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At least 1,621 records · Page 90Linked to original sources
USGS2026

Field methods, quality-assurance, and data management plan for water-quality activities and water-level measurements, Idaho National Laboratory, Idaho

Introduction Water-quality activities and water-level measurements conducted by the U.S. Geological Survey (USGS) Idaho National Laboratory (INL) Project Office coincide with the USGS mission of evaluating the quantity and quality of the Nation’s water resources. The activities are conducted in cooperation with the U.S. Department of Energy’s (DOE) Idaho Operations Office. Results of water-quality and hydraulic head research efforts are presented in various USGS and scientific journal publications (refer to Fisher, 2022). These data are stored internally in the Aquarius Time Series and Aquarius Samples databases and are publicly accessible through National Water Quality Monitoring Council (2025) and U.S. Geological Survey (2025). Data collected from our studies are used by researchers, Federal and State agencies, water management and regulatory organizations, as well as the public. This quality assurance plan (QAP) describes the methods and processes for field methods, data collection, data management, data auditing, and equipment management for both the water-quality and water-level programs at the USGS INL Project Office (hereto referred to as INL Project Office). A comprehensive quality assurance (QA) plan ensures that the processes defined in this document will guide the program staff to collect and publish reliable, useful, and defensible data products for stakeholders. This QAP supersedes previous versions of this document and is intended to complement the Quality Assurance and Data Management (QADM) Plan for the Idaho Water Science Center (IDWSC; Christopher Mebane and Lauren Zinsser, written commun., 2024).

Idaho↗
USGS2014

Transformation products and human metabolites of triclocarban and tricllosan in sewage sludge across the United States

Removal of triclocarban (TCC) and triclosan (TCS) from wastewater is a function of adsorption, abiotic degradation, and microbial mineralization or transformation, reactions that are not currently controlled or optimized in the pollution control infrastructure of standard wastewater treatment. Here, we report on the levels of eight transformation products, human metabolites, and manufacturing byproducts of TCC and TCS in raw and treated sewage sludge. Two sample sets were studied: samples collected once from 14 wastewater treatment plants (WWTPs) representing nine states, and multiple samples collected from one WWTP monitored for 12 months. Time-course analysis of significant mass fluxes (α = 0.01) indicate that transformation of TCC (dechlorination) and TCS (methylation) occurred during sewage conveyance and treatment. Strong linear correlations were found between TCC and the human metabolite 2′-hydroxy-TCC ( r = 0.84), and between the TCC-dechlorination products dichlorocarbanilide (DCC) and monochlorocarbanilide ( r = 0.99). Mass ratios of DCC-to-TCC and of methyl-triclosan (MeTCS)-to-TCS, serving as indicators of transformation activity, revealed that transformation was widespread under different treatment regimes across the WWTPs sampled, though the degree of transformation varied significantly among study sites (α = 0.01). The analysis of sludge sampled before and after different unit operation steps (i.e., anaerobic digestion, sludge heat treatment, and sludge drying) yielded insights into the extent and location of TCC and TCS transformation. Results showed anaerobic digestion to be important for MeTCS transformation (37–74%), whereas its contribution to partial TCC dechlorination was limited (0.4–2.1%). This longitudinal and nationwide survey is the first to report the occurrence of transformation products, human metabolites, and manufacturing byproducts of TCC and TCS in sewage sludge.

Environmental Science & Technology↗
USGS2022

Evolving magma temperature and volatile contents over the 2008–2018 summit eruption of Kīlauea Volcano

Magma rheology and volatile contents exert primary and highly nonlinear controls on volcanic activity. Subtle changes in these magma properties can modulate eruption style and hazards, making in situ inference of their temporal evolution vital for volcano monitoring. Here, we study thousands of impulsive magma oscillations within the shallow conduit and lava lake of Kīlauea Volcano, Hawai‘i, USA, over the 2008–2018 summit eruptive sequence, encoded by “very-long-period” seismic events and ground deformation. Inversion of these data with a petrologically informed model of magma dynamics reveals significant variation in temperature and highly disequilibrium volatile contents over days to years, within a transport network that evolved over the eruption. Our results suggest a framework for inferring subsurface magma dynamics associated with prolonged eruptions in near real time that synthesizes petrologic and geophysical volcano monitoring approaches.

Hawaii↗
USGS2020

Stony coral tissue loss disease in Florida is associated with disruption of host–zooxanthellae physiology

Samples from eight species of corals ( Colpophyllia natans , Dendrogyra cylindrus , Diploria labyrinthiformis , Meandrina meandrites , Montastraea cavernosa , Orbicella faveolata, Pseudodiploria strigosa , and Siderastrea siderea ) that exhibited gross clinical signs of acute, subacute, or chronic tissue loss attributed to stony coral tissue loss disease (SCTLD) were collected from the Florida Reef Tract during 2016–2018 and examined histopathologically. The hallmark microscopic lesion seen in all eight species was focal to multifocal lytic necrosis (LN) originating in the gastrodermis of the basal body wall (BBW) and extending to the calicodermis, with more advanced lesions involving the surface body wall. This was accompanied by other degenerative changes in host cells such as mucocyte hypertrophy, degradation and fragmentation of gastrodermal architecture, and disintegration of the mesoglea. Zooxanthellae manifested various changes including necrosis (cytoplasmic hypereosinophilia, pyknosis); peripheral nuclear chromatin condensation; cytoplasmic vacuolation accompanied by deformation, swelling, or atrophy; swollen accumulation bodies; prominent pyrenoids; and degraded chloroplasts. Polyhedral intracytoplasmic eosinophilic periodic acid–Schiff-positive crystalline inclusion bodies (∼1–10 μm in length) were seen only in M. cavernosa and P. strigosa BBW gastrodermis in or adjacent to active lesions and some unaffected areas (without surface lesions) of diseased colonies. Coccoidlike or coccobacilloidlike structures (Gram-neutral) reminiscent of microorganisms were occasionally associated with LN lesions or seen in apparently healthy tissue of diseased colonies along with various parasites and other bacteria all considered likely secondary colonizers. Of the 82 samples showing gross lesions of SCTLD, 71 (87%) were confirmed histologically to have LN. Collectively, pathology indicates that SCTLD is the result of a disruption of host–symbiont physiology with lesions originating in the BBW leading to detachment and sloughing of tissues from the skeleton. Future investigations could focus on identifying the cause and pathogenesis of this process.

Florida↗
USGS2001

USGS Mineral Resources Program; national maps and datasets for research and land planning

The U.S. Geological Survey, the Nation’s leader in producing and maintaining earth science data, serves as an advisor to Congress, the Department of the Interior, and many other Federal and State agencies. Nationwide datasets that are easily available and of high quality are critical for addressing a wide range of land-planning, resource, and environmental issues. Four types of digital databases (geological, geophysical, geochemical, and mineral occurrence) are being compiled and upgraded by the Mineral Resources Program on regional and national scales to meet these needs. Where existing data are incomplete, new data are being collected to ensure national coverage. Maps and analyses produced from these databases provide basic information essential for mineral resource assessments and environmental studies, as well as fundamental information for regional and national land-use studies. Maps and analyses produced from the databases are instrumental to ongoing basic research, such as the identification of mineral deposit origins, determination of regional background values of chemical elements with known environmental impact, and study of the relationships between toxic elements or mining practices to human health. As datasets are completed or revised, the information is made available through a variety of media, including the Internet. Much of the available information is the result of cooperative activities with State and other Federal agencies. The upgraded Mineral Resources Program datasets make geologic, geophysical, geochemical, and mineral occurrence information at the state, regional, and national scales available to members of Congress, State and Federal government agencies, researchers in academia, and the general public. The status of the Mineral Resources Program datasets is outlined below.

Fact Sheet↗
USGS2008

Monitoring lingering oil from the Exxon Valdez spill on Gulf of Alaska armored beaches and mussel beds sixteen years post-spill

Final Rept. ; Prepared in Cooperation With Alaska Univ., Fairbanks. Inst. of Arctic Biology. Sponsored By National Marine Fisheries Service, Juneau, Ak. Alaska Fisheries Science Center. ; Stranded Exxon Valdez Oil Has Persisted for 16 Years At Boulder- Armored Beach Sites Along National Park Coastlines Bordering the Gulf of Alaska . These Sites Are Up to 640 Km From the Spill Origin and Were Contaminated By Oil Mousse, a Viscous Water-in- Oil Emulsion. Although Surface Oil Has Continued to Decline, Subsurface Oiling Persists in Patches. Especially Striking Is the General Lack of Weathering of Stranded Oil on Armored Beaches Over the Last 16 Years . At Three of the Four Sites Where Oil Was Sampled in 2005, the Oil Was Compositionally Similar to 11-Day Old Exxon Valdez Oil , Even After 16 Years . The Formation of Mousse Allowed Less-Weathered Oil to Be Transported Long Distances. The Sequestration of the Oil Beneath a Boulder Armor, Coupled With the Stability of the Boulder Armoring (Investigated By Examining Movement of Marked Boulders), Had Contributed to the Lengthy Persistence of This Stranded Oil. Opportunistic Sampling of Several Previously Studied Oiled Mussel Beds Indicates Continued Contamination of At Least One of the Sites By Not Very Weathered Exxon Valdez Oil. Long-Term Persistence of Oil in These Habitats Should Cause Reconsideration of Response Activities After Spills, and May Influence the Environmental Sensitivity Indices Applied to These Habitats.

Report↗
USGS1999

Preliminary study on the mode of occurrence of arsenic in high arsenic coals from southwest Guizhou Province

Coal samples from high arsenic coal areas have been analyzed by electron micropbe analyzer (EMPA), scanning electron microscopy with an energy dispersive X-ray analyzer (SEM-EDX), X-ray diffinction analysis (XRD), low temperature ashing (LTA), transmission electron microscopy (TEM), X-ray absorption fine structure (XAFS), instnunent neutron activation analysis (INAA) and wet chemical analysis. Although some As-bearing minerals such as pyrite, arsenopyrite, realgar (?), As-bearing sulfate, and As-bearing clays are found in the high arsenic coals, their contents do not account for the abundance of arsenic in the some coals. Analysis of the coal indicates that arsenic exists mainly in the form of A s 5+ and A s 3+ , combined with compounds in the organic matrix. The occurrence of such exceptionally high arsenic contents in coal and the fact that the arsenic is dominantly organically associated are unique observations. The modes of occurrence of arsenic in high As-coals are discussed.

Science in China, Series D: Earth Sciences↗
USGS2004

The geochemistry of Seine River Basin particulate matter: Distribution of an integrated metal pollution index

Spatial analysis (1994-2001) and temporal trends (1980-2000) for particulate-associated metals at key stations in the Seine River Basin have been determined using a new metal pollution index (MPI). The MPI is based on the concentrations of Cd, Cu, Hg, Pb and Zn, normalized to calculated background levels estimated for each particulate matter samples for four fractions (clays and other aluminosilicates, carbonates, organic matter, and quartz). Background levels ascribed to each fraction were determined from a specific set of samples collected from relatively pristine areas in the upper Seine basin and validated on prehistoric samples. The unitless MPI is designed to vary between 0 for pristine samples to 100 for the ones extremely impacted by human activities and to assess the trends of general metal contamination and its mapping. Throughout the Seine basin, MPI currently range from 1 to 40, but values exceeding 100 have been found in periurban streams and the Eure tributary. Based on the MPI spatial distribution, the Seine River Basin displays a wide range of anthropogenic impacts linked to variations in population density, stream order, wastewater discharges and industrial activities. Correlations between the MPI and other trace elements indicate that anthropogenic impacts also strongly affect the concentrations of Ag, Sb, and P, marginally affect the concentrations of Ba, Ni, and Cr, and appear to have little effect on the concentrations of Li, Be, V, Co, and the major elements. Temporal MPI trends can also be reconstituted from past regulatory surveys. In the early 1980s, MPI were 2-5 times higher than nowadays at most locations, particularly downstream of Greater Paris where it reached levels as high as 250 (now 40), a value characteristic of present Paris urban sewage. The exceptional contamination of the Seine basin is gradually improving over the last 20 years but remains very high. ?? 2004 Elsevier B.V. All rights reserved.

Science of the Total Environment↗
USGS1997

Kinetics of the coesite to quartz transformation

The survival of coesite in ultrahigh-pressure (UHP) rocks has important implications for the exhumation of subducted crustal rocks. We have conducted experiments to study the mechanism and rate of the coesite→quartz transformation using polycrystalline coesite aggregates, fabricated by devitrifying silica glass cylinders containing 2850 H/10 6 Si at 1000°C and 3.6 GPa for 24 h. Conditions were adjusted following synthesis to transform the samples at 700–1000°C at pressures 190–410 MPa below the quartz–coesite equilibrium boundary. Reaction proceeds via grain-boundary nucleation and interface-controlled growth, with characteristic reaction textures remarkably similar to those seen in natural UHP rocks. We infer that the experimental reaction mechanism is identical to that in nature, a prerequisite for reliable extrapolation of the rate data. Growth rates obtained by direct measurement differ by up to two orders of magnitude from those estimated by fitting a rate equation to the transformation–time data. Fitting the rates to Turnbull's equation for growth therefore yields two distinct sets of parameters with similar activation energies (242 or 269 kJ/mol) but significantly different pre-exponential constants. Extrapolation based on either set of growth rates suggests that coesite should not be preserved on geologic time scales if it reaches the quartz stability field at temperatures above 375–400°C. The survival of coesite has previously been linked to its inclusion in strong phases, such as garnet, that can sustain a high internal pressure during decompression. Other factors that may play a crucial role in preservation are low fluid availability — possibly even less than that of our nominally “dry” experiments — and the development of transformation stress, which inhibits nucleation and growth. These issues are discussed in the context of our experiments as well as recent observations from natural rocks.

Earth and Planetary Science Letters↗
USGS2021

Widespread use of the nitrification inhibitor nitrapyrin: Assessing benefits and costs to agriculture, ecosystems, and environmental health

Agricultural production and associated applications of nitrogen (N) fertilizers have increased dramatically in the last century, and current projections to 2050 show that demands will continue to increase as the human population grows. Applied in both organic and inorganic fertilizer forms, N is an essential nutrient in crop productivity. Increased fertilizer applications, however, create the potential for more N loss before plant uptake. One strategy for minimizing N loss is the use of enhanced efficiency fertilizers, fortified with a nitrification inhibitor, such as nitrapyrin. In soils and water, nitrapyrin inhibits the activity of ammonia monooxygenase, a microbial enzyme that catalyzes the first step of nitrification from ammonium to nitrite. Potential benefits of using nitrification inhibitors range from reduced nitrate leaching and nitrous oxide emissions to increased crop yield. The extent of these benefits, however, depends on environmental conditions and management practices. Thus, such benefits are not always realized. Additionally, nitrapyrin has been shown to transport off-field, and it is unknown what effects environmental nitrapyrin could have on nontarget organisms and the ecological nitrogen cycle. Here, we review the agronomic and environmental benefits and costs of nitrapyrin use and present a series of research questions and considerations to be addressed with future nitrification inhibitor research.

Environmental Science and Technology↗
USGS2003

Organochlorine compounds in Lake Superior: Chiral polychlorinated biphenyls and biotransformation in the aquatic food web

The enantiomeric composition of seven chiral PCB congeners was measured in the Lake Superior aquatic food web sampled in 1998, to determine the extent of enantioselective biotransformation in aquatic biota. All chiral PCB congeners studied (CBs 91, 95, 136, 149, 174, 176, and 183) biomagnified in the Lake Superior aquatic food web, based on biomagnification and food web magnification factors greater than unity. PCB atropisomers were racemic in phytoplankton and zooplankton, suggesting no biotransformation potential toward PCBs for these low trophic level organisms. However, Diporeia and mysids had significantly nonracemic residues for most chiral congeners studied. This observation suggests that these macrozooplankton can stereoselectively metabolize chiral congeners. Alternatively, macrozooplankton obtained nonracemic residues from feeding on organic-rich suspended particles and sediments, which would imply that stereoselective microbial PCB biotransformation may be occurring in Lake Superior sediments at PCB concentrations far lower than that previously associated with such activity. Widely nonracemic PCB residues in forage fish (lake herring, rainbow smelt, and slimy sculpin) and lake trout suggest a combination of both in vivo biotransformation and uptake of nonracemic residues from prey for these species. Minimum biotransformation rates, calculated from enantiomer mass balances between predators and prey, suggest metabolic half-lives on the order of 8 yr for CB 136 in lake trout and 2.6 yr for CB 95 in sculpins. This result suggests that significant biotransformation may occur for metaboliz able PCB congeners over the lifespan of these biota. This study highlights the potential of chiral analysis to study biotransformation processes in food webs.

Environmental Science & Technology↗
USGS2007

Incidence of the enterococcal surface protein ( esp ) gene in human and animal fecal sources

The occurrence of the enterococcal surface protein ( esp ) gene in the opportunistic pathogens Enterococcus faecalis and E. faecium is well-documented in clinical research. Recently, the esp gene has been proposed as a marker of human pollution in environmental waters; however, information on its relative incidence in various human and animal fecal sources is limited. We have determined the occurrence of the esp gene in enterococci from human ( n = 64) and animal ( n = 233) fecal samples by polymerase chain reaction using two primer sets: one presumably specific for E. faecium ( esp fm ) and the other for both E. faecalis and E. faecium ( esp fs/fm ). We believe that this research is the first to explore the use of esp fs/fm for the detection of human waste in natural environmental settings. The incidence in human sources was 93.1% esp fm and 100% esp fs/fm in raw sewage influent; 30% for both esp fm and esp fs/fm in septic waste; and 0% esp fm and 80% esp fs/fm in active pit toilets. The overall occurrence of the gene in animal feces was 7.7% ( esp fs/fm ) and 4.7% ( esp fm ); animal types with positive results included dogs (9/43, all esp fm ), gulls (10/34, esp fs/fm ; 2/34, esp fm ), mice (3/22, all esp fs/fm ), and songbirds (5/55, all esp fs/fm ). The esp gene was not detected in cat (0/34), deer (0/4), goose (0/18), or raccoon (0/23) feces. The inconsistent occurrence, especially in septic and pit toilet sewage, suggests a low statistical power of discrimination between animal and human sources, which means a large number of replicates should be collected. Both esp fm and esp fs/fm were common in raw sewage, but neither one efficiently differentiated between animal and other human sources.

Environmental Science & Technology↗
USGS2025

Module 4: Basic biology of wetland animals

An assortment of animals inhabit wetlands, with many invertebrates, amphibians and reptiles, fishes, birds, and some mammals being wetland specialists. Wetlands provide ample water, food, and cover that benefits resident animals, but periodic high floods, frequent drying, and harsh water qualities (low-oxygen, acidic, saline) can stress wetland animals. Animals that rely on wetlands have developed numerous adaptations to cope with these stresses. The animal biodiversity in wetlands is particularly valued by people, from deep historical and cultural connections, to modern ecotourists and bird watchers who observe it and hunters and anglers who appreciate the consumptive resources they provide. Animals such as alligators and beavers create or physically-modify wetland environments; this activity is called ecosystem engineering and makes these animals among the most important organisms to wetland ecology. Wetlands are high in biodiversity and support rich communities of wetland invertebrates, are primary breeding habitats for most amphibians, and nearly all migratory birds rely on wetlands during some part of their annual cycle. The interactions of animals with plants (herbivory, cutting) and each other (predation) strongly shape wetland environments and affect nutrient cycling. Human impacts on wetlands can negatively affect many animals through habitat loss and degradation, resulting in many wetland amphibians, reptiles, and birds being listed as threatened and endangered species. Thus, wetland conservation is vital to conserve many animal species.

Wetland Science & Practice↗
USGS2018

Rayleigh and S wave tomography constraints on subduction termination and lithospheric foundering in central California

The crust and upper mantle structure of central California have been modified by subduction termination, growth of the San Andreas plate boundary fault system, and small-scale upper mantle convection since the early Miocene. Here we investigate the contributions of these processes to the creation of the Isabella Anomaly, which is a high seismic velocity volume in the upper mantle. There are two types of hypotheses for its origin. One is that it is the foundered mafic lower crust and mantle lithosphere of the southern Sierra Nevada batholith. The alternative suggests that it is a fossil slab connected to the Monterey microplate. A dense broadband seismic transect was deployed from the coast to the western Sierra Nevada to fill in the least sampled areas above the Isabella Anomaly, and regional-scale Rayleigh and S wave tomography are used to evaluate the two hypotheses. New shear velocity (Vs) tomography images a high-velocity anomaly beneath coastal California that is sub-horizontal at depths of ∼40–80 km. East of the San Andreas Fault a continuous extension of the high-velocity anomaly dips east and is located beneath the Sierra Nevada at ∼150–200 km depth. The western position of the Isabella Anomaly in the uppermost mantle is inconsistent with earlier interpretations that the Isabella Anomaly is connected to actively foundering foothills lower crust. Based on the new Vs images, we interpret that the Isabella Anomaly is not the dense destabilized root of the Sierra Nevada, but rather a remnant of Miocene subduction termination that is translating north beneath the central San Andreas Fault. Our results support the occurrence of localized lithospheric foundering beneath the high elevation eastern Sierra Nevada, where we find a lower crustal low Vs layer consistent with a small amount of partial melt. The high elevations relative to crust thickness and lower crustal low Vs zone are consistent with geological inferences that lithospheric foundering drove uplift and a ∼3–4 Ma pulse of basaltic magmatism.

Earth and Planetary Science Letters↗
USGS2008

High Resolution Imaging Science Experiment (HiRISE) observations of glacial and periglacial morphologies in the circum-Argyre Planitia highlands, Mars

The landscape of the Argyre Planitia and adjoining Charitum and Nereidum Montes in the southern hemisphere of Mars has been heavily modified since formation of the Argyre impact basin. This study examines morphologies in the Argyre region revealed in images acquired by the High Resolution Imaging Science Experiment (HiRISE) camera and discusses the implications for glacial and periglacial processes. Distinctive features such as large grooves, semicircular embayments in high topography, and streamlined hills are interpreted as glacially eroded grooves, cirques, and whalebacks or roche moutonnée, respectively. Large boulders scattered across the floor of a valley may be ground moraine deposited by ice ablation. Glacial interpretations are supported by the association of these features with other landforms typical of glaciated landscapes such as broad valleys with parabolic cross sections and stepped longitudinal profiles, lobate debris aprons interpreted as remnant debris covered glaciers or rock glaciers, and possible hanging valleys. Aligned boulders observed on slopes may also indicate glacial processes such as fluting. Alternatively, boulders aligned on slopes and organized in clumps and polygonal patterns on flatter surfaces may indicate periglacial processes, perhaps postglaciation, that form patterned ground. At least portions of the Argyre region appear to have been modified by processes of ice accumulation, glacial flow, erosion, sediment deposition, ice stagnation and ablation, and perhaps subsequent periglacial processes. The type of bedrock erosion apparent in images suggests that glaciers were, at times, wet based. The number of superposed craters is consistent with geologically recent glacial activity, but may be due to subsequent modification.

Journal of Geophysical Research E: Planets↗
USGS2025

Hybrid coral reef restoration can be a cost-effective nature-based solution to provide protection to vulnerable coastal populations

Coral reefs can mitigate flood damages by providing protection to tropical coastal communities whose populations are dense, growing fast, and have predominantly lower-middle income. This study provides the first fine-scale, regionally modeled valuations of how flood risk reductions associated with hybrid coral reef restoration could benefit people, property, and economic activity along Florida and Puerto Rico’s 1005 kilometers of reef-lined coasts. Restoration of up to 20% of the regions’ coral reefs could provide flood reduction benefits greater than costs. Reef habitats with the greatest benefits are shallow, nearshore, and fronting low-lying, vulnerable communities, which are often where reef impacts and loss are the greatest. Minorities, children, the elderly, and those below the poverty line could receive more than double the hazard risk reduction benefits of the overall population, demonstrating that reef restoration as a nature-based solution can have positive returns on investment economically and socially by providing protection to the most vulnerable people.

Florida↗
USGS1992

Submarine sedimentary features on a fjord delta front, Queen Inlet, Glacier Bay, Alaska

Side-scan sonar images provide a view of an actively changing delta front in a marine outwash fjord in Glacier Bay, Alaska. Numerous interconnected gullies and chute-like small channels form paths for the transport of sand and coarse silt from the braided glacial outwash streams on the delta plain to the sinuous turbidity-current channels incised into the fjord floor. These turbidity-current channels carry coarse sediment through the fjord and into the adjoining glacial trunk valley. Several sedimentary processes affect the development of this delta front: overflow plumes deposit fine sediment; sediment gravity flows result from episodic delivery of large loads of coarse sediment; and mass movement may be triggered by earthquakes and, more regularly, by spring-tidal drawdown or hydraulic loading.

Canadian Journal of Earth Sciences↗
USGS1990

Selenium speciation methods and application to soil saturation extracts from San Joaquin Valley, California

Methods to determine soluble concentrations of selenite, selenate, and organic Se were evaluated on saturation extracts of soil samples collected from three sites on the Panoche Creek alluvial fan in the western San Joaquin Valley, California. The methods were used in combination with hydride-generation atomic-absorption spectrometry for detection of Se, and included a selective chemical-digestion method and three chromatographic methods using XAD-8 resin, Sep-Pak C 18 cartridge, and a combination of XAD-8 resin and activated charcoal. The chromatography methods isolate dissolved organic matter that can inhibit Se detection by hydride-generation atomic-absorption spectrometry. Isolation of hydrophobic organic matter with XAD-8 did not affect concentrations of selenite and selenate, and the isolated organic matter represents a minimal estimation of organic Se. Ninety-eight percent of the Se in the extracts was selenate and about 100% of the isolated organic Se was associated with the humic acid fraction of dissolved organic matter. The depth distribution of Se species in the soil saturation extracts support a hypothesis that the distribution of soluble Se and salinity in these soils is the result of evaporation from a shallow water table and leaching by irrigation water low in Se and salinity.

California↗