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Arc-related porphyry molybdenum deposit model

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments. Arc-related porphyry molybdenum deposits are a substantial resource for molybdenum metal and may have anomalous concentrations of tungsten. The deposits contain low-grade ore (0.03-0.22 percent molybdenum) as molybdenite, but are large-tonnage, making them amenable to bulk mining open-pit techniques. The mineralizing system usually has fluorine contents of less than 0.1 percent. The cogenetic intrusion is a differentiated calc-alkaline granitoid, typically granodiorite to quartz monzonite in composition, with low rubidium and niobium, and moderate to high strontium concentrations. Metals and hydrothermal fluids are sourced from these intrusions, with an additional meteoric fluid component contributing to peripheral alteration but not adding more metal. The lithology of the surrounding country rocks is not important to the formation of these deposits, but a surrounding carbonate unit may be altered to skarn that contains economic mineralization. The creation of contact-metamorphosed hornfels adjacent to the intrusion is common. Formation of arc-related porphyry molybdenum deposits typically occurs within a continental arc environment related to arc-continent or continent-continent collision and subduction. Few deposits are found in an island arc setting. Most classified arc-related porphyry molybdenum deposits are located in the western cordillera of North America, notably in British Columbia and Alaska. Hydrothermal alteration provides a key component to the identification of a deposit. Alteration usually is zoned from a core of potassic plus/minus silicic alteration outwards through phyllic to propylitic alteration. Argillic alteration may be irregular in shape and will overprint earlier hydrothermal alteration. Exploration should be limited to magmatic arc belts that have been unroofed and eroded to levels of a few kilometers depth. Important geological vectors toward areas of higher grade mineralization include intensity of hydrothermal alteration, veining, and faulting. Anomalous levels of molybdenum, tungsten, copper, lead, or zinc in soils, tills, stream sediments, and drainage waters may indicate the presence of an arc-related porphyry molybdenum deposit. Geophysical exploration techniques have been met with minimal success because of the overall low concentration of associated sulfide and oxide minerals. Geoenvironmental concerns are generally low because of low volumes of sulfide minerals. Most deposits are marginally acid-generating to non-acid-generating with drainage waters being near-neutral pH because of the acid generating potential of pyrite being partially buffered by late-stage calcite-bearing veins. The low ore content results in a waste:ore ratio of nearly 1:1 and large tailings piles from the open-pit method of mining.

Scientific Investigations Report

Alteration Map Showing Major Faults and Veins and Associated Water-Quality Signatures of the Animas River Watershed Headwaters Near Silverton, Southwest Colorado

This map was produced to provide hard-copy and digital data for alteration assemblages in the historical mining area centered on the Tertiary San Juan and Silverton calderas. The data have direct application to geoenvironmental and mineral exploration objectives. This dataset represents alteration mapping for the upper Animas River watershed near Silverton, Colorado. The map is based on detailed 1:12,000-scale field mapping, X-ray diffraction (XRD) analysis, mineral mapping by remote sensing (AVIRIS) data, and 1:24,000-scale aerial photographic interpretation. Geologic structures were compiled and generalized from multiple published and unpublished sources (Burbank and Luedke, 1964; Steven and others, 1974; Luedke and Burbank 1975a, b; Lipman, 1976; Luedke and Burbank, 1987; Luedke, 1996) (see Index Map). Unpublished mapping of the Ironton quadrangle by D.J. Bove and J.P. Kurtz in 1997-1999 was included.

Scientific Investigations Map

Reconnaissance geology of the Sabkhat Muraysis quadrangle, Kingdom of Saudi Arabia

The Sabkhat Muraysis quadrangle .covers an area of 2843 sq km in the central part of the Kingdom of Saudi Arabia. In the northwestern quarter of the area Precambrian rocks are exposed. They are overlain toward the .south and east by sedimentary formations of Permian and younger age. Four main units of Precambrian .rocks were identified in this area. From oldest to youngest they are: hornblende-biotite granite gneiss; amphibolite and rhyolite of the Halaban Group; graywacke and chlorite-sericite schist of the Bi'r Khountina Group; and biotite-hornblende granite, The hornblende-biotite granite gneiss unit and the biotite-hornblende granite .unit are both poorly exposed and largely covered by veneers of sand, Owing to these factors the boundaries between the granitic, rocks are obscure, Much of what is shown as hornblende-biotite granite gneiss may actually be biotite-hornblende granite. The Halaban Group is represented by an older amphibolite unit called the Umm Mushraha Formation and by a younger rhyolite unit., called the Wadi al Jifr Formation. Layered and msslve components in the Umm Mushraha Formation represent metamorphosed .andesite and graywacke, ,and metamorphosed diorite., gabbro, and pyroxenite. The Wadi al Jifr Formation consists of virtually unmetamorphosed to strongly sheared and metamorphosed rhyolite, rhyolite porphyry, and rhyolite tuff which at many places has been metamorphosed to quartz-sericite schist and biotite-muscovite schist. These schists retain porphyroclasts of blue quartz which also form conspicuous phenocrysts in the unsheared rhyolite. Locally, the sheared rhyolite ha s been hydrothermally altered resulting in the formation of quartz-chlorite-ankerite veins and a sparse impregnation of pyrite. The Bi'r Khountina Group consists of a unit of graywacke and argillite with interbedded andesite that is metamorphosed to chlorite-sericite schist near the contacts of intrusive biottte-hornblende granite. This .unit is-called the Abu Sawarir Formation. It is Intruded by masslve gabbro and pyroxenite. No ancient mines or old prospects were found in the Precambrian part of the quadrangle. Three alteration zones in rhyolite near the northwestern corner of the quadrangle tend to have threshold amounts of molybdenum and tungsten, but they have only background amounts of the base metals and silver. Pyrite is more common in the altered rhyolite than in adjacent rocks. Geological mapping plus and electromagnetic surveys of this area are recommended to explore for sulfide minerals.

Open-File Report

Stratigraphic sections of the Phosphoria formation in Idaho, 1947-48, Part I

The Permian Phosphoria formation of the western states contains one of the world's largest reserves of phosphate. Although previous investigations (see especially Mansfield, 1927), including reconnaissance geologic mapping and sampling, established the location of most of the important deposits and their quality of scattered localities, they were not sufficiently detailed to permit a comparison of the merits of individual deposits or an appraisal of the reserves of phosphate rock that might be available under present economic conditions. Because the growing importance of the western phosphate deposits requires a better, more detailed understanding of their distribution and quality, the Geological Survey began in 1947 a comprehensive investigation, including (1) reconnaissance geologic mapping, mostly in Montana, of areas in which the Phosphoria formation could occur but where it had not previously been looked for or found; (2) geologic mapping, mostly in Montana, at a scale no smaller than 1:62,500, of several areas known to contain the Phosphoria formation but not previously mapped except in reconnaissance fashion; (3) geologic and topographic mapping, at a scale of 1:12,000, of some of the richest, thickest, and most accessible deposits; (4) measuring, describing, and sampling all beds of the phosphatic and shaly parts, and in some places the full thickness, of the Phosphoria formation and its stratigraphic equivalents at one or two localities per township over the entire field; (5) chemical and spectrographic analysis of the samples for phosphate, fluorine, minor metals, oil, and rock-forming constituents; and (6) petrologic and geochemical studies of the rocks and minerals of the formation. These studies are designed to define the regional and local geologic structures in which the phosphate bed lie, to provide a basis for the estimation of reserves of the inferred class over the entire region, and to determine the origin of the rocks and the elements contained in them. The data collected are not of the detail required to plan actual mining operations, but it is hoped they will guide industry in the selection of individual deposits worthy of further exploration. Most of the field work contemplated as a part of this investigation is now completed. Although the data will not be compiled or published in final form for some years to come, segments of the data, accompanied by little or no interpretation, will be published as preliminary maps or reports as they are assembled. The present report is the first of a series presenting in abbreviated form the description and analyses of the beds measured and sampled at various localities in southeastern Idaho (pl. 1). Companion reports presenting segments of the data from Montana, Wyoming, and Utah (Swanson and others, 1952, and McKelvey and others, 1952a and 1952b) are being released at the same time as this report, and others are in preparation.

Idaho

A study of uranium favorability of Cenozoic sedimentary rocks, Basin and Range Province, Arizona: Part I. General geology and chronology of pre-late Miocene Cenozoic sedimentary rocks

This study focuses attention on Cenozoic sedimentary rocks in the Basin and Range Province of Arizona. The known occurrences of uranium and anomalous radioactivity in these rocks are associated with sediments that accumulated in a low energy environment characterized by fine-grained clastics, including important tuffaceous materials, and carbonate rocks. Most uranium occurrences, in these rocks appear to be stratabound. Emphasis was placed on those sedimentary materials that pre-date the late Cenozoic Basin and Range disturbance. They are deformed and crop out on pedimented range blocks and along the province interface with the Transition Zone. Three tentative age groups are recognized: Group I - Oligocene, pre-22 m.y., Group II - early Miocene - 22 m.y. - 16 m.y., and Group III - middle Miocene - 16 m.y. to 13--10 m.y. Regionally, these three groups contain both coarse to fine-grained red clastics and low energy lighter colored 'lacustrine' phases. Each of the three groups has been the object of uranium exploration. Group II, the early Miocene strata, embraces the Anderson Mine - Artillery region host rocks and also the New River - Cave Creek early Miocene beds-along the boundary with the Transition Zone. These three groups of rocks have been tectonically deformed to the extent that original basins of deposition cannot yet be reconstructed. However, they were considerably more extensive in size than the late Cenozoic basins the origin of which deformed the former. Group II rocks are judged to be of prime interest because of: (1) the development and preservation of organic matter in varying lithologies, (2) apparent contemporaneity with silicic volcanic centers, (3) influence of Precambrian crystalline rocks, and (4) relative outcrop continuity near the stable Transition Zone. The Transition Zone, especially along its boundary with the Basin and Range Province, needs additional geologic investigation, especially as regards the depositional continuity of Group II sediment s.

Arizona

Geologic map of Kundelan ore deposits and prospects, Zabul Province, Afghanistan; modified from the 1971 original map compilations of K.I. Litvinenko and others

This map and cross sections are redrafted modified versions of the Geological map of the Kundelan ore deposit area, scale 1:10,000 (graphical supplement no. 18) and the Geological map of the Kundelan deposits, scale 1:2,000 (graphical supplement no. 3) both contained in an unpublished Soviet report by Litvinenko and others (1971) (report no. 0540). The unpublished Soviet report was prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan in Kabul during 1971. This redrafted map and cross sections illustrate the geology of the main Kundelan copper-gold skarn deposit, located within the Kundelan copper and gold area of interest (AOI), Zabul Province, Afghanistan. Areas of interest (AOIs) of non-fuel mineral resources within Afghanistan were first described and defined by Peters and others (2007) and later by the work of Peters and others (2011a). The location of the main Kundelan copper-gold skarn deposit (area of this map) and the Kundelan copper and gold AOI is shown on the index map provided on this map sheet. The estimated resources of the Kundelan copper-gold skarn deposit are 21,400 metric tons (t) of copper, 1.6 t of gold, and 133.4 t of molybdenum at an average grade of 1.21 weight percent (wt. %) copper (ranging from 0.66 to 4.03 wt. % copper); 0.9 grams per metric ton (g/t) gold (ranging from 0.3 to 3.1 g/t gold); 0.14 wt. % molybdenum; and as much as 10 g/t silver and 0.03 wt. % bismuth (Peters and others, 2011b). Small past production of gold and base metals is also reported by Douvgal and others (1971) from many prospects within the Kundelan copper and gold AOI. Outside the skarn areas, argillic hydrothermal alteration is present (Abdullah and others, 1977). Most copper and gold prospects in the Kundelan copper and gold AOI are reported to contain commercial-grade ores of copper and (or) gold, and many prospect areas have potential for these commodities to be discovered in commercial volumes. Future initial mine exploration and later development in many of the prospects, and specifically in the Kundelan copper-gold skarn deposit, could result in near-term small- to medium-sized gold mining operations (Peters and others, 2011b). The redrafted map and cross sections reproduce the topology of rock units, contacts, faults, and so forth, of the original Soviet map and cross sections, and they include modifications based on our examination of these documents and our observations made during a brief field visit in August of 2010. We have attempted to translate the original Russian terminology and rock classifications into modern English geologic usage as literally as possible without changing any genetic or process-oriented implications in the original descriptions. We also use the age designations from the original Soviet maps, except for the phase I and II intrusive igneous rocks. Phase I and II igneous rocks are reassigned an Early Cretaceous age (from lower Paleogene) based on a uranium-lead (U-Pb) zircon SHRIMP analysis from quartz diorite, which yielded an age of 104±1 Ma (mega-annum). The information provided in the description of map units is from both the source report by Litvinenko and others (1971) and the original 1:10,000 scale map (graphical supplement no. 18), also from Litvinenko and others (1971). Because of the poor quality of the original map, some map features could not be identified and some features may be misinterpreted. The rock unit colors used on the redrafted maps and cross sections differ from the colors shown on the original Soviet version. Colors were selected according to the color and pattern scheme of the Commission for the Geological Map of the World (CGMW) at http://www.ccgm.org. Elevations on the cross sections are derived from the original Soviet topography and may not match the Global Digital Elevation Model (GDEM) topography used on the redrafted map of this report. Most hydrography derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) has not been included on our redrafted version of the map because of a poor fit with alluvial deposits from the unmodified original Soviet map (graphical supplement no. 18; Litvinenko and others, 1971).

Zabul Province

Geohydrologic and water-quality characterization of a fractured-bedrock test hole in an area of Marcellus shale gas development, Tioga County, Pennsylvania

An integrated analysis of core, geophysical logs, gas isotopes, and specific-depth water-quality samples from the Cherry Flats test hole was used to characterize the stratigraphy, water-bearing zones, and groundwater quality at a site in southern Tioga County, Pennsylvania. The study was completed as a cooperative effort between the Pennsylvania Department of Natural Resources, Bureau of Topographic and Geologic Survey (BTGS) and the U.S. Geological Survey (USGS). The multi-disciplinary characterization of the test hole provided information to aid the bedrock mapping of the Cherry Flats 7.5-minute quadrangle by BTGS, and to help quantify the depth and character of fresh and saline groundwater in an area of shale-gas exploration. The Cherry Flats test hole was cored to a depth of 1,513 feet (ft) below land surface (bls) and cased to 189 ft through the collapsed mine workings of the former Arnot No. 2 underground coal mine. The test hole penetrated 128.0 ft of Allegheny Formation and 154.1 ft of Pottsville Formation of Pennsylvanian age, 564.8 ft of Huntley Mountain Formation of Mississippian and Devonian age, and 666.3 ft of Catskill Formation of Devonian age. Core recovery was nearly 100 percent, except where complete core loss occurred from a depth of 1,231.1 to 1,240.8 ft. Several coal beds and mined-out coal horizons were penetrated in the Allegheny and Pottsville Formations. The test hole penetrated the entire thickness of the Huntley Mountain Formation and was completed in the middle part of the Catskill Formation. Bedding features penetrated by the test hole were estimated to have a strike of 021 degrees and dip about 1.7 degrees to the southeast, consistent with the test-hole location on the north limb of the Blossburg syncline. Most fractures penetrated by the test hole were parallel to bedding, with steeply dipping fractures present but much less common. Fracture density, determined from optical televiewer, acoustic televiewer, and video logs, generally increased with depth from the base of casing to about 400 ft bls, then decreased with depth to the bottom of the hole except for an increase from 506 to 568 ft bls. Very few fractures were penetrated from 600 to 850 ft. The depths of fresh and saline water-bearing zones were identified in the test hole by geophysical-log analysis and, for inflow zones, verified by specific-depth groundwater sampling by the use of a wire-line point sampler. Under ambient conditions and during pumping of the test hole, fresh water entered the hole from fractures at 567 and 580.5 ft bls, within grayish-red siltstone and greenish-gray sandstone, respectively, and flowed upward and exited at fractures from 303 to 319.5 ft; a very minor amount exited into fractures within coal beds at 240.4 and 252 ft bls. Transmissivity, estimated from analysis of the specific-capacity data and flowmeter logs, was about 18 ft2/d for the fracture zones from 567 to 580.5 ft and 6.7 ft2/d for fracture zones from 240.4 to 252 ft bls. The analysis estimated the hydraulic head of the lower zone and that of the upper flow zone was 8 ft higher and 37 ft lower than the composite water level in the test hole, respectively. Water samples of the freshwater inflow from zones at 567 to 580.5 ft bls had a total dissolved solids concentration of 577 mg/L indicating that these zone are in the lower part of the active groundwater flow system. Below the freshwater-bearing zone at 580.5 ft, the flowmeter did not detect any vertical flow in the test hole, and the gradient of the temperature log approached the geothermal gradient, indicating little ambient fluid flow and minimal fracture transmissivity below this depth. However, small seeps of saline water having total dissolved solids concentrations of greater than about 6,200 mg/L at 945 and 946 ft bls, from dark-greenish-gray to greenish-gray silty beds, were delineated by a time series of specific conductancelogs and observed on the video log. A wat

Pennsylvania

Porphyry copper assessment of East and Southeast Asia: Philippines, Taiwan (Republic of China), Republic of Korea (South Korea), and Japan

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of East and Southeast Asia as part of a global mineral resource assessment. The assessment covers the Philippines in Southeast Asia, and the Republic of Korea (South Korea), Taiwan (Province of China), and Japan in East Asia. The Philippines host world class porphyry copper deposits, such as the Tampakan and Atlas deposits. No porphyry copper deposits have been discovered in the Republic of Korea (South Korea), Taiwan (Province of China), or Japan. Thirteen geographic areas were delineated as tracts that are permissive for porphyry copper deposits in the assessed area. Individual tracts range from about 3,000 to 100,000 square kilometers in area. Permissive tracts are delineated on the basis of mapped distributions of igneous rocks of specific age ranges that define subduction-related magmatic arcs or magmatic belts that might contain porphyry copper deposits. Most of these magmatic arcs are subduction related, although some porphyry deposits and prospects are present in back-arc or poorly understood tectonic settings. Maps at various scales were used in the compilation; however, the final tract boundaries are intended for use at a scale of 1:1,000,000. Numbers of undiscovered deposits were estimated at different levels of confidence for 10 permissive tracts in the Philippines including one area that extends to eastern Taiwan (Republic of China); permissive tracts in South Korea and Japan are discussed qualitatively. Estimates of numbers of undiscovered deposits were combined with grade and tonnage models using Monte Carlo simulation to estimate amounts of undiscovered resources. Grades and tonnages of known porphyry copper deposits in the study area were compared with global grade and tonnage models to determine the appropriate model for simulation of undiscovered resources. Most of the known deposits are best described as copper-gold subtypes of porphyry copper deposits. For some permissive tracts, a general porphyry copper-gold-molybdenum model was used. Thirty-eight porphyry copper deposits are known in the Philippines; the mean number of undiscovered deposits was estimated to be 28. Mean (arithmetic) resources that could be associated with the undiscovered deposits are 90 million metric tons of copper and 5,800 metric tons of gold, as well as byproduct molybdenum and silver. Additional resources that could be discovered in extensions to known deposits were not evaluated. Assessment results, presented in tables and graphs, indicate expected amounts of total contained metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. The Philippines have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in the region. South Korea and Japan have been thoroughly explored for many types of mineral deposits. Available data suggest that the permissive rocks in South Korea typically are too deeply eroded to preserve porphyry copper deposits. Porphyry copper systems may be present in Japan, but are likely to lie at depths greater than the 1 kilometer from the surface protocol adopted for this study. Descriptions of the geologic basis for delineating each tract, the data used, the geologic criteria and rationale for the assessment, and results of the assessment are included in appendixes along with the description of a geographic information system (GIS) that includes tract boundaries, known porphyry copper deposits and significant prospects, and assessment results.

Scientific Investigations Report

The Hydrogeology of the San Juan Mountains Chapter 5

Knowledge of the occurrence, storage, and flow of groundwater in mountainous regions is limited by the lack of integrated data from wells, streams, springs, and climate. In his comprehensive treatment of the hydrogeology of the San Luis Valley, Huntley (1979) hypothesized that the underlying, fractured volcanic bedrock of the San Juan Mountains has relatively high bulk permeability and a regional-scale water table with a low hydraulic gradient. Other (some more recent) studies of fractured crystalline bedrock in mountainous terrain indicate that these rock units can act as aquifers (Kahn et al. 2008; Manning and Caine 2007; Robinson 1978; Stober and Bucher 2005). The body of recent work also suggests that the conception that fractured crystalline bedrock is of such low permeability that it constitutes a “no-flow zone” may be inappropriate. In addition to establishing a new baseline, the data presented here are used to test Huntley’s (1979) hypotheses that suggest that the San Juan Mountains may be underlain by a substantial groundwater system. With the advent of computers and digital databases, many types of publicly available data can be used to test hypotheses and provide new insights into mountain hydrogeology at the regional scale in the San Juan Mountains. Plate 16 illustrates processes that suggest several fundamental questions arising from our lack of knowledge of mountain hydrogeology. These questions include: What are the dynamic interrelationships among the tectonics of mountain building, climate, and groundwater, and what are the time scales over which associated processes operate? How does extreme topographic relief allow for groundwater recharge along steep surfaces rather than simply causing precipitation to run off ? How does extreme relief translate into hydraulic gradients that drive groundwater flow? Can extreme gradients drive large volumes of meteoric water deep into the Earth’s upper crust? Once in the subsurface, what are the residence times of these waters? Finally, how does complex geology, commonly associated with mountainous terrain, influence these processes and control potentially heterogeneous and tortuous flow pathways? This chapter presents a synthesis of hydrogeological data, in a reconnaissance style, at the regional scale for the San Juan Mountains. Analyses of these data shed some light on the questions posed earlier for the San Juan Mountains and on mountain hydrogeologic processes in general. These analyses are based on public digital data from geologic and topographic maps, precipitation networks, stream gauges, groundwater wells, and springs. These data can be integrated using the hydrologic cycle expressed as a mass balance between inputs and outputs. The data types noted earlier form the basic set of measurements used to explore, characterize, and quantify elements of the hydrologic cycle. This exploration at a variety of scales yields insight into the relationships among the physical geological framework, climatological and hydrological budgets, and the hydraulic properties of the major aquifers in the San Juan Mountains. Each of these factors has been broken down and investigated separately and then integrated at the end of the chapter, using a conceptual model. Although the San Juan Mountains contain extensive precious- and base-metal deposits that have led to natural and mining-related groundwater contamination, this topic is not addressed here. Interested readers should refer to the extensive body of US Geological Survey work in Gray et al. (1994), Plumlee et al. (1995), Wirt et al. (1999), Johnson and Yager (2006), Johnson et al. (2007), and Church, von Guerard, and Finger (2007). Huntley (1979) also provided a large database for regional hydro-geochemistry of the San Juan Mountains (SJM).

Colorado

Mineral deposits of the Mesoproterozoic Midcontinent Rift system in the Lake Superior region – A space and time classification

The Mesoproterozoic Midcontinent Rift System (MRS) of North America hosts a diverse suite of magmatic and hydrothermal mineral deposits in the Lake Superior region where rift rocks are exposed at or near the surface. Historically, hydrothermal deposits, such as Michigan’s native copper deposits and the White Pine sediment-hosted stratiform copper deposit, were major MRS metal producers. On-going exploration for and potential development of copper-nickel sulfide deposits hosted by the Duluth Complex of Minnesota and the opening of the Eagle nickel mine in Michigan indicate an expanding interest in MRS magmatic deposits. MRS hydrothermal and magmatic mineral deposits, many of which are significant past, present, and likely future providers of critical minerals, here are placed into a space and time metallogenic framework. To construct this framework, regional MRS mineral deposits extracted from the U.S. Geological Survey Mineral Resources Data System (MRDS) and the Ontario Ministry of Energy, Northern Development and Mines Mineral Deposit Inventory (MDI) were supplemented by other known and recently recognized mineral deposits described in the literature. All mineral deposits were classified by deposit type, host rock age and type, and estimated timing of mineralization. Deposits were then put into a tectonic evolutionary framework (stages) for the MRS, which shows that deposits formed within discrete spatial and temporal stages of rift evolution.

Lake Superior region

Spatial and temporal trends in selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001–16

Phosphate mining in southeastern Idaho has been an important economic driver for the region and State for over 100 years, but weathering of mining waste rock has also released selenium into the Blackfoot River. This report analyzes and presents data from three separate but complementary studies monitoring selenium in streams in the region. The U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management, has been collecting streamflow and water-quality samples year-round on the Blackfoot River above reservoir near Henry, Idaho, (USGS streamgage 13063000) since 2001. Over the same period, the Idaho Department of Environmental Quality (IDEQ) has collected streamflow and water-quality samples from the Blackfoot River and tributaries during spring runoff. Data collected from 2001 to 2012 during these two studies were analyzed previously. This report extends the analysis using new data collected through 2016. This report also presents the results of a joint USGS and IDEQ seepage study conducted in June 2016 in the Blackfoot River near Dry Valley. Although limited in scope, this study explored the hypothesis that unaccounted selenium loading (loading in excess of tributary inputs) in this reach could be caused by groundwater inflow. USGS dissolved selenium concentration data from streamgage 13063000 on the Blackfoot River and IDEQ data from the mainstem and mining-affected tributaries are highest shortly after peak runoff and correlate with streamflow magnitude. Although earlier analyses indicated increasing selenium concentrations from 2001 to 2012, this study shows that runoff and baseflow dissolved selenium concentrations increased and then decreased during 2001–16. High median runoff concentrations from 2005 through 2011 are associated with high snowpack and streamflow. This result suggests that more snowmelt moving through selenium-bearing waste rock leads to increased instream concentrations. The time lag between peak runoff and then peak selenium concentrations suggests that selenium mobilization may occur as snowmelt percolates through waste rock rather than by faster surface runoff. However, variability in local snow accumulation and snowmelt conditions likely affects interannual variability in selenium concentrations in the mainstem Blackfoot River and tributaries. In contrast to runoff selenium concentrations, median baseflow (August to October) dissolved selenium concentrations were highest from 2009 to 2013. Aquatic plant senescence and release of selenium is an unlikely explanation for this trend because plants are still growing during this time of year. In addition, this trend is observed during and shortly after the observed period of high snowpack. Thus, increased baseflow selenium concentrations suggest that increased selenium loading to alluvial groundwater may occur during periods of high snowmelt and manifest in later years as higher instream concentrations during baseflows when the majority of streamflow is attributable to groundwater gains. Runoff-period streamflow and selenium loads were calculated for the tributaries and mainstem Blackfoot River. Selenium loads vary from year to year with mainstem loads greater than the total tributary contributions in some years and less than tributary contributions in other years. In general, East Mill Creek usually accounted for the largest proportion of the total Blackfoot River load, and unaccounted loads (loads in excess of tributary inputs) often occurred in the vicinity of Spring Creek and Dry Valley. The latter observation led the USGS and IDEQ to conduct a seepage study to further investigate groundwater and selenium loading to the Blackfoot River near Dry Valley. The seepage study results show consistent albeit small unaccounted increases in streamflow and dissolved selenium load in the Blackfoot River near Dry Valley. Field observation of a spring to the north of the river and independent groundwater monitoring data from Dry Valley to the south of the river suggest that alluvial groundwater may discharge to the river from both sides. However, the small unaccounted selenium load measured in the June 2016 study relative to loads measured during runoff suggest that groundwater loading in this reach may occur primarily during runoff. An improved understanding of alluvial groundwater extent, gradient, hydraulic conductivity, and quality would aid in interpreting unaccounted gains and losses in selenium loads in the Blackfoot River. Finally, State of Idaho selenium water-quality criteria have recently shifted to a hierarchical fish tissue and water concentration scheme. This report summarizes existing fish tissue and water-quality data in the mainstem and offers considerations for future selenium monitoring in the Blackfoot River.

Idaho

A contribution to the geology of northeastern Texas and southern Oklahoma

The region in central and northeastern Texas and southern Oklahoma known as the Black and Grand prairies abounds in features of interest to physiographers, geologists, and paleontologists, and the pioneer investigators of this region must have experienced renewed satisfaction in each day's exploration. The reports of Joseph A. Taff, Robert T. Hill, and others, published chiefly under the auspices of State and Federal surveys, represent with approximate accuracy at most places the general distribution of the outcrops of the formations in this region, and contain detailed descriptions of many sections that constitute a mine of useful information. The reader of the present paper is urged, therefore, to hold as most important the general excellence of the earlier reports of these authors and to relegate the inaccuracies and mistakes to which his attention will be called to the relatively unimportant place in which they belong, remembering at the same time that a future generation of investigators may find our own shortcomings as great as those we now criticize.

Oklahoma;Texas

Proceedings for a workshop on deposit modeling, mineral resource assessment, and their role in sustainable development

The world's use of nonfuel mineral resources continues to increase to support a growing population and increasing standards of living. The ability to meet this increasing demand is affected especially by concerns about possible environmental degradation associated with minerals production and by competing land uses. What information does the world need to support global minerals development in a sustainable way? Informed planning and decisions concerning sustainability and future mineral resource supply require a long–term perspective and an integrated approach to resource, land use, economic, and environmental management worldwide. Such perspective and approach require unbiased information on the global distribution of identified and especially undiscovered resources, the economic and political factors influencing their development, and the potential environmental consequences of their exploitation. The U.S. Geological Survey and the former Deposit Modeling Program of the International Union of Geological Sciences (IUGS) of the United Nations Educational, Scientific and Cultural Organization (UNESCO) sponsored a workshop on "Deposit Modeling, Mineral Resource Assessment, and Their Role in Sustainable Development" at the 31st International Geological Congress (IGC) in Rio de Janeiro, Brazil, on August 18–19, 2000. The purpose of the workshop was to review the state-of-the-art in mineral deposit modeling and resource assessment and to examine the role of global assessments of nonfuel mineral resources in sustainable development. The workshop addressed questions such as the following: Which of the available mineral deposit models and assessment methods are best suited for predicting the locations, deposit types, and amounts of undiscovered nonfuel mineral resources remaining in the world? What is the availability of global geologic, mineral deposit, and mineral exploration information? How can mineral resource assessments be used to address economic and environmental issues? Presentations included overviews of assessment methods applied in previous national and other small-scale assessments of large regions and of the resulting assessment products and their uses. Twenty-seven people from Canada, China, Finland, Germany, Japan, Peru, Slovenia, South Africa, United States, and Venezuela participated in the 2-day post-Congress workshop. The attendees represented academia, government, environmental organizations, and the mining industry.

Circular

Mineral resource potential map of the Stansbury Roadless Area, Tooele County, Utah

The U.S. Bureau of Mines and the U.S. Geological Survey have conducted a survey to determine the mineral resource potential of the eastern part (D4757) of the Stansbury Roadless Area, Tooele County, Utah. The results of this survey indicate that a low to moderate potential for copper, lead, and silver mineralization exists in part of area D4757. The balance of area D4757 is considered to have a low potential for metallic mineralization. The oil and gas potential is not known and cannot be assessed without a program of geophysical exploration and exploratory drilling. Limestone and dolomite are exposed over a large part of the roadless area, forming a major industrial mineral resource, but an extensive sampling and testing program is needed to determine the degree of purity of the rocks and, hence, the value of the resource. There are no known geothermal resources within the study area.

Utah

Appraisal of Hydrologic Information Needed in Anticipation of Lignite Mining in Lauderdale County, Tennessee

Lignite in western Tennessee occurs as lenses or beds at various stratigraphic horizons in the Coastal Plain sediments of Late Cretaceous and Tertiary age. The occurrence of this lignite has been known for many decades, but not until the energy crisis was it considered an important energy resource. In recent years, several energy companies have conducted extensive exploration programs in western Tennessee, and tremendous reserves of lignite have been found. From available information, Lauderdale County was selected as one of the counties where strip-mining of lignite will most likely occur. Lignite in this county occurs in the Jackson and Cockfield Formations, undivided, of Tertiary age. The hydrology of the county is known only from regional studies and the collection of some site-specific data. Therefore, in anticipation of the future mining of lignite, a plan is needed for obtaining hydrologic and geologic information to adequately define the hydrologic system before mining begins and to monitor the effects of strip-mining once it is begun. For this planning effort, available hydrologic, geologic, land use, and associated data were located and compiled; a summary description of the surface and shallow subsurface hydrologic system was prepared: the need for additional baseline hydrologic information was outlined; and plans to monitor the effects of strip-mining were proposed. This planning approach, although limited to a county area, has transferability to other Coastal Plain areas under consideration for strip-mining of lignite.

Water-Resources Investigations Report

Carolina slate belt gold deposits in Virginia, North Carolina, South Carolina, and Georgia

The Southeastern United States, in particular, the Carolina slate belt of Virginia, North Carolina, South Carolina, and Georgia, has been an important region of mineral production (fig. 1). This region is thought to have major potential for containing large undiscovered deposits of gold and silver, as well as copper, lead, zinc, molybdenum, and tin. Gold production from the major mines (Haile, Brewer, Ridgeway, and Barite Hill) in South Carolina ranked sixth in the Nation in 1992. Despite the closing of all but one mine in 1997, the region continues to attract intense scrutiny by the mining industry. Current U.S. Geological Survey (USGS) efforts in the slate belt are led by a multidisciplinary team focused on an integrated, multistate, and multiyear project that has the potential to result in a fundamental reinterpretation of the economic geology of the region. The slate belt is considered a scientific frontier because of the rapid pace of data acquisition by the USGS, academia, and private sector geologists and because emerging concepts of its geologic evolution are controversial. Establishing the origin of the gold deposits is important, not only in guiding exploration, but for more accurate assessment of the potential for the occurrence of new deposits throughout the southern Appalachians. These efforts may result in further industry exploration that may lead to discovery of new economically viable mineral deposits, which would have a broad economic impact on the region. Another goal is to find ways to prevent human activities related to gold extraction from remobilizing toxic metals found in these deposits, which could have potential harmful effects on the environment.

Georgia, North Carolina, South Carolina, Virginia

Great Basin geoscience data base

This CD-ROM serves as the archive for 73 digital GIS data set for the Great Basin. The data sets cover Nevada, eastern California, southeastern Oregon, southern Idaho, and western Utah. Some of the data sets are incomplete for the total area. On the CD-ROM, the data are provided in three formats, a prototype Federal Data Exchange standard format, the ESRI PC ARCVIEW1 format for viewing the data, and the ESRI ARC/INFO export format. Extensive documentation is provided to describe the data, the sources, and data enhancements. The following data are provided. One group of coverages comes primarily from 1:2,000,000-scale National Atlas data and can be assembled for use as base maps. These various forms of topographic information. In addition, public land system data sets are provided from the 1:2,500,000-scale Geologic Map of the United States and 1:500,000-scale geologic maps of Nevada, Oregon, and Utah. Geochemical data from the National Uranium Resource Evaluation (NURE) program are provided for most of the Great Basin. Geophysical data are provided for most of the Great Basin, typically gridded data with a spacing of 1 km. The geophysical data sets include aeromagnetics, gravity, radiometric data, and several derivative products. The thematic data sets include geochronology, calderas, pluvial lakes, tectonic extension domains, distribution of pre-Cenozoic terranes, limonite anomalies, Landsat linear features, mineral sites, and Bureau of Land Management exploration and mining permits.

Data Series

Review of samples of water, sediment, tailings, and biota at the Little Bonanza mercury mine, San Luis Obispo County, California

Background and Objectives The Little Bonanza mercury (Hg) mine, located in San Luis Obispo County, California, is a relatively small mine with, a historical total Hg production of about 1,000 flasks. The mine workings and tailings are located in the headwaters of the previously unnamed west fork of Las Tablas Creek (WF Las Tablas Creek), which flows into the Nacimiento Reservoir. Wasterock and tailings eroded from the Little Bonanza Hg Mine have contributed Hg-enriched mine wastes to the headwaters of WF Las Tablas Creek. The mine is located on Federal land managed by the U.S. Bureau of Land Management (BLM), which requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in tailings, sediment, water, and biota at and downstream from the minesite. This report is in response that request, from the lead agency which is mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Little Bonanza minesite as a means of reducing Hg transport to WF Las Tablas Creek. This report summarizes data obtained from field sampling of mine tailings, wasterock, sediment, water, and biota at the Little Bonanza Mine that was completed on April 6, 2010. Conditions during sampling were dry and no rain had occurred in the watershed for several weeks. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could produce elevated levels of monomethyl mercury (MMeHg) in WF Las Tablas Creek and in biota. History and Geology The history of the Little Bonanza Hg mine is summarized here from Yates (1943) and other references as cited. The Little Bonanza Mine, located 20 mi west of Paso Robles, was discovered in 1862. Although production was minor until 1900, from 1900 to 1906, the mine produced about 1,000 flasks of Hg. Intermittent production continued into the 1940s but was relatively limited. Underground workings, now caved and inaccessible, include about 3,000 ft of drifts, crosscuts, and raises on three levels extending 260 ft downward. The workings at the Little Bonanza Mine explore a zone of fault breccia, which trends northwest. The breccia is composed of fragments of sandstone, greenstone, serpentine, and chert in a shale matrix. The serpentine has been hydrothermally altered to silica-carbonate rock, and the Hg deposit is hosted within the zone of alteration. The veins are discontinuous and irregular, but form a steplike pattern along the fault zone. The principal mineralization occurring in the veins is irregular, consisting of disseminated zones of cinnabar. Most of the veins in the mine area contain cinnabar. Sample Sites and Methods Samples were collected to assess the concentrations of Hg and biogeochemically relevant constituents in tailings and wasterock piles at the Little Bonanza Hg mine. Tailings are present adjacent to a three-pipe retort used to process the Hg ore. The tailings occur in the upper 15 cm of the soil adjacent to the retort and slag from the retort is present on the surface. An area of disturbed soil and rock uphill from the retort was likely formed during construction of a dam that provided water for mining activities. Wasterock in these piles was sampled. The largest amount of tailings is exposed to the west of the retort in the bank of WF Las Tablas Creek. Water, sediment, and biota were sampled from WF Las Tablas Creek, which flows through the mine area. Sample-site locations are shown in figures 10 and 11 and listed in table 1. Samples were collected when streamflow was low and no precipitation had occurred.

California