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Simulated ground motion dataset in the Azores Plateau, Portugal, on rock and soil sites

Building on a previously developed bedrock dataset, this study extends the Azores Plateau ground motion simulations to include soil-amplified records and introduces a comprehensive validation framework. Soil amplification is modeled using one-dimensional soil profiles. A stochastic source-based approach is employed to generate the dataset, incorporating randomization of input-model parameters to account for the aleatory uncertainty in seismic activity. The accuracy of the dataset is verified through a comprehensive validation framework, showing that the randomization effectively captures variance and inter-period correlation observed in records. This work provides a robust dataset for advancing seismic hazard and risk assessment in the Azores Plateau.

central and eastern Azores islands

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Stream habitat characteristics at selected sites in the Georgia-Florida coastal plain

Habitat characterization is part of a multidisciplinary approach to water-quality assessment implemented by the National Water-Quality Assessment Program. Habitat data were collected in the Georgia-Florida Coastal Plain study unit at 24 sites during 1993-95. Data were collected for habitat characteristics at three spatial scales: basin, segment, and reach. Basin data include physiography, land resource provinces, and land use, providing a description of the environmental setting at each site. Segment data include length, gradient, and sinuosity. A Kendall correlation analysis performed on segment characteristics and the log-of-basin area showed a correlation between segment gradient and the log-of-basin area and a correlation between sinuosity and segment length. Reach data consist of field-collected measurements of both instream and riparian habitats. Sand and detritus were the most common channel-bed substrates among the sampled sites. Measurements of channel width, water depth, and bank width and height were used to create cross-sectional profiles of each sampled area. Elevations of selected durations plotted on cross sections illustrated the percentage of time that the banks were inundated at each site. Sites were divided into two groups based on duration of bank inundation (less than or equal to 1 percent and greater than 1 percent). Bank woody vegetation was also sampled and a clustering algorithm known as Two-Way INdicator SPecies ANalysis (TWINSPAN) was used to analyze these data. TWINSPAN divided the sites into two groups based on their vegetation composition. A statistical comparison of the two types of site groups (duration of bank inundation and vegetation) was performed. The significant association between these groups was consistent with the hypothesis that inundation frequency affected riparian vegetation.

Florida, Georgia

Base flow and ground water in upper Sweetwater Valley, Tennessee

The upper Sweetwater Valley area has a flow system with complex interaction between surface and ground water. A water budget study indicated that during dry years approximately three-fourths of the annual flow to Sweetwater Creek may be derived from ground-water sources. Hydrograph analysis showed seasonal variation of recharge to the ground-water flow system. Streamflow records were analyzed to estimate the frequency of low flow of Sweetwater Creek at river mile 16.7, and indicated the lowest average flow for 1 day in 20 years to be about 5.1 cubic feet per second. Two periods of base-flow measurements of Sweetwater Creek identified channel reaches with significant gains and losses of streamflow. Base flow measurements also showed interbasin transfer of water among sub-basins of the valley. Major flow surpluses were associated with areas in which the majority of flow originated at a spring. Topographically low areas adjacent to the main stem of Sweetwater Creek generally have surplus flow. Topographically higher areas generally have deficient surface outflow unless significant spring flow occurs in the basin. Ground-water recharge occurs by water draining into sinkholes, faults, and fractures. Ground-water flow is regionally diffused across formation strikes from the topographically low areas unless the water is exposed to highly permeable formations or impervious formations. Ground water infiltrates the highly permeable formations and flows along strike. Ground water encountering impervious formations may discharge at small springs at the contact, or may reroute along the contact if the upgradient rock is sufficiently permeable or has well developed secondary porosity. Groundwater discharges to streams at innumerable seeps and at a few large springs. Areas of ground-water flow up-gradient of large springs are hypothesized as likely areas of significant ground-water reservoirs.

Tennessee

Simulation of groundwater flow in the Long Island, New York regional aquifer system for pumping and recharge conditions from 1900 to 2019

The U.S. Geological Survey has developed a transient, groundwater-flow model that simulates hydrologic conditions in the Long Island aquifer system as part of an ongoing (since 2016) multiyear, cooperative investigation with the New York State Department of Environmental Conservation. The goals of this investigation are to assist stakeholders and resource managers to evaluate the response of the hydrologic system to changes in future hydraulic stresses. Responses in the hydrologic system include changes in water levels in the hydrogeologic units; discharge to streams, coastal waters, and subsurface infrastructure; and the extent of saline groundwater in the aquifers. Hydraulic stresses include future water-supply management and changes in land use and infrastructure. The numerical model synthesizes a diverse set of physiographic, geologic, climatic, land-use, and historical population, water use, and infrastructure data to physically represent the Long Island aquifer system from land surface to bedrock and to simulate annual hydrologic conditions between 1900 and 2019. A three-dimensional hydrogeologic framework was developed from existing and recently collected borehole geologic and geophysical data collected as part of a companion drilling program. Water-transmitting properties of the principal aquifer sediments were defined in three dimensions from new and existing lithologic logs. The distribution of recharge from precipitation was estimated from landscape characteristics and climate data. Anthropogenic recharge from wastewater, leaky infrastructure, and storm runoff were estimated from population, infrastructure, and pumping data. Water-use data, including well locations, depths, and pumping rates, were obtained from historical sources and records and used to estimate pumping stresses continuously in time and space, at an annual average time scale. The data were incorporated into a three-dimensional numerical model using the U.S. Geological Survey finite difference modeling code MODFLOW 6; the model encompassed all of Long Island and surrounding surface waters and simulated historical hydrologic conditions from 1900 to 2019. The calibration process involved trial and error adjustments using prior knowledge to improve general fit to observations followed by an inverse calibration to update and optimize input parameters, using an iterative ensemble smoother algorithm implemented in PEST++ version 5.0. This resulted in a model that generally was in good agreement with observed, dynamically varying hydrologic conditions from 1900 to 2019. The calibrated model was used to develop two base-case models for scenario testing of future, hypothetical conditions where one represented average-annual conditions, and one represented average-seasonal conditions from 2010 to 2019. The model representing average-annual conditions was modified further to represent an alternate sea-level position of 6 feet above the North American Vertical Datum of 1988, and the model representing average-seasonal conditions was modified to represent the average seasonal effects of a 5-year drought imposed upon current hydrologic conditions. Recharge is the sole source of water to the aquifer system; groundwater discharges to coastal water and streams and is withdrawn by pumped wells. Model-estimated annual recharge ranged from about 11 inches in 1965 to 41 inches in 1983. On average, from 2010 to 2019, about 23 percent of water was pumped from wells, and about 47 and 27 percent discharged to coastal waters and streams, respectively; the remaining 4 percent was water that moved into storage in the aquifer matrix. Water levels on Long Island vary naturally during time in response to changes in recharge; the amount of variation is largest in the interior of the island, in areas with highest water table altitudes near groundwater divides and lowest near streams and the coastal waters. The total range of water table altitudes on Long Island between 1900 and 2019 ranged from near 0 to more than 70 feet in western parts of Long Island. The largest range in altitudes is in New York City and is associated with areas of large historical withdrawals between the 1920s and the late 1980s. Water table altitudes generally varied by less than 10 feet in eastern Suffolk County, where the aquifer is under more natural conditions. Saltwater intrusion is of great concern on Long Island, particularly in western Long Island where both the unconfined and confined parts of the aquifer system have been intruded in response to large-scale groundwater withdrawals; however, the volume of freshwater in the islandwide aquifer system only has changed by about 5 percent between 1900 and 2019. The decadal change in the freshwater volume was largest during the early and mid-20th century, corresponding to the largest historical pumping, but that volume change did not exceed 1 percent. The negligible change in freshwater volume suggests that saltwater intrusion as of 2019 was limited at an islandwide scale but continues to occur in local areas of Queens and Nassau Counties, adversely affecting current water supplies and limiting future water supplies for affected communities. The regional groundwater model developed for this investigation is a tool that can be used to help determine the viability of current and future water supplies at a regional scale and can be used to support development of additional models at finer scale to support more focused assessments of groundwater sustainability.

New York

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2024

Potentiometric-surface and depth-to-water maps for spring 2024 were created for the Mississippi River Valley alluvial aquifer using groundwater-altitude data from 1,151 wells completed in the Mississippi River Valley alluvial aquifer and from the altitude of the top of the water surface in area rivers from 160 U.S. Geological Survey and U.S. Army Corps of Engineers streamgages. The potentiometric-surface and depth-to-water maps for 2024 were created to support investigations to characterize the Mississippi River Valley alluvial aquifer as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the Mississippi River Valley alluvial aquifer for spring 2024 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 330 feet (ft) above the North American Vertical Datum of 1988. The regional direction of the groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient direction was into the depression, and near rivers, where the groundwater gradient direction was either from the aquifer to the river or from the river into the aquifer. Groundwater depressions in the potentiometric-surface map are in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions. Depth to water by well in the Mississippi River Valley alluvial aquifer in spring 2024 ranged from 0.27 ft above land surface to 145.65 ft below land surface.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas

Imaging of seismic discontinuities using an adjoint method

For imaging of seismic discontinuities at depth, reverse time migration (RTM) is a powerful method to apply to recordings of seismic events. It is especially powerful when an extensive receiver array, numerous seismic sources, or both, permit adequate reconstruction of incident and scattered wavefields at depth. Reconstructing either the incident or scattered wavefield at depth becomes less accurate when relatively few recordings of seismic events are available. Here we explore an inverse scattering approach to imaging discontinuities based on an adjoint method, employing sensitivity kernels (Frechet derivatives) that represent jumps in material properties across seismic-discontinuity surfaces. When combined with ray-based requirements on scattering geometry, it constitutes a powerful approach to determining the locations and amplitudes of the discontinuities, recovering only those properties that can be resolved by a spatially limited source and/or receiver distribution. This is illustrated by synthetic examples with local sources followed by a field example in a subduction zone setting

Washington

Deep syntectonic burial of the Anthracite belt, Eastern Pennsylvania

Fluid inclusion microthermometry and Raman spectroscopy of fluid inclusions in quartz veins from the Pennsylvanian rocks of the Anthracite belt, eastern Pennsylvania support a deep burial model of coalification in favor of focused orogenic hot fluid flow. High-temperature (250 to 255 °C) trapping of CH 4 ± CO 2 saturated aqueous fluids and CH 4 ± CO 2 inclusions indicate fluid trapping at depths of 11.5 to 13.4 km under a cover of Pennsylvanian to Permian(?) syntectonic load. In the folded rocks to the south of the Anthracite belt, CH 4 ± CO 2 fluid inclusions indicate a sediment load that was up to 16.3 km thick. Re -equilibrated aqueous fluid inclusions from veins in Silurian through Devonian rocks give the same range of trapping conditions but a wide range of fluid salinities suggesting that folding, fracturing, and meteoric recharge resulted in the intermixing of fluids from throughout the stratigraphic succession.

Pennsylvania

Remote compositional analyses of space-weathered lunar maria

Visible-to-shortwave infrared (VSWIR) reflectance spectroscopy has revolutionized our understanding of planetary surface compositions. However, space-weathering processes on airless bodies complicate quantitative compositional analyses. Here, we present a framework to isolate the signatures of space weathering in VSWIR spectra of lunar maria by leveraging radiative transfer modeling under the assumptions that (i) a space-weathered target can be expressed as a mixture of fresh and fully space-weathered components and (ii) remaining signatures can be modeled by including agglutinates as an end-member component. We first validate this approach against laboratory spectra of space-weathered Apollo mare soils of known mineral compositions using a probabilistic Markov Chain Monte Carlo implementation of the Hapke radiative transfer model. Second, we illustrate how this approach can be applied to orbital Moon Mineralogy Mapper data. The proposed space-weathering correction workflow for lunar maria could be expanded to other lunar lithologies and applied to existing and future data sets.

Planetary Science Journal

Statewide surficial geologic map of Nebraska underscores Quaternary landscape evolution from the High Plains to the Central Lowland

Surficial geologic mapping in Nebraska has been conducted primarily at the 1:24,000 scale since the mid-1990s, although there have also been limited efforts to map generalized Quaternary and surficial geology within the state and the region. We compiled and evaluated disparate maps (1:24,000–1:1,000,000) and datasets—including geologic, soil and soil parent material, and geomorphic maps as well as LiDAR derivatives—to produce a single 1:500,000 scale surficial geologic map of Nebraska that is the first of its kind. This new map provides a coarse-scale surficial geologic map that will be incorporated into a nationwide U.S. Geological Survey Quaternary geologic map. It also reflects the variation and uniqueness of physical landscapes in the state, where the Great Plains and Central Lowland physiographic provinces meet, further developing a richer interdisciplinary understanding of regional geomorphology in the heart of North America.

Nebraska

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas

Analysis of nutrients in the surface waters of the Georgia–Florida Coastal Plain study unit, 1970–91

During the early phase of the Georgia-Florida National Water Quality Assessment study, existing information on nutrients was compiled and analyzed in order to evaluate the nutrient concentrations within the 61,545 square mile study unit. Evaluation of the nutrient concentrations collected at surface-water sites between October 1, 1970, and September 30, 1991, utilized the environmental characteristics of land resource provinces, land use, and nonpoint and point-source discharges within the study unit. Long-term trends were investigated to determine the temporal distribution of nutrient concentrations. In order to determine a level of concern for nutrient concentrations, the U.S. Environmental Protection Agency (USEPA) guidelines were used: (1) for nitrate concentrations, the maximum contaminant level in public-drinking water supplies (10 mg/L); (2) for ammonia concentrations, the chronic exposure of aquatic organisms to un-ionized ammonia (2.1 mg/L); (3) for total-phosphorus concentrations, the recommended concentration in flowing water to discourage excessive growth of aquatic plants (0.1 mg/L); and (4) for kjeldahl concentrations, however, no guidelines were available. For sites within the 10 major river basins, median nutrient concentrations were enerally below USEPA guidelines, except for total-phosphorus concentrations where 45 percent of the medians exceeded the guideline. The only median ammonia concentration that exceeded the guideline occurred at the Swift Creek site (3.4 mg/L), in the Suwannee River basin, perhaps due to wastewater discharges. For all sites within the Withlacoochee, Aucilla, and St. Marys River basins, median concentrations of nitrate, ammonia, and total phosphorus were below the USEPA guidelines. Nutrient data at each monitoring site within each major basin were aggregated for comparisons of median nutrient concentrations among major basins. The Ochlockonee and Hillsborough River basins had the highest median nutrient concentrations, the Aucilla River basin had the lowest. Median concentrations of nitrate and ammonia among all major basins were below USEPA guidelines. The median total-phosphorus concentrations for the following river basins exceeded the USEPA guideline: Hillsborough, St. Johns, Suwannee, Ochlockonee, Satilla, Altamaha, and Ogeechee. Although nutrient concentrations within the study unit were low, long-term increasing trends were found in all four nutrients. All 18 study-unit wide nitrate trends had increasing slopes ranging from less than 0.01 to 0.07 (mg/L)/yr. The range in slope for the 13 ammonia trends was -0.03 to 0.01 (mg/L)/yr with 6 increasing trends in the northern part of the study unit. Of the 17 total-phosphorus trends found in the study unit, 10 were found at sites where the median concentration exceeded the USEPA guideline. At these 10 sites, 4 sites had increasing trends with slopes ranging from less than 0.01 to 0.07 (mg/L)/yr, 5 sites had decreasing trends with slopes ranging from -0.01 to -0.24 (mg/L)/yr, and one site showed a seasonal concentration trend. Median nutrient concentrations were significantly different among the four land resource provinces: Southern Piedmont, Southern Coastal Plain, Coastal Flatwoods, and Central Florida Ridge. As a result, nutrient concentrations among basins with similar nutrient inputs but located within different land resource provinces are not expected to be the same due to differences in the combination of factors such as soil permeability, runoff rates, and stream channel slopes. This concept is an important consideration in designing a surface-water quality network within the study area. For the most part, the Coastal Flatwoods showed the lowest median nutrient concentrations and the Southern Coastal Plain had the highest median nutrient concentrations. Lower median nitrate concentrations in surface-water basins were associated with the forest/wetland land-use category and higher median concentrations of nitrate and ammonia with the urban category when land-use percentages were classified into four land-use categories (agriculture, forest/wetland, mixed, and urban). These results were reasonable based on expected high nutrient inputs from urban areas and low inputs from forested and wetland areas. However, the lack of association between high nutrient concentrations and the agricultural land-use category was not expected since high nutrient inputs are generally needed for agriculture production.

Florida, Georgia

Evaluating the impact of uncertainty in ground motion forecasts for post-earthquake impact modeling applications

The US Geological Survey’s (USGS) ShakeMap system provides a rapid characterization of strong ground shaking in areas directly affected by an earthquake. This study focuses on studying the aggregate effects of macroseismic shaking estimates from ShakeMap, expressed in terms of modified Mercalli intensity (MMI), when accounting for the uncertainty in forecasted ground motions. We use a Monte Carlo approach to generate numerous spatially correlated realizations of ground motions by utilizing a combination of circulant embedding and kriging techniques for efficiently handling the correlations. We then assessed the aggregate effects of shaking by looking at bin counts across these realizations. We demonstrate that the aggregate shaking regarding the mean macroseismic intensity estimates (from the ShakeMap output) is a biased representation of the aggregate shaking when shaking uncertainty is included. Incorporating shaking uncertainty can help to improve various downstream earthquake impact applications, such as the USGS Prompt Assessment of Global Earthquakes for Response (PAGER) overall earthquake fatality distribution or estimates of shaking-induced ground failure impacts from consequential earthquakes.

Earthquake Spectra Journal

Synthesizing a twelve-year sediment trap time series of planktic foraminiferal flux in the Gulf of America (Mexico)

Sediment trap time series provide powerful frameworks for testing hypotheses about planktic foraminiferal assemblage composition, seasonality, and geochemical responses to environmental variability, all of which are central to improving paleoceanographic reconstructions. We present high resolution foraminiferal assemblage data from a long-running sediment trap (2008–2020) in the northern Gulf of America (Mexico). This study summarizes the species composition, seasonality, and size distribution of the fifteen most abundant species of planktic foraminifera, which account for 98% of total flux. Foraminiferal flux peaks in winter and reaches a minimum in summer, following the seasonal pattern of primary production in the northern Gulf. Winter assemblages are dominated by non-spinose taxa, whereas spinose taxa prevail during summer. Across nearly all species, average monthly test size covaries with temperature, independent of seasonal flux trends. Notably, Trilobatus sacculifer and Neogloboquadrina dutertrei show a significant decline in relative abundance and flux during 2017–2020, nearly disappearing from the assemblage.

Journal of Foraminiferal Research

Evolution of arsenic speciation during thermal treatment simulating wildfire heating in arsenic-rich sediments

Understanding arsenic transformations during wildfires can help better constrain the environmental impacts of increased wildfire intensity, frequency, and burned area. Previous studies have monitored the evolution of metal(loid) speciation at specific time/temperature endpoints, hampering the comprehension of the dynamic transformations of metal(loid)s during wildfires. Here, a novel approach, namely in situ time-resolved X-ray absorption near edge structure (TR-XANES) spectroscopy, was used for the first time to monitor the heat-induced redox transformations of arsenic (As) in two As-rich sediments with different characteristics. No arsenic transformations were observed in either sediment at room temperature or when the sediments were heated to a maximum temperature of 400 ºC. When heated to a maximum temperature of 600 or 700 ºC, As underwent complex, dynamic, and partially reversible redox transformations, the extent of which varied with sediment properties, initial As speciation, and heating temperature and duration. In the case of sediments initially containing As(V) and a low sulfide/sulfate ratio, the As(V) was reduced to As(III) over a short period of time, followed by immediate reoxidation of As(III) to As(V). The extent of the transient As reduction increased with increasing maximum temperature. The final As speciation at the end of the heating experiment was not substantially different from that at the beginning of the experiment. In contrast, in sediments that were best described by a more complex combination of reference compounds (As(V) coprecipitated with or adsorbed on iron oxide, arseniosiderite, arsenopyrite) with a high sulfide/sulfate ratio, As(V) phases were reduced to As(III) and As(III) was further reduced to As(-I) (at 700 ºC, only), followed by delayed reoxidation of As(-I) to As(III) (at 700 ºC, only) and reoxidation of As(III) to As(V). Approximately 9% and 26% of all As remained as As(III) ( i.e., was not reoxidized to As(V)) at the end of the experiment when heated to a maximum temperature of 600 and 700 ºC, respectively, which is higher than the relative abundance of As(III) in the native sediment. These fire-induced As transformations can potentially enhance As mobilization to surface water and groundwater, posing risks to environmental and human health.

California

Avian navigation: Comparing the olfactory navigational “map” and the infrasound direction-finding hypotheses to aeronautics

Animal navigation has long been a fascinating but bewildering subject. Humans and animals might well share similar navigational strategies because they developed within the same physical environments. A “map-and-compass” model has been proposed to explain the two-step avian navigational process, but the “map” step has remained elusive. Although scalar values from bicoordinate geomagnetic or atmospheric olfactory gradients have been considered foundational to the avian map, neither has proved convincing engendering decades of controversy. The olfactory map, and an alternative infrasound direction-finding (IDF) hypothesis, are discussed in this review. The olfactory map hypothesis currently requires extensive stable gradients of trace-odor ratios, but such gradients are highly unlikely within a turbulent and rapidly mixed lower atmosphere. The IDF hypothesis, on the other hand, postulates a two-step navigational model analogous to the maritime and aeronautical radio direction-finding technique. This review was also written to encourage further investigation, and direct testing, of the acoustic navigational process. The IDF hypothesis, at present, appears the better explanation of observed avian navigational behavior and accuracy within the atmosphere’s physical environment.

Journal of Comparative Physiology A

The U.S. Geological Survey, the U.S. Department of Defense, and the U.S. Intelligence Community—100 years of mapping and remote sensing collaboration, 1879–1979

Introduction The U.S. Geological Survey (USGS)—a Federal civilian agency—and U.S. military and intelligence agencies collaborate on mapping and remote sensing and have since the establishment of the USGS. The organizations exchange data and information and share technology to further their respective missions in service to the American people. Often referred to as examples of “good government” or “whole of government,” the collaboration avoids costly duplication and maximizes time and effort for the government sectors. Collaboration between these sectors started with the original mapping of the United States and evolved to include remote sensing after the advent of aerial photography and satellite imagery.

Circular