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Background and comparison of water-quality, streambed-sediment, and biological characteristics of streams in the Viburnum Trend and the exploration study areas, southern Missouri, 1995 and 2001

Missouri has a long history of lead mining in the Park Hills and Viburnum Trend areas. Lead ore production has been a significant economic presence since the settlement of Missouri in the 1700?s. As lead sources are depleted in active mining areas, new areas are being explored for economical ore bodies. The exploration area south of Winona, a possible extension of the Viburnum Trend lead-producing area, lies in an area of intense interest because of its scenic beauty and sensitive environment. Water-quality, streambed-sediment, fish tissue, instream and riparian habitat, and invertebrate-community samples were collected from three sites in the Viburnum Trend for the National Water-Quality Assessment (NAWQA) program Black River synoptic study in 1995 and from four sites in the exploration study area in 2001. The samples, which were collected using NAWQA protocols, were analyzed and compared to establish background conditions and similarities between sites. Bacteria, lead, and zinc concentrations were substantially different between the study areas. Habitat characteristics, such as streambed substrate size and embeddedness were similar. The Eleven Point River at Turner?s Mill is substantially larger in size than the other six surveyed sites. Trace element concentrations in fish tissue samples collected in the two study areas are similar. Samples from both areas had elevated mercury levels. Invertebrate community data indicated similarity among the Viburnum Trend study area sites, but these sites had little in common with the exploration study area sites. The invertebrate community structure in the exploration study area were not similar.

Water-Resources Investigations Report↗

Two-dimensional hydrodynamic simulation of surface-water flow and transport to Florida Bay through the Southern Inland and Coastal Systems (SICS)

Successful restoration of the southern Florida ecosystem requires extensive knowledge of the physical characteristics and hydrologic processes controlling water flow and transport of constituents through extremely low-gradient freshwater marshes, shallow mangrove-fringed coastal creeks and tidal embayments, and near-shore marine waters. A sound, physically based numerical model can provide simulations of the differing hydrologic conditions that might result from various ecosystem restoration scenarios. Because hydrology and ecology are closely linked in southern Florida, hydrologic model results also can be used by ecologists to evaluate the degree of ecosystem restoration that could be achieved for various hydrologic conditions. A robust proven model, SWIFT2D, (Surface-Water Integrated Flow and Transport in Two Dimensions), was modified to simulate Southern Inland and Coastal Systems (SICS) hydrodynamics and transport conditions. Modifications include improvements to evapotranspiration and rainfall calculation and to the algorithms that describe flow through coastal creeks. Techniques used in this model should be applicable to other similar low-gradient marsh settings in southern Florida and elsewhere. Numerous investigations were conducted within the SICS area of southeastern Everglades National Park and northeastern Florida Bay to provide data and parameter values for model development and testing. The U.S. Geological Survey and the National Park Service supported investigations for quantification of evapotranspiration, vegetative resistance to flow, wind-induced flow, land elevations, vegetation classifications, salinity conditions, exchange of ground and surface waters, and flow and transport in coastal creeks and embayments. The good agreement that was achieved between measured and simulated water levels, flows, and salinities through minimal adjustment of empirical coefficients indicates that hydrologic processes within the SICS area are represented properly in the SWIFT2D model, and that the spatial and temporal resolution of these processes in the model is adequate. Sensitivity analyses were conducted to determine the effect of changes in boundary conditions and parameter values on simulation results, which aided in identifying areas of greatest uncertainty in the model. The parameter having the most uncertainty (most in need of further field study) was the flow coefficient for coastal creeks. Smaller uncertainties existed for wetlands frictional resistance and wind. Evapotranspiration and boundary inflows indicated the least uncertainty as determined by varying parameters used in their formulation and definition. Model results indicated that wind was important in reversing coastal creek flows. At Trout Creek (the major tributary connecting Taylor Slough wetlands with Florida Bay), flow in the landward direction was not simulated properly unless wind forcing was included in the simulation. Simulations also provided insight into the major influence that wind has on salinity mixing along the coast, the varying distribution of wetland flows at differing water levels, and the importance of topography in controlling flows to the coast. Slight topographic variations were shown to highly influence the routing of water. A multiple regression analysis was performed to relate inflows at the northern boundary of Taylor Slough bridge to a major pump station (S-332) north of the SICS model area. This analysis allows Taylor Slough bridge boundary conditions to be defined for the model from operating scenarios at S-332, which should facilitate use of the SICS model as an operational tool.

Florida↗

Hydrogeology and Extent of Saltwater Intrusion in the Northern Part of the Town of Oyster Bay, Nassau County, New York: 1995–98

The Oyster Bay study area, in the northern part of Nassau County, N.Y., is underlain by unconsolidated deposits that form a sequence of aquifers and confining units. At least one production well has been affected by the intrusion of saltwater from Hempstead Harbor, Long Island Sound, and Cold Spring Harbor. Nineteen boreholes were drilled during 1995-98 for the collection of hydrogeologic, geochemical, and geophysical data to delineate the subsurface geology and the extent of saltwater intrusion. Continuous high-resolution marine-seismic-reflection surveys in the surrounding embayments of the Oyster Bay study area were conducted in 1996. New drill-core data indicate two hydrogeologic units—the North Shore aquifer and the North Shore confining unit—where the Lloyd aquifer, the Raritan confining unit, and the Magothy aquifer have been completely removed by glacial erosion. Water levels at 95 observation wells were measured quarterly during 1995–98. These data and continuous water-level records indicated that (1) the upper glacial (water-table) and Magothy aquifers are hydraulically connected and that their water levels did not respond to tidal fluctuations, and (2) the Lloyd and North Shore aquifers are hydraulically connected and their water levels responded to pumping and to tidal fluctuations. Marine seismic-reflection surveys in the surrounding embayments indicate at least four glacially eroded buried valleys with subhorizontal, parallel reflectors indicative of draped bedding that is interpreted as infilling by silt and clay. The buried valleys (1) truncate the surrounding coarse-grained deposits, (2) are asymmetrical and steep sided, (3) trend northwest-southeast, (4) are several miles long and about 1 mile wide, and (5) extend to more than 500 feet below sea level. Water samples taken during 1995–98 from three production wells and six observation wells screened in the upper glacial and Magothy aquifers contained volatile organic compounds in concentrations that exceeded the New York State Department of Health Drinking Water Maximum Contaminant Levels. High iron or nitrate concentrations were detected in water samples taken in 1997–98 from 39 observation wells. Previous high concentrations resulted in the shutdown of two production wells. Four distinct areas of saltwater intrusion in the Oyster Bay study area were delineated—three were in the upper glacial aquifer, and the fourth was in the Lloyd aquifer. Borehole-geophysical-logging data indicated that three of these saltwater "wedges" ranged from a few feet thick to more than 100 feet thick and had sharp freshwater-saltwater interfaces. Chloride concentrations in water from eight observation wells within these wedges in 1997 ranged from 125 to 13,750 milligrams per liter. One production well in Bayville has been shut down as of 1996 and others in the area may be affected by these saltwater wedges.

New York↗

Possible Extent and Depth of Salt Contamination in Ground Water Using Geophysical Techniques, Red River Aluminum Site, Stamps, Arkansas, April 2003

A surface-geophysical investigation of the Red River Aluminum site at Stamps, Arkansas, was conducted in cooperation with the Arkansas Department of Environmental Quality to determine the possible extent and depth of saltwater contamination. Water-level measurements indicate the distance to water level below land surface ranges from about 1.2 to 3.9 feet (0.37 to 1.19 meters) in shallow monitor wells and about 10.5 to 17.1 feet (3.20 to 5.21 meters) in deeper monitoring wells. The two-dimensional, direct-current resistivity method identified resistivities less than 5 ohm-meters which indicated possible areas of salt contamination occurring in near-surface or deep subsurface ground water along four resistivity lines within the site. One line located east of the site yielded data that demonstrated no effect of salt contamination. Sections from two of the five data sets were modeled. The input model grids were created on the basis of the known geology and the results and interpretations of borehole geophysical data. The clay-rich Cook Mountain Formation is modeled as 25 ohm-meters and extends from 21 meters (68.9 feet) below land surface to the bottom of the model (about 52 meters (170.6 feet)). The models were used to refine interpretation of the resistivity data and to determine extent of saltwater contamination and depth to the Cook Mountain Formation. Data from the resistivity lines indicate both near-surface and subsurface saltwater contamination. The near-surface contamination appears as low resistivity (less than 5 ohm-meters) on four of the five resistivity lines, extending up to 775 meters (2,542.8 feet) horizontally in a line that traverses the entire site south to north. Model resistivity data indicate that the total depth of saltwater contamination is about 18 meters (59 feet) below land surface. Data from four resistivity lines identified areas containing low resistivity anomalies interpreted as possible salt contamination. A fifth line located just east of the site showed no saltwater contamination.

Water-Resources Investigations Report↗

Hydrogeologic controls on ground-water discharge to the Washington METRO subway tunnel near the Medical Center station and Crossover, Montgomery County, Maryland

Excessive water intrusion has been observed inside several of the Washington Metropolitan Area Transit Authority subway tunnels, with the worst leakage occurring along the Red Line tunnels and stations north of Dupont Circle in Washington, D.C. These tunnels were constructed in bedrock that contains permeable (water-bearing) joints and fractures. Excessive water leakage through the walls and water inside the underground facilities has damaged mechanical and electrical components in the tunnel, and has escalated the deterioration rate of the rail system. The U.S. Geological Survey and the Washington Metropolitan Area Transit Authority have worked cooperatively on a study from 200003 to describe and quantify the factors controlling ground-water flow into the Red Line subway tunnel near the Medical Center Station and Crossover in Montgomery County, Maryland. The Red Line near the Medical Center Station and Crossover passes through or beneath the gneissic Sykesville Formation and the biotite-hornblende tonalite member of the Georgetown Intrusive Suite, both of which contain numerous fractures. The mapped foliation and joints of the Sykesville Formation in the vicinity of the Medical Center Station and Crossover are generally orientated north-south. Fractures in the Sykesville Formation in outcrops appear to be poorly connected. In the biotite-hornblende tonalite member of the Georgetown Intrusive Suite, the general orientation of the mapped foliation and joints is east-west. In contrast to the fractures in the Sykesville Formation, the fractures in the Georgetown Intrusive Suite in outcrops appear to be more numerous and have a greater degree of connectivity. Fractures intersecting four bedrock wells near the Medical Center Station and Crossover that were drilled into the biotite-hornblende tonalite member of the Georgetown Intrusive Suite show an east-west orientation matching the foliation and joints shown on geologic maps. The excessive water intrusion at the Medical Center Station and Crossover could be the result of its location within the Georgetown Intrusive Suite. The abrupt changes in the mapped directions of ground-water flow based on the hydraulic heads at the contact between the Sykesville Formation and biotite-hornblende tonalite member of the Georgetown Intrusive Suite could also be the result of the change in fracturing between these two lithologies. Saprolite, a residual of soft, red/brown to gray clay from decomposed crystalline rock, overlies the bedrock and varies from about 20 to 55 feet thick, depending on location. On the basis of a slug test conducted in the lower part of the saprolite near the Medical Center Station and Crossover, transmissivity and storativity of the saprolite were estimated to be 10 feet squared per day and 10-6 , respectively. The transmissivity of fractures intersecting bedrock boreholes drilled in the biotite-hornblende tonalite member of the Georgetown Intrusive Suite varies over five orders of magnitude, from a maximum of approximately 10 feet squared per day to the detection limit of the in situ testing apparatus, which is approximately 10-4 feet squared per day. In general, the transmissivity of fractures intersecting the boreholes increases with depth. The low transmissivity of bedrock fractures in close proximity to the saprolite is likely to be caused by the fractures being filled with byproducts of rock weathering, resulting in reduced permeability. 2 Hydrogeologic Controls on Ground-Water Discharge to the Washington METRO Subway Tunnel The bulk transmissivity of the bedrock aquifer is approximately 3.7 feet squared per day, as determined from an aquifer test conducted by pumping a 240-foot-deep borehole and monitoring the drawdown over 3 days in the pumped borehole and several observation boreholes. In general, the hydraulic head decreases with depth in bedrock boreholes, indicating the potential for downward ground-water flow. Based on hydraulic head values mea

Water-Resources Investigations Report↗

Relations among floodplain water levels, instream dissolved-oxygen conditions, and streamflow in the lower Roanoke River, North Carolina, 1997-2001

The lower Roanoke River corridor in North Carolina contains a floodplain of national significance. Data from a network of 1 streamflow-measurement site, 13 river-stage sites, 13 floodplain water-level sites located along 4 transects, and 5 in situ water-quality monitoring sites were used to characterize temporal and spatial variations of floodplain and river water levels during 1997-2000 and to describe dissolved-oxygen conditions in the lower Roanoke River for the period 1998-2001. Major differences in the relation of floodplain inundation to flow occurred both among sites at a given transect and among transects. Several floodplain sites were inundated for the full range of flow conditions measured during the study. These included one site on the Big Swash transect (at about river kilometer 119); one site on the Broadneck Swamp transect (river kilometer 97), which was inundated 91 percent of the time during the study; one site on the Devils Gut transect (river kilometer 44), which was inundated throughout the study; and three sites on the Cow Swamp transect (near river kilometer 10). The relation of floodplain inundation depth to Roanoke River flow was highly variable among sites. There was no relation between flow and inundation depth at one of the Big Swash sites or at any of the four Cow Swamp sites. At two of the Big Swash transect sites, there was some relation between inundation depth and 10-day mean flow for flows greater than 700 cubic meters per second. A relatively strong relation between inundation depth and 10-day mean flow occurred at two of the Broadneck Swamp sites and, to a lesser degree, at two of the Devils Gut transect sites. There was much greater interannual variability in floodplain water levels, as represented by the difference between the maximum and minimum daily water level for a given calendar date during January-May and September-October than during the summer and late fall months. If data from this study are representative of long-term conditions, then this means that there is less uncertainty about what future floodplain water levels will be during June-August and November-December than during other months. Rates of ground-water decline, primarily due to evapotranspiration, were fairly similar at all sites, ranging from about 3 to 4 centimeters per day. For a 10-day mean flow of 300 cubic meters per second, an evaporative loss of 2 centimeters per day is equal to about 56 cubic meters per second. Evapotranspiration rates are much lower during the fall and winter months, so losses of river flow to floodplain processes likely are much lower during those months. The ground-water gradient at most sites was from the floodplain to the river, indicating a potential for ground-water movement into the river from the floodplain. At two of the Devils Gut sites, however, the water level often was higher in the river than in the floodplain when floodplain sites were not inundated. This indicates that there is a potential for river water to move as ground water from the river into the floodplain. It seems likely that this feature observed at the Devils Gut transect occurs elsewhere in the lower Roanoke River corridor. Dissolved-oxygen concentrations typically decrease with increasing distance from Roanoke Rapids Dam. During the 1998-2001 study period, the median dissolved-oxygen concentration at Halifax (river kilometer 187), the upstream-most station, was 8.4 milligrams per liter, and the median concentration at the downstream-most station (NC-45, bottom sensor; river kilometer 2.6) was 6.6 milligrams per liter. Several synoptic measurements of dissolved-oxygen concentration down the river identified the presence of a dissolved-oxygen sag in the vicinity of Halifax, with some recovery of concentrations between Halifax and about Scotland Neck at river kilometer 156. Data from the synoptic measurements also indicated that the greatest rate of dissolved-oxygen change with distance along the riv

North Carolina↗

Quantification of metal loading to Silver Creek through the Silver Maple Claims area, Park City, Utah, May 2002

The Silver Maple Claims area along Silver Creek, near Park City, Utah, is administered by the Bureau of Land Management. To quantify possible sources of elevated zinc concentrations in Silver Creek that exceed water-quality standards, the U.S. Geological Survey conducted a mass-loading study in May 2002 along a 1,400-meter reach of Silver Creek that included the Silver Maple Claims area. Additional samples were collected upstream and downstream from the injection reach to investigate other possible sources of zinc and other metals to the stream. Many metals were investigated in the study, but zinc is of particular concern for water-quality standards. The total loading of zinc along the study reach from Park City to Wanship, Utah, was about 49 kilograms per day. The Silver Maple Claims area contributed about 38 percent of this load. The Silver Creek tailings discharge pipe, which empties just inside the Silver Maple Claims area, contributed more than half the load of the Silver Maple Claims area. Substantial zinc loads also were added to Silver Creek downstream from the Silver Maple Claims area. Ground-water discharge upstream from the waste-water treatment plant contributed 20 percent of the total zinc load, and another 17 percent was contributed near the waste-water treatment plant. By identifying the specific areas where zinc and other metal loads are contributed to Silver Creek, it is possible to assess the needs of a remediation plan. For example, removing the tailings from the Silver Maple Claims area could contribute to lowering the zinc concentration in Silver Creek, but without also addressing the loading from the Silver Creek tailings discharge pipe and the ground-water discharge farther downstream, the zinc concentration could not be lowered enough to meet water-quality standards. Additional existing sources of zinc loading downstream from the Silver Maple Claims area could complicate the process of lowering zinc concentration to meet water-quality standards.

Utah↗

Status of ground-water levels and storage volume in the Equus Beds aquifer near Wichita, Kansas, January 2000-January 2003

The Equus Beds aquifer northwest of Wichita, Kansas, was developed to supply water to Wichita residents and for irrigation in south-central Kansas beginning on September 1, 1940. Ground-water pumping for city and agricultural use from the aquifer caused water levels to decline in a large part of the area. Irrigation pumpage in the area increased substantially during the 1970s and 1980s and accelerated water-level declines. A period of water-level rises associated with greater-than-average precipitation and decreased city pumpage from the study area began in 1993. An important factor in the decreased city pumpage was increased use of Cheney Reservoir as a water-supply source by the city of Wichita; as a result, city pumpage from the Equus Beds aquifer during 1993-2002 went from being greater than one-half to slightly less than one-third of Wichita's water usage. Since 1995, the city also has been investigating the use of artificial recharge in the study area to meet future water-supply needs and to protect the aquifer from the intrusion of saltwater from natural and human-related sources to the west. During January 2003, the direction of ground-water flow in the Equus Beds aquifer in the area was generally from west to east similar to predevelopment of the aquifer. The maximum water-level decline since 1940 for the period January 2000 to January 2003 was 29.54 feet in July 2002 at well 3 in the northern part of the area. Cumulative water-level changes from January 2000 to January 2003 typically were less than 4 feet with rises of less than 4 feet common in the central part of the area; however, declines of more than 4 feet occurred in the northwestern and southern parts of the area. The recovery of water levels and aquifer storage volumes from record low levels in October 1992 generally continued to April 2000. The recovery of about 182,000 acre-feet of storage volume in the area from October 1992 to April 2000 represents about a 64-percent recovery of the storage depletion that occurred from August 1940 to October 1992. About 47 percent of this recovery was lost from April 2000 to October 2002 when storage volume in the area decreased by about 86,000 acre-feet. Major contributors to the decreases in water levels and storage volumes were reduced recharge associated with precipitation that was less than in the preceding 5 years and increased irrigation pumpage. The loss of storage probably would have been larger if the continued decrease in city pumpage, which is closely associated with the water-level rises in the central part of the study area, and increased city use of water from Cheney Reservoir had not occurred. The effect of artificial recharge on water levels and storage volume probably was masked by the generally larger decreases in city pumpage in the area.

Kansas↗

Evaluation of Water Quality for Two St. Johns River Tributaries Receiving Septic Tank Effluent, Duval County, Florida

Tributary streamflow to the St. Johns River in Duval County is thought to be affected by septic tank leachate from residential areas adjacent to these tributaries. Water managers and the city of Jacksonville have committed to infrastructure improvements as part of a management plan to address the impairment of tributary water quality. In order to provide data to evaluate the effects of future remedial activities in selected tributaries, major ion and nutrient concentrations, fecal coliform concentrations, detection of wastewater compounds, and tracking of bacterial sources were used to document septic tank influences on the water quality of selected tributaries. The tributaries Fishing Creek and South Big Fishweir Creek were selected because they drain subdivisions identified as high priority locations for septic tank phase-out projects: the Pernecia and Murray Hill B subdivisions, respectively. Population, housing (number of residences), and septic tank densities for the Murray Hill B subdivision are greater than those for the Pernecia subdivision. Water-quality samples collected in the study basins indicate influences from ground water and septic tanks. Estimated concentrations of total nitrogen ranged from 0.33 to 2.86 milligrams per liter (mg/L), and ranged from less than laboratory reporting limit (0.02 mg/L) to 0.64 mg/L for total phosphorus. Major ion concentrations met the State of Florida Class III surface-water standards; total nitrogen and total phosphorus concentrations exceeded the U.S. Environmental Protection Agency Ecoregion XII nutrient criteria for rivers and streams 49 and 96 percent of the time, respectively. Organic wastewater compounds detected at study sites were categorized as detergents, antioxidants and flame retardants, manufactured polycarbonate resins, industrial solvents, and mosquito repellent. The most commonly detected compound was para-nonylphenol, a breakdown product of detergent. Results of wastewater sampling give evidence that stream water in the study basins is affected by septic tank effluent. Fecal coliform bacteria concentrations were measured on a monthly basis; of 115 samples, 63 percent exceeded the State of Florida fecal coliform bacteria standard for Class III surface waters of 800 colonies per 100 milliliters of water on any 1 day. Fecal coliform bacteria concentrations ranged from less than 20 colonies per 100 milliliters of sample to greater than or equal to 160,000 colonies per 100 milliliters of sample. Antibiotic resistance patterns of fecal coliform bacteria were used to identify the sources of fecal coliform bacteria. Significant sources of fecal coliform bacteria included wild animals, dogs, and humans. A majority of the fecal coliform bacteria were classified to be from human sources. Because the primary source of fecal coliform bacteria is from human sources, and most likely septic tank effluent, management of human sources may substantially improve microbiological water quality in both the Fishing Creek and South Branch Big Fishweir Creek basins.

Water-Resources Investigations Report↗

Water use, ground-water recharge and availability, and quality of water in the Greenwich area, Fairfield County, Connecticut and Westchester County, New York, 2000-2002

Ground-water budgets were developed for 32 small basin-based zones in the Greenwich area of southwestern Connecticut, where crystalline-bedrock aquifers supply private wells, to determine the status of residential ground-water consumption relative to rates of ground-water recharge and discharge. Estimated residential ground-water withdrawals for small basins (averaging 1.7 square miles (mi 2 )) ranged from 0 to 0.16 million gallons per day per square mile (Mgal/d/mi 2 ). To develop these budgets, residential ground-water withdrawals were estimated using multiple-linear regression models that relate water use from public water supply to data on residential property characteristics. Average daily water use of households with public water supply ranged from 219 to 1,082 gallons per day (gal/d). A steady-state finite-difference ground-water- flow model was developed to track water budgets, and to estimate optimal values for hydraulic conductivity of the bedrock (0.05 feet per day) and recharge to the overlying till deposits (6.9 inches) using nonlinear regression. Estimated recharge rates to the small basins ranged from 3.6 to 7.5 inches per year (in/yr) and relate to the percentage of the basin underlain by coarse- grained glacial stratified deposits. Recharge was not applied to impervious areas to account for the effects of urbanization. Net residential ground-water consumption was estimated as ground-water withdrawals increased during the growing season, and ranged from 0 to 0.9 in/yr. Long-term average stream base flows simulated by the ground-water-flow model were compared to calculated values of average base flow and low flow to determine if base flow was substantially reduced in any of the basins studied. Three of the 32 basins studied had simulated base flows less than 3 in/yr, as a result of either ground-water withdrawals or reduced recharge due to urbanization. A water-availability criteria of the difference between the 30-day 2-year low flow and the recharge rate for each basin was explored as a method to rate the status of water consumption in each basin. Water consumption ranged from 0 to 14.3 percent of available water based on this criteria for the 32 basins studied. Base-flow water quality was related to the amount of urbanized area in each basin sampled. Concentrations of total nitrogen and phosphorus, chloride, indicator bacteria, and the number of pesticide detections increased with basin urbanization, which ranged from 18 to 63 percent of basin area.

Connecticut, New York↗

Effects of Jefferson Road stormwater-detention basin on loads and concentrations of selected chemical constituents in East Branch of Allen Creek at Pittsford, Monroe County, New York

Discharge and water-quality data collection at East Branch Allen Creek from 1990 through 2000 provide a basis for estimating the effect of the Jefferson Road detention basin on loads and concentrations of chemical constituents downstream from the basin. Mean monthly flow for the 5 years prior to construction of the detention basin (8.71 ft 3 /s) was slightly lower than after (9.08 ft 3 /s). The slightly higher mean monthly flow after basin construction may have been influenced by the peak flow for the period of record that occurred in July 1998 or variations in flow diverted from the canal. No statistically significant difference in average monthly mean flow before and after basin installation was indicated. Total phosphorus was the only constituent to show no months with significant differences in load after basin construction. Several constituents showed months with significantly smaller loads after basin construction than before, whereas some constituents showed certain months with smaller and some months with greater loads, after basin construction. Statistical analysis of the "mean monthly load" for all months before and all months after construction of the detention basin showed only one constituent (ammonia + organic nitrogen) with a significantly lower load after construction and none with higher loads. Median concentrations of ammonia + organic nitrogen showed a statistically significant decrease (from 0.78 mg/L to 0.60 mg/L) after basin installation, as did nitrite + nitrate (from 1.50 mg/L to 0.96 mg/L); in contrast, the median concentration of dissolved chloride increased from 95.5 mg/L before basin installation to 109 mg/L thereafter. A trend analysis of constituent concentrations before and after installation of the detention basin showed that total phosphorus had a downward trend after installation. Analysis of the data collected at East Branch Allen Creek indicates that the Jefferson Road detention basin, in some cases, provides an improvement (reduction) in loads of some constituents. These results are uncertain, however, because hydrologic conditions before basin installation differed from those in the 5 years that followed, and because inflow from the Erie-Barge canal may alter the water quality in the 1-mi reach between the basin outflow and the gaging station.

New York↗

Estimated use of water in the Tennessee River watershed in 2000 and projections of water use to 2030

Estimates indicate that after increases in water withdrawals from 1965 to 1980 in the Tennessee River watershed, withdrawals declined from 1980 to 1985 and remained steady from 1985 to 1995. Water withdrawals in the Tennessee River watershed during 2000 averaged about 12,211 million gallons per day (Mgal/d) of freshwater for offstream uses?22 percent more than the 1995 estimate. The 2000 estimate is nearly the same as the estimate for 1980, the highest year of record, with 12,260 Mgal/d. The reuse potential of water from the Tennessee River is high because most of the water withdrawn for offstream use is returned to the river system. Besides water quality, reuse potential reflects the quantity of water available for subsequent uses and is gaged by consumptive use, which is the difference between water withdrawals and return flow. For the Tennessee River watershed, return flow was estimated to be 11,562 Mgal/d, or 95 percent of the water withdrawn during 2000. Total consumptive use accounts for the remaining 5 percent, or 649 Mgal/d. Estimates of water withdrawals by source indicate that during 2000, withdrawals from surface water accounted for 98 percent of the total withdrawals, or 11,996 Mgal/d, 23 percent more than during 1995. Total ground-water withdrawals during 2000 were 215 Mgal/d, or 17 percent less than during 1995. During 2000, thermoelectric power withdrawals were estimated to be 10,276 Mgal/d; industrial, 1,205 Mgal/d; public supply, 662 Mgal/d; and irrigation, 68.9 Mgal/d. Return flows were estimated to be: thermoelectric power, 10,244 Mgal/d; industrial, 942 Mgal/d; and public supply, 377 Mgal/d. Consumptive use was estimated to be: thermoelectric power, 32.2 Mgal/d; industrial, 263 Mgal/d; public supply, 285 Mgal/d; and irrigation, 68.9 Mgal/d. Each category of use affects the reuse potential of the return flows differently. The consumptive use in the river is comparatively small because most of the water withdrawn from the Tennessee River watershed is used for once-through cooling for the thermoelectric power and industrial sectors. Average per capita use for all offstream uses was 2,710 gallons per day per person in 2000, compared to the record high of 3,200 in 1975 and 1980. The intensity of use for the Tennessee River watershed as measured as a function of area was 298,489 gallons per day per square mile in 2000. In 2030, water withdrawals are projected to increase by about 15 percent to 13,990 Mgal/d. By category, water withdrawals are projected to increase as follows: thermoelectric power, 11 percent or 1,152 Mgal/d; industry, 31 percent or 368 Mgal/d; public supply, 35 percent or 232 Mgal/d; and irrigation, 37 percent or 25.2 Mgal/d. Total consumptive use is projected to increase about 51 percent or 334 Mgal/d to 980 Mgal/d. Per capita use in 2030 is calculated to be about 2,370 gallons per day, about 26 percent less than in 1980. Water transfers to the Tennessee-Tombigbee waterway for navigation lockages were estimated as 200 Mgal/d for 2000 and 800 Mgal/d for 2030. Water transfers for hydropower commitments through Barkley Canal averaged 3,361 Mgal/d for 2000 and are estimated to be an average of 4,524 Mgal/d in 2030.

Water-Resources Investigations Report↗

Use of RORA for Complex Ground-Water Flow Conditions

The RORA computer program for estimating recharge is based on a condition in which ground water flows perpendicular to the nearest stream that receives ground-water discharge. The method, therefore, does not explicitly account for the ground-water-flow component that is parallel to the stream. Hypothetical finite-difference simulations are used to demonstrate effects of complex flow conditions that consist of two components: one that is perpendicular to the stream and one that is parallel to the stream. Results of the simulations indicate that the RORA program can be used if certain constraints are applied in the estimation of the recession index, an input variable to the program. These constraints apply to a mathematical formulation based on aquifer properties, recession of ground-water levels, and recession of streamflow.

Water-Resources Investigations Report↗

Total dissolved gas and water temperature in the lower Columbia River, Oregon and Washington, 2003: Quality-assurance data and comparison to water-quality standards

Significant Findings When water is released through the spillways of dams, air is entrained in the water, increasing the concentration of total dissolved gas. Excess dissolved-gas concentrations can have adverse effects on freshwater aquatic life. The U.S. Geological Survey (USGS), in cooperation with the U.S. Army Corps of Engineers, collected total- dissolved-gas and water-temperature data at seven sites on the lower Columbia River in 2003. Significant findings from the data include: For the seven monitoring sites in water year 2003, an average of 98.9% of the total-dissolved-gas data were received in real time by the USGS satellite downlink and were within 1% saturation of the expected value, based on calibration data, replicate quality-control measurements in the river, and comparison to ambient river conditions at adjacent sites. Most field checks of total-dissolved-gas sensors with a secondary standard were within plus or minus 1% saturation. Field checks of barometric pressure and water temperature were usually within plus or minus 1 millimeter of mercury and plus or minus 0.1 degree Celsius, respectively. The variances to the States of Oregon and Washington water-quality standards for total dissolved gas were exceeded at six of the seven monitoring sites. The sites at Camas and Bonneville forebay had the most days exceeding the variance of 115% saturation. The forebay exceedances may have been the result of the cumulative effects of supersaturated water moving downstream through the lower Columbia River. Apparently, the levels of total dissolved gas did not decrease rapidly enough downstream from the dams before reaching the next site. From mid-July to mid-September, water temperatures were usually above 20 degrees Celsius at each of the seven lower Columbia River sites. According to the Oregon water-quality standard, when the temperature of the lower Columbia River exceeds 20 degrees Celsius, no measurable temperature increase resulting from anthropogenic activities is allowed. Transient increases of about 1 degree Celsius were noted at the John Day forebay site, due to localized solar heating.

Oregon, Washington↗

Hydrogeologic characteristics of four public drinking-water supply springs in northern Arkansas

In October 2000, a study was undertaken by the U.S. Geological Survey (USGS) in cooperation with the Arkansas Department of Health to determine the hydrogeologic characteristics, including the extent of the recharge areas, for Hughes Spring, Stark Spring, Evening Shade Spring, and Roaring Spring, which are used for public-water supply in northern Arkansas. Information pertaining to each spring can be used to enable development of effective management plans to protect these water resources and public health. An integrated approach to determine the ground-water characteristics and the extent of the local recharge areas of the four springs incorporated tools and methods of hydrology, structural geology, geomorphology, geophysics, and geochemistry. Analyses of discharge, temperature, and water quality were completed to describe ground-water flow characteristics, source-water characteristics, and connectivity of the ground-water system with surface runoff. Water-level contour maps were constructed to determine ground-water flow directions and ground-water tracer tests were conducted to determine the extent of the recharge areas and ground-water flow velocities. Hughes Spring supplies water for the city of Marshall, Arkansas, and the surrounding area. The mean annual discharge for Hughes Spring was 2.9 and 5.2 cubic feet per second for water years 2001 and 2002, respectively. Recharge to the spring occurs mainly from the Boone Formation (Springfield Plateau aquifer). Ground-water tracer tests indicate the recharge area for Hughes Spring generally coincides with the surface drainage area (15.8 square miles) and that Hughes Spring is connected directly to the surface flow in Brush Creek. The geochemistry of Hughes Spring demonstrated variations with flow conditions and the influence of surface-runoff in the recharge area. Calcite saturation indices, total dissolved solids concentrations, and hardness demonstrate noticeable differences with flow conditions reflecting the reduced residence time and interaction of water with the source rock within the ground-water system at higher discharges for Hughes Spring. Concentrations of fecal indicator bacteria also demonstrated a substantial increase during high-flow conditions, suggesting that a non-point source of bacteria possibly from livestock may enter the system. Conversely, nutrient concentrations did not vary with flow and were similar to concentrations reported for undeveloped sites in the Springfield Plateau and Ozark aquifers in northern Arkansas and southern Missouri. Deuterium and oxygen-18 data show that the Hughes Spring discharge is representative of direct precipitation and not influenced by water enriched in oxygen-18 through evaporation. Discharge data show that Hughes Spring is dominated by conduit type ground-water flow, but a considerable component of diffuse flow also exists in the ground-water system. Carbon-13 data indicate a substantial component of the recharge water interacts with the surface material (soil and regolith) in the recharge area before entering the ground-water system for Hughes Spring. Tritium data for Hughes Spring indicate that the discharge water is a mixture of recent recharge and sub-modern water (recharged prior to 1952). Stark Spring supplies water for the city of Cushman, Arkansas, and the surrounding area. 2 Hydrogeologic Characteristics of Four Public Drinking-Water Supply Springs in Northern Arkansas The mean annual discharge for Stark Spring was 0.5 and 1.5 cubic feet per second for water years 2001 and 2002, respectively. The discharge and water-quality data show the ground-water system for Stark Spring is dominated by rapid recharge from surface runoff and mainly consists of a conduit- type flow system with little diffuse-type flow. Analyses of discharge data show that the estimated recharge area (0.79 square mile) is larger than the surface drainage area (0.34 square mile). Ground-water tracer tests and the outcrop of the

Water-Resources Investigations Report↗

Methods for estimating flood frequency in Montana based on data through water year 1998

Annual peak discharges having recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years (T-year floods) were determined for 660 gaged sites in Montana and in adjacent areas of Idaho, Wyoming, and Canada, based on data through water year 1998. The updated flood-frequency information was subsequently used in regression analyses, either ordinary or generalized least squares, to develop equations relating T-year floods to various basin and climatic characteristics, equations relating T-year floods to active-channel width, and equations relating T-year floods to bankfull width. The equations can be used to estimate flood frequency at ungaged sites. Montana was divided into eight regions, within which flood characteristics were considered to be reasonably homogeneous, and the three sets of regression equations were developed for each region. A measure of the overall reliability of the regression equations is the average standard error of prediction. The average standard errors of prediction for the equations based on basin and climatic characteristics ranged from 37.4 percent to 134.1 percent. Average standard errors of prediction for the equations based on active-channel width ranged from 57.2 percent to 141.3 percent. Average standard errors of prediction for the equations based on bankfull width ranged from 63.1 percent to 155.5 percent. In most regions, the equations based on basin and climatic characteristics generally had smaller average standard errors of prediction than equations based on active-channel or bankfull width. An exception was the Southeast Plains Region, where all equations based on active-channel width had smaller average standard errors of prediction than equations based on basin and climatic characteristics or bankfull width. Methods for weighting estimates derived from the basin- and climatic-characteristic equations and the channel-width equations also were developed. The weights were based on the cross correlation of residuals from the different methods and the average standard errors of prediction. When all three methods were combined, the average standard errors of prediction ranged from 37.4 percent to 120.2 percent. Weighting of estimates reduced the standard errors of prediction for all T-year flood estimates in four regions, reduced the standard errors of prediction for some T-year flood estimates in two regions, and provided no reduction in average standard error of prediction in two regions. A computer program for solving the regression equations, weighting estimates, and determining reliability of individual estimates was developed and placed on the USGS Montana District World Wide Web page. A new regression method, termed Region of Influence regression, also was tested. Test results indicated that the Region of Influence method was not as reliable as the regional equations based on generalized least squares regression. Two additional methods for estimating flood frequency at ungaged sites located on the same streams as gaged sites also are described. The first method, based on a drainage-area-ratio adjustment, is intended for use on streams where the ungaged site of interest is located near a gaged site. The second method, based on interpolation between gaged sites, is intended for use on streams that have two or more streamflow-gaging stations.

Montana↗

Changes in ground-water quality near two granular-iron permeable reactive barriers in a sand and gravel aquifer, Cape Cod, Massachusetts, 1997-2000

Two experimental permeable reactive barriers (PRBs) of granular zero-valent iron were emplaced in the path of a tetrachloroethene plume (the Chemical Spill-10 plume) at the Massachusetts Military Reservation, Cape Cod, Massachusetts, in June 1998. The goal of the field experiment was to achieve emplacement of a granular-iron PRB deeper than attempted before. The PRBs were expected to create a reducing environment and degrade the tetrachloroethene by reductive dechlorination. The goal of the work presented in this report was to observe temporary and sustained changes to the ground-water chemistry downgradient from the PRBs. A hydraulic-fracturing method involving injection of the granular iron with a guar-biopolymer and enzyme slurry was used to install the parallel 30- to 33-foot-wide wall-shaped barriers at a depth of 82 to 113 feet below land surface. An acetic acid and enzyme mixture was subsequently injected in wells near the barriers to degrade the guar biopolymer. Prior to the emplacement, tetrachloroethene concentrations in the Chemical Spill-10 plume at the study area were as high as 250 micrograms per liter. Other water properties in the plume generally were similar to the properties of uncontaminated ground water in the area, which typically has dissolved oxygen concentrations of 250 to 375 micromoles per liter, pH of 5.5 to 6.0, and specific conductance of 60 to 90 microsiemens per centimeter. Water-quality samples were collected periodically from monitoring wells near the PRBs to determine how the emplacement of the granular-iron walls altered the ground-water quality. In addition, an automated well-sampling device measured temperature, specific conductance, pH, and dissolved oxygen every 1–4 days for 16 months in a well downgradient from the two parallel PRBs. Temporary increases (lasting about 5 to 6 months) in specific conductance were observed downgradient from the PRBs as a result of the sodium chloride, potassium carbonate, and other salts included in the slurry and the acetic acid and enzyme mixture that was subsequently injected to degrade the guar biopolymer. Temporary increases in the concentrations of major cations (sodium, potassium, magnesium, and calcium) were observed downgradient from the PRBs, as were temporary but substantial increases in the dissolved and total organic carbon concentrations. Methane was detected, sulfate concentrations decreased temporarily, and concentrations of dissolved inorganic carbon increased in samples from wells downgradient from the PRBs. A sustained (longer than 12 months) reducing environment, in which dissolved oxygen concentrations decreased to zero, the pH increased to about 6.8, and dissolved iron concentrations increased substantially, developed as a result of the oxidation (corrosion) of the granular iron; this zone persisted at least 65 feet downgradient from the PRBs. The pH and dissolved iron concentrations increased with distance from the granular-iron walls. Concentrations of arsenic, cobalt, manganese, and phosphorus increased, and nitrate concentrations were reduced to below the detection limit downgradient from the walls. A sustained decrease of tetrachloroethene concentrations was not observed; however, reductive dechlorination products were observed at wells downgradient from the PRBs during several rounds of sampling. The emplacement of zero-valent iron in the aquifer to remove tetrachloroethene from the ground water caused changes in the water chemistry that persisted farther downgradient from the PRBs than has been observed at other sites because of the low chemical reactivity of the quartz-dominated aquifer sediments and the low ambient dissolved chemical concentrations in the ground water. The small transverse dispersion in the aquifer and the probable long-term persistence of the iron indicate that the chemically altered zone probably will extend a substantial distance downgradient from the PRBs for a substantial period of time (years); further investigation would be needed to determine this distance.

Massachusetts↗