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At least 1,621 records · Page 90Linked to original sources

Time-courses in the retention of food material in the bivalves Potamocorbula amurensis and Macoma balthica significance to the absorption of carbon and chromium

Time courses for ingestion, retention and release via feces of microbial food was investigated using 2 bivalves with different feeding strategies, Potamocorbula amurensis and Macoma balthica . The results showed 2 pathways for the uptake of food material in these clams. The first is represented by an initial label pulse in the feces. The second pathway operates over longer time periods. Inert 51 Cr-labeled beads were used to determine time frames for these pathways. The first pathway, involving extracellular digestion and intestinal uptake, is relatively inefficient in the digestion of bacterial cells by P. amurensis but more efficient in M. balthica . The second pathway, involving intracellular digestion within the digestive gland of both clams, was highly efficient in absorbing bacterial carbon, and was responsible for most chromium uptake. Differences in the overall retention of microbial 51 Cr and 14 C relate not to gut-passage times but to the processing and release strategies of the food material by these 2 clams.

Marine Ecology Progress Series↗

Assessment of marine-derived nutrients in the Copper River Delta, Alaska, using natural abundance of the stable isotopes of nitrogen, sulfur, and carbon

We performed nitrogen, sulfur, and carbon stable isotope analysis (SIA) on maturing and juvenile anadromous sockeye and coho salmon, and periphyton in two Copper River delta watersheds of Alaska to trace salmonderived nutrients during 2003–2004. Maturing salmon were isotopically enriched relative to alternate freshwater N, S, and C sources as expected, with differences consistent with species trophic level differences, and minor system, sex, and year-to-year differences, enabling use of SIA to trace these salmon-derived nutrients. Periphyton naturally colonized, incubated, and collected using Wildco Periphtyon Samplers in and near spawning sites was 34 S- and 15 N-enriched, as expected, and at all freshwater sites was 13 C-depleted. At nonspawning and coho-only sites, periphyton 34 S and 15 N was generally low. However, 34 S was low enough at some sites to be suggestive of sulfate reduction, complicating the use of S isotopes. Juvenile salmon SIA ranged in values consistent with using production derived from re-mineralization as well as direct utilization, but only by a minority fraction of coho salmon. Dependency on salmon-derived nutrients ranged from relatively high to relatively low, suggesting a space-limited system. No one particular isotope was found to be superior for determining the relative importance of salmon-derived nutrients.

American Fisheries Society Symposium↗

Hydrology and geochemistry of carbonate springs in Mantua Valley, northern Utah

Water chemistry, tritium data, precipitation-discharge relations, geology, topography, and dye tracing were used to determine recharge areas, ground-water residence times, factors influencing ground-water flow, and aquifer characteristic for five springs that discharge from Paleozoic limestones and dolostones along the margin of Manuta Valley, northern Utah. Temperature of Mantua Valley spring water ranged between 6.0 and 15.0 degrees Celsius. Spring-water temperature indicates that depth of circulation of ground water could be as shallow as 80 feet (25 meters) to as much as 1,150 feet (350 meters). Dissolved-solids concentration in the water from springs ranged from 176 to 268 milligrams per liter. Average total hardness of spring water ranged from 157 to 211 milligrams per liter. Water from all of the springs is a calcium-magnesium-bicarbonate type that generally is undersaturated with respect to calcite and dolomite. The molar calcium/magnesium ratio in spring water ranged from 1.21 to 1.88, and indicates that ground water flows through impure dolostone or a mixed limestone and dolostone terrace. Discharge from carbonate springs in Mantua Valley ranges from about to 10 to 4,300 gallons per minute (0.6 to 271 liters per second). Seasonal variations in chemical parameters and discharge indicate that the aquifers supplying water to most of these springs are predominantly diffuse-flow systems that have been locally enhanced by bedrock dissolution. Estimated recharge area for th springs ranges from 2.7 to 7 square miles (7 to 18 square kilometers). On the basis of tritium age dating, the mean residence time of ground water discharges from Olsens-West Hallins and Maple Springs was determined to be from 3 to 9, and from 4 to 15 years, respectively. Dye tracing from point sources 2.65 miles (4.26 kilometers) southeast of Maple Spring, however, indicates a substantially faster component of flow during snowmelt runoff, with a travel time of about 5 days, or an average ground-water velocity of about 2,700 feet per day (823 meters per day).

Utah↗

Correlation of pre-Carboniferous carbonate successions of northern Alaska

Fault-bounded successions of pre-Carboniferous (meta)carbonate rocks occur throughout northern Alaska. Successions studied in detail are those in the York Mountains (Seward Peninsula), the western and eastern Baird Mountains (western Brooks Range), the Snowden Mountain area (central Brooks Range), and the Sublik and Sadlerochit Mountains (eastern Brooks range); they are correlated on the basis of the lithofacies and conodont biostratigraphy. Available lithologic and biogeographic data are best explained by postulating that these successions accumulated on a single continental margin or platform that had faunal exchange with both Siberia and North America, rather than on a series of discrete platforms juxtaposed by later tectonic events.

Alaska↗

Carbon dioxide enhanced oil recovery and residual oil zone studies at the U.S. Geological Survey

The U.S. Geological Survey (USGS) is preparing a national resource assessment of the potential hydrocarbons recoverable after injection of carbon dioxide (CO2) into conventional oil reservoirs in the United States. The implementation of CO2-enhanced oil recovery (CO2-EOR) techniques can increase hydrocarbon production, and lead to incidental retention of CO2 in reservoir pore space allowing long-term storage of anthropogenic CO2. A Comprehensive Resource Database (CRD) containing proprietary data on location, geologic, petrophysical, and reservoir parameters, plus production and well counts for major oil and gas reservoirs in onshore areas and State waters of the conterminous United States and Alaska, was developed to support the USGS assessment. Residual oil zones (ROZs) also can provide potential pore space for long-term storage of anthropogenic CO2. However, ROZs are not included in the upcoming USGS national CO2-EOR assessment because assessment methods for ROZs still are being developed. Additional ROZ CO2-EOR and CO2 retention data and reservoir simulations are needed to calibrate national ROZ assessment estimates.

Conference Paper↗

Geology and mineral resources of the Lehighton and Palmerton quadrangles, Carbon and Northampton Counties, Pennsylvania

The Lehighton and Palmerton 73 1/2-minute quadrangles cover an area of about 112 square miles of diversified terrain in the folded Appalachian Mountain and Great Valley sections of the Valley and Ridge physiographic province in Carbon, Lehigh, and Northampton Counties, Pennsylvania. The Lehigh River and Blue Mountain are the prominent features of the topography. Rock units defined and mapped in the area are the lithified sediments that were deposited in a variety of offshore marine, marine shelf, marginal marine, and fluvial environments associated with two phases of basin filling. The rocks are separated into four lithotectonic units, each deformed semi-independently of adjacent lithotectonic units. Decollements presumably separate the lithotectonic units. Lithotectonic unit 1 consists of about 12,000 feet of slate and graywacke of the Middle and Upper Ordovician Martinsburg Formation. This unit contains mainly asymmetric, similar, and nearly isoclinal folds, with wave lengths of 1,000 to 3,000 feet and amplitudes of 400 to 2,000 feet, formed mainly by passive flow and slip. Lithotectonic unit 2 includes about 3,100 feet of sandstone, siltstone, shale, and conglomerate of the Shawangunk Formation (Ordovician(?) and Silurian), Bloomsburg Red Beds (Silurian), and the lower part of the Poxono Island Formation (Silurian). This unit contains mainly asymmetric and concentric folds, with wavelengths of about one mile and amplitudes of 1,500 to 5,000 feet, formed by flexural slip with minor passive slip and flow. Lithotectonic unit 3 contains about 750 feet of limestone, shale, siltstone, sandstone, and dolomite of the upper part of the Poxono Island Formation, Bossardville Limestone, and Decker Formation (all Silurian), the Coeymans and New Scotland Formations, Shriver Chert, and Ridgeley Formation of the Oriskany Group and the Schoharie-Esopus Formation (all Lower Devonian), and the Palmerton Formation and Buttermilk Falls Limestone (both Middle Devonian). This unit has asymmetric, concentric, similar, and flap folds, with wavelengths of 1,000 to 1,500 feet and amplitudes of about 1,550 feet, formed by flexural slip and flow and passive slip and flow. Lithotectonic unit 4 consists of more than 13,000 feet of sandstone, conglomerate, siltstone, and shale of the Middle Devonian Marcellus and Mahantango Formations, the Upper Devonian Trimmers Rock and Catskill Formations, the Devonian-Mississippian Spechty Kopf Forma tion, the Mississippian Pocono and Mauch Chunk Formations, and the Pennsylvanian Pottsville Formation. This unit contains nearly symmetric, concentric flexural-slip folds with wavelengths of more than five miles and amplitudes of about one mile. Surficial deposits occur throughout the mapped area and include: Pleistocene pre-lllinoian(?) till and outwash(?), lllinoian(?) till and outwash, Wisconsinan outwash, shale-chip rubble, boulder fields, and colluvium; and Holocene alluvium, landslide deposits, and man-made dumps. The rocks of the mapped area, except for the deeply weathered lime stones, generally have good slope stability and foundation support strength, moderate to low primary infiltration capacity and aquifer potential but moderate to high secondary values for these properties, moderate resistance to weathering, and are moderately difficult to difficult to excavate. All of these properties are strongly influenced by the abundant bedding, cleavage, and joint partings of the rocks. Similar evaluations for the surficial deposits indicate less desirable values except for the ease of excavation of most of the unconsolidated materials. Currently active and potential mineral resources are numerous in the Lehighton and Palmerton quadrangles and include slate, sand, paint ore, building stone, crushed rock, lightweight aggregate, clinker residue, clay, hydraulic cement, and roofing granules.

Pennsylvania↗

Thermal conductimetric determination of submilligram amounts of total water in silicate and carbonate minerals

A simple and rapid method was developed for determining sub milligram amounts of total water in silicate and carbonate minerals. Powdered samples are fused by heating with sodium tungstate vanadium pentoxide flux in a Vycor combustion tube, and the evolved water vapor is absorbed on silica gel. After the water collection, the silica gel is heated at a controlled rate, and the released water vapor, carried by helium, is detected by thermal conductivity.

Journal of Research of the U.S. Geological Survey↗

Brannerite from the Penn Haven Junction uranium occurrence, Carbon County, Pennsylvania

Thorium-free brannerite has been identified in Upper Devonian uraniferous sandstone from Penn Haven Junction, Carbon County, Pa. The brannerite was located by a variation of the "Lexan" technique and is associated with galena, uraninite, and clausthalite. The angular thorium-free nature of the brannerite suggests that it formed by metamorphism of uranium-saturated leucoxene. As a result of the metamorphism some uranium may be in less soluble minerals than those found in the uranium deposits of the Western United States. For this reason, in-place leaching of the uranium may be impractical.

Pennsylvania↗

Mangrove habitat persistence and carbon vulnerability associated with increased nutrient loading and sea-level rise at Ding Darling National Wildlife Refuge (Sanibel Island, Florida, USA)

J.N. “Ding” Darling National Wildlife Refuge (DDNWR) is located on Sanibel Island along the southwestern coast of Florida, USA. Sanibel Island is heavily developed, but DDNWR provides protection for a large mangrove area that supports biodiversity and recreational opportunity. However, nitrogen (N) and phosphorus (P) eutrophication attributed to agriculture discharge along the Caloosahatchee River has affected the area’s aquatic habitat with algal blooms and may be causing untimely degradation of Sanibel’s mangrove forests. We launched a series of studies to understand how additional nutrient loading to the levels expected in the future might affect DDNWR’s mangrove resource. We experimentally fertilized selected mangrove forest areas with N fertilizer (+N; NH4) and P fertilizer (+P; P 2 O 5 ) for three years, and monitored soil surface elevation change, soil and pneumatophore CO 2 fluxes from respiration, mangrove tree sap flow from two species ( Avicennia germinans , Rhizophora mangle ), and individual tree and stand water use, from which we developed carbon (C) budgets for +N and +P vs. control simulations as applied to DDNWR’s 1112 ha mangrove area. Many of the measured response variables provided hints of subtle changes in response to +P rather than +N, which were compounded when scaled. From this, we found that additional P loading is expected to stimulate CO 2 uptake via net ecosystem exchange of C, likely pressing the system beyond metabolic capacity and leading to a projected 41% increase in lateral C export to the estuary. Additional lateral C export is concomitant to a reduction in vertical soil surface elevation with +P. Furthermore, an inability of DDNWR’s mangroves to bury additional P and a release of P-bound ions to lateral export may exacerbate estuarine eutrophication. We also modelled the effect of sea-level rise influences on DDNWR’s mangroves through 2100 using a soil cohort model (WARMER-Mangroves) and found that the mangroves may be resilient to current rates of sea-level rise into the future but may also be susceptible to moderate accelerations. Greater eutrophication could create additional vulnerabilities to mangrove submergence, especially to basin mangroves where P concentrations are high and already reducing soil surface elevations in some mangroves. Our results suggest that amelioration of current P concentrations and avoidance of additional P loading to Sanibel Island’s mangroves are management options to consider.

Florida↗

Coordination of space data acquisition in support of geo forest carbon tracking

The Group on Earth Observation (GEO) required for their Forest Carbon Tracking (FCT) task the assistance of the Committee on Earth Observation Satellites (CEOS) space agencies to implement coordinated data acquisition strategies from Earth Observation (EO) over key areas of interest to demonstrate the value of linking coordinated acquisition of satellite data with standardised processing methods, forest inventory and ecosystem models. Both optical and radar of midresolution have been acquired within the coordinated acquisition campaigns developed in 2009 and 2010. Homogeneous and coherent EO databases have already started by means of full key areas coverage according with suitable sensor operating modes. CEOS effort seeks now continuing with an updated strategy over expanded area coverage.

Conference Paper↗

Permafrost history in the sporadic zone as context for recent carbon loss using acryostratigraphy, plant macrofossil, and stable isotope approach

Permafrost and landscape history, in addition to ground ice content, are increasingly identified as important components in predicting permafrost thaw trajectories. Together with cryostratigraphy, plant remains and stable isotopes can provide useful information about past permafrost aggradation and thaw. We applied these methods with radiocarbon dating on peat and permafrost cores in the sporadic zone on the Kenai Peninsula, Alaska, to provide a longterm framework for understanding recent thaw and implications for carbon loss.

Alaska↗

Dealing with uncertainty and sensitivity issues in process-based models of carbon and nitrogen cycles in northern forest ecosystems

Many process-based models on carbon (C) and nitrogen (N) cycles have been developed for northern forest ecosystems. These models are widely used to evaluate the long-term decisions in forest management dealing with effects like particulate pollution, productivity and climate change. Regarding climate change, one of the key questions that have sensitive political implications is whether northern forests will sequester atmospheric C or not. Whilst many process-based models have been tested for accuracy by evaluating or validating against observed data, few have dealt with the complexity of the incorporated procedures to estimate uncertainties associated with model predictions or the sensitivity of these predictions to input factors in a systematic, inter-model comparison fashion. In general, models differ in their underlying attempts to match natural complexities with assumed or imposed model structure and process formulations to estimate model parameters, to gather data and to address issues on scope, scale and natural variations. Uncertainties may originate from model structure, estimation of model parameters, data input, representation of natural variation and scaling exercises. Model structure relates to the mathematical representation of the processes modelled and the type of state variables that a model contains. The modelling of partitioning among above- and below-ground C and N pools and the interdependence among these pools remain a major source of uncertainty in model structure and error propagation. Most soil C models use at least three state variables to represent the different types of soil organic matter (SOM). This approach results in creating three artificial SOM pools, assuming that each one contains C compounds with same turnover rate. In reality, SOM consists of many different types of C compounds with widely different turnover rates. Uncertainty in data and parameter estimates are closely linked. Data uncertainties are associated with high variations in estimating forest biomass, productivity and soil organic matter and may be incomplete for model initialization, calibration, validation and sensitivity analysis of generalized predictor models. The scale at which a model is being used also affects the level of uncertainty, as the errors in the prediction of the C and N dynamics differ from the site to the landscape levels and across climatic regions. If the spatial or temporal scale of a model application is changed, additional uncertainty arises from neglecting natural variability in system variables in time and space. Uncertainty issues are also intimately related to model validation and sensitivity analysis. The estimation of uncertainties is needed to inform decision process, in order to detect the possible corridor of development. Uncertainty in this context is an essential measure of quality for stakeholder and decision makers.

Conference Paper↗

Temporal changes in nitrogen adsorption properties of single-walled carbon nanotubes

Temporal evolution of N2 adsorption (77 K) properties of as-produced and purified single-walled nanotubes (SWNTs) samples is described here. The N2 adsorption isotherms are used to characterize the samples' surface areas and porosities. The as-produced samples demonstrate a temporal increase in surface area and pore volumes for up to 16 months. The purified samples, however, reached their stable values of surface area and pore volumes within four to seven months. N2 adsorption capacity of the purified SWNTs also increased when the fresh samples were subjected to thermal pre-processing, with diminishing changes in adsorption capacity with increased age. These observations indicate that the freshly prepared SWNTs, both as-produced and purified, were in an unstable state with their porosity changing with increasing sample age and thermal treatments. It is hypothesized that SWNTs undergo slow but progressive changes in their surface chemistry which causes their N2 adsorption properties to change over several months. ?? 2004 Elsevier Ltd. All rights reserved.

Carbon↗

Adsorption site analysis of impurity embedded single-walled carbon nanotube bundles

Bundle morphology and adsorptive contributions from nanotubes and impurities are studied both experimentally and by simulation using a computer-aided methodology, which employs a small physisorbed probe molecule to explore the porosity of nanotube samples. Grand canonical Monte Carlo simulation of nitrogen adsorption on localized sites of a bundle is carried out to predict adsorption in its accessible internal pore volume and on its external surface as a function of tube diameter. External adsorption is split into the contributions from the clean surface of the outermost nanotubes of the bundle and from the surface of the impurities. The site-specific isotherms are then combined into a global isotherm for a given sample using knowledge of its tube-diameter distribution obtained by Raman spectroscopy. The structural parameters of the sample, such as the fraction of open-ended nanotubes and the contributions from impurities and nanotube bundles to total external surface area, are determined by fitting the experimental nitrogen adsorption data to the simulated isotherm. The degree of closure between experimental and calculated adsorption isotherms for samples manufactured by two different methods, to provide different nanotube morphology and contamination level, further strengthens the validity and resulting interpretations based on the proposed approach. The average number of nanotubes per bundle and average bundle size, within a sample, are also quantified. The proposed method allows for extrapolation of adsorption properties to conditions where the purification process is 100% effective at removing all impurities and opening access to all intrabundle adsorption sites. ?? 2006 Elsevier Ltd. All rights reserved.

Carbon↗

A new sulfur and carbon degassing inventory for the Southern Central American Volcanic Arc: The importance of accurate time-series datasets and possible tectonic processes responsible for temporal variations in arc-scale volatile emissions

This work presents a new database of SO 2 and CO 2 fluxes from the Southern Central American Volcanic Arc (SCAVA) for the period 2015–2016. We report ∼300 SO 2 flux measurements from 10 volcanoes and gas ratios from 11 volcanoes in Costa Rica and Nicaragua representing the most extensive available assessment of this ∼500 km arc segment. The SO 2 flux from SCAVA is estimated at 6,240 ± 1,150 T/d, about a factor of three higher than previous estimations (1972–2013). We attribute this increase in part to our more complete assessment of the arc. Another consideration in interpreting the difference is the context of increased volcanic activity, as there were more eruptions in 2015–2016 than in any period since ∼1980. A potential explanation for increased degassing and volcanic activity is a change in crustal stress regime (from compression to extension, opening volcanic conduits) following two large (Mw > 7) earthquakes in the region in 2012. The CO 2 flux from the arc is estimated at 22,500 ± 4,900 T/d, which is equal to or greater than estimates of C input into the SCAVA subduction zone. Time‐series data sets for arc degassing need to be improved in temporal and spatial coverage to robustly constrain volatile budgets and tectonic controls. Arc volatile budgets are strongly influenced by short‐lived degassing events and arc systems likely display significant short‐term variations in volatile output, calling for expansion of nascent geochemical monitoring networks to achieve spatial and temporal coverage similar to traditional geophysical networks.

Geochemistry, Geophysics, Geosystems↗