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At least 1,621 records · Page 90Linked to original sources
USGS2004

Basic ground-water hydrology

Ground water is one of the Nation's most valuable natural resources. It is the source of about 40 percent of the water used for all purposes exclusive of hydropower generation and electric powerplant cooling. Surprisingly, for a resource that is so widely used and so important to the health and to the economy of the country, the occurrence of ground water is not only poorly understood but is also, in fact, the subject of many widespread misconceptions. Common misconceptions include the belief that ground water occurs in underground rivers resembling surface streams whose presence can be detected by certain individuals. These misconceptions and others have hampered the development and conservation of ground water and have adversely affected the protection of its quality. In order for the Nation to receive maximum benefit from its ground-water resource, it is essential that everyone, from the rural homeowner to managers of industrial and municipal water supplies to heads of Federal and State water-regulatory agencies, become more knowledgeable about the occurrence, development, and protection of ground water. This report has been prepared to help meet the needs of these groups, as well as the needs of hydrologists, well drillers, and others engaged in the study and development of ground-water supplies. It consists of 45 sections on the basic elements of ground-water hydrology, arranged in order from the most basic aspects of the subject through a discussion of the methods used to determine the yield of aquifers to a discussion of common problems encountered in the operation of ground-water supplies. Each section consists of a brief text and one or more drawings or maps that illustrate the main points covered in the text. Because the text is, in effect, an expanded discussion of the illustrations, most of the illustrations are not captioned. However, where more than one drawing is included in a section, each drawing is assigned a number, given in parentheses, and these numbers are inserted at places in the text where the reader should refer to the drawing. In accordance with U.S. Geological Survey policy to encourage the use of metric units, these units are used in most sections. In the sections dealing with the analysis of aquifer (pumping) test data, equations are given in both consistent units and in the inconsistent inch-pound units still in relatively common use among ground-water hydrologists and well drillers. As an aid to those who are not familiar with metric units and with the conversion of ground-water hydraulic units from inch-pound units to metric units, conversion tables are given on the inside back cover. Definitions of ground-water terms are given where the terms are first introduced. Because some of these terms will be new to many readers, abbreviated definitions are also given on the inside front cover for convenient reference by those who wish to review the definitions from time to time as they read the text. Finally, for those who need to review some of the simple mathematical operations that are used in ground-water hydrology, a section on numbers, equations, and conversions is included at the end of the text.

Water Supply Paper↗
USGS2024

Predicting redox conditions in groundwater at a national scale using random forest classification

Redox conditions in groundwater may markedly affect the fate and transport of nutrients, volatile organic compounds, and trace metals, with significant implications for human health. While many local assessments of redox conditions have been made, the spatial variability of redox reaction rates makes the determination of redox conditions at regional or national scales problematic. In this study, redox conditions in groundwater were predicted for the contiguous United States using random forest classification by relating measured water quality data from over 30,000 wells to natural and anthropogenic factors. The model correctly predicted the oxic/suboxic classification for 78 and 79% of the samples in the out-of-bag and hold-out data sets, respectively. Variables describing geology, hydrology, soil properties, and hydrologic position were among the most important factors affecting the likelihood of oxic conditions in groundwater. Important model variables tended to relate to aquifer recharge, groundwater travel time, or prevalence of electron donors, which are key drivers of redox conditions in groundwater. Partial dependence plots suggested that the likelihood of oxic conditions in groundwater decreased sharply as streams were approached and gradually as the depth below the water table increased. The probability of oxic groundwater increased as base flow index values increased, likely due to the prevalence of well-drained soils and geologic materials in high base flow index areas. The likelihood of oxic conditions increased as topographic wetness index (TWI) values decreased. High topographic wetness index values occur in areas with a propensity for standing water and overland flow, conditions that limit the delivery of dissolved oxygen to groundwater by recharge; higher TWI values also tend to occur in discharge areas, which may contain groundwater with long travel times. A second model was developed to predict the probability of elevated manganese (Mn) concentrations in groundwater (i.e., ≥50 μg/L). The Mn model relied on many of the same variables as the oxic/suboxic model and may be used to identify areas where Mn-reducing conditions occur and where there is an increased risk to domestic water supplies due to high Mn concentrations. Model predictions of redox conditions in groundwater produced in this study may help identify regions of the country with elevated groundwater vulnerability and stream vulnerability to groundwater-derived contaminants.

contiguous United States↗
USGS2022

Response of soil respiration to changes in soil temperature and water table level in drained and restored peatlands of the southeastern United States

Extensive drainage of peatlands in the southeastern United States coastal plain for the purposes of agriculture and timber harvesting has led to large releases of soil carbon as carbon dioxide (CO 2 ) due to enhanced peat decomposition. Growth in mechanisms that provide financial incentives for reducing emissions from land use and land-use change could increase funding for hydrological restoration that reduces peat CO 2 emissions from these ecosystems. Measuring soil respiration and physical drivers across a range of site characteristics and land use histories is valuable for understanding how CO 2 emissions from peat decomposition may respond to raising water table levels. We combined measurements of total soil respiration, depth to water table from soil surface, and soil temperature from drained and restored peatlands at three locations in eastern North Carolina and one location in southeastern Virginia to investigate relationships among total soil respiration and physical drivers, and to develop models relating total soil respiration to parameters that can be easily measured and monitored in the field.

North Carolina↗
USGS1964

Chemical quality of public water supplies of the United States and Puerto Rico, 1962

Municipal water systems in the United States and Puerto Rico supply water for many commercial and industrial uses as well as for domestic wells. It is generally known that our water resources are unequally distributed throughout the country, but it is not quite so well understood that the quality of our water resources is also variable. This hydrologic investigations atlas shows, State by State, some of the chemical quality aspects of our public water supplies. This information can be used to evaluate the suitability of the public supplies for many uses – among them, manufacturing processes, food processing, cooling water, and domestic use.

Hydrologic Atlas↗
USGS1950

Water resources of the Cumberland area, Maryland-West Virginia

The area covered by this report consists of Garrett and Allegany Counties, the two most westernmost counties of Maryland, and Mineral County, West Virginia. The city of Cumberland, population 37,732 (1950 census), which is the economic and commercial center of the area, is on the North Branch pf the Potomac River in Allegany County. The report was prepared in response to a request from the United States Department of Commerce, which desired an appraisal of the water resources of the Cumberland atra in order to evaluate the effect of the availability of water on the economic development of the area. Accordingly, the purpose of this report is to summarize the available water information and to describe the hydrologic factors that affect the availability of water.

Maryland; West Virginia↗
USGS2004

Tree-regeneration and mortality patterns and hydrologic change in a forested karst wetland--Sinking Pond, Arnold Air Force Base, Tennessee

Multiple lines of evidence point to climate change as the driving factor suppressing tree regeneration since 1970 in Sinking Pond, a 35-hectare seasonally flooded karst depression located on Arnold Air Force Base near Manchester, Tennessee. Annual censuses of 162-193 seedling plots from 1997 through 2001 demonstrate that the critical stage for tree survival is the transition from seedling to sapling and that this transition is limited to shallow (less than 0.5 meters) ponding depths. Recruitment of saplings to the small adult class also was restricted to shallow areas. Analysis of the spatial and elevation distribution of tree-size classes in a representative 2.3-hectare area of Sinking Pond showed a general absence of overcup oak saplings and young adults in deep (ponding depth greater than 1 meter) and intermediate (ponding depth 0.5-1 meter) areas, even though overcup oak seedlings and mature trees are concentrated in these areas. Analysis of tree rings from 45 trees sampled in a 2.3-hectare spatial-analysis plot showed an even distribution of tree ages across ponding-depth classes from the 1800s through 1970, followed by complete suppression of recruitment in deep and intermediate areas after 1970. Trees younger than 30 years were spatially and vertically concentrated in a small area with shallow ponding depth, about 0.5 meter below the spillway elevation. Results of hydrologic modeling, based on rainfall and temperature records covering the period January 1854 through September 2002, show ponding durations after 1970 considerably longer than historical norms, across ponding-depth classes. This increase in ponding duration corresponds closely with similar increases documented in published analyses of streamflow and precipitation in the eastern United States and with the suppression of tree regeneration at ponding depths greater than 0.5 meter indicated by tree-ring analysis. Comparison of the simulated stage record for Sinking Pond with the ages and elevations of sampled trees shows that prolonged (200 days or more per year) inundation in more than 2 of the first 5 years after germination is inversely related to successful tree recruitment and that such inundation was rare before 1970 and common afterwards.

Water-Resources Investigations Report↗
USGS1987

Louisiana ground-water map no. 1: Potentiometric surface, 1985, and water-level changes, 1983-85, of the Chicot aquifer in southwestern Louisiana

The Chicot aquifer is the principle source of groundwater in southwestern Louisiana and is the most extensively pumped (nearly 1 billion gallons per day) aquifer in the State. Withdrawals from the Chicot aquifer are used primarily for irrigation. Two maps show the generalized potentiometric surfaces of the upper sand unit ('200-ft ' sand in the Lake Charles area) and the ' 500-ft ' sand of the Chicot aquifer. General water level altitudes and flow directions may be inferred from these maps which were prepared in cooperation with the Louisiana Department of Transportation and Development, Office of Public Works. Previous studies of groundwater hydrology in southwestern Louisiana are included in selected references.

Louisiana↗
USGS2022

Multi-task deep learning of daily streamflow and water temperature

Deep learning (DL) models can accurately predict many hydrologic variables including streamflow and water temperature; however, these models have typically predicted hydrologic variables independently. This study explored the benefits of modeling two interdependent variables, daily average streamflow and daily average stream water temperature, together using multi-task DL. A multi-task scaling factor controlled the relative contribution of the auxiliary variable's error to the overall loss during training. Our experiments examined the improvement in prediction accuracy of the multi-task approach using paired streamflow and water temperature data from sites across the conterminous United States. Our results showed that for 56 out of 101 sites, the best performing multi-task models performed better overall than the single-task models in terms of Nash-Sutcliffe efficiency for predicting streamflow with single-site models. For 43 sites, the best multi-task, single-site models made no significant difference in predicting streamflow. The multi-task approach had a smaller effect when applied to a model trained with data from 101 sites together, significantly improving performance for only 17 sites. The multi-task scaling factor was consequential in determining to what extent the multi-task approach was beneficial. A naïve selection of this factor led to significantly worse-performing models for 3 of 101 sites when predicting streamflow as the primary variable, and 47 of 53 sites when predicting stream temperature as the primary variable. We conclude that a multi-task approach can make more accurate predictions by leveraging information from interdependent hydrologic variables, but only for some sites, variables, and model configurations.

Water Resources Research↗
USGS1963

The hydraulic geometry of a shallow estuary

An analogy with entropy production in steady-state systems leads to a statement that the geometry of natural waterways is governed by two opposing influences: a ) equal work per unit of area of bed, and b) minimum work done in the system as a whole. The resulting calculations applied to shallow , estuaries are verified by field measurements.

International Association of Scientific Hydrology ↗
USGS1981

Selective annotated bibliography of geology and ground-water resources for the Montana part of the Northern Great Plains regional aquifer-system analysis

Increasing demand for water to meet needs for energy, industry, irrigation, domestic, and municipal uses has resulted in a study of the geology and hydrology of rocks of Mesozoic and Cenozoic age. This report presents the results of a literature search for the part of the study area in Montana. It consists of an annotated listing of pertinent published reports, a partial subject and area index of the reports, and a correlation chart of geologic and aquifer units listed in the annotations. (USGS)

Open-File Report↗
USGS2006

Analysis of sensitivity of simulated recharge to selected parameters for seven watersheds modeled using the precipitation-runoff modeling system

Recharge is a vital component of the ground-water budget and methods for estimating it range from extremely complex to relatively simple. The most commonly used techniques, however, are limited by the scale of application. One method that can be used to estimate ground-water recharge includes process-based models that compute distributed water budgets on a watershed scale. These models should be evaluated to determine which model parameters are the dominant controls in determining ground-water recharge. Seven existing watershed models from different humid regions of the United States were chosen to analyze the sensitivity of simulated recharge to model parameters. Parameter sensitivities were determined using a nonlinear regression computer program to generate a suite of diagnostic statistics. The statistics identify model parameters that have the greatest effect on simulated ground-water recharge and that compare and contrast the hydrologic system responses to those parameters. Simulated recharge in the Lost River and Big Creek watersheds in Washington State was sensitive to small changes in air temperature. The Hamden watershed model in west-central Minnesota was developed to investigate the relations that wetlands and other landscape features have with runoff processes. Excess soil moisture in the Hamden watershed simulation was preferentially routed to wetlands, instead of to the ground-water system, resulting in little sensitivity of any parameters to recharge. Simulated recharge in the North Fork Pheasant Branch watershed, Wisconsin, demonstrated the greatest sensitivity to parameters related to evapotranspiration. Three watersheds were simulated as part of the Model Parameter Estimation Experiment (MOPEX). Parameter sensitivities for the MOPEX watersheds, Amite River, Louisiana and Mississippi, English River, Iowa, and South Branch Potomac River, West Virginia, were similar and most sensitive to small changes in air temperature and a user-defined flow routing parameter. Although the primary objective of this study was to identify, by geographic region, the importance of the parameter value to the simulation of ground-water recharge, the secondary objectives proved valuable for future modeling efforts. The value of a rigorous sensitivity analysis can (1) make the calibration process more efficient, (2) guide additional data collection, (3) identify model limitations, and (4) explain simulated results.

Scientific Investigations Report↗
USGS2017

Nutrient and sediment concentrations and loads in the Steele Bayou Basin, northwestern Mississippi, 2010–14

The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers-Vicksburg District, monitored streamflow, water quality, and sediment at two stations on the Steele Bayou in northwestern Mississippi from October 2010 through September 2014 to characterize nutrient and sediment concentrations and loads in areas where substantial implementation of conservation efforts have been implemented. The motivation for this effort was to quantify improvements, or lack thereof, in water quality in the Steele Bayou watershed as a result of implementing large- and small-scale best-management practices aimed at reducing nutrient and sediment concentrations and loads. The results of this study document the hydrologic, water-quality, and sedimentation status of these basins following over two decades of ongoing implementation of conservation practices. Results from this study indicate the two Steele Bayou stations have comparable loads and yields of total nitrogen, phosphorus, and suspended sediment when compared to other agricultural basins in the southeastern and central United States. However, nitrate plus nitrite yields from basins in the Mississippi River alluvial plain, including the Steele Bayou Basin, are generally lower than other agricultural basins in the southeastern and central United States. Seasonal variation in nutrient and sediment loads was observed at both stations and for most constituents. About 50 percent of the total annual nutrient and sediment load was observed during the spring (February through May) and between 25 and 50 percent was observed during late fall and winter (October through January). These seasonal patterns probably reflect a combination of seasonal patterns in precipitation, runoff, streamflow, and in the timing of fertilizer application. Median concentrations of total nitrogen, nitrate plus nitrite, total phosphorus, orthophosphate, and suspended sediment were slightly higher at the upstream station, Steele Bayou near Glen Allan, than at the downstream station, Steele Bayou at Grace Road at Hopedale, MS, although the differences typically were not statistically significant. Mean annual loads of nitrate plus nitrite and suspended sediment were also larger at the upstream station, although the annual loads at both stations were generally within the 95-percent confidence intervals of each other.

Mississippi↗
USGS1997

Effect of faulting on ground-water movement in the Death Valley Region, Nevada and California

This study characterizes the hydrogeologic system of the Death Valley region, an area covering approximately 100,000 square kilometers. The study also characterizes the effects of faults on ground-water movement in the Death Valley region by synthesizing crustal stress, fracture mechanics, and structural geologic data. The geologic conditions are typical of the Basin and Range Province; a variety of sedimentary and igneous intrusive and extrusive rocks have been subjected to both compressional and extensional deformation. Faulting and associated fracturing is pervasive and greatly affects ground-water flow patterns. Faults may become preferred conduits or barriers to flow depending on whether they are in relative tension, compression, or shear and other factors such as the degree of dislocations of geologic units caused by faulting, the rock types involved, the fault zone materials, and the depth below the surface. The current crustal stress field was combined with fault orientations to predict potential effects of faults on the regional groundwater flow regime. Numerous examples of faultcontrolled ground-water flow exist within the study area. Hydrologic data provided an independent method for checking some of the assumptions concerning preferential flow paths.

California, Nevada↗
USGS2013

Geology, water-quality, hydrology, and geomechanics of the Cuyama Valley groundwater basin, California, 2008--12

To assess the water resources of the Cuyama Valley groundwater basin in Santa Barbara County, California, a series of cooperative studies were undertaken by the U.S. Geological Survey and the Santa Barbara County Water Agency. Between 2008 and 2012, geologic, water-quality, hydrologic and geomechanical data were collected from selected sites throughout the Cuyama Valley groundwater basin. Geologic data were collected from three multiple-well groundwater monitoring sites and included lithologic descriptions of the drill cuttings, borehole geophysical logs, temperature logs, as well as bulk density and sonic velocity measurements of whole-core samples. Generalized lithologic characterization from the monitoring sites indicated the water-bearing units in the subsurface consist of unconsolidated to partly consolidated sand, gravel, silt, clay, and occasional cobbles within alluvial fan and stream deposits. Analysis of geophysical logs indicated alternating layers of finer- and coarser-grained material that range from less than 1 foot to more than 20 feet thick. On the basis of the geologic data collected, the principal water-bearing units beneath the monitoring-well sites were found to be composed of younger alluvium of Holocene age, older alluvium of Pleistocene age, and the Tertiary-Quaternary Morales Formation. At all three sites, the contact between the recent fill and younger alluvium is approximately 20 feet below land surface. Water-quality samples were collected from 12 monitoring wells, 27 domestic and supply wells, 2 springs, and 4 surface-water sites and were analyzed for a variety of constituents that differed by site, but, in general, included trace elements; nutrients; dissolved organic carbon; major and minor ions; silica; total dissolved solids; alkalinity; total arsenic and iron; arsenic, chromium, and iron species; and isotopic tracers, including the stable isotopes of hydrogen and oxygen, activities of tritium, and carbon-14 abundance. Of the 39 wells sampled, concentrations of total dissolved solids and sulfate from 38 and 37 well samples, respectively, were greater than the U.S. Environmental Protection Agency’s secondary maximum contaminant levels. Concentrations greater than the maximum contaminant levels for nitrate were observed in five wells and were observed for arsenic in four wells. Differences in the stable-isotopic values of hydrogen and oxygen among groundwater samples indicated that water does not move freely between different formations or between different zones within the Cuyama Valley. Variations in isotopic composition indicated that recharge is derived from several different sources. The age of the groundwater, expressed as time since recharge, was between 600 and 38,000 years before present. Detectable concentrations of tritium indicated that younger water, recharged since the early 1950s, is present in parts of the groundwater basin. Hydrologic data were collected from 12 monitoring wells, 56 domestic and supply wells, 3 surface-water sites, and 4 rainfall-gaging stations. Rainfall in the valley averaged about 8 inches annually, whereas the mountains to the south received between 12 and 19 inches. Stream discharge records showed seasonal variability in surface-water flows ranging from no-flow to over 1,500 cubic feet per second. During periods when inflow to the valley exceeds outflow, there is potential recharge from stream losses to the groundwater system Water-level records included manual quarterly depth-to-water measurements collected from 68 wells, time-series data collected from 20 of those wells, and historic water levels from 16 wells. Hydrographs of the manual measurements showed declining water levels in 16 wells, mostly in the South-Main zone, and rising water levels in 14 wells, mostly in the Southern Ventucopa Uplands. Time-series hydrographs showed daily, seasonal, and longer-term effects associated with local pumping. Water-level data from the multiple-well monitoring sites indicated seasonal fluctuations as great as 80 feet and water-level differences between aquifers as great as 40 feet during peak pumping season. Hydrographs from the multiple-well groundwater monitoring sites showed vertical hydraulic gradients were upward during the winter months and downward during the irrigation season. Historic hydrographs showed water-level declines in the Southern-Main, Western Basin, Caliente Northern-Main, and Southern Sierra Madre zone ranging from 1 to 7 feet per year. Hydrographs of wells in the Southern Ventucopa Uplands zone showed several years with marked increases in water levels that corresponded to increased precipitation in the Cuyama Valley. Investigation of hydraulic properties included hydraulic conductivity and transmissivity estimated from aquifer tests performed on 63 wells. Estimates of horizontal hydraulic conductivity ranged from about 1.5 to 28 feet per day and decreased with depth. The median estimated hydraulic conductivity for the older alluvium was about five times that estimated for the Morales Formation. Estimates of transmissivity ranged from 560 to 163,400 gallons per day per foot and decreased with depth. The median estimated transmissivity for the younger alluvium was about three times that estimated for the older alluvium. Geomechanical analysis included land-surface elevation changes at five continuously operating global positioning systems (GPS) and land-subsidence detection at five interferometric synthetic aperture radar (InSAR) reference points. Analysis of data collected from continuously operating GPS stations showed the mountains to the south and west moved upward about 1 millimeter (mm) annually, whereas the station in the center of the Southern-Main zone moved downward more than 7 mm annually, indicating subsidence. It is likely that this subsidence is inelastic (permanent) deformation and indicates reduced storage capacity in the aquifer sediments. Analysis of InSAR data showed local and regional changes that appeared to be dependent, in part, on the time span of the interferogram, seasonal variations in pumping, and tectonic uplift. Long-term InSAR time series showed a total maximum detected subsidence rate of approximately 12 mm per year at one location and approximately 8 mm per year at a second location, while short-term InSAR time series showed maximum subsidence of about 15 mm at one location and localized maximum uplift of about 10 mm at another location.

California↗
USGS1970

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗
USGS1959

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗
USGS2003

Application of two hydrologic models with different runoff mechanisms to a hillslope dominated watershed in the northeastern US: A comparison of HSPF and SMR

Differences in the simulation of hydrologic processes by watershed models directly affect the accuracy of results. Surface runoff generation can be simulated as either: (1) infiltration-excess (or Hortonian) overland flow, or (2) saturation-excess overland flow. This study compared the Hydrological Simulation Program - FORTRAN (HSPF) and the Soil Moisture Routing (SMR) models, each representing one of these mechanisms. These two models were applied to a 102 km2 watershed in the upper part of the Irondequoit Creek basin in central New York State over a seven-year simulation period. The models differed in both the complexity of simulating snowmelt and baseflow processes as well as the detail in which the geographic information was preserved by each model. Despite their differences in structure and representation of hydrologic processes, the two models simulated streamflow with almost equal accuracy. Since streamflow is an integral response and depends mainly on the watershed water balance, this was not unexpected. Model efficiency values for the seven-year simulation period were 0.67 and 0.65 for SMR and HSPF, respectively. HSPF simulated winter streamflow slightly better than SMR as a result of its complex snowmelt routine, whereas SMR simulated summer flows better than HSPF as a result of its runoff and baseflow processes. An important difference between model results was the ability to predict the spatial distribution of soil moisture content. HSPF aggregates soil moisture content, which is generally related to a specific pervious land unit across the entire watershed, whereas SMR predictions of moisture content distribution are geographically specific and matched field observations reasonably well. Important is that the saturated area was predicted well by SMR and confirmed the validity of using saturation-excess mechanisms for this hillslope dominated watershed. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Hydrology↗
USGS2001

Carbon and nitrogen isotopic compositions of particulate organic matter in four large river systems across the United States

Riverine particulate organic matter (POM) samples were collected bi‐weekly to monthly from 40 sites in the Mississippi, Colorado, Rio Grande, and Columbia River Basins (USA) in 1996–97 and analysed for carbon and nitrogen stable isotopic compositions. These isotopic compositions and C : N ratios were used to identify four endmember sources of POM: plankton, fresh terrestrial plant material, aquatic plants, and soil organic material. This large‐scale study also incorporated ancillary chemical and hydrologic data to refine and extend the interpretations of POM sources beyond the source characterizations that could be done solely with isotopic and elemental ratios. The ancillary data were especially useful for differentiating between seasonal changes in POM source materials and the effects of local nutrient sources and in‐stream biogeochemical processes. Average values of δ 13 C and C : N for all four river systems suggested that plankton is the dominant source of POM in these rivers, with higher percentages of plankton downstream of reservoirs. Although the temporal patterns in some rivers are complex, the low δ 13 C and C : N values in spring and summer probably indicate plankton blooms, whereas relatively elevated values in fall and winter are consistent with greater proportions of decaying aquatic vegetation and/or terrestrial material. Seasonal shifts in the δ 13 C of POM when the C : N remains relatively constant probably indicate changes in the relative rates of photosynthesis and respiration. Periodic inputs of plant detritus are suggested by C : N ratios >15, principally on the Columbia and Ohio Rivers. The δ 15 N and δ 13 C also reflect the importance of internal and external sources of dissolved carbon and nitrogen, and the degree of in‐stream processing. Elevated δ 15 N values at some sites probably reflect inputs from sewage and/or animal waste. This information on the spatial and temporal variation in sources of POM in four major river systems should prove useful in future food web and nutrient transport studies.

Hydrological Processes↗