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USGS2012

Sea-level history during the Last Interglacial complex on San Nicolas Island, California: implications for glacial isostatic adjustment processes, paleozoogeography and tectonics

San Nicolas Island, California has one of the best records of fossiliferous Quaternary marine terraces in North America, with at least fourteen terraces rising to an elevation of ~270 m above present-day sea level. In our studies of the lowest terraces, we identified platforms at 38-36 m (terrace 2a), 33-28 m (terrace 2b), and 13-8 m (terrace 1). Uranium-series dating of solitary corals from these terraces yields three clusters of ages: ~120 ka on terrace 2a (marine isotope stage [MIS] 5.5), ~120 and ~100 ka on terrace 2b (MIS 5.5 and 5.3), and ~80 ka (MIS 5.1) on terrace 1. We conclude that corals on terrace 2b that date to ~120 ka were reworked from a formerly broader terrace 2a during the ~100 ka sea stand. Fossil faunas differ on the three terraces. Isolated fragments of terrace 2a have a fauna similar to that of modern waters surrounding San Nicolas Island. A mix of extralimital southern and extralimital northern species is found on terrace 2b, and extralimital northern species are on terrace 1. On terrace 2b, with its mixed faunas, extralimital southern species, indicating warmer than present waters, are interpreted to be from the ~120 ka high sea stand, reworked from terrace 2a. The extralimital northern species on terrace 2b, indicating cooler than present waters, are interpreted to be from the ~100 ka sea stand. The abundant extralimital northern species on terrace 1 indicate cooler than present waters at ~80 ka. Using the highest elevations of the ~120 ka platform of terrace 2a, and assuming a paleo-sea level of +6 m based on previous studies, San Nicolas Island has experienced late Quaternary uplift rates of ~0.25-0.27 m/ka. These uplift rates, along with shoreline angle elevations and ages of terrace 2b (~100 ka) and terrace 1 (~80 ka) yield relative (local) paleo-sea level elevations of +2 to +6 m for the ~100 ka sea stand and -11 to -12 m for the ~80 ka sea stand. These estimates are significantly higher than those reported for the ~100 ka and ~80 ka sea stands on New Guinea and Barbados. Numerical models of the glacial isostatic adjustment (GIA) process presented here demonstrate that these differences in the high stands are expected, given the variable geographic distances between the sites and the former Laurentide and Cordilleran ice sheets. Moreover, the numerical results show that the absolute and differential elevations of the observed high stands provide a potentially important constraint on ice volumes during this time interval and on Earth structure.

California↗

USGS2014

Coastal tectonics on the eastern margin of the Pacific Rim: Late Quaternary sea-level history and uplift rates, Channel Islands National Park, California, USA

The Pacific Rim is a region where tectonic processes play a significant role in coastal landscape evolution. Coastal California, on the eastern margin of the Pacific Rm, is very active tectonically and geomorphic expressions of this include uplifted marine terraces. There have been, however, conflicting estimates of the rate of late Quaternary uplift of marine terraces in coastal California, particularly for the orthern Channel Islands. In the present study, the terraces on San Miguel Island and Santa Rosa Island were mapped and new age estimates were generated using uranium-series dating of fossil corals and amino acid geochronology of fossil mollusks. Results indicate that the 2nd terrace on both islands is ~120 ka and the 1st terrace on Santa Rosa Island is ~80 ka. These ages correspond to two global high-sea stands of the Last Interglacial complex, marine isotope stages (MIS) 5.5 and 51, respectively. The age estimates indicate that San Miguel Island and Santa Rosa Island have been tectonically uplifted at rates of 0.12e0.20 m/ka in the late Quaternary, similar to uplift rates inferred from previous studies on neighboring San Cruz Island. The newly estimated uplift rates for the northern Channel Islands are, however, an order of magnitude lower than a recent study that generated uplift rates from an offshore terrace dating to the Last Glacial period. The differences between the estimated uplift rates in the present study and the offshore study are explained by the magnitude of glacial isostatic adjustment (GIA) effects that were not known at the time of the earlier study. Set in the larger context of northeastern Pacific Rim tectonics, Channel Islands uplift rates are higher than those coastal localities on the margin of the East Pacific Rise spreading center, but slightly lower than those of most localities adjacent to the Cascadia subduction zone. The uplift rates reported here for the northern Channel Islands are similar to those reported for most other localities where strike-slip tectonics are dominant, but lower than localities where restraining bends (such as the Big Bend of the San Andreas Fault) result in crustal shortening.

California↗

USGS2017

Late Quaternary uplift along the North America-Caribbean plate boundary: Evidence from the sea level record of Guantanamo Bay, Cuba

The tectonic setting of the North America-Caribbean plate boundary has been studied intensively, but some aspects are still poorly understood, particularly along the Oriente fault zone. Guantanamo Bay, southern Cuba, is considered to be on a coastline that is under a transpressive tectonic regime along this zone, and is hypothesized to have a low uplift rate. We tested this by studying emergent reef terrace deposits around the bay. Reef elevations in the protected, inner part of the bay are ∼11–12 m and outer-coast, wave-cut benches are as high as ∼14 m. Uranium-series analyses of corals yield ages ranging from ∼133 ka to ∼119 ka, correlating this reef to the peak of the last interglacial period, marine isotope stage (MIS) 5.5. Assuming a span of possible paleo-sea levels at the time of the last interglacial period yields long-term tectonic uplift rates of 0.02–0.11 m/ka, supporting the hypothesis that the tectonic uplift rate is low. Nevertheless, on the eastern and southern coasts of Cuba, east and west of Guantanamo Bay, there are flights of multiple marine terraces, at higher elevations, that could record a higher rate of uplift, implying that Guantanamo Bay may be anomalous. Southern Cuba is considered to have experienced a measurable but modest effect from glacial isostatic adjustment (GIA) processes. Thus, with a low uplift rate, Guantanamo Bay should show no evidence of emergent marine terraces dating to the ∼100 ka (MIS 5.3) or ∼80 ka (MIS 5.1) sea stands and results of the present study support this.

Guantanamo Bay↗

USGS2022

Hyperspectral remote sensing of white mica: A review of imaging and point-based spectrometer studies for mineral resources, with spectrometer design considerations

Over the past ~30 years, hyperspectral remote sensing of chemical variations in white mica have proven to be useful for ore deposit studies in a range of deposit types. To better understand mineral deposits and to guide spectrometer design, this contribution reviews relevant papers from the fields of remote sensing, spectroscopy, and geology that have utilized spectral changes caused by chemical variation in white micas. This contribution reviews spectral studies conducted at the following types of mineral deposits: base metal sulfide, epithermal, porphyry, sedimentary rock hosted gold deposits, orogenic gold, iron oxide copper gold, and unconformity-related uranium. The structure, chemical composition, and spectral features of white micas, in this contribution defined as muscovite, paragonite, celadonite, phengite, illite, and sericite, are given. Reviewed laboratory spectral studies determined that shifts in the position of the white mica 2200 nm combination feature of 1 nm correspond to a change in Al oct content of approximately ±1.05%. Many of the reviewed spectral studies indicated that a shift in the position of the white mica 2200 nm combination feature of 1 nm was geologically significant. A sensitivity analysis of spectrometer characteristics; bandpass, sampling interval, and channel position, is conducted using spectra of 19 white micas with deep absorption features to determine minimum characteristics required to accurately measure a shift in the position of the white mica 2200 nm combination feature. It was determined that a sampling interval < 16.3 nm and bandpass <17.5 nm are needed to achieve a root mean square error (RMSE) of 2 nm, whereas a sampling interval < 8.8 nm and bandpass <9.8 nm are needed to achieve a RMSE of 1 nm. For comparison, commonly used imaging spectrometers HyMap, AVIRIS-Classic, SpecTIR®'s AisaFENIX 1K, and HySpex tm SWIR 384 have 2.1, 1.2, 0.96, and 0.95 nm RMSE in determining the position of the 2200 nm white mica combination feature, respectively. An additional sensitivity analysis is conducted to determine the effect of signal to noise ratio (SNR) on the RMSE of the position of the white mica 2200 nm combination feature, using spectra of 18 white micas with deep absorption features. For a spectrometer with sampling interval and bandpass of 1 nm, we estimate that RMSEs of 1 and 1.5 nm are achievable with spectra having a minimum SNR of approximately 246 and 64, respectively. For a spectrometer with sampling interval and bandpass of 5 nm, we estimate that RMSEs of 1 and 1.5 nm are attainable with spectra having a minimum SNR of approximately 431 and 84, respectively. When using a spectrometer with a sampling interval 8.8 nm and a bandpass of 9.8 nm, a RMSE of 1 is only achievable with convolved, noiseless reference spectra. For the 8.8_9.8 nm spectrometer, spectra with SNR of 250 and 100 result in RMSE of 1.1 and 1.3, respectively. Therefore, fine spectral resolution characteristics achieve RMSEs better than 1 nm for high SNR spectra while spectrometers with coarse spectral resolution have larger RMSE, perform well with noisy data, and are useful for white mica studies if RMSE of 1.1 to 1.5 nm is acceptable.

Remote Sensing of Environment↗

USGS2012

Chemical mixtures in untreated water from public-supply wells in the U.S. — Occurrence, composition, and potential toxicity

Chemical mixtures are prevalent in groundwater used for public water supply, but little is known about their potential health effects. As part of a large-scale ambient groundwater study, we evaluated chemical mixtures across multiple chemical classes, and included more chemical contaminants than in previous studies of mixtures in public-supply wells. We (1) assessed the occurrence of chemical mixtures in untreated source-water samples from public-supply wells, (2) determined the composition of the most frequently occurring mixtures, and (3) characterized the potential toxicity of mixtures using a new screening approach. The U.S. Geological Survey collected one untreated water sample from each of 383 public wells distributed across 35 states, and analyzed the samples for as many as 91 chemical contaminants. Concentrations of mixture components were compared to individual human-health benchmarks; the potential toxicity of mixtures was characterized by addition of benchmark-normalized component concentrations. Most samples (84%) contained mixtures of two or more contaminants, each at concentrations greater than one-tenth of individual benchmarks. The chemical mixtures that most frequently occurred and had the greatest potential toxicity primarily were composed of trace elements (including arsenic, strontium, or uranium), radon, or nitrate. Herbicides, disinfection by-products, and solvents were the most common organic contaminants in mixtures. The sum of benchmark-normalized concentrations was greater than 1 for 58% of samples, suggesting that there could be potential for mixtures toxicity in more than half of the public-well samples. Our findings can be used to help set priorities for groundwater monitoring and suggest future research directions for drinking-water treatment studies and for toxicity assessments of chemical mixtures in water resources.

Science of the Total Environment↗

USGS2015

Impact of wastewater infrastructure upgrades on the urban water cycle: Reduction in halogenated reaction byproducts following conversion from chlorine gas to ultraviolet light disinfection

The municipal wastewater treatment facility (WWTF) infrastructure of the United States is being upgraded to expand capacity and improve treatment, which provides opportunities to assess the impact of full-scale operational changes on water quality. Many WWTFs disinfect their effluent prior to discharge using chlorine gas, which reacts with natural and synthetic organic matter to form halogenated disinfection byproducts (HDBPs). Because HDBPs are ubiquitous in chlorine-disinfected drinking water and have adverse human health implications, their concentrations are regulated in potable water supplies. Less is known about the formation and occurrence of HDBPs in disinfected WWTF effluents that are discharged to surface waters and become part of the de facto wastewater reuse cycle. This study investigated HDBPs in the urban water cycle from the stream source of the chlorinated municipal tap water that comprises the WWTF inflow, to the final WWTF effluent disinfection process before discharge back to the stream. The impact of conversion from chlorine-gas to low-pressure ultraviolet light (UV) disinfection at a full-scale (68,000 m 3 d −1 design flow) WWTF on HDBP concentrations in the final effluent was assessed, as was transport and attenuation in the receiving stream. Nutrients and trace elements (boron, copper, and uranium) were used to characterize the different urban source waters, and indicated that the pre-upgrade and post-upgrade water chemistry was similar and insensitive to the disinfection process. Chlorinated tap water during the pre-upgrade and post-upgrade samplings contained 11 (mean total concentration = 2.7 μg L −1 ; n=5) and 10 HDBPs (mean total concentration = 4.5 μg L −1 ), respectively. Under chlorine-gas disinfection conditions 13 HDBPs (mean total concentration = 1.4 μg L −1 ) were detected in the WWTF effluent, whereas under UV disinfection conditions, only one HDBP was detected. The chlorinated WWTF effluent had greater relative proportions of nitrogenous, brominated, and iodinated HDBPs than the chlorinated tap water. Conversion of the WWTF to UV disinfection reduced the loading of HDBPs to the receiving stream by >90%.

Science of the Total Environment↗

USGS2017

Aquatic concentrations of chemical analytes compared to ecotoxicity estimates

We describe screening level estimates of potential aquatic toxicity posed by 227 chemical analytes that were measured in 25 ambient water samples collected as part of a joint USGS/USEPA drinking water plant study. Measured concentrations were compared to biological effect concentration (EC) estimates, including USEPA aquatic life criteria, effective plasma concentrations of pharmaceuticals, published toxicity data summarized in the USEPA ECOTOX database, and chemical structure-based predictions. Potential dietary exposures were estimated using a generic 3-tiered food web accumulation scenario. For many analytes, few or no measured effect data were found, and for some analytes, reporting limits exceeded EC estimates, limiting the scope of conclusions. Results suggest occasional occurrence above ECs for copper, aluminum, strontium, lead, uranium, and nitrate. Sparse effect data for manganese, antimony, and vanadium suggest that these analytes may occur above ECs, but additional effect data would be desirable to corroborate EC estimates. These conclusions were not affected by bioaccumulation estimates. No organic analyte concentrations were found to exceed EC estimates, but ten analytes had concentrations in excess of 1/10th of their respective EC: triclocarban, norverapamil, progesterone, atrazine, metolachlor, triclosan, para-nonylphenol, ibuprofen, venlafaxine, and amitriptyline, suggesting more detailed characterization of these analytes.

Science of the Total Environment↗

USGS2020

Mixed organic and inorganic tapwater exposures and potential effects in greater Chicago area, USA

Safe drinking water at the point of use (tapwater, TW) is a public-health priority. TW exposures and potential human-health concerns of 540 organics and 35 inorganics were assessed in 45 Chicago area United States (US) homes in 2017. No US Environmental Protection Agency (EPA) enforceable Maximum Contaminant Level(s) (MCL) were exceeded in any residential or water treatment plant (WTP) pre-distribution TW sample. Ninety percent (90%) of organic analytes were not detected in treated TW, emphasizing the high quality of the Lake Michigan drinking-water source and the efficacy of the drinking-water treatment and monitoring. Sixteen (16) organics were detected in >25% of TW samples, with about 50 detected at least once. Low-level TW exposures to unregulated disinfection byproducts (DBP) of emerging concern, per/polyfluoroalkyl substances (PFAS), and three pesticides were ubiquitous. Common exceedances of non-enforceable EPA MCL Goal(s) (MCLG) of zero for arsenic [As], lead [Pb], uranium [U]), bromodichloromethane, and tribromomethane suggest potential human health concerns and emphasize the continuing need for improved understanding of cumulative effects of low-concentration mixtures on vulnerable sub-populations. Because DBP dominated TW organics, residential TW concentrations are potentially predictable with expanded pre-distribution DBP monitoring. However, several TW chemicals, notably Pb and several infrequently detected organic compounds, were not readily explained by pre distribution samples, illustrating the need for continued broad inorganic/organic TW characterization to support consumer assessment of acceptable risk and point-of-use treatment options.

Illinois↗

USGS2023

Juxtaposition of intensive agriculture, vulnerable aquifers, and mixed chemical/microbial exposures in private-well tapwater in northeast Iowa

In the United States and globally, contaminant exposure in unregulated private-well point-of-use tapwater (TW) is a recognized public-health data gap and an obstacle to both risk-management and homeowner decision making. To help address the lack of data on broad contaminant exposures in private-well TW from hydrologically-vulnerable (alluvial, karst) aquifers in agriculturally-intensive landscapes, samples were collected in 2018–2019 from 47 northeast Iowa farms and analyzed for 35 inorganics, 437 unique organics, 5 in vitro bioassays, and 11 microbial assays. Twenty-six inorganics and 51 organics, dominated by pesticides and related transformation products (35 herbicide-, 5 insecticide-, and 2 fungicide-related), were observed in TW. Heterotrophic bacteria detections were near ubiquitous (94 % of the samples), with detection of total coliform bacteria in 28 % of the samples and growth on at least one putative-pathogen selective media across all TW samples. Health-based hazard index screening levels were exceeded frequently in private-well TW and attributed primarily to inorganics (nitrate, uranium). Results support incorporation of residential treatment systems to protect against contaminant exposure and the need for increased monitoring of rural private-well homes. Continued assessment of unmonitored and unregulated private-supply TW is needed to model contaminant exposures and human-health risks.

Iowa↗

USGS2017

Late Quaternary sea-level history and the antiquity of mammoths ( Mammuthus exilis and Mammuthus columbi ), Channel Islands NationalPark, California, USA

Fossils of Columbian mammoths ( Mammuthus columbi ) and pygmy mammoths ( Mammuthus exilis ) have been reported from Channel Islands National Park, California. Most date to the last glacial period (Marine Isotope Stage [MIS] 2), but a tusk of M. exilis (or immature M. columbi ) was found in the lowest marine terrace of Santa Rosa Island. Uranium-series dating of corals yielded ages from 83.8 ± 0.6 ka to 78.6 ± 0.5 ka, correlating the terrace with MIS 5.1, a time of relatively high sea level. Mammoths likely immigrated to the islands by swimming during the glacial periods MIS 6 (~ 150 ka) or MIS 8 (~ 250 ka), when sea level was low and the island–mainland distance was minimal, as during MIS 2. Earliest mammoth immigration to the islands likely occurred late enough in the Quaternary that uplift of the islands and the mainland decreased the swimming distance to a range that could be accomplished by mammoths. Results challenge the hypothesis that climate change, vegetation change, and decreased land area from sea-level rise were the causes of mammoth extinction at the Pleistocene/Holocene boundary on the Channel Islands. Pre-MIS 2 mammoth populations would have experienced similar or even more dramatic changes at the MIS 6/5.5 transition.

California↗

USGS2002

U-Pb geochronology of zircon and polygenetic titanite from the Glastonbury Complex, Connecticut, USA: An integrated SEM, EMPA, TIMS, and SHRIMP study

U-Pb ages for zircon and titanite from a granodioritic gneiss in the Glastonbury Complex, Connecticut, have been determined using both isotope dilution thermal ionization mass spectrometry (TIMS) and the sensitive high resolution ion microprobe (SHRIMP). Zircons occur in three morphologic populations: (1) equant to stubby, multifaceted, colorless, (2) prismatic, dark brown, with numerous cracks, and (3) elongate, prismatic, light tan to colorless. Cathodoluminescence (CL) imaging of the three populations shows simple concentric oscillatory zoning. The zircon TIMS age [weighted average of 207Pb/206Pb ages from Group 3 grains-450.5 ?? 1.6 Ma (MSWD=1.11)] and SHRIMP age [composite of 206Pb/238 U age data from all three groups-448.2 ?? 2.7 Ma (MSWD = 1.3)], are interpreted to suggest a relatively simple crystallization history. Titanite from the granodioritic gneiss occurs as both brown and colorless varieties. Scanning electron microscope backscatter (BSE) images of brown grains show multiple cross-cutting oscillatory zones of variable brightness and dark overgrowths. Colorless grains are unzoned or contain subtle wispy or very faint oscillatory zoning. Electron microprobe analysis (EMPA) clearly distinguishes the two populations. Brown grains contain relatively high concentrations of Fe2O3, Ce2O3 (up to ~ 1.5 wt.%), Nb2O5, and Zr. Cerium concentration is positively correlated with total REE + Y concentration, which together can exceed 3.5 wt.%. Oscillatory zoning in brown titanite is correlated with variations in REE concentrations. In contrast, colorless titanite (both as discrete grains and overgrowths on brown titanite) contains lower concentrations of Y, REE, Fe2O3, and Zr, but somewhat higher Al2O3 and Nb2O5. Uranium concentrations and Th/U discriminate between brown grains (typically 200-400 ppm U; all analyses but one have Th/U between about 0.8 and 2) and colorless grains (10-60 ppm U; Th/U of 0-0.17). In contrast to the zircon U-Pb age results, SHRIMP U-Pb data from titanite indicate multiple growth episodes. In brown grains, oscillatory zoned cores formed at 443 ?? 6 Ma, whereas white (in BSE) cross-cutting zones are 425 ?? 9 Ma. Colorless grains and overgrowths on brown grains yield an age of 265 ?? 8 Ma (using the Total Pb method) or 265 ?? 5 Ma (using the weighted average of the 206Pb/238U ages). However, EMPA chemical data identify zoning that suggests that this colorless titanite may preserve three growth events. Oscillatory zoned portions of brown titanite grains are igneous in origin; white cross-cutting zones probably formed during a previously unrecognized event that caused partial dissolution of earlier titanite and reprecipitation of a slightly younger generation of brown titanite. Colorless titanite replaced and grew over the magmatic titanite during the Permian Alleghanian orogeny. These isotopic data indicate that titanite, like zircon, can contain multiple age components. Coupling SHRIMP microanalysis with EMPA and SEM results on dated zones as presented in this study is an efficient and effective technique to extract additional chronologic ?? 2002 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

USGS1998

Comparison of two stable hydrogen isotope-ratio measurement techniques on Antarctic surface-water and ice samples

A comparison of the new hydrogen isotope-ratio technique of Vaughn et al. ([Vaughn, B.H., White, J.W.C., Delmotte, M., Trolier, M., Cattani, O., Stievenard, M., 1998. An automated system for hydrogen isotope analysis of water. Chem. Geol. (Isot. Geosci. Sect.), 152, 309-319]; the article immediately preceding this article) for the analysis of water samples utilizing automated on-line reduction by elemental uranium showed that 94% of 165 samples of Antarctic snow, ice, and stream water agreed with the ??2H values determined by H2-H2O platinum equilibration, exhibiting a bias of +0.5??? and a 2 - ?? variation of 1.9???. The isotopic results of 10 reduction technique samples, however, gave ??2H values that differed by 3.5??? or more, and were too negative by as much as 5.4??? and too positive by as much as 4.9??? with respect to those determined using the platinum equilibration technique.

Chemical Geology↗

USGS2000

Characterization of U(VI)-carbonato ternary complexes on hematite: EXAFS and electrophoretic mobility measurements

We have measured U(VI) adsorption on hematite using EXAFS spectroscopy and electrophoresis under conditions relevant to surface waters and aquifers (0.01 to 10 μM dissolved uranium concentrations, in equilibrium with air, pH 4.5 to 8.5). Both techniques suggest the existence of anionic U(VI)-carbonato ternary complexes. Fits to EXAFS spectra indicate that U(VI) is simultaneously coordinated to surface FeO 6 octahedra and carbonate (or bicarbonate) ligands in bidentate fashions, leading to the conclusion that the ternary complexes have an inner-sphere metal bridging (hematite-U(VI)-carbonato) structure. Greater than or equal to 50% of adsorbed U(VI) was comprised of monomeric hematite-U(VI)-carbonato ternary complexes, even at pH 4.5. Multimeric U(VI) species were observed at pH ≥ 6.5 and aqueous U(VI) concentrations approximately an order of magnitude more dilute than the solubility of crystalline β-UO 2 (OH) 2 . Based on structural constraints, these complexes were interpreted as dimeric hematite-U(VI)-carbonato ternary complexes. These results suggest that Fe-oxide-U(VI)-carbonato complexes are likely to be important transport-limiting species in oxic aquifers throughout a wide range of pH values.

Geochimica et Cosmochimica Acta↗

USGS2000

206Pb-230Th-234U-238U and 207Pb-235U geochronology of Quaternary opal, Yucca Mountain, Nevada

U–Th–Pb isotopic systems have been studied in submillimeter-thick outermost layers of Quaternary opal occurring in calcite–silica fracture and cavity coatings within Tertiary tuffs at Yucca Mountain, Nevada, USA. These coatings preserve a record of paleohydrologic conditions at this site, which is being evaluated as a potential high-level nuclear waste repository. The opal precipitated from groundwater is variably enriched in 234 U (measured 234 U/ 238 U activity ratio 1.124–6.179) and has high U (30–313 ppm), low Th (0.008–3.7 ppm), and low common Pb concentrations (measured 206 Pb/ 204 Pb up to 11,370). It has been demonstrated that the laboratory acid treatment used in this study to clean sample surfaces and to remove adherent calcite, did not disturb U–Th–Pb isotopic systems in opal. The opal ages calculated from 206 Pb∗/ 238 U and 207 Pb∗/ 235 U ratios display strong reverse discordance because of excess radiogenic 206 Pb∗ derived from the elevated initial 234 U. The data are best interpreted using projections of a new four-dimensional concordia diagram defined by 206 Pb∗/ 238 U, 207 Pb∗/ 235 U, 234 U/ 238 U activity , and 230 Th/ 238 U activity . Ages and initial 234 U/ 238 U activity ratios have been calculated using different projections of this diagram and tested for concordance. The data are discordant, that is observed 207 Pb∗/ 235 U ages of 170 ± 32 (2σ) to 1772 ± 40 ka are systematically older than 230 Th/U ages of 34.1 ± 0.6 to 452 ± 32 ka. The age discordance is not a result of migration of uranium and its decay products under the open system conditions, but a consequence of noninstantaneous growth of opal. Combined U–Pb and 230 Th/U ages support the model of slow mineral deposition at the rates of millimeters per million years resulting in layering on a scale too fine for mechanical sampling. In this case, U–Pb ages provide more accurate estimates of the average age for mixed multiage samples than 230 Th/U ages, because ages based on shorter-lived isotopes are nonlinearly biased by younger mineral additions. Use of the combined U–Th–Pb technique to date Yucca Mountain Quaternary opals significantly extends the age range beyond that of the 230 Th/U dating method and shows that selected fracture pathways in the unsaturated zone felsic tuffs of Yucca Mountain have been active throughout the Quaternary.

Geochimica et Cosmochimica Acta↗

USGS1997

Mapping the radon potential of the united states: Examples from the Appalachians

The geologic radon potential of the United States was recently assessed by the U.S. Geological Survey. Results indicate that approximately 33% of the U.S. population lives within geologic provinces where the average indoor radon levels have the potential to be greater than 4 pCi/L (147 Bq/m3). Rock types most commonly associated with high indoor radon include: 1) Uraniferous metamorphosed sediments, volcanics, and granite intrusives, especially those that are highly deformed or sheared. 2) Glacial deposits derived from uranium-bearing rocks and sediments. 3) Carboniferous, black shales. 4) Soils derived from carbonate rock, especially in karstic terrain. 5) Uraniferous fluvial, deltaic, marine, and lacustrine deposits. Different geologic terrains of the eastern United States illustrate some of the problems inherent in correlating indoor radon with geology. The Central and Southern Appalachian Highlands of the eastern United States have not been glaciated and most soils there are saprolitic, derived directly from the underlying bedrock. Regression analyses of bedrock geologic and radon parameters yield positive correlations (R > 0.5 to 0.9) and indicate that bedrock geology can account for a significant portion of the indoor radon variation. In glaciated areas of the United States such as the northern Appalachian Highlands and Appalachian Plateau, the correlation of bedrock geology to indoor radon is obscured or is positive only in certain cases. In these glaciated areas of the country, it is the type, composition, thickness, and permeability of glacial deposits, rather than the bedrock geology, that controls the radon source.

Conference Paper↗

USGS2002

U-Pb ages of secondary silica at Yucca Mountain, Nevada: Implications for the paleohydrology of the unsaturated zone

Uranium, Th and Pb isotopes were analyzed in layers of opal and chalcedony from individual mm- to cm-thick calcite and silica coatings at Yucca Mountain, Nevada, USA, a site that is being evaluated for a potential high-level nuclear waste repository. These calcite and silica coatings on fractures and in lithophysal cavities in Miocene-age tuffs in the unsaturated zone (UZ) precipitated from descending water and record a long history of percolation through the UZ. Opal and chalcedony have high concentrations of U (10 to 780 ppm) and low concentrations of common Pb as indicated by large values of 206Pb/204Pb (up to 53,806), thus making them suitable for U-Pb age determinations. Interpretations of U-Pb isotope systems in opal samples at Yucca Mountain are complicated by the incorporation of excess 234U at the time of mineral formation, resulting in reverse discordance of U-Pb ages. However, the 207PB/235U ages are much less affected by deviation from initial secular equilibrium and provide reliable ages of most silica deposits between 0.6 and 9.8 Ma. For chalcedony subsamples showing normal age discordance, these ages may represent minimum times of deposition. Typically, 207Pb/235U ages are consistent with the microstratigraphy in the mineral coating samples, such that the youngest ages are for subsamples from outer layers, intermediate ages are from inner layers, and oldest ages are from innermost layers. 234U and 230Th in most silica layers deeper in the coatings are in secular equilibrium with 238U, which is consistent with their old age and closed system behavior during the past -0.5 Ma. The ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from lithophysal cavities in the welded part of the Topopah Spring Tuff yield slow long-term average growth rates of 1 to 5 mm/Ma. These data imply that the deeper parts of the UZ at Yucca Mountain maintained long-term hydrologic stability over the past 10 Ma. despite significant climate variations. U-Pb ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from fractures in the shallower part of the UZ (welded part of the overlying Tiva Canyon Tuff) indicate larger long-term average growth rates up to 23 mm/Ma and an absence of recently deposited materials (ages of outermost layers are 3-5 Ma.). These differences between the characteristics of the coatings for samples from the shallower and deeper parts of the UZ may indicate that the nonwelded tuffs (PTn), located between the welded parts of the Tiva Canyon and Topopah Spring Tuffs, play an important role in moderating UZ flow.

Applied Geochemistry↗

USGS1998

Factors controlling As and U in shallow ground water, southern Carson Desert, Nevada

Unusually high As and U concentrations (> 100 ??g/L) are widespread in shallow ground water beneath the southern Carson Desert. The high concentrations, which locally exceed 1000 ??g/L, are of concern from a human health standpoint because the shallow ground water is used for domestic supply. Possible affects on wildlife are also of concern because the ground water flows into shallow lakes and marshes within wildlife refuges. Arsenic and U concentrations in ground water of the southern Carson Desert appear to be affected by evaporative concentration, redox reactions, and adsorption. The relation of these elements with Cl suggest that most of the high concentrations can be attributed to evaporative concentration of Carson River water, the primary source of recharge. Some ground water contains higher As and U concentrations that cannot be explained by evaporative concentration alone. Oxidation-reduction reactions, involving metal oxides and sedimentary-organic matter, appear to contribute As, U, inorganic C, Fe and Mn to the ground water. Arsenic in Fe-oxide was confirmed by chemical extraction and is consistent with laboratory adsorption studies. Uranium in both sedimentary-organic C and Fe-oxide coatings has been confirmed by fission tracks and petrographic examination. Arsenic concentrations in the ground water and chemical extracts of aquifer sediments are broadly consistent with adsorption as a control on some dissolved As concentrations. An apparent loss of As from some ground water as evaporative concentration proceeds is consistent with adsorption as a control on As. However, evidence for adsorption should be viewed with caution, because the adsorption model used values for the adsorbent that have not been shown to be valid for the aquifer sediments throughout the southern Carson Desert. Hydrologic and geochemical conditions in the Carson Desert are similar to other areas with high As and U concentrations in ground water, including the Salton Sea basin and southern San Joaquin Valley of California. Hydrologic and geochemical conditions that produced some sandstone-tyPe U-ore deposits, including those in the non-marine, closed-basin sediments of the Morrison Formation near Grants, New Mexico, suggest that the Carson Desert may be a modern analog for those systems.

Applied Geochemistry↗

USGS2017

Taphonomic problems in reconstructing sea-level history from the late Quaternary marine terraces of Barbados

Although uranium series (U-series) ages of growth-position fossil corals are important to Quaternary sea-level history, coral clast reworking from storms can yield ages on a terrace dating to more than one high-sea stand, confounding interpretations of sea-level history. On northern Barbados, U-series ages corals from a thick storm deposit are not always younger with successively higher stratigraphic positions, but all date to the last interglacial period (~127 ka to ~112 ka), Marine Isotope Substage (MIS) 5.5. The storm deposit ages are consistent with the ages of growth-position corals found at the base of the section and at landward localities on this terrace. Thus, in this case, analysis of only a few corals would not have led to an error in interpreting sea-level history. In contrast, a notch cut into older Pleistocene limestone below the MIS 5.5 terrace contains corals that date to both MIS 5.5 (~125 ka) and MIS 5.3 (~108 ka). We infer that the notch formed during MIS 5.3 and the MIS 5.5 corals are reworked. Similar multiple ages of corals on terraces have been reported elsewhere on Barbados. Thus, care must be taken in interpreting U-series ages of corals that are reported without consideration of taphonomy.

Quaternary Research↗