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Ground-water quality data in the San Francisco Bay study unit, 2007: Results from the California GAMA Program

Ground-water quality in the approximately 620-square-mile San Francisco Bay study unit (SFBAY) was investigated from April through June 2007 as part of the Priority Basin project of the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The study was designed to provide a spatially unbiased assessment of raw ground-water quality, as well as a statistically consistent basis for comparing water quality throughout California. Samples in SFBAY were collected from 79 wells in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. Forty-three of the wells sampled were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Thirty-six wells were sampled to aid in evaluation of specific water-quality issues (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]), naturally occurring inorganic constituents (nutrients, major and minor ions, trace elements, chloride and bromide isotopes, and uranium and strontium isotopes), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14 isotopes, and stable isotopes of hydrogen, oxygen, nitrogen, boron, and carbon), and dissolved noble gases (noble gases were analyzed in collaboration with Lawrence Livermore National Laboratory) also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blank samples, replicate samples, matrix spike samples) were collected for approximately one-third of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control information from the field blanks resulted in applying “V” codes to approximately 0.1 percent of the data collected for ground-water samples (meaning a constituent was detected in blanks as well as the corresponding environmental data). See the Appendix section “Quality-Control-Sample Results.” This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is delivered to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in about one-half of the grid wells, while pesticides were detected in about one-fifth of the grid wells. Concentrations of all VOCs and pesticides detected in samples from all SFBAY wells were below health-based thresholds. No pharmaceutical compounds were detected in any SFBAY well. One potential wastewater-indicator compound, caffeine, was detected in one grid well in SFBAY. Concentrations of most trace elements and nutrients detected in samples from all SFBAY wells were below health-based thresholds. Exceptions include nitrate, detected above the USEPA maximum contaminant level (MCL-US) in 3samples; arsenic, above the USEPA maximum contaminant level (MCL-US) in 3 samples; cadmium, above the MCL-US in 1 sample; boron, above the CDPH notification level (NL-CA) in 2 samples; and strontium, above the USEPA lifetime health advisory level (HAL-US) in 2 samples. The radioactive constituent radon-222 was detected above the proposed MCL-US in two grid wells, but no wells had detections above the proposed alternative MCL-US. Most of the samples from all SFBAY wells had concentrations of major ions, total dissolved solids, and trace elements below the non-enforceable thresholds set for aesthetic concerns. Six or fewer samples contained chloride, sulfate, or iron at concentrations above the SMCL-CA thresholds. No microbial indicators were detected in SFBAY grid wells.

California↗

MODIS phenology image service ArcMap toolbox

Seasonal change is important to consider when managing conservation areas at landscape scales. The study of such patterns throughout the year is referred to as phenology. Recurring life-cycle events that are initiated and driven by environmental factors include animal migration and plant flowering. Phenological events capture public attention, such as fall color change in deciduous forests, the first flowering in spring, and for those with allergies, the start of the pollen season. These events can affect our daily lives, provide clues to help understand and manage ecosystems, and provide evidence of how climate variability can affect the natural cycle of plants and animals. Phenological observations can be gathered at a range of scales, from plots smaller than an acre to landscapes of hundreds to thousands of acres. Linking these observations to diverse disciplines such as evolutionary biology or climate sciences can help further research in species and ecosystem responses to climate change scenarios at appropriate scales. A cooperative study between the National Park Service (NPS), the U.S. Geological Survey (USGS), and the National Aeronautics and Space Administration (NASA) has been exploring how satellite information can be used to summarize phenological patterns observed at the park or landscape scale and how those summaries can be presented to both park managers and visitors. This study specifically addressed seasonal changes in plants, including the onset of growth, photosynthesis in the spring, and the senescence of deciduous vegetation in the fall. The primary objective of the work is to demonstrate that seasonality even in protected areas changes considerably across years. A major challenge is to decouple natural variability from possible trends—directional change that can lead to a permanent and radically different ecosystem state. Trends can be either a gradual degradation of the landscape (often from external influences) or steady improvement (by implementing long-term conservation plans). In either case, it is important to first grasp the magnitude of natural variation so that it is not confused with actual trends. This work used existing and freely available remote sensing data, specifically the NASA-funded 250-meter (m) spatial resolution land-surface phenology product for North America. This product is calculated from an annual record of vegetation health observed by NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The land-surface phenology product is, in essence, a method to summarize all the observations throughout a year into a few key, ecologically relevant “metrics”.

Open-File Report↗

Petrologic and isotopic data from the Cretaceous (Campanian) Blackhawk Formation and Star Point Sandstone (Mesaverde Group), Wasatch Plateau, Utah

The presence of discrete minerals associated with coal—whether (1) detrital or authigenic constituents of the coals or in thin mudstone or siltstone units interbedded with coals, or (2) authigenic phases that formed along cleats—might influence its utilization as an energy resource. The build-up of sintered ash deposits on the surfaces of heat exchangers in coal-fired power plants, due to the alteration of minerals during combustion of the coal, can seriously affect the functioning of the boiler and enhance corrosion of combustion equipment. In particular, the presence of sodium in coals has been considered a key factor in the fouling of boilers; however, other elements (such as calcium or magnesium) and the amount of discrete minerals burned with coal can also play a significant role in the inefficiency of and damage to boilers. Previous studies of the quality of coals in the Cretaceous (Campanian) Blackhawk Formation of the Wasatch Plateau, Utah, revealed that the sodium content of the coals varied across the region. To better understand the origin and distribution of sodium in these coals, petrologic studies were undertaken within a sedimentological framework to evaluate the timing and geochemical constraints on the emplacement of sodium-bearing minerals, particularly analcime, which previously had been identified in coals in the Blackhawk Formation. Further, the study was broadened to include not just coals in the Blackhawk Formation from various localities across the Wasatch Plateau, but also sandstones interbedded with the coals as well as sandstones in the underlying Star Point Sandstone. The alteration history of the sandstones in both formations was considered a key component of this study because it records the nature and timing of fluids passing through them and the associated precipitation of sodium-bearing minerals; thus, the alteration history could place constraints on the distribution and timing of sodium mineralization in the interbedded or overlying Blackhawk coals. Although some preliminary results were previously presented at scientific meetings, the petrologic and geochemical data have not been fully compiled and reported. The purpose of this report is to present the methods of data acquisition and the results of petrologic and isotopic analyses on coal and sandstone samples from the Blackhawk Formation as well as sandstones of the underlying Star Point Sandstone.

Utah↗

Water-resources-related information for the Milwaukee Metropolitan Sewerage District planning area, Wisconsin, 1970-2002

The Milwaukee Metropolitan Sewerage District (MMSD) Corridor Study is a three-phase project designed to improve the understanding of water resources in the stream corridors of the MMSD planning area by initially compiling existing data and using the compiled information to develop 3-year baseline and long-term monitoring plans. This report is one of the products of Phase I of the Corridor Study. A literature review of surface-water-quality, surface water- quantity, and ecology studies conducted from 1970 through 2001 was completed and is summarized in this report. An inventory of Geographic Information System spatial coverages available for the MMSD planning area has been assembled. A database of water, sediment, and tissue (fish, shellfish, and others) chemistry, macroinvertebrates, fish, algae, habitat, geomorphic, and other physical and ecological data was compiled from data sets from MMSD, U.S. Geological Survey, Wisconsin Department of Natural Resources, and the U.S. Environmental Protection Agency. More than 2.7 million results are available in the MMSD Corridor Study database and the compilation of multiple datasets allows for retrieving data from a central database rather than from each of the source datasets. Data for 1970 through 2002 were collected for the 420-square-mile planning area by various agencies using different field data-collection and laboratory analysis methods. Chemical constituents and ecological components that are important to an urban setting and well represented in the database were selected for further investigation. Each constituent or component is described in this report with some or all of the following: a text summary, map of sampling locations, and in some cases median concentrations, statistical distributions of concentrations by subwatershed, table of summary statistics by subwatershed, and graphs of temporal and (or) seasonal trends. Physical data presented in the report include streamflow, stream stage, and precipitation data. Chemical indicators of water quality presented in the report include field measurements and miscellaneous constituents (pH, alkalinity, specific conductance, hardness, dissolved oxygen, biochemical oxygen demand, and chloride), sediment (total suspended solids and suspended sediment), nutrients (total nitrogen, nitrate, Kjeldahl nitrogen, total phosphorus, and dissolved phosphorus), trace elements (cadmium, mercury, copper, lead, arsenic, chromium, nickel, and zinc), pesticides (historically used pesticides and pesticides still in use), and polychlorinated biphenyls. Ecological indicators of water quality discussed in the report include community surveys of macroinvertebrates and fish, chlorophyll a concentrations, habitat assessments and channel-measurement data, and fecal coliform and E. coli bacterial counts. In addition to the compilation of the database, a major purpose of this investigation was to identify additional sampling that should be conducted under the baseline monitoring phase, which will be the second phase of the Corridor Study. Additional sampling may include: • Some subwatersheds, such as those in the headwaters. • Emerging contaminants such as pharmaceuticals and personal care products (PPCPs), human hormones, organic wastewater contaminants, and other constituents that result from human activity. • E. coli, which can serve as an indicator of health risk to swimmers and other recreational water users. • Pesticides in all media. • PCBs. • Trace elements in water, bed sediment, and tissues (fish, shellfish, and others). • Samples during winter months or during early snowmelt episodes to address constituents such as chloride and some nutrients that have seasonal variability and that may be affected by factors such as road deicing during the winter. • Samples for macroinvertebrate and fish-community data and habitat assessments. • Physical data such as stream-channel cross-section profiles, bridge-scour assessments, flood-plain maps, structures, and shoreline conditions.

Wisconsin↗

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Naval Station Mayport, Florida

Ground-water flow through the surficial aquifer system at Naval Station Mayport near Jacksonville, Florida, was simulated with a two-layer finite-difference model as part of an investigation conducted by the U.S. Geological Survey. The model was calibrated to 229 water-level measurements from 181 wells during three synoptic surveys (July 17, 1995; July 31, 1996; and October 24, 1996). A quantifiable understanding of ground-water flow through the surficial aquifer was needed to evaluate remedial-action alternatives under consideration by the Naval Station Mayport to control the possible movement of contaminants from sites on the station. Multi-well aquifer tests, single-well tests, and slug tests were conducted to estimate the hydraulic properties of the surficial aquifer system, which was divided into three geohydrologic units�an S-zone and an I-zone separated by a marsh-muck confining unit. The recharge rate was estimated to range from 4 to 15 inches per year (95 percent confidence limits), based on a chloride-ratio method. Most of the simulations following model calibration were based on a recharge rate of 8 inches per year to unirrigated pervious areas. The advective displacement of saline pore water during the last 200 years was simulated using a particle-tracking routine, MODPATH, applied to calibrated steady-state and transient models of the Mayport peninsula. The surficial aquifer system at Naval Station Mayport has been modified greatly by natural and anthropogenic forces so that the freshwater flow system is expanding and saltwater is being flushed from the system. A new MODFLOW package (VAR1) was written to simulate the temporal variation of hydraulic properties caused by construction activities at Naval Station Mayport. The transiently simulated saltwater distribution after 200 years of displacement described the chloride distribution in the I-zone (determined from measurements made during 1993 and 1996) better than the steady-state simulation. The advective movement of contaminants from selected sites within the solid waste management units to discharge points was simulated using MODPATH. Most of the particles were discharged to the nearest surface-water feature after traveling less than 1,000 feet in the ground-water system. Most areas within 1,000 feet of a surface-water feature or storm sewer had traveltimes of less than 50 years, based on an effective porosity of 40 percent. Contributing areas, traveltimes, and pathlines were identified for 224 wells at Naval Station Mayport under steady-state and transient conditions by back-tracking a particle from the midpoint of the wetted screen of each well. Traveltimes to contributing areas that ranged between 15 and 50 years, estimated by the steady-state model, differed most from the transient traveltime estimates. Estimates of traveltimes and pathlines based on steady-state model results typically were 10 to 20 years more and about twice as long as corresponding estimates from the transient model. The models differed because the steady-state model simulated 1996 conditions when Naval Station Mayport had more impervious surfaces than at any earlier time. The expansion of the impervious surfaces increased the average distance between contributing areas and observation wells.

Florida↗

National Park Service Vegetation Mapping Inventory Program: Great Smoky Mountains National Park vegetation mapping project

The National Park Service (NPS) Vegetation Mapping Inventory (VMI) Program is an effort to classify, describe, and map existing vegetation communities in national park units throughout the United States. The NPS VMI Program is managed by the NPS Natural Resource Stewardship and Science Inventory and Monitoring Program and provides baseline vegetation information to natural resource managers, researchers, and ecologists. The U.S. Geological Survey Upper Midwest Environmental Sciences Center, NatureServe, and NPS Great Smoky Mountains National Park (GRSM, also referred to as the “Park”) have completed vegetation classification and mapping of GRSM, including the Foothills Parkway, for the NPS VMI Program. Mappers, ecologists, and botanists collaborated to affirm vegetation types of GRSM and to determine how best to map the vegetation types by using aerial imagery. A vegetation classification developed in 2003 by NatureServe and the NPS served as a foundation to further classify and map the vegetation types of the Park. Data from an additional 10 vegetation plots supported vegetation types either rare or not documented in the 2003 classification. Data from 203 verification sites were collected to test the field key to vegetation types and the application of vegetation types to a sample set of map polygons. Furthermore, data from 972 accuracy assessment (AA) sites were collected (of which 966 were used to test accuracy of the vegetation map layer). This GRSM vegetation mapping project identified 112 vegetation types consisting of 105 association types in the U.S. National Vegetation Classification (USNVC), 2 “park-special” types, 1 “map-special” type, and 4 cultural types in the USNVC. To map the vegetation and land cover of GRSM, 52 map classes were developed. Of these 52 map classes, 46 represent natural (including ruderal) vegetation types, most of which types are recognized in the USNVC. For the remaining 6 of the 52 map classes, 4 represent USNVC cultural types for agricultural and developed areas, and 2 represent non-USNVC types for nonvegetated open water and nonvegetated rock. Features were interpreted from viewing four-band digital aerial imagery using digital onscreen three-dimensional stereoscopic workflow systems in geographic information systems; digital aerial imagery was collected during September 23–October 30, 2015. The interpreted data were digitally and spatially referenced, thus making the spatial-database layers usable in a geographic information system. Polygon units were mapped to either a 0.5- or 0.25- hectare (ha) minimum mapping unit, depending on vegetation type. A geodatabase containing several feature-class layers and tables provides the locations and data of USNVC vegetation types (vegetation map layer), vegetation plots, verification sites, AA sites, project boundary extent, and aerial image centers and flight lines. Covering 210,875 ha, the feature-class layer and related tables for the vegetation map layer provide 34,084 polygons of detailed attribute data when special modifiers are not considered (average polygon size of 6.2 ha) and 36,589 polygons of detailed attribute data when special modifiers are considered (average polygon size of 5.8 ha). Each map polygon is assigned a map-class code and name and, when applicable, are linked to USNVC classification tables within the geodatabase. The vegetation map extent includes the administrative boundary for GRSM and the Foothills Parkway. A summary report, generated from the vegetation map layer, concludes that the 46 map classes representing natural (including ruderal) vegetation types apply to 99.2% of polygons (33,797 polygons; average size of 6.2 ha) and cover 98.6% of the Park (207,971.4 ha). Further broken down, map classes representing natural vegetation types indicate that the Park is 97.7% forest and woodland (205,882.5 ha), 0.6% shrubland (1,174.6 ha), and 0.4% herbaceous (914.3 ha). Map classes representing cultural vegetation types apply to 0.8% of polygons (259 polygons; average size of 4.9 ha) and cover 0.6% of the Park (1,277.4 ha). Map classes representing nonvegetation open and flowing water and unvegetated rock apply to 0.08% of polygons (28 polygons; average size of 58.1 ha) and cover 0.8% of the Park (1,625.9 ha). A thematic AA study was completed of map classes representing the natural (including ruderal) vegetation types of the Park. Initial AA results were discussed with NPS staff from the Park. Following input from NPS staff on how to handle map classes that fell below accuracy standards, adjustments were made to the vegetation map layer. Final results indicate an overall accuracy of 80.64% (kappa index of 79.96% for chance agreements) based on data from 966 of the 972 AA sites. Most individual map-class themes exceed the NPS VMI Program standard of 80% with a 90% confidence interval. The GRSM vegetation mapping project delivers many geospatial and vegetation data products, including an in-depth project report discussing methods and results, which includes map classification and map-class descriptions. This suite of products also includes descriptions and a field key to vegetation types; a database of vegetation plots, verification sites, and AA sites; digital images of field sites; field data sheets; digital aerial imagery; hardcopy and digital maps; a geodatabase of vegetation and land cover (map layer), field sites (vegetation plots, verification sites, and AA sites), aerial imagery index, project boundary, and metadata; and a contingency table listing AA results. Geospatial products are projected in the Universal Transverse Mercator, Zone 17 North, by using the North American Datum of 1983. Information on the NPS VMI Program and completed mapping projects are on the internet at https://www.nps.gov/im/vegetation-inventory.htm.

North Carolina, Tennessee↗

Shale-gas assessment: Comparison of gas-in-place versus performance-based approaches

The recent interest in exploration for shale gas increases the demand for a reliable, compatible resource assessment. Many different assessment methods are used, commonly depending on types and quantity of data available, which may lead to significantly divergent results for the same shale-gas play. This study compares results obtained using performance-based and gas-in-place methodologies to assess a well-developed and active shale-gas play (Woodford Shale, Arkoma Basin, USA) and two untested, hypothetical shale-gas plays (Shublik and Brookian, Alaska North Slope, USA). Results show that the two assessment methods produce comparable results when assessment units are identically defined and similar geological constraints are used as input parameters. Inherent uncertainties are associated with both assessment methods, and these are related to aspects of shale-gas production that are not well understood. The performance-based method relies on decline trend analysis to generate distributions of estimated ultimate recovery (EUR), and uncertainty increases in cases of short production history. The gas-in-place method requires the application of a recovery factor to estimate technically recoverable resources, and both absolute values of recovery factors and their spatial variability are poorly documented, and therefore a source of uncertainty.

Natural Resources Research↗

Twenty-first-century projections of shoreline change along inlet-interrupted coastlines

Sandy coastlines adjacent to tidal inlets are highly dynamic and widespread landforms, where large changes are expected due to climatic and anthropogenic influences. To adequately assess these important changes, both oceanic (e.g., sea-level rise) and terrestrial (e.g., fluvial sediment supply) processes that govern the local sediment budget must be considered. Here, we present novel projections of shoreline change adjacent to 41 tidal inlets around the world, using a probabilistic, reduced complexity, system-based model that considers catchment-estuary-coastal systems in a holistic way. Under the RCP 8.5 scenario, retreat dominates (90% of cases) over the twenty-first century, with projections exceeding 100 m of retreat in two-thirds of cases. However, the remaining systems are projected to accrete under the same scenario, reflecting fluvial influence. This diverse range of response compared to earlier methods implies that erosion hazards at inlet-interrupted coasts have been inadequately characterised to date. The methods used here need to be applied widely to support evidence-based coastal adaptation.

Nature--Scientific Reports↗

Long Term Resource Monitoring procedures—Aquatic vegetation monitoring

This standard operating procedure (SOP) manual describes the collection of standardized, long-term data for aquatic vegetation communities in selected study pools of the Upper Mississippi River System in the United States. The primary intent of the data collection is to assess the status and trends that aid in understanding the unique river ecosystem and to guide large-scale ecological restoration of the river and its biological communities, like aquatic plants and their dependent wildlife. This SOP is an update to the version published in 2000 and reflects modifications to sample sizes and additions of new data collection procedures. All long-term monitoring programs and their SOPs must be adapted to changing conditions and be improved through learning, and this SOP clarifies procedures and adds new elements since the initial SOP was written more than 25 years ago. The SOP is intended for multiple audiences, including vegetation specialists through the Upper Mississippi River Restoration Program, data analysts using the publicly available data generated through this SOP, and natural resource managers and restoration practitioners who need data and science to guide some decisions. This SOP may be transferable and adaptable to other ecosystems when the aquatic plant community is the focus.

Illinois, Iowa, Minnesota, Missouri, Wisconsin↗

National Park Service socioeconomic monitoring pilot survey: Visitor spending analysis

The National Park Service (NPS) is in the process of establishing a formal socioeconomic monitoring (SEM) program that will provide a standard visitor survey instrument and a long-term, systematic sampling design for in-park visitor surveys. The development of the pilot SEM survey provided the opportunity to add to the set of available visitor spending profiles for use in the NPS Visitor Spending Effects analysis and enabled the exploration of improved visitor spending estimation methodologies. Fourteen park units were selected for SEM pilot visitor surveys to represent a variety of park unit types (i.e., National Parks, National Recreation Areas, National Historic Parks, etc.), activities, settings (i.e., urban, rural, seashore, parkway, etc.), and difficulty of survey administration (i.e., highly controlled entrances vs. dispersed access). This report describes the methods developed to estimate visitor spending using the SEM pilot surveys and provides visitor spending profiles for the 14 pilot parks. The experiences gained through the pilot effort provide useful feedback for learning and improving future survey efforts.

Natural Resource Report↗

A methodology for quantifying and mapping ecosystem services provided by watersheds

Watershed processes – physical, chemical, and biological – are the foundation for many benefits that ecosystems provide for human societies. A crucial step toward accurately representing those benefits, so they can ultimately inform decisions about land and water management, is the development of a coherent methodology that can translate available data into the ecosystem services (ES) produced by watersheds. Ecosystem services (ES) provide an instinctive way to understand the tradeoffs associated with natural resource management. We provide a synthesis of common terminology and explain a rationale and framework for distinguishing among the components of ecosystem service delivery, including: an ecosystem’s capacity to produce a service; societal demand for the service; ecological pressures on this service; and flow of the service to people. We discuss how interpretation and measurement of these components can differ among provisioning, regulating, and cultural services and describe selected methods for quantifying ES components as well as constraints on data availability. We also present several case studies to illustrate our methods, including mapping capacity of several water purification services and demand for two forms of wildlife-based recreation, and discuss future directions for ecosystem service assessments. Our flexible framework treats service capacity, demand, ecological pressure, and flow as separate but interactive entities to better evaluate the sustainability of service provision across space and time and to help guide management decisions.

Book chapter↗

Differentiating transpiration from evaporation in seasonal agricultural wetlands and the link to advective fluxes in the root zone

The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flowrates and tracer concentrations atwetland inflows and outflows. We used two ideal reactormodel solutions, a continuous flowstirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these nonideal agricultural wetlands in which check ponds are in series. Using a fluxmodel, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment–water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemicalmechanisms affecting dissolved constituent cycling in the root zone. In addition,our understanding of internal root zone cycling of Hg and other dissolved constituents, benthic fluxes, and biological irrigation may be greatly affected.

Science of the Total Environment↗

Application of the top specified boundary layer (TSBL) approximation to initial characterization of an inland aquifer mineralization 1. Direct contact between fresh and saltwater

This paper presents a basic study in generalized terms that originates from two needs: (1) to understand the major mechanisms involved in the mineralization of groundwater of the Great Bend Prairie aquifer of Kansas by saltwater originating from a deeper Permian bedrock formation, and (2) to develop simple, robust tools that can readily be used for local assessment and management activities in the salt-affected region. A simplified basic conceptual model is adopted, incorporating two horizontal layers of porous medium which come into contact at a specific location within the model domain. The top layer is saturated with freshwater, and the bottom layer is saturated with saltwater. The paper considers various stages of approximation which can be useful for simplified simulation of the build-up of the transition zone (TZ) between the freshwater and the saltwater. The hierarchy of approximate approaches leads to the development of the top specified boundary layer (TSBL) method, which is the major tool used in this study for initial characterization of the development of the TZ. It is shown that the thickness of the TZ is mainly determined by the characteristic dispersivity. The build-up of the TZ is completed after a time period equal to the time needed to advect a fluid particle along the whole extent of the TZ. Potential applications and the effects of natural recharge and pumpage on salinity transport in the domain are discussed and evaluated in the context of demonstrating the practicality of the TSBL approach.

Journal of Contaminant Hydrology↗

Estimating the hatchery fraction of a natural population: a Bayesian approach

There is strong and growing interest in estimating the proportion of hatchery fish that are in a natural population (the hatchery fraction). In a sample of fish from the relevant population, some are observed to be marked, indicating their origin as hatchery fish. The observed proportion of marked fish is usually less than the actual hatchery fraction, since the observed proportion is determined by the proportion originally marked, differential survival (usually lower) of marked fish relative to unmarked hatchery fish, and rates of mark retention and detection. Bayesian methods can work well in a setting such as this, in which empirical data are limited but for which there may be considerable expert judgment regarding these values. We explored a Bayesian estimation of the hatchery fraction using Monte Carlo–Markov chain methods. Based on our findings, we created an interactive Excel tool to implement the algorithm, which we have made available for free.

North American Journal of Fisheries Management↗

Water quality trends in the Blackwater River watershed, West Virginia

An understanding of historic and current water quality is needed to manage and improve aquatic communities within the Blackwater River watershed, WV. The Blackwater River, which historically offered an excellent Salvelinus fontinalis (Brook Trout) fishery, has been affected by logging, coal mining, use of off-road vehicles, and land development. Using information-theoretic methods, we examined trends in water quality at 12 sites in the watershed for the 14 years of 1980–1993. Except for Beaver Creek, downward trends in acidity and upward trends in alkalinity, conductivity, and hardness were consistent with decreases in hydrogen ion concentration. Water-quality trends for Beaver Creek were inconsistent with the other sites and reflect ongoing coal-mining influences. Dissolved oxygen trended downward, possibly due to natural conditions, but remained above thresholds that would be detrimental to aquatic life. Water quality changed only slightly within the watershed from 1980–1993, possibly reflecting few changes in development and land uses during this time. These data serve as a baseline for future water-quality studies and may help to inform management planning.

West Virginia↗

Comment on “Interpretation of Kappa and fmax filters as source effect”, by Igor A. Beresnev

Beresnev (2019) advocates the use of an earthquake slip function that produces an ω-2.5 high-frequency falloff of Fourier displacement spectra in the far field, where ω denotes the angular frequency. He argues that the observed high-frequency decay of earthquake spectra can be adequately modeled by this ω-2.5 falloff, without needing to include high frequency attenuation at shallow depth under the site, commonly characterized as fmax or kappa. In his abstract, Beresnev (2019) describes source models with falloffs intermediate between ω-2 and ω-3 as “providing natural high-cut filtering exclusively as a source effect.” In many studies to date, observed spectra are modeled using an ω-2 source spectrum combined with attenuation along the propagation path, including strong attenuation at shallow depths (< 1 km) beneath a site. It is not clear whether Beresnev (2019) is claiming that path effects (including site attenuation) are unimportant to ground motions or if he is proposing a simple, pragmatic method to fit the high-frequency decay of earthquake spectra.

Bulletin of the Seismological Society of America↗

Potential drivers of change in fluxes of nutrients and total suspended solids in the upper White River Basin, Indiana, Water Years 1997–2019

The U.S. Geological Survey and The Nature Conservancy previously collaborated to evaluate changes and trends in the concentrations and flux of nutrients (total phosphorus, as phosphorus; nitrate plus nitrite, as nitrogen; and total Kjeldahl nitrogen, as nitrogen) and total suspended solids (TSS) at three study gages located on the upper White River at Muncie, near Nora, and near Centerton, Indiana. That work is extended and updated using 3 additional years of data (through 2020) and newer estimation methods. In addition, information is provided about climatic and anthropogenic factors that could influence the concentrations and fluxes of nutrients and TSS in the upper White River Basin.

Indiana↗

A literature review of interaction of oxidized uranium species and uranium complexes with soluble organic matter

Organic material is commonly found associated with uranium ores in sandstone-type deposits. This review of the literature summarizes the classes and separations of naturally occurring organic material but the emphasis is on soluble organic species. The main class of materials of interest is humic substances which are high-molecular-weight complex molecules that are soluble in alkaline solution. These humic substances are able to solubilize (make soluble) minerals and also to complex [by ion exchange and (or) chelation] many cations. The natural process of soil formation results in both mineral decomposition and element complexing by organic species. Uranium in solution, such as ground water, can form many species with other elements or complexes present depending on Eh and pH. In natural systems (oxidizing Eh, pH 5-9) the uranium is usually present as a complex with hydroxide or carbonate. Thermodynamic data for these species are presented. Interacting metals and organic materials have been observed in nature and studied in the laboratory by many workers in diverse scientific disciplines. The results are not easily compared. Measurements of the degree of complexation are reported as equilibrium stability constant determinations. This type of research has been done for Mn, Fe, Cu, Zn, Pb, Ni, Co, Mg, Ca, Al, and to a limited degree for U. The use of Conditional Stability Constants has given quantitative results in some cases. The methods utilized in experiments and calculations are reviewed.

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