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Orpiment, As 2 S 3 , containing up to 1.5 percent antimony has been recognized in carbonaceous arsenic-rich gold ores in the unoxidized East ore body of the Carlin gold deposit. Associated hydrothermal minerals include realgar (AsS) and quartz. Stibnite, commonly associated with realgar in the ores, has not been observed associated with this type of orpiment.
Analytical data, optical properties, and unit-cell parameters are presented for 24 samples of accessory apatites recovered from hybrid granitoid rocks of the southern Snake Range, Nev. A complete chemical analysis is given for one. In the Snake Creek-Williams Canyon outcrop area, where the hybrid rocks grade from granodiorite with 63 percent SiO 2 to a quartz monzonite with 76 percent SiO 2 within a horizontal distance of about 3 miles, abundance and crystal habit of the apatite change with rock chemistry. The apatite probably is slightly more than 90 mole percent fluorapatite in the most felsic rocks, slightly less in the most mafic. The range of F->OH substitution in apatite from this outcrop area is much smaller than in the coexisting biotites. Except for manganese, strontium, sodium, and the rare earths, there is very limited substitution for calcium in the crystal structure of these apatites. Apatites from the more mafic rocks tend to contain a lighter, more basic assemblage of rare earths, in agreement with results obtained for coexisting allanites, monazites, and zircons.
Cuprobismutite from Tunnel Extension Number Two mine, Ohio mining district, Utah, was chemically analyzed using the electron microprobe. Its empirical formula was determined to be Cu 20.8 Ag 0.97 Pb 0.35 Mn 0.22 Bi 26.7 Sb 0.06 Te 0.05 Se 0.55 S 50.4. The tentative conclusion is that unsubstituted cuprobismutite has the chemical formula 6Cu 2 S*6Bi 2 S 3 rather than the previously ascribed formula 6Cu 2 S*6Bi 2 S 3 and that cuprobismutite is therefore not dimorphous with emplectite.
Ion activity products for the dissolution of calcite, aragonite, gypsum, monetite, brushite, dolomite, magnesite, hydroxyapatite, and fluorapatite were calculated for a South Pacific guano island brine with an ionic strength of 6.4. Environmental conditions for the brine at the time of analysis and of sampling indicated saturation with respect to calcite, aragonite, gypsum, hydroxyapatite and fluorapatite; a comparison of the ion activity products and equilibrium constants indicated saturation or supersaturation with respect to most minerals found in lake sediments or elsewhere on the island. The results suggest that chemical thermodynamic calculations for brines may have some usefulness despite the many assumptions and estimations that must be made.
Many housing projects in the metropolitan area of Boston are beyond the reach of municipal sewer systems. Waste water disposed of through septic-tank or cesspool systems percolates to ground-water reservoirs and eventually reaches the streams. The dissolved-solids load in the streams receiving septic-tank effluent is increased by an amount that can be predicted from the housing density. In the study area, highway deicing salts are the only materials other than septic-tank discharge that contribute to water-quality degradation. The effect of these salts on the relationship with housing density is eliminated by subtracting the specific conductance due to sodium chloride from the measured specific conductance of a water sample. The difference is called residual conductance and is proportional to the dissolved-solids content minus the concentration of sodium chloride.
In the autumn of 1969, unusual meteorological conditions over Europe and northern Africa caused an enormous persistent desert storm in Tunisia and eastern Algeria. Poorly developed drainage patterns and gypsum-encrusted surfaces of these desert regions intensified effects of the storm and contributed to the heavy loss of life and property. Destruction of Roman bridges suggests that such storms may have recurrence probabilities of several thousands of years. The event also suggests that, although desert storms are less frequent than those of temperate regions, they can be similar in magnitude.
Hydraulic sand models are useful physical tools in the investigation of the transition zone that occurs between salt and fresh ground water in coastal aquifers. Such models are used to demonstrate the effects of transport mechanisms that influence the dynamic behavior and the shape of the transition zone. The techniques employed in obtaining in-place measurements of solute concentrations are generally the stumbling block in generating data for two-dimensional dispersion systems. Two in-place measurement techniques were used in the studies described: (1) conductivity probes when salt was used as a tracer; and (2) photoelectric cells when organic dye was used as a tracer. Results indicate that conductivity methods are more reliable; however, care must be exercised inasmuch as the probes tend to disturb the fluid flow.
Specific-ion electrodes were used to simultaneously determine the activity changes of calcium, hydrogen, sodium, fluoride, and divalent ions when 50 g of a natural, untreated material containing calcium-rich mixed-layer illite-montmorillonite clay, quartz sand, and calcium carbonate was added to 250 ml of natural Canadian River water containing 220 mg/1 Na. Calcium and magnesium were displaced from the clay by the sodium; the exchanged and dissolved noncarbonate calcium precipitated as calcium carbonate, and the magnesium remained in solution. Fluoride entered into both a rapid reaction and a long-term reaction, indicating solution from the material. The pH decreased rapidly. The reactions for all observed ions, other than fluoride, were faster than the response time of their respective electrodes and were complete in less than one minute. Rapid solution of material containing calcium, magnesium, sodium, and fluoride was also observed when a duplicate sample of the earth material was added to distilled water; pH also changed rapidly in this mixture. These results suggest that many important water-rock reactions can be considered nearly instantaneous for purposes of digital modeling of the geochemical changes during artificial recharge.
The orientation of joints in igneous and sedimentary rocks was measured at 21 localities in California, Maine, and New York to investigate the hypothesis that glaciation may open joints in bedrock. A summary of strikes of all joint sets shows the following pattern relative to the direction of glacial advance: two sets, thought to be extension joints, flank the direction of advance and are separated from it by about 10°; two sets, thought to be shear joints, flank the direction of advance by about 40°; and two sets, thought to be release joints, are about 70° to 80° from the direction of advance, or nearly perpendicular to the extension joints. An average of five joint sets, including three or four in this pattern, was found at each locality. The joints are believed to have been opened, in response to stress applied by the moving ice, along preexisting zones of weakness (potential regional joints) in the rock. Some new joints may have formed where no such zone was present near the position required for fracture under the applied stress. Additional investigation of the hypothesis is desirable because of its possible bearing on glacial erosion by quarrying, on interpretation of joint patterns in glaciated regions, and on the nature of aquifers in glaciated bedrock.
The acid-insoluble impurities of small samples of minerals are determined by a microgravimetric procedure. A Schwarz von Bergkampf glass filter stick with paper filter medium is used to separate the insoluble material. The filtration apparatus and procedural details are described.
Recently completed fission-track and K-Ar dating of zircon, sphene, apatite, muscovite, biotite, and hornblende indicate that the Clayton Peak stock was intruded 37-41 m.y. ago, the Alta stock about 32-33 m.y. ago, and the Little Cottonwood stock between 24 and 31 m.y. ago. Pb-a ages on zircon, though showing the same sequence, are about twice as great and are inferred to represent a partial mixing of inherited Precambrian zircons. Acceptance of a middle Tertiary age for the Little Cottonwood stock requires revision of earlier interpretations that it could be as old as Late Cretaceous. K-Ar dates also indicate that the Keetley Volcanics are 32 to 35 m.y. old, and a single date of 37.3 m.y. was obtained on the Traverse Volcanics, suggesting that they are more closely related to volcanic activity in the adjoining Oquirrh Mountains.
Roll-type uranium deposits contain both ore-stage pyrite and preore or diagenetic pyrite that was present in the host rock before the deposits began to form. Ore-stage pyrite forms as the result of redistribution and accretion from the preore pyrite. Accretion of the ore-stage pyrite seems to be governed by natural laws that limit its concentration to only a few times the concentration of the preore pyrite. Accumulations of ore-stage pyrite build up along the leading edge of a supergene oxidation zone which spreads through the host rocks, literally pushing the ore deposits ahead of it. The ore-stage pyrite probably progresses much as a wave that first grows to a nearly fixed amplitude and thereafter is steadily maintained as the mature deposit continues to advance.
The occurrence of the second known specimen of Parahyus vagus , from the Tepee Trail Formation, Wyoming, is recorded. As the first specimen was reported from the lower Eocene, this second occurrence casts doubt on the supposed age ranges of both Parahyus and the Tepee Trail.
Lithostrotion reiseri n. sp. is a cerioid, colonial coral, index fossil for microfossil zones 12-13 (Meramec) in the Lisburne Group in the central and eastern Brooks Range, arctic Alaska.
A thick sequence of highly deformed flyschlike metasandstone, slate, and argillite crops out in southern Alaska in the Kenai-Chugach Mountains and on Kodiak and the Shumagin Islands to the southwest. These poorly fossiliferous rocks have long been considered Cretaceous in age because of scattered occurrences of fragmentary shells of Inoceramus . Mainly on the basis of new fossil collections, the age of some of these rocks can now be firmly established as Late Cretaceous (Maestrichtian); the critical fossil is Inoceramus kusiroensis Nagao and Matsumoto. Inoceramus kusiroensis also occurs in the much more fossiliferous and only slightly deformed Matanuska Formation that forms a parallel belt north of the Chugach Mountains. On the basis of faunal, lithologic, and bedding characteristics, the Matanuska Formation is the shelf equivalent of the deepwater, trench, or continental-rise deposits of the Kenai-Chugach Mountains and islands to the southwest. " Inoceramya concentrica " Ulrich occurs with Inoceramus kusiroensis and is Maestrichtian in age, not Early Jurassic as E. 0. Ulrich suggested in 1910. The syntypes of I. concentrica are refigured and a lectotype is designated.
Humic acids, the most abundant organic components of natural water systems, are complex mixtures of molecular aggregates of different chemical and physical properties. The first step in the study of such a mixture is the fractionation of the mixture. The most common approach with humic acids is to attempt to obtain a molecular weight fractionation by gel-permeation chromatography. However, since the preponderance of evidence indicates that the components of humic acid do not fulfill the basic criteria of uniform shape and chemical structure necessary for obtaining a molecular fractionation on gel-permeation media, molecular weight distributions in humic acids cannot be evaluated by this method. A fractionation dependent upon chemical structure can be obtained by the manipulation of elution conditions on a gel-permeation column. This procedure provides a beginning in the isolation and identification of discrete components of humic acids.
Some unusual characteristics of streamflow occur in regions underlain by carbonate rocks. The streamflow characteristics are related to processes of karstification, these processes being dependent on circulation of subsurface water and solution of the rock to form characteristic topography and underground cavern systems. Very highly cavernous and permeable unsaturated zones tend to keep the water table depressed below land surface in many karst regions, a condition that leads to a low density of perennial streams. The uneven distribution of permeability beneath surface karst streams causes them to lose or gain water, depending on the position of the water table with reference to stream level. The conventional techniques of interpolation and extrapolation that have been reasonably successful in approximating streamflow of ungaged sites in nonkarstic regions have only limited use in karst regions. An understanding of principles of karstification and an understanding of the hydrogeologic framework of a carbonate terrane provide a useful basis for evaluating the streamflow characteristics.
The potentiometric surface of the Lloyd aquifer in 1970 locally was as much as 40 feet lower than in 1900. During this period, withdrawal of water from wells was estimated to exceed 300 billion gallons, and the amount of water released from aquifer storage by compressive forces was estimated to be 1.6 billion gallons (about 0.5 percent of the withdrawal). The remainder of the withdrawal was derived from downward leakage through overlying aquifers and confining layers and by the displacement of fresh water in the aquifer by landward movement of salty ground water