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Rheology of the lithosphere

During the quadrennial term 1979–1982, major advances have been made in our knowledge of the rheology of the oceanic lithosphere by the skillful combination of experimental and theoretical rock mechanics, seismology and marine geophysics in increasingly sophisticated models for the flexure of the oceanic lithosphere at seamounts and island chains, along transform faults, and at subduction zones. The relative simplicity of plate bending geometry, thermal history, and mineralogical and chemical compositions of the oceanic plates in these settings make the geophysical observations very powerful constraints on the in situ rheology of the oceanic lithosphere. In the first part of this paper, I review the laboratory work on materials appropriate to the oceanic lithosphere with emphasis on contributions during the quadrennial period and the need for future work. The important results of flexure models incorporating realistic material properties are then summarized.

Reviews of Geophysics and Space Physics↗

A model for nematode locomotion in soil

Locomotion of nematodes in soil is important for both practical and theoretical reasons. We constructed a model for rate of locomotion. The first model component is a simple simulation of nematode movement among finite cells by both random and directed behaviours. Optimisation procedures were used to fit the simulation output to data from published experiments on movement along columns of soil or washed sand, and thus to estimate the values of the model's movement coefficients. The coefficients then provided an objective means to compare rates of locomotion among studies done under different experimental conditions. The second component of the model is an equation to predict the movement coefficients as a function of controlling factors that have been addressed experimentally: soil texture, bulk density, water potential, temperature, trophic group of nematode, presence of an attractant or physical gradient and the duration of the experiment. Parameters of the equation were estimated by optimisation to achieve a good fit to the estimated movement coefficients. Bulk density, which has been reported in a minority of published studies, is predicted to have an important effect on rate of locomotion, at least in fine-textured soils. Soil sieving, which appears to be a universal practice in laboratory studies of nematode movement, is predicted to negatively affect locomotion. Slower movement in finer textured soils would be expected to increase isolation among local populations, and thus to promote species richness. Future additions to the model that might improve its utility include representing heterogeneity within populations in rate of movement, development of gradients of chemical attractants, trade-offs between random and directed components of movement, species differences in optimal temperature and water potential, and interactions among factors controlling locomotion.

Nematology↗

Sulfide oxidation and distribution of metals near abandoned copper mines in coastal environments, Prince William Sound, Alaska, USA

The oxidation of sulfide-rich rocks, mostly leftover debris from Cu mining in the early 20th century, is contributing to metal contamination of local coastal environments in Prince William Sound, Alaska. Analyses of sulfide, water, sediment, precipitate and biological samples from the Beatson, Ellamar, and Threeman mine sites show that acidic surface waters generated from sulfide weathering are pathways for redistribution of environmentally important elements into and beyond the intertidal zone at each site. Volcanogenic massive sulfide deposits composed of pyrrhotite and (or) pyrite + chalcopyrite + sphalerite with subordinate galena, arsenopyrite, and cobaltite represent potent sources of Cu, Zn, Pb, As, Co, Cd, and Hg. The resistance to oxidation among the major sulfides increases in the order pyrrhotite ??? sphalerite < chalcopyrite ??? pyrite; thus, pyrrhotite-rich rocks are typically more oxidized than those dominated by pyrite. The pervasive alteration of pyrrhotite begins with rim replacement by marcasite followed by replacement of the core by sulfur, Fe sulfate, and Fe-Al sulfate. The oxidation of chalcopyrite and pyrite involves an encroachment by colloform Fe oxyhydroxides at grain margins and along crosscutting cracks that gradually consumes the entire grain. The complete oxidation of sulfide-rich samples results in a porous aggregate of goethite, lepidocrocite and amorphous Fe-oxyhydroxide enclosing hydrothermal and sedimentary silicates. An inverse correlation between pH and metal concentrations is evident in water data from all three sites. Among all waters sampled, pore waters from Ellamar beach gravels have the lowest pH (???3) and highest concentrations of base metals (to ???25,000 ??g/L), which result from oxidation of abundant sulfide-rich debris in the sediment. High levels of dissolved Hg (to 4100 ng/L) in the pore waters probably result from oxidation of sphalerite-rich rocks. The low-pH and high concentrations of dissolved Fe, Al, and SO4 are conducive to precipitation of interstitial jarosite in the intertidal gravels. Although pore waters from the intertidal zone at the Threeman mine site have circumneutral pH values, small amounts of dissolved Fe2+ in the pore waters are oxidized during mixing with seawater, resulting in precipitation of Fe-oxyhydroxide flocs along the beach-seawater interface. At the Beatson site, surface waters funneled through the underground mine workings and discharged across the waste dumps have near-neutral pH (6.7-7.3) and a relatively small base-metal load; however, these streams probably play a role in the physical transport of metalliferous particulates into intertidal and offshore areas during storm events. Somewhat more acidic fluids, to pH 5.3, occur in stagnant seeps and small streams emerging from the Beatson waste dumps. Amorphous Fe precipitates in stagnant waters at Beatson have high Cu (5.2 wt%) and Zn (2.3 wt%) concentrations that probably reflect adsorption onto the extremely high surface area of colloidal particles. Conversely, crystalline precipitates composed of ferrihydrite and schwertmannite that formed in the active flow of small streams have lower metal contents, which are attributed to their smaller surface area and, therefore, fewer reactive sorption sites. Seeps containing precipitates with high metal contents may contribute contaminants to the marine environment during storm-induced periods of high runoff. Preliminary chemical data for mussels (Mytilus edulis) collected from Beatson, Ellamar, and Threeman indicate that bioaccumulation of base metals is occurring in the marine environment at all three sites.

Applied Geochemistry↗

Relationships among sea-floor structure and benthic communities in Long Island Sound at regional and benthoscape scales

Long Island Sound is comprised of a rich and spatially heterogeneous mix of sea-floor environments which provide habitat for an equally diverse set of assemblages of soft-sediment communities. Information from recent research on the geomorphological and chemical attributes of these environments, as well as from studies of the hydrodynamics of the Sound, provide the opportunity to develop a landscape, or "benthoscape" framework for understanding the soft-sediment ecology of this estuary and for guiding future research focusing on structure and function at multiple spatial scales. This contribution reviews past research on benthic communities in Long Island Sound and addresses how they may be shaped by sea-floor characteristics at regional and benthoscape scales. At the regional scale (i.e. the entire Sound), differences in benthic community composition correspond to the distribution of general sedimentary environments. However, significant variation in community structure also occurs at the benthoscape scale (within regions) related to local variations in sediment properties, and physical and biogenic topographic features. Several topical areas in particular need further research in Long Island Sound, including temporal dynamics of benthic communities relative to sea-floor structure and the interaction between the dynamics of benthoscapes and hydrologic seascapes.

Connecticut, New York↗

Understanding behavioral responses of fish to pheromones in natural freshwater environments

There is an abundance of experimental studies and reviews that describe odorant-mediated behaviors of fish in laboratory microcosms, but research in natural field conditions has received considerably less attention. Fish pheromone studies in laboratory settings can be highly productive and allow for controlled experimental designs; however, laboratory tanks and flumes often cannot replicate all the physical, physiological and social contexts associated with natural environments. Field experiments can be a critical step in affirming and enhancing understanding of laboratory discoveries and often implicate the ecological significance of pheromones employed by fishes. When findings from laboratory experiments have been further tested in field environments, often different and sometimes contradictory conclusions are found. Examples include studies of sea lamprey (Petromyzon marinus) mating pheromones and fish alarm substances. Here, we review field research conducted on fish pheromones and alarm substances, highlighting the following topics: (1) contradictory results obtained in laboratory and field experiments, (2) how environmental context and physiological status influences behavior, (3) challenges and constraints of aquatic field research and (4) innovative techniques and experimental designs that advance understanding of fish chemical ecology through field research.

Journal of Comparative Physiology A↗

Hydrogeologic data and water-quality data from a thick unsaturated zone at a proposed wastewater-treatment facility site, Yucca Valley, San Bernardino County, California, 2008-11

The Hi-Desert Water District, in the community of Yucca Valley, California, is considering constructing a wastewater-treatment facility and using the reclaimed water to recharge the aquifer system through surface spreading. The Hi-Desert Water District is concerned with possible effects of this recharge on water quality in the underlying groundwater system; therefore, an unsaturated-zone monitoring site was constructed by the U.S. Geological Survey (USGS) to characterize the unsaturated zone, monitor a pilot-scale recharge test, and, ultimately, to monitor the flow of reclaimed water to the water table once the treatment facility is constructed. In June and July 2008, a borehole (YVUZ-5) was drilled by the USGS through the unsaturated zone in the vicinity of the proposed wastewater-treatment facility site by using an overburden drilling method. In addition to a variety of unsaturated-zone instrumentation, an observation well screened near the water table was installed in the borehole. The drilling procedures, lithologic and geophysical data, construction details, physical properties of unsaturated alluvial deposits, and instrumentation installed in YVUZ-5 are described in this report. Core material was analyzed for bulk-density, porosity, effective porosity, volumetric water content, residual water content, saturation, effective saturation, matric-potential, and saturated hydraulic conductivity. Concentrations of soluble anions, including bromide, chloride, fluoride, sulfate, nitrate, nitrite, phosphate, and orthophosphate, in unsaturated-zone sediment and dissolved in unsaturated-zone water were determined by analyzing water extracted from drill-cutting material. A 0.1-acre pilot-scale infiltration pond was constructed in the vicinity of YVUZ-5. Water was applied to the pond over a period of about 8 months and allowed to infiltrate into the underlying unsaturated zone. Data were collected on chemical and isotopic composition of the groundwater, unsaturated-zone water, and infiltration pond water before, during, and after infiltration of water from the constructed pond. Selected drill cuttings and core samples collected during drilling were analyzed for the presence or absence of denitrifying and nitrate-reducing bacteria. Water levels in the observation well ranged from about 367 to 370 feet below land surface during the period of the study. Measured saturated hydraulic conductivity of core material ranged from 2.1 to 11.0 feet per day. Average vertical infiltration rates in the pilot-scale infiltration pond ranged from 0.7 to 2.4 feet per day. Both denitrifying and nitrate-reducing bacteria were present in drill cutting material in most probable numbers ranging from below detection limits to 2,400,000 for denitrifying and to 93,000 for nitrate-reducing bacteria.

California↗

The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska

On June 6–8, 1912, ∼ 15 km 3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ∼ 20 km 3 of air-fall tephra and 11–15 km 3 of ash-flow tuff within ∼ 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km 2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91–98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to < 2%. The later, rhyolite-poor flows were hotter, less mobile, and widely produced partially welded tuff and vapor-indurated sillar. The main ash flow was too deflated and sluggish 16 km from the vent to surmount a 25-m-high moraine in its path but was diverted around it and continued 5 km down-valley, engulfing and charring trees but not toppling all of them. Thin ash-flow veneers feather 30–40 m up the enclosing valley walls but only where a constriction in the central VTTS locally raised the flow level. In the upper VTTS, the “high sand mark” is not a veneer but a marginal bench formed in thick tuff by differential compaction. Flooding from adjacent glaciers led to phreatic explosions that ejected blocks of tuff more welded than any yet exposed. A cluster of phreatic craters dammed a lake atop the tuff, the breaching of which caused a flood that scoured the ash-flow surface in the central VTTS, transported 50-cm blocks of welded tuff > 20 km to the lowermost VTTS, and deposited 1–8 m of debris there. Rhyolitic ejecta contain only 1–2% phenocrysts but andesite and dacite have 30–45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the andesite. The zoning ranges of phenocrysts in the rhyolitic and intermediate ejecta do not overlap. New chemical data show the bulk SiO 2 range to be: rhyolite 77 ± 0.6, dacite 66-64.5, and andesite 61.5–58.5%. The dacitic and andesitic ejecta contrast in color and density, and it is not certain whether they form a compositional continuum. Analyses reported by Fenner within the 66–76% SiO 2 range were of banded pumice and lava and of bulk tephra that mechanically fractionated and mixed during flight. Despite the gap of 10% SiO 2 , Fe-Ti-oxide temperatures show a continuous range from rhyolite (805–850°C) through dacite (855–955°C) to andesite (955–990°C). Thermal continuity and isotopic and trace-element data suggest that all were derived from a single magmatic system, whether or not they were physically contiguous before eruption. If the rhyolitic liquid separated from dacitic magma, extraction was so efficient that no dacitic phenocrysts were retained and no bulk compositions in the range 66–76% SiO 2 were created; if it were a partial melt of roof rocks atop an intermediate magma body, then such rocks had no O- or Sr-isotopic contrast with the andesite-dacite magma and clearly did not include the Jurassic arkosic or granitic basement. The presence of Holocene domes of pre-1912 glassy dacite adjacent to the 1912 vent suggest that the 7 km 3 (or more) of high-silica rhyolitic magma (a composition rare in the Aleutian arc) was generated in less than a few thousand years. The 1912 vent is semi-encircled by several andesitic stratocones and is as close to Mageik, Trident, and Griggs volcanoes as it is to Mt. Katmai. The erupted magma probably occupied only shallow levels of an extensive system of injection and storage under a cluster of several stratovolcanoes. Although Quaternary basalt is not known to have erupted here, the intrusion of basaltic magma probably sustains the greater-VTTS magmatic system.

Alaska↗

Water quality of storm runoff and comparison of procedures for estimating storm-runoff loads, volume, event-mean concentrations, and the mean load for a storm for selected properties and constituents for Colorado Springs, southeastern Colorado, 1992

The U.S. Environmental Protection Agency requires that municipalities that have a population of 100,000 or greater obtain National Pollutant Discharge Elimination System permits to characterize the quality of their storm runoff. In 1992, the U.S. Geological Survey, in cooperation with the Colorado Springs City Engineering Division, began a study to characterize the water quality of storm runoff and to evaluate procedures for the estimation of storm-runoff loads, volume and event-mean concentrations for selected properties and constituents. Precipitation, streamflow, and water-quality data were collected during 1992 at five sites in Colorado Springs. Thirty-five samples were collected, seven at each of the five sites. At each site, three samples were collected for permitting purposes; two of the samples were collected during rainfall runoff, and one sample was collected during snowmelt runoff. Four additional samples were collected at each site to obtain a large enough sample size to estimate storm-runoff loads, volume, and event-mean concentrations for selected properties and constituents using linear-regression procedures developed using data from the Nationwide Urban Runoff Program (NURP). Storm-water samples were analyzed for as many as 186 properties and constituents. The constituents measured include total-recoverable metals, vola-tile-organic compounds, acid-base/neutral organic compounds, and pesticides. Storm runoff sampled had large concentrations of chemical oxygen demand and 5-day biochemical oxygen demand. Chemical oxygen demand ranged from 100 to 830 milligrams per liter, and 5.-day biochemical oxygen demand ranged from 14 to 260 milligrams per liter. Total-organic carbon concentrations ranged from 18 to 240 milligrams per liter. The total-recoverable metals lead and zinc had the largest concentrations of the total-recoverable metals analyzed. Concentrations of lead ranged from 23 to 350 micrograms per liter, and concentrations of zinc ranged from 110 to 1,400 micrograms per liter. The data for 30 storms representing rainfall runoff from 5 drainage basins were used to develop single-storm local-regression models. The response variables, storm-runoff loads, volume, and event-mean concentrations were modeled using explanatory variables for climatic, physical, and land-use characteristics. The r2 for models that use ordinary least-squares regression ranged from 0.57 to 0.86 for storm-runoff loads and volume and from 0.25 to 0.63 for storm-runoff event-mean concentrations. Except for cadmium, standard errors of estimate ranged from 43 to 115 percent for storm- runoff loads and volume and from 35 to 66 percent for storm-runoff event-mean concentrations. Eleven of the 30 concentrations collected during rainfall runoff for total-recoverable cadmium were censored (less than) concentrations. Ordinary least-squares regression should not be used with censored data; however, censored data can be included with uncensored data using tobit regression. Standard errors of estimate for storm-runoff load and event-mean concentration for total-recoverable cadmium, computed using tobit regression, are 247 and 171 percent. Estimates from single-storm regional-regression models, developed from the Nationwide Urban Runoff Program data base, were compared with observed storm-runoff loads, volume, and event-mean concentrations determined from samples collected in the study area. Single-storm regional-regression models tended to overestimate storm-runoff loads, volume, and event-mean con-centrations. Therefore, single-storm local- and regional-regression models were combined using model-adjustment procedures to take advantage of the strengths of both models while minimizing the deficiencies of each model. Procedures were used to develop single-stormregression equations that were adjusted using local data and estimates from single-storm regional-regression equations. Single-storm regression models developed using model- adjustment proce

Colorado↗

Relations between continuous real-time physical properties and discrete water-quality constituents in the Little Arkansas River, south-central Kansas, 1998-2014

Water from the Little Arkansas River is used as source water for artificial recharge of the Equus Beds aquifer, one of the primary water-supply sources for the city of Wichita, Kansas. The U.S. Geological Survey has operated two continuous real-time water-quality monitoring stations since 1995 on the Little Arkansas River in Kansas. Regression models were developed to establish relations between discretely sampled constituent concentrations and continuously measured physical properties to compute concentrations of those constituents of interest. Site-specific regression models were originally published in 2000 for the near Halstead and near Sedgwick U.S. Geological Survey streamgaging stations and the site-specific regression models were then updated in 2003. This report updates those regression models using discrete and continuous data collected during May 1998 through August 2014. In addition to the constituents listed in the 2003 update, new regression models were developed for total organic carbon. The real-time computations of water-quality concentrations and loads are available at http://nrtwq.usgs.gov . The water-quality information in this report is important to the city of Wichita because water-quality information allows for real-time quantification and characterization of chemicals of concern (including chloride), in addition to nutrients, sediment, bacteria, and atrazine transported in the Little Arkansas River. The water-quality information in this report aids in the decision making for water treatment before artificial recharge.

Kansas↗

Water, water everywhere, but every drop unique: Emerging challenges in the science to understand the role of contaminants in management of drinking water supplies

The protection and management of water resources continues to be challenged by multiple and ongoing factors such as shifts in demographic, social, economic, and public health requirements. Physical limitations placed on access to potable supplies include natural and human-caused factors such as aquifer depletion, aging infrastructure, saltwater intrusion, floods, and drought. These factors, although varying in magnitude, spatial extent, and timing, can exacerbate the potential for contaminants of concern (CECs) to be present in sources of drinking water, infrastructure, premise plumbing and associated tap water. This monograph examines how current and emerging scientific efforts and technologies increase our understanding of the range of CECs and drinking water issues facing current and future populations. It is not intended to be read in one sitting, but is instead a starting point for scientists wanting to learn more about the issues surrounding CECs. This text discusses the topical evolution CECs over time (Section 1), improvements in measuring chemical and microbial CECs, through both analysis of concentration and toxicity (Section 2) and modeling CEC exposure and fate (Section 3), forms of treatment effective at removing chemical and microbial CECs (Section 4), and potential for human health impacts from exposure to CECs (Section 5). The paper concludes with how changes to water quantity, both scarcity and surpluses, could affect water quality (Section 6). Taken together, these sections document the past 25 years of CEC research and the regulatory response to these contaminants, the current work to identify and monitor CECs and mitigate exposure, and the challenges facing the future.

GeoHealth↗

Restoration of Rio Grande cutthroat trout Oncorhynchus clarkii virginalis to the Mescalero Apache Reservation

Rio Grande Cutthroat trout Oncorhynchus clarkii virginalis (RGCT) represents the most southern subspecies of cutthroat trout, endemic to Rio Grande, Canadian, and Pecos basins of New Mexico and southern Colorado. The subspecies currently occupies less than 12% of its historic range. The Mescalero Apache Tribe has partnered with U.S. Geological Survey-New Mexico Cooperative Fish and Wildlife Research Unit, New Mexico State University, U.S. Fish and Wildlife Service, and New Mexico Department of Game and Fish to meet mutually shared goals of restoring and maintaining a Pecos strain of RGCT to Tribal lands. The goal of this project was to assess the suitability of the Rio Ruidoso within the Mescalero Apache Reservation to support a self-sustaining RGCT population by conducting a systematic and comprehensive survey. We conducted three surveys (fall 2010, spring 2011 and 2012) to characterize water quality, macroinvertebrate assemblages, fish communities, and physical habitat (stream size, channel gradient, channel substrate, habitat complexity, riparian vegetation cover and structure, migration barriers to movement). Seven-100 m reaches throughout three major tributaries of the Rio Ruidoso within the Tribal lands were sampled during baseflow conditions October 2010, May 2011, and June 2012. Despite the onset of severe drought in 2011, water quality, physical habitat, and fish populations revealed that the Rio Ruidoso and its three tributaries would most likely support a self-sustaining RGCT population. Pools were abundant (mean, 8.9 pools/100 m), instream woody debris was present (range, 3.8-45.6 pieces/100 m), and instream dataloggers revealed daily maximum stream temperatures rarely exceeded criteria established in New Mexico for coldwater fishes, however, presence of frazil and anchor ice may limit fish distribution in the winter. Aquatic macroinvertebrate samples revealed a community of benthic invertebrates reflective of high quality cool to cold water. Overall densities of brown trout, rainbow trout and brook trout were high (overall mean, 0.23 fish/m2) and in relatively good condition (range of mean relative weight, 84-117). Should the Mescalero Apache Tribe decide to introduce RGCT, prior to chemical treatment, a barrier placed below the confluence of Middle and South forks of the Rio Ruidoso would create approximately 12 km of perennial flow and help protect against invasion of non-native fishes. The North Fork of the Rio Ruidoso is not a good candidate for reintroduction because of easy access by the public to reintroduce non-native fishes into the watershed. Lastly, an annual, long-term monitoring program of RGCT would help document that there was no subsequent incursion of non-native fishes.

Cooperator Science Series↗

Water-Quality and Biological Assessment of the Iowa River and Tributaries Within and Contiguous to the Meskwaki Settlement of the Sac and Fox Tribe of the Mississippi in Iowa, 2006-07

In cooperation with the Sac and Fox Tribe of the Mississippi in Iowa (Meskwaki Nation), the U.S. Geological Survey conducted a 2-year baseline assessment of the chemical and biological quality of streams within the Meskwaki Settlement in central Iowa. The Meskwaki Nation is a federally recognized tribe that wishes to establish water-quality standards to safeguard the integrity of surface waters and aquatic biota within the settlement for the health and welfare of the tribal community. The settlement is drained by the Iowa River and four tributaries (Onion, Cattail, Raven, and Bennett Creeks). Water-quality samples were collected at three sites on the Iowa River, two sites on Onion Creek, and one site each on Cattail, Raven, and Bennett Creeks from April 2006 through July 2007. Biological and habitat assessments were conducted at all three sites on the Iowa River and the downstream-most site on Onion Creek from June through August 2007. Analysis of physical properties, major ions, nutrients, trace compounds, bacteria, and total suspended solids in water, and trace metals and organic compounds in streambed sediment provided information about the effects of anthropogenic (human related) activities on the water quality of settlement streams. Analysis of biological samples collected during the summer of 2007, including fish community, benthic macroinvertebrates, and periphyton samples, as well as physical habitat characteristics, provided information on the effects of water quality on the condition of the aquatic environment. The majority of surface water sampled within the settlement was predominately a calcium bicarbonate type. Nitrates (nitrate plus nitrite as nitrogen) exceeded the U.S. Environmental Protection Agency's (USEPA) primary drinking-water Maximum Contaminant Level of 10 ug/L in 19 of 36 samples from sites on the Iowa River and Raven and Bennett Creeks but not in samples from Onion and Cattail Creeks. None of the samples analyzed for pesticides, trace metals, wastewater, or fuel contaminants were found to exceed drinking-water regulations for the USEPA or State of Iowa targeted constituents. Bacteria densities for Escherichia coli (E. coli) ranged from less than 10 to more than 600,000 colony-forming units per 100 milliliters of water and were largest following intense rainfall runoff. The largest densities were recorded in samples collected from the tributaries, most notably from Cattail Creek downstream from the tribal headquarters area and Onion Creek downstream from the sewage lagoons. Arsenic and nickel concentrations in bottom sediment from Onion Creek exceeded the USEPA threshold effects level in a composite sample collected during the habitat assessment in July 2007. Suspended-sediment concentration was estimated in terms of total suspended solids. Overall, Onion and Bennett Creeks were the least turbid, whereas the ephemeral Cattail Creek had the most turbid samples. Aquatic-community data were collected at four sites on the Meskwaki Settlement during the summer of 2007 to provide a baseline biological assessment of stream conditions. This assessment was based on sampling of the fish, benthic macroinvertebrate, and periphyton communities along with physical habitat characteristics. Individual biological metrics were derived from the data collected during the community surveys. These metrics were used to calculate Indexes of Biological Integrity (IBIs). The calculated values from the IBIs provided a numerical value that was used to provide an assessment of the biological condition at each biological sampling site. The fish community samples indicated that all of the sampling sites would be considered in fair condition, with one exception being a collection site on the Iowa River at Highway 49 near Tama, Iowa, which was classified in poor condition. The benthic macroinvertebrate IBI indicated a classification of good for three of the four biological sampling sites, with the Iowa River near Montour, Iowa,

Scientific Investigations Report↗

Statistical Approaches to Interpretation of Local, Regional, and National Highway-Runoff and Urban-Stormwater Data

Decision makers need viable methods for the interpretation of local, regional, and national-highway runoff and urban-stormwater data including flows, concentrations and loads of chemical constituents and sediment, potential effects on receiving waters, and the potential effectiveness of various best management practices (BMPs). Valid (useful for intended purposes), current, and technically defensible stormwater-runoff models are needed to interpret data collected in field studies, to support existing highway and urban-runoffplanning processes, to meet National Pollutant Discharge Elimination System (NPDES) requirements, and to provide methods for computation of Total Maximum Daily Loads (TMDLs) systematically and economically. Historically, conceptual, simulation, empirical, and statistical models of varying levels of detail, complexity, and uncertainty have been used to meet various data-quality objectives in the decision-making processes necessary for the planning, design, construction, and maintenance of highways and for other land-use applications. Water-quality simulation models attempt a detailed representation of the physical processes and mechanisms at a given site. Empirical and statistical regional water-quality assessment models provide a more general picture of water quality or changes in water quality over a region. All these modeling techniques share one common aspect-their predictive ability is poor without suitable site-specific data for calibration. To properly apply the correct model, one must understand the classification of variables, the unique characteristics of water-resources data, and the concept of population structure and analysis. Classifying variables being used to analyze data may determine which statistical methods are appropriate for data analysis. An understanding of the characteristics of water-resources data is necessary to evaluate the applicability of different statistical methods, to interpret the results of these techniques, and to use tools and techniques that account for the unique nature of water-resources data sets. Populations of data on stormwater-runoff quantity and quality are often best modeled as logarithmic transformations. Therefore, these factors need to be considered to form valid, current, and technically defensible stormwater-runoff models. Regression analysis is an accepted method for interpretation of water-resources data and for prediction of current or future conditions at sites that fit the input data model. Regression analysis is designed to provide an estimate of the average response of a system as it relates to variation in one or more known variables. To produce valid models, however, regression analysis should include visual analysis of scatterplots, an examination of the regression equation, evaluation of the method design assumptions, and regression diagnostics. A number of statistical techniques are described in the text and in the appendixes to provide information necessary to interpret data by use of appropriate methods. Uncertainty is an important part of any decisionmaking process. In order to deal with uncertainty problems, the analyst needs to know the severity of the statistical uncertainty of the methods used to predict water quality. Statistical models need to be based on information that is meaningful, representative, complete, precise, accurate, and comparable to be deemed valid, up to date, and technically supportable. To assess uncertainty in the analytical tools, the modeling methods, and the underlying data set, all of these components need be documented and communicated in an accessible format within project publications.

Open-File Report↗

Transport of sludge-derived organic pollutants to deep-sea sediments at deep water dump site 106

Linear alkylbenzenes (LABs), coprostanol and epi-coprostanol, were detected in sediment trap and bottom sediment samples at the Deep Water Dump Site 106 located 185 km off the coast of New Jersey, in water depths from 2400 to 2900 m. These findings clearly indicate that organic pollutants derived from dumped sludge are transported through the water column and have accumulated on the deep-sea floor. No significant difference in LABs isomeric composition was observed among sludge and samples, indicating little environmental biodegradation of these compounds. LABs and coprostanol have penetrated down to a depth of 6 cm in sediment, indicating the mixing of these compounds by biological and physical processes. Also, in artificially resuspended surface sediments, high concentrations of LABs and coprostanols were detected, implying that sewage-derived organic pollutants initially deposited on the deep-sea floor can be further dispersed by resuspension and transport processes. Small but significant amounts of coprostanol were detected in the sediment from a control site at which no LABs were detected. The coprostanol is probably derived from feces of marine mammals and sea birds and/or from microbial or geochemical transformations of cholesterol. Polcyclic aromatic hydrocarbons (PAHs) in sediment trap samples from the dump site were largely from the sewage sludge and had a mixed petroleum and pyrogenic composition. In contrast, PAHs in sediments in the dump site were mainly pyrogenic; contributed either from sewage sludge or from atmospheric transport to the overlying waters. & 1994 American Chemical Society.

Environmental Science & Technology↗

Wildlife, urban inputs, and landscape configuration are responsible for degraded swimming water quality at an embayed beach

Jeorse Park Beach, on southern Lake Michigan, experiences frequent closures due to high Escherichia coli ( E. coli ) levels since regular monitoring was implemented in 2005. During the summer of 2010, contaminant source tracking techniques, such as the conventional microbial and physical surveys and hydrodynamic models, were used to determine the reasons for poor water quality at Jeorse Park. Fecal indicator bacteria ( E. coli , enterococci) were high throughout the season, with densities ranging from 12&ndash;2419 (culturable E. coli ) and 1&ndash;2550 and < 1&ndash;5831 (culturable and qPCR enterococci, respectively). Genetic markers for human ( Bacteroides HF183) and gull ( Catellicoccus marimammalium ) fecal contamination were found in 15% and 37% of the samples indicating multiple sources contributing to poor water quality. Nesting colonies of double-crested cormorants ( Phalacrocorax auritus ) have steadily increased since 2005, coinciding with high E. coli levels. A hydrodynamic model indicated that limited circulation allows bacteria entering the embayed area to be retained in nearshore areas; and bacterial resuspension from sand and stranded beach wrack during storm events compounds the problem. The integration of hydrodynamics, expanded use of chemical and biological markers, as well as more complex statistical multivariate techniques can improve microbial source tracking, informing management actions to improve recreational water quality. Alterations to embayed structures to improve circulation and reduce nuisance algae as well as growing native plants to retain sand to improve beach morphometry are among some of the restoration strategies under consideration in ongoing multi-agency collaborations.

Indiana↗

Astrogeologic studies, semiannual progress report, February 26, 1961 to August 24, 1961

This report is the second semiannual report on a geological program of research conducted by the Geological Survey on behalf of the National Aeronautics and Space Administration. This research is being carried out under the Branch of Astrogeology. The long-range objectives of this program are to determine and map the stratigraphy and structure of the Moon's crust, to develop basic information on processes that have led to the present condition of the Moon's surface, and to work out the sequence of events in the geologic history recorded in the Moon's stratigraphy and structure. The work includes three closely interrelated areas of study: (1) investigation of the chemistry, petrography, and physical properties of extraterrestrial materials that may have been derived from the Moon, such as tektites, certain types of meteorites, and extraterrestrial dust; (2) experimental and field investigations of the mechanics and phenomena of impact of high-speed objects and of cratering; and (3) geologic mapping of the Moon. Immediate objectives for the fiscal year 1961 have included the preparation of geologic maps for the nominal target area for the Ranger Project of the National Aeronautics and Space Administration. Field and laboratory work on craters was directed toward developing data and an adequate theory for the integrated effect of meteoroid bombardment of the lunar surface. Special attention has been given to phase changes and solid state changes produced in rock by meteorite impact. American and Philippine tektites were the principal materials of possible lunar origin to receive detailed petrographic and chemical analysis.

Open-File Report↗

Mineralogy and petrology of the currant creek magnesite deposits and associated rocks of Nevada

Cryptocrystalline magnesite occurs as relatively small dense, white masses in a Tertiary volcanic tuff, here named the Currant tuff, in White Pine and Nye counties, 29 miles southwest of Ely, Nevada. The deposits are small, but some of the magnesite is of very high quality with almost no iron or aluminum. However, much of the magnesite is mixed with dolomite and calcite, and a serpentinelike mineral occurs in one of the deposits in sufficient abundance to be of possible use in ceramics. In scattered areas the tuff has been altered by solutions rich in magnesium and bicarbonic acid to dolomite, magnesite, magnesium silicate, and calcite. Mineral and chemical characteristics are the same throughout the entire rock assemblage of flows and tuffs, suggesting that all the rocks have been derived from the same parent magma. The tuff formation, which ranges in thickness from a few feet to over 400 feet, occurs between two groups of volcanic flows here referred to as the lower volcanics and the upper volcanics. The lower volcanics is composed mainly of flows of hypersthene dacite, but in the southwestern part of the area flows of a hypersthene andesite of balsaltic habit occur between the dacite and the overlying Currant tuff. The upper volcanics which overlie the Currant tuff consist of porphyritic quartz latite and an overlying massive latite crystal tuff. The Currant tuff containing the magnesite has both unmodified and reworked tuff members. The formation of hydrothermal dolomite, magnesite, and deweylite is discussed in detail, and the physical chemistry of solutions containing calcium, magnesium, and carbon dioxide is applied in an explanation of the origin of magnesium-rich solutions.

Nevada↗

Magnetic susceptibilities of minerals

Magnetic separation of minerals is a topic that is seldom reported in the literature for two reasons. First, separation data generally are byproducts of other projects; and second, this study requires a large amount of patience and is unusually tedious. Indeed, we suspect that most minerals probably are never investigated for this property. These data are timesaving for mineralogists who concentrate mono-mineralic fractions for chemical analysis, age dating, and for other purposes. The data can certainly be used in the ore-beneficiation industries. In some instances, magnetic-susceptibility data may help in mineral identification, where other information is insufficient. In past studies of magnetic separation of minerals, (Gaudin and Spedden, 1943; Tille and Kirkpatrick, 1956; Rosenblum, 1958; Rubinstein and others, 1958; Flinter, 1959; Hess, 1959; Baker, 1962; Meric and Peyre, 1963; Rojas and others, 1965; and Duchesne, 1966), the emphasis has been on the ferromagnetic and paramagnetic ranges of extraction. For readers interested in the history of magnetic separation of minerals, Krumbein and Pettijohn (1938, p. 344-346) indicated nine references back to 1848. The primary purpose of this paper is to report the magnetic-susceptibility data on as many minerals as possible, similar to tables of hardness, specific gravity, refractive indices, and other basic physical properties of minerals. A secondary purpose is to demonstrate that the total and best extraction ranges are influenced by the chemistry of the minerals. The following notes are offered to help avoid problems in separating a desired mineral concentrate from mixtures of mineral grains.

Open-File Report↗