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USGS2024

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science↗

USGS1991

Effects of septic-tank effluent on ground-water quality in northern Williamson County and southern Davidson County, Tennessee

An investigation of the potential contamination of ground water from septic tank systems blasted in bedrock in Williamson and Davidson Counties, Tennessee, was conducted during 1988-89. Water samples were collected from domestic and observation wells, springs, and surface-water sites in a residential subdivision in the northern part of Williamson County near Nashville. The subdivision has a high density of septic-tank field lines installed into blasted bedrock Water samples also were collected from a well located in an area of Davidson County where field lines were installed in 5 feet of soil. Samples were analyzed for major inorganic constituents, nutrients, total organic carbon, optical brighteners, and bacteria. Although results of analyses of water samples from wells indicate no effect of septic-tank effluent on ground-water quality at these sites, water from two springs located downgradient from the subdivision had slightly larger concentrations of nitrite plus nitrate (2.2 and 2.7 milligrams per liter N), and much larger concentrations of fecal coliform and fecal streptococci bacteria (2,000 to 3,200 and 700 to 900 colonies per 100 milliliters of sample, respectively), than other wells and springs sampled during 1988. Water from one of these springs contained optical brighteners, which indicates that septic-tank effluent is affecting ground-water quality.

Tennessee↗

USGS2024

Streamflow depletion caused by groundwater pumping: Fundamental research priorities for management-relevant science

Reductions in streamflow caused by groundwater pumping, known as “streamflow depletion,” link the hydrologic process of stream-aquifer interactions to human modifications of the water cycle. Isolating the impacts of groundwater pumping on streamflow is challenging because other climate and human activities concurrently impact streamflow, making it difficult to separate individual drivers of hydrologic change. In addition, there can be lags between when pumping occurs and when streamflow is affected. However, accurate quantification of streamflow depletion is critical to integrated groundwater and surface water management decision making. Here, we highlight research priorities to help advance fundamental hydrologic science and better serve the decision-making process. Key priorities include (a) linking streamflow depletion to decision-relevant outcomes such as ecosystem function and water users to align with partner needs; (b) enhancing partner trust and applicability of streamflow depletion methods through benchmarking and coupled model development; and (c) improving links between streamflow depletion quantification and decision-making processes. Catalyzing research efforts around the common goal of enhancing our streamflow depletion decision-support capabilities will require disciplinary advances within the water science community and a commitment to transdisciplinary collaboration with diverse water-connected disciplines, professions, governments, organizations, and communities.

Water Resource Research↗

USGS2024

Comparison of water quality in shallow groundwater near agricultural areas in the Delaware Coastal Plain, 2014 and 2019

The State of Delaware has encouraged agricultural conservation practices to improve nutrient uptake by crops and mitigate nutrient transport to groundwater in the surficial aquifer. To study recent changes in groundwater quality, the U.S. Geological Survey and the Delaware Department of Agriculture (DDA) developed a network of shallow wells near agricultural areas throughout the Delaware Coastal Plain. This network was designed to characterize water quality related to agricultural practices and to detect any recent changes in shallow groundwater quality, in particular groundwater nitrate concentrations. The shallow well network was first sampled in 2014 and resampled in 2019. In 2019, field parameters (including dissolved oxygen, pH, specific conductance, and temperature), major ions, nutrients, stable isotopes of water, and isotopes of nitrate were measured in groundwater samples collected between October and December. Wells were organized into three groups based on their geochemical characteristics measured in 2014: the Agricultural, Urban, and Mixed Groups. Results from the 2019 sampling showed little change in water quality from the 2014 sampling. Land-use factors continued to be the driving influence between groups. Groundwater moves slowly and changes in groundwater quality are likely to respond slowly to changes in conservation practices. Continued sampling of both groundwater quality in this network and monitoring land management practices can help detect groundwater quality trends in the future.

Delaware↗

USGS2026

Tectonic implications of transitional melting regimes from petrological, geochronological, and compositional characterization of the ophiolitic Seventymile terrane, Alaska, USA

New geochemical, U-Pb geochronology, and Sr-Nd-Hf isotope data provide evidence for the tectonic evolution of the Seventymile terrane in interior Alaska, USA. Ultramafic and mafic rocks of the Seventymile terrane are thought to represent components of a dismembered ophiolite and provide unique constraints on regional terrane evolution and accretion. The Seventymile ophiolite represents fragments of the Devonian to Permian Slide Mountain Ocean (SMO) that separated allochthonous and parautochthonous continental fragments of western North America. It now occurs as multiple thrust sheets containing Permian mafic and ultramafic rocks overlying and/or possibly imbricated with amphibolite-facies supracrustal rocks of allochthonous Yukon-Tanana terrane and parautochthonous North America. Seventymile klippen contain variably serpentinized peridotite, primarily harzburgite, low-grade meta-mafic rocks, and minor oceanic sedimentary rocks (argillite, chert, limestone, and metasandstone). Mafic rocks include gabbro to diabase, typically as dikes, veinlets, or rare massive stocks intruding peridotite. Mafic rocks also include greenstones of the Seventymile assemblage in klippen structurally underlying, and in shear zone contact with, ultramafic klippen. New trace element and radiogenic isotope data from mafic magmatic rocks associated with the Seventymile ultramafic bodies show evidence for a weakly subduction-modified mantle source, like the mantle source of normal mid-ocean-ridge basalt (N-MORB) or back-arc basin basalt (BABB). Seventymile assemblage greenstones are more heterogeneous. They range from N-MORB to enriched mid-ocean-ridge basalt (E-MORB) and ocean-island basalt (OIB), with a subset of samples indicative of continental arc affinity. These geochemistry results indicate that distinct tectonic environments are represented by at least two, and possibly three, lithological and structural units comprising the Seventymile terrane. Hf-Nd isotope systematics are consistent with a depleted MORB mantle (DMM)−like component that overlaps with Pacific MORB. Primary zircon is rare, but new in situ U-Pb data for gabbro and greenstone indicate ca. 274−272 Ma peak zircon and titanite crystallization. Scattered younger zircons define a ca. 255 Ma zircon peak and correspond to secondary crystallization associated with baddeleyite reaction of high-Si fluids during low-grade metamorphism. If Seventymile suites are contemporaneous, obduction associated with the closure of the SMO resulted in the stacking of ophiolitic packages representing distinct tectonomagmatic settings across the transition from pericontinental, to epicontinental, to distal ocean back-arc. Intrusions hosted in klippe of ultramafic rocks, plus the least subduction-modified greenstones underlying them, geologically and compositionally resemble Slide Mountain rocks of the Campbell Range formation in eastern Yukon and may provide a new piercing point across the Tintina fault.

Alaska, British Columbia↗

USGS2026

Predictions of anthropogenic background PFAS concentrations in soil and relation to bedrock lithology and groundwater quality

Detectable concentrations of per- and polyfluoroalkyl substances (PFAS) have been observed in soils in remote areas and presumably originate from atmospheric deposition. These anthropogenic background concentrations may enable some PFAS to leach to groundwater at levels that exceed regulatory criteria for drinking water. However, anthropogenic background soil concentrations and their connection to groundwater are not well characterized. We developed a boosted regression tree model to predict perfluorooctanesulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) concentrations in shallow soils across northern New England. Low soil pH was the most important predictor of elevated anthropogenic PFOS and PFOA concentrations in background soils, rather than potential PFAS sources, land use, or population density. Total organic carbon (TOC) was also an important predictor for PFOS soil concentrations. Model predictions indicate that 73% of the shallow soils within Maine, Vermont, and New Hampshire exceed New Hampshire’s Soil Remediation Standard for PFOS (0.5 ng/g) and 41% exceed the PFOA standard (0.4 ng/g). Analysis of soil model results and groundwater data suggests that areas with high soil pH are associated with higher groundwater detection frequencies, illustrating how areas with less retention in soil are, conversely, also areas with potentially greater groundwater vulnerability. Further analysis indicates that groundwater may be more vulnerable in calcareous lithologies.

Maine, New Hampshire, Vermont↗

USGS2025

Estimated ultimate recovery (EUR) Prediction for Eagle Ford Shale using integrated datasets and artificial neural networks

The estimated ultimate recovery (EUR) is an important parameter for forecasting oil and gas production and informing decisions regarding field development strategies. In this study, we combined site-specific geologic, completion, and operational parameters with the predictive capabilities of machine learning (ML) models to predict EURs of the wells for the Eagle Ford Marl Continuous Oil Assessment Unit. We developed an extensive dataset of wells that have produced from the lower and upper Eagle Ford Shale intervals and reduced the model complexity using principal component analysis. We tested the ML models and estimated the sensitivities of ML-predicted EURs to changes in the values of different input variables. The results of applying the optimized ML model to the Eagle Ford suggest that the approach developed in this study could be promising. The ML estimates of the EURs fit the DCA-based values with an R 2 ~ 0.9 and a mean absolute error of ~36 × 10 3 bbl. In the lower Eagle Ford Shale, the EUR estimates were found to be most sensitive to changes in porosity, net thickness of the interval, clay volume, and the API gravity of the oil; and that in the upper Eagle Ford Shale they were most sensitive to changes in the total organic carbon and water saturation, which suggests that it could be important to consider these parameters in assessing these intervals or close analogs.

Louisiana, Mississippi, Texas↗

USGS2026

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes↗

USGS2024

A conceptual framework to assess post-wildfire water quality: State of the science and knowledge gaps

Wildfire substantially alters aquatic ecosystems by inducing moderate to catastrophic physical and chemical changes. However, the relations of environmental and watershed variables that drive those effects are complex. We present a Driver-Factor-Stressor-Effect (DFSE) conceptual framework to assess the current state of the science related to post-wildfire water-quality. We reviewed 64 peer-reviewed papers using the DFSE framework to identify drivers, factors, stressors, and effects associated with each study. A total of five drivers were identified and ranked according to their frequency of occurrence in the literature: atmospheric processes > fire characteristics > ecologic processes and characteristics > land surface characteristics > soil characteristics. Commonly reported stressors include increased nutrients, runoff, and sediment transport. Furthermore, although several different factors have been used at least once to explain water-quality effects, relatively few factors outside of precipitation and fire characteristics are frequently studied. We identified several gaps indicating the need for long-term monitoring, multi-factor studies, consideration of organic contaminants, consideration of groundwater, and inclusion of soil characteristics. This assessment expands on other reviews and meta-analyses by exploring causal linkages between influential variables and overall effects in post-wildfire watersheds. Information gathered from our assessment and the framework itself can be used to inform future monitoring plans and as a guide for modeling efforts focused on better understanding specific processes or to mitigate potential risks of post-wildfire water quality.

Water Resources Research↗

USGS2023

Explosive trachyte eruptions from the Al Efairia volcanic center in northern Harrat Rahat, Kingdom of Saudi Arabia

Harrat Rahat is an alkali basalt, continental, intraplate volcanic field located within the central-western part of the Kingdom of Saudi Arabia. The northern quarter of Harrat Rahat contains evolved volcanic products that achieve trachyte compositions (>60 weight percent SiO 2 ). Within the Al Efairia volcanic center, pyroclastic-flow and -surge deposits that reflect explosive trachyte volcanism (and minor exposed lava domes that reflect effusive trachyte eruptions) sit at the surface as the youngest expression of volcanic activity within this part of the Harrat Rahat volcanic field. Five trachyte deposits emplaced explosively have been identified within the Al Efairia volcanic center based on geologic mapping, petrography, geochemistry, and paleomagnetism. These units are the trachytes of Um Rgaibah, Gura 5, Gura 4, Al Efairia, and Al Qayf, in descending stratigraphic order. Here, we present 14 40 Ar/ 39 Ar analyses from four of these units, which yield eruption ages of 4.2±5.2 thousand years (ka) for the trachyte of Um Rgaibah, 79.7±1.6 ka for the trachyte of Gura 5, 84.3±1.6 ka for the trachyte of Gura 4, and 88.0±1.8 ka for the trachyte of Al Efairia. The eruption age of the trachyte of Al Qayf has been constrained to between 410.3±3.4 and 418.8±1.9 ka using paleomagnetic correlations and 40 Ar/ 39 Ar ages from overlying and underlying intermediate composition lava flows. Most of these trachytes have distinct geochemical compositions, petrographic characteristics, and directions of remanent magnetization. The exceptions are for the trachytes of Gura 4 and Gura 5, which overlap in their geochemical, petrographic, paleomagnetic, and geochronologic affinities. Based on these similarities, we interpret the trachytes of Gura 4 and Gura 5 to have erupted during a closely spaced (a few decades) time interval from the same magma batch but from craters that are >2 kilometers (km) apart. The eruption of the trachyte of Al Efairia at 88.0±1.8 ka is the result of a different magma batch that erupted a few thousand years prior to the trachytes of Gura 4 and Gura 5. The Al Efairia volcanic center is remarkably different from the Matan volcanic center located ~10 km to the north, which has also erupted young (<150 ka) trachytes. The Matan volcanic center has been shown to produce trachyte compositions only after eruption of basalt followed by intermediate lava flows, whereas only trachyte compositions have erupted within the Al Efairia volcanic center over this same time interval.

Al Efairia volcanic center, Harrat Rahat↗

USGS2026

Variable pH habitats could help prepare stone crabs for coastal acidification

Coastal acidification is being exacerbated by terrestrial organic inputs, especially after high precipitation events. Florida’s rainy season coincides with stone crab ( Menippe mercenaria) reproduction, and pH extremes could limit future harvests by reducing reproductive output. Populations that experience pH variability can serve as “natural laboratories” for estimating the tolerance of a species to coastal acidification. Here, we conducted a series of experiments to determine if ovigerous stone crabs conditioned in more variable pH habitats (seagrass) would result in faster embryonic development, greater hatching success, and higher larval survival relative to crabs conditioned in habitats with lower pH variability (sandy habitats). After field conditioning, crabs were transported to the laboratory and randomly acclimated to either a control pH (pH = ~ 7.90) or a reduced pH condition (pH = ~ 7.60) until larval release. The rate of embryo development was slower in the laboratory reduced pH treatment, however, there were no observable field condition effects on embryo development rate. Crabs conditioned in the more pH variable seagrass habitat did have greater hatching success and higher larval survival than crabs in less pH variable sandy habitats; however, larval survival was low across all treatments. These results suggest that the pH variability experienced in seagrass habitats during brooding may serve as a mechanism for stone crabs to acclimatize to extremes in seawater pH.

Marine Biology↗

USGS1976

Uranium and trace elements in stream sediments as an exploration tool

More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.

Open-File Report↗

USGS2025

Laboratory assessment for recovery of porcine circovirus 2 and porcine reproductive and respiratory syndrome virus using two types of commercially available hollow-fiber ultrafilters

Groundwater near swine farms is an uninvestigated reservoir for porcine reproductive and respiratory syndrome virus (PRRSV) and porcine circoviruses (PCVs). Enteric microorganisms are often collected from groundwater via dead-end ultrafiltration, but recovery of PRRSV and PCV with this method has not been assessed. We recovered PRRSV2 and PCV2 by dead-end ultrafiltration followed by polyethylene glycol (PEG) precipitation, nucleic acid extraction, and reverse-transcription quantitative real-time PCR. We also compared 2 commercial hemodialysis ultrafilters (Asahi Kasei Rexeed-25A, Nipro Elisio-25H) and compared PRRSV2 recovery in these filters to other waterborne microorganisms. On average, 8 ± 1% of PRRSV2 was recovered by dead-end ultrafiltration and PEG precipitation, compared to 25 ± 6% for adenovirus 41. Full-process recovery of bacteria in the same filters was 5–15%; Cryptosporidium parvum recovery was 42 ± 12%. PCV2 was detected in 4 of 12 replicate filters, but low stock concentrations precluded quantitative recovery estimates. Elisio-25H ultrafilters performed similarly to Rexeed-25A filters for all organisms tested and is an effective replacement for the Rexeed-25A, which is no longer available in the United States. Our recovery of PRRSV2 and PCV2 by dead-end ultrafiltration in the laboratory suggests that PRRSV2 detection limits are as low as 3–50 genomic copies/L in sample volumes of 100–1,500 L. Based on quantitative microbial risk assessment, these concentrations are relevant to PRRSV2 infection rates in the U.S. swine herd.

Journal of Veterinary Diagnostic Investigation↗

USGS1995

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida↗

USGS2024

Anaerobic biodegradation of perfluorooctane sulfonate (PFOS) and microbial community composition in soil amended with a dechlorinating culture and chlorinated solvents

Perfluorooctane sulfonate (PFOS), one of the most frequently detected per - and polyfluoroalkyl substances (PFAS) occurring in soil, surface water, and groundwater near sites contaminated with aqueous film-forming foam (AFFF), has proven to be recalcitrant to many destructive remedies, including chemical oxidation. We investigated the potential to utilize microbially mediated reduction (bioreduction) to degrade PFOS and other PFAS through addition of a known dehalogenating culture, WBC-2, to soil obtained from an AFFF-contaminated site. A substantial decrease in total mass of PFOS (soil and water) was observed in microcosms amended with WBC-2 and chlorinated volatile organic compound (cVOC) co-contaminants — 46.4 ± 11.0 % removal of PFOS over the 45-day experiment. In contrast, perfluorooctanoate (PFOA) and 6:2 fluorotelomer sulfonate (6:2 FTS) concentrations did not decrease in the same microcosms. The low or non-detectable concentrations of potential metabolites in full PFAS analyses, including after application of the total oxidizable precursor assay, indicated that defluorination occurred to non-fluorinated compounds or ultrashort-chain PFAS. Nevertheless, additional research on the metabolites and degradation pathways is needed. Population abundances of known dehalorespirers did not change with PFOS removal during the experiment, making their association with PFOS removal unclear. An increased abundance of sulfate reducers in the genus Desulfosporosinus (Firmicutes) and Sulfurospirillum (Campilobacterota) was observed with PFOS removal, most likely linked to initiation of biodegradation by desulfonation. These results have important implications for development of in situ bioremediation methods for PFAS and advancing knowledge of natural attenuation processes.

Science of the Total Environment↗

USGS2024

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey↗

USGS2024

Sensitivity of Alabama freshwater gastropod species to nickel exposure

Snails are effective bioindicators due to their prolific distribution, high level of endemism, and capacity to accumulate contaminants. Freshwater snails have unique ecological niches which are imperiled by land‐use change and the introduction of hazardous chemicals. To assess how environmental alterations affect gastropods, lab‐based studies are needed to characterize the toxicity of specific stressors. This can help guide policy decisions and remediation efforts. The aim of this research was to characterize acute toxicity of nickel (Ni) on endemic snails ( Somatogyrus georgianus [Walker, 1904], Elimia cahawbensis [Lea, 1861], and Elimia spp.) and measure the accumulation of Ni and mineral elements including calcium (Ca), magnesium, potassium, and sodium (Na). Snails were exposed to six concentrations (25–800 µg/L) of Ni for 96 h. Among the studied snail species, E. cahawbensis was the most sensitive to Ni, with the lowest lethal concentration where 50% of the organisms died (LC50) at 88.88 µg/L Ni after 96 h. The LC50 at 96 h for S. georgianus was 167.78 µg/L Ni, and 393.13 μg/L Ni for Elimia spp. Except for Elimia spp., mortality of the other two snail species corresponded to the whole‐body uptake of Ni. Nickel exposure also influenced Ca and Na uptake for Elimia spp. All three endemic species are potential candidate species for evaluating localized effects of human activities, and the present study provides a first step in characterizing how snails would be affected by environmental alterations. More research could further characterize potential effects of other human stressors on these endemic snail species. Future research into subindividual responses and routes of exposure can further elucidate variations in species sensitivity.

Alabama↗

USGS2025

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California↗