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Reducing sedimentation of depressional wetlands in agricultural landscapes

Depressional wetlands in agricultural landscapes are easily degraded by sediments and contaminants accumulated from their watersheds. Several best management practices can reduce transport of sediments into wetlands, including the establishment of vegetative buffers. We summarize the sources, transport dynamics, and effect of sediments, nutrients, and contaminants that threaten wetlands and the current knowledge of design and usefulness of grass buffers for protecting isolated wetlands. Buffer effectiveness is dependent on several factors, including vegetation structure, buffer width, attributes of the surrounding watershed (i.e., area, vegetative cover, slope and topography, soil type and structure, soil moisture, amount of herbicides and pesticides applied), and intensity and duration of rain events. To reduce dissolved contaminants from runoff, the water must infiltrate the soil where microbes or other processes can break down or sequester contaminants. But increasing infiltration also diminishes total water volume entering a wetland, which presents threats to wetland hydrology in semi-arid regions. Buffer effectiveness may be enhanced significantly by implementing other best management practices (e.g., conservation tillage, balancing input with nutrient requirements for livestock and crops, precision application of chemicals) in the surrounding watershed to diminish soil erosion and associated contaminant runoff. Buffers require regular maintenance to remove sediment build-up and replace damaged or over-mature vegetation. Further research is needed to establish guidelines for effective buffer width and structure, and such efforts should entail a coordinated, regional, multi-scale, multidisciplinary approach to evaluate buffer effectiveness and impacts. Direct measures in "real-world" systems and field validations of buffer-effectiveness models are crucial next steps in evaluating how grass buffers will impact the abiotic and biotic variables attributes that characterize small, isolated wetlands. ?? 2008 The Society of Wetland Scientists.

Wetlands↗

Not all water becomes wine: Sulfur inputs as an opportune tracer of hydrochemical losses from vineyards

California's widespread and economically important vineyards offer substantial opportunities to understand the interface between hydrology and biogeochemistry in agricultural soils. The common use of native sulfur (S) as a fumigant or soil additive provides a novel way to isotopically differentiate among sulfate (SO 4 2− ) pools, allowing the estimation of water and SO 4 2− budgets. The objectives of this study were (1) to characterize the near‐surface hydrological flow paths in a vineyard during irrigation and storm events and (2) to determine how those flow paths affect the fate and transport of SO 4 2− across seasons. Integrating hydrological theory with measurements of SO 4 2− concentration and sulfate‐S isotopic ratios (expressed as [SO 4 2− ] and δ 34 S, respectively) in inputs, soil water, and leachate provided a means of determining flow paths. Low [SO 4 2− ] and δ 34 S in leachate during 4‐h irrigation events reflect minimal engagement of the soil matrix, indicating that preferential flow was the dominant path for water in the near surface. In contrast, high [SO 4 2− ] and δ 34 S values during 8‐h irrigation and storm events reflect near‐complete engagement of the soil matrix, indicating that lateral flow was the dominant pathway. Because hydrologic response and SO 4 2− mobility are tightly coupled in these soils, the magnitude of water fluxes through the near surface controls S cycling both on and off site. These results indicate that preferential flow is an important loss pathway to consider in managing both water resources and water quality (reactive elements) in vineyard land use systems.

Water Resources Research↗

Ground Water Atlas of the United States: Segment 5, Arkansas, Louisiana, Mississippi

The States of Arkansas, Louisiana, and Mississippi, which are located adjacent to each other and north of the Gulf of Mexico, compose Segment 5 of this Atlas. The three-State area encompasses an area of nearly 149,000 square miles. These States are drained by numerous rivers and streams, such as the Atchafalaya, the Teche, the Vermilion, the Calcasieu, the Mermentau, the Sabine, the Tombigbee, the Pascagoula, the Wolf, and the Pearl Rivers, that drain directly to the Gulf of Mexico. The Yazoo, the Big Black, the Arkansas, the St. Francis, the Red, and the White Rivers are tributaries of the Mississippi River, which is the largest of the rivers that drain the three States. Although surface water is the largest source of freshwater to public supply, domestic and commercial, industrial, mining, thermoelectric power and agricultural users, ground water also is important and accounts for 38 percent of total water use in Arkansas, Louisiana, and Mississippi. Precipitation is the ultimate source of water that recharges the ma-jor aquifers in Segment 5. Average annual rainfall (1951-80) amounts range from about 40 to about 68 inches (fig. 1). Temporal (seasonal) and spatial variations in precipitation are evident in the three-State area. Average annual rainfall is greatest (60 inches per year or more) in southern Louisiana and southern Mississippi and diminishes in Arkansas and in northwestern Louisiana. Precipitation is greatest during January and May in Arkansas. May to September represent the wettest months in southeastern Louisiana and southern Mississippi. March and April are the wettest months in northern Mississippi. Average annual (1951-80) runoff ranges from less than 12 inches in western Louisiana and northwestern Arkansas to more than 20 inches in southern and northern Mississippi and in central and western Arkansas (fig. 2). Comparison of precipitation and runoff maps shows that less than one-half of the annual precipitation leaves the area as stream runoff. Much of the water that does not exit Segment 5 as runoff is returned to the atmosphere by evapotranspiration, which is the combination of transpiration by vegetation and evaporation from marshes, swamps, lakes and streams. A small amount of water recharges aquifers that are either exposed or buried to shallow depths, and an even smaller amount percolates downward and enters the deep flow system.

Arkansas, Louisiana, Mississippi↗

Comparison of riparian plant communities under four land management systems in southwestern Wisconsin

Riparian plant community composition is influenced by moisture, erosion, original native plant communities, and current and past land use. This study compared riparian plant communities under four types of management: woody buffer strip, grassy buffer strip, rotational grazing, and continuous grazing. Study sites were located along spring-fed streams in the unglaciated region of southwestern Wisconsin, USA. At each site, plant community surveys were conducted using a point transect method. Among the treatments, woody buffer strips, rotationally grazed and continuously grazed riparian areas had greater plant species richness than grassy buffer strips, and woody buffer strips had the greatest native plant species richness. Reed canary grass (Phalaris arundinacea L.) was prevalent in grassy buffer strips (44% of all observations), common in woody buffer strips (15%), and rare in sites that were rotationally or continuously grazed (3 and 5%, respectively). Pasture sites had greater proportions of native grasses and grass relatives and moderate levels of overall native species richness. Considered a water quality best management practice, well-managed rotational grazing may be a reasonable alternative to buffer strips which can contribute to protection and enhancement of native vegetation biodiversity. ?? 2002 Elsevier Science B.V. All rights reserved.

Agriculture, Ecosystems and Environment↗

Impacts of climate change on ecosystem services

Key Findings By 2050, climate change will triple the fraction of counties in the U.S. that are at high or extremely high risk of outstripping their water supplies (from 10 percent to 32 percent). The most at risk areas in the U.S. are the West, Southwest and Great Plains regions. Regulation of drinking water quality will be strained as high rainfall and river discharge conditions may lead to higher levels of nitrogen in rivers and greater risk of waterborne disease outbreaks. Climate change will have uneven effects on timber production across the U.S. Recent increases in tree mortality due to disease and pests, and the intensity of fires and area burned will continue to destroy productive forests. On the other hand, in some regions climate change is expected to boost overall forest productivity due to longer growing seasons. There is a better than 50 percent chance that climate change will overwhelm the ability of natural systems to mitigate the harm to people resulting from extreme weather events (such as heat waves, heavy rains, and drought). Vulnerability of people and property in coastal areas is highly likely to increase dramatically – due to the effects of sea-level rise, storm surge, and the loss of habitats that provide protection from flooding and erosion. The areas at greatest risk to coastal hazards in the U.S. are the Atlantic and Gulf coasts. The human communities most vulnerable to climate-related increases in coastal hazards are the elderly and the poor who are less able to respond quickly before and during hazards and to respond over the long term through relocation. Changes in abundance and ranges of commercially important marine fish are highly likely to result in loss of some local fisheries, and increases in value for others if fishing communities and management practices can adapt. In recreation and tourism, the greatest negative climate impacts will continue to be felt in winter sports and beach recreation (due to coastal erosion). Other forms of recreation are highly likely to increase due to better weather, leading to a redistribution of the industry and its economic impacts, with visitors and tourism dollars shifting away from some communities in favor of others. Supporting, regulating, and provisioning ecosystem services all contribute to food security in the United States, and the fate of the nation’s food production are very likely to depend on the interplay of these services and how the agriculture and fishery sectors respond to climate stresses.

Book chapter↗

Occurrence and fate of pesticides in four contrasting agricultural settings in the United States

Occurrence and fate of 45 pesticides and 40 pesticide degradates were investigated in four contrasting agricultural settings—in Maryland, Nebraska, California, and Washington. Primary crops included corn at all sites, soybeans in Maryland, orchards in California and Washington, and vineyards in Washington. Pesticides and pesticide degradates detected in water samples from all four areas were predominantly from two classes of herbicides—triazines and chloroacetanilides; insecticides and fungicides were not present in the shallow ground water. In most samples, pesticide degradates greatly exceeded the concentrations of parent pesticide. In samples from Nebraska, the parent pesticide atrazine [6-chloro- N -ethyl- N ′-(1-methylethyl)-1,3,5-triazine-2,4-diamine] was about the same concentration as the degradate, but in samples from Maryland and California atrazine concentrations were substantially smaller than its degradate. Simazine [6-chloro- N,N′ -diethyl-1,3,5-triazine-2,4-diamine], the second most detected triazine, was detected in ground water from Maryland, California, and Washington. Metolachlor [2-chloro- N -(2-ethyl-6-methylphenyl)- N -(2-methoxy-1-methylethyl)acetamide] rarely was detected without its degradates, and when they were detected in the same sample metolachlor always had smaller concentrations. The Root-Zone Water-Quality Model was used to examine the occurrence and fate of metolachlor at the Maryland site. Simulations accurately predicted which metolachlor degradate would be predominant in the unsaturated zone. In analyses of relations among redox indicators and pesticide variance, apparent age, concentrations of dissolved oxygen, and excess nitrogen gas (from denitrification) were important indicators of the presence and concentration of pesticides in these ground water systems.

California, Maryland, Nebraska, Washington↗

Social-value maps for Arapaho, Roosevelt, Medicine Bow, Routt, and White River National Forests, Colorado and Wyoming

Executive Summary The continued pressures of population growth on the life-sustaining, economic, and cultural ecosystem services provided by our national forests, particularly those located near rapidly growing urban areas, present ongoing challenges to forest managers. Achieving an effective assessment of these ecosystem services includes a proper accounting of the ecological, economic, and social values attributable to them. However, assessments of ecosystem goods and services notably lack information describing the spatial distribution and relative intensity of social values—the perceived, nonmarket values derived particularly from cultural ecosystem services. A geographic information system (GIS) tool developed to fill this need, Social Values for Ecosystem Services (SolVES; http://solves.cr.usgs.gov ), now provides the capability to generate social-value maps at a range of spatial scales. This report presents some of the methods behind SolVES, procedures needed to apply the tool, the first formal map products resulting from its application at a regional scale, and a discussion of the management implications associated with this type of information. In this study, we use SolVES to identify the location and relative intensity of social values as derived from survey responses gathered from residents living in counties adjacent to Arapaho, Roosevelt, Medicine Bow, Routt, and White River National Forests. The results, presented as a series of social-value maps, represent the first publicly available spatial data on social-value intensity for the southern Rocky Mountain region. Our analysis identified high-value areas for social values including aesthetic, biodiversity, and life sustaining within wilderness areas. Other values, like recreation, show high-value areas both within wilderness and throughout the general forest areas, which can be attributed to people using the forests for a diverse set of recreational activities. The economic social-value type was lower within wilderness areas, which was an expected outcome because of the restrictions inside wilderness areas that preclude resource extraction, development, and motorized or mechanized recreation. Providing spatially explicit social-value information collected from residents in counties adjacent to these national forests can assist in facilitating the U.S. Department of Agriculture Forest Service’s Multiple-Use Sustained-Yield Act of 1960 (16 U.S.C. 528) note and the 2012 Forest Service Planning Rule (36 CFR Part 219), which encourage public participation in planning and management. By making these maps available to the public, we hope to encourage exploration of potential uses of these data for resource management and planning.

Colorado, Wyoming↗

Periphyton biomass and community compositions as indicators of water quality in the Lower Grand River hydrologic unit, Missouri and Iowa, 2011–18

Biological communities, including periphyton, are continuously affected by chemical, physical, and other biological factors, and the health of these communities can reflect the overall health of the aquatic system. A diverse community is more robust, and communities with lower richness and evenness often indicate a degraded community dominated by few taxa tolerant to the degraded conditions, which makes the community more susceptible to ecological changes. Water-quality nutrient samples were collected at sites in the Lower Grand River during 2010 through 2018 and periphyton sample collections began in 2011 to describe the periphyton community and overall ecological health. Nutrient sample concentrations were generally elevated at these sites, which can lead to eutrophication, excessive plant and algae growth, drinking-water taste and odor problems, low dissolved-oxygen concentrations, and harmful algal blooms. Concentrations of total nitrogen were greater than acceptable as described by the U.S. Environmental Protection Agency, and total phosphorus concentrations were greater than reference concentrations. Periphyton communities were dominated by taxa that are tolerant to or indicative of elevated nutrient concentrations; and nuisance algae, or harmful algal bloom producers, were identified at all sites, except one. The presence of these producers indicates that harmful algal blooms may have high potential during optimal conditions at these sites. Chlorophyll concentrations that exceed 100 milligrams per square meter are considered nuisance and were determined in 11 percent of the samples and at every site during September 2012. Samples were collected during low-flow conditions when nutrient concentrations are generally lower than during high-flow and runoff conditions. Elevated nutrient concentrations during low-flow conditions indicate nutrient concentrations are likely elevated throughout most of the year. Agriculture is the primary land use within the Lower Grand River and is likely a primary source of nutrients and sediments. Conservation practices intended to reduce nutrient loss from agriculture fields have increased because of the Mississippi River Basin Healthy Watersheds Initiative and will potentially increase the ecological, chemical, and physical health of these waterways.

Iowa, Missouri↗

Potentiometric surface, 2013, and water-level differences, 1991-2013, of the Carrizo-Wilcox aquifer in northwest Louisiana

The Carrizo-Wilcox aquifer is the primary source of fresh groundwater for public supply as well as industrial, agricultural, and domestic uses in several parishes in northwestern Louisiana, including Bienville, Bossier, Caddo, De Soto, Natchitoches, Red River, Sabine, and Webster. In 2010, about 19 million gallons per day (Mgal/d) were withdrawn from the Carrizo-Wilcox aquifer in Louisiana. This is an increase of over 6 Mgal/d from 1990 withdrawal amounts. The largest increase in withdrawals occurred in Caddo (3.79 Mgal/d) and De Soto Parishes (2.32 Mgal/d), whereas the largest decrease in withdrawals occurred in Natchitoches Parish (1.17 Mgal/d). Groundwater withdrawals from the Carrizo-Wilcox aquifer have caused water-level declines throughout much of the aquifer in the study area. Additional knowledge about the effects of withdrawals on water levels and flow directions in the Carrizo-Wilcox aquifer are needed to assess current conditions in the aquifer. In 2012, the U.S. Geological Survey (USGS) in cooperation with the Louisiana Department of Natural Resources began a study to document current water levels and water-level changes in selected aquifers. This report presents data and maps that illustrate the potentiometric surface of the Carrizo-Wilcox aquifer during March–May 2013 and water-level differences from 1991 to 2013. The potentiometric surface map can be used for determining the direction of groundwater flow, hydraulic gradients, and effects of withdrawals on the groundwater resource. The rate of groundwater movement also can be estimated from the gradient when the hydraulic conductivity is applied. Water-level data collected for this study are stored in the USGS National Water Information System (NWIS) ( http://waterdata.usgs.gov/nwis ) and are on file at the USGS office in Baton Rouge, La.

Louisiana↗

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia— A summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

North Carolina, Virginia↗

Emission of pesticides into the air

During and after the application of a pesticide in agriculture, a substantial fraction of the dosage may enter the atmosphere and be transported over varying distances downwind of the target. The rate and extent of the emission during application, predominantly as spray particle drift, depends primarily on the application method (equipment and technique), the formulation and environmental conditions, whereas the emission after application depends primarily on the properties of the pesticide, soils, crops and environmental conditions. The fraction of the dosage that misses the target area may be high in some cases and more experimental data on this loss term are needed for various application types and weather conditions. Such data are necessary to test spray drift models, and for further model development and verification as well. Following application, the emission of soil fumigants and soil incorporated pesticides into the air can be measured and computed with reasonable accuracy, but further model development is needed to improve the reliability of the model predictions. For soil surface applied pesticides reliable measurement methods are available, but there is not yet a reliable model. Further model development is required which must be verified by field experiments. Few data are available on pesticide volatilization from plants and more field experiments are also needed to study the fate processes on the plants. Once this information is available, a model needs to be developed to predict the volatilization of pesticides from plants, which, again, should be verified with field measurements. For regional emission estimates, a link between data on the temporal and spatial pesticide use and a geographical information system for crops and soils with their characteristics is needed.

Conference Paper↗

Isotopic analysis of N and O in nitrite and nitrate by sequential selective bacterial reduction to N2O

Nitrite is an important intermediate species in the biogeochemical cycling of nitrogen, but its role in natural aquatic systems is poorly understood. Isotopic data can be used to study the sources and transformations of NO 2 - in the environment, but methods for independent isotopic analyses of NO 2 - in the presence of other N species are still new and evolving. This study demonstrates that isotopic analyses of N and O in NO 2 - can be done by treating whole freshwater or saltwater samples with the denitrifying bacterium Stenotrophomonas nitritireducens , which selectively reduces NO 2 - to N 2 O for isotope ratio mass spectrometry. When calibrated with solutions containing NO 2 - with known isotopic compositions determined independently, reproducible δ 15 N and δ 18 O values were obtained at both natural-abundance levels (±0.2−0.5‰ for δ 15 N and ±0.4−1.0‰ for δ 18 O) and moderately enriched 15 N tracer levels (±20−50‰ for δ 15 N near 5000‰) for 5−20 nmol of NO 2 - (1−20 μmol/L in 1−5 mL aliquots). This method is highly selective for NO 2 - and was used for mixed samples containing both NO 2 - and NO 3 - with little or no measurable cross-contamination. In addition, mixed samples that were analyzed with S. nitritireducens were treated subsequently with Pseudomonas aureofaciens to reduce the NO 3 - in the absence of NO 2 - , providing isotopic analyses of NO 2 - and NO 3 - separately in the same aliquot. Sequential bacterial reduction methods like this one should be useful for a variety of isotopic studies aimed at understanding nitrogen cycling in aquatic environments. A test of these methods in an agricultural watershed in Indiana provides isotopic evidence for both nitrification and denitrification as sources of NO 2 - in a small stream.

Indiana↗

Pesticide concentrations in multiple physical and biological stream matrices are impacted by a bioenergy production facility receiving pesticide coated corn seeds

Insecticide and fungicide seed coatings have become prevalent in conventional agriculture in recent decades. From 2015 to 2021, the AltEn bioenergy plant (Mead, Nebraska, USA) generated ethanol from almost 100% unused/expired treated corn seeds. This use of these seeds for ethanol production resulted in the accumulation of large amounts of contaminated wastewater and solid residue, a portion of which was applied to surrounding farmland. To better understand the potential long-term environmental effects from the processing of treated seeds at this facility, five nearby stream sites were sampled in 2022 after the closure of the plant; these included two sites directly impacted by AltEn, one upstream, and two downstream of the impacted sites. Water and sediment were collected in March through July, and algae and fish samples were collected in July for chemical analysis. Overall, 60 pesticide compounds (parents and transformation products) were detected in one or more matrices, including 23 fungicides, 20 insecticides, 16 herbicides, and 1 bacterial growth inhibitor. Pesticide results (maximum detection frequency, maximum concentration) varied substantially by environmental compartment: water (100% multiple pesticides; 4,600 ng L −1 thiamethoxam transformation product (NOA-407475)), algae (100% multiple pesticides, 190 ng g −1 atrazine), sediment (60% dithiopyr, 2.3 ng g −1 acetochlor) and fish (20% pyraclostrobin, 2.2 ng g −1 atrazine). Pesticides associated with treated corn seeds (e.g., insecticides clothianidin, thiamethoxam; fungicides fluoxastrobin, thiabendazole) were detected at significantly higher concentrations ( p < 0.05) in stream water from sites impacted by the AltEn facility compared to non-impacted sites. Study results indicate that pesticides associated with the AltEn facility continue to be a source of contaminants to aquatic systems after the plant’s closure in 2021.

Environmental Toxicology and Chemistry↗

The Landscape Data Commons: A system for standardizing, accessing, and applying large environmental datasets for agroecosystem research and management

Understanding where, when, and why agroecosystems are changing requires quality information about ecosystems that span land tenure, ecological processes, and spatial scales. Over the past two decades, land management agencies and research groups have adopted a suite of standardized methods for monitoring rangelands, which have been implemented at over 85,000 monitoring locations globally. However, the ability to use these data to understand agroecosystem dynamics and change across scales and across land ownership has been limited because, until now, these data have not been available in a harmonized, accessible format for analyses, modeling, and decision-support tools. We present the Landscape Data Commons, a cyberinfrastructure platform that harmonizes and aggregates standardized agroecosystem data, enables linkages to models, and facilitates analysis and interpretation of data within decision-support tools. The Landscape Data Commons provides a community platform for users to contribute data and develop next-generation tools to support agroecosystem management through the 21st century.

Agricultural & Environmental Letters↗

The role of reserves and anthropogenic elements for functional connectivity and resilience of ephemeral habitats

Ecological reserves provide important wildlife habitat in many landscapes, and the functional connectivity of reserves and other suitable habitat patches is crucial for the persistence and resilience of spatially structured populations. To maintain or increase connectivity at spatial scales larger than individual patches, conservation actions may focus on creating and maintaining reserves and/or influencing management on non-reserves. Using a graph-theoretic approach, we assessed the functional connectivity and spatial distribution of wetlands in the Rainwater Basin of Nebraska, USA, an intensively cultivated agricultural matrix, at four assumed, but ecologically realistic, anuran dispersal distances. We compared connectivity in the current landscape to the historical landscape and putative future landscapes, and evaluated the importance of individual and aggregated reserve and non-reserve wetlands for maintaining connectivity. Connectivity was greatest in the historical landscape, where wetlands were also the most densely distributed. The construction of irrigation reuse pits for water storage has maintained connectivity in the current landscape by replacing destroyed wetlands, but these pits likely provide suboptimal habitat. Also, because there are fewer total wetlands (i.e., wetlands and irrigation reuse pits) in the current landscape than the historical landscape, and because the distribution of current wetlands is less clustered than that of historical wetlands, larger and longer dispersing, sometimes nonnative species may be favored over smaller, shorter dispersing species of conservation concern. Because of their relatively low number, wetland reserves do not affect connectivity as greatly as non-reserve wetlands or irrigation reuse pits; however, they likely provide the highest quality anuran habitat. To improve future levels of resilience in this wetland habitat network, management could focus on continuing to improve the conservation status of non-reserve wetlands, restoring wetlands at spatial scales that promote movements of shorter dispersing species, and further scrutinizing irrigation reuse pit removal by considering effects on functional connectivity for anurans, an emblematic and threatened group of organisms. However, broader conservation plans will need to give consideration to other wetland-dependent species, incorporate invasive species management, and address additional challenges arising from global change in social-ecological systems like the Rainwater Basin.

Nebraska↗

Climatic and topographical factors affecting the vegetative carbon stock of rangelands in arid and semiarid regions of China

Rangeland systems play an important role in ecological stabilization and the terrestrial carbon cycle in arid and semiarid regions. However, little is known about the vegetative carbon dynamics and climatic and topographical factors that affect vegetative carbon stock in these rangelands. Our goal was to assess vegetative carbon stock by examining meteorological data in conjunction with NDVI (normalized difference vegetation index) time series datasets from 2001–2012. An improved CASA (Carnegie Ames Stanford Approach) model was then applied to simulate the spatiotemporal dynamic variation of vegetative carbon stock, and analyze its response to climatic and topographical factors. We estimated the vegetative carbon stock of rangeland in Gansu province, China to be 4.4× 1014 gC, increasing linearly at an annual rate of 9.8×10 11 gC. The mean vegetative carbon density of the whole rangeland was 136.5 gC m -2 . Vegetative carbon density and total carbon varied temporally and spatially and were highly associated with temperature, precipitation and solar radiation. Vegetative carbon density reached the maximal value on elevation at 2500–3500 m, a slope of >30°and easterly aspect. The effect of precipitation, temperature and solar radiation on the vegetative carbon density of five rangeland types (desert and salinized meadow, steppe, alpine meadow, shrub and tussock, and marginal grassland in the forest) depends on the acquired quantity of water and heat for rangeland plants at all spatial scales. The results of this study provide new evidence for explaining spatiotemporal heterogeneity in vegetative carbon dynamics and responses to global change for rangeland vegetative carbon stock, and offer a theoretical and practical basis for grassland agriculture management in arid and semiarid regions.

Gansu↗

Metamodeling and mapping of nitrate flux in the unsaturated zone and groundwater, Wisconsin, USA

Nitrate contamination of groundwater in agricultural areas poses a major challenge to the sustainability of water resources. Aquifer vulnerability models are useful tools that can help resource managers identify areas of concern, but quantifying nitrogen (N) inputs in such models is challenging, especially at large spatial scales. We sought to improve regional nitrate (NO 3 − ) input functions by characterizing unsaturated zone NO 3 − transport to groundwater through use of surrogate, machine-learning metamodels of a process-based N flux model. The metamodels used boosted regression trees (BRTs) to relate mappable landscape variables to parameters and outputs of a previous “vertical flux method” (VFM) applied at sampled wells in the Fox, Wolf, and Peshtigo (FWP) river basins in northeastern Wisconsin. In this context, the metamodels upscaled the VFM results throughout the region, and the VFM parameters and outputs are the metamodel response variables. The study area encompassed the domain of a detailed numerical model that provided additional predictor variables, including groundwater recharge, to the metamodels. We used a statistical learning framework to test a range of model complexities to identify suitable hyperparameters of the six BRT metamodels corresponding to each response variable of interest: NO 3 − source concentration factor (which determines the local NO 3 − input concentration); unsaturated zone travel time; NO 3 − concentration at the water table in 1980, 2000, and 2020 (three separate metamodels); and NO 3 − “extinction depth”, the eventual steady state depth of the NO 3 − front. The final metamodels were trained to 129 wells within the active numerical flow model area, and considered 58 mappable predictor variables compiled in a geographic information system (GIS). These metamodels had training and cross-validation testing R 2 values of 0.52 – 0.86 and 0.22 – 0.38, respectively, and predictions were compiled as maps of the above response variables. Testing performance was reasonable, considering that we limited the metamodel predictor variables to mappable factors as opposed to using all available VFM input variables. Relationships between metamodel predictor variables and mapped outputs were generally consistent with expectations, e.g. with greater source concentrations and NO 3 − at the groundwater table in areas of intensive crop use and well drained soils. Shorter unsaturated zone travel times in poorly drained areas likely indicated preferential flow through clay soils, and a tendency for fine grained deposits to collocate with areas of shallower water table. Numerical estimates of groundwater recharge were important in the metamodels and may have been a proxy for N input and redox conditions in the northern FWP, which had shallow predicted NO 3 − extinction depth. The metamodel results provide proof-of-concept for regional characterization of unsaturated zone NO 3 − transport processes in a statistical framework based on readily mappable GIS input variables.

Wisconsin↗

Hydrogeology and water quality of the upper Floridan aquifer, western Albany area, Georgia

Geologic, hydrologic, and water-quality data were collected to refine the hydrogeologic framework conceptual model of the Upper Floridan aquifer, and to qualitatively evaluate the potential of human activities to impact water quality in the Upper Floridan aquifer in the western Albany area, Georgia. Ground-water age dating was conducted by using chlorofluorocarbons (CFC) and tritium concentrations in water from the Upper Floridan aquifer to determine if recharge and possible contaminant migration to the aquifer is recent or occurred prior to the introduction of CFCs and tritium in the early 1950's into the global natural water system. Data were collected from core holes and wells installed during this study and previously existing wells in the Albany area. Hydrogeologic data collected during this study compare well to the regional hydrogeologic conceptual model developed during previous studies. However, the greater data density available from this study shows the dynamic and local variability in the hydrologic character of the Upper Floridan aquifer in more detail. The occurrence of sediment sizes from clay to gravel in the overburden, the absence of overburden because of erosion or sinkhole collapse, and large areas lacking surface drainage west of the Flint River provide potential areas for recharge and contaminant migration from the surface to the Upper Floridan aquifer throughout the study area. Ground-water ages generally range from 9 to 34 years, indicating that recharge consisting of 'modern' water (post early-1950's) is present in the aquifer. Ground-water ages and hydraulic heads in the Upper Floridan aquifer have an irregular distribution, indicating that localized areas of recharge to the aquifer are present in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area.

Georgia↗