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Small watershed studies: Analytical approaches for understanding ecosystem response to environmental change

Biogeochemical studies in small watersheds provide an analytical approach to understand how ecosystems respond to natural climatic variations and human-induced environmental change. Small watersheds, usually less than 5 km2, are small enough to permit characterization and understanding of ecosystem processes within relatively simple, homogeneous biological and physical settings; yet they are large enough to incorporate more complex processes and element cycles than can be studied at plot scales. Watersheds comprise discrete hydrochemical environments allowing quantification of hydrologic, element, and energy budgets. Element budgets, or mass balances, can be quantified as the difference between the mass of a solute that enters a watershed in wet and dry deposition and leaves a watershed in streamflow. Element budgets are primary tools used to investigate biogeochemical processes. Monitoring various aspects of element budgets to assess ecosystem health and stability is analogous to measuring the pulse or blood chemistry of a patient. Monitoring streamwater chemistry, basic climate, soil, and biotic variables provide a means to integrate complex biogeochemical processes and evaluate trends in water quality. Small watershed studies provide a scientific basis to develop predictive models of watershed function. Major emphases of small watershed studies include investigation of hydrologic and chemical responses to natural climate variation, anthropogenic stressors, and alternate forest-management practices. The nature and significance of biogeochemical research in small watersheds is reviewed by Moldan and Cerny (1994). The U.S. Geological Survey, U.S. Department of Agriculture Forest Service, and other federal agencies support several long-term small watershed studies to provide insight into a variety of ecosystem processes. Long-term records are essential to distinguish trends resulting from natural climatic variations or other stressors. The following sites, with noted periods of records, are examples of intensively studied forested watersheds in eastern USA supported by federal agencies: ■ Coweeta Hydrologic Laboratory, North Carolina, (1939-present), Swank and Crossley (1988). ■ Hubbard Brook Experimental Forest, New Hampshire, (1956-present), Bormann and Likens (1979). ■ Sleepers River Research Watershed, Vermont, (1958-present), Shanley et al. (1995). ■ Walker Branch Watershed, Tennessee, (1967-present), Johnson and Van Hook (1989). ■ Catoctin Mountains Research Site, Maryland, (1982-present), Rice and Bricker (1995). ■ Catskill Stream Network, New York, (1983- present), Murdoch and Stoddard (1992). ■ Panola Mountain Research Watershed, Georgia, (1985-present), Huntington et al. (1993). Small watershed studies also provide essential baseline information for understanding variations in water quality and element cycling in "pristine" ecosystems that can be used as benchmarks to evaluate anthropogenic impacts and alternate watershed management practices. This paper provides examples of how analytical tools developed through watershed research provide insight into ecosystem processes and can contribute to the management of watershed resources.

Conference Paper↗

Large streamflow differences between forested and urbanized watersheds in the energy-limited eastern United States: The role of evapotranspiration and impervious surfaces

Urban forests and other green infrastructures have been viewed as part of the “Nature-based Solutions” (NbS) to mitigate emerging urban environmental change. This study focuses on the role of evapotranspiration (ET) in regulating water balances of small watersheds in the eastern United States. We compared streamflow and ET patterns at daily, monthly and annual scales and linked these hydrological variables to the physical properties of 11 paired watersheds dominated by forests (FW) or urban (UW) land covers. The annual precipitation ranged from 1028 mm to 1683 mm and potential ET (PET) from 815 mm to 1450 mm. The mean annual flow/precipitation (Q/P) ratios were 0.26 ± 0.13 and 0.41 ± 0.1 for FW and UW, respectively. Overall, UW had lower annual ET (772 mm in UW vs. 947 mm in FW), but higher mean annual and (∼58% higher), monthly water yield (17%–186% higher), and peakflow rates (up to 100 times higher) than FW. The streamflow differences between FW and UW were most pronounced during the growing season and early winter (June-November). The mean Q/P ratios for 30 large hurricane events (2016–2021) were 0.12 ± 0.11 and 0.38 ± 0.23 for FW and UW, respectively. The flow rates in the dormant season (around December-May) in UW were similar or lower than FW. We developed conceptual models to explain the seasonal and storm event streamflow differences using background climate (PET), ET, and land surface characteristics. Urban NbS designs should factor in strategies that maximize ET while minimizing impervious surfaces enhancing watershed “sponge” and “pump” functions.

eastern United States↗

Cursed? Why one does not simply add new data sets to supervised geothermal machine learning models

Recent advances in machine learning (ML) identifying areas favorable to hydrothermal systems indicate that the resolution of feature data remains a subject of necessary improvement before ML can reliably produce better models. Herein, we consider the value of adding new features or replacing other, low-value features with new input features in existing ML pipelines. Our previous work identified stress and seismicity as having less value than the other feature types (i.e., heat flow, distance to faults, and distance to magmatic activity) for the 2008 USGS hydrothermal energy assessment; hence, a fundamental question regards if the addition of new but partially correlated features will improve resulting models for hydrothermal favorability. Therefore, we add new maps for shear strain rate and dilation strain rate to fit logistic regression and XGBoost models, resulting in new 7-feature models that are compared to the old 5-feature models. Because these new features share a degree of correlation with the original relatively uninformative stress and seismicity features, we also consider replacement of the two lower-value features with the two new features, creating new 5-feature models. Adding the new features improves the predictive skill of the new 7-feature model over that of the old 5-feature model; albeit, that improvement is not statistically significant because the new features are correlated with the old features and, consequently, the new features do not present considerable new information. However, the new 5-feature XGBoost model has a statistically significant increase in predictive skill for known positives over the old 5-feature model at p = 0.06. This improved performance is due to the lower-dimensional feature space of the former than that of the latter. In higher-dimensional feature space, relationships between features and the presence or absence of hydrothermal systems are harder to discern (i.e., the 7-feature model likely suffers from the “curse of dimensionality”).

Geothermal Resources Council Transactions↗

Geohydrology of the High Energy Laser System Test Facility site, White Sands Missile Range, Tularosa Basin, south-central New Mexico

The Yesum-HoHoman and Gypsum land (hummocky) soils at the High Energy Laser System Test Facility (HELSTF) represent wind deposits from recently desiccated lacustrine deposits and deposits from the ancestral Lake Otero. The upper 15-20 feet of the subsurface consists of varved gypsiferous clay and silt. Below these surfidai deposits the lithology consists of interbedded clay units, silty-clay units, and fine- to medium-grained quartz arenite units in continuous and discontinuous horizons. Clay horizons can cause perched water above the water table. Analyses of selected clay samples indicate that clay units are composed chiefly of kaolinire and mixed-layer illite/ smectite. The main aquifer is representative of a leaky-confined aquifer. Estimated aquifer properties are: transmissivity (T) = 780 feet squared per day, storage coefficient (S) = 3.1 x 10-3, and hydraulic conductivity (K) = 6.0 feet per day. Ground water flows south and southwest; the estimated hydraulic gradient is 5.3 feet per mile. Analyses of water samples indicate that ground water at the HELSTF site is brackish to slightly saline at the top of the main aquifer. Dissolved-solids concentration near the top of the main aquifer ranges from 5,940 to 11,800 milligrams per liter. Predominant ions are sodium and sulfate. At 815 feet below land surface, the largest dissolved-solids concentration measured is 111,000 milligrams per liter, which indicates increasing salinity with depth. Predominant ions are sodium and chloride.

Water-Resources Investigations Report↗

Water-level data from wells and test holes through 1991 and potentiometric contours as of 1991 for Yucca Flat, Nevada Test Site, Nye County, Nevada

The underground nuclear-testing program of the U.S. Department of Energy takes place at the Nevada Test Site, about 65 miles northwest of Las Vegas, Nev. Water levels in Yucca Flat may be affected by underground nuclear testing. The purpose of this map report is to present water-level data collected from wells and test holes through December 1991, and to present potentiometric contours representing 1991 water-table conditions in Yucca Flat. Water-level data from 91 sites are shown on the map and include information from 54 sites shown on a 1983 map. Water levels ranged from 519.5 to 2,162.9-feet below land surface. Potentiometric contours are drawn from water-level data to represent the altitude of the water table. Water-level altitudes ranged from about 2,377 ft to 2,770 ft above sea level in the central part of Yucca Flat and from about 4,060 ft to 2,503 ft above sea level in the western and northern parts of Yucca Flat. The water-level data were contoured considering the hydrologic setting, including the concept that water levels within the Cenozoic hydrologic units in the central part of the study area are elevated with respect to water levels in the adjacent and underlying Paleozoic hydrologic units. The most notable feature in the central part of the area is the presence of four ground-water mounds not shown on the 1983 map.

Water-Resources Investigations Report↗

Water quality and hydrology of the Lac Vieux Desert watershed, Gogebic County, Michigan, and Vilas County, Wisconsin, 2002-04

Lac Vieux Desert is a prominent 6.6 square-mile lake that straddles the Michigan-Wisconsin border and forms the headwaters of the Wisconsin River. For generations, the Lac Vieux Desert Band of Lake Superior Chippewa Indians have used Lac Vieux Desert and the surrounding area for growing and harvesting wild rice, and hunting and fishing. The Lac Vieux Desert Band is concerned about the impact of lake-stage regulation on hydrology and ecology, and the impact on water quality of development along and near the shore, and recreational watercraft use and sport fishing. In 2005, the U.S. Geological Survey completed a water-resources investigation of the Lac Vieux Desert watershed in cooperation with the Lac Vieux Desert Band of Lake Superior Chippewa Indians. Water quality of Lac Vieux Desert is typical of many lakes in the northern United States. Trophic State Index calculations classify Lac Vieux Desert as a highly productive eutrophic lake. The pH of water in Lac Vieux Desert ranged from 6.5 to 9.5, and specific conductance ranged from 62 to 114 µs/cm. Chloride concentration was less than 1.5 mg/L, indicating little effect from septic-tank or road-salt input. Results indicate that the water can be classified as soft, with hardness concentrations reported as calcium carbonate ranging from 29 to 49 mg/L. Concentrations of calcium, magnesium, chloride, and other dissolved solids ranged from 47 to 77 mg/L. Alkalinity of Lac Vieux Desert ranged from 27 to 38 mg/L. Pervasive aquatic blooms, including a bloom noted during the September 2003 sampling, are apparently common in late summer. Biological productivity at Lac Vieux Desert does not appear to have changed appreciably between 1973 and 2004. In the current study, total phosphorus concentrations ranged from 0.01 to 0.064 mg/L and dissolved nitrite plus nitrate nitrogen concentrations ranged from at, or below detection limit to 0.052 mg/L. Overabundance of nutrients in Lac Vieux Desert, particularly nitrogen and phosphorus, could result in considerable degradation in lake-water quality. The estimated water balance includes the following inputs from the surrounding watershed: direct precipitation (35 percent); runoff, composed of streamflow and overland flow (50 percent); and ground-water flow (15 percent). Outputs from Lac Vieux Desert include streamflow into the Wisconsin River (68 percent) and evaporation from the lake surface (32 percent). Seasonal regulation of Lac Vieux Desert outflow results in an artificially high lake stage throughout the year, except from late winter to very early spring, prior to snowmelt and runoff. Regulation of Lac Vieux Desert outflow causes Wisconsin River streamflow to be artificially low during spring and summer and artificially high in fall and winter. Recent studies indicate that lake-level regulation over the past century may have affected wild rice growth and propagation in Lac Vieux Desert. As per licensing agreement between the Federal Energy Regulatory Commission and the Wisconsin Valley Improvement Company (operators of the dam at the outlet), the maximum lake level of Lac Vieux Desert was lowered about 0.8 feet to investigate the relation between lake-level regulation and propagation of wild rice from 2003 through 2012. Recent plantings of wild rice by the Lac Vieux Desert Band have been successful, indicating that suitable habitat and hydrologic regime were present in 2004-05.

Michigan, Wisconsin↗

Crystalline-rock ejecta and shocked minerals of the Chesapeake Bay impact structure, USGS-NASA Langley core, Hampton, Virginia, with supplemental constraints on the age of impact

The USGS-NASA Langley corehole at Hampton , Va., was drilled 2000 as the first in a series of new coreholes drilled in the late Eocene Chesapeake Bay impact structure to gain a comprehensive understanding of its three-dimensional character. This understanding is important for assessing ground-water resources in the region, as well as for learning about marine impacts on Earth. We studied crystalline-rock ejecta and shock-metamorphosed minerals from the Langley core to determine what they reveal about the geology of crystalline rocks beneath the Atlantic Coastal Plain and how those rocks were affected by the impact . An unusual polymict diamicton, informally called the Exmore beds (upper Eocene), is 33.8 meters (m; 110.9 feet (ft)) thick and lies at a depth of 269.4 to 235.65 m (884.0 to 773.12 ft) in the core . This matrix-supported sedimentary deposit contains clasts of Tertiary and Cretaceous sediment (ranging up to boulder size) and sparse pebbles of crystalline rock . The matrix consists of muddy sand that contains abundant quartz grains and minor glauconite and potassium feldspar. Significantly, the sandy matrix of the Exmore beds contains sparse quartz grains (0.1 to 0.3 millimeter (0.004 to 0.012 inch) in diameter) that contain multiple sets of intersecting planar deformation features formerly referred to as shock lamellae. As many as five different sets have been observed in some quartz grains. Planar deformation features also occur in quartz grains in reworked crystalline-rock clasts in the Exmore beds. Such grains are clearly of shock-metamorphic origin. The presence of these features indicates that the quartz grains have experienced pressures greater than 6 gigapascals (GPa) and strain rates greater than 10 6 /second. Thus, the shock-metamorphosed quartz grains, although rare, provide clear and convincing evidence that the Exmore beds are of hybrid impact origin. Identification of shocked quartz grains in the Langley core adds to the number of sites in the structure where their presence is confirmed. Most of the clasts of crystalline rock that are in and just below the Exmore beds are rounded, detrital, and typical of coastal plain sediments. However, a few have angular shapes and consist of cataclastically deformed felsite having aphanitic-porphyritic to aphanitic texture and peraluminous rhyolite composition. Three of these clasts contain quartz grains that display two sets of planar deformation features of shock-metamorphic origin. Shock-metamorphosed quartz is an integral part of the cataclastic fabric in these three clasts, indicating that both the fabric and the shocked quartz were produced by the same high-energy impact event. Some felsite clasts have spherulitic textures that may be features either of an impact melt or of preimpact volcanic rocks. A weighted-mean total-fusion 40 Ar/ 39 Ar age of 35.3±0.1 Ma (±lσ) for 19 analyses of 4 North American tektites records the age of the late Eocene Chesapeake Bay impact event.

Chesapeake Bay↗

Geohydrology of the proposed Waste Isolation Pilot Plant site, Los Medanos area, southeastern New Mexico

Geohydrologic data have been collected in the Los Medanos area at the U.S. Department of Energy 's proposed Waste Isolation Pilot Plant (WIPP) site in southeastern New Mexico since 1975 as part of an intensive study evaluating the feasibility of storing defense-associated nuclear wastes within the bedded salt of the Salado Formation of Permian age. Drilling and hydrologic testing have identified three principal water-producing zones above the salt, including the Rustler-Salado Formational contact and the Culebra and Magenta Dolomite Members of the Permian Rustler Formation. Below the bedded salt there is another water-bearing zone, the channel sandstones of the Bell Canyon formation of the Permian Delaware Mountain Group. Most data collected from 33 hydrologic test holes indicate that the water-bearing zones are characterized by low transmissivities and contain slightly saline to briny water. Data collected from drill-stem tests in the Bell Canyon Formation indicate the channel sandstones have hydraulic conductivities ranging from 0.02 to 0.36 feet per day grade vertically and laterally into siltstones and shales of very low permeability. The Rustler Formation contains the principal water-producing zones identified at the WIPP site. The Rustler-Salado formational contact has the least transmissivity, ranging from 0.00003 to 0.003 feet squared per day. The Culebra Dolomite is the most productive unit at the WIPP site with transmissivities ranging from 0.001 to 73 feet squared per day; the greater values result from fracturing in the dolomite created by dissolution of underlying halite. Minute vertical permeabilities prevent movement of water between hydrologic units. (USGS)

Water-Resources Investigations Report↗

Water-power resources in upper Carson River basin, California - Nevada

West Fork Carson River offers the best opportunity for power development in the Carson River basin. The Hope Valley reservoir site could be developed to provide adequate storage regulation and concentration of fall would permit utilization of 1,400 feet of head in 51h miles below the clam site, or 1,900 feet of head in about 972 miles below the dam site; however, the average annual runoff susceptible of development is only about 70,000 acre-feet which limits the power that could be developed continuously in an average year with regulation to about 8,700 kilowatts utilizing 1,400 feet of head, or 12,000 kilowatts utilizing 1,900 feet of head. The method and degree of development will be determined to large extent by the method devised to supplement regulated flows from the Hope Valley reservoir to supply the water already appropriated for irrigation. If the Hope Valley site and the Watasheamu site on East Fork Carson River were developed coordinately water could be transferred to the West Fork for distribution through canals leading from that stream thus satisfying the deficiency due to regulation at Hope Valley and release of stored water on a power schedule. This would permit utilization of the entire 1,900 feet of fall. Independent development of the West Fork for optimum power production would require re-regulation of releases from Hope Valley reservoir and storage of a considerable part of the fall and winter flow for use during the irrigation season. Adequate storage capacity is apparently not available on the West Fork below Hope Valley; but offstream storage may be available in Diamond Valley which could be utilized by diversion from the West Fork near Woodfords. This would limit the utilization of the stream for power purposes to the development of the 1,400 feet of head between the Hope Valley dam site and Wood fords. In a year of average discharge East Fork Carson River and three of its principal tributaries could be developed to produce about 13,500 kilowatts of firm power upstream of the Watasheamu site, which has been proposed as the location of a storage reservoir, the principal use of which would be for irrigation and flood control purposes. Substantial storage regulation would be required because of the seasonal variation in flow; and while sufficient storage capacity is available for such regulation, its value for power development is limited because of the lack of concentration of fall below the storage sites where head could be economically developed. The Watasheamu reservoir with a powerplant near the Horseshoe: Bend site could be operated to develop about 5,400 kilowatts of continuous power in a year of average discharge; however, priority to use of water for irrigation purposes would undoubtedly require operation of the Watasheamu reservoir on a schedule unfavorable to the production of firm power. It is estimated that 47 million kilowatt-hours represents the maximum generation capability of a plant at the Horseshoe Bend site in year of average discharge and a large proportion of this amount would be generated during the period of peak irrigation demand and would be seasonal in nature. Installation of about 7,000 kilowatts of capacity in a plant at the Horseshoe Bend site appears feasible. Annual energy generation would probably be less than the maximum represented by streamflow, depending on the magnitude of releases from the Watasheamu reservoir for irrigation and the demand for seasonal power. It is judged, from a general consideration of the probable cost of the required Structures in relation to the benefits which would accrue from the power that could be produced, that development of East and West Forks Carson River for power purposes only would not be feasible.

California, Nevada↗

Stage-discharge relations for selected culverts and bridges in the Big Lost River flood plain at the Idaho National Engineering and Environmental Laboratory, Idaho

Information is needed by the U.S. Department of Energy at the Idaho National Engineering and Environmental Laboratory to determine the extent and severity of potential flooding at facilities along the Big Lost River. Two computer programs—the Culvert Analysis Program (CAP) and the HECRAS model—were used to define stage-discharge relations for 31 culverts and 2 bridge sites in a 10- mile reach of the river. These relations can be used to improve surface-water-flow models to evaluate potential flooding. Relations between headwater, tailwater, and discharge through each structure were unique. Discharge through the culverts as computed by the CAP ranged from about 0 cubic feet per second to as much discharge as could be conveyed, and tailwater elevations ranged from about 0 to 30 feet above the outlet elevation. Discharge through the bridges, as computed by the HEC-RAS model, ranged from nearly 0 to 7,000 cubic feet per second, and tailwater elevations ranged from nearly 0 to 30 feet above the streambed on the downstream cross section of each bridge. Stage-discharge relations provided in lookup tables in this report can be incorporated into numerical surface-water-flow models to simulate the effects of hydraulic structures on flood flows. One limitation of the CAP and HEC-RAS models is that changes in flow conditions, such as obstruction by sediment and debris, are not simulated. If flow through a hydraulic structure is obstructed by sediment or debris, then model-simulated discharges through the structure might be greater than would be experienced under actual conditions.

Idaho↗

Early avian research at the Savannah River Site, South Carolina: historical highlights and possibilities for the future

Avian biology and collection of baseline population data was a major part of the first decade (1951-1961) of field research at the Savannah River Site (SRS). Baseline inventories involving organisms and land-use types were part of the mission in the early contracts between the Atomic Energy Commission (now the Department of Energy) and the University of Georgia prior to the establishment of the Savannah River Ecology Laboratory (SREL) as a National Environmental Research Park Laboratory. About 27% of the SREL publications during this first decade dealt with birds. Since that time, research on the SRS landscape has expanded and broadened with less than 10% of the publications dealing with birds. SRS changed also from an agriculturally dominated area with ca. 40% open areas (fields, crops, pastures) to a timber-managed area with ca. 80% forests, 12% open areas, and 2% open water impoundments. Baseline breeding bird populations of the SRS in the 1950s were typical for the region with avian species richness and density increasing with the age and succession of the vegetation (0-26 species and densities of 0-741 pairs/km2 for the habitats surveyed). During the first decade at the SRS, the resident game bird population of Northern Bobwhites (Colinus virginianus) increased and the Mourning Dove (Zenaida rnacroura) population, a migratory upland game bird, remained stable. Current avian research efforts, as well as new opportunities to reexamine the breeding bird populations and the landscape of SRS, will provide a better understanding of the potential causes of declines of neotropical migratory birds, declines of resident and migratory game birds, and how habitat influences invasions and extinctions of breeding birds in the region. Emphasis for future research and monitoring should be on neotropical migratory bird populations in decline (Yellow-billed Cuckoo, Coccyzus americanus; Eastern Wood-Pewee, Contopus virens; Wood Thrush, Hylocichla mustelina; Prairie Warbler, Dendroica discolor; and Painted Bunting, Passerina ciris), resident species in decline (e.g., Loggerhead Shrike, Lanius ludovicianus), certain species groups (e.g., waterfowl and wading birds), important habitat, and recent invasions and extinctions of breeding species. Old growth forested wetlands should be monitored because of the large number of neotropical migratory birds that depend on this habitat in the southeastern United States. A variety of survey techniques will be needed to determine population trends: line transects, call or song playbacks, roadside point surveys (call counts for game birds), aerial surveys, and presence or absence of species within stratified areas of SRS. The SRS provides opportunity for avian research at the landscape level with the potential to solve problems important to the survival of many bird populations as well as to increase our knowledge on how to manage and conserve our avian natural resources for the future.

Book chapter↗

Organic petrology and micro-spectroscopy of Tasmanites microfossils: Applications to kerogen transformations in the early oil window

The transformation of kerogen to hydrocarbons in the early stages of oil generation is critical for understanding the resource potential of liquid-rich shale plays. Organic petrology commonly is used for visual evaluation of type, quality, and thermal maturity of organic matter, but the relationship of visual petrographic changes to chemical transformations is not well characterized. To improve understanding of these processes, organic-walled microfossils of the unicellular green alga Tasmanites (composed of algaenan) in Upper Devonian Ohio Shale (Huron Member, Appalachian Basin) were analyzed by micro-spectroscopy techniques including micro-Fourier transform infrared (micro-FTIR), X-ray photoelectron (XPS), electron probe microanalysis (EPMA), and fluorescence. Immature to mid-oil window maturation sequences of core and outcrop samples with solid bitumen reflectance (BR) and vitrinite reflectance (VR) values ranging from 0.45 to 0.80 %Ro were used. Hydrous pyrolysis was applied to low-maturity (BR: 0.25–0.39 %Ro) Huron and time-correlative New Albany shale samples to create similar artificial maturation sequences for comparison. Micro-FTIR spectroscopy revealed a decrease in the CH 2 /CH 3 ratio with increasing maturity, indicating Tasmanites aliphatic chains become shorter and more branched. Oxygenated functional groups decreased relative to aliphatic stretching bands and increased aromaticity was noted at the highest maturities. In samples that were pyrolyzed for 72 h at temperatures of 300–320 °C (BR: 0.56–0.68 %Ro), Tasmanites showed similar trends, whereas at pyrolysis temperatures of 340 °C and higher (BR > 1.0 %Ro), Tasmanites was pseudomorphed by accumulations of solid bitumen, carbonate and sulfide. Replacement of Tasmanites by these phases in hydrous pyrolysis experiments ≥340 °C and its absence at higher maturities (peak oil, VR and BR ≥ 0.9 %Ro) in naturally matured samples, as documented in a previous study, implies that a large fraction of the algaenan component of original organic carbon is converted to petroleum during thermal maturation. XPS analysis indicated the molar proportion of aliphatic carbon increases with increasing thermal maturity, accompanied by decreases in oxygenated functional groups and olefinic carbon. EPMA of Tasmanites showed highest concentrations of S, with concentrations of redox-sensitive trace elements U, Mo, Ni and V generally at or below detection limits. Decrease in organic S with increasing thermal maturity may be related to cleavage of Tasmanites at C S linkages; however, this relationship was inconsistent and presence of adjacent or entrained nanoscale silicate or sulfide phases may impact measured trace element concentrations. Fluorescence microscopy and spectroscopy showed a red shift in spectral maxima and decreased emission intensities with increasing maturity, interpreted as due to non-radiative energy loss possibly because of increased aromaticity. Collectively, these results provide new insights into the in situ chemical transformations that accompany petrographic changes as oil-prone kerogen converts to petroleum with thermal advance from immature conditions into the mid-oil window.

Organic Geochemistry↗

Great Lakes spatial priorities study

Spatial data about the bathymetry, habitat characteristics, underlying geology, and other features of the ocean and inland seas are essential for decision-making. Marine research and management organizations use these data to help ensure safe navigation, promote sustainable fisheries, extract energy, and protect marine habitats in the coastal and ocean waters of the U.S. Exclusive Economic Zone (EEZ) and Laurentian Great Lakes. Many of these organizations may have overlapping or shared mapping interests without knowing it. In a multi-jurisdictional planning environment, it can be challenging and cumbersome to determine where other entities have shared or overlapping mapping interests, especially across a transnational region such as the Great Lakes. State and provincial governments, federal governments, academia, tribes and First Nations, and other stakeholders from both the U.S. and Canada all have mapping interests across Great Lakes waters. Identifying and communicating target geographies for new data collection that are shared among multiple organizations can both help to avoid redundancy of new mapping efforts, and create opportunities for greater efficiency through collaboration. To address this issue, a spatial priorities study was conducted using a geospatial tool developed by the National Ocean Services National Centers for Coastal and Ocean Science (NCCOS). The tool provided an easy-to-use online interface in which programs can identify their priorities in a simple and straightforward way. This study asked representatives of Great Lakes management and science organizations to identify the areas for which they needed maps of lakebed features on a near-term, mid-term, and long-term timeframe, and why. Then, the responses were analyzed and overlaid to determine areas of shared mapping need and opportunity and to determine the types of map products needed. The analysis revealed high interest among multiple organizations in discrete geographies including the Minnesota and Wisconsin shoreline from Duluth to the eastern extent of the Bayfield Peninsula, Green Bay in Lake Michigan, and the southern coastlines of Lake Erie and Lake Ontario, the St. Marys River, and the northern Lake Superior coastal waters near Grand Portage, MN. Lower priority mapping interest were distributed widely across all lakes, but tended to be concentrated in nearshore areas (<30 m depth). The analysis also indicated that the top mapping justifications were Habitat/biota/natural area, Benthic exploration, Commercial and recreational fishing, and Scientific research. The top desired map product types were Elevation, Substrate/sub-bottom geologic characterization, and Habitat map/characterization, although participants on some lakes noted other less prevalent product types. Following from previously conducted NOAA and non-NOAA Federal spatial prioritization exercises, the results of this regional focus can help mapping organizations better understand how their priorities align with the needs of regional organizations, allow for more efficient coordination and funding, and enable partners to leverage assets and resources to fill their most pressing data and information gaps across Great Lakes waters. The U.S. Mapping Coordination Site hosts the results of this study and other spatial prioritization studies. Through this website, one can interact with the study results along with recent and planned mapping efforts. NOAA intends to update their spatial priorities on a three- to five-year basis. Future studies should strive to expand participation of federal agencies, state and local governments, federally-recognized tribes, academia, and private industry (among other stakeholders) to seek out ocean mapping partnerships in conjunction with the National Ocean Mapping, Exploration and Characterization (NOMEC) goals map once, use many times.”

Great Lakes↗

POLARIS properties: 30-meter probabilistic maps of soil properties over the contiguous United States

Soils play a critical role in the cycling of water, energy, and carbon in the Earth system. Until recently, due primarily to a lack of soil property maps of a sufficiently high‐quality and spatial detail, a minor emphasis has been placed on providing high‐resolution measured soil parameter estimates for land surface models and hydrologic models. This study introduces Probabilistic Remapping of SSURGO (POLARIS) soil properties—a database of 30‐m probabilistic soil property maps over the contiguous United States (CONUS). The mapped variables over CONUS include soil texture, organic matter, pH, saturated hydraulic conductivity, Brooks‐Corey and Van Genuchten water retention curve parameters, bulk density, and saturated water content. POLARIS soil properties was assembled by (1) depth harmonizing and aggregating the pedons in the National Cooperative Soil Survey Soil Characterization Database and the components in Soil Survey Geographic Database into a database of 21,481 different soil series, each soil series having its own vertical profiles of different soil properties, (2) pruning the original POLARIS soil series maps using conventional soil maps to improve soil series prediction accuracy, and (3) merging the assembled soil series databases with the pruned POLARIS soil series maps to construct the soil property maps over CONUS. POLARIS soil properties includes 100‐bin histograms for each layer and variable per grid cell and a series of summary statistics at 30‐, 300‐, and 3,000‐m spatial resolution. Evaluation of POLARIS soil properties using in situ measurements shows an average R2 of 0.41, normalized root‐mean‐square error of 12%, and a normalized mean absolute error of 8.8%.

Water Resources Research↗

Use of ground-based remotely sensed data for surface energy balance evaluation of a semiarid rangeland

An interdisciplinary field experiment was conducted to study the water and energy balance of a semiarid rangeland watershed in southeast Arizona during the summer of 1990. Two subwatersheds, one grass dominated and the other shrub dominated, were selected for intensive study with ground-based remote sensing systems and hydrometeorological instrumentation. Surface energy balance was evaluated at both sites using direct and indirect measurements of the turbulent fluxes (eddy correlation, variance, and Bowen ratio methods) and using an aerodynamic approach based on remote measurements of surface reflectance and temperature and conventional meteorological information. Estimates of net radiant flux density ( R n ), derived from measurements of air temperature, incoming solar radiation, and surface temperature and radiance compared well with values measured using a net radiometer (mean absolute difference (MAD) ≃ 50 W/m 2 over a range from 115 to 670 W/m 2 ). Soil heat flux density ( G ) was estimated using a relation between G / R n and a spectral vegetation index computed from the red and near-infrared surface reflectance. These G estimates compared well with conventional measurements of G using buried soil heat flux plates (MAD ≃ 20 W/m 2 over a range from −13 to 213 W/m 2 ). In order to account for the effects of sparse vegetation, semiempirical adjustments to the single-layer bulk aerodynamic resistance approach were required for evaluation of sensible heat flux density ( H ). This yielded differences between measurements and remote estimates of H of approximately 33 W/m 2 over a range from 13 to 303 W/m 2 . The resulting estimates of latent heat flux density, LE , were of the same magnitude and trend as measured values; however, a significant scatter was still observed: MAD ≃ 40 W/m 2 over a range from 0 to 340 W/m 2 . Because LE was solved as a residual, there was a cumulative effect of errors associated with remote estimates of R n , G , and H .

Water Resources Research↗

Assessment of the role of bottomland hardwoods in sediment and erosion control

Drainage and clearing of bottomland hardwoods have long been recognized by the U.S. Environmental Protection Agency (EPA) and the U.S. Fish and Wildlife Service (Service) as important impacts of Federal water projects in the lower Mississippi River Valley. More recently, the water quality impacts of such projects (e.g., increases in sediments, nutrients, and pesticides) have also become of concern. In 1984, in an effort to better define problems concerning wetland losses and water degradation, EPA initiated a cooperative project with the Western Energy and Land Use Team (now the National Ecology Research Center) of the Service. Three phases of the project were identified: 1. To collect existing literature and data; 2. To select, develop, and test the utility of methods to quantify the relationships between land use, cover types, soils, hydrology, and water quality (as represented by sediment); and 3. To apply selected methodologies to several sites within the Yazoo Basin of Mississippi to determine the, potential effectiveness of various management alternatives to reduce sediment yield, increase sediment deposition, and improve water quality. Methods development focused on linking a simulation of water and sediment movement to a computerized geographic information system. We had several objectives for the resulting model. We desired that it should: 1. Estimate the importance of bottomland and hardwoods as a cover type that performs the functions of erosion and sediment control, 2. Simulate effects of proportions of ' various cover types and their specific spatial configurations, 3. Be applicable to moderately large spatial areas with minimal site-specific calibration, 4. Simulate spatial patterns of sediment loss-gain over time, and 5. Represent both sediment detachment and transport. While it was recognized that impacts and management alternatives could be sorted roughly into landscape measures and channel measures, the decision was made to focus study efforts mainly on landscape measures. Landscape measures include altered drainage and flooding patterns, altered cover types (e.g., conversion of bottomland hardwoods to agricultural crops, reforestation of cropland to bottomland hardwoods, and creation of riparian buffer strips), altered cropping and tillage patterns, altered routing of water, and creation of buffer strips along wetlands and channel margins. Channel measures include vegetative bank stabilization, grade control structures, and regulation of channel water volume and velocity. During the first year of the study, EPA decided not to fund the third phase of the project. This required considerable rescoping of the project with the result that application of the sediment mobilization, routing, and deposition models to various management alternatives and portions of the Yazoo Basin was somewhat restricted. We believe, however, that this report will provide a good understanding of the various modes of sediment mobilization, transport, and deposition within the Yazoo Basin, as well as of the role of bottomland hardwoods. The model developed in this study could be applied to a variety of management or mitigation alternatives prior to implementation to determine their relative effectiveness. Policy, political, and socio-economic consequences of any proposed management/mitigation practice, however, must ultimately be taken into consideration by those charged with management of water resources within the Yazoo Basin before any practice is implemented. This study makes no effort to judge the feasibility of management alternatives in this regard.

Report↗

Precision and accuracy of manual water-level measurements taken in the Yucca Mountain area, Nye County, Nevada, 1988-90

Water-level measurements have been made in deep boreholes in the Yucca Mountain area, Nye County, Nevada, since 1983 in support of the U.S. Department of Energy's Yucca Mountain Project, which is an evaluation of the area to determine its suitability as a potential storage area for high-level nuclear waste. Water-level measurements were taken either manually, using various water-level measuring equipment such as steel tapes, or they were taken continuously, using automated data recorders and pressure transducers. This report presents precision range and accuracy data established for manual water-level measurements taken in the Yucca Mountain area, 1988-90. Precision and accuracy ranges were determined for all phases of the water-level measuring process, and overall accuracy ranges are presented. Precision ranges were determined for three steel tapes using a total of 462 data points. Mean precision ranges of these three tapes ranged from 0.014 foot to 0.026 foot. A mean precision range of 0.093 foot was calculated for the multiconductor cable, using 72 data points. Mean accuracy values were calculated on the basis of calibrations of the steel tapes and the multiconductor cable against a reference steel tape. The mean accuracy values of the steel tapes ranged from 0.053 foot, based on three data points to 0.078, foot based on six data points. The mean accuracy of the multiconductor cable was O. 15 foot, based on six data points. Overall accuracy of the water-level measurements was calculated by taking the square root of the sum of the squares of the individual accuracy values. Overall accuracy was calculated to be 0.36 foot for water-level measurements taken with steel tapes, without accounting for the inaccuracy of borehole deviations from vertical. An overall accuracy of 0.36 foot for measurements made with steel tapes is considered satisfactory for this project.

Water-Resources Investigations Report↗

Hydrology and snowmelt simulation of Snyderville Basin, Park City, and adjacent areas, Summit County, Utah

Increasing residential and commercial development is placing increased demands on the ground- and surface-water resources of Snyderville Basin, Park City, and adjacent areas in the southwestern corner of Summit County, Utah. Data collected during 1993-95 were used to assess the quantity and quality of the water resources in the study area. Ground water within the study area is present in consolidated rocks and unconsolidated valley fill. The complex geology makes it difficult to determine the degree of hydraulic connection between different blocks of consolidated rocks. Increased ground-water withdrawal during 1983- 95 generally has not affected ground-water levels. Ground-water withdrawal in some areas, however, caused seasonal fluctuations and a decline in ground-water levels from 1994 to 1995, despite greater-than-normal recharge in the spring of 1995. Ground water generally has a dissolved-solids concentration that ranges from 200 to 600 mg/L. Higher sulfate concentrations in water from wells and springs near Park City and in McLeod Creek and East Canyon Creek than in other parts of the study area are the result of mixing with water that discharges from the Spiro Tunnel. The presence of chloride in water from wells and springs near Park City and in streams and wells near Interstate Highway 80 is probably caused by the dissolution of applied road salt. Chlorofluorocarbon analyses indicate that even though water levels rise within a few weeks of snowmelt, the water took 15 to 40 years to move from areas of recharge to areas of discharge. Water budgets for the entire study area and for six subbasins were developed to better understand the hydrologic system. Ground-water recharge from precipitation made up about 80 percent of the ground-water recharge in the study area. Ground-water discharge to streams made up about 40 percent of the surface water in the study area and ground-water discharge to springs and mine tunnels made up about 25 percent. Increasing use of ground water has the potential to decrease discharge to streams and affect both the amount and quality of surface water in the study area. A comparison of the 1995 to 1994 water budgets emphasizes that the hydrologic system in the study area is very dependent upon the amount of annual precipitation. Although precipitation on the study area was much greater in 1995 than in 1994, most of the additional water resulted in additional streamflow and spring discharge that flows out of the study area. Ground-water levels and groundwater discharge are dependent upon annual precipitation and can vary substantially from year to year. Snowmelt runoff was simulated to assist in estimating ground-water recharge to consolidated rock and unconsolidated valley fill. A topographically distributed snowmelt model controlled by independent inputs of net radiation, meteorological parameters, and snowcover properties was used to calculate the energy and mass balance of the snowcover.

Utah↗