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At least 1,657 records · Page 92Linked to original sources

High-resolution seismic-reflection profiling data from the inner continental shelf of southeastern Massachusetts

Six hundred-seventy kilometers of closely spaced high-resolution seismic-­reflection data have been collected from eastern Rhode Island Sound and Vineyard Sound, Mass, by the U.S. Geological Survey in cooperation with the Massachusetts Department of Public Works. These data were obtained during the June 1975 cruise of the R/V ASTERIAS as part of a continuing regional study of the Massachusetts offshore area to assess potential mineral resources, to evaluate environmental impact of mining of resources and of offshore disposal of solid waste and harbor dredge-spoil materials, and to map the offshore geology and shallow structure. The data were obtained by using a surface-towed EG&G Unit Pulse Boomer* (300 joules: 400 Hz-8kHz frequency) sound source. Reflected acoustic energy was detected by a 4.6-m, a-element hydrophone array, was amplified, was actively filtered (400 Hz-4kHz bandpass), and was graphically displayed on an EPC* dry paper recorder at a 0.25-second sweep rate. System resolution was generally 1 to 1.5 m. Navigational control was provided by Loran C (posi­tional accuracy within 0.2 km) and was supplemented by radar and visual fixes. Positional information was logged at 15-minute intervals and at major course changes. The original records may be examined at the Data Library, U.S. Geological Survey, Woods Hole, MA 02543. Microfilm copies of the data are available for purchase from the National Geophysical and Solar-Terrestrial Data Center (NGSDC), Boulder, CO 80302.

Open-File Report↗

Development of a high-resolution binational vegetation map of the Santa Cruz River riparian corridor and surrounding watershed, southern Arizona and northern Sonora, Mexico

This report summarizes the development of a binational vegetation map developed for the Santa Cruz Watershed, which straddles the southern border of Arizona and the northern border of Sonora, Mexico. The map was created as an environmental input to the Santa Cruz Watershed Ecosystem Portfolio Model (SCWEPM) that is being created by the U.S. Geological Survey for the watershed. The SCWEPM is a map-based multicriteria evaluation tool that allows stakeholders to explore tradeoffs between valued ecosystem services at multiple scales within a participatory decision-making process. Maps related to vegetation type and are needed for use in modeling wildlife habitat and other ecosystem services. Although detailed vegetation maps existed for the U.S. side of the border, there was a lack of consistent data for the Santa Cruz Watershed in Mexico. We produced a binational vegetation classification of the Santa Cruz River riparian habitat and watershed vegetation based on NatureServe Terrestrial Ecological Systems (TES) units using Classification And Regression Tree (CART) modeling. Environmental layers used as predictor data were derived from a seasonal set of Landsat Thematic Mapper (TM) images (spring, summer, and fall) and from a 30-meter digital-elevation-model (DEM) grid. Because both sources of environmental data are seamless across the international border, they are particularly suited to this binational modeling effort. Training data were compiled from existing field data for the riparian corridor and data collected by the NM-GAP (New Mexico Gap Analysis Project) team for the original Southwest Regional Gap Analysis Project (SWReGAP) modeling effort. Additional training data were collected from core areas of the SWReGAP classification itself, allowing the extrapolation of the SWReGAP mapping into the Mexican portion of the watershed without collecting additional training data.

Arizona↗

Land cover mapping of the upper Kuskokwim Resource Managment Area using LANDSAT and a digital data base approach

Digital land cover and terrain data for the Upper Kuskokwim Resource Hanagement Area (UKRMA) were produced by the U.S. Geological Survey, Earth Resources Observation Systems Field Office, Anchorage, Alaska for the Bureau of Land Management. These and other environmental data, were incorporated into a digital data base to assist in the management and planning of the UKRMA. The digital data base includes land cover classifications, elevation, slope, and aspect data centering on the UKRMA boundaries. The data are stored on computer compatible tapes at a 50-m pixel size. Additional digital data in the data base include: (a) summer and winter Landsat multispectral scanner (MSS) data registered to a 50-m Universal Transverse Mercator grid; (b) elevation, slope, aspect, and solar illumination data; (c) soils and surficial geology; and (e) study area boundary. The classification of Landsat MSS data resulted in seven major classes and 24 subclasses. Major classes include: forest, shrubland, dwarf scrub, herbaceous, barren, water, and other. The final data base will be used by resource personnel for management and planning within the UKRMA.

Alaska↗

The U.S. Geological Survey Flagstaff Science Campus—Providing expertise on planetary science, ecology, water resources, geologic processes, and human interactions with the Earth

T he U.S. Geological Survey’s Flagstaff Science Campus is focused on interdisciplinary study of the Earth and solar system, and has the scientific expertise to detect early environmental changes and provide strategies to minimize possible adverse effects on humanity. The Flagstaff Science Campus (FSC) is located in Flagstaff, Arizona, which is situated in the northern part of the State, home to a wide variety of landscapes and natural resources, including (1) young volcanoes in the San Francisco Volcanic Field, (2) the seven ecological life zones of the San Francisco Peaks, (3) the extensive geologic record of the Colorado Plateau and Grand Canyon, (4) the Colorado River and its perennial, ephemeral, and intermittent tributaries, and (5) a multitude of canyons, mountains, arroyos, and plains. More than 200 scientists, technicians, and support staff provide research, monitoring, and technical advancements in planetary geology and mapping, biology and ecology, Earth-based geology, hydrology, and changing climate and landscapes. Scientists at the FSC work in collaboration with multiple State, Federal, Tribal, municipal, and academic partners to address regional, national, and global environmental issues, and provide scientific outreach to the general public.

Arizona↗

Steroidal hormones and other endocrine active compounds in shallow groundwater in nonagricultural areas of Minnesota—Study design, methods, and data, 2009–10

The U.S. Geological Survey, in cooperation with the Minnesota Pollution Control Agency, completed a study on the occurrence of steroidal hormones and other endocrine active compounds in shallow groundwater in nonagricultural areas of Minnesota during 2009–10. This report describes the study design and methods, and presents the data collected on steroidal hormones and other related compounds. Environmental and quality-control samples were collected from 40 wells as part of this study. Samples were analyzed by the U.S. Geological Survey National Water Quality Laboratory for 16 steroidal hormones and 4 other related compounds, of which all but 2 compounds are endocrine active compounds. Most of the water samples did not contain detectable concentrations of any of the 20 compounds analyzed. Water samples from three wells had detectable concentrations of one or more compounds. Bisphenol A was detected in samples from three wells, and trans-diethylstilbestrol was detected in one of the samples in which bisphenol A also was detected.

Minnesota↗

Puerto Rico: Marine sediments, terrestrial and seafloor imagery, and tectonic interpretations

Introduction: Puerto Rico is an island situated in the plate boundary zone between the Caribbean and the North American Plates. This is a geologically fascinating, tectonically active region, where the Caribbean Plate has over-ridden the North American Plate and is now sliding past it with strike-slip motion. The details of this tectonic interaction are poorly understood, largely because much of the region lies under water, making it difficult to study. The geologic setting of Puerto Rico has created or contributed to several pressing societal issues, related to human safety, environmental health, and economic development. Because the island lies on an active plate boundary, earthquakes are a constant threat and the densely populated coastal areas are vulnerable to tsunamis. Coastal erosion is a concern in many coastal areas, but is particularly serious to an island economy which relies heavily on a thriving tourist industry. In Puerto Rico, illegal mining of beach sands for use as aggregate has exacerbated coastal erosion and left coastal communities more exposed to the ravages of storms and tsunamis. The serious need for an affordable local source of aggregate to use in the growing construction industry on the island has created a strong interest in locating and evaluating offshore sand and gravel deposits. During the last 20 years the U.S. Geological Survey, often in cooperation with the Puerto Rico Department of Natural Resources and/or the University of Puerto Rico, has conducted a variety of projects to address the geologic aspects of these pressing societal issues. The papers and data presented here are the results of these projects. Some have been previously published elsewhere; others, such as the database of surficial sediments of the Puerto Rico insular shelf, interpretation of side-looking airborne radar imagery of the island, and the GIS data, are presented here for the first time. The purpose of this CD is to make the results of these diverse studies available in a readily accessible digital form, so that managers, planners, and other researchers can utilize the results.

Puerto Rico↗

Arctic National Wildlife Refuge, 1002 area, petroleum assessment, 1998, including economic analysis

The Alaska National Interest Lands Conservation Act (1980) established the Arctic National Wildlife Refuge (ANWR). In section 1002 of that act, Congress deferred a decision regarding future management of the 1.5-million-acre coastal plain ("1002 area") in recognition of the area’s potentially enormous oil and gas resources and its importance as wildlife habitat. A report on the resources (including petroleum) of the 1002 area was submitted in 1987 to Congress by the Department of the Interior (DOI). Since completion of that report, numerous wells have been drilled and oil fields discovered near ANWR, new geologic and geophysical data have become available, seismic processing and interpretation capabilities have improved, and the economics of North Slope oil development have changed significantly. The U.S. Geological Survey (USGS) commonly is asked to provide the Federal Government with timely scientific information in support of decisions regarding land management, environmental quality, and economic and strategic policy. To do so, the USGS must anticipate issues most likely to be the focus of policymakers in the future. Anticipating the need for scientific information and considering the decade-old perspective of the petroleum resource estimates included in the 1987 Report to Congress, the USGS has reexamined the geology of the ANWR 1002 area and has prepared a new petroleum resource assessment.

Fact Sheet↗

Chester County ground-water atlas, Chester County, Pennsylvania

Chester County encompasses 760 square miles in southeastern Pennsylvania. Groundwater-quality studies have been conducted in the county over several decades to address specific hydrologic issues. This report compiles and describes water-quality data collected during studies conducted mostly after 1990 and summarizes the data in a county-wide perspective. In this report, water-quality constituents are described in regard to what they are, why the constituents are important, and where constituent concentrations vary relative to geology or land use. Water-quality constituents are grouped into logical units to aid presentation: water-quality constituents measured in the field (pH, alkalinity, specific conductance, and dissolved oxygen), common ions, metals, radionuclides, bacteria, nutrients, pesticides, and volatile organic compounds. Water-quality constituents measured in the field, common ions (except chloride), metals, and radionuclides are discussed relative to geology. Bacteria, nutrients, pesticides, and volatile organic compounds are discussed relative to land use. If the U.S. Environmental Protection Agency (USEPA) or Chester County Health Department has drinking water standards for a constituent, the standards are included. Tables and maps are included to assist Chester County residents in understanding the water-quality constituents and their distribution in the county. Ground water in Chester County generally is of good quality and is mostly acidic except in the carbonate rocks and serpentinite, where it is neutral to strongly basic. Calcium carbonate and magnesium carbonate are major constituents of these rocks. Both compounds have high solubility, and, as such, both are major contributors to elevated pH, alkalinity, specific conductance, and the common ions. Elevated pH and alkalinity in carbonate rocks and serpentinite can indicate a potential for scaling in water heaters and household plumbing. Low pH and low alkalinity in the schist, quartzite, and gneiss rocks can indicate a potential for corrosive water. The only constituent measured in the field that has a USEPA Secondary Maximum Contaminant Level (SMCL) is pH. The SMCL for pH is 6.5-8.5; 64 percent of samples analyzed for pH were acidic (below pH 6.5). Only 1 percent of samples were basic (above pH 8.5). Of the common ions, the USEPA has SMCLs for chloride, sulfate, and total dissolved solids. The USEPA has a SMCL and a Primary Maximum Contaminant Level (PMCL) for fluoride. Chloride is more closely related to land use than geology. In Chester County, chloride exceeded the SMCL (250 mg/L) only in 5 percent of the services (commercial services, community services, and military) land-use areas. No samples analyzed for sulfate exceeded the SMCL (250 mg/L). Only 3 percent of samples analyzed for total dissolved solids exceeded the SMCL (500 milligrams per liter) (mg/L). No samples analyzed for fluoride equaled or exceeded the SMCL (2.0 mg/L) or PMCL (4.0 mg/L). Iron concentrations exceeded the USEPA SMCL in 11 percent of samples and were highest in schist (14 percent) and gneiss (13 percent). Manganese concentrations exceeded the SMCL in 19 percent of samples and were highest in quartzite and schist (both 28 percent). Lead and arsenic were present in low concentrations: the highest concentrations of lead occurred in water from quartzite (8 percent exceeded the USEPA Action Level), and arsenic was detected mostly in Triassic sedimentary rocks (9 percent exceeded the USEPA PMCL). The highest concentrations of copper occurred more frequently in quartzite rocks, and to a lesser extent were evenly distributed between ground water in gneiss, schist, and Triassic sedimentary rocks. Elevated concentrations of radon-222 and the combined radium-226/radium-228 radionuclides were common in water from quartzite and schist. Gross alpha and gross beta particle activities were elevated in water from quartzite and carbonate rocks. In contrast, elevated concentrations of uranium primarily were measured in water from Triassic sedimentary and carbonate rocks. Despite a sampling bias towards agricultural land use, only two samples indicated the presence of fecal coliforms. Samples analyzed for nutrients generally exhibited low concentrations, but about 11 percent of samples collected for nitrate exceeded the USEPA PMCL. Only one nitrite sample (less than 1 percent) exceeded the respective USEPA PMCL. Approximately 190 samples were collected for each of the three pesticides in this report: lindane, dieldrin, and diazinon. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Approximately 95 percent of samples for each pesticide were below minimum reporting levels (MRL). Only lindane has a USEPA PMCL, and only one sample exceeded the standard. Results for dieldrin and diazinon were similar, except results for two diazinon samples where concentrations were 57.0 and 490 micrograms per liter (μg/L). Volatile organic compounds in this report were analyzed in water from 198 samples. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Two percent of samples analyzed for trichloroethylene and less than 1 percent of samples analyzed for tetrachloroethylene exceeded their respective USEPA PMCLs (each 5.0 μg/L). No samples analyzed for 1,1,1-trichloroethane exceeded the USEPA PMCL (200 μg/L). No samples analyzed for methyl tert-butyl ether exceeded the USEPA Drinking Water Advisory (20μg/L).

Open-File Report↗

Benthic invertebrate assemblages and their relation to physical and chemical characteristics of streams in the Eastern Iowa Basins, 1996-98

Over 250 benthic invertebrate taxa were identified from snags and woody debris in streams and rivers of the Wapsipinicon, Cedar, Iowa, and Skunk River Basins in the Eastern Iowa Basins (EIWA) study unit of the U.S. Geological Survey National Water-Quality Assessment Program. The composition, distribution, and abundance of 74 predominant taxa were related to environmental conditions in the study unit, using habitat, hydrologic, and water-quality data. Four groups of sites were defined, based on the distribution and relative abundance of taxa. Detrended correspondence analysis was used to identify relations in the structure of the invertebrate assemblages, and the correspondence of taxa and sites in the groups was related to habitat, hydrologic, and water-quality information. Responses of invertebrate assemblages were explained by natural factors, such as surficial geology or physical habitat conditions, as well as human influences, such as agriculture or high-density hog-feeding operations. Mayflies, caddisflies, and true flies were well represented in streams and rivers of the EIWA study unit. The mayflies Tricorythodes and Baetis intercalaris , the net-spinning caddisflies Hydropsyche bidens and H. simulans, and the Chironomidae Glyptotendipes , Polypedilum , and Rheotanytarsus predominated. Spatial variation in benthic invertebrate assemblages within a site was less than that observed among sites. Assemblages from 3 years of sampling generally were grouped by site, with exceptions related to differences in discharge among years. The benthic invertebrate assemblages associated with the four groups of sites reflected the cumulative effects of agricultural and urban land use, sources of nutrient and organic enrichment, and longitudinal stream succession—the natural sequence of communities in streams from headwaters to large rivers. These factors, especially the natural changes from upstream to downstream, were influential in characterizing the benthic invertebrate assemblages of the site groups. Stream size, a reflection of basin area, was a principal influence in categorizing the benthic invertebrate assemblages, with sites that have the largest basin areas forming a separate group. Although it is difficult to distinguish among the contributions of large basin area, increased concentrations of nutrients and pesticides, and decreasing instream habitat diversity, the resulting invertebrate assemblage described was distinct. The remaining sites were headwater or tributary streams that reflected conditions more common to smaller streams, such as higher gradients and the potential for more diverse or extensive riparian habitat, but were distinguished by landform. Following basin area in importance, landform contributed to the differences observed among the benthic invertebrate communities at the remaining sites.

Iowa, Minnesota↗

Application of geologic map information to water quality issues in the southern part of the Chesapeake Bay watershed, Maryland and Virginia, eastern United States

Geologic map units contain much information about the mineralogy, chemistry, and physical attributes of the rocks mapped. This paper presents information from regional-scale geologic maps in Maryland and Virginia, which are in the southern part of the Chesapeake Bay watershed in the eastern United States. The geologic map information is discussed and analyzed in relation to water chemistry data from shallow wells and stream reaches in the area. Two environmental problems in the Chesapeake Bay watershed are used as test examples. The problems, high acidity and high nitrate concentrations in streams and rivers, tend to be mitigated by some rock and sediment types and not by others. Carbonate rocks (limestone, dolomite, and carbonate-cemented rocks) have the greatest capacity to neutralize acidic ground water and surface water in contact with them. Rocks and sediments having high carbon or sulfur contents (such as peat and black shale) potentially contribute the most toward denitrification of ground water and surface water in contact with them. Rocks and sediments that are composed mostly of quartz, feldspar, and light-colored clay (rocks such as granite and sandstone, sediments such as sand and gravel) tend not to alter the chemistry of waters that are in contact with them. The testing of relationships between regionally mapped geologic units and water chemistry is in a preliminary stage, and initial results are encouraging.Geologic map units contain much information about the mineralogy, chemistry, and physical attributes of the rocks mapped. This paper presents information from regional-scale geologic maps in Maryland and Virginia, which are in the southern part of the Chesapeake Bay watershed in the eastern United States. The geologic map information is discussed and analyzed in relation to water chemistry data from shallow wells and stream reaches in the area. Two environmental problems in the Chesapeake Bay watershed are used as test examples. The problems, high acidity and high nitrate concentrations in streams and rivers, tend to be mitigated by some rock and sediment types and not by others. Carbonate rocks (limestone, dolomite, and carbonate-cemented rocks) have the greatest capacity to neutralize acidic ground water and surface water in contact with them. Rocks and sediments having high carbon or sulfur contents (such as peat and black shale) potentially contribute the most toward denitrification of ground water and surface water in contact with them. Rocks and sediments that are composed mostly of quartz, feldspar, and light-colored clay (rocks such as granite and sandstone, sediments such as sand and gravel) tend not to alter the chemistry of waters that are in contact with them. The testing of relationships between regionally mapped geologic units and water chemistry is in a preliminary stage, and initial results are encouraging.

Journal of Geochemical Exploration↗

Environmental consequences of the Retsof Salt Mine roof collapse

In 1994, the largest salt mine in North America, which had been in operation for more than 100 years, catastrophically flooded when the mine ceiling collapsed. In addition to causing the loss of the mine and the mineral resources it provided, this event formed sinkholes, caused widespread subsidence to land, caused structures to crack and subside, and changed stream flow and erosion patterns. Subsequent flooding of the mine drained overlying aquifers, changed the groundwater salinity distribution (rendering domestic wells unusable), and allowed locally present natural gas to enter dwellings through water wells. Investigations including exploratory drilling, hydrologic and water-quality monitoring, geologic and geophysical studies, and numerical simulation of groundwater flow, salinity, and subsidence have been effective tools in understanding the environmental consequences of the mine collapse and informing decisions about management of those consequences for the future. Salt mines are generally dry, but are susceptible to leaks and can become flooded if groundwater from overlying aquifers or surface water finds a way downward into the mined cavity through hundreds of feet of rock. With its potential to flood the entire mine cavity, groundwater is a constant source of concern for mine operators. The problem is compounded by the viscous nature of salt and the fact that salt mines commonly lie beneath water-bearing aquifers. Salt (for example halite or potash) deforms and “creeps” into the mined openings over time spans that range from years to centuries. This movement of salt can destabilize the overlying rock layers and lead to their eventual sagging and collapse, creating permeable pathways for leakage of water and depressions or openings at land surface, such as sinkholes. Salt is also highly soluble in water; therefore, whenever water begins to flow into a salt mine, the channels through which it flows increase in diameter as the surrounding salt dissolves. Some mines leak at a slow rate for decades before a section of rock gives way, allowing what initially was a trickle of water to suddenly become a cascade and finally a torrent. Other mines become flooded and are destroyed when an errant drill hole punctures the mine ceiling, allowing water from overlying sources to flow into the mine. Either scenario can cause catastrophic flooding and permanent loss of the mine. Occasionally, a mine that has remained dry for a century will undergo a roof collapse that results in flooding.

New York↗

Geophysical investigations of well fields to characterize fractured-bedrock aquifers in southern New Hampshire

Bedrock-fracture zones near high-yield bedrock wells in southern New Hampshire well fields were located and characterized using seven surface and six borehole geophysical survey methods. Detailed surveys of six sites with various methods provide an opportunity to integrate and compare survey results. Borehole geophysical surveys were conducted at three of the sites to confirm subsurface features. Hydrogeologic settings, including a variety of bedrock and surface geologic materials, were sought to gain an insight into the usefulness of the methods in varied terrains. Results from 15 survey lines, 8 arrays, and 3 boreholes were processed and interpreted from the 6 sites. The surface geophysical methods used provided physical properties of fractured bedrock. Seismic refraction and ground-penetrating radar (GPR) primarily were used to characterize the overburden materials, but in a few cases indicated bedrock-fracture zones. Magnetometer surveys were used to obtain background information about the bedrock to compare with other results, and to search for magnetic lows, which may result from weathered fractured rock. Electromagnetic terrain conductivity surveys (EM) and very-low-frequency electromagnetic surveys (VLF) were used as rapid reconnaissance techniques with the primary purpose of identifying electrical anomalies, indicating potential fracture zones in bedrock. Direct-current (dc) resistivity methods were used to gather detailed subsurface information about fracture depth and orientation. Two-dimensional (2-D) dc-resistivity surveys using dipole-dipole and Schlumberger arrays located and characterized the overburden, bedrock, and bedrock-fracture zones through analysis of data inversions. Azimuthal square array dc-resistivity survey results indicated orientations of conductive steep-dipping bedrock-fracture zones that were located and characterized by previously applied geophysical methods. Various available data sets were used for site selection, characterizations, and interpretations. Lineament data, developed as a part of a statewide and regional scale investigation of the bedrock aquifer, were available to identify potential near-vertical fracture zones. Geophysical surveys indicated fracture zones coincident with lineaments at 4 of the sites. Geologic data collected as a part of the regional scale investigation provided outcrop fracture measurements, ductile fabric, and contact information. Dominant fracture trends correspond to the trends of geophysical anomalies at 4 of the sites. Water-well drillers? logs from water supply and environmental data sets also were used where available to characterize sites. Regional overburden information was compiled from stratified-drift aquifer maps and surficial-geological maps.

Water-Resources Investigations Report↗

Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes

A comparison study of selected static leaching and acid–base accounting (ABA) methods using a mineralogically diverse set of 12 modern-style, metal mine waste samples was undertaken to understand the relative performance of the various tests. To complement this study, in-depth mineralogical studies were conducted in order to elucidate the relationships between sample mineralogy, weathering features, and leachate and ABA characteristics. In part one of the study, splits of the samples were leached using six commonly used leaching tests including paste pH, the U.S. Geological Survey (USGS) Field Leach Test (FLT) (both 5-min and 18-h agitation), the U.S. Environmental Protection Agency (USEPA) Method 1312 SPLP (both leachate pH 4.2 and leachate pH 5.0), and the USEPA Method 1311 TCLP (leachate pH 4.9). Leachate geochemical trends were compared in order to assess differences, if any, produced by the various leaching procedures. Results showed that the FLT (5-min agitation) was just as effective as the 18-h leaching tests in revealing the leachate geochemical characteristics of the samples. Leaching results also showed that the TCLP leaching test produces inconsistent results when compared to results produced from the other leaching tests. In part two of the study, the ABA was determined on splits of the samples using both well-established traditional static testing methods and a relatively quick, simplified net acid–base accounting (NABA) procedure. Results showed that the traditional methods, while time consuming, provide the most in-depth data on both the acid generating, and acid neutralizing tendencies of the samples. However, the simplified NABA method provided a relatively fast, effective estimation of the net acid–base account of the samples. Overall, this study showed that while most of the well-established methods are useful and effective, the use of a simplified leaching test and the NABA acid–base accounting method provide investigators fast, quantitative tools that can be used to provide rapid, reliable information about the leachability of metals and other constituents of concern, and the acid-generating potential of metal mining waste.

Applied Geochemistry↗

A chemostratigraphic method to determine the end of impact-related sedimentation at marine-target impact craters (Chesapeake Bay, Lockne, Tvären)

To better understand the impact cratering process and its environmental consequences at the local to global scale, it is important to know when in the geological record of an impact crater the impact-related processes cease. In many instances, this occurs with the end of early crater modification, leaving an obvious sedimentological boundary between impactites and secular sediments. However, in marine-target craters the transition from early crater collapse (i.e., water resurge) to postimpact sedimentation can appear gradual. With the a priori assumption that the reworked target materials of the resurge deposits have a different chemical composition to the secular sediments we use chemostratigraphy (δ 13 C carb , %C org , major elements) of sediments from the Chesapeake Bay, Lockne, and Tvären craters, to define this boundary. We show that the end of impact-related sedimentation in these cases is fairly rapid, and does not necessarily coincide with a visual boundary (e.g., grain size shift). Therefore, in some cases, the boundary is more precisely determined by chemostratigraphy, especially carbonate carbon isotope variations, rather than by visual inspection. It is also shown how chemostratigraphy can confirm the age of marine-target craters that were previously determined by biostratigraphy; by comparing postimpact carbon isotope trends with established regional trends.

Chesapeake Bay, Lockne crater, Tvären crater↗

In situ evidence for an ancient aqueous environment at Meridiani Planum, Mars

Sedimentary rocks at Eagle crater in Meridiani Planum are composed of fine-grained siliciclastic materials derived from weathering of basaltic rocks, sulfate minerals (including magnesium sulfate and jarosite) that constitute several tens of percent of the rock by weight, and hematite. Cross-stratification observed in rock outcrops indicates eolian and aqueous transport. Diagenetic features include hematite-rich concretions and crystal-mold vugs. We interpret the rocks to be a mixture of chemical and siliciclastic sediments with a complex diagenetic history. The environmental conditions that they record include episodic inundation by shallow surface water, evaporation, and desiccation. The geologic record at Meridiani Planum suggests that conditions were suitable for biological activity for a period of time in martian history.

Science↗

Assessing decadal-scale coastal change likelihood to define the accuracy and application of scientific information

Defining the accuracy and uncertainties of scientific data products is critical to the usability and trustworthiness of scientific information for environmental management and conservation purposes, such as coastal resource prioritization, design, adaptation, and mitigation. The U.S. Geological Survey has a new decadal-scale coastal change assessment product that synthesizes nearly two dozen coastal datasets. A supervised machine-learning framework is used to combine existing datasets that describe the landscape and the hazards that affect it to determine the coastal change likelihood (CCL) in the coming decade at a resolution of 10 m per pixel for the NE United States from Maine to Virginia. Here, results from a series of statistical tests conducted on source data, the supervised classification, and the CCL outcomes as compared with historical land-cover change are presented. The overall accuracy of the aggregated land-cover dataset that serves as the foundation to which other source datasets are appended is 94%. The supervised learning classification that determines the final CCL output has an overall accuracy of 92%. The CCL predictions of high expected coastal change were consistent with 95% of the coastal and low-elevation landscape change in the last 20 years, as recorded by the Coastal Change Analysis Program land-cover change atlas. Results suggest that CCL provides accurate estimates of coastal landscape change in the next decade that are consistent with recent observed change. Additionally, best practices for applying CCL for planning purposes are outlined, and citing limitations, knowledge gaps, and opportunities for improved accuracy and further investigation are considered.

Journal of Coastal Research↗

Contaminants of emerging concern in the Great Lakes: Science to inform management practices for protecting the health and integrity of wildlife populations from adverse effects: GLRI action plan I, focus area 1, goal 5

Executive Summary: Under Action Plan I (2010-2014) of the Great Lakes Restoration Initiative (GLRI), Federal and Academic partners began an investigation of the presence and distribution of contaminants of emerging concern (CECs) in the Great Lakes and potential impacts on fish and wildlife. The term CECs is applied to a broad range of chemicals that are currently in use but for which we currently lack good understanding of whether fish, wildlife, or humans are being exposed and/or whether negative health or environmental effects are expected if exposure occurs. Pharmaceuticals, personal care products, flame retardants, many current use pesticides, and poly- and perfluorinated chemicals are some well-known groups of CECs, but there is no definitive or comprehensive list that can be used to support the management of CECs to reduce impacts on the Great Lakes ecosystem. Four overarching goals were identified for this collaborative investigation: 1. Evaluate the sources, occurrence, and distribution of CECs across the Great Lakes Basin. 2. Examine associations between the distribution of CECs and land-use patterns. 3. Review both scientific literature and field-generated data to determine the potential for CECs to cause adverse effects on Great Lakes fish and wildlife populations. 4. Develop efficient strategies to survey and/or monitor for threats that CECs may pose in order to take effective management actions before those threats evolve into large scale impacts on Great Lakes ecosystems or the services they provide. Achievement of these goals ensures progress towards Focus Area 1: Toxic Substances and Areas of Concern from GLRI Action Plan I, Goal 5: “ The health and integrity of wildlife populations and habitat are protected from adverse chemical and biological effects associated with the presence of toxic substances in the Great Lakes Basin ”. This large-scale research effort was comprised of individual and collaborative projects from multiple federal agencies and academic institutions, involving over 85 investigators, and overseen by the U.S. Environmental Protection Agency (EPA) Region 5, Great Lakes National Program Office. Partners include the United States Geological Survey, the National Oceanic and Atmospheric Administration, U.S. Fish and Wildlife Service, Saint Cloud State University, the U.S. EPA Office of Research and Development, and the U.S. Army Corps of Engineers. Key findings: 1. Contaminants of emerging concern were found throughout the monitored Great Lakes tributaries, but types and concentrations vary in association with regional land use. CECs were detected in nearly all samples collected. The type and concentration of the specific contaminants detected varied considerably among field sites and in association with land use type, such as urban, agricultural, wetland, 2 or forest. Contaminants were detected in the water column, sediment, and tissues of all species surveyed in the current work (mussels, aquatic insects, fish, and insect-eating birds). 2. There were over 20 contaminants for which CEC concentrations approached or exceeded those reported to cause toxicity in laboratory experiments. This was based on detection in water, sediments and or biota at one or more field sites. These contaminants represent compounds that warrant further investigation and monitoring with respect to potential impacts in certain areas of the Great Lakes basin. Based on the present investigation, compounds of greatest concern include: polycyclic aromatic hydrocarbons, associated with oil-based products and combustion of organic matter; atrazine, an herbicide; dichlorvos, an insecticide; and ibuprofen and venlafaxine, both pharmaceuticals. 3. Results suggest that mixtures of CECs presently found in most Great Lakes tributary locations surveyed may elicit subtle biological effects, but likely are not, alone, causing obvious detriment to current communities of fish and wildlife. CECs detected in the Great Lakes were associated with subtle biological effects like changes in gene expression, altered circulating glucose, etc. in both wild-caught and laboratory-reared organisms. These effects were generally not indicative of reproductive failure or mortality. However, the effects may have more serious implications when combined with other sources of stress like habitat degradation, changing climate conditions, and competition with invasive species. Due to limited historical data, it is unknown whether severe CEC-related impacts have already affected aquatic communities in waterbodies that have received long-term inputs of these contaminants. Likewise, under Action Plan I, biological effects were not necessarily evaluated at the sites where CEC concentrations exceeding laboratory toxicity thresholds were detected. As a result, strategic, ongoing surveillance and monitoring of CECs is warranted. This collaborative investigation resulted in new tools, approaches, and data that can be used to inform and support the management of CECs to reduce their impacts on Great Lakes natural resources. The following products of this research effort are available through https://communities.geoplatform.gov/glri/ or by contacting the investigators (see technical chapters found in Appendices A-F): 1. Database of CEC occurrence and concentrations in US tributary streams. The database includes CEC detections in water, sediment, and fish and wildlife tissues, and represents the most comprehensive survey of CECs in the Great Lakes Region. 2. Synopses of results and key findings. Integrated summaries of results, conclusions, and management implications of the CEC research are available through reports, topical fact sheets, and presentations. 3. Technical publications: This collaborative research effort has resulted in over 50 peer-reviewed publications, agency reports, and data releases that can be of use to resource managers, the scientific community, and members of the public. 4. Innovative tools. Innovative monitoring devices, sampling equipment, conceptual frameworks, and software applications were developed over the course of this 3 research. These tools are transferable to stakeholders via internet accessibility or via specifications, instructions, and demonstration detailed in technical publications. Hypotheses to guide CECs research under Action Plan II. Findings from 2010-2014 were used to guide further research in 2015-2018 for basin-wide surveillance of CECs and for sites warranting further study of potential biological impacts of CECs. Additional surveillance included both evaluation of additional classes of contaminants and expanded lists for chemical classes shown to be of greatest concern. Mixtures of some of the most frequently detected contaminants were also tested in laboratory studies to understand whether long term exposures to multiple contaminants may result in effects not evident from uncontrolled, short-term field experiments.

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Understanding our fragile environment; Lessons from geochemical studies

An understanding of our fragile environment can begin with a recognition of the importance of certain elements, commonly called "minerals substances" (such as iron and zinc), in the lives of humans and animals and in the soils that support plants. This recognition is well deserved because these elements are essential for the life or optimum health of an organism. Some elements such as carbon, hydrogen, oxygen, magnesium, potassium, and phosphorus are required in relatively large amounts by organisms. However, others are required in smaller quantities; these are referred to as trace elements. Diseases have been related to the deficiency of about 20 elements in animals and humans and to the deficiency of approximately 13 elements in plants. At the same time, if these and other elements occur in quantities great enough, toxicity can result. An element, or any substance, that occurs in the environment and contains concentrations above what are considered to be background levels may be considered a contaminant. When contaminants occur at levels that are potentially harmful to organisms, they are labeled as hazards. Often the quantitative difference between essential amounts and toxic concentrations of these elements is very small. For example, the trace element selenium is required at a level of no less than 0.4 ppm in the diet of cattle but can be toxic at levels greater than approximately 4ppm. Elements that are required for survival by animals and plants are termed essential, while those not required are nonessential. Trace essential elements such as fluorine, copper, selenium, molybdenum, and others listed in the table on page 1 can be hazardous to life forms if present at high levels. Nonessential heavy metals such as arsenic, lead, mercury, cadmium, and chromium are usually toxic to organisms at much lower levels than trace essential elements. Depending on the association that these nonessential elements may form with natural geologic materials such as organic matter, other elements or minerals, and adsorbers (such as clays), these elements can range from being safe to being extremely toxic. The elemental composition of plants, animals, and humans correlates with the geologic makeup of the Earth, and life has evolved reflecting these natural occurrences. The science of environmental geochemistry examines the interrelationship of life with the physical and chemical Earth.

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