwalder mine) with past uranium production. Stream water and sediment collected downstream from the mine's surface operations have locally anomalous concentrations of uranium. Fine-grained sediments downstream from the mine contain rare minute particles (10-20 micrometers) of uraninite, which is unstable in a stream environment and thus probably of recent origin related to mining. Additional rare particles of very fine grained (less than 5 micrometer) barite likely entered the stream as discharge from settling ponds in which barite precipitation was formerly used to scavenge dissolved radium from mine effluent.

Colorado↗

Geologic map of the Weka Dur gold deposit, Badakhshan Province, Afghanistan, modified from the 1967 original map compilation of M.P. Guguev and others

This geologic map of the Weka Dur gold deposit located in Badakhshan Province, Afghanistan, is a redrafted and modified version of the Geological map of the Weka Dur area, scale 1:10,000 and Geological map of the Weka Dur deposit, scale 1:2,000 from Guguev and others (1967) (Soviet report no. R1584). That unpublished Soviet report contains the original maps and cross sections, which were prepared in cooperation with the Ministry of Mines and Industries of the Republic of Afghanistan in 1967 under contract no. 1378 (Technoexport, USSR). This USGS publication not only reproduces the geology of the original Soviet maps and cross sections, but also illustrates a mapped adit with reported gold concentrations from sampling within the adit, and shows the location of Soviet trenches along the Weka Dur gold deposit. The Weka Dur gold deposit lies in a cluster of other gold deposits in Badakhshan Province (Ragh district), such as the Kadar, Nesheb Dur, and Rishaw gold occurrences. These gold occurrences lie within a zone of late Hercynian folding and are most likely related to fluids that originated from orogenic processes. The Weka Dur deposit is the largest recorded gold occurrence in Afghanistan and is hosted in Proterozoic mica schist and amphibolite that is intruded by diabase dikes and other intrusive rocks. The tabular orebody is 350 meters (m) long and 2 m wide and can be traced downdip for 110 m. Mineralization consists of ochreous, brecciated schists containing high gold concentrations along gently and steeply dipping fissures. The brecciated rocks grade to 46.7 grams per ton (g/t) silver and contain arsenopyrite, galena, chalcopyrite, and scheelite. Trenches and adits were constructed, mapped, and sampled during the 1960s. Calculated resources are 958.3 kilograms of gold, averaging 4.1 g/t gold.

Badakhshan Province↗

Emsian synorogenic paleogeography of the Maine Applachians

The Acadian deformation front in the northern Appalachians of Maine and New Hampshire can now be closely located during the early Emsian (Early Devonian; 408-406 Ma). Tight correlations between paleontologically and isotopically dated rocks are possible only because of a new 408-Ma time scale tie point for the early Emsian. The deformation front lay between a belt of Lower Devonian flysch and molasse that were deposited in an Acadian foreland basin and had not yet been folded and a belt of early Emsian plutons that intruded folded Lower Devonian rocks. This plutonic belt includes the newly dated Ore Mountain gabbro (U/Pb; 406 Ma), which hosts magmatic-sulfide mineralization. Along the deformation front, a 407-Ma pluton that locally truncates Acadian folds (Katahdin) was the feeder to volcanic rocks (Traveler Rhyolite; 406-407 Ma) that are part of the foreland-basin succession involved in these same folds. The Emsian igneous rocks thus define a syncollisional magmatic province that straddled the deformation front. These findings bear on three alternative subduction geometries for the Acadian collision.

Journal of Geology↗

Reconnaissance geology of the Al'Awshaziyah Quadrangle, sheet 26/41 B, Kingdom of Saudi Arabia

The Al 'Awshaziyah quadrangle (26/41 B) is located between lat 26&deg;30' and 27&deg;00 f N. and long 41&deg;30' and 42&deg;00' E. in the northeastern part of the Arabian Shield. The quadrangle contains surficial Quaternary deposits and locally exposed underlying upper Proterozoic intrusive, volcanic, and volcaniclastic rocks. The oldest rocks, gabbro and pyroxenite, are tentatively correlated with the Ha'il mafic-ultramafic complex to the north of the quadrangle. Two younger volcanic sequences, structurally more or less distinct but compositionally transitional, have been identified. The Aqab formation (about 640-610 Ma old) consists of slightly metamorphosed, moderately to strongly folded flows and tuffs of basalt, dacite, and minor rhyolite. An interlayered subaerial conglomerate and a lack of deep-marine sediments distinguish the Aqab from the older and distinctly oceanic Nuf formation. The.Aqab formation is overlain by felsic ash-flow tuffs and related fragmental rocks of the Al 'Awshaziyah formation whose major source is a large caldera in the western part of the quadrangle. Plutonic rocks include granites that predate and postdate both the Aqab and Al 'Awshaziyah formations. The youngest granites, dated at about 580 Ma, are the Salma and Ar Rumman batholiths and are more -alkaline and more silicic than the older granites. The Ar Rumman granite is peralkaline. Even the youngest intrusive rocks have been cut by faults that are probably related to the northwest-trending Najd fault system. No metallic mineralization has been recognized in the quadrangle. A small quarry near the western boundary of the quadrangle produces crushed rock.

Open-File Report↗

Geologic, geochemical, and isotopic studies of a carbonate- and siliciclastic-hosted Pb-Zn deposit at Lion Hill, Vermont

Zn-, Pb-, Cu-, and Fe-bearing rocks of the Lion Hill area in western Vermont formed during the Early Cambrian by syngenetic sedimentary-exhalative and diagenetic replacement processes. Sphalerite, galena, chalcopyrite, pyrite, and, locally, magnetite form stratabound and broadly stratiform lenticular zones, -300 meters long and 25-50 meters thick, which are uneconomic at the present time. The lenses are structurally disrupted and metamorphosed to greenschist facies, probably due to the Taconic orogeny. Textural evidence suggests that mineralizing fluids permeated the sediments prior to lithification and that a dilatant fracture zone, possibly a feeder zone, contains some of the discordant veins at Lion Hill. The veins may have formed when the sediments were in a plastic, semiconsolidated state. The association of layered iron formation containing base-metal sulfide minerals provides possible lithologic evidence for syngenetic mineralization by submarine exhalative activity. Sand bars and tidal channels present in the sedimentary section could have acted as permeable pathways for movement of mineralizing fluids. The complex interlayering in the sedimentary sequence of carbonate and siliciclastic rock types having widely varying permeabilities created numerous fluid traps. Homogenization temperatures of primary and secondary inclusions in vein sphalerite range from 152&deg;C to 196&deg;C; salinities range from 11.5 to 14.0 equivalent weight percent NaCl. &delta; 34 S values of sulfides from Lion Hill vary from -25.9 to +10.0 per mil, and fall within the expected range for sulfide produced from bacteriogenic reduction of sulfate with &delta; 34 S values of 25 to 30 per mil. In addition, some pyrite probably formed from sulfate in trapped pore fluid that resulted in heavier isotopic values characteristic of more closed-system behavior. Three sphalerite samples that have heavier sulfur isotopic values may reflect a change in the source of sulfur during a later episode of mineralization, perhaps a change to a deep-seated source. Lead isotopic compositions of galenas from mineralized zones at Lion Hill range from 18.351 to 18.632 for 206 Pb/ 204 Pb, from 15.546 to 15.618 for 207 Pb/ 204 Pb, and from 38.126 to 38.496 for 208 Pb/ 204 Pb. The lead isotopic compositions of galena from Lion Hill and fluid inclusion and sulfur isotopic values for the Lion Hill sulfides are more like those of Pb-Zn-Ag deposits of Ireland than those of MVT or Appalachian-type Zn deposits. The prospect of an Irish-type sedimentary-exhalative origin for stratabound Pb-Zn deposits of the Paleozoic shelf of North America is of considerable importance to understanding the timing of mineralization relative to platform evolution and for evaluating the mineral resource potential of the region. Our study of the Lion Hill deposit indicates a potential for Irish-type Pb-Zn deposits in platform rocks of western Vermont; however, at Lion Hill they contain enrichments of Pb, Zn, and Cu rather than a Pb, Zn, and Ag association.

Vermont↗