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Sources of dissolved salts in the central Murray Basin, Australia

Large areas of the Australian continent contain scattered saline lakes underlain by shallow saline groundwaters of regional extent and debated origin. The normative salt composition of subsurface pore fluids extracted by squeezing cores collected during deep drilling at Piangil West 2 in the central Murray Basin in southeastern Australia, and of surface and shallow subsurface brines produced by subaerial evaporation in the nearby Lake Tyrrell systems, helps constrain interpretation of the origin of dissolved solutes in the groundwaters of this part of the continent. Although regional sedimentation in the Murray Basin has been dominantly continental except for a marine transgression in Oligocene-Pliocene time, most of the solutes in saline surface and subsurface waters in the central Murray Basin have a distinctly marine character. Some of the Tyrrell waters, to the southwest of Piangil West 2, show the increase in NaCl and decrease in sulfate salts expected with evaporative concentration and gypsum precipitation in an ephemeral saline lake or playa environment. The salt norms for most of the subsurface saline waters at Piangil West 2 are compatible with the dilution of variably fractionated marine bitterns slightly depleted in sodium salts, similar to the more evolved brines at Lake Tyrrell, which have recharged downward after evaporation at the surface and then dissolved a variable amount of gypsum at depth. Apparently over the last 0.5 Ma significant quantities of marine salt have been blown into the Murray Basin as aerosols which have subsequently been leached into shallow regional groundwater systems basin-wide, and have been transported laterally into areas of large evaporative loss in the central part of the basin. This origin for the solutes helps explain why the isotopic compositions of most of the subsurface saline waters at Piangil West 2 have a strong meteoric signature, whereas the dissolved salts in these waters appear similar to a marine assemblage. ?? 1994.

Chemical Geology↗

Reinterpretation of the peninsular Florida Oligocene: An integrated stratigraphic approach

A very thick (> 300 m) nearly continuous Oligocene section exists in southern peninsular Florida, as revealed by lithostratigraphic, biostratigraphic (mollusks and dinocysts), chronostratigraphic (Sr isotopes) and petrographic analyses of twelve cores and two quarries. The Oligocene deposits in the subsurface of southern Florida are the thickest documented in the southeastern U.S., and they also may represent the most complete record of Oligocene deposition in this region. No major unconformities within the Oligocene section are detected in the southern portion of the peninsula; hiatuses at the Eocene-Oligocene boundary, the early Oligocene-late Oligocene boundary, and the late Oligocene-Miocene boundary, are of limited duration if they exist at all. No significant disconformity is recognized between the Suwannee Limestone and the Arcadia Formation in southern Florida. However, on the east coast of Florida a hiatus of more than 12 m.y., spanning from at least the middle of the early Oligocene to early Miocene is present. The Suwannee Limestone was deposited during the early Oligocene. The top of the Suwannee Limestone appears to be diachronous across the platform. The 'Suwannee' Limestone, previously identified incorrectly as a late Oligocene unit, is herein documented to be early Oligocene and is encompassed in the lower Oligocene Suwannee Limestone. An unnamed limestone, found on the east coast of the peninsula is, at least in part, correlative with the Suwannee Limestone. The Arcadia Formation, basal Hawthorn Group, accounts for a large portion of the Oligocene deposition in southern Florida, spanning the interval from the middle of the early Oligocene to at least the early Miocene. Comparisons of the depositional patterns, and the distribution of dolomite and phosphate within the Suwannee Limestone and the Arcadia Formation, suggest fluctuating sea levels and that the paleo-Gulf Stream played a role in determining the nature and extent of Oligocene deposition in peninsular Florida.

Florida↗

Geologic map of the Nelson quadrangle, Lewis and Clark County, Montana

The geologic map of the Nelson quadrangle, scale 1:24,000, was prepared as part of the Montana Investigations Project to provide new information on the stratigraphy, structure, and geologic history of an area in the geologically complex southern part of the Montana disturbed belt. In the Nelson area, rocks ranging in age from Middle Proterozoic through Cretaceous are exposed on three major thrust plates in which rocks have been telescoped eastward. Rocks within the thrust plates are folded and broken by thrust faults of smaller displacement than the major bounding thrust faults. Middle and Late Tertiary sedimentary and volcaniclastic rocks unconformably overlie the pre-Tertiary rocks. A major normal fault displaces rocks of the western half of the quadrangle down on the west with respect to strata of the eastern part. Alluvial and terrace gravels and local landslide deposits are present in valley bottoms and on canyon walls in the deeply dissected terrain. Different stratigraphic successions are exposed at different structural levels across the quadrangle. In the northeastern part, strata of the Middle Cambrian Flathead Sandstone, Wolsey Shale, and Meagher Limestone, the Middle and Upper Cambrian Pilgrim Formation and Park Shale undivided, the Devonian Maywood, Jefferson, and lower part of the Three Forks Formation, and Lower and Upper Mississippian rocks assigned to the upper part of the Three Forks Formation and the overlying Lodgepole and Mission Canyon Limestones are complexly folded and faulted. These deformed strata are overlain structurally in the east-central part of the quadrangle by a succession of strata including the Middle Proterozoic Greyson Formation and the Paleozoic succession from the Flathead Sandstone upward through the Lodgepole Limestone. In the east-central area, the Flathead Sandstone rests unconformably on the middle part of the Greyson Formation. The north edge, northwest quarter, and south half of the quadrangle are underlain by a succession of rocks that includes not only strata equivalent to those of the remainder of the quadrangle, but also the Middle Proterozoic Newland, Greyson, and Spokane Formations, Pennsylvanian and Upper Mississippian Amsden Formation and Big Snowy Group undivided, the Permian and Pennsylvanian Phosphoria and Quadrant Formations undivided, the Jurassic Ellis Group and Lower Cretaceous Kootenai Formation. Hornblende diorite sills and irregular bodies of probable Late Cretaceous age intrude Middle Proterozoic, Cambrian and Devonian strata. No equivalent intrusive rocks are present in structurally underlying successions of strata. In this main part of the quadrangle, the Flathead Sandstone cuts unconformably downward from south to north across the Spokane Formation into the upper middle part of the Greyson Formation. Tertiary (Miocene?) strata including sandstone, pebble and cobble conglomerate, and vitric crystal tuff underlie, but are poorly exposed, in the southeastern part of the quadrangle where they are overlain by late Tertiary and Quaternary gravel. The structural complexity of the quadrangle decreases from northeast to southwest across the quadrangle. At the lowest structural level (Avalanche Butte thrust plate) exposed in the canyon of Beaver Creek, lower and middle Paleozoic rocks are folded in northwest-trending east-inclined disharmonic anticlines and synclines that are overlain by recumbently folded and thrust faulted Devonian and Mississippian rocks. The Mississippian strata are imbricated adjacent to the recumbent folds. In the east-central part of the quadrangle, a structurally overlying thrust plate, likely equivalent to the Hogback Mountain thrust plate of the Hogback Mountain quadrangle adjacent to the east (Reynolds, 20xx), juxtaposes recumbently folded Middle Proterozoic and unconformably overlying lower Paleozoic rocks on the complexly folded and faulted rocks of the Avalanche Butte thrust plate. The highest structural plate, bounded below

IMAP↗

Development of inverted metamorphic isograds in the western metamorphic belt, Juneau, Alaska

An inverted metamorphic gradient is preserved in the western metamorphic belt near Juneau, Alaska. The western metamorphic belt is part of the Coast plutonic–metamorphic complex of western Canada and southeastern Alaska that developed as a result of tectonic overlap and/or compressional thickening of crustal rocks during collision of the Alexander and Stikine terranes. Detailed mapping of pelitic single-mineral isograds, systematic changes in mineral assemblages, and silicate geothermometry indicate that thermal peak metamorphic conditions increase structurally upward over a distance of about 8 km. Peak temperatures of metamorphism increase progressively from about 530 °C for the garnet zone to about 705 °C for the upper kyanite–biotite zone. Silicate geobarometry suggests that the thermal peak metamorphism occurred under pressures of 9–11 kbar. The metamorphic isograds are in general parallel to the tonalite sill that is regionally continuous along the east side of the western metamorphic belt, although truncation of the isograds north of Juneau indicates that the sill intrusion continued after the isograds were established. Our preferred interpretation of the cause of the inverted gradient is that it formed during compression of a thickened wedge of relatively wet and cool rocks in response to heat flow associated with the formation and emplacement of the tonalite sill magma. Garnet rim compositions and widespread growth of chlorite suggest partial re-equilibration of the schists under pressures of 5–6 kbar during uplift in response to final emplacement and crystallization of the tonalite sill. The combined results of this study with previous studies elsewhere in the western metamorphic belt indicate that high-T/high-P metamorphism associated with the collision of the Alexander and Stikine terranes was a long-lived event, extending from about 98 Ma to about 67 Ma.

Journal of Metamorphic Geology↗

Contrasting methods of fracture trend characterization in crystalline metamorphic and igneous rocks of the Windham quadrangle, New Hampshire

The bedrock of the Windham quadrangle in southeastern New Hampshire consists of deformed early Palaeozoic crystalline metamorphic and intrusive igneous rocks intruded by Mesozoic igneous dikes. Generally, less common northeast striking, steeply dipping fractures developed sub-parallel to the pre-existing tectonic foliation in the Palaeozoic rocks. Mesozoic lamprophyre and diabase dikes intruded along the northeast trending fractures, utilizing the pre-existing anisotropy in the crystalline rocks. Northwest striking, steeply dipping systematic joints and joint sets are the most prominent fractures in the area and, at least in part, post-date the Mesozoic dikes. Sub-horizontal sheeting joints occur in all rock types. Locally, the coincidence of the sub-horizontal fractures with a sub-horizontal Paleozoic cleavage suggests that some of the sheeting fractures utilized the pre-existing ductile anisotropy during unloading. Generally, the metasedimentary rocks show a less complex pattern of fracturing than the intrusive rocks suggesting that rock type is a controlling factor. Metasedimentary rocks in the biotite zone and well-foliated igneous rocks show a greater tendency to fracture along pre-existing bedding and foliation surfaces than metasedimentary rocks in the garnet zone and poorly foliated igneous rocks. A comparison of mapped fracture data and station fracture data indicates that either mapped data or station data can be used to identify regional fracture trends. Local fracture trends can not be identified by limited measurements at a few fracture stations, however, because they do not address spatial variability. Some fracture trends may be scale-dependant because they may be either unique to a local area or present only at regional scales.

Northeastern Geology and Environmental Sciences↗

Water-level conditions in the confined aquifers of the New Jersey Coastal Plain, 2013

The Coastal Plain aquifers of New Jersey provide an important source of water for more than 3.5 million people. In 2013, groundwater withdrawals from 10 confined aquifers of the New Jersey Coastal Plain totaled about 190 million gallons per day. Steadily increasing withdrawals from the late 1800s to the early 1990s resulted in declining water levels and the formation of regional cones of depression in many confined Coastal Plain aquifers. Starting in 1978, the U.S. Geological Survey (USGS) began mapping the potentiometric surfaces of the major confined Coastal Plain aquifers every 5 years to provide a regional assessment of groundwater conditions. In a study conducted by the USGS, in cooperation with the New Jersey Department of Environmental Protection, water levels in 10 confined aquifers of the New Jersey Coastal Plain were measured and evaluated to provide a regional overview of groundwater conditions during fall 2013. Water levels were measured in 987 wells in New Jersey, and parts of Pennsylvania and Delaware. Potentiometric-surface maps were prepared for, in ascending order of age, the confined Cohansey aquifer of Cape May County, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the Upper, Middle, and Lower aquifers of the Potomac-Raritan-Magothy (PRM) aquifer system. Persistent, regionally extensive cones of depression were present in the potentiometric surfaces of the Englishtown aquifer system and Wenonah-Mount Laurel aquifer in Ocean and Monmouth Counties; Wenonah-Mount Laurel and Upper, Middle, and Lower PRM aquifers in Camden County; and Atlantic City 800-foot sand in Atlantic County. Changes in water levels from 2008 to 2013 were measured in many Coastal Plain aquifers in New Jersey. In some areas, water levels continued to decline as a result of pumping, but in other areas water levels continued to recover as a result of regulated decreases in groundwater withdrawals. Since 2008, in the confined Cohansey aquifer in Cape May County, water levels generally did not change; however, cones of depression in the potentiometric surface of the Piney Point aquifer in some areas of Cumberland County deepened by more than 20 feet (ft). In Critical Area 1, an area of restricted withdrawals, measured water levels in the Wenonah-Mount Laurel aquifer declined in parts of southern Monmouth County by more than 10 ft; however, rises in water levels of more than 10 ft were measured in parts of northern Ocean and Monmouth Counties. Since 2008, in Critical Area 2, also an area of restricted withdrawals, measured water levels in the Wenonah-Mount Laurel aquifer rose more than 20 ft in parts of western Burlington County and more than 20 ft in parts of western Camden County. Since 2008, in Critical Area 1, measured water levels in the Englishtown aquifer system declined in parts of eastern Ocean County by more than 10 ft and in southeastern Monmouth County by more than 20 ft; however, rises in water levels of more than 10 ft were measured in other parts of Ocean and Monmouth Counties. In general, since 2008 in Critical Area 2, in the Upper PRM aquifer, measured water levels continued to rise by 10 ft or more in central and western Burlington and central Camden Counties. In the Middle PRM aquifer in Critical Area 2, measured water levels rose in parts of central Camden County by 10 ft or more. However, measured water levels in the Lower PRM aquifer in Critical Area 2 were more than 10 ft lower in the center of the cone of depression in central Camden County, but measured water levels continued to rise updip from this area in Critical Area 2. Seasonal water-level fluctuations are presented in time-series hydrographs for 77 wells during 1978–2013. Analyses of long-term water-level changes for the period 2008–13 indicate downward water-level trends at 14 wells (18 percent), upward trends at 34 wells (44 percent), and no substantial change at 29 wells (38 percent). Downward trends were most often observed for wells screened in the Piney Point aquifer and the Atlantic City 800-foot sand. Upward water-level trends were most often measured for wells screened in the PRM aquifer system. Upward water-level trends also were measured for wells in the Englishtown aquifer system and the Wenonah-Mount Laurel aquifer in Critical Area 1 in some areas; however, downward trends and no substantial changes were measured in other areas.

New Jersey↗

Extreme Quaternary plate boundary exhumation and strike slip localized along the southern Fairweather fault, Alaska, USA

The Fairweather fault (southeastern Alaska, USA) is Earth’s fastest-slipping intracontinental strike-slip fault, but its long-term role in localizing Yakutat–(Pacific–)North America plate motion is poorly constrained. This plate boundary fault transitions northward from pure strike slip to transpression where it comes onshore and undergoes a <25°, 30-km-long restraining double bend. To the east, apatite (U-Th)/He (AHe) ages indicate that North America exhumation rates increase stepwise from ~0.7 to 1.7 km/m.y. across the bend. In contrast, to the west, AHe age-depth data indicate that extremely rapid 5–10 km/m.y. Yakutat exhumation rates are localized within the bend. Further northwest, Yakutat AHe and zircon (U-Th)/He (ZHe) ages gradually increase from 0.3 to 2.6 Ma over 150 km and depict an interval of extremely rapid >6–8 km/m.y. exhumation rates that increases in age away from the bend. We interpret this migration of rapid, transient exhumation to reflect prolonged advection of the Cenozoic–Cretaceous sedimentary cover of the eastern Yakutat microplate through a stationary restraining bend along the edge of the North America plate. Yakutat cooling ages imply a long-term strike-slip rate (54 ± 6 km/m.y.) that mimics the millennial (53 ± 5 m/k.y.) and decadal (46 mm/yr) rates. Fairweather fault slip can account for all Pacific–North America relative plate motion throughout Quaternary time and indicates stability of highly localized plate boundary strike slip on a single fault where extreme rock uplift rates are persistently localized within a restraining bend.

Alaska↗

Water-level altitudes 2015 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973-2014 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Most of the land-surface subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction of the aquifer sediments, mostly in the fine-grained silt and clay layers. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured cumulative compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. The report contains regional-scale maps depicting approximate 2015 water-level altitudes (represented by measurements made during December 2014&ndash;March 2015) for the Chicot, Evangeline, and Jasper aquifers; maps depicting 1-year (2014&ndash;15) water-level changes for each aquifer; maps depicting approximate contoured 5-year (2010&ndash;15) water-level changes for each aquifer; maps depicting approximate contoured long-term (1990&ndash;2015 and 1977&ndash;2015) water-level changes for the Chicot and Evangeline aquifers; a map depicting approximate contoured long-term (2000&ndash;15) water-level changes for the Jasper aquifer; a map depicting locations of borehole-extensometer sites; and graphs depicting measured cumulative compaction of subsurface sediments at the borehole extensometers during 1973&ndash;2014. Three tables listing the water-level data used to construct each water-level map for each aquifer and a table listing the measured cumulative compaction data for each extensometer site and graphs are included. In 2015, water-level-altitude contours for the Chicot aquifer ranged from 175 feet (ft) below the vertical datum (the National Geodetic Vertical Datum of 1929 or the North American Vertical Datum of 1988; hereinafter, datum) in a localized area in northwestern Harris County to 200 ft above datum in northern and western Montgomery County. Water-level changes for 2014&ndash;15 in the Chicot aquifer ranged from a 24-ft decline to a 31-ft rise. Contoured 5-year and long-term water-level changes in the Chicot aquifer ranged from a 40-ft decline to a 40-ft rise (2010&ndash;15), from a 100-ft decline to a 100-ft rise (1990&ndash;2015), and from a 100-ft decline to a 200-ft rise (1977&ndash;2015). In 2015, water-level-altitude contours for the Evangeline aquifer ranged from 250 ft below datum in a localized area extending from south-central Montgomery County into north-central Harris County and in an additional area located in central Harris County to 200 ft above datum in southeastern Grimes and northwestern Montgomery Counties. Water-level changes for 2014&ndash;15 in the Evangeline aquifer ranged from a 66-ft decline to a 78-ft rise. Contoured 5-year and long-term water-level changes in the Evangeline aquifer ranged from a 60-ft decline to an 80-ft rise (2010&ndash;15), from a 200-ft decline to a 240-ft rise (1990&ndash;2015), and from a 320-ft decline to a 240-ft rise (1977&ndash;2015). In 2015, water-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum in south-central Montgomery County that extends into north-central Harris County to 250 ft above datum in northwestern Montgomery County. Water-level changes for 2014&ndash;15 in the Jasper aquifer ranged from a 17-ft decline to a 35-ft rise. Contoured 5-year and long-term water-level changes in the Jasper aquifer ranged from a 60-ft decline to four small, localized areas of 10-ft rises (2010&ndash;15) and from a 220-ft decline to no change (2000&ndash;15). Compaction of subsurface sediments (mostly in the fine-grained silt and clay layers) composing the Chicot and Evangeline aquifers was recorded continuously by using analog technology at the 13 borehole extensometers at 11 sites that were either activated or installed between 1973 and 1980. For the period of record beginning in 1973 (or later depending on activation or installation date) and ending in December 2014, measured cumulative compaction at the 13 extensometers ranged from 0.101 ft at the Texas City-Moses Lake extensometer to 3.668 ft at the Addicks extensometer. During 2014, a total of 10 of the 13 extensometers recorded a slight net decrease of land-surface elevation; the extensometers at the Lake Houston and Clear Lake (shallow) sites recorded slight net increases of land-surface elevation, and the extensometer at the Texas City-Moses Lake site recorded no change in elevation. The rate of compaction varies from site to site because of differences in rates of groundwater withdrawal in the areas adjacent to each extensometer site and differences among sites in the ratios of sand, silt, and clay and compressibilities of the subsurface sediments. It is not appropriate, therefore, to extrapolate or infer a rate of compaction for an adjacent area on the basis of the rate of compaction measured at nearby extensometers.

Texas↗

Mapping areas of groundwater susceptible to transient contamination events from rapid infiltration into shallow fractured-rock aquifers in agricultural regions of the conterminous United States

Current time-invariant groundwater vulnerability assessments may not capture intermittent contamination events in landscape areas that experience rapid infiltration following precipitation or snowmelt. Occurrences of rapid infiltration and intermittent degradation of groundwater quality are frequently reported in fractured-rock aquifers. This investigation identifies landscape areas underlain by fractured rock within the conterminous United States (CONUS) that may be susceptible to rapid infiltration and where groundwater is a principal source of water supply to the population. Our analysis shows that approximately 27 percent of the CONUS, corresponding to a population of approximately 150 million people, is both underlain by fractured rock and denoted as an area of significant groundwater use. The results of this survey identified shallow fractured-rock aquifers underlying glacial sediments in the upper Midwest and northeastern United States as areas that may be subject to rapid infiltration events. Additionally, aquifers associated with the early Mesozoic basins located in the northeastern and mid-Atlantic United States and bands of carbonate aquifers in the southeastern United States show high susceptibility to rapid infiltration. Index values used in this investigation indicate isolated areas in the western half of the United States also show high susceptibility to rapid infiltration. The isolated areas in Oklahoma, Texas, Arkansas, and southwestern Missouri correspond to karst regions of carbonate aquifers. The isolated areas showing high susceptibility to rapid infiltration and contamination from agricultural sources are locations where more detailed investigations of transient contamination events are warranted. This survey also addresses the potential for contaminant longevity in fractured-rock aquifers stemming from intermittent contamination events. Contaminants that can dissolve into the groundwater following infiltration may be introduced into fractures, and the dissolved constituents can diffuse from fractures into the porosity of the adjacent rock matrix. These constituents can then diffuse back into permeable fractures and adversely affect groundwater quality at downgradient locations over an extended time frame. Rock types with larger matrix porosities have the capacity to retain and then release larger quantities of dissolved constituents, resulting in longer residence times for dissolved groundwater contaminants. The magnitude of the dissolved contaminant concentration infiltrating to the water table will also dictate whether the contaminant concentration in the groundwater exceeds limits for human consumption over the duration of a contamination event. In general, sedimentary- and carbonate-rock aquifers have larger matrix porosities in comparison to igneous- and metamorphic-rock aquifers, and thus, they are more susceptible to longer contaminant residence times. Aquifers composed of sedimentary or carbonate rock constitute approximately 51 percent of the CONUS, and 19 percent of the CONUS is associated with sedimentary- or carbonate-rock aquifers that are of significance for groundwater use. Depending on the contaminants of concern and the concentration of the contaminants introduced into the groundwater from infiltrating water, it would be beneficial for investigations of susceptibility to rapid infiltration to also consider the potential for contaminant longevity. This investigation identifies areas of rapid infiltration into fractured rock using index values applied to the attributes (1) depth to the water table, (2) depth to bedrock, and (3) percentage of sand in soil, where larger index values indicate a greater susceptibility to rapid infiltration. These attributes are selected as the most likely factors that affect rapid infiltration to the water table. The combination of depth to water table and depth to bedrock highlight those aquifer settings that are characterized as shallow fractured-rock aquifers, where the water table may reside either in the bedrock or in overlying unconsolidated geologic materials. In addition, we consider the percentage of agricultural use as a land-use attribute when formulating an index of susceptibility to rapid infiltration and contamination. Agricultural areas are well recognized as nonpoint sources of contaminants that can affect groundwater quality because of seasonal amendments applied to the land surface. Rural agricultural areas are also characterized by septic tanks and leach fields for onsite treatment of wastewater, which may also be a source of contamination that may be introduced into the groundwater following precipitation or snowmelt events.

Conterminous United States↗

Heat transport by fluids during late Cretaceous regional metamorphism in the Big Maria Mountains, southeastern California

The Big Maria Mountains of southeastern California comprise a Late Cretaceous regional metamorphic terrain involving Paleozoic cratonal sediments. Siliceous limestone of the upper Paleozoic Supai Formation has reacted to form massive wollastonite, requiring an enormous fluid flux. The minimum volume ratio of fluid:rock that is necessary to explain the formation of wollastonite may be calculated from the reaction quartz + calcite = wollastonite + CO 2 , using the method of Rice and Ferry. Given average conditions of 3 kbar, 500 °C, an infiltrating fluid of composition X H2O = 1.00, an equilibrium fluid composition of X H2O = 0.97, and 90% wollastonite in the final rock, a fluid:rock ratio of 17:1 may be calculated. Infiltrating fluids of composition 1.00 > X H2O > 0.97 require still higher ratios. Metamorphic reactions which took place in other units of the sequence (metapelites, massive carbonates, metavolcaniclastics) did not record the massive fluid flux, but fluids must have passed through them to have affected structurally isolated masses of Supai Formation. Passage of fluids must have occurred along fractures. Neither magmatism nor radioactive heat sources are adequate to explain the temperatures of metamorphism. If the minimum quantity of fluid that is estimated to have passed through the area was initially at 680 °C, it would result in a 300-degree rise in temperature over that of the stable-craton geotherm. Late metamorphic pegmatite dikes which are most abundant in areas of high metamorphic grade may stem from melts anatectically derived at deeper levels, perhaps as a result of the same fluid flux. Heat that is introduced by large fluid fluxes may be an important cause of anomalously high temperatures which are observed in many cases in regional metamorphic terrains.

California↗

Nomenclature and correlation of some upper Precambrian and basal Cambrian sequences in western Utah and southeastern Idaho

Recent stratigraphic studies in three widely separated localities in southeastern Idaho and western Utah have revealed a startling continuity of both individual rock units and of rock sequences over a distance of some 300 mi parallel to the strike of a late Precambrian and Cambrian depositional trough. Between 15,000 and 25,000 ft of beds were deposited in the axis of the trough, whereas only 1000 to 3300 ft of correlative rocks were laid down on the shelf to the east. In several areas a diamictite is present near the base of the sequence; this is underlain locally and overlain generally by argillites containing lenticular limestones and dolomites; these in turn are succeeded by quartzitic rocks containing a thick grayish-red to maroon unit—the Mutual Formation. In each area the sequence includes, at the top, quartzites typical of the basal Cambrian. Deposition in the basin was essentially continuous from late Precambrian into Cambrian time but was interrupted by uplift and erosion on the shelf. The hinge line of the ancient seaway is inferred to have coincided roughly with the present “Wasatch line,” but erosion prior to deposition of the Tintic Quartzite has removed most of the data needed to establish this with certainty. Rocks in each of the three areas described here in detail are regarded as allochthonous and appear to have been thrust eastward during the Sevier orogeny. A precise reconstruction of the sedimentary basin must therefore await not only additional stratigraphic studies in such areas as the Promontory Range of Utah and the Bannock and Malad Ranges of southern Idaho, but also final resolution of the structural events.

Idaho, Utah↗

A proposed glacial history of the Henrys Lake Basin, Idaho

Deposits of several glaciations from oldest to youngest, pre-Bull Lake, Bull Lake, and Pinedale are in and near the Henrys Lake basin, a northwest-trending hourglass-shaped trough in southeastern Idaho. Glacial deposits of pre-Bull Lake age are represented by till remnants confined mostly to the higher levels of the surrounding mountains. The extent of Bull Lake ice into the basin is uncertain. Glacial deposits and ice-marginal features suggest that a lobe of Bull Lake ice the Henrys Lake ice lobe moved into the basin and advanced as far north as the north edge of Henrys Lake. After this lobe melted back far enough to expose the north end of the basin, melt waters, chiefly from alpine glaciers in Targhee Creek and its tributaries, formed the broad low Howard Creek fan at the mouth of the valley of Howard Creek. Shortly thereafter, a complex of channels was cut into the fan by periodic melt-water floods which flowed westward through Targhee Pass during the waste of another Bull Lake ice lobe which lay in the West Yellowstone Basin. Melt waters from various sources ponded to form a shallow lake in front of the wasting Henrys Lake ice lobe. Waters from this lake drained southwestward around the southwest flank of the lobe via an ice-marginal channel. Upon total melt of the ice lobe, the lake was drained, the ice-marginal channel was abandoned, and the waters resumed their pre-ice course to the southeast. During the interglaciation, prior to the onset of the Pinedale Glaciation, northward-flowing streams deposited a veneer of obsidian sand and gravel along the south edge of the basin. In Pinedale time, alpine glaciers formed in the high mountain valleys near the basin, but none advanced into the basin.

Idaho↗

Tilting history of the San Manuel-Kalamazoo porphyry system, southeastern Arizona

The Laramide San Manuel-Kalamazoo porphyry system of Arizona has been pivotal in concepts of both extensional tectonics and alteration-mineralization zoning. This paper reexamines the tilting history in light of new work in the region and reinterprets the geometry of the deposit. The porphyry mineralization occurs in and near an intrusion of Laramide San Manuel porphyry in Precambrian Oracle Granite. The area has an extremely complicated history of Tertiary crustal extension and fanglomerate deposition, but the blocks containing the two main fragments of the original orebody (separated by the San Manuel fault) were involved in only the later parts of this history and are less tilted than other nearby blocks. Originally horizontal features of mid-Tertiary age are tilted about 30 degrees , those of Laramide age about 35 degrees , and those of pre-Laramide age about 45 degrees to the northeast. Paleomagnetism of the porphyry intrusion itself suggests tilting of about 33 degrees . The data thus suggest that postemplacement tilt of the Laramide porphyry system was 30 degrees to 35 degrees and that virtually all of it was mid-Tertiary in age. An earlier interpretation of greater tilt magnitude was apparently based in part on correlation with adjacent areas showing greater tilt magnitude (as in the Tar Wash allochthon) and in part on a choice of cross section that gives the impression of a nearly recumbent attitude. However, Lowell's sections are oriented along the strike of both the orebodies and the productive porphyry intrusion, which are dipping tablo-cylindroidal bodies. Ore forms a hollow envelope whose inner margin has an aspect ratio of about >4.3 (length)/>2.5 (downdip height)/l (limb separation). The productive intrusion, around which ore is wrapped, has a similar aspect ratio in the same plane (strike N 58 degrees E, dip 47 degrees SE). Reconstruction of the original attitudes of intrusion and ore yields a common strike near N 75' E and a steep dip to the south. This is a common attitude for undisturbed productive porphyry dikes of Laramide age.

Arizona↗

Recurrent eruption and subsidence at the Platoro caldera complex, southeastern San Juan volcanic field, Colorado: New tales from old tuffs

Reinterpretation of a voluminous regional ash-flow sheet (Masonic Park Tuff) as two separate tuff sheets of similar phenocryst-rich dacite erupted from separate source calderas has important implications for evolution of the multicyclic Platoro caldera complex and for caldera-forming processes generally. Masonic Park Tuff in central parts of the San Juan field, including the type area, was erupted from a concealed source at 28.6 Ma, but widespread tuff previously mapped as Masonic Park Tuff in the southeastern San Juan Mountains is the product of the youngest large-volume eruption of the Platoro caldera complex at 28.4 Ma. This large unit, newly named the “Chiquito Peak Tuff,” is the last-erupted tuff of the Treasure Mountain Group, which consists of at least 20 separate ash-flow sheets of dacite to low-silica rhyolite erupted from the Platoro complex during a 1 m.y. interval (29.5−28.4 Ma). Two Treasure Mountain tuff sheets have volumes in excess of 1000 km 3 each, and five more have volumes of 50–150 km 3 . The total volume of ash-flow tuff exceeds 2500 km 3 , and caldera-related lavas of dominantly andesitic composition make up 250-500 km 3 more. A much greater volume of intermediate-composition magma must have solidified in subcaldera magma chambers. Most preserved features of the Platoro complex-including postcollapse asymmetrical trap-door resurgent uplift of the ponded intracaldera tuff and concurrent infilling by andesitic lava flows-postdate eruption of the Chiquito Peak Tuff. The numerous large-volume pre-Chiquito Peak ash-flow tuffs document multiple eruptions accompanied by recurrent subsidence; early-formed caldera walls nearly coincide with margins of the later Chiquito Peak collapse. Repeated syneruptive collapse at the Platoro complex requires cumulative subsidence of at least 10 km. The rapid regeneration of silicic magmas requires the sustained presence of an andesitic subcaldera magma reservoir, or its rapid replenishment, during the 1 m.y. life span of the Platoro complex. Either case implies large-scale stoping and assimilative recycling of the Tertiary section, including intracaldera tuffs.

Colorado↗

A Lower Carboniferous two-stage extensional basin along the Avalon-Meguma terrane boundary: Evidence from southeastern Isle Madame, Nova Scotia

Anomalously thick and coarse clastic sedimentary successions, including over 5000 m of conglomerate, are exposed on Isle Madame off the southern coast of Cape Breton island. Two steeply to moderately dipping stratigraphic packages are recognized: one involving Horton and lower Windsor groups (Tournasian–Visean); the other involving upper Windsor and Mabou (Visean–Namurian) groups. Also anomalous on isle Madame are three long narrow belts of “basement” rocks, together with voluminous chloritic microbreccia and minor semi-ductile mylonite, which are separated from the conglomerate-dominated successions by faults. The angular relations between the cataclastic rocks and the conglomerate units, combined with the presence of cataclasite clasts in the conglomerate units and evidence of dip-slip faults within the basin, suggest an extensional setting, where listric normal faults outline detachment allochthons. Allochthon geometry requires two stages of extension, the older stage completed in early Windsor Group time and including most of the island, and the more local younger stage completed in Mabou Group time. Domino-style upper-plate faulting in the younger stage locally repeated the older detachment relation of basement and conglomerate to form the observed narrow belts. Re-rotation of older successions in the younger stage also locally overturned the Horton Group. These features developed within a broad zone of Carboniferous dextral transcurrent faulting between already-docked Avalon and Meguma terranes. Sites of transpression and transtension alternated along the Cobequid-Chedabucto fault zone that separated these terranes. The earlier extensional features in isle Madame likely represent the northern headwall and associated clastic debris of a pull-apart or other type of transtensional basin developed along part of this fault zone that had become listric; they were repeated and exposed by being up-ended in the second stage of extension, also on listric faults. The two-stage history on isle Madame exposes the deeper parts of one of the Horton-age extensional basins of the Maritimes, others of which have been described as half-grabens based on their shallower exposures.

Nova Scotia↗

Stormwater quantity and quality in selected urban watersheds in Hampton Roads, Virginia, 2016–2020

Urbanization can substantially alter sediment and nutrient loadings to streams. Although a growing body of literature has documented these processes, conditions may vary widely by region and physiographic province (PP). Substantial investments are made by localities to meet federal, state, and local water-quality goals and locally relevant monitoring data are needed to appropriately set standards and track progress. In 2016, a long-term stormwater monitoring program was initiated to characterize water-quality and streamflow conditions and compute average annual nutrient- and sediment-loading rates across the three dominant land-use types—commercial (COM), high-density residential, and single-family residential (SFR)—in the Hampton Roads metropolitan region within the Coastal Plain PP in southeastern Virginia. This report summarizes the first five years of data collection to (1) assess patterns in streamflow and water chemistry across the three major land-use types in the region; (2) compute annual sediment and nutrient loads; and (3) compare annual loading rates to those in other urbanized regions. Patterns in watershed hydrology characteristics and conditions were similar to those observed in other urban monitoring studies. Base-flow indices were lower and stream flashiness indices were higher in the study watersheds compared to those in less developed reference watersheds. These patterns reflect a decrease in infiltration and consequent increase in storm runoff as a result of urbanization. Stream flashiness was strongly positively related to degree of impervious land cover and negatively to watershed area. Hydrologic metrics varied across the land-use gradient, reflecting greater and more rapid runoff in the COM watersheds than in SFR watersheds. Event-based analyses conducted exclusively on periods of runoff highlight longer duration events, longer time-to-peak streamflow, and a longer lag between peak precipitation and peak streamflow in SFR watersheds, and higher stormflow yields, runoff ratios, and peak flows in COM watersheds. Event-based metrics varied seasonally because of regional meteorological patterns. Concentrations of total suspended solids (TSS) and total phosphorus (TP) were positively correlated to streamflow, whereas concentrations of total nitrogen (TN) varied little across the hydrologic regime. Phosphorus composition varied spatially and seasonally—the proportion of orthophosphate (PO 4 3- ) was highest in samples collected from stations draining residential land-use types and was elevated in summer and fall. Nitrogen composition varied with hydrologic condition: nitrate plus nitrite (NO 3 - ) dominance during base flow shifted to total organic nitrogen (TON) dominance during periods of runoff. For all three major constituents (TSS, TP, and TN), concentrations were highest in SFR watersheds, whereas yields were greatest in COM watersheds. This seeming contradiction in concentration and yield across land-use types occurred because of spatial differences in streamflow yield. The network average TSS yield in Hampton Roads was lower than that in comparable networks in Fairfax County, Virginia, and Gwinnett County, Georgia, a difference that may reflect dissimilarities in the topographic and soil characteristics of the Coastal Plain versus those in Piedmont PPs, as well as differences in engineered concrete stormwater conveyances versus earthen streams. The average annual TP yield in Hampton Roads was higher than averages reported in comparison studies and was primarily driven by elevated PO 4 3- . Elevated PO 4 3- yields may be related to unique soil and geological features of the Coastal Plain PP that limit phosphorus retention. Total nitrogen yields in the Hampton Roads and Fairfax County networks were similar; however, composition did vary, with greater total organic nitrogen yields in Hampton Roads and greater NO 3 - yields in Fairfax County. Cross-correlation analyses and mass-volume curves were used to assess the timing of sediment and nutrient loadings. The majority of TSS and TP was typically transported during the initial phase of a storm-runoff event, a phenomenon commonly termed the “first flush.” Although TN concentrations typically peaked within an hour of peak streamflow, reflecting the particulate dominance of TN during stormflows, and loadings were greater during the early phase of most storm events, the stricter first-flush criterion was rarely met. This suggests that the most abundant sources of TN in these watersheds are not as directly connected to the stormwater-conveyance system as are TSS and TP.

Virginia↗

Recharge areas and quality of ground water for the Glen Canyon and valley-fill aquifers, Spanish Valley area, Grand and San Juan counties, Utah

The Spanish Valley area in southeastern Utah (fig. 1) is experiencing a rapid increase in development of residential and business property. In this report, the Spanish Valley area refers to the geographic area shown in figures 1, 3, and 4. This area includes Moab Valley, Spanish Valley, and the mesa area.-; to the northeast. Substantial development is taking place on the cast side of Spanish Valley, where the Navajo Sandstone, the Kaycnta Formation, and the Wingate Sandstone forn the Glen Canyon aquifer, wltich is the principal aquifer that supplies drinking water for the area. Additional business construction and subdivision development are occurring in Spanish Valley south of Moab, where valley-fill deposits make up a secondary aquifer that is used mostly for irrigation and stock watering but also for domestic drinking water. Because current (1995) sewage treatment facilities arc not adequate to accommodate the increase in development, county officials are concerned about protecting the ground-water resources from excess nitrate loading that might result if additional septic systems are used for the effluent disposal. Traditional land use in the Spanish Valley area has been agricultural, but more subdivisions and small farms with horse pastures are being developed. Sumsion (1971) reported that water from five wells in the valley-fill aquifer contained nitrate concentrations that ranged from 9 to 26 mg/Las NO 3 (2.0 to 5.87 mg/Las N). With the increased use of septic systems in the south end of the valley, nitrate plus nitrite concentrations might have increased in the valley-fill aquifer. Few data on nitrate plus nitrite concentration have been collected since 1968-69. Also, with the increased development, other types of contamination such as organic compounds might be infiltrating the valley-fill aquifer. Little or no sampling for organic compounds has been done in the valley-fill aquifer in Moab and Spanish Valleys. To protect ground-water resources in Grand County, Grand County Commissioners would like to classify the ground-water system according to the Ground Water Quality Protection Administrative Rule R317-6 of the Utah Administrative Code (table I. part A. located on the back of this report) (Utah Department of Environmental Quality, Division of Water Quality, 1995). The code states that when sufficient information is available, entire aquifers or parts thereof may be classified by the lJLah Water Quality Board according to the quality of ground water contained therein. After classification, groundwater protection levels are established and used to regulate existing and potential sources of contamination to ground water from new and existing facilities within the classified area. This investigation was done by the U.S. Geological Survey (USGS) in cooperation with the Utah Department of Environmental Quality, Division of Water Quality; Grand County; the city of Moab; and the U.S. Environmental Protection Agency.

Utah↗

Chronostratigraphic and depositional sequences of the Fort Union formation (Paleocene), Williston Basin, North Dakota, South Dakota, and Montana

The Fort Union Formation in the Williston Basin of North Dakota, South Dakota, and Montana comprises chronostratigraphic and depositional sequences of Paleocene age. Individual chronostratigraphic sequences are defined by palynostratigraphic (pollen and spore) biozones and radiometric ( 40 Ar/ 39 Ar) ages obtained from tonsteins or volcanic ash layers. Analyses of depositional sequences are based on lithofacies constrained by the radiometric ages and biozones. The lower Paleocene (biozones P1-P3) contains three marine parasequences (landward stepping) in southwestern North Dakota that sequentially onlapped westward between 65 and 61 Ma (lower Ludlow and Cannonball Members). Maximum flooding (transgressive systems tract) occurred during an approximate 1-m.y. interval from 65 to 64 Ma, which regionally is correlated biostratigraphically to a tidally influenced, distributary-shoreface, and fluvial-channel complex in the Cave Hills, northwestern South Dakota, and to channel-dominated fluvial (low-stand incised paleovalley systems) and tidally influenced, flood-plain-deltaic transition facies in the Ekalaka area of southeastern Montana. The progradational parasequences in the Cannonball Member consist of shore-face sandstone beds (with ravinement lag deposits) deposited by strand-plain barrier systems. Landward of the barrier systems, tidal-estuarine and mire deposits included thick but laterally discontinuous peat accumulations (e.g., Beta and Yule coal beds in the Ludlow Member, southwestern North Dakota). However, landward of the coastal deposits, the laterally equivalent T-Cross-Big Dirty coal zone (dated 64.78 Ma) in southeastern Montana formed as thick, laterally extensive peat accumulations in mires in a fluvial setting. In the flood-plain-deltaic, tidal transition zone near Ekalaka, Montana, the Ludlow Member consists of flood-plain facies, discontinuous coal beds, and rooted and burrowed horizons that contain the marine or brackish trace fossil Skolithos. The flood-plain-deltaic tidal transition zone facies are incised by a massive, agglomerated channel sandstone complex (paleovalley fill) that is exposed along the modern Snow Creek drainage south of Mill Iron, Montana. The flood-plain-tidal transition zone was reworked during the maximum sea level highstand during the early Paleocene. This event was followed by a fall of sea level and deposition of the paleovalley fill. Sea level fall during the mid-Paleocene (biozones P3 and P4) produced a regressive shallow-marine and lower deltaic tidal system (seaward stepping) that deposited strata that thin toward the east. These strata are overlain by a widespread paleosol (Rhame bed) and, in turn, a lignite-bearing fluvial facies (Tongue River Member) containing the laterally persistent Harmon-Hanson coal zone (61.23 Ma). Upper Paleocene biozone P5 is represented by fluvial, coal-bearing strata that contain several economically minable coal beds (HT Butte, Hagel, and Beulah-Zap zones, Sentinel Butte Member). The Fort Union Formation of the Williston Basin contains significant coal resources. These coal deposits are now being explored for their potential coal-bed gas resources. A better understanding of the depositional setting for these deposits can lead to improved exploration and exploitation practices and a better understanding of regional paleogeography and paleoclimate during the Paleocene.

Montana, North Dakota, South Dakota↗